CN101781422B - Formula of non-painted automobile spoiler with metal luster and production process thereof - Google Patents

Formula of non-painted automobile spoiler with metal luster and production process thereof Download PDF

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Publication number
CN101781422B
CN101781422B CN201010138613A CN201010138613A CN101781422B CN 101781422 B CN101781422 B CN 101781422B CN 201010138613 A CN201010138613 A CN 201010138613A CN 201010138613 A CN201010138613 A CN 201010138613A CN 101781422 B CN101781422 B CN 101781422B
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parts
automobile spoiler
abs
aluminium powder
metal luster
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CN101781422A (en
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张敏敏
秦舒浩
于杰
宋洁
郭建兵
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National Composite Modified Polymer Material Engineering Technology Research Cen
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National Composite Modified Polymer Material Engineering Technology Research Cen
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Abstract

The invention provides a non-painted automobile spoiler with metal luster and a production process thereof. The automobile spoiler is prepared from the following components in part by weight: 90 to 100 parts of PP, 5 to 10 parts of talcpowder and 0.5 to 3.5 parts of aluminum powder; or 90 to 100 parts of ABS and 0.5 to 1.5 parts of aluminum powder. The automobile spoiler produced by blending the aluminum powder and the PP or ABS; by using the PP or ABS as a raw material to produce the automobile spoiler, the surface of the automobile spoiler can obtain the metal luster without spraying treatment, and the metal luster is not lost or fades, the inner part of the product still obtains the metal luster even if the surface of the product is scratched or damaged, the surface treatment process of spraying the metal flashing paint on the surface of the product is unnecessary, and the metal luster is high in durability, particularly excellent in light ageing resistance; and in addition, the paint-spraying process step in a process of producing the automobile spoiler adopting the formula is saved, so that the production flow is simplified, and the production cost is greatly lowered.

Description

Non-painted automobile spoiler and production technique with metalluster
Technical field
The present invention relates to a kind of plastic material and production technique, especially a kind of non-painted automobile spoiler and production technique with metalluster.
Background technology
In the painting dressing automobiles, the color of finish paint (color) can be divided into two big types: true qualities (solid colors) and metallic color (metallic colors).True qualities can be divided into Chromatic color (meaning the color that has color such as red, yellow, blue, green) and Achromatic color (meaning not colored colors such as white, grey, black) again by its color.Metallic color also can be subdivided into flash metal luster look and pearly-lustre look, and the tendency of Chromatic colorization.During the nearly last ten years; Automobile finish is coated with reload request high-decorationization (high clarity, high brightness, high flash colorize); Use the automobile of flash metal luster look and pearly-lustre look finish paint to increase year by year, in car coating, surpassed for 50% (car of the country that has and producer's matel coated flash of light look surpasses 70%).The price of matel coated flash of light look finish paint automobile is wanted expensive several thousand yuan than true qualities at home; But still develop very soon; Popularization and application is to the application of minicar, mini-bus, motor bus vehicle body; Heavy automobile cab adopts flash metal luster look finish paint also to occupy certain ratio (like " liberation " of a vapour Qingdao automobile factory, " steyr " of Ji vapour).The application of flash metal luster look originates in later stage the 1950's, is base-material with Nitrocellulose varnish, and to the mid-1960s, the Application and Development of thermosetting acrylic resin makes the application of flash of light look be able to further develop.At that time coating process is identical with the true qualities finish paint, is one to be coated with one and to dry by the fire (1C1B) technology, and film performances such as its outward appearance, weathering resistance, acid resistance, alkali resistance are low; Just produce the disadvantage of the deterioration of filming in a short time.Get into the seventies after all approach improve weathering resistance, scuff resistance and the decorative appearance of filming, just form two be coated with one dry by the fire (2C1B) finish paint Lacquer finish coating process, promptly now background color layer adds the finish paint coating process of Lacquer finish.For adapting to the needs of environmental regulation, American-European newly-built paint line has all adopted the finish paint system of environment-friendly type since the nineties, and promptly the water-based base coat adds the coating varnish (like powder clear coatings, high-solid level varnish or water varnish etc.) of environment-friendly type.
The metallize polychromatic finish need be used custom-designed air gun, and the air gun of using with spraying true qualities finish paint compares, and the paint output is many, and air pressure is high, and injection is large-minded.With strong air pressure aluminium powder is knocked attached on the application surface at a high speed, and the aluminium powder oriented parallel is arranged, a large amount of air volatilizees the solvent in the coating at short notice, the flowing of aluminium powder that is being coated with is prevented from as quick as thought, but the air gun spray efficiency is low.For improving coating efficiency; In recent years the coating process that the electrostatic spraying metal flash paint occurs; When adopting electrostatic spraying metallize flash of light look base coat, being coated with efficient has raising by a relatively large margin, makes aluminium powder arrange to be in filming at electrostatic spraying metallic basecoat occasion electrostatic interaction and is arranged (hair as the people is holded up next at electrostatic field) to being coated with Surface Vertical; Diminish reflection of light, and make appearance of film not good.
The plasthetics that plastic material is processed has advantages such as shaping cycle is short, production efficiency is high, in light weight, therefore receives widespread use, and automobile spoiler is exactly wherein a kind of plastic prod.But the feel of common automobile spoiler is general, and luminance brightness is lower, in use surperficial easy abrasion, and the texture that does not possess present people and pursued, value added is not high.Therefore, carry out suitable surface treatment usually and improve its result of use.In the existing method, disclosed the surface property that the method that plastic rubber substrate is carried out surface coated coating is improved plasthetics.But the coating adhesion that this method exists coating to form is low, comes off easily, wears no resistance; Can't life-time service etc. characteristics, and the method for this coating composition, corresponding different plastic rubber substrate need use different coating; Otherwise sticking power maybe be poorer; And for automobile spoiler in irregular shape surface, lacquering technique is difficulty more, and not environmental protection.
Summary of the invention
The objective of the invention is: a kind of prescription and production technique with non-painted automobile spoiler of metalluster is provided; Adopt technology of the present invention to need not that spray treatment is carried out on the surface of automobile spoiler and just have metalluster; The effect of its metalluster can not come off, fade, and appearance is desirable, and the wearing quality of product is strong; The feature of environmental protection is good, to overcome the deficiency of prior art.
The present invention is achieved in that the non-painted automobile spoiler with metalluster, calculates by weight, is made up of 90~100 parts of PP, 5~10 parts of talcum powder and 0.5~1.5 part of aluminium powder; Or form by 90~100 parts of ABS and 0.5~3.5 part of aluminium powder.
The trade mark of described PP is K8303, and the trade mark of ABS is 301.
Aluminium powder is a silver dollar type aluminium powder.Adopt silver dollar type aluminium powder can make the metallic travel of product outstanding.
Production technique with non-painted automobile spoiler of metalluster; Calculate by weight; 90~100 parts of PP and 5~10 parts of talcous mixtures or 90~100 parts of ABS and 0.5~1.5 part of aluminium powder and 5~10 parts of talcum powder are carried out blend, obtain mixture A behind the thorough mixing; Mixture A is joined fusion and extruding pelletization in the twin screw extruder, obtain plastic granule B; Plastic granule B is joined blow molding in the blow moulding machine, obtain interceptor C.
The extrusion temperature that mixture A joins in the twin screw extruder is 170 ℃~230 ℃, the screw speed 300rad/min of twin screw extruder.
Owing to adopted technique scheme; The present invention is employed among PP or the ABS and adds the aluminium powder blend, and it is used to produce automobile spoiler as material, need not the processing that the surface to automobile spoiler sprays and just has metalluster; And the effect of its metalluster can not come off, fade; Even the surface of goods is abraded, weares and teares, its inside also still has metalluster, and need not carry out the process of surface treatment of metallize polychromatic finish to its surface; And wearing quality is strong, especially has excellent light aging resisting property.Adopt the prepared product of the present invention to have metallic travel, and shaping cycle is short, production efficiency is high, in light weight, be not easy to come off; Advantages such as wear resistance is good; Use this automobile spoiler to save this process step that sprays paint in the production process, simplified Production Flow Chart, can significantly reduce production costs; Implement easily, result of use is good.
Experiment according to changing prescription obtains data as shown in the table
Table 1
Figure GDA0000073781660000031
Data according to the experiment form; We can learn; Along with the add-on increase of aluminium powder, the glossiness of product descends gradually, therefore need the add-on of aluminium powder be controlled in certain scope; Make plastics able to produce metal gloss after promptly guaranteeing to add, can not make the glossiness of product receive obvious influence again; Utilize aluminium powder and PP or ABS blend can significantly increase the shock resistance of material, but its flexural strength can descend.With having added aluminium powder after their blend; The automobile spoiler that obtains of producing can be removed paint from and spray paint and obtain metalluster, has the advantage of environmental protection, has saved this process step that sprays paint in the production process; Produce the effect that resulting product has surperficial metallize polychromatic finish through this prescription and method; And the wearing quality of this metalluster is strong, can also can not lose metalluster because of surface abrasion because of environmental factors comes off; And, therefore reclaim also convenient because does not paint on the automobile spoiler surface.
Embodiment
Embodiments of the invention 1: have the non-painted automobile spoiler of metalluster, calculate by weight, PP, 1.5 parts of silver dollar type aluminium powders and 10 parts of talcum powder of being K8303 with 90 parts of trades mark carry out blend, obtain mixture A behind the thorough mixing; Mixture A is joined in the twin screw extruder, and fusion and extruding pelletization under 200 ℃, the situation of screw speed 300rad/min obtain plastic granule B; Plastic granule B is joined blow molding in the blow moulding machine, obtain interceptor C.
Embodiments of the invention 2: have the non-painted automobile spoiler of metalluster, calculate by weight, the ABS of 100 parts of trades mark 301,1.0 parts of silver dollar type aluminium powders are carried out blend, obtain mixture A behind the thorough mixing; Mixture A is joined in the twin screw extruder, and fusion and extruding pelletization under 230 ℃, the situation of screw speed 300rad/min obtain plastic granule B; Plastic granule B is joined blow molding in the blow moulding machine, obtain interceptor C.

Claims (3)

1. the non-painted automobile spoiler with metalluster is characterized in that: calculate by weight, be made up of 90~100 parts of PP, 5~10 parts of talcum powder and 0.5~1.5 part of silver dollar type aluminium powder; Or form by 90~100 parts of ABS and 0.5~3.5 part of silver dollar type aluminium powder; The trade mark of described PP is K8303, and the trade mark of ABS is 301.
2. production technique with non-painted automobile spoiler of metalluster; It is characterized in that: calculate by weight; 90~100 parts of PP and 5~10 parts of talcous mixtures or 90~100 parts of ABS and 0.5~1.5 part of aluminium powder are carried out blend, obtain mixture A behind the thorough mixing; Mixture A is joined fusion and extruding pelletization in the twin screw extruder, obtain plastic granule B; Plastic granule B is joined blow molding in the blow moulding machine, obtain interceptor C; The trade mark of described PP is K8303, and the trade mark of ABS is 301, and aluminium powder is a silver dollar type aluminium powder.
3. the production technique with non-painted automobile spoiler of metalluster according to claim 2 is characterized in that: the extrusion temperature that mixture A joins in the twin screw extruder is 170 ℃~230 ℃, the screw speed 300rad/min of twin screw extruder.
CN201010138613A 2010-04-02 2010-04-02 Formula of non-painted automobile spoiler with metal luster and production process thereof Expired - Fee Related CN101781422B (en)

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Families Citing this family (5)

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Publication number Priority date Publication date Assignee Title
CN102492216A (en) * 2011-11-14 2012-06-13 江苏金发科技新材料有限公司 Polypropylene material with paint spraying effect and preparation method for polypropylene material
CN104830014A (en) * 2015-04-09 2015-08-12 武圣化学株式会社 Aluminum powder-containing ABS resin, ABS resin particles and production method thereof
CN104827647A (en) * 2015-05-14 2015-08-12 芜湖市金晟中空塑业有限公司 Molding technique for automobile spoiler
CN104999633A (en) * 2015-07-27 2015-10-28 广东工业大学 Device and method for forming metal flash products directly through ultrasonic-assisted injection molding
CN109705517B (en) * 2018-12-28 2021-05-11 金旸(厦门)新材料科技有限公司 Preparation method of micro-foaming ABS material and high-surface-quality light injection molding material

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