CN101787187A - Resin button difficult to break and processing method - Google Patents
Resin button difficult to break and processing method Download PDFInfo
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- CN101787187A CN101787187A CN201010042873A CN201010042873A CN101787187A CN 101787187 A CN101787187 A CN 101787187A CN 201010042873 A CN201010042873 A CN 201010042873A CN 201010042873 A CN201010042873 A CN 201010042873A CN 101787187 A CN101787187 A CN 101787187A
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Abstract
The invention discloses a resin button difficult to break and a processing method. The button comprises a main material and an auxiliary material, wherein the auxiliary material comprises the following components in percentage by weight: 0.8-1.0 percent of accelerating agent, 0.5-1.2 percent of pearl pigment and 1.0-1.2 percent of curing agent; and the rest besides the auxiliary material is the main material comprising the following components in percentage by weight: 87-92 percent of o-phthalate resin and 5-10 percent of isophthalic type resin. The invention changes the formula of the resin button and ensures that the resin button not only meets the ASTM D5171 standard of the U.S.A in hardness, but also can greatly reduce the production cost.
Description
Technical field
The present invention discloses a kind of button and working method, particularly a kind of resin button difficult to break and working method.
Background technology
Along with the raising of people's living standard, also more and more higher to the requirement of clothes, relatively as one of auxiliary material of clothes---the performance of resin button has also proposed higher requirement.At present, the U.S. has put into effect a kind of inspecting standard of button, it is the standard of ASTM-D5171, it requires to test to hardness of resin, in numerous button manufacturer, in order to satisfy the inspecting standard of the U.S., adopt the metaphenylene production of resins mostly, as the DS-905 resin of Milky Way resin, the BSH-2057 resin of Changzhou Hua Ri etc., but the isophthalic resin price is all higher, makes the resin button cost high.
Summary of the invention
At the above-mentioned high shortcoming of mentioning of isophthalic resin button cost of the prior art, the invention provides a kind of prescription and working method of new resin button difficult to break, resin button difficult to break adds other batching in adjacent benzene resin, make its hardness can reach the standard that meets, and greatly reduce cost.
The technical scheme that the present invention solves its technical problem employing is: a kind of resin button difficult to break, it is characterized in that: described button comprises major ingredient and auxiliary material, and described auxiliary material comprises that weight ratio is that the promotor of 0.8-1.0%, pearly pigment and the weight ratio that weight ratio is 0.5-1.2% are the solidifying agent of 1.0%-1.2%; Other adopt major ingredient, and described major ingredient comprises that weight ratio is the adjacent benzene type resin of 87-92% and the metaphenylene resin that weight ratio is 5-10%.
A kind of as above-mentioned manufacture method of resin button difficult to break, manufacture method comprises the steps:
A, with after the mixing of materials, under 36 ℃-38 ℃ temperature, made sheet material in 3 minutes 30 seconds to 4 minutes at the centrifugal barrel inner gel;
B, taking-up sheet material are tiled on the grillage, with the test of food sclerometer, treat to use when hardness reaches 70-75 Pasteur the dicing machine pelletizing;
C, the base pellet is immersed in proportion fully is 1.38, and temperature is in 89-91 ℃ the salt solution, under the non-pressurized condition water bath processing 29-31 minute;
D, the button blank cooled off fully after, with the test of Ba Keer sclerometer, hardness reaches 20-25 crust back and is processed into button with the system deduction.
The technical scheme that the present invention solves its technical problem employing further comprises:
Described promotor is adopted cobalt naphthenate.
Described solidifying agent adopts methylethyl ketone peroxide.
Described adjacent benzene type resin adopts 92%, and described metaphenylene resin adopts 5%.
The invention has the beneficial effects as follows: the present invention has changed the prescription of resin button, makes it not only can satisfy the standard of U.S. ASTM-D5171 on hardness, and production cost is reduced greatly.
The present invention will be further described below in conjunction with embodiment.
Embodiment
Present embodiment is the preferred embodiment for the present invention, and other all its principle is identical with present embodiment or proximate with basic structure, all within protection domain of the present invention.
Resin button material among the present invention comprises major ingredient and auxiliary material, auxiliary material comprises that weight ratio is that the promotor of 0.8-1.0%, pearly pigment and the weight ratio of 0.5-1.2% are the solidifying agent of 1.0%-1.2%, in the present embodiment, promotor is adopted cobalt naphthenate, and the model that can select for use AEKYUNG CHEMICAL CO.LTD company to produce is the promotor of RP-126; Pearly pigment adopts the pearl white pearlite slurry, and the model that can select for use Merck KGaA company to produce is Biflair 88 pearly pigments; Solidifying agent adopts methylethyl ketone peroxide, the methylethyl ketone peroxide that can select for use Luoyang bimonthly solidifying agent company limited to produce.Except that the auxiliary material of fixed proportion, other materials is a major ingredient, major ingredient comprises that weight ratio is the adjacent benzene type resin of 87-92%, in the present embodiment, the model that adjacent benzene type resin adopts sky, Nantong and resin company limited to produce is the unsaturated polyester resin of DS-987 and the metaphenylene resin that weight ratio is 5-10%, in the present embodiment, the model that the metaphenylene resin adopts sky, Nantong and resin company limited to produce is the unsaturated polyester resin of DS-292.To be divided into several embodiments below is described in detail the present invention:
Embodiment one: major ingredient adopts 95%DS-987 resin and 2%DS-292 resin, add corresponding auxiliary material, the Ba Keer hardness (GB3854-1987) of the button of making is the 22-25 crust, and 15 buttons carry out striking experiment under U.S. ASTM-D5171 standard, 15 buttons break 8, and are defective.
Embodiment two: major ingredient adopts 92%DS-987 resin and 5%DS-292 resin, add corresponding auxiliary material, the Ba Keer hardness (GB3854-1987) of the button of making is the 20-25 crust, 15 buttons carry out striking experiment under U.S. ASTM-D5171 standard, 15 buttons all pass through, and do not have fracture phenomena.
Embodiment two: major ingredient adopts 91%DS-987 resin and 6%DS-292 resin, add corresponding auxiliary material, the Ba Keer hardness (GB3854-1987) of the button of making is the 20-25 crust, 15 buttons carry out striking experiment under U.S. ASTM-D5171 standard, 15 buttons all pass through, and do not have fracture phenomena.
Embodiment three: major ingredient adopts 90%DS-987 resin and 7%DS-292 resin, add corresponding auxiliary material, the Ba Keer hardness (GB3854-1987) of the button of making is the 20-23 crust, 15 buttons carry out striking experiment under U.S. ASTM-D5171 standard, 15 buttons all pass through, and do not have fracture phenomena.
Embodiment four: major ingredient adopts 89%DS-987 resin and 8%DS-292 resin, add corresponding auxiliary material, the Ba Keer hardness (GB3854-1987) of the button of making is the 20-23 crust, 15 buttons carry out striking experiment under U.S. ASTM-D5171 standard, 15 buttons all pass through, and do not have fracture phenomena.
Embodiment five: major ingredient adopts 88%DS-987 resin and 9%DS-292 resin, add corresponding auxiliary material, the Ba Keer hardness of the button of making is 20 crust, and 15 buttons carry out striking experiment under U.S. ASTM-D5171 standard, 15 buttons all pass through, and do not have fracture phenomena.
Embodiment six: major ingredient adopts 87%DS-987 resin and 10%DS-292 resin, add corresponding auxiliary material, the Ba Keer hardness of the button of making is 20 crust, and 15 buttons carry out striking experiment under U.S. ASTM-D5171 standard, 15 buttons all pass through, and do not have fracture phenomena.
The manufacture method that the present invention adopts above-mentioned prescription to make button comprises the steps:
A, with after the mixing of materials, under 36 ℃-38 ℃ temperature, made sheet material in 3 minutes 30 seconds to 4 minutes at the centrifugal barrel inner gel;
B, taking-up sheet material are tiled on the grillage, with the test of food sclerometer, treat to use when hardness reaches 70-75 Pasteur the dicing machine pelletizing;
C, the base pellet is immersed in proportion fully is 1.38, and temperature is in the salt solution of 90 ℃ (temperature value is optional be used in 90 ± 1 ℃ the scope temperature), water bath processing 30 minutes under the non-pressurized condition (time is optional be used in 30 ± 1 minutes the scope treatment time);
D, the button blank cooled off fully after, with the test of Ba Keer sclerometer, hardness reaches 20-25 crust back and is processed into button with the system deduction.
In the present embodiment, step B, C and D are with of the prior art identical.
Claims (6)
1. resin button difficult to break, it is characterized in that: described button comprises major ingredient and auxiliary material, described auxiliary material comprises that weight ratio is that the promotor of 0.8-1.0%, pearly pigment and the weight ratio that weight ratio is 0.5-1.2% are the solidifying agent of 1.0%-1.2%; Other adopt major ingredient, and described major ingredient comprises that weight ratio is the adjacent benzene type resin of 87-92% and the metaphenylene resin that weight ratio is 5-10%.
2. resin button difficult to break according to claim 1 is characterized in that: described adjacent benzene type resin adopts 92%, and described metaphenylene resin adopts 5%.
3. resin button difficult to break according to claim 1 and 2 is characterized in that: described promotor is adopted cobalt naphthenate.
4. resin button difficult to break according to claim 1 and 2 is characterized in that: described solidifying agent adopts methylethyl ketone peroxide.
5. resin button difficult to break according to claim 1 and 2 is characterized in that: described pearly pigment adopts the pearl white pearlite slurry.
6. the manufacture method of a resin button difficult to break as claimed in claim 1, it is characterized in that: described manufacture method comprises the steps:
A, with after the mixing of materials, under 36 ℃-38 ℃ temperature, made sheet material in 3 minutes 30 seconds to 4 minutes at the centrifugal barrel inner gel;
B, taking-up sheet material are tiled on the grillage, with the test of food sclerometer, treat to use when hardness reaches 70-75 Pasteur the dicing machine pelletizing;
C, the base pellet is immersed in proportion fully is 1.38, and temperature is in 89 ℃-91 ℃ the salt solution, under the non-pressurized condition water bath processing 29-31 minute;
D, the button blank cooled off fully after, with the test of Ba Keer sclerometer, hardness reaches 20-25 crust back and is processed into button with the system deduction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010100428730A CN101787187B (en) | 2010-01-20 | 2010-01-20 | Resin button difficult to break and processing method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010100428730A CN101787187B (en) | 2010-01-20 | 2010-01-20 | Resin button difficult to break and processing method |
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| Publication Number | Publication Date |
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| CN101787187A true CN101787187A (en) | 2010-07-28 |
| CN101787187B CN101787187B (en) | 2011-12-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010100428730A Expired - Fee Related CN101787187B (en) | 2010-01-20 | 2010-01-20 | Resin button difficult to break and processing method |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101933691A (en) * | 2010-09-06 | 2011-01-05 | 俞善锋 | Reflective button and production technology thereof |
| CN101953543A (en) * | 2010-09-06 | 2011-01-26 | 俞善锋 | Luminous button and production technology thereof |
| CN102389185A (en) * | 2011-07-27 | 2012-03-28 | 广东溢达纺织有限公司 | Unsaturated polyester resin button and preparation method thereof |
| CN102551277A (en) * | 2012-01-09 | 2012-07-11 | 广东溢达纺织有限公司 | Thermo-oxidative aging resistant unsaturated polyester resin button and preparation method thereof |
| CN103182760A (en) * | 2012-09-24 | 2013-07-03 | 浙江伟星实业发展股份有限公司 | Resin button and production method |
| CN103181656A (en) * | 2012-10-31 | 2013-07-03 | 浙江伟星实业发展股份有限公司 | Button and manufacturing method thereof |
| CN104026812A (en) * | 2014-06-19 | 2014-09-10 | 浙江伟星实业发展股份有限公司 | Preparation method of unsaturated polyester resin buttons |
| CN105218756A (en) * | 2015-09-30 | 2016-01-06 | 浙江伟星实业发展股份有限公司 | A kind of artificial imitative wooden button and preparation method thereof |
| CN105524394A (en) * | 2015-10-29 | 2016-04-27 | 浙江伟星实业发展股份有限公司 | Metal-simulative button and preparation method thereof |
| CN105985699A (en) * | 2015-01-30 | 2016-10-05 | 浙江伟星实业发展股份有限公司 | Preparation method for color-variable button |
| CN106118368A (en) * | 2016-07-26 | 2016-11-16 | 浙江伟星实业发展股份有限公司 | Production technology and the button of a kind of semi-transparent metals gloss button spray paint |
| CN107141746A (en) * | 2017-05-23 | 2017-09-08 | 浙江伟星实业发展股份有限公司 | A kind of high impact resins button and preparation method thereof |
| CN107383820A (en) * | 2017-07-14 | 2017-11-24 | 深圳联达钮扣有限公司 | A kind of degradable button and preparation method thereof |
| CN107692409A (en) * | 2017-09-14 | 2018-02-16 | 海宁市盛祥线业有限公司 | A kind of kirsite button and its processing method |
| CN109135318A (en) * | 2018-07-20 | 2019-01-04 | 金永福 | A kind of resin button and its preparation process |
| CN109135198A (en) * | 2018-06-29 | 2019-01-04 | 罗顺旺 | A kind of resin button and preparation method thereof |
| CN110591320A (en) * | 2019-09-24 | 2019-12-20 | 深圳联达钮扣有限公司 | PET environment-friendly button and preparation method thereof |
-
2010
- 2010-01-20 CN CN2010100428730A patent/CN101787187B/en not_active Expired - Fee Related
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101953543A (en) * | 2010-09-06 | 2011-01-26 | 俞善锋 | Luminous button and production technology thereof |
| CN101953543B (en) * | 2010-09-06 | 2012-10-03 | 嘉善天路达工贸有限公司 | Luminous button and production technology thereof |
| CN101933691B (en) * | 2010-09-06 | 2013-01-30 | 嘉善天路达工贸有限公司 | Reflective button and production technology thereof |
| CN101933691A (en) * | 2010-09-06 | 2011-01-05 | 俞善锋 | Reflective button and production technology thereof |
| CN102389185A (en) * | 2011-07-27 | 2012-03-28 | 广东溢达纺织有限公司 | Unsaturated polyester resin button and preparation method thereof |
| CN102551277A (en) * | 2012-01-09 | 2012-07-11 | 广东溢达纺织有限公司 | Thermo-oxidative aging resistant unsaturated polyester resin button and preparation method thereof |
| CN103182760B (en) * | 2012-09-24 | 2014-12-17 | 浙江伟星实业发展股份有限公司 | Resin button and production method |
| CN103182760A (en) * | 2012-09-24 | 2013-07-03 | 浙江伟星实业发展股份有限公司 | Resin button and production method |
| CN103181656A (en) * | 2012-10-31 | 2013-07-03 | 浙江伟星实业发展股份有限公司 | Button and manufacturing method thereof |
| CN104026812B (en) * | 2014-06-19 | 2016-06-08 | 浙江伟星实业发展股份有限公司 | The preparation method of a kind of unsaturated polyester resin button |
| CN104026812A (en) * | 2014-06-19 | 2014-09-10 | 浙江伟星实业发展股份有限公司 | Preparation method of unsaturated polyester resin buttons |
| CN105985699A (en) * | 2015-01-30 | 2016-10-05 | 浙江伟星实业发展股份有限公司 | Preparation method for color-variable button |
| CN105218756A (en) * | 2015-09-30 | 2016-01-06 | 浙江伟星实业发展股份有限公司 | A kind of artificial imitative wooden button and preparation method thereof |
| CN105524394B (en) * | 2015-10-29 | 2018-11-20 | 浙江伟星实业发展股份有限公司 | A kind of imitative metal sense button and preparation method thereof |
| CN105524394A (en) * | 2015-10-29 | 2016-04-27 | 浙江伟星实业发展股份有限公司 | Metal-simulative button and preparation method thereof |
| CN106118368A (en) * | 2016-07-26 | 2016-11-16 | 浙江伟星实业发展股份有限公司 | Production technology and the button of a kind of semi-transparent metals gloss button spray paint |
| CN107141746A (en) * | 2017-05-23 | 2017-09-08 | 浙江伟星实业发展股份有限公司 | A kind of high impact resins button and preparation method thereof |
| CN107383820A (en) * | 2017-07-14 | 2017-11-24 | 深圳联达钮扣有限公司 | A kind of degradable button and preparation method thereof |
| CN107692409A (en) * | 2017-09-14 | 2018-02-16 | 海宁市盛祥线业有限公司 | A kind of kirsite button and its processing method |
| CN108741447A (en) * | 2017-09-14 | 2018-11-06 | 海宁市盛祥线业有限公司 | A kind of processing method of kirsite button |
| CN109135198A (en) * | 2018-06-29 | 2019-01-04 | 罗顺旺 | A kind of resin button and preparation method thereof |
| CN109135318A (en) * | 2018-07-20 | 2019-01-04 | 金永福 | A kind of resin button and its preparation process |
| CN110591320A (en) * | 2019-09-24 | 2019-12-20 | 深圳联达钮扣有限公司 | PET environment-friendly button and preparation method thereof |
| CN110591320B (en) * | 2019-09-24 | 2022-04-15 | 深圳联达钮扣有限公司 | PET environment-friendly button and preparation method thereof |
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|---|---|
| CN101787187B (en) | 2011-12-14 |
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