CN101747747A - 5.6GY 9/1 pigment composite, sample for Chinese architectural color cards and preparation method thereof - Google Patents

Abstract

The invention discloses a 5.6GY 9/1 pigment composite, a sample for Chinese architectural color cards and a preparation method thereof. The composite contains the following components by weight portion: 995 to 1005 portions of CBCC-A base stock; 0.02 portions of PG36 containing 39 percent of pigment; 0.23 to 0.25 portions of PBK11 containing 50 percent of pigment; and 0.01 to 0.02 portions of PY110 containing 33 percent of pigment. The main component of the CBCC-A base stock is acrylic copolymer, accounting for 30 percent to 40 percent. TiO2 is chosen as the main white pigment, accounting for 18 percent to 22 percent. The contrast ratio of the base stock is 0.90 to 0.96, the Stormer viscosity is 90 KU to 100 KU, and when the incident angle is 85 degrees, the glossiness is 5 degrees and 10 degrees. The sample for Chinese architectural color cards has good weather resistance and stability, the proportioning reproducibility is good, and the adopted materials and technique come up to the environmental requirement and standard of low-VOC and zero-VOC; and compared with the national standard sample GSB16-1517-2002 for Chinese architectural color cards, the sample has the advantages of little color difference and high color production accuracy, and can be widely applied in the construction industry related to colors.

Description

A kind of composition of 5.6GY 9/1 pigment and be applied to the sample and the preparation method of Chinese architecture colour atla

[technical field]

The present invention relates to a kind of composition, particularly be a kind of composition of 5.6GY 9/1 pigment.

The invention still further relates to said composition and be applied to the sample of Chinese architecture colour atla,

The invention still further relates to the preparation method who prepares sample for Chinese architectural color card with said composition simultaneously.

[background technology]

A kind of color comprises form and aspect, lightness and chroma, as long as determined form and aspect, lightness and chroma, just can determine unique a kind of color.Stipulate among the Chinese colour system GB/T 15608-1995 that in the Chinese colour system theoretical model, any color can be demarcated with the tone on the color solid, lightness and chroma, and gives certain label.Scaling method is to write out tone H earlier, writes lightness V then, writes chroma C behind oblique line, represent with H V/C, and be example with color 10BG 5.5/6,10BG represents tone, 5.5 expression lightness, 6 expression chromas.

The method for expressing GB/T 18922-2008 of building color is according to the Chinese colour system GB/T 15608-1995 formulation of encoding, and Chinese architecture colour atla national standard sample GSB16-1517-2002 compilation principles is with the relevant regulations in this standard, adopts the Chinese colour system aspect system to represent color.Chinese architecture colour atla national standard sample GSB16-1517-2002 provides effective tool using for the color normalization management of building circle.

In the production process of sample for Chinese architectural color card, can relate to multinomial important steps such as aberration Δ E, raw material, prescription and technology.Wherein, Difference Control is to weigh the unalterable quota of a national colours reproducing technology ability, and the degree of approach that aberration is more little, the color theory value is reduced into the color matter sample is high more, and technical difficulty is big more, the scientific research strength that indicates this state simultaneously is strong more, and state of the art is high more.

[summary of the invention]

The objective of the invention is in order to overcome technical difficulty recited above, a kind of composition of 5.6GY 9/1 pigment is provided, reach sample with this preparation of compositions Chinese architecture colour atla and preparation method thereof, the fast light sex change and the favorable reproducibility of this sample for Chinese architectural color card coating, glossiness is moderate, and environmental protection.

A kind of composition of 5.6GY 9/1 pigment consists of by weight:

995～1005 parts of CBCC-A base-materials;

PG36, pigment content are 39%, 0.02 part;

PBK11, pigment content are 50%, 0.23～0.25 part;

PY110, pigment content are 33%, 0.01～0.02 part;

Above-mentioned CBCC-A base-material main component is an acrylic copolymer, and content is 30～40%, and its average molecular weight range is 15～200,000, median size is 0.1～0.2 μ m, and minimum film-forming temperature is 10～22 ℃, and second-order transition temperature is 25～35 ℃, anionic, pH value are 8.5～10.0.Select TiO for use ₂Content 〉=95%, oil number＜20g/100g, the reducing power Reynolds is several now 1800, and ISO 591R2 type is as main white pigment, and content is 18～22%.The contrast ratio of this base-material is 0.90～0.96, and stormer viscosity is 90～100KU, when incident angle is 85 °, and 5 °～10 ° of glossiness.

A kind of sample for Chinese architectural color card of 5.6GY9/1 color, press above-mentioned raw materials and proportioning, when incident angle is 85 °, its glossiness is 4 °～6 °, and the requirement that the building colour atla of the method for expressing national Specification of GB/T 18922-2008 building color is demarcated aberration latitude Δ E≤3 of colourimetric number and its standard value is satisfied in aberration Δ E≤3.0 between the standard value.

The technological method of the sample for Chinese architectural color card preparation of above-mentioned 5.6GY 9/1 color comprises the steps:

1) raw material blending: the proportioning by above-mentioned 5.6GY 9/1 color takes by weighing raw material, mixes.

2) coating: at ambient relative humidity 50% ± 5%, under 23 ± 2 ℃ of conditions of room temperature, adopt mechanical coating method, composition evenly entirely is coated on the base material, base material is metallic substance or non-metallic material, and the coating wet-film thickness is 250 μ m.

3) drying: place 50 ± 2 ℃ of dry 3～4h of accurate baking oven to constant weight composition coating, take out, be cooled to room temperature, obtain sample for Chinese architectural color card.

Advantage of the present invention: said composition weathering resistance and stability are high, and good proportion repeatability, raw materials used and technological process meet low VOC and zero VOC environmental protection requirement and standard; It is little that this sample and the standard value of Chinese architecture colour atla national standard sample GSB16-1517-2002 are compared color distortion, and the order of accuarcy height that color realizes can be widely used in the building field relevant with color.

[embodiment]

Pigment preferred for this invention comprises that international pigment index codes is PG36 (pigment content is 39%), PBK11 (pigment content is 50%) and PY110 (pigment content is 33%).Wherein, PG36 (pigment content is 39%) is the halogenated ketone phthalocyanine green, has the sun-proof and the resistance toheat of phthalocyanine pigment excellence, and when to adjust the high saturation mass-tone be green color, the PG7 that compares had the form and aspect of inclined to one side Huang and better brightness; PBK11 (pigment content is 50%) has splendid solvent resistance and chemical stability, fabulous weather resistance and weathering resistance and light permanency for iron black.Though tinting strength, is applicable to more that building field is to protecting the place that the light tint retention is had relatively high expectations not as good as carbon black; PY110 (pigment content is 33%) isoindolinone Huang is brightly painted organic yellow ultramarine, and the red partially phase of lightness height, form and aspect is mainly adjusted red yellow mutually, has excellent fast light and heat-resistant stability.

Adopting contrast ratio is 0.90～0.96, and stormer viscosity is 90～100KU, and the CBCC-A base-material that glossiness (85 °) is 5 °～10 ° is realized the underlying carrier of color as us, and the CBCC-A base-material is provided by the Hiachuan Industry Co., Ltd., Shenzhen.

According to 3.1 regulation in the method for expressing of GB/T 18922-2008 building color, the method for expressing of building color is represented with Chinese colour system label and corresponding building color coding, we are encoded to CBCC1331 with the sample for Chinese architectural color card that generates, its coding concerns one to one with 5.6GY 9/1, its standard L* value, standard A * value, standard B* value are respectively 93.55 ,-1.07,1.16, the observed value of this sample for Chinese architectural color card and aberration Δ E≤3.0 between the standard value.

Embodiment 1:

Take by weighing 0.02 gram PG36 by weight, 0.24 gram PBK11,0.01 gram PY110, CBCC-A base-material 1000 grams.With above-mentioned mixing of materials mixing, then with the composition of gained, at ambient relative humidity 50% ± 5%, under 23 ± 2 ℃ of conditions of room temperature, adopt mechanical coating method, evenly entirely be coated on the base material, base material is metallic substance or non-metallic material, and the coating wet-film thickness is 250 μ m, place 50 ± 2 ℃ of dry 3～4h of accurate baking oven to constant weight then, take out, be cooled to room temperature, obtain sample for Chinese architectural color card.

Embodiment 2:

Take by weighing 0.02 gram PG36 by weight, 0.23 gram PBK11,0.01 gram PY110, CBCC-A base-material 1000 grams.Making processes is with embodiment 1.

Embodiment 3:

Take by weighing 0.02 gram PG36 by weight, 0.24 gram PBK11,0.02 gram PY110, CBCC-A base-material 1005 grams.Making processes is with embodiment 1.

Embodiment 4:

Take by weighing 0.02 gram PG36 by weight, 0.25 gram PBK11,0.02 gram PY110, CBCC-A base-material 995 grams.Making processes is with embodiment 1.

Sample for Chinese architectural color card detected result tabulation with embodiment 1 to 4:

Table 1

Circulation ratio: 0.01	Measure the L value	Measure the A value	Measure the B value	??ΔE	Glossiness (85 °)
						Embodiment 1	??93.55	??-1.06	??1.18	??0.02	??5°
Embodiment 2	??93.65	??-1.07	??1.26	??0.14	??5°
						Embodiment 3	??93.65	??-0.92	??1.16	??0.18	??5°
Embodiment 4	??93.55	??-0.92	??1.31	??0.21	??5°

Remarks: in the CIE1976LAB uniform colour space, Δ E=[(L-L*) ²+ (A-A*) ²+ (B-B*) ²] ^1/2, be used for the degree of closeness of judgement sample and standard.Wherein Δ E represents total color difference, and L represents the standard brightness value, and L* represents to measure brightness value, A represent standard red/green value, red/green value that A* represents to measure, B represents standard Huang/indigo plant value, B* represents to measure Huang/indigo plant value.Glossiness refers to the gloss intensity with the body surface of data statement.

Detect through DATACOLOR 600 spectrophotometers, in the embodiment of table 1, aberration Δ E≤3.0 between average value measured and the standard value, the Chromatic color that satisfies GB/T 15608-1995 Chinese colour system national Specification are the requirement (GB/T 15608-1995) of sample aberration latitude Δ E≤3.

Composition does not have the disadvantages of filming such as loose colour, layering and flocculation in put procedure, volatile organic compounds in technology making processes (VOC) burst size＜200g/L, free formaldehyde≤0.1g/kg, dissoluble lead≤90mg/kg, soluble cadmium≤75mg/kg, soluble chromium≤60mg/kg, soluble mercury≤60mg/kg, LD50/ per os/mouse:＞7000 milligrams/kilogram.The sample for Chinese architectural color card color reproducibility is good.

Other some test performances are as shown in the table:

Table 2

	Composition weathering resistance (GB/T1865-1997)	Composition heat storage stability (GB 6753.3-86)
			Embodiment 1	700h is no abnormal	??ΔE≤0.30
Embodiment 2	700h is no abnormal	??ΔE≤0.30

	Composition weathering resistance (GB/T1865-1997)	Composition heat storage stability (GB 6753.3-86)
			Embodiment 3	700h is no abnormal	??ΔE≤0.30
Embodiment 4	700h is no abnormal	??ΔE≤0.30

Can clearly be seen that by last table 2, the composition coating weathering resistance that selected embodiment obtains detects the prescribed value of data fit national standard, and detect by the heat storage stability experiment, colour-change is lower than 0.30, has guaranteed to realize the accuracy and the permanent stability of sample for Chinese architectural color card.

Claims (4)

1. the composition of 5.6GY 9/1 pigment consists of by weight:

995～1005 parts of CBCC-A base-materials;

PG36, pigment content are 39%, 0.02 part;

PBK11, pigment content are 50%, 0.23～0.25 part;

PY110, pigment content are 33%, 0.01～0.02 part;

Above-mentioned CBCC-A base-material main component is an acrylic copolymer, and content is 30～40%, and its average molecular weight range is 15～200,000, median size is 0.1～0.2 μ m, and minimum film-forming temperature is 10～22 ℃, and second-order transition temperature is 25～35 ℃, anionic, pH value are 8.5～10.0; Select TiO for use ₂Content 〉=95%, oil number＜20g/100g, the reducing power Reynolds is several now 1800, and ISO 591R2 type is as main white pigment, and content is 18～22%; The contrast ratio of this base-material is 0.90～0.96, and stormer viscosity is 90～100KU, when incident angle is 85 °, and 5 °～10 ° of glossiness.

2. the sample for Chinese architectural color card of a 5.6GY9/1 color is characterized in that: by the raw material and the proportioning preparation of claim 1.

3. the sample for Chinese architectural color card of 5.6GY 9/1 color according to claim 2, be encoded to CBCC1331, its coding concerns one to one with 5.6GY 9/1, it is characterized in that: when incident angle is 85 °, 4 °～6 ° of its glossiness, and aberration Δ E≤3.0 between the standard value.

4. the technological method of the sample for Chinese architectural color card of preparation claim 2 or 3 described 5.6GY 9/1 colors comprises the steps:

1) raw material blending: take by weighing raw material by proportioning, mix;

2) coating: at ambient relative humidity 50% ± 5%, under 23 ± 2 ℃ of conditions of room temperature, adopt mechanical coating method, composition evenly entirely is coated on the base material, base material is metallic substance or non-metallic material, and the coating wet-film thickness is 250 μ m;

3) drying: place 50 ± 2 ℃ of dry 3～4h of accurate baking oven to constant weight composition coating, take out, be cooled to room temperature, obtain sample for Chinese architectural color card.