CN101763947B - Preparation method of flexible packed super-capacitor - Google Patents
Preparation method of flexible packed super-capacitor Download PDFInfo
- Publication number
- CN101763947B CN101763947B CN 200910212478 CN200910212478A CN101763947B CN 101763947 B CN101763947 B CN 101763947B CN 200910212478 CN200910212478 CN 200910212478 CN 200910212478 A CN200910212478 A CN 200910212478A CN 101763947 B CN101763947 B CN 101763947B
- Authority
- CN
- China
- Prior art keywords
- electrolyte
- capacitor
- plastic film
- bag
- aluminum plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Abstract
The invention discloses a preparation method of a flexible packed super-capacitor. The improvement of the invention includes that a liquid injection pipe with a copper bar is inserted into one side of an aluminum-plastic film bag after an electrical core is arranged in the bag, the open part and the joint part of the bag and the pipe are heat-sealed under the temperature of 200-300 degrees Celsius; the copper bar is pulled out and the bag is vacuumized to be under 0.05-0.09MPa, then is injected with electrolyte and laid aside for 8-12 hours under normal temperature, and then has formation process; the bag is vacuumized along with the formation, meanwhile, the inside pressure of the bag is kept within 0.01-0.05MPa, and the lost electrolyte is supplemented after the formation; finally, the protruding part of the liquid injection pipe is released from heat seal. The super-capacitor produced in the method has no gas expansion, avoids potential explosion danger, and guarantees good security and reliability; furthermore, the invention can ensure sufficient capacitance, improves the coherence of single body combination and cycle life of the module, and obtains excellent charge-discharge performance.
Description
Technical field
The present invention relates to a kind of manufacture method of ultracapacitor manufacture method, particularly a kind of flexible packed super-capacitor.
Background technology
Ultracapacitor also belongs to double electric layer capacitor, it is a kind of of capacity maximum in the present double electric layer capacitor, the double electric layer capacitor of its basic principle and other kind is the same, all is the capacity that utilizes the double electrical layers acquisition super large of active carbon porous electrode and electrolyte composition.
In the double electric layer capacitor, adopt absorbent charcoal material to be made into porous electrode, while filling electrolyte solution between relative carbon porous electrode, when applying voltage at two ends, assemble positron-electron on the relative porous electrode respectively, and the negative ions in the electrolyte solution will gather respectively on the interface relative with positive/negative plate owing to electric field action, thereby forms two current collection layers, is equivalent to two capacitors in series and the double electric layers supercapacitor that constitutes.
Usually, ultracapacitor produces gas changing into Shi Douhui for the first time, as fails timely discharge and will influence the chemical property of ultracapacitor, when the air pressure of inside acquires a certain degree and fail in time to discharge decompression, the phenomenon of might blasting.Especially in flexible packed super-capacitor, in case produce gas and will be difficult to discharge, the possibility that above-mentioned phenomenon takes place increases greatly after packaged fully.
At present in the manufacturing process of flexible packed super-capacitor to gaseous emission problem neither one adequate solution way also.
Summary of the invention
The objective of the invention is to overcome weak point of the prior art, the manufacture method of a kind of safe and reliable, capacity foot, flexible packed super-capacitor that chemical property is good is provided.
Technical scheme of the present invention is: the manufacture method of flexible packed super-capacitor, comprise that electric core is made, aluminum plastic film packing and capacitor change into master operation, and its improvements are: it is as follows that described aluminum plastic film packing and capacitor change into method of operation:
(1) the electric core that has pole that conventional method is made is put into U-shaped aluminum plastic film bag, and inserts the liquid injection pipe of being with copper rod in aluminum plastic film bag one side, then the opening of aluminum plastic film bag and the junction of liquid injection pipe and aluminum plastic film bag is sealed;
(2) extract copper rod in the liquid injection pipe, be evacuated to 0.05~0.09MPa, inject water-based system or organic system electrolyte to electric in-core portion again, the reservoir quantity unanimity of each ultracapacitor monomer changes into after shelving 8~12h at normal temperatures then routinely;
When (3) changing into aluminum plastic film bag inner chamber is vacuumized, pressing in keeping is 0.01~0.05MPa, change into end after, mend electrolyte of the same race once more, the loss amount of electrolyte during the amount of mending equals to change into, promptly the benefit of electrolyte is gone into amount (weight) M=(M
0+ M
1)-M
2, M in the formula
0Be the weight of ultracapacitor before the fluid injection, M
1Be the electrolyte weight of injecting first, M
2For changing into the weight that finishes the back ultracapacitor, unit is kg.
Further scheme is: described liquid injection pipe is made by polypropylene, polyethylene or polyvinyl chloride; The heating-up temperature of described heat-sealing is 200~300 ℃; Described water-based system electrolyte is potassium hydroxide or sulfuric acid electrolyte; Described organic system electrolyte is that tetraethylammonium tetrafluoroborate salt or triethyl group methyl tetrafluoroborate are dissolved in the electrolyte that acetonitrile or propene carbonate constitute; Described injection electrolyte utilizes fluid injection machine or syringe or height above sea level pump to carry out.
The good effect of technical solution of the present invention is: a side of aluminum plastic film bag is inserted liquid injection pipe and is used to inject electrolyte and vacuumizes, and inserts copper rod in the liquid injection pipe, is convenient to the heat-sealing of liquid injection pipe and aluminum plastic film bag, and can adhesion in the liquid injection pipe after the assurance heat-sealing.Vacuumize earlier before injecting electrolyte, can guarantee fluid injection smoothly and reservoir quantity consistent, change into again after shelving 8~12h at normal temperatures after the fluid injection, can make electrolyte fully immerse electric core, the raising formation effect.Change into while vacuumizing when changing into, can in time discharge the inner gas that produces of capacitor, avoid ultracapacitor to have swell even explosion caused, improve the product safety reliability because of gas is arranged.Take the method for secondary fluid injection after changing into, replenish an amount of electrolyte, and the loss amount of electrolyte when amount infused is vacuumized in equaling to change into, prevent to cause the problem of condenser capacity deficiency on the one hand because of the electrolyte content deficiency, guarantee the electrolyte content unanimity in each capacitor monomer on the other hand, the cycle life of the module that the consistency during with raising capacitor combination of monomers and each monomer are formed obtains the excellent charging and discharging performance.
Embodiment
Further specify the present invention below in conjunction with embodiment.
Example one: make flexible packed super-capacitor by following method and step.
1, the electric core of the band pole that conventional method is made is put into U-shaped aluminum plastic film bag, and insert the liquid injection pipe of making by polypropylene (PP) of band copper rod in a side of bag, the liquid injection pipe insertion end flushes with aluminum plastic film bag inboard, then aluminum plastic film bag opening part and liquid injection pipe and aluminum plastic film bag junction are sealed 250 ℃ of heat-sealing temperatures;
2, extract copper rod in the liquid injection pipe, be evacuated to 0.07MPa, adopt the height above sea level pump to inject potassium hydroxide electrolyte (weight percent concentration is 40%) to electric in-core, each capacitor monomer reservoir quantity unanimity is shelved 10h at normal temperatures and is changed into according to a conventional method;
3, change into simultaneously vacuumizing in the aluminum plastic film bag, press in keeping to be 0.03MPa, change into end after, mend electrolyte of the same race again, mend amount (weight) M=(M
0+ M
1)-M
2, M in the formula
0Be the weight of each ultracapacitor monomer before the fluid injection, M
1For injecting electrolyte weight, M first
2For changing into the weight that finishes each capacitor monomer of back, unit is kg;
4, the liquid injection pipe ledge is removed the post heat-seal mouth of pipe, 250 ℃ of heat-sealing temperatures.
Example two, example three methods of operation and step are with example one, and only change has related parameter, is listed as follows:
? | Heat-sealing temperature ℃ | Vacuumize MPa before the fluid injection | Electrolyte | Shelve time h before changing into | Vacuumize MPa when changing into |
Example two | 200 | 0.05 | Tetraethylammonium tetrafluoroborate salt is dissolved in acetonitrile (weight ratio 1: 2) | 8 | 0.01 |
Example three | 300 | 0.09 | Triethyl group methyl tetrafluoroborate is dissolved in propene carbonate (weight ratio 1: 3) | 12 | 0.05 |
Claims (6)
1. the manufacture method of a flexible packed super-capacitor comprises that electric core is made, aluminum plastic film packing and capacitor change into master operation, it is characterized in that: it is as follows that described aluminum plastic film packing and capacitor change into method of operation:
(1) the electric core that has pole that conventional method is made is put into U-shaped aluminum plastic film bag, and inserts the liquid injection pipe of being with copper rod in aluminum plastic film bag one side, then the opening of aluminum plastic film bag and the junction of liquid injection pipe and aluminum plastic film bag is sealed;
(2) extract copper rod in the liquid injection pipe, be evacuated to 0.05~0.09MPa, inject water-based system or organic system electrolyte to electric in-core portion again, the reservoir quantity unanimity of each ultracapacitor monomer changes into after shelving 8~12h at normal temperatures then routinely;
When (3) changing into aluminum plastic film bag inner chamber is vacuumized, pressing in keeping is 0.01~0.05MPa, change into end after, mend electrolyte of the same race once more, the loss amount of electrolyte during the amount of mending equals to change into, promptly the benefit of electrolyte is gone into amount (weight) M=(M
0+ M
1)-M
2, M in the formula
0Be the weight of ultracapacitor before the fluid injection, M
1Be the electrolyte weight of injecting first, M
2For changing into the weight that finishes the back ultracapacitor, unit is kg.
2. by the manufacture method of the described flexible packed super-capacitor of claim 1, it is characterized in that: described liquid injection pipe is made by polypropylene, polyethylene or polyvinyl chloride.
3. by the manufacture method of the described flexible packed super-capacitor of claim 1, it is characterized in that: the heating-up temperature of described heat-sealing is 200~300 ℃.
4. by the manufacture method of the described flexible packed super-capacitor of claim 1, it is characterized in that: described water-based system electrolyte is potassium hydroxide or sulfuric acid electrolyte.
5. by the manufacture method of the described flexible packed super-capacitor of claim 1, it is characterized in that: described organic system electrolyte is that tetraethylammonium tetrafluoroborate salt or triethyl group methyl tetrafluoroborate are dissolved in the electrolyte that acetonitrile or propene carbonate constitute.
6. by the manufacture method of the described flexible packed super-capacitor of claim 1, it is characterized in that: described injection electrolyte utilizes fluid injection machine or syringe or height above sea level pump to carry out.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910212478 CN101763947B (en) | 2009-11-09 | 2009-11-09 | Preparation method of flexible packed super-capacitor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910212478 CN101763947B (en) | 2009-11-09 | 2009-11-09 | Preparation method of flexible packed super-capacitor |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101763947A CN101763947A (en) | 2010-06-30 |
CN101763947B true CN101763947B (en) | 2011-09-14 |
Family
ID=42495047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200910212478 Expired - Fee Related CN101763947B (en) | 2009-11-09 | 2009-11-09 | Preparation method of flexible packed super-capacitor |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101763947B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102082035A (en) * | 2010-12-20 | 2011-06-01 | 南京双登科技发展研究院有限公司 | Super capacitor of flexible package water system |
CN102509645A (en) * | 2011-09-28 | 2012-06-20 | 江苏富朗特新能源有限公司 | Super capacitor cell encapsulation method |
CN103247443A (en) * | 2012-02-14 | 2013-08-14 | 马云青 | Pole core, super capacitor and method for pouring electrolyte solution into super capacitor |
GB2548128B (en) * | 2016-03-09 | 2021-12-15 | Zapgo Ltd | Method of reducing outgassing |
CN111276754A (en) * | 2020-01-22 | 2020-06-12 | 天津荣盛盟固利新能源科技有限公司 | Manufacturing method of soft package battery |
-
2009
- 2009-11-09 CN CN 200910212478 patent/CN101763947B/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN101763947A (en) | 2010-06-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101763947B (en) | Preparation method of flexible packed super-capacitor | |
CN101944585B (en) | Injection method for lithium battery | |
KR100913514B1 (en) | Electric double-layer capacitor | |
CN106571442B (en) | A kind of priming device and electrolyte filling method of soft package lithium battery electrolyte | |
CN105552372B (en) | A kind of N doped carbons microfiber material and its preparation method and application | |
CN105762430A (en) | Lithium iron phosphate power battery formation method | |
CN105645410B (en) | 3D network pore structure Supercapacitor carbons and preparation method thereof | |
CN107681104A (en) | A kind of liquid injection process of polymer soft bag lithium ionic cell | |
CN107464908B (en) | Membrane infiltration method of soft package lithium ion battery | |
CN103337602B (en) | Isolating film and electrochemical device | |
CN105161766A (en) | Filling formation method for power type lithium battery | |
CN107579282A (en) | A kind of Soft Roll silicon-carbon cathode formation of Li-ion batteries technique | |
CN110492191B (en) | Polymer lithium ion battery formation process capable of exhausting and replenishing liquid | |
CN108417757A (en) | A kind of safety-type lithium battery and preparation method thereof | |
CN105340038A (en) | Electrolyte solution and electrochemical device | |
CN105428085A (en) | Biomass-based colloidal electrolyte and biomass-based colloidal electrolyte super capacitor | |
JPWO2009028722A1 (en) | Portable hydrogen generation unit | |
CN105869918B (en) | A kind of ultracapacitor based on carbon nanomaterial and preparation method thereof | |
CN105428728B (en) | Polymer power battery and preparation method | |
CN104393348A (en) | Preparation method of laminated flexible-package lithium-ion battery | |
CN102496482B (en) | A kind of super-capacitor pole piece and preparation method thereof | |
CN104167566A (en) | Sealing forming method of lithium ion battery | |
CN203562319U (en) | Flexible-package laminated super capacitor | |
CN217485301U (en) | Leakage-proof electrolyte injection device for super capacitor | |
CN201663058U (en) | Electrolyte filling device for flexible packaging electrical double-layer capacitor |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110914 Termination date: 20131109 |