CN101792285A - Chromium-free environment-friendly epoxy anticorrosion primer - Google Patents

Chromium-free environment-friendly epoxy anticorrosion primer Download PDF

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CN101792285A
CN101792285A CN 201010138075 CN201010138075A CN101792285A CN 101792285 A CN101792285 A CN 101792285A CN 201010138075 CN201010138075 CN 201010138075 CN 201010138075 A CN201010138075 A CN 201010138075A CN 101792285 A CN101792285 A CN 101792285A
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primer
anticorrosion
component
mixed
chromium
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CN 201010138075
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CN101792285B (en )
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国建坡
张雅琴
林志宏
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德莱特恩环保涂料(北京)有限公司
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Abstract

The invention relates to an environment-friendly double-component epoxy anticorrosion primer without containing heavy metals such as chromium and the like. The primer is prepared from components A and B, wherein the component A contains bisphenol A epoxy resin, active dilute, tinting pigment, antirust pigment, filler, auxiliary agent, mixed solvent and the like; and the component A is a curing agent component and contains two cashew nut shell modified phenolic aldehyde amine curing agents with different amine values and a mixed solvent. During use, the components A and B are mixed in a weightratio of 5 to 1. The anticorrosion primer does not contain the heavy metals such as chromium and the like, and meanwhile has excellent anticorrosion performance, physical and mechanical properties, salt mist resistance and acid and alkali resistance. The primer is particularly suitable for coating steel materials, aluminum materials, aluminum alloy and the like, and can be used as a surface anticorrosion primer for airplanes, rapid trains and the like with high anticorrosion requirements. The primer can be normally constructed even at the low temperature of 5 DEG C below zero, and has excellent matching property with finishing paint.

Description

无铬环保环氧防腐底漆 Environmental non-chromium anticorrosive primer Epoxy

技术领域 FIELD

[0001] 本发明涉及一种防腐底漆,更具体的,涉及一种双组分无铬环保环氧防腐底漆。 [0001] The present invention relates to an anti-corrosion primer, more particularly, it relates to a two-component epoxy anti-corrosion primer chromium-free environmentally friendly.

背景技术 Background technique

[0002] 环氧防腐底漆被广泛的用于船舶、管道内外壁、矿井钢架、飞机、高速列车等重防腐领域。 [0002] The epoxy anticorrosive primer is widely used in the field of heavy duty marine, pipe inner and outer walls, mines steel, aircraft, high-speed trains. 为了获得更佳的防腐蚀效果,现有的环氧防腐底漆中一般都加有含铬的防锈颜料,例如含六价铬的铬酸盐等,来提高防腐性能。 In order to obtain better anti-corrosion effect, the conventional epoxy anticorrosive primer is generally added a chromium-containing anticorrosive pigment such as a chromate containing hexavalent chromium to improve the corrosion resistance. 如中国专利申请公开CN101457116A、 CN100526406C公开了双组分的防腐涂料,采用了锌黄、铬黄、锶黄、磷铬酸锌等作为其防锈颜料的必要成分,这些颜料所含的金属铬对人体有害,尤其六价铬具有致癌性。 Chinese Patent Application Publication CN101457116A, CN100526406C discloses a two-component anti-corrosion coating, using a zinc yellow, chrome yellow, strontium yellow, zinc chromate phosphate as an essential component of its anti-rust pigments, these pigments contain chromium to harmful, especially hexavalent chromium is carcinogenic. 底漆中含有铬等重金属颜料会在涂料的制备、施工以及成膜后的使用期间,对施工人员和环境造成严重危害。 Will, during the preparation of the construction and the use of the coating after film formation, causing serious harm to the construction personnel and the environment primers containing heavy metals such as chromium pigments.

[0003] 为此,国内外陆续开发出一些无铬的防腐涂料,如中国专利申请公开CN101260252 公开了一种无铬达克罗涂料,以鳞片状锌粉和铝粉作为防锈颜料。 [0003] For this purpose, at home and abroad have developed a number of non-chromium anticorrosive coating, as disclosed in Chinese Patent Application No. CN101260252 discloses a chromium-free coating Dacromet, zinc and aluminum flakes to a rust preventive pigment. 然而,此类涂料在耐候性方面存在一定缺陷。 However, there are some defects in the coating such weather resistance. 在飞机、高速列车等的应用中,由于涂层所处环境温度在短时间内发生急剧变化,对防腐底漆的性能提出了更高的要求,在这些应用中使用的底漆必须具有与底材更强的附着力以及更好的韧性,否则随着温度的变化引起的底材热胀冷縮,涂层与底材的附着力将不断劣化,韧性变差,发生脆化和出现裂纹,使用一段时间之后会引起涂层脱落和剥离,失去防腐作用。 In aircraft applications, such as high-speed trains, due to dramatic changes in the environment temperature coating occurs in a short time, the performance of anti-corrosion primer put forward higher requirements, the primer used in these applications must have the bottom material stronger adhesion and better toughness, or with the substrate thermal expansion and contraction due to temperature changes, adhesion of the coating and the substrate will continue to deteriorate in toughness, and embrittlement cracks, after a period of time will cause the coating peeling off and lose corrosion.

[0004] 因此,开发一种环保且具有一定韧性,耐冲击、防腐、可在低温_5°C固化的综合性能优异的防腐涂料,越来越受到人们的高度重视。 [0004] Thus, the development of an environmentally friendly and has a certain toughness, impact resistance, corrosion protection, at low temperatures _5 ° C cured anticorrosive coating excellent in overall performance, more and more people's attention.

发明内容 SUMMARY

[0005] 本发明要解决的技术问题是克服现有的环氧防腐底漆存在的不环保、漆膜韧性差易脆的缺点,提供一种无铬环氧防腐底漆。 [0005] The present invention is to overcome the technical problem of environmental protection existing in the prior anticorrosive epoxy primer disadvantage brittle film poor toughness, there is provided a non-chromium anticorrosive epoxy primer. 该底漆对底材具有良好的附着力,在气候急剧变化的环境条件下能够保持对底材良好的附着力和韧性,从而为底材提供良好的防护。 The primer has excellent adhesion to the substrate, under the rapidly changing climate conditions can be maintained good adhesion and toughness of the substrate, thereby providing good protection for the substrate. [0006] 本发明提供了一种双组分无铬环氧防腐底漆,由A组分和B组分按照5 : 1的重量比配制而成,其中: [0006] The present invention provides a two-component non-chromium anticorrosive epoxy primer, 5 in accordance with the A and B components: 1 ratio by weight of the preparation, wherein:

[0007] A组分包含按照重量份计的以下成分: [0007] A component comprises the following ingredients parts by weight meter according to:

[0008] 双酚A环氧树脂20〜35 [0008] Bisphenol A epoxy resin 20~35

[0009] 活性稀释剂1〜6 [0009] The reactive diluent 1~6

[0010] 颜料:着色颜料8〜16 [0010] Pigment: coloring pigment 8~16

[0011] 防锈颜料10〜30 [0011] The anti-corrosive pigment 10~30

[0012] 填料:超细石英粉3〜10 [0012] Filler: superfine quartz powder 3~10

[0013] 铝粉2〜8 [0013] Aluminum 2~8

[0014] 滑石粉8〜15 [0014] talc 8~15

[00巧]助剂:附着力促进剂1〜5[0016] 防沉防流挂助剂0. 3〜1 [00 Qiao] additives: adhesion promoter ~ 5 [0016] The anti-sagging anti-settling aids 0. 3~1

[0017] 分散齐U 0. 5〜1.5 [0017] Homogeneous dispersion U 0. 5~1.5

[0018] 流平剂0. 3〜1 [0018] Leveling agent 0.5 3~1

[0019] 消泡齐U 0. 3〜1 [0019] anti-foaming Qi U 0. 3~1

[0020] 混合溶剂:丙二醇甲醚醋酸酯3〜15 [0020] mixed solvent: propylene glycol methyl ether acetate 3~15

[0021] 丁醇1〜10 [0021] butanol 1~10

[0022] 二甲苯1〜15 [0022] Xylene 1~15

[0023] B组分包含按照重量份计的以下成分: [0023] B component comprises the following ingredients in accordance with the terms of parts by weight:

[0024] 胺值为180〜210腰果壳改性酚醛胺固化剂25〜40 [0024] The amine value of 180~210 modified phenolic cashew nut shell liquid amine curing agent 25~40

[0025] 胺值为220〜270腰果壳改性酚醛胺固化剂25〜40 [0025] The amine value of 220~270 modified phenolic cashew nut shell liquid amine curing agent 25~40

[0026] 二甲苯5〜20 [0026] Xylene 5~20

[0027] 丁醇5〜20 [0027] butanol 5~20

[0028] 三甲苯5〜20。 [0028] mesitylene 5~20.

[0029] 其中,所述的双酚A环氧树脂可以是:601 (E-20) 、618 (E-51)、 1001、 128或828,优 [0029] wherein the epoxy resin may be bisphenol A: 601 (E-20), 618 (E-51), 1001, 128, or 828, preferably

选采用两种不同分子量的双酚A环氧树脂搭配使用。 Two different molecular weights selected from the group of bisphenol A epoxy resin with use. 其中环氧树脂601例如是无锡树脂厂生产的0191-X-75环氧树脂。 Wherein the epoxy resin 601, for example, the Wuxi Resin Factory 0191-X-75 epoxy resin. 特别优选的是将分子量为850〜1050的中分子量双酚A环氧树脂601和分子量为300〜417的液体双酚A环氧树脂618共同作为双酚A环氧树脂成分。 Particularly preferred is a molecular weight of 850~1050 bisphenol A epoxy resin having a molecular weight of 601 and a molecular weight of a liquid bisphenol A epoxy resin of 618 300~417 together as bisphenol A epoxy resin component.

[0030] 所述活性稀释剂可赋予涂料韧性,如带有不饱和脂肪酸长链的醇醚,例如卡德莱 [0030] The reactive diluent may impart toughness coatings, such as having a long-chain unsaturated fatty alcohol ethers, e.g. Cardolite

公司的NX-513 ;或(^〜CM縮水甘油醚型活性稀释齐U,例如Epodil 748 (AGE);或者是气味 's NX-513; or (^ ~CM glycidyl ether reactive diluent homogeneous U, for example, Epodil 748 (AGE); or smell

小、粘度低的縮水甘油醚型活性稀释剂,例如张家港卡邦化工有限公司的KB-62。 Small, low viscosity reactive diluents glycidyl ether type, for example, KB-62 Zhangjiagang Chemical Co. Capone.

[0031] 所述着色颜料采用钛白粉、不含铬的有机黄色颜料或者酞菁蓝颜料。 The [0031] use of a coloring pigment titanium dioxide, chromium-free organic yellow pigment or phthalocyanine blue pigment. 钛白粉优选 Titanium dioxide is preferred

金红石型钛白粉,例如R902+。 Rutile titanium dioxide, such as R902 +.

[0032] 所述防锈颜料为三聚磷酸铝、磷酸锌、Heubach公司的SRPP (改性水合多聚磷酸锶铝)或者Pigmentan公司的465M(磷酸氨基氧化镁盐)。 The [0032] anti-rust pigment is aluminum tripolyphosphate, zinc, Heubach, the SRPP Company (a modified hydrated strontium aluminum polyphosphate) or Pigmentan's 465M (amino acid magnesium salt). [0033] 所述超细石英粉是市售产品,例如矽比科的X7。 [0033] The superfine quartz powder are commercially available products, e.g. Sibelco of X7.

[0034] 所述附着力促进剂例如是加拿大Canfair Technologies的AP3000、德谦1121、德固萨LTW或KH560硅烷偶联剂。 [0034] The adhesion promoter is, for example, Canadian Canfair Technologies AP3000, Deuchem 1121, Degussa LTW or KH560 silane coupling agent.

[0035] 所述防沉防流挂助剂是有机膨润土、气相二氧化硅或者改性脲溶液。 [0035] The anti-sagging anti-settling aids are organic bentonite, fumed silica or a modified urea solution. 所述改性脲溶液是BYK-410。 The modified urea solution is BYK-410.

[0036] 所述分散剂例如是毕克公司的BYK-P104S、 BYK-103或ANTI-TERRA-U等常用分散剂。 [0036] The dispersing agent is, for example, Bi Kegong Division BYK-P104S, BYK-103 ANTI-TERRA-U, or the like commonly used dispersing agents.

[0037] 所述腰果壳改性酚醛胺固化剂可以商购,其中胺值为180〜210的腰果壳改性酚醛胺固化剂例如是卡德莱NX-2015、卡德莱NX-2015A或者是上海美东生物材料有限公司的MD2015、MD2015C或MD2041 ;所述胺值为220〜270的腰果壳改性酚醛胺固化剂例如是卡德莱NX-2041、济南运嘉化工有限公司的YJC-301或者YJC_102。 The [0037] modified phenolic cashew nut shell commercially available amine curing agent, wherein the cashew nut shell value 180~210 phenolic modified amine curing agents, for example, an amine Cardolite NX-2015, or Cardolite NX-2015A MD2015, MD2015C or MD2041 US East Shanghai Co. biological material; amine value of the cashew nut shell liquid modified phenolic amine curing agent 220~270 example Cardolite NX-2041, Jinan Yunjia Chemical Co. YJC-301 or YJC_102. 上述两种不同胺值的腰果壳改性酚醛胺固化剂搭配使用。 Cashew nut shell liquid modified phenolic amine curing agent of the two different values ​​with the use of amines.

[0038] 本发明还提供了该无铬环保环氧防腐底漆的制备方法,其包括以下步骤: [0039] 1)配制组分A [0038] The present invention further provides a method for preparing the chromium-free environmentally friendly anti-corrosion epoxy primer, comprising the steps of: [0039] 1) Preparation of component A

5[0040] 首先制备色浆:将组分A中部分的双酚A环氧树脂与活性稀释剂、分散剂、防沉防流挂助剂、混合溶剂加入拌合罐分散均匀,再加入颜料和填料,搅拌搅匀,加入砂磨机中,研磨至细度合格,过滤,备用; 5 [0040] was first prepared paste: A bisphenol A epoxy resin component with the active portion diluents, dispersing agents, anti-sagging anti-settling aids, mixing tank was added a mixed solvent of uniform dispersion, then adding pigments and a filler, stir stirring, was added a sand mill, ground to a fineness qualified, filtered, standby;

[0041] 将该研磨好的色浆加入调漆罐,加入组分A中剩余的成分,搅拌均匀,测粘度达80〜120秒后,过滤、包装得组分A ; [OO42] (2)配制组分B [0041] After the paste was added lapped paint cans, added the remaining ingredients of component A, uniformly stirring, the viscosity was measured 80~120 seconds, filtered, packaged component A; [OO42] (2) formulation component B

[0043] 按配方量依次将组分B的各个成分加入容器中,搅拌均匀,过滤,包装得到组分B ; [0044] (3)使用前将A组分和B组分按照5 : 1的重量比混合均匀,采用无气喷涂或者常规空气喷涂或者刷涂施工。 [0043] The components according to the formula amount of the respective components are sequentially added to the vessel B, stir, filter and packaged to obtain component B; [0044] (3) Before using the A and B components of 5: 1 by weight were mixed to homogeneity using a conventional airless spray or air spray or brush application.

[0045] 若采用高压喷涂施工,无需添加稀释剂,将A组分和B组分按照5 : 1的重量比混合均匀即可喷涂。 [0045] When using high-pressure spray, without adding a diluent, the A and B components of 5: 1 by weight were mixed to homogeneity to spraying.

[0046] 对本发明对所使用的底材没有特别的限制,可以列举的底材包括钢材、铝合金、不锈钢等等。 [0046] There is no particular restriction on the substrate used in the present invention include substrates include steel, aluminum, stainless steel and the like. 特别优选的底材是铝合金底材。 A particularly preferred substrate is an aluminum alloy substrate.

[0047] 本发明的底漆对于后续施涂的面漆或者中涂漆的性能、种类没有限制,配套性好。 [0047] The primer of the present invention is not limited in the paint or topcoat applied subsequent performance, type, matching is good. 通常本领域常规使用的面漆或者中涂漆都可以用于本发明的底漆上。 Or the topcoat paint typically used in conventional in the art may be used in the primer of the invention. 所述的面漆或者中涂漆包括但不限于环氧、丙烯酸、聚氨酯、聚酯、醇酸、酚醛和乙烯类涂料。 The intermediate coat or topcoat include, but are not limited to, epoxy, acrylic, polyurethane, polyester, alkyd, vinyl and phenolic-based paint.

[0048] 本发明的底漆特别适用于飞机、高速列车上使用,以提供优异的防腐性能和机械性能。 [0048] The primer of the present invention is particularly suitable for aircraft use on high-speed train, to provide excellent corrosion resistance and mechanical properties.

[0049] 本发明具有以下的有益效果: [0049] The present invention has the following advantages:

[0050] 1.环保性能好,在防锈颜料的选择上摒弃了对人和环境危害很大的含铅、铬等重金属颜料,最终的涂料组合物和涂层是一种无铬涂料组合物和涂层,不会对作业人员和环境造成危害。 [0050] 1. Good environmental performance, eliminating heavy metal pigments for a lot of human and environmental hazards of lead, chromium and other rust-preventive pigment in the choice of the final coating composition and the coating is a chromium-free coating composition and coatings, will not cause harm to workers and the environment.

[0051] 2.同时,为了弥补无铬颜料与含铬颜料在防腐性能上的差异,本发明选用了三聚磷酸铝、磷酸锌、Heubach公司的SRPP或者Pigmentan公司的465M高性能防锈颜料。 [0051] 2. Meanwhile, in order to compensate for differences in chromium-free chromium-containing pigment and the pigment in the corrosion resistance, the present invention selects the aluminum tripolyphosphate, zinc, Heubach, SRPP company or companies Pigmentan 465M high-performance anti-corrosive pigment. [0052] 3.采用了两种不同胺值的固化剂,并且使用了活性稀释剂、附着力促进剂,大大提高了最终的涂膜对于底材的附着性,获得了优异的附着力效果;涂膜更加致密,防腐性能和机械性能得到提高,其防腐性能相当于或者超过了传统的含铬环氧底漆的防腐性能。 [0052] 3. Use of an amine curing agent, two different values, and the use of a reactive diluent, an adhesion promoter, greatly improving the final coating film for adhesion to the substrate, excellent adhesion effect is obtained; more dense coating film, corrosion resistance and improved mechanical properties, corrosion resistance which equals or exceeds the performance of conventional chromium-containing anticorrosive epoxy primer. [0053] 4.在对最终涂层性能的测试中的发现,由于在涂料组合物中使用了活性稀释剂, 使得最终涂层的韧性大大提高,改善了涂层耐受温度急剧变化的环境的能力。 [0053] 4. the final coating performance test findings, the use of reactive diluents in the coating composition, such that the final coating greatly improved toughness, improved tolerance to sudden change of the coating temperature environment ability. 活性稀释剂在降低涂料V0C含量的同时又能保证漆膜的理化性能,同时还能调节施工操作时间和涂膜的韧性。 Reactive diluent while reducing coating V0C content can guarantee the physical and chemical properties of the film, while adjusting the operating time of the construction and the toughness of the coating. 它独特的结构使它能与各种环氧体系有极佳的相容性,对施工表面有很强烈的浸润性能,对涂层的柔韧性、防腐、耐候防护具有很好的促进作用 Its unique structure enables it to have excellent compatibility with various epoxy systems, have a very strong construction surface wetting properties, has a good role in promoting flexibility, corrosion, weather barrier coating

具体实施方式 detailed description

[0054] 下面结合具体的实施例对本发明优选的实施方案以及其所产生的有益的技术效果进一步作出说明,但是,本领域技术人员应当理解,本发明并不局限于这些具体的实施方式和实施例的内容。 [0054] Examples of specific embodiments further below in conjunction with clarification of the preferred embodiment of the invention, and advantageous technical effects it produces, however, those skilled in the art will appreciate, the present invention is not limited to these embodiments and specific embodiments an example of content.

[0055] 在实施例中,除非另有明确的指示,否则"份"指的是"重量份","比例"指的是"重量比","% "指的是"重量百分比"。 [0055] In an embodiment, unless expressly indicated otherwise, "parts" means "parts by weight" and "ratio" means "weight ratio", "%" means "% by weight." [0056] 实施例1 [0056] Example 1

[0057] 在实施例1中,双酚A环氧树脂为601环氧树脂(无锡树脂厂牌号为0191-X75)和液体环氧树脂618 ;活性稀释剂为卡德莱NX-513 ;着色颜料是金红石型二氧化钛和有机黄色颜料;防锈颜料为三聚磷酸铝(800目)和Pigmentan公司的465M;附着力促进剂是德固萨LTW ;防沉防流挂助剂是有机膨润土和BYK-410 ;分散剂是BYK-103 ;流平剂是BYK-358N ; 消泡剂是BYK-A530 ;胺值为180〜210的腰果壳改性酚醛胺固化剂是卡德莱NX-2015 ;胺值 [0057] In Example 1, a bisphenol A epoxy resin is an epoxy resin 601 (Wuxi Resin Factory designation 0191-X75) 618 and a liquid epoxy resin; reactive diluent is Cardolite NX-513; color pigments rutile titanium dioxide and an organic yellow pigment; anti-rust pigment is aluminum tripolyphosphate (800 mesh) and Pigmentan's 465M; adhesion promoter is the LTW Degussa; anti-sagging anti-settling aids are organic bentonite and BYK- 410; dispersing agent is BYK-103; leveling agent is BYK-358N; defoamer is BYK-A530; amine value 180~210 cashew nut shell liquid modified phenolic curing agents are amine Cardolite NX-2015; amine value

为220 - 〜270的腰果壳改性酚醛胺固化剂是上海美东生物材料有限公司的MD2041。 Is 220-- ~270 cashew nut shell liquid modified phenolic amine curing agent is a biological material MD2041 Shanghai US East Limited. [0058] 底漆1的制备: Preparation [0058] Primer 1:

[0059] A组分包含按照重量份的以下成分: [0059] A component comprising the following ingredients according to the parts by weight:

[0060] 双酚A环氧树脂0191-X75 24 [0060] a bisphenol A epoxy resin 0191-X75 24

[0061] 双酚A环氧树脂618 5 [0061] a bisphenol A epoxy resin 6,185

[0062] 活性稀释剂:NX-513 3 [0062] The reactive diluent: NX-513 3

[0063] 着色颜料:二氧化钛 8 [0063] coloring pigment: Titanium dioxide 8

[0064] 有机黄色颜料 0. 6 [0064] Organic yellow pigment 0.6

[0065] 防锈颜料:465M 8 [0065] The anti-corrosive pigment: 465M 8

[0066] 三聚磷酸铝(800目) 10. 3 [0066] The aluminum tripolyphosphate (800 mesh) 10.3

[0067] 填料:超细石英粉X7 7 [0067] Filler: superfine quartz powder X7 7

[0068] 铝粉 2 [0068] 2 Aluminum

[0069] 滑石粉(soo目) 10 [0069] Talc (Soo mesh) 10

[0070] 助剂:附着力促进剂:德固萨LTW 3 [0070] additives: adhesion promoter: Degussa LTW 3

[0071] 防沉防流挂助剂:有机膨润土 0. 5 [0071] The anti-sagging anti-settling aids: Organic bentonite 0.5

[0072] BYK-410 0. 3 [0072] BYK-410 0. 3

[0073] 分散剂:BYK-103 1 [0073] Dispersant: BYK-103 1

[0074] 流平剂:BYK-358N 0. 6 [0074] Leveling agent: BYK-358N 0. 6

[0075] 消泡剂:BYK A530 0. 5 [0075] The defoaming agent: BYK A530 0. 5

[0076] 混合溶剂:丙二醇甲醚醋酸酯 5. 5 [0076] mixed solvent: propylene glycol methyl ether acetate 5.5

[0077] 丁醇 3 [0077] 3-butanol

[0078] 二甲苯 7. 7 [0078] Xylene 7.7

[0079] B组分包含按照重量份计的以下成分: [0079] B component comprises the following ingredients in accordance with the terms of parts by weight:

[0080] 腰果壳改性酚醛胺固化剂NX-2015 32 [0080] The modified phenolic cashew nut shell liquid amine curing agent NX-2015 32

[0081] 腰果壳改性酚醛胺固化剂MD2041 30 [0081] The modified phenolic cashew nut shell liquid amine curing agent MD2041 30

[0082] 二甲苯 23 [0082] Xylene 23

[0083] 丁醇 8 [0083] 8-butanol

[0084] 三甲苯 7 [0084] 7-trimethylbenzene

[0085] 制备方法如下: [0085] was prepared as follows:

[0086] 1)配制组分A [0086] 1) Preparation of component A

[0087] 首先制备色浆:将组分A中的两种环氧树脂各取2/3,与活性稀释剂、分散剂 防流挂助剂、混合溶剂加入拌合罐分散均匀,再加入颜料和填料,搅拌搅匀,加入砂磨机中, [0087] First Preparation of Ink: The two from each of the epoxy resin component A 2/3, and a reactive diluent, an anti-sagging agent, dispersing aids, mixing tank was added a mixed solvent of uniform dispersion, then adding pigments and a filler, stir stirring, was added a sand mill,

研磨至细度合格,过滤,备用;[0088] 将该研磨好的色浆加入调漆罐,加入组分A中剩余的成分,搅拌均匀,测粘度达80〜120秒后,过滤、包装得组分A ; [0089] (2)配制组分B Passing to a fineness of grind, filtered standby; after [0088] The colorant is added lapped paint cans, component A was added the remaining ingredients, mix well, measuring the viscosity of 80~120 seconds, filtered, packaged component A; [0089] (2) preparation of component B

[0090] 按配方量依次将组分B的各个成分加入容器中,搅拌O. 5〜1小时,过滤包装得到组分B ; [0090] The components according to the formula amount of the respective components are sequentially added to the vessel B, O. 5~1 hours with stirring, filtered to give the packaging component B;

[0091] (3)使用前将A组分和B组分按照5 : 1的重量比混合,即获得所述的涂料组合物。 [0091] (3) Before using the A and B components of 5: 1 weight ratio mixture, i.e., obtain a coating composition according to.

[0092] 实施例2 [0092] Example 2

[0093] 在实施例2中,活性稀释剂为C12〜C14縮水甘油醚;防锈颜料是三聚磷酸铝(800 目)和Heubach公司的SRPP ;附着力促进剂是加拿大CanfairTechnologies的AP_3000。 [0093] In Example 2, the reactive diluent is glycidyl ether C12~C14; anti-rust pigments are aluminum tripolyphosphate (800 mesh) and the SRPP Heubach's; adhesion promoter of Canada CanfairTechnologies AP_3000. 胺值为180〜210的固化剂是卡德莱NX-2015A,胺值为220〜270的固化剂是济南运嘉化工有限公司的YJC-301。 180~210 amine value of the curing agent is Cardolite NX-2015A, the curing agent is an amine value of 220~270 YJC-301 Chemical Co., Ltd., Jinan Yunjia. 其它与实施例1相同。 Other same as in Example 1.

[0094] A组分包含按照重量份的以下成分: [0094] A component comprising the following ingredients according to the parts by weight:

[0095] 双酚A环氧树脂0191-X75 24 [0095] a bisphenol A epoxy resin 0191-X75 24

[0096] 双酚A环氧树脂618 5 [0096] a bisphenol A epoxy resin 6,185

[0097] 活性稀释剂:C12〜C14縮水甘油醚 2 [0097] The reactive diluent: C12~C14 ether 2

[0098] 着色颜料:二氧化钛 8 [0098] coloring pigment: Titanium dioxide 8

[0099] 有机黄色颜料 0. 6 [0099] Organic yellow pigment 0.6

[0100] 防锈颜料:SRPP 10 [0100] anticorrosive pigments: SRPP 10

[0101] 三聚磷酸铝(800目) 10 [0101] Aluminum Triphosphate (800 mesh) 10

[0102] 填料:超细石英粉X7 7 [0102] Filler: superfine quartz powder X7 7

[0103] 铝粉 2 [0103] 2 Aluminum

[0104] 滑石粉(soo目) 10. [0104] Talc (Soo mesh) 10.

[0105] 助剂:附着力促进剂:AP-3000 2 [0105] additives: adhesion promoter: AP-3000 2

[0106] 防沉防流挂助剂:有机膨润土 0. 5 [0106] Anti-sagging anti-settling aids: Organic bentonite 0.5

[0107] BYK-410 0. 5 [0107] BYK-410 0. 5

[0108] 分散剂:BYK-103 1 [0108] Dispersant: BYK-103 1

[0109] 流平剂:BYK-358N 0. 6 [0109] Leveling agent: BYK-358N 0. 6

[0110] 消泡剂:BYK-A530 0. 5 [0110] antifoaming agent: BYK-A530 0. 5

[o川] 混合溶剂:丙二醇甲醚醋酸酯 5. 7 [O Chuan] a mixed solvent: propylene glycol methyl ether acetate 5.7

[0112] 丁醇 3 [0112] 3-butanol

[0113] 二甲苯 7 [0113] Xylene 7

[0114] B组分包含按照重量份计的以下成分: [0115] 腰果壳改性酚醛胺固化剂NX-2015A 30 [0114] B component comprises the following ingredients in accordance with the terms of parts by weight: [0115] modified phenolic cashew nut shell liquid amine curing agent NX-2015A 30

[0116] 腰果壳改性酚醛胺固化剂YJC-301 35 [0116] modified phenolic cashew nut shell liquid amine curing agent YJC-301 35

[0117] 二甲苯 19 [0117] Xylene 19

[0118] 丁醇 8 [0118] 8-butanol

[0119] 三甲苯 8 [0119] trimethylbenzene 8

[0120] 实施例2的制备方法与实施例1相同。 Preparation [0120] Example 2 is the same as in Example 1. [0121: [0121:

[0122: [0123: [0122: [0123:

施例 Example

[0124: [0125: [0126: [0127: [0128: [0129: [0124: [0125: [0126: [0127: [0128: [0129:

[0130: [0131: [0130: [0131:

[0132: [0133: [0134: [0135: [0136: [0137: [0138: [0139: [0132: [0133: [0134: [0135: [0136: [0137: [0138: [0139:

[0140: [0141: [0140: [0141:

[0142: [0143: [0144: [0145: [0146: [0147: [0148: [0149: [0142: [0143: [0144: [0145: [0146: [0147: [0148: [0149:

[0150: [0151: [0150: [0151:

[0152: [0153: [0152: [0153:

A组分和B组分按照5 : 1的重量比混合,即获得所述的涂料组合物。 A and B components of 5: 1 weight ratio mixture, i.e., obtain a coating composition according to. 实施例3 Example 3

在实施例3中,所述活性稀释剂为KB-62 ;附着力促进剂是德固萨LTW ;其它与实2相同。 In Example 3, the reactive diluent is a KB-62; adhesion promoter is the LTW Degussa; the same as the other two solid.

A组分包含按照重量份的以下成分: 双酚A环氧树脂0191-X75 24 双酚A环氧树脂618 5 活性稀释剂:KB-62 2 着色颜料:二氧化钛8 有机黄颜料0. 6 A component comprises the following ingredients according to the parts by weight: bisphenol A epoxy resin 0191-X75 24 6185 bisphenol A epoxy resin reactive diluent: KB-62 2 coloring pigments: titanium dioxide, organic yellow pigment 0.6 8

防锈颜料:SRPP 10 三聚磷酸铝(800目) 10 填料:超细石英粉X7 7 铝粉2 滑石粉(800目) 10. 8 Rust paint: the SRPP 10 aluminum triphosphate (800 mesh) filler 10: superfine quartz powder aluminum X7 7 2 talc (800 mesh) 10.8

助剂:附着力促进剂:德固萨LTW 3 防沉防流挂助剂:有机膨润土0. 45 Additives: adhesion promoter: Degussa LTW 3 anti-sagging anti-settling additives: organic bentonite 0.45

BYK-410 0. 3 BYK-410 0. 3

分散剂BYK-103 1 流平剂BYK-358N 0. 5 Dispersant BYK-103 1 leveling agent BYK-358N 0. 5

消泡剂BYK-A530 0. 5 Defoamer BYK-A530 0. 5

混合溶剂:丙二醇甲醚醋酸酯4. 8 A mixed solvent: propylene glycol methyl ether acetate 4.8

丁醇3 二甲苯7.05 B组分包含按照重量份计的以下成分: 腰果壳改性酚醛胺固化剂NX-2015A 30 腰果壳改性酚醛胺固化剂YJC-301 35 二甲苯20 丁醇8 三甲苯7 实施例3的制备方法与实施例1相同。 Xylene Butanol 3 7.05 B component comprises the following ingredients in accordance with the terms of parts by weight: cashew nut shell liquid modified phenolic amine curing agent NX-2015A 30 cashew nut shell liquid modified phenolic amine curing agent YJC-301 35 xylene 20 butanol trimethylbenzene 8 preparation Example 3 of embodiment 7 is the same as in Example 1.

A组分和B组分按照5 : 1的重量比混合,即获得所述的涂料组合物。 A and B components of 5: 1 weight ratio mixture, i.e., obtain a coating composition according to. 对比例1 Comparative Example 1

对比例1中,不使用活性稀释剂,而代之以卡德莱公司非活性稀释剂NX-2020 ;防 Comparative Example 1, the reactive diluent is not used, but instead inert diluent Cardolite Corporation NX-2020; anti-

锈颜料是三聚磷酸铝(800目)和Heubach公司的SRPP: 它与实施例2相同。 Rust pigments are aluminum tripolyphosphate (800 mesh) and Heubach's SRPP: it is the same as in Example 2.

[0154] A组分包含按照重量份的以下成分: [0154] A component comprising the following ingredients according to the parts by weight:

[0155] 双酚A环氧树脂0191-X75 24 [0155] a bisphenol A epoxy resin 0191-X75 24

[0156] 双酚A环氧树脂618 5 [0156] a bisphenol A epoxy resin 6,185

固化剂采用卡德莱NX-2015A,其 Cardolite curing agents using the NX-2015A, which

9:0157] 稀释剂NX-2020 2 9: 0157] diluent NX-2020 2

:0158] 着色颜料:二氧化钛8 : 0158] coloring pigment: Titanium dioxide 8

:0159] 有机黄着色颜料0.6 : 0159] The organic coloring pigment 0.6 Yellow

:0160] 防锈颜料:SRPP 10 : 0160] anticorrosive pigments: SRPP 10

:0161] 三聚磷酸铝(800目) 10 : 0161] aluminum tripolyphosphate (800 mesh) 10

:0162] t真料:超细石英粉X7 7 : 0162] t really expected: superfine quartz powder X7 7

:0163] 铝粉2 : 0163] 2 aluminum powder

:0164] 滑石粉(800目) 10.8 : 0164] talc (800 mesh) 10.8

:0165] 助剂:附着力促进剂:AP3000 2 : 0165] additives: adhesion promoter: AP3000 2

:0166] 防沉防流挂助剂:有机膨润土0.5 : 0166] Anti-sagging anti-settling additives: 0.5 Organic Bentonite

:0167] BYK-410 0.3 : 0167] BYK-410 0.3

:0168] 分散剂:BYK-103 1 : 0168] Dispersant: BYK-103 1

:0169] 流平剂:BYK-358N 0.6 : 0169] Leveling agent: BYK-358N 0.6

:0170] 消泡剂:BYK-A530 0.5 : 0170] antifoaming agent: BYK-A530 0.5

:0171] 混合溶剂:丙二醇甲醚醋酸酯5.7 : 0171] mixed solvent: propylene glycol methyl ether acetate 5.7

:0172] 丁醇3 : 0172] 3-butanol

:0173] 二甲苯7 : 0173] Xylene 7

:0174] B组分包含按照重量份计的以下成分: : 0174] B component comprises the following ingredients in accordance with the terms of parts by weight:

:0175] 腰果壳改性酚醛胺固化剂NX-2015 60 : 0175] cashew nut shell liquid modified phenolic amine curing agent NX-2015 60

:0176] 二甲苯24 : 0176] Xylene 24

:0177] 丁醇8 : 0177] 8-butanol

:0178] 三甲苯8 : 0178] trimethylbenzene 8

:0179] 制备方法同实施例l。 : Preparation 0179] The method of Example l with the embodiment.

[0180] A组分和B组分按照5 : 1的重量比混合,即获得所述的涂料组合物。 [0180] A and B components of 5: 1 weight ratio mixture, i.e., obtain a coating composition according to. [0181] 对比例2 [0181] Comparative Example 2

[0182] 对比例2中,不采用活性稀释剂,防锈颜料用复合磷酸锌,固化剂采用市售的650 聚酰胺固化剂。 [0182] In Comparative Example 2, the reactive diluent is not used, a composite zinc phosphate anticorrosive pigment, a curing agent 650 using a commercially available polyamide curing agents. 其它与实施例3相同。 Other same as in Example 3.

[0183] A组分包含按照重量份的以下成分: [0183] A component comprising the following ingredients according to the parts by weight:

[0184] 双酚A环氧树脂0191-X75 24 [0184] a bisphenol A epoxy resin 0191-X75 24

[0185] 双酚A环氧树脂618 5 [0185] a bisphenol A epoxy resin 6,185

[0186] 着色颜料:二氧化钛 8 [0186] coloring pigment: Titanium dioxide 8

[0187] 有机黄着色颜料 0. 6 [0187] The organic coloring pigment 0.6 Yellow

[0188] 防锈颜料:复合磷酸锌 10 [0188] anticorrosive pigments: zinc phosphate composite 10

[0189] 三聚磷酸铝(800目) 10 [0189] Aluminum Triphosphate (800 mesh) 10

[0190] 填料:超细石英粉X7 7 [0190] Filler: superfine quartz powder X7 7

[0191] 铝粉 2 [0191] 2 Aluminum

[0192] 滑石粉(soo目) 9 [0192] Talc (Soo mesh) 9

[0193] 助剂:附着力促进剂:AP3000 2 [0193] additives: adhesion promoter: AP3000 2

[0194] 防沉防流挂助剂:膨润土 0. 5[0195] BYK-410 0. 3 [0194] Anti-sagging anti-settling additives: Bentonite 0. 5 [0195] BYK-410 0. 3

[0196] 分散剂BYK-103 1 [0196] Dispersant BYK-103 1

[0197] 流平剂BYK-358N 0. 6 [0197] leveling agent BYK-358N 0. 6

[0198] 消泡剂BYK-A530 0. 5 [0198] defoamer BYK-A530 0. 5

[0199] 混合溶剂:丙二醇甲醚醋酸酯 8 [0199] mixed solvent: propylene glycol methyl ether acetate 8

[0200] 丁醇 3 [0200] 3-butanol

[0201] 二甲苯 8. 5 [0201] Xylene 8.5

[0202] B组分包含按照重量份计的以下成分: [0202] B component comprises the following ingredients in accordance with the terms of parts by weight:

[0203] 650聚酰胺固化剂65 [0203] 650 65 polyamide curing agent

[0204] 二甲苯25 [0204] Xylene 25

[0205] 丁醇10 [0205] 10 butoxide

[0206] 制备方法同实施例l。 Preparation [0206] The method of Example l with the embodiment.

[0207] A组分和B组分按照5 : 1的重量比混合,即获得所述的涂料组合物。 [0207] A and B components of 5: 1 weight ratio mixture, i.e., obtain a coating composition according to.

[0208] 将实施例1-3以及对比例1、对比例2使用常规空气喷涂制备样板,并对所形成的 [0208] Examples 1-3 and Comparative Example 1, Comparative Example 2 prepared using conventional air spraying model, and the formed

漆膜的性能,按照国家标准进行检测,结果如下: [0209]<table>table see original document page 12</column></row> <table> Properties of the film, tested in accordance with national standards, results are as follows: [0209] <table> table see original document page 12 </ column> </ row> <table>

[0211] A注:耐盐雾采用GB/T 1991标准,板面不起泡,不生锈;十字划痕处锈蚀宽度《2mm,为合格。 [0211] A NOTE: use of salt spray GB / T 1991 standard, board no foaming, no rust; corrosion width at the cross hatch "2mm, qualified.

[0212] 从上述检测结果中可以看出,与不含活性稀释剂的对比例1的漆膜性能相比较, 本发明的实施例1-3的漆膜性能在固含量、表干时间、柔韧性、附着性能、耐盐雾性能方面都有明显的优势。 [0212] As can be seen from the above detection result, the ratio of diluent to 1 film properties compared with no active, film properties of Examples 1-3 of the present invention in the solid content, dry time, flexible resistance, adhesion properties, salt spray resistance performance has obvious advantages.

[0213] 对比例2不含活性稀释剂制备的油漆溶剂含量高。 [0213] High Comparative Example 2 containing no paint solvent prepared reactive diluent content. 采用聚酰胺固化剂干燥性能 By drying properties of polyamide curing agent

慢,漆膜柔韧性、附着性能、耐盐雾性能方面都对比实施例1-3的漆膜性差。 Slow, film flexibility, adhesion properties, salt spray resistance aspects of Comparative Examples 1-3 difference film embodiment.

[0214] 虽然已经结合目前被认为是最实用和优选的实施方案对本发明进行了描述,但是 [0214] While there has been in conjunction with what is presently considered to be the most practical and preferred embodiments of the present invention has been described,

应当理解本发明并不仅仅局限于上述所公开的实施方案,本领域技术人员能够想到在本发 It should be understood that the present invention is not limited to the embodiments disclosed above, it will occur to those skilled in the present

明的主旨和精神内对本发明的技术方案进行改变和改进,而不脱离在附加的权利要求书中 Ming within the spirit and the technical spirit of the present invention changes and modifications without departing from the appended claims

所定义的本发明的范范围。 Fan scope of the invention as defined herein.

Claims (11)

  1. 一种双组分无铬环氧防腐底漆,由A组分和B组分按照5∶1的重量比配制而成,其中:A组分包含按照重量份计的以下成分:双酚A环氧树脂 20~35活性稀释剂 1~6颜料:着色颜料 8~16 防锈颜料 10~30填料:超细石英粉 3~10 铝粉 2~8 滑石粉 8~15助剂:附着力促进剂 1~5 防沉防流挂助剂 0.3~1 分散剂 0.5~1.5 流平剂 0.3~1 消泡剂 0.3~1混合溶剂:丙二醇甲醚醋酸酯 3~15 丁醇 1~10 二甲苯 1~15B组分包含按照重量份计的以下成分:胺值为180~210 A two-component non-chromium anticorrosive epoxy primer, in a weight ratio of 5:1 formulated with component A and component B, wherein: component A comprising the following ingredients in accordance with the terms of parts by weight: bisphenol A ring 20 - 35 epoxy resin reactive diluent having 1 to 6 pigment: coloring pigment rust-preventive pigment 10 16 ~ 8 ~ 30 filler: superfine quartz powder 3-10 aluminum 2-8 8-15 talc additives: adhesion promoter 1 to 5, anti-sagging anti-settling aids 0.3-1 dispersant leveling agent 1.5 0.5 ~ 0.3 0.3 ~ 1 ~ 1 antifoaming agent mixed solvent: propylene glycol methyl ether acetate 15 butanol 3 ~ 1 ~ 10 ~ 1 xylene 15B component comprises by weight parts of the meter in accordance with the following ingredients: an amine value of 180 to 210 果壳改性酚醛胺固化剂 25~40胺值为220~270腰果壳改性酚醛胺固化剂 25~40二甲苯 5~20丁醇 5~20三甲苯 5~20。 Nut shell liquid modified phenolic amine curing agent having an amine value of 25 to 220 40 to 270 cashew nut shell liquid modified phenolic amine curing agent 25 to 40 xylene 20 butanol 5 ~ 5 ~ 5 ~ 20 20 mesitylene.
  2. 2. 根据权利要求1所述的双组分无铬环氧防腐底漆,其中所述的双酚A环氧树脂是分为850〜1050的中分子量双酚A环氧树脂601和分子量为300〜417的液体双酚A环氧树脂618。 The two-component according to claim 1 non-chromium anticorrosive epoxy primer, wherein said bisphenol A epoxy resin is divided 850~1050 molecular weight bisphenol A epoxy resin of molecular weight of 300 and 601 ~417 liquid bisphenol a epoxy resin 618.
  3. 3. 根据权利要求1或2所述的双组分无铬环氧防腐底漆,其中所述活性稀释剂为卡德莱公司的NX-513、Epodil 748、常熟佳发化学有限公司的JX-015或张家港卡邦化工有限公司的KB-62。 The bicomponent claim 1 or claim 2 non-chromium anticorrosive epoxy primer, wherein said reactive diluent is a company Cardolite NX-513, Epodil 748, good hair Changshu Chemical Co. JX- 015 or Capone Zhangjiagang Chemical Co., Ltd. KB-62.
  4. 4. 根据权利要求1所述的双组分无铬环氧防腐底漆,其中所述着色颜料采用钛白粉、 不含铬的有机黄色颜料或者酞青蓝颜料。 4. A non-chromium anticorrosive epoxy primer, wherein said colored pigment using titanium dioxide, chrome-free phthalocyanine blue organic pigment or a yellow pigment according to claim 1 bicomponent claim.
  5. 5. 根据权利要求4所述的双组分无铬环氧防腐底漆,其中所述钛白粉为金红石型钛白粉。 The two-component according to claim 4, wherein the non-chromium anticorrosive epoxy primer, wherein said titanium dioxide is rutile titanium dioxide.
  6. 6. 根据权利要求1所述的双组分无铬环氧防腐底漆,其中所述防锈颜料为三聚磷酸铝、磷酸锌、Heubach公司的SRPP或者Pigmentan公司的465M。 The two-component according to claim 1 non-chromium anticorrosive epoxy primer, wherein the anti-rust pigment is aluminum tripolyphosphate, zinc, Heubach, SRPP company or companies Pigmentan 465M.
  7. 7. 根据权利要求1所述的双组分无铬环氧防腐底漆,其中所述附着力促进剂为加拿大Canfair Technologies的AP3000、德谦1121、德固萨LTW或KH560硅烷偶联剂。 7. A non-chromium anticorrosive epoxy primer, wherein the adhesion promoter AP3000 of Canada Canfair Technologies, Deuchem 1121, Degussa LTW KH560 silane coupling agent or a two-component according to claim 1.
  8. 8. 根据权利要求1所述的双组分无铬环氧防腐底漆,其中所述防沉防流挂助剂是有机膨润土、气相二氧化硅或者改性脲溶液。 8. The two-component according to claim 1 non-chromium anticorrosive epoxy primer, wherein said anti-sagging anti-settling aids are organic bentonite, fumed silica or a modified urea solution.
  9. 9. 根据权利要求8所述的双组分无铬环氧防腐底漆,其中所述改性脲溶液是BYK-410。 According to claim 8, wherein said two-component non-chromium anticorrosive epoxy primer, wherein said modified urea solution is BYK-410.
  10. 10. 根据权利要求1所述的双组分无铬环氧防腐底漆,其中所述胺值为180〜210的腰果壳改性酚醛胺固化剂是卡德莱NX-2015、卡德莱NX-2015A或者是上海美东生物材料有限公司的MD2015、 MD2015C或MD2041 ;所述胺值为220〜270的腰果壳改性酚醛胺固化剂是卡德莱NX-2041、济南运嘉化工有限公司的YJC-301或者YJC_102。 10. The two-component according to claim 1, said non-chromium anticorrosive epoxy primer, wherein the modified phenolic cashew nut shell said amine curing agent is an amine value of 180~210 Cardolite NX-2015, NX Cardolite -2015A or MD2015 Shanghai eastern US biological materials Co., MD2015C or MD2041; modified phenolic cashew nut shell said amine curing agent is an amine value of 220~270 Cardolite NX-2041, Jinan Yunjia Chemical Co. YJC-301 or YJC_102.
  11. 11. 权利要求i-io中任一项所述的双组分无铬环氧防腐底漆的制备方法,包括以下步骤:(1) 配制组分A首先制备色浆:将组分A中部分的双酚A环氧树脂与活性稀释剂、分散剂、防沉防流挂助剂、混合溶剂加入拌合罐分散均匀,再加入颜料和填料,搅拌搅匀,加入砂磨机中,研磨至细度合格,过滤,备用;将该研磨好的色浆加入调漆罐,加入组分A中剩余的成分,搅拌均匀,测粘度达80〜120秒后,过滤、包装得组分A ;(2) 配制组分B按配方量依次将组分B的各个成分加入容器中,搅拌均匀,过滤,包装得到组分B ;(3) 使用前将A组分和B组分按照5 : l的重量比混合均匀,采用无气喷涂或者常规空气喷涂或者刷涂施工。 The method of preparing a two-component according to any i-io non-chromium anticorrosive epoxy primer as claimed in claim 11, comprising the steps of: (1) A first preparing a paste formulation components: Components A portion bisphenol a epoxy resin and reactive diluent, dispersing agent, anti-sagging anti-settling aids, mixing tank was added a mixed solvent of uniform dispersion, adding pigments and fillers, stirring stir, added a sand mill, ground to a qualified fineness, filtered standby; the colorant added lapped paint cans, component a was added the remaining ingredients, mix well, after measuring the viscosity of 80~120 seconds, filtered, packaged component a; ( 2) preparation of component B according to the formula amount of each component in turn, the component B into a vessel, stir, filter and packaged to obtain component B; front (3) using the a and B components in accordance with 5: l of by weight were mixed to homogeneity using a conventional airless spray or air spray or brush application.
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CN102191009A (en) * 2011-03-18 2011-09-21 赣州市赐彩油墨涂料实业有限公司 Double-component modifier and preparation and construction methods thereof
CN102277074A (en) * 2011-07-25 2011-12-14 东来涂料技术(上海)有限公司 A high-opacity waterborne automotive refinish and preparation method
CN102559006A (en) * 2011-12-13 2012-07-11 上海安福隆涂复工业有限公司 Black dacromet paint
CN102559016A (en) * 2011-12-26 2012-07-11 天津美士邦涂料化工有限公司 High solid epoxy paint formula and preparation process as well as application thereof
CN102604511A (en) * 2012-03-05 2012-07-25 大连理工大学 High solid labour-saving paint
CN102775880A (en) * 2012-08-24 2012-11-14 西北永新化工股份有限公司 Low-temperature quick-drying type epoxy paste paint and preparation method thereof
CN102786862A (en) * 2012-07-12 2012-11-21 中国石油天然气集团公司 Multifunctional epoxy primer for offshore platforms and manufacturing method thereof
CN102911586A (en) * 2012-10-24 2013-02-06 江苏纽克莱涂料有限公司 Epoxy anticorrosion decoration paint
CN103013278A (en) * 2012-12-11 2013-04-03 金继典 Bottle transparent blue primer and preparation process thereof
CN103254722A (en) * 2013-04-07 2013-08-21 常州市武进燎原化工有限公司 Special epoxy anticorrosion paint and preparation method thereof
CN103409037A (en) * 2013-08-06 2013-11-27 信和新材料股份有限公司 Solvent type double-composition epoxy coating material quick to solidify at low temperature and preparation method thereof
CN103509425A (en) * 2012-06-28 2014-01-15 永记造漆工业(昆山)有限公司 Solid coating and preparation method thereof
CN103525246A (en) * 2013-09-28 2014-01-22 芜湖中集瑞江汽车有限公司 Rusted antirust paint and preparation method thereof
CN104017458A (en) * 2014-03-31 2014-09-03 中国船舶重工集团公司第七二五研究所 Solvent-free epoxy antirust coating capable of coating with rust and preparation method thereof
CN104087039A (en) * 2014-06-27 2014-10-08 江苏大力城电气有限公司 Protection coating for constant force spring support hanger
CN104449241A (en) * 2014-12-19 2015-03-25 中国海洋石油总公司 Coating system for aerial aircraft
CN104789090A (en) * 2015-04-22 2015-07-22 中航百慕新材料技术工程股份有限公司 Flexible epoxy anticorrosive primer and preparation method thereof
CN105073817A (en) * 2013-03-08 2015-11-18 3M创新有限公司 Gel sealing corrosion prevention tape
CN105219215A (en) * 2015-09-28 2016-01-06 洛阳双瑞防腐工程技术有限公司 Preparing method for high-performance epoxy primer for engineering machinery
CN107090230A (en) * 2017-06-13 2017-08-25 合肥光聚财建筑装饰工程有限公司 Waterborne epoxy primer and preparation method

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Cited By (26)

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CN102191009B (en) 2011-03-18 2013-06-05 赣州市赐彩油墨涂料实业有限公司 Double-component modifier and preparation and construction methods thereof
CN102191009A (en) * 2011-03-18 2011-09-21 赣州市赐彩油墨涂料实业有限公司 Double-component modifier and preparation and construction methods thereof
CN102277074A (en) * 2011-07-25 2011-12-14 东来涂料技术(上海)有限公司 A high-opacity waterborne automotive refinish and preparation method
CN102559006A (en) * 2011-12-13 2012-07-11 上海安福隆涂复工业有限公司 Black dacromet paint
CN102559016A (en) * 2011-12-26 2012-07-11 天津美士邦涂料化工有限公司 High solid epoxy paint formula and preparation process as well as application thereof
CN102559016B (en) 2011-12-26 2014-03-26 天津美士邦涂料化工有限公司 High solid epoxy paint formula and preparation process as well as application thereof
CN102604511A (en) * 2012-03-05 2012-07-25 大连理工大学 High solid labour-saving paint
CN102604511B (en) 2012-03-05 2014-05-21 大连理工大学 High solid labour-saving paint
CN103509425A (en) * 2012-06-28 2014-01-15 永记造漆工业(昆山)有限公司 Solid coating and preparation method thereof
CN102786862A (en) * 2012-07-12 2012-11-21 中国石油天然气集团公司 Multifunctional epoxy primer for offshore platforms and manufacturing method thereof
CN102775880A (en) * 2012-08-24 2012-11-14 西北永新化工股份有限公司 Low-temperature quick-drying type epoxy paste paint and preparation method thereof
CN102911586B (en) * 2012-10-24 2015-10-07 江苏纽克莱涂料有限公司 Epoxy anticorrosive coating Rust
CN102911586A (en) * 2012-10-24 2013-02-06 江苏纽克莱涂料有限公司 Epoxy anticorrosion decoration paint
CN103013278A (en) * 2012-12-11 2013-04-03 金继典 Bottle transparent blue primer and preparation process thereof
CN105073817A (en) * 2013-03-08 2015-11-18 3M创新有限公司 Gel sealing corrosion prevention tape
CN103254722A (en) * 2013-04-07 2013-08-21 常州市武进燎原化工有限公司 Special epoxy anticorrosion paint and preparation method thereof
CN103409037A (en) * 2013-08-06 2013-11-27 信和新材料股份有限公司 Solvent type double-composition epoxy coating material quick to solidify at low temperature and preparation method thereof
CN103525246A (en) * 2013-09-28 2014-01-22 芜湖中集瑞江汽车有限公司 Rusted antirust paint and preparation method thereof
CN104017458A (en) * 2014-03-31 2014-09-03 中国船舶重工集团公司第七二五研究所 Solvent-free epoxy antirust coating capable of coating with rust and preparation method thereof
CN104087039A (en) * 2014-06-27 2014-10-08 江苏大力城电气有限公司 Protection coating for constant force spring support hanger
CN104087039B (en) * 2014-06-27 2016-05-25 江苏大力城电气有限公司 One kind of constant force spring hangers with a protective coating
CN104449241A (en) * 2014-12-19 2015-03-25 中国海洋石油总公司 Coating system for aerial aircraft
CN104789090A (en) * 2015-04-22 2015-07-22 中航百慕新材料技术工程股份有限公司 Flexible epoxy anticorrosive primer and preparation method thereof
CN104789090B (en) * 2015-04-22 2017-07-14 中航百慕新材料技术工程股份有限公司 A flexible epoxy anti-corrosion primer and preparation method
CN105219215A (en) * 2015-09-28 2016-01-06 洛阳双瑞防腐工程技术有限公司 Preparing method for high-performance epoxy primer for engineering machinery
CN107090230A (en) * 2017-06-13 2017-08-25 合肥光聚财建筑装饰工程有限公司 Waterborne epoxy primer and preparation method

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