CN101760078A - Reactive ink for printing and dyeing and method for carrying out jet printing on denim fabric by adopting same - Google Patents
Reactive ink for printing and dyeing and method for carrying out jet printing on denim fabric by adopting same Download PDFInfo
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- CN101760078A CN101760078A CN201010019291A CN201010019291A CN101760078A CN 101760078 A CN101760078 A CN 101760078A CN 201010019291 A CN201010019291 A CN 201010019291A CN 201010019291 A CN201010019291 A CN 201010019291A CN 101760078 A CN101760078 A CN 101760078A
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Abstract
The invention relates to reactive ink for printing and dyeing, containing the following components of 5%-20% of vinyl-sulfone epoxy resin-based high-polymer reactive dyes, 0.5%-1% of surface active agents OP-10, 5%-10% of propylene glycol PEG and 69%-89.5% of deionized water, and the pH value of the high-polymer reactive ink for printing and dyeing is 7-9 through adding a pH-value buffer solution after mixing the components. The invention also relates to a method for carrying out jet printing on a denim fabric by adopting the ink, comprising the following steps of: pretreating and drying the denim fabric, then carrying out jet printing by adopting the high-polymer reactive ink for printing and dyeing, aftertreating and drying the denim fabric, and finally washing and drying the denim fabric. After being used, the reactive ink for printing and dyeing and the method for carrying out jet printing on the denim fabric have the advantages of environmental protection and energy saving; the printed denim fabric has the advantages of high washing-resistant color fastness and wear-resistant color fastness and favorable hand feeling; and meanwhile, the quality level and the additional value of denim garment are enhanced.
Description
Technical field
The present invention relates to technical field of textile printing, be specifically related to a kind of printing and dyeing with active ink and adopt this ink to carry out the method for jet printing on denim fabric.
Background technology
Cowboy's industry development prospect is very wide, and focus development tencel and functional jean can further satisfy the demand that jeans develop at present.Though current enterprise competitiveness constantly strengthens, domestic jean is still based on low-and-medium-grade products, and high-grade jean proportion is not high, and traditional jean can not satisfy the needs in market.Greatly developing high value added product is the key issue that present jean and clothes production enterprise face.
The innovation of back finishing technique and utilization have become the necessary means that improves product quality and added value.The jean facework is put in order by dyeing and printing technology, can obtain good effect and the aesthetic effect taken.Traditional clothing fabric with art pattern mainly is by multiple printing and dyeing processing technology, makes different dyestuffs by flower version painted formation pattern on the fiber of lining.In addition, also have the method for passing through other chemical processes or passing through digital spray printing, hot transfer printing to form the clothing fabric design.
Ink-jet printed is that the image that will handle by digitizing technique is input to computer, after the layout of computer stamp colour splitting system, control ink-jet printed system by special software (RIP) again, with the direct spray printing of special-purpose ink to various textiless, thereby form the PRINTED FABRIC of design requirements.Ink-jet printedly compare traditional printing technology following advantage is arranged: (1) does not have a version stamp.The computer coloured image can directly show on the fabric, can save operations such as traditional printing stencil, saves operationlocation.(2) save the labour.Compare with traditional printing machine, ink-jet printed usefulness be bantam.Movably mechanical part has only head section and fabric to transport part, and their mechanism is all fairly simple.(3) print quality top grade.Ink-jet printed rich color, transition are level and smooth naturally, do not have the restriction of cover chromatic number, can print the level smoothness, have the decorative pattern of photograph style, can reflect the complexity and the fineness of pattern realistically.(4) form by limited primitive colour.Need not make a plate, only need four primitive colour dye inks of CMYK, just can obtain required color.(5) repeatable production.But the whole pattern data of CAD system prolonged preservation can repeat when needing to call.(6) can be satisfying personalized, small serial production and fast-developing needs.(7) change batch efficient height.Only needing the numerical information of new pattern is delivered to ink-jet decorating machine is interchangeable batch.(8) help environmental protection.Dyestuff be need based jet on matrix, be anhydrous arrangement, reduced the waste of chemical preparations and the discharging of waste water, and the noise during ink-jet is low relatively, these all can reduce the injury to human body.
Employed printing ink is generally the polymerizability ink-jet dye on the domestic market at present, and it is most of from import, also there are a lot of problems in the price height of printing ink at aspects such as color depth, washing fastnesses, and this also is the at present ink-jet printed universal major cause that do not have.
Summary of the invention
The object of the present invention is to provide a kind of polymer, nontoxic, safe printing and dyeing active ink, and adopt the very environmental protection of this active ink, the method for energy-conservation, jet printing on denim fabric that stability is good.
The object of the present invention is achieved like this: a kind of printing and dyeing active ink is characterized in that: described printing and dyeing comprise with the polymer active ink: vinyl sulfone epoxy resin-matrix macromolecule reactive dye 5-20%; Tensio-active agent OP-10 0.5-1%; Wetting Agent for Printing Inks PEG 5-10%; Deionized water 69-89.5%, after preparing by above-mentioned prescription, by add the pH value damping fluid make printing and dyeing with the pH value of polymer active ink between 7-9.
A kind of method that adopts the described printing and dyeing of claim 1 to carry out jet printing on denim fabric with active ink, it is characterized in that: at first jean is carried out pretreatment process, and oven dry, adopt printing and dyeing to carry out ink-jet printed then with the polymer active ink, carry out postprocessing working procedures and oven dry again, carry out washing step and oven dry at last.
Described pretreatment process carries out enzyme desizing and anti-imbibition processing for jean is immersed in the solution, its solution formula is to add in every premium on currency: amylase 2-10g, salt 5-15g, sodium alginate 1-5g, sodium bicarbonate 2-10g, urea 1.5-7.5g, after preparing by above-mentioned prescription, to make the pH value of solution be 5-7 by adding the pH value damping fluid; Treatment condition: temperature is 45-70 ℃.
Described aftertreatment technology is to add alkali 10-20g in every premium on currency for spray thermokalite technology, the concentration of alkali, and temperature is 60-90 ℃.
The bake out temperature of described technological process is controlled at 60-120 ℃.
The composition of described jean can be to contain cotton fibre, polyster fibre, regenerated cellulose fibre, silk.
Positively effect of the present invention is: the printing and dyeing active ink that adopts the vinyl sulfone epoxy resin-matrix macromolecule reactive dye preparation, it has following characteristics: (1) combines with high molecular owing to organic dye molecule, the migration of dye molecule and permeate less, can improve shortcoming, the especially azoic dyestuff of the easy migration of general small molecules dyestuff and the resistance to migration of anthraquinone dye significantly improves greatly; (2) have water-solublely, can be directly used in the textile ink-jet stamp, realize anhydrous artistic finishing; (3) molecular weight is big, can not be seen through by cytolemma, can be by bacterium, microbiological degradation, thus do not absorbed by organism, harmless to organism; (4) have high melt point, thermotolerance improves greatly.Therefore (5) because high molecular dye is the dyeing of molecular level, compare with the small molecules dyestuff, consumption greatly reduces, show bright-colored, colourity jail, dye utilization rate advantages of higher; (6) general dissolving seldom or is not fully dissolved in solvent, and fugitive color has not contained chromophoric group owing in the macromole, and it becomes the structure colored materials, thereby shows good washing fastness in cowboy's wash water.
This polymeric dye belongs to functional polymer, and is nontoxic, and safety meets the direction of the development of materialogy from now on, also meets the aim of green colouring material chemical developer simultaneously.With it ink-jet printed arrangement that is applied to cowboy's fabric, reduced not only that dyeing waste-water is administered and to the load of environment, and reduced production process, saved the production time and make production cost reduce greatly.
Description of drawings
Fig. 1 carries out the method flow diagram of jet printing on denim fabric for adopting printing and dyeing with active ink;
Fig. 2 is the structural formula of vinyl sulfone epoxy resin-matrix macromolecule reactive dye.
Embodiment
Below in conjunction with specific embodiment the present invention is described in further detail.
Embodiment one
Get one of indigo jean, be immersed in earlier and carry out enzyme desizing and anti-imbibition pre-treatment in the solution, the effect of enzyme desizing is the slurry of removing on the face liber, help dyestuff and better contact and bond with fiber on the lining, the effect of anti-imbibition be when preventing stamp ink bigger to around spread and cause spending the pattern paste.The technical recipe of its solution is to add in every premium on currency: amylase 4g, and salt 5g, sodium alginate 1g, sodium bicarbonate 2g, urea 1.5g, after preparing by above-mentioned prescription, adding the pH value damping fluid, to regulate pH value be 5.5, treatment condition: temperature is 55 ℃; Then 90 ℃ of oven dry down; Vinyl sulfone epoxy resin-matrix macromolecule reactive dye 5% is being housed; Tensio-active agent OP-100.6%; Wetting Agent for Printing Inks PEG 5%; Deionized water 89.4%, after preparing by above-mentioned prescription, adding the pH value damping fluid, to regulate pH value be 8, the printer of the ink of preparation is printed down; Through the aftertreatment of a spray thermokalite, wherein concentration of lye is that every premium on currency adds alkali 10g again, and temperature is 70 ℃; 90 ℃ of oven dry, washing is again 90 ℃ of oven dry.
Every technical parameter of ink-jet printed back cowboy is as follows:
Degree of fixation is: 75%
The K/S value is: 1.3
The water-fast colour fastness of washing is: 4 grades
Colour fastness to rubbing is: 3 grades
Embodiment two
Get one of indigo jean, be immersed in earlier and carry out enzyme desizing and anti-imbibition pre-treatment in the solution, the technical recipe of its solution is to add in every premium on currency: amylase 6g, salt 7g, sodium alginate 2g, sodium bicarbonate 5g, urea 4g, after preparing by above-mentioned prescription, adding the pH value damping fluid, to regulate pH value be 6, and treatment condition: temperature is 60 ℃; Then 100 ℃ of oven dry down; Vinyl sulfone epoxy resin-matrix macromolecule reactive dye 10% is being housed; Tensio-active agent OP-100.7%; Wetting Agent for Printing Inks PEG 7%; Deionized water 82.3%, after preparing by above-mentioned prescription, adding the pH value damping fluid, to regulate pH value be 8, the printer of the ink of preparation is printed down; Through the aftertreatment of a spray thermokalite, wherein concentration of lye is that every premium on currency adds alkali 15g again, and temperature is 75 ℃; 100 ℃ of oven dry, washing is again 100 ℃ of oven dry.
Every technical parameter of ink-jet printed back cowboy is as follows:
Degree of fixation is: 80%
The K/S value is: 1.5
The water-fast colour fastness of washing is: 5 grades
Colour fastness to rubbing is: 4 grades
Embodiment three
Get one of indigo jean, be immersed in earlier and carry out enzyme desizing and anti-imbibition pre-treatment in the solution, add in the every premium on currency of the technical recipe of its solution: amylase 8 g, salt 9g, sodium alginate 4g, sodium bicarbonate 7g, urea 6g, after preparing by above-mentioned prescription, adding the pH value damping fluid, to regulate pH value be 6.5, and condition: temperature is 65 ℃; Then 110 ℃ of oven dry down; Vinyl sulfone epoxy resin-matrix macromolecule reactive dye 15% is being housed; Tensio-active agent OP-100.9%; Wetting Agent for Printing Inks PEG 9%; Deionized water 75.1%, after preparing by above-mentioned prescription, adding the pH value damping fluid, to regulate pH value be 8, the printer of the ink of preparation is printed down; Through the aftertreatment of a spray thermokalite, wherein concentration of lye is that every premium on currency adds alkali 18g again, and temperature is 78 ℃; 110 ℃ of oven dry, washing is again 110 ℃ of oven dry.
Every technical parameter of ink-jet printed back cowboy is as follows:
Degree of fixation is: 87%
The K/S value is: 1.6
The water-fast colour fastness of washing is: 5 grades
Colour fastness to rubbing is: 4 grades.
Claims (6)
1. printing and dyeing active ink, it is characterized in that: described printing and dyeing comprise with the polymer active ink: vinyl sulfone epoxy resin-matrix macromolecule reactive dye 5-20%; Tensio-active agent OP-10 0.5-1%; Wetting Agent for Printing Inks PEG 5-10%; Deionized water 69-89.5%; After preparing by above-mentioned prescription, by add the pH value damping fluid make printing and dyeing with the pH value of polymer active ink between 7-9.
2. method that adopts the described printing and dyeing of claim 1 to carry out jet printing on denim fabric with active ink, it is characterized in that: at first jean is carried out pretreatment process, and oven dry, adopt printing and dyeing to carry out ink-jet printed then with the polymer active ink, carry out postprocessing working procedures and oven dry again, carry out washing step and oven dry at last.
3. the method for jet printing on denim fabric is carried out in employing printing and dyeing according to claim 2 with active ink, it is characterized in that: described pretreatment process carries out enzyme desizing and anti-imbibition processing for jean is immersed in the solution, its solution formula is to add in every premium on currency: amylase 2-10g, salt 5-15g, sodium alginate 1-5g, sodium bicarbonate 2-10g, urea 1.5-7.5g, after preparing by above-mentioned prescription, make the pH value of solution between 5-7 by adding the pH value damping fluid; Treatment condition: temperature is 45-70 ℃.
4. employing according to claim 2 is printed and dyed and carried out the method for jet printing on denim fabric with active ink, it is characterized in that: described aftertreatment technology is to add alkali 10-20g in every premium on currency for spray thermokalite technology, the concentration of alkali, and temperature is 60-90 ℃.
5. employing according to claim 2 is printed and dyed and is carried out the method for jet printing on denim fabric with the polymer active ink, and it is characterized in that: the bake out temperature of described technological process is controlled at 60-120 ℃.
6. employing according to claim 2 is printed and dyed and is carried out the method for jet printing on denim fabric with active ink, and it is characterized in that: the composition of described jean can be to contain cotton fibre, polyster fibre, regenerated cellulose fibre, silk.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010019291 CN101760078B (en) | 2010-01-04 | 2010-01-04 | Reactive ink for printing and dyeing and method for carrying out jet printing on denim fabric by adopting same |
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| CN 201010019291 CN101760078B (en) | 2010-01-04 | 2010-01-04 | Reactive ink for printing and dyeing and method for carrying out jet printing on denim fabric by adopting same |
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| CN101760078A true CN101760078A (en) | 2010-06-30 |
| CN101760078B CN101760078B (en) | 2013-04-10 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102226316A (en) * | 2011-04-25 | 2011-10-26 | 深圳市墨库图文技术有限公司 | Environmentally-friendly digital inkjet textile printing ink with reactive dye and preparation method thereof |
| CN104131478A (en) * | 2014-07-24 | 2014-11-05 | 哈尔滨市朗威尔科技发展有限公司 | Color printing and dyeing technology of active ink dye on linen fabric |
| CN105908498A (en) * | 2016-05-18 | 2016-08-31 | 浙江钱江纺织印染有限公司 | Process of high-speed digital printing and interweaving of silks with gold and silver wires |
| CN106243834A (en) * | 2016-08-23 | 2016-12-21 | 深圳市南方煜森电子有限公司 | One is printed upon non-fading ink and application process thereof on cotton |
| CN106978746A (en) * | 2017-04-28 | 2017-07-25 | 泉州市众科专利技术标准化研究院有限责任公司 | A kind of ink-jet cloth printing technique |
| CN107326707A (en) * | 2017-06-26 | 2017-11-07 | 浙江喜得宝丝绸科技有限公司 | PRINTED FABRIC non-evaporatingization non-water washing treatment method |
| CN108071023A (en) * | 2016-11-08 | 2018-05-25 | 绍兴市海印数码科技有限公司 | A kind of living polymer dye ink and its applied to the ink-jet printed dyeing and printing process on cotton fabric |
| CN110699981A (en) * | 2019-10-22 | 2020-01-17 | 徐州双辰服饰有限公司 | Printing adhesive cement for coating of jeans |
| CN111395021A (en) * | 2020-04-20 | 2020-07-10 | 天津工业大学 | Digital ink-jet printing process of polyester/cotton fiber fabric |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119686A (en) * | 1993-11-08 | 1996-04-03 | 佳能株式会社 | Ink-jet printing cloth, textile printing process, and print |
-
2010
- 2010-01-04 CN CN 201010019291 patent/CN101760078B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119686A (en) * | 1993-11-08 | 1996-04-03 | 佳能株式会社 | Ink-jet printing cloth, textile printing process, and print |
Non-Patent Citations (4)
| Title |
|---|
| 孙冉青 等: ""共聚型环氧树脂基高分子染料的制备和表征"", 《功能高分子学报》 * |
| 张 伟 等: ""喷墨印花墨水及其发展"", 《针织工业》 * |
| 王 梅 等: ""纯棉牛仔布的生物酶减量整理"", 《印染助剂》 * |
| 王宏付 等: ""牛仔布喷墨印花工艺探讨"", 《上海纺织科技》 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102226316A (en) * | 2011-04-25 | 2011-10-26 | 深圳市墨库图文技术有限公司 | Environmentally-friendly digital inkjet textile printing ink with reactive dye and preparation method thereof |
| CN102226316B (en) * | 2011-04-25 | 2013-09-04 | 深圳市墨库图文技术有限公司 | Environmentally-friendly digital inkjet textile printing ink with reactive dye and preparation method thereof |
| CN104131478A (en) * | 2014-07-24 | 2014-11-05 | 哈尔滨市朗威尔科技发展有限公司 | Color printing and dyeing technology of active ink dye on linen fabric |
| CN105908498B (en) * | 2016-05-18 | 2019-11-12 | 浙江钱江纺织印染有限公司 | A kind of high-speed digital printing and silk metallized thread interweaving process |
| CN105908498A (en) * | 2016-05-18 | 2016-08-31 | 浙江钱江纺织印染有限公司 | Process of high-speed digital printing and interweaving of silks with gold and silver wires |
| CN106243834A (en) * | 2016-08-23 | 2016-12-21 | 深圳市南方煜森电子有限公司 | One is printed upon non-fading ink and application process thereof on cotton |
| CN106243834B (en) * | 2016-08-23 | 2019-11-05 | 深圳市南方煜森电子有限公司 | One kind being printed upon non-fading ink and its application method on cotton |
| CN108071023A (en) * | 2016-11-08 | 2018-05-25 | 绍兴市海印数码科技有限公司 | A kind of living polymer dye ink and its applied to the ink-jet printed dyeing and printing process on cotton fabric |
| CN108071023B (en) * | 2016-11-08 | 2020-07-17 | 绍兴市海印数码科技有限公司 | Ink-jet printing and dyeing process for applying active macromolecular dye ink to cotton fabric |
| CN106978746A (en) * | 2017-04-28 | 2017-07-25 | 泉州市众科专利技术标准化研究院有限责任公司 | A kind of ink-jet cloth printing technique |
| CN107326707A (en) * | 2017-06-26 | 2017-11-07 | 浙江喜得宝丝绸科技有限公司 | PRINTED FABRIC non-evaporatingization non-water washing treatment method |
| CN110699981A (en) * | 2019-10-22 | 2020-01-17 | 徐州双辰服饰有限公司 | Printing adhesive cement for coating of jeans |
| CN111395021A (en) * | 2020-04-20 | 2020-07-10 | 天津工业大学 | Digital ink-jet printing process of polyester/cotton fiber fabric |
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| CN101760078B (en) | 2013-04-10 |
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Owner name: GUANGDONG JUN'AN JEANS RESEARCH INSTITUTE Free format text: FORMER OWNER: GUANGDONG HONGCHANG FABRIC + CLOTHING DESIGN HOLDING CO., LTD. Effective date: 20120606 |
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Effective date of registration: 20120606 Address after: Shunde District 528000 of Guangdong province Foshan City Jun'an Hongan Road No. 9 Applicant after: Guangdong Junan Jeans Research Institute Address before: 528000, Guangdong, Foshan, Shunde District, anzhen Town, Pu Pu mold City Xingye Road, No. two, 7 and facade Applicant before: Guangdong Hongchang Garment Creative Co., Ltd. |
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