CN101781005B - Bionomic precipitator - Google Patents

Bionomic precipitator Download PDF

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Publication number
CN101781005B
CN101781005B CN2010101155232A CN201010115523A CN101781005B CN 101781005 B CN101781005 B CN 101781005B CN 2010101155232 A CN2010101155232 A CN 2010101155232A CN 201010115523 A CN201010115523 A CN 201010115523A CN 101781005 B CN101781005 B CN 101781005B
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China
Prior art keywords
component
weight
bionomic
precipitation agent
ingredient
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Expired - Fee Related
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CN2010101155232A
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Chinese (zh)
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CN101781005A (en
Inventor
王崇宇
贾柠宁
李楠
马文瀚
苏航
卢丽杰
陈寅嵩
王寅
邢文超
路雯潇
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Hebei Agricultural University
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Hebei Agricultural University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention discloses a bionomic precipitator and a preparation method and an application method thereof, which are used for sewage purification and pretreatment of integrated constructed wetland. The bionomic precipitator contains A ingredient and B ingredient at proportion of 1: 1.4-2 in parts by weight, wherein the A ingredient contains 40-50 wt% of reed, 30-40 wt% of eichhornia crassipes and 15-25wt% of lotus leaf, and the B ingredient contains diatomite, vermiculite and active carbon at proportion of 1:2:3 in parts by weight. The A ingredient is prepared through the following steps: breaking and blending reed, eichhornia crassipes and lotus leaf at above proportion by weight, soaking the mixture in deionized water and distilling 30wt% of concentrated solution, and the B ingredient is prepared as follows: mixing and grinding the diatomite, vermiculite and active carbon at proportion of 1:2:3 in parts by weight to powder. The bionomic precipitator is prepared by mixing the A ingredient and the B ingredient at proportion of 1: 1.4-2 in parts by weight, adding the mixture into a kneader and then blending. When the bionomic precipitator is used, the dosage of the bionomic precipitator is 0.2-0.65% of the sewage by weight. The bionomic precipitator is economic, efficient and high in bionomic safety.

Description

A kind of ecological precipitation agent
Technical field
The present invention relates to the sewage purification process field, specifically is the precipitation technology that is applied to combined artificial wetland sewage purification pretreatment stage, especially a kind of be applied to the pretreated ecological precipitation agent of combined artificial wetland sewage purification and its production and application method.
Background technology
Along with the Chinese society rapid development of economy; Quantity of wastewater effluent increases year by year; Under the development of several years novel ecological technology, the artificial swamp method is disposed of sewage and is more and more received people's favor, stops up because of carrying excessive suspended substance (SS) or impurity in the sewage in order to prevent artificial wet land system; Need carry out pre-treatment; The precipitation agent effect quality of pretreatment stage plays an important role for the steady running of system, and artificial wet land treating system requires the processing links of its upstream and downstream all to have the environmental treatment technology that matches as a kind of ecological environment-friendly type sewage disposal technology.And with regard to the production application feature of China's precipitation agent; Also be difficult to find the product that is complementary; Mainly show: existing electrodeless precipitation agent exists function singleness at present, and suitable water body is limited in scope, and usage quantity is big, the flco amount is big, sedimentation speed is slow, sludge dewatering is difficult and ready-made of mud place is high; Especially remain in the aluminum ion in the water body, can cause unnecessary pollution; Organic synthesis polymer precipitation agent; Not only production cost is high; And bigger to human health damage in the production building-up process, use the back difficult degradation, a large amount of accumulation and long-term existence in physical environment; Environment is produced secondary pollution, and its toxicity of the material that small portion is degraded and carinogenicity are all very strong.Existing precipitation agent is difficult to satisfy the deposition needs of artificial swamp sewage purification pretreatment stage.
Summary of the invention
The technical problem that the present invention will solve provide a kind of economy, efficient, ecological security is high, non-secondary pollution, environment amenable ecological precipitation agent.
The present invention also provides the preparation method of above-mentioned ecological precipitation agent.
The present invention further provides the application method of above-mentioned ecological precipitation agent.
For solving the problems of the technologies described above; The technical scheme that the present invention taked is: a kind of ecological precipitation agent; Be used for combined artificial wetland sewage purification pre-treatment; It is that 1: 1.4~2 component A and B component are formed by ratio of weight and number, and said A component contains 40-50wt% reed, 30-40wt% Herba Eichhorniae and 15-25wt% lotus leaf, and said B component is that 1: 2: 3 zeyssatite, vermiculite, activated carbon formed by ratio of weight and number.
The preparation method of above-mentioned ecological precipitation agent provided by the invention is: prepare component A and B component respectively; The preparation method of component A is for to smash stirring with 40-50wt% reed, 30-40wt% Herba Eichhorniae and 15-25wt% lotus leaf; Soaked 10-15 days with deionized water; Soak solution is concentrated, concentration is 30wt% again;
The preparation method of B component is for taking by weighing zeyssatite and vermiculite in 1: 2 by ratio of weight and the number of copies; Mix; Under 150-350 ℃ of temperature, be ground to 350~450 orders, and then the equal rank particulate of quality gac such as sneak into, at last three's mixture is put into stirrer and evenly stir and form powder;
Obtained component A and B component 1: 1.4 by ratio of weight and the number of copies~2 are joined in the high speed kneader, be heated to 50-90 ℃, stirred 20-30 minute.
The application method of above-mentioned ecological precipitation agent provided by the invention is: when being used for sewage pre-treatment deposition, ecological precipitation agent add-on is 0.2~0.65% of a sewage weight, mixes fully after the input, sewage water filtration is drawn to get final product then.
This ecological precipitation agent principle of work is: after the ecological precipitation agent that is applied to combined artificial wetland sewage purification processing joins in the sewage; Under high-speed stirring, be diffused in the water body rapidly; This moment ecological precipitation agent surface uneven current potential in the charge potential of suspended ion; Its current potential that repels each other is weakened,, form floc sedimentation or be condensed into bigger wadding with precipitation agent and spend and make colloidalmaterial, suspended solids and part be partly dissolved material because bonding, net catches, roll up effect such as sweep; Because the surface-area that ecological precipitation agent is huge, the extremely strong adsorptive power of nanometer micropore volume, it is inner that the fine material in the sewage, virus etc. are adsorbed onto the surface-area space.Simultaneously, ecological precipitation agent can discharge has the allelochemical that suppresses or kill the algae effect, and this allelochemical can be killed the algae in the sewage on the one hand, can suppress algae grows on the other hand.The floc sedimentation particle precipitates rapidly under action of gravity subsequently, and separates with the clean water body after handling, thereby makes turbidity, colourity, organism, inorganics and the algae of water body obtain the deposition removal.
Adopt the beneficial effect that technique scheme produced to be: 1, this ecological precipitation agent flocculence is good, and adsorptivity is strong, and consumption is few, and flocculation gathers that speed is fast, and the alumen ustum size is big, and settling of floccus speed is fast, and settling time is short; It not only has significant removal effect to the suspended substance in the sewage, impurity, and to virus, and mushroom and algae are also killed or suppress the growth effect; It is nontoxic, harmless, pollution-free, does not produce verivate, safety and environmental protection.
2, preparation process of the present invention is simple, need not complex apparatus and any chemical substance, and with short production cycle, cost is low.
3, the present invention is applied to artificial compound wet land sewage purification pre-treatment, can greatly reduce the processing pressure of sewage in the subsequent processes.
Embodiment
Below in conjunction with embodiment the present invention is done further detailed explanation.
Among the following embodiment, SS is a suspended substance, and CODcr is a COD.
Embodiment 1
The sewage in certain paper mill, the water quality leading indicator is before handling: SS is 1067mg/L, and CODcr is 4800mg/L, and colourity is 96.
The preparation method of used ecological precipitation agent is: percentage ratio at first by weight, after the reed with 45%, 35% Herba Eichhorniae, 20% lotus leaf are smashed stirring, soaked 13 days with deionized water, and extract 30% liquid concentrator, make component A; Vermiculite mixed with zeyssatite in 2: 1 by ratio of weight and the number of copies then; Under temperature 150-350 ℃ condition, be ground to 380 orders; Sneak into again and the equal rank particulate of quality gacs such as above-mentioned vermiculite and diatomaceous mixture, and the formation powder that stirs, make B component; Component A was mixed with B component in 1: 1.5 by ratio of weight and the number of copies, join in the high speed kneader, be heated to 85 ℃ and stirred 20 minutes, promptly make this ecological precipitation agent.This ecological precipitation agent is joined in the sewage by 0.65% of required pre-treatment water yield weight, through stirring, flocculate, adsorb, kill processes such as algae, precipitate and separate, accomplish pre-treatment then sewage.
Water quality after the processing is: SS is 47.7mg/L, and CODcr is 180mg/L, and colourity is 12, and clearance is respectively 95.5%, 96.3%, 87.5%.
Embodiment 2
The sewage in certain paper mill, the water quality leading indicator is before handling: SS is 1067mg/L, and CODcr is 4800 mg/L, and colourity is 96.
The preparation process of used ecological precipitation agent is: percentage ratio at first by weight, after the reed with 40%, 30% Herba Eichhorniae, 15% lotus leaf are smashed stirring, soaked 14 days with deionized water, and extract 30% liquid concentrator, make component A; Then 2: 1 vermiculite of ratio of weight and number is mixed with zeyssatite, under temperature 150-350 ℃ condition, be ground to 400 orders, the equal rank particulate of quality gac such as sneak into again, and the formation powder that stirs, make B component; Component A was mixed with B component in 1: 1.7 by ratio of weight and the number of copies, join in the high speed kneader, be heated to 90 ℃ and stirred 25 minutes, promptly make this ecological precipitation agent.This precipitation agent is joined in the sewage by 0.5% of the existing water yield quality in required preparatory place, through stirring, flocculate, adsorb, kill processes such as algae, precipitate and separate, accomplish processing then sewage.
Water quality after the processing is: SS is 64.2mg/L, and CODcr is 249mg/L, and colourity is 13, and clearance is respectively 93.9%, 94.8%, 86.5%.
Embodiment 3
The sewage in certain paper mill, the water quality leading indicator is before handling: SS is 1067mg/L, and CODcr is 4800mg/L, and colourity is 96.
The preparation process of used ecological precipitation agent is: percentage ratio at first by weight, after the reed with 50%, 40% Herba Eichhorniae, 20% lotus leaf are smashed stirring, soaked 15 days with deionized water, and extract 30% liquid concentrator, make component A; Vermiculite mixed with zeyssatite in 2: 1 by ratio of weight and the number of copies then, under temperature 150-350 ℃ condition, be ground to 450 orders, the equal rank particulate of quality gac such as sneak into again, and the formation powder that stirs, make B component; Component A was mixed with B component in 1: 2 by ratio of weight and the number of copies, join in the high speed kneader, be heated to 90 ℃ and stirred 30 minutes, promptly make this ecological precipitation agent.Ecological precipitation agent is joined in the sewage by 0.3% of required pre-treatment water yield quality, through stirring, flocculate, adsorb, kill processes such as algae, precipitate and separate, accomplish processing then sewage.
Water quality after the processing is: SS is 42.7mg/L, and CODcr is 167mg/L, and colourity is 12, and clearance is respectively 95.9%, 96.5%, 87.5%.
Through theoretical analysis and a large amount of simulated experiments, can draw and adopt this ecological precipitation agent can obtain good pretreating effect.

Claims (1)

1. ecological precipitation agent; Be used for combined artificial wetland sewage purification pre-treatment; It is characterized in that: by ratio of weight and number is that 1: 1.4~2 component A and B component are formed; Said A component contains 40-50wt% reed, 30-40wt% Herba Eichhorniae and 15-25wt% lotus leaf, and said B component is that 1: 2: 3 zeyssatite, vermiculite, activated carbon formed by ratio of weight and number;
The preparation method of described ecological precipitation agent is: prepare component A and B component respectively, the preparation method of component A soaked 10-15 days with deionized water for reed, Herba Eichhorniae and lotus leaf are smashed stirring, soak solution was concentrated again, and concentration is 30wt%;
The preparation method of B component is for taking by weighing zeyssatite and vermiculite in 1: 2 by ratio of weight and the number of copies; Mix; Under 150-350 ℃ of temperature, be ground to 350~450 orders, and then the equal rank particulate of quality activated carbon such as sneak into, at last three's mixture is put into stirrer and evenly stir and form powder;
Obtained component A and B component 1: 1.4 by ratio of weight and the number of copies~2 are joined in the high speed kneader, be heated to 50-90 ℃, stirred 20-30 minute;
Ecological precipitation agent add-on is 0.2~0.65% of a sewage weight, mixes fully after the input.
CN2010101155232A 2010-03-02 2010-03-02 Bionomic precipitator Expired - Fee Related CN101781005B (en)

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105731583A (en) * 2016-04-19 2016-07-06 肥东县柯文斌家庭农场 Water clarifying agent prepared from kieselguhr
CN106629892A (en) * 2016-11-25 2017-05-10 南宁市黑晶信息技术有限公司 Phosphorus-free corrosion-inhibiting sewage treatment agent for papermaking waste water, and preparation method thereof
CN107082477A (en) * 2017-05-12 2017-08-22 湖州梦源环保科技有限公司 A kind of sewage treatment process of sewage-treating agent and the application inorganic agent
CN107311247B (en) * 2017-07-12 2020-09-01 光合文旅控股股份有限公司 Garden sewage treatment system and treatment method thereof
CN109548710A (en) * 2018-11-15 2019-04-02 南宁学院 A kind of ecological cultivation method of silver carp
CN111875022A (en) * 2020-08-28 2020-11-03 南京融众环境工程研究院有限公司 Precipitator for treating chemical wastewater and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1375465A (en) * 2001-03-19 2002-10-23 方超 Dispersed combined water purifying agent for purifying sewage and its usage
CN101003401A (en) * 2007-01-25 2007-07-25 河北农业大学 Ecological, environmental protective composite water treatment agent
CN101148273A (en) * 2006-09-20 2008-03-26 张金香 Sewage processing agent and its preparation method
WO2008040884A3 (en) * 2006-10-05 2008-05-22 Eurotab Two-layer compacted solid product for water potabilization and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1375465A (en) * 2001-03-19 2002-10-23 方超 Dispersed combined water purifying agent for purifying sewage and its usage
CN101148273A (en) * 2006-09-20 2008-03-26 张金香 Sewage processing agent and its preparation method
WO2008040884A3 (en) * 2006-10-05 2008-05-22 Eurotab Two-layer compacted solid product for water potabilization and preparation method
CN101003401A (en) * 2007-01-25 2007-07-25 河北农业大学 Ecological, environmental protective composite water treatment agent

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