CN101785952B - Desorption method and device with low energy consumption - Google Patents

Desorption method and device with low energy consumption Download PDF

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CN101785952B
CN101785952B CN2009100039956A CN200910003995A CN101785952B CN 101785952 B CN101785952 B CN 101785952B CN 2009100039956 A CN2009100039956 A CN 2009100039956A CN 200910003995 A CN200910003995 A CN 200910003995A CN 101785952 B CN101785952 B CN 101785952B
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desorption
sorbing material
energy consumption
low energy
electrode
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CN101785952A (en
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郑名山
施明宪
黄朝琴
林育立
周雅文
黄廷位
张佑铭
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Industrial Technology Research Institute ITRI
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Abstract

The invention discloses desorption method and device with low energy consumption. An electrode is coupled and electrified with a desorption material and the current is directly connected with the desorption material, so that the desorption material generates a desorption effect and can further maintain the desorption capability for continuous operation. By adopting the method and the device, energy sources required by desorption can be reduced and the desorption efficiency can be improved.

Description

The low energy consumption desorption method and apparatus
Technical field
The present invention relates to a kind of desorption method and device, relate in particular to that a kind of mode of utilizing energising makes the material conduction and a kind of low energy consumption desorption method and apparatus of carrying out desorption.
Background technology
Common sorbing material has porous carbon material, zeolite, silica gel or the like; Organic volatile (volatile organic compound in can absorbed air; VOC) or moisture, usually be to realize continuous operation during use with multi-tower type structure or runner structure.When for example a certain tower adsorbed, another tower just carried out desorption and regeneration, when treating that absorption and desorption and regeneration reach capacity, just exchanged runner.If with rotary-type structure, then can on the area of runner, distinguish the zones of different of desorption and regeneration and absorption, through the rotation of runner, let material alternately through absorption and desorption and regeneration zone, reach the purpose of continuous running.
The method of regeneration desorption, lets the warm-up movement of molecule be enough to destroy sorbing material and be adsorbed intermolecular key knot power or attraction, and reaches the purpose of desorption through hot blast heating sorbing material and the molecule that is adsorbed nothing more than the hot blast through extreme temperatures.This kind desorption method must add hot-air earlier; Transmit desorption through the heat between air and sorbing material again,, add the efficiency of heating surface problem of heater itself by heat loss is arranged between air heater to the sorbing material easily; Therefore, the required energy loss of desorption is very big.In the compact product of this external ask for something, often lack the heater that enough areas are installed in the space, because heat exchange area is not enough, the surface temperature of heater itself is high when therefore adding hot-air, also causes extra radiation heat loss.
For example, Fig. 1 analyzes for the family expenses drip type dehumidifier energy resource consumption of using desiccant wheel, and the surface temperature of heater is high, and the electric energy that therefore most heater consumes is that the mode with radiation sheds.During the power consumption of the family expenses formula dehumidifier in figure one was analyzed, the amount of dripping is about 6.6 liter/day, and (20C, 60%RH), about 600 watts of heater power consumption wherein had 479 watts to be radiant heat, only has 121 watts to be used in and to add hot-air.
The rotary-type adsorption and dehumidification machine of prior art; All be with electric heater thermal regeneration sidewind; Improve the regeneration air temperature; The thermal desorption mechanism that adds of this technology mainly is divided into two partly: (one) air-flow heat exchange vaporization: produce thermograde with the heat cycles air-flow, with the moisture content in the dehumidification structure in the heat vaporization dehumidifying body that heat exchange was produced.Owing to need just can carry out the steam desorption, therefore need high energy consumption just can reach the target of drying dehumidification with high temperature air.(2) radiant heat vaporization: heating wire produces high temperature after through electric current in the heater, and this heat makes the hydrone in the structure in the dehumidifying body can directly absorb radiant heat vaporization desorption with photothermal form.Because radiations heat energy becomes the biquadratic direct ratio with surface temperature, the electric heater surface all is higher than more than 400 ℃, and radiations heat energy is high, and the steam desorption effect that is therefore produced is even more important far beyond the vaporization of the air-flow heat exchange in aforementioned () desorption.
By above-mentioned two vaporization mechanism analysis, the heated type regeneration desorption mode of prior art is no matter be that the heat cycles air-flow causes the indirect vaporizing desorption; Or radiant heat is when being absorbed by hydrone; Most of radiations heat energy is also absorbed by the dehumidifying body, therefore, causes inevasible power consumption source.In addition, radiations heat energy causes absorbent structure surface temperature to rise, and also is unfavorable for the absorption of hydrone, significantly reduces dehumidifying effect.Therefore heated type regeneration desorption method is to cause rotary-type dehydrating unit power consumption higher, the main cause that dehumidification rate reduces.
In order to overcome above-mentioned problem, as shown in Figure 2, it has disclosed and a kind ofly utilizes isoionic mode to replace prior art to add the mode sketch map of thermal desorption dehumidifying body moisture for Japanese publication spy opens 2001-179037.In this technology, utilize the electrode 11 and 12 that is arranged at Dehumidifying element 10 both sides to produce plasma Dehumidifying element 10 adsorbed moisture are broken away from.But in this technology, electrode 11 does not directly contact with Dehumidifying element 10 with 12, comes desorption Dehumidifying element 10 for utilizing point discharge to produce isoionic mode.
Summary of the invention
Technical problem to be solved by this invention provides a kind of low energy consumption desorption method; It makes electric current pass through this sorbing material through sorbing material is directly switched on; By the adsorbed material of this sorbing material,, and can promote desorption efficient with desorption with the needed energy of reduction desorption.
Another technical problem to be solved by this invention is to provide a kind of low energy consumption desorption device; It is to be provided with electrode in the sorbing material both sides; Through making electric current be able to through this sorbing material to this electrifying electrodes, and then desorption is by the adsorbed material of this sorbing material.In addition, the passage of air-guiding can be set more in the zone of counter electrode, make air-flow be able to sorbing material, to increase the speed of desorption through energising.
In one embodiment, the present invention provides a kind of low energy consumption desorption method, includes the following step: provide and use a sorbing material; Both sides in this sorbing material connect conductive electrode; And the conductive electrode that applies a voltage to these both sides makes this sorbing material conducting electric current and then desorption.
In another embodiment, the present invention more provides a kind of low energy consumption desorption device, includes the following step: a sorbing material, and it provides absorption at least one material; The pair of electrodes structure, it connects with the both sides of this sorbing material mutually by chance; And a voltage source, it connects electrode with this mutually by chance, and this voltage source provides a voltage in this electrode structure to be made this sorbing material conducting electric current and then desorption.
In another embodiment, the present invention more provides a kind of low energy consumption desorption device, includes the following step: a sorbing material, and it provides absorption at least one material; The pair of electrodes structure, it connects with the both sides of this sorbing material mutually by chance; One voltage source, it connects electrode with this mutually by chance, and this voltage source provides a voltage in this electrode structure to be made this sorbing material conducting electric current and then desorption; And an air-flow guiding channel, it is arranged at this side to electrode structure.
Comprehensively above-mentioned, low energy consumption desorption method and apparatus provided by the invention reduces the advantage that the energy uses and increases the desorption effect owing to have.Therefore, can improve the competitiveness of this industry and drive arround the development of industry.
Description of drawings
Fig. 1 uses the family expenses drip type dehumidifier energy resource consumption of desiccant wheel for prior art and analyzes sketch map;
Fig. 2 replaces prior art to add the mode sketch map of thermal desorption dehumidifying body moisture for the isoionic mode of utilizing that Japanese publication spy opens the 2001-179037 exposure;
Fig. 3 is a low energy consumption desorption method embodiment schematic flow sheet of the present invention;
Fig. 4 is a low energy consumption desorption device embodiment sketch map of the present invention.
Fig. 5 A is an electrode structure front elevational schematic of the present invention.
Fig. 5 B is electrode structure of the present invention and sorbing material generalized section.
Fig. 6 is an electrode structure action sketch map of the present invention.
Fig. 7 is connected with air-flow guiding channel sketch map for electrode structure of the present invention.
The result of Fig. 8 for testing with the rotary dehumidifier that uses in the dehumidifier.
Wherein, Reference numeral:
The 10-Dehumidifying element
The 11-12 electrode
2-low energy consumption desorption method
20~22-step
The 3-desorption apparatus
30,300-sorbing material
31,32-electrode structure
310-net metal electrode
311,321-Insulating frame
312,322-metal frame
313-desorption structural region
The 314-conductive layer
The 33-voltage source
The 330-brush
34-air-flow guiding channel
The 90-air-flow
The specific embodiment
For making your juror further cognition and understanding arranged to characteristic of the present invention, purpose and function; The hereinafter spy describes the relevant thin portion structure of device of the present invention and the theory reason of design; So that the juror can understand characteristics of the present invention, specify statement as follows:
See also shown in Figure 3ly, this figure is a low energy consumption desorption method embodiment schematic flow sheet of the present invention.In the present embodiment, this method includes the following step, at first provides with step 20 and uses a sorbing material.This sorbing material is used to adsorb organic volatile, nitrogen or moisture, but not as limit.Generally speaking, more commonly this sorbing material is applied to the family expenses dehumidification equipment, for example: and the wheeled dehumidification equipment that dehumidifies, but not as limit.Material as for this sorbing material can be made from porous material, for example: zeolite, silica gel, activated carbon, CNT, the organic framework compound of metal (metal organic framework) etc.In addition, this sorbing material also can be the imporosity material of dehydrogenation metal.
Then carry out step 21, connect conductive electrode in the both sides of this sorbing material.Then, carry out step 22, the conductive electrode that applies a voltage to these both sides makes the material on this sorbing material break away from this sorbing material.In the present embodiment, the voltage that applies can be alternating voltage or DC voltage.When electric current can cause temperature to rise through sorbing material, influence the key knot power that is adsorbed between molecule and sorbing material simultaneously, therefore cause the desorption effect.The mechanism of current lead-through can be the ion transition in the sorbing material, also can be to be adsorbed ion or the proton conduction that dissociating of molecule caused, and also can be the synthesis result of two kinds of effects.If absorption is to liking hydrone, also maybe be because hydrone to the ionization in the sorbing material, increases electrical conductivity.In any case owing to directly to material effects, must not add hot-air earlier, therefore, effect is direct, can reduce heat loss, reduce the desorption energy consumption.In addition, among step 22, more can apply an air-flow, make the zone of its stream of this heat through the energising desorption.Through flowing of this thermal current, more can increase desorption rate, to promote the effect of sorbing material desorption.In one embodiment, this air-flow is the air-flow through the higher temperature of heating, to increase the effect of sorbing material desorption.
See also shown in Figure 4ly, this figure is a low energy consumption desorption device embodiment sketch map of the present invention.In the present embodiment, this device 3 has a sorbing material 30, pair of electrodes structure 31 and 32 and one voltage source 33.This sorbing material 30, it provides absorption at least one material.This sorbing material 30 and the material that can adsorb are not done at this and to be given unnecessary details as previously mentioned.This is to electrode structure 31 and 32, and its both sides with this sorbing material 30 connect mutually by chance.This voltage source 33, its with this to electrode structure 31 and 32 mutually the idol connect, this voltage source 33 provide a voltage in this to electrode structure 31 and 32.This voltage source 33 can be direct current or alternating current.Because electrode structure 31 and 32 is applied to two ends of sorbing material 30, after energising, sorbing material 30 can cause desorption through electric current.
Dehumidification equipment with rotary dehumidifier is an example; In order only to let when rotary dehumidifier rotates the reaction that in the specific region of the sorbing material of rotary dehumidifier, produces desorption; And let the effect of other zone maintenance absorption of sorbing material, on electrode, have more insulator electrode is divided into a plurality of zones.Former between each zone because of the existence that insulator is arranged; Therefore; Only having the specific region to have in the time of can guaranteeing electrifying electrodes can conduct electricity, and makes that the zone of corresponding powered electrode can produce the desorption effect on the sorbing material, and other electrode zone that is not energized then can be kept the ability of absorption.
See also shown in Fig. 5 A, this figure is an electrode structure front elevational schematic of the present invention.In the present embodiment, be example with electrode structure 31, this electrode structure 31 has a net metal electrode 310 and an Insulating frame 311.The material of this net metal electrode 310 does not have certain limitation, so long as can conductive metallic material get final product.Have metal frame 312 in the periphery of this net metal electrode 310, can keep the smooth of this net metal electrode 310 on the one hand, the contact point of contact brush 330 when can be used as rotation on the other hand.And this Insulating frame 311 is arranged at the inside of net metal electrode 310, with being divided into a plurality of desorption structural regions 313 in this net metal electrode 310.This Insulating frame 311 more can be strengthened the structure of net metal electrode 310 except can this net metal electrode 310 being divided into a plurality of conductive regions, and keeps the flatness of net metal electrode 310.Former between the adjacent desorption structural region because of having Insulating frame 311; Therefore can mutually insulated; When brush 330 touched metal frame 312, the desorption structural region that also has only metal frame 312 to be connected to can conduct electricity in the future, and can not arrive adjacent desorption structural region by image.
See also shown in Fig. 5 B, this figure is electrode structure of the present invention and sorbing material partial cutaway schematic.Coat a conductive layer 314 between net metal electrode 310 and the sorbing material 30,, and impel electric current evenly to distribute with the reduction contact resistance.In the present embodiment, this conductive layer 314 is silver medal lacquer or other conductive material.See also shown in Figure 6ly, this figure is an electrode structure of the present invention action sketch map.The both sides of sorbing material 30 have electrode structure 31 and 32 respectively, and the metal frame 312 with brush 30 contacts when sorbing material 30 rotates can touch corresponding desorption structural region, make the desorption structural region conduct electricity.Because electrode structure 31 of the present invention and 32 has the design of Insulating frame 311 and 321; So when brush 330 touches the metal frame 312 of electrode structure 31 and 32 and 322 the time; Because conduction only has the desorption structural region that corresponds to contact position; Therefore, can guarantee only to have the sorbing material 300 that corresponds to the desorption structural region electric current to be arranged through carrying out desorption.Can continue the absorption action as for 30 of the sorbing materials that does not correspond to energising, make this sorbing material 30 can have the effect of absorption and desorption simultaneously.See also shown in Figure 7ly, the both sides of the desorption structural region that is touched at corresponding brush 330 more can be provided with an air-flow guiding channel 34.This air-flow guiding channel 34 can import air-flow 90 in the desorption structural region of corresponding energising, crosses the sorbing material of the desorption structural region of corresponding energising through air communication, will be taken out of by the material of desorption, to increase desorption rate.Take the efficient of material out of in order to increase air-flow, this air-flow 90 can be the higher temperature air-flow through heating, increases desorption rate again with auxiliary desorption.
Above-mentioned desorption method goes for any sorbing material with the ability of conducting and is adsorbed molecular combinations, can be to be applied in fixed bed or tower desorption during enforcement, also can be applied in the runner desorption.For example be applied in the rotary-type dehumidifier that drips of family expenses, the result of Fig. 8 for testing with the rotary dehumidifier that uses in the dehumidifier.About 6.6 liters/day of the former dehumidifier desorption water yield (20 ℃, 60%RH), desorption is to adopt the hot blast mode of heating, required power consumption is 600 watts (as shown in Figure 1), is equivalent to every desorption 1g water yield, needs the energy of 7854J.And in the non-rotary experiment of rotary dehumidifier, adopt electrifying electrodes but not the hot blast desorption, power consumption is merely 4200~4700J/g.
The longitudinal axis among Fig. 8 is the decline degree of rotary dehumidifier weight, the water yield of expression desorption, and transverse axis then is the time.Different curve representative experiments repeatedly, each experimental period length is different, and wherein, the implication of each bar line is following:
Figure G2009100039956D00061
3sec?Wt.D=77mm?#Vin=200
Figure G2009100039956D00062
6sec?Wt.D=77mm?#Vin=200
Figure G2009100039956D00063
10sec?Wt.D=77mm?#Vin=200
Figure G2009100039956D00064
15sec?Wt.D=77mm?#Vin=200。
The numeral that Fig. 8 indicates is that the power consumption of actual measurement is except that the last desorption water yield and get.Can know that by Fig. 8 that adopts electrifying electrodes can (drop to 4200J/g by 7854J/g) more than 45% to economize.Though the data of Fig. 8 are under the situation that rotary dehumidifier does not rotate, to test, identical principle can be utilized in various situation, comprises tower and runner rotary type, and difference only is the change of electrode contacting pattern.
Comprehensively above-mentioned, low energy consumption desorption method and apparatus provided by the invention reduces the advantage that the energy uses and increases the desorption effect owing to have.Therefore, can improve the competitiveness of this industry and drive arround the development of industry.
Certainly; The present invention also can have other various embodiments; Under the situation that does not deviate from spirit of the present invention and essence thereof; Those of ordinary skill in the art work as can make various corresponding changes and distortion according to the present invention, but these corresponding changes and distortion all should belong to the protection domain of the appended claim of the present invention.

Claims (19)

1. a low energy consumption desorption method is characterized in that, includes the following step:
Provide and use a sorbing material;
Both sides in this sorbing material connect conductive electrode, and this conductive electrode has: a net metal electrode, and the periphery of this net metal electrode has metal frame; And, a plurality of Insulating frames, it is arranged at this net metal electrode interior, this net metal electrode is divided into the electrode of a plurality of mutually insulateds, promptly a plurality of desorption structural regions; And,
The conductive electrode that applies a voltage to these both sides makes this sorbing material conducting electric current and then desorption; This voltage provides through brush; When this sorbing material rotates; When this brush touches said metal frame, have only this desorption structural region that is connected to this metal frame to conduct electricity, and do not influence adjacent desorption structural region.
2. low energy consumption desorption method according to claim 1 is characterized in that, this sorbing material is the sorbing material in order to dehumidifying.
3. low energy consumption desorption method according to claim 1 is characterized in that, the adsorbed material of this sorbing material is water, organic volatile or nitrogen.
4. low energy consumption desorption method according to claim 1 is characterized in that, applying also to include after the voltage provides an air communication to cross the material that this sorbing material will break away from this sorbing material to take this sorbing material out of.
5. low energy consumption desorption method according to claim 4 is characterized in that, this air-flow is a process heated air stream.
6. low energy consumption desorption method according to claim 1 is characterized in that, voltage is an alternating voltage or DC voltage.
7. low energy consumption desorption method according to claim 1 is characterized in that, this sorbing material is a made from porous material.
8. low energy consumption desorption method according to claim 1 is characterized in that, this sorbing material is the imporosity material.
9. a low energy consumption desorption device is characterized in that, includes the following step:
One sorbing material, it provides absorption at least one material;
The pair of electrodes structure, it connects with the both sides of this sorbing material mutually by chance, and this electrode structure has: a net metal electrode, the periphery of this net metal electrode has metal frame; And, a plurality of Insulating frames, it is arranged at this net metal electrode interior, this net metal electrode is divided into the electrode of a plurality of mutually insulateds, promptly a plurality of desorption structural regions; And,
One voltage source, it connects electrode with this mutually by chance, this voltage source provide a voltage in this to electrode structure; Make this sorbing material conducting electric current and then desorption; This voltage provides through brush, when this sorbing material rotates, when this brush touches said metal frame; Have only this desorption structural region that is connected to this metal frame to conduct electricity, and do not influence adjacent desorption structural region.
10. low energy consumption desorption device according to claim 9 is characterized in that, this sorbing material is the sorbing material in order to dehumidifying.
11. low energy consumption desorption device according to claim 9 is characterized in that, the adsorbed material of this sorbing material is water, organic volatile or nitrogen.
12. low energy consumption desorption device according to claim 9 is characterized in that, after applying voltage, also including provides an air communication to cross the material that this sorbing material will break away from this sorbing material to take this sorbing material out of.
13. low energy consumption desorption device according to claim 12 is characterized in that, this air-flow is a process heated air stream.
14. low energy consumption desorption device according to claim 9 is characterized in that, voltage is an alternating voltage or DC voltage.
15. low energy consumption desorption device according to claim 9 is characterized in that, this sorbing material is a made from porous material.
16. low energy consumption desorption device according to claim 9 is characterized in that, this sorbing material is an imporosity material.
17. low energy consumption desorption device according to claim 9 is characterized in that, also has a conductive layer between each electrode structure and this sorbing material.
18. low energy consumption desorption device according to claim 9 is characterized in that, this is to also having an air-flow guiding channel on the corresponding each other position of metal electrode.
19. low energy consumption desorption device according to claim 9 is characterized in that, it is for carrying out a rotational motion.
CN2009100039956A 2009-01-24 2009-01-24 Desorption method and device with low energy consumption Expired - Fee Related CN101785952B (en)

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CN103084156A (en) 2011-11-04 2013-05-08 财团法人工业技术研究院 Dehumidification device and electrifying desorption device thereof
JP5453490B2 (en) * 2011-12-21 2014-03-26 財團法人工業技術研究院 Dehumidification and release device and system
CN103638777B (en) * 2013-12-18 2016-02-17 王斌 The runner of rotary dehumidifier
CN106693940A (en) * 2017-03-02 2017-05-24 江苏苏净集团有限公司 Electrothermal desorption molecular sieve device and desorption method
CN107051108A (en) * 2017-04-14 2017-08-18 东南大学 A kind of carbon dioxide adsorption desorption device of Co-generation
CN112958057B (en) * 2021-01-20 2022-05-17 江苏科威环保技术有限公司 Desorption device for enhancing desorption capacity of activated carbon

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