CN101792124B - Method for producing hydrogen chloride and sodium hydrogen sulfate crystals by taking rock salt as raw material - Google Patents
Method for producing hydrogen chloride and sodium hydrogen sulfate crystals by taking rock salt as raw material Download PDFInfo
- Publication number
- CN101792124B CN101792124B CN2010190260648A CN201019026064A CN101792124B CN 101792124 B CN101792124 B CN 101792124B CN 2010190260648 A CN2010190260648 A CN 2010190260648A CN 201019026064 A CN201019026064 A CN 201019026064A CN 101792124 B CN101792124 B CN 101792124B
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- CN
- China
- Prior art keywords
- sodium
- sulfuric acid
- rock salt
- raw material
- pyrosulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title claims abstract description 59
- 235000002639 sodium chloride Nutrition 0.000 title claims abstract description 51
- 239000011780 sodium chloride Substances 0.000 title claims abstract description 44
- 239000013078 crystal Substances 0.000 title claims abstract description 39
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229910000041 hydrogen chloride Inorganic materials 0.000 title claims abstract description 38
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 title claims abstract description 38
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 title claims abstract description 24
- 239000002994 raw material Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 229910000342 sodium bisulfate Inorganic materials 0.000 title claims abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 145
- 239000000203 mixture Substances 0.000 claims abstract description 76
- 238000006243 chemical reaction Methods 0.000 claims abstract description 56
- 238000000034 method Methods 0.000 claims abstract description 34
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 33
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 32
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000002425 crystallisation Methods 0.000 claims description 48
- JXAZAUKOWVKTLO-UHFFFAOYSA-L sodium pyrosulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OS([O-])(=O)=O JXAZAUKOWVKTLO-UHFFFAOYSA-L 0.000 claims description 45
- 230000008025 crystallization Effects 0.000 claims description 44
- 229910000831 Steel Inorganic materials 0.000 claims description 17
- 239000010959 steel Substances 0.000 claims description 17
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 16
- 238000009413 insulation Methods 0.000 claims description 15
- 238000000967 suction filtration Methods 0.000 claims description 15
- 230000000977 initiatory effect Effects 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 abstract description 25
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000000706 filtrate Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 42
- 239000000243 solution Substances 0.000 description 16
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
- 239000005864 Sulphur Substances 0.000 description 12
- 238000010521 absorption reaction Methods 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 7
- 239000000047 product Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 241001131796 Botaurus stellaris Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 description 1
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- ZINYVIQFBRWMQB-UHFFFAOYSA-K S(=O)(=O)([O-])OS(=O)(=O)[O-].Cl[Na].[Na+].[Na+] Chemical compound S(=O)(=O)([O-])OS(=O)(=O)[O-].Cl[Na].[Na+].[Na+] ZINYVIQFBRWMQB-UHFFFAOYSA-K 0.000 description 1
- KYAXVUURGCWDJW-UHFFFAOYSA-N [K].P(=O)(O)(O)[O-].[NH4+] Chemical compound [K].P(=O)(O)(O)[O-].[NH4+] KYAXVUURGCWDJW-UHFFFAOYSA-N 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HRQGCQVOJVTVLU-UHFFFAOYSA-N bis(chloromethyl) ether Chemical compound ClCOCCl HRQGCQVOJVTVLU-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- -1 ester compound Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
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Abstract
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2010190260648A CN101792124B (en) | 2010-02-05 | 2010-02-05 | Method for producing hydrogen chloride and sodium hydrogen sulfate crystals by taking rock salt as raw material |
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CN2010190260648A CN101792124B (en) | 2010-02-05 | 2010-02-05 | Method for producing hydrogen chloride and sodium hydrogen sulfate crystals by taking rock salt as raw material |
Publications (2)
Publication Number | Publication Date |
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CN101792124A CN101792124A (en) | 2010-08-04 |
CN101792124B true CN101792124B (en) | 2012-03-07 |
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CN2010190260648A Expired - Fee Related CN101792124B (en) | 2010-02-05 | 2010-02-05 | Method for producing hydrogen chloride and sodium hydrogen sulfate crystals by taking rock salt as raw material |
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Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102153111B (en) * | 2011-02-28 | 2012-07-04 | 绍兴市东湖生化有限公司 | Method for preparing anhydrous sodium hydrogen sulfate by using ethephon production waste liquid |
CN103396286B (en) * | 2013-07-19 | 2015-09-23 | 淮阴师范学院 | With the method that sodium-chlor and low-concentration ethanol are raw material production monochloroethane |
CN106044801A (en) * | 2016-05-26 | 2016-10-26 | 中国中轻国际工程有限公司 | Process for producing sodium bisulfate from sodium sulfate and sodium chloride containing carrier |
CN106672904A (en) * | 2017-01-23 | 2017-05-17 | 科莱环境工程(北京)有限公司 | Method for comprehensively treating sulfur-containing flue gas and solid waste abraum salt |
CN106672903A (en) * | 2017-01-23 | 2017-05-17 | 科莱环境工程(北京)有限公司 | Method of recycling solid waste salts in chemical wastewater |
CN106731582A (en) * | 2017-01-23 | 2017-05-31 | 科莱环境工程(北京)有限公司 | A kind of method of integrated treatment sulfide hydrogen acid waste gas and solid waste carnallite |
CN109384198A (en) * | 2018-12-13 | 2019-02-26 | 中南大学 | A method of hydrochloric acid is produced with sodium chloride |
CN114436898A (en) * | 2020-11-02 | 2022-05-06 | 田雨 | Production process of guanidine sulfate |
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2010
- 2010-02-05 CN CN2010190260648A patent/CN101792124B/en not_active Expired - Fee Related
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Owner name: JIANGSU YINZHU CHEMICAL GROUP CO., LTD. Effective date: 20120321 |
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C41 | Transfer of patent application or patent right or utility model | ||
C53 | Correction of patent for invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Chu Xiaozhong Inventor after: Qian Huaiguo Inventor after: Xu Rui Inventor after: Lv Yu Inventor after: Zhang Weiguang Inventor after: Lv Jinshun Inventor after: Zhao Yijiang Inventor after: Xu Jiming Inventor after: Su Juan Inventor after: Zhou Shouyong Inventor after: Li Meisheng Inventor after: Liu Wenxin Inventor before: Chu Xiaozhong Inventor before: Zhang Weiguang Inventor before: Lv Jinshun Inventor before: Zhao Yijiang Inventor before: Xu Jiming Inventor before: Su Juan Inventor before: Zhou Shouyong Inventor before: Li Meisheng |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: CHU XIAOZHONG ZHANG WEIGUANG LV JINSHUN ZHAO YIJIANG XU JIMING SU JUAN ZHOU SHOUYONG LI MEISHENG TO: CHU XIAOZHONG ZHANG WEIGUANG LV JINSHUN ZHAO YIJIANG XU JIMING SU JUAN ZHOU SHOUYONG LI MEISHENG LIU WENXIN QIAN HUAIGUO XU RUI LV YU |
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TR01 | Transfer of patent right |
Effective date of registration: 20120321 Address after: 223300 Huaian Changjiang Road, Huaiyin District, Jiangsu, No. 111 Co-patentee after: Jiangsu Yinzhu Chemical Group Co., Ltd. Patentee after: Huaiyin Normal College Address before: 223300 Huaian Changjiang Road, Huaiyin District, Jiangsu, No. 111 Patentee before: Huaiyin Normal College |
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Application publication date: 20100804 Assignee: Nanjing, Hongze spices company limited Assignor: Huaiyin Normal University|Jiangsu Yinzhu Chemical Group Co. Ltd. Contract record no.: 2013320000472 Denomination of invention: Method for producing hydrogen chloride and sodium hydrogen sulfate crystals by taking rock salt as raw material Granted publication date: 20120307 License type: Exclusive License Record date: 20130530 |
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