CN101747012B - Caulking desulphurization gypsum - Google Patents
Caulking desulphurization gypsum Download PDFInfo
- Publication number
- CN101747012B CN101747012B CN2008102402668A CN200810240266A CN101747012B CN 101747012 B CN101747012 B CN 101747012B CN 2008102402668 A CN2008102402668 A CN 2008102402668A CN 200810240266 A CN200810240266 A CN 200810240266A CN 101747012 B CN101747012 B CN 101747012B
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- CN
- China
- Prior art keywords
- caulking
- gypsum
- desulfurization gypsum
- agent
- desulfurization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/144—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
- C04B2111/343—Crack resistant materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses caulking desulfurization gypsum. The caulking desulfurization gypsum comprises the following components in percentage by weight: 0.1-8% of conditioning agent, 1-25% of pulverized fuel ash, 0.3-1% of water-retaining agent, 0.01-0.2% of adhesive agent, 0.01-0.5% of retarder and balance of construction desulfurization gypsum. In the invention, the caulking desulfurization gypsum is produced by making full use of two industrial solid wastes the desulfurization gypsum and the pulverized fuel ash of a fuel electric plant. Besides, the caulking desulfurization gypsum has higher intensity, and the maximum folding strength can reach 4.0 MPa, while the folding strength of the caulked joint of natural gypsum is generally in the range of 3.0-3.4 MPa. In addition, the caulking desulfurization gypsum has good cracking resistance and is detected according to the experimental requirements of ASTM C475/C475M-02. The caulking desulfurization gypsum has no cracks in any form, while the caulked joint of the natural gypsum can generate some fine cracks within the index range generally.
Description
Technical field
The present invention relates to a kind of filleting gypsum.
Background technology
In recent years, Chinese society Economic development face, topsoil also is on the rise, and wherein the discharging of sulfurous gas is one of important factor that causes topsoil.Relevant data shows, the total emission volumn of China's sulfurous gas in 2006 is 4,500 ten thousand tons, and wherein the sulfur dioxide emissions total amount of thermoelectric industry surpasses 50% of total release, expects the year two thousand twenty, and the quantity discharged of sulfurous gas will reach 9000 tons.The lime-gypsum method desulfurization has solved the pollution problem of Sulfur Dioxide In The Atmosphere, has also produced a large amount of using industrial solid waste-desulfurated plasters simultaneously.
The filleting gypsum is normally made by natural plaster of Paris, does not also adopt desulfurated plaster to prepare the report of filleting gypsum at present.Mainly be to adopt desulfurated plaster to prepare the filleting gypsum to exist intensity lower, and easy problems of crack.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of desulfurized gypsum to substitute natural gypsum that can utilize and prepares the filleting gypsum, can reduce the cost of filleting putty, and fully utilize the desulfurated plaster resource.
In order to address the above problem, the invention provides a kind of caulking desulphurization gypsum and comprise following component: adjusting agent 0.1~8%, flyash 1~25%, water-holding agent 0.3~1%, caking agent 0.01~0.2%, retardant 0.01~0.5%, surplus is the building desulfurated plaster; Wherein, described per-cent is weight percentage.
Preferably, described adjusting agent is sulfonate.
Preferably, described water-retaining admixture is methylcellulose gum, Xylo-Mucine or ether of cellulose.
Preferably, described caking agent is rubber powder.
Preferably, described retardant is citric acid.
Preferably, the granularity of described flyash is greater than 80 orders.
The present invention takes full advantage of two kinds of using industrial solid waste-desulfurated plasters and the flyash in fuel-burning power plant, produces a kind of caulking desulphurization gypsum.In addition, caulking desulphurization gypsum of the present invention has higher intensity, and its folding strength is the highest can to reach 4.0Mpa, and the folding strength of plaster of paris filleting is generally at 3.0~3.4Mpa.Caulking desulphurization gypsum of the present invention has well anti-cracking performance in addition, detect according to ASTM C475/C 475M-02 requirement of experiment, caulking desulphurization gypsum of the present invention is without what crackle of appointing form, and plaster of paris filleting generally can produce the minute crack in some indication ranges.
Embodiment
Embodiment 1
The caulking desulphurization gypsum of the present embodiment comprises following component: adjusting agent 0.1%, flyash 1%, water-holding agent 0.3%, caking agent 0.01%, toughener 0.1%, and surplus is the building desulfurated plaster; Wherein, above-mentioned per-cent is weight percentage.
Preparation process is as follows:
The building desulfurization gypsum powder enters mixer through metering, simultaneously with granularity can be all flyash and other admixtures by 80 mesh standard sieves enter mixer through metering, behind the mixing by certainweight pack product.
Above-mentioned adjusting agent is sulfonate, and water-holding agent is methylcellulose gum, Xylo-Mucine or ether of cellulose, and binding agent is rubber powder, and retardant is citric acid.
After testing, the caulking desulphurization gypsum intensity of the present embodiment reaches 3.6MPa, detects its anti-cracking performance according to ASTM C475/C475M-02 requirement of experiment, and caulking desulphurization gypsum putty of the present invention is without any crackle.
Embodiment 2
The caulking desulphurization gypsum of the present embodiment comprises following component: adjusting agent 8%, flyash 25%, water-holding agent 1%, caking agent 0.2%, toughener 2%, and surplus is the building desulfurated plaster; Wherein, above-mentioned per-cent is weight percentage.
Preparation process is with embodiment 1.
Above-mentioned adjusting agent is sulfonate, and water-holding agent is methylcellulose gum, Xylo-Mucine or ether of cellulose, and binding agent is rubber powder, and retardant is citric acid.
After testing, the caulking desulphurization gypsum intensity of the present embodiment reaches 4.0MPa, detects its anti-cracking performance according to ASTM C475/C475M-02 requirement of experiment, and caulking desulphurization gypsum putty of the present invention is without any crackle.
Embodiment 3
The caulking desulphurization gypsum of the present embodiment comprises following component: adjusting agent 4%, flyash 13%, water-holding agent 0.7%, caking agent 0.1%, toughener 1%, and surplus is the building desulfurated plaster; Wherein, above-mentioned per-cent is weight percentage.
Preparation process is with embodiment 1.
Above-mentioned adjusting agent is sulfonate, and water-holding agent is methylcellulose gum, Xylo-Mucine or ether of cellulose, and binding agent is rubber powder, and retardant is citric acid.
After testing, the caulking desulphurization gypsum intensity of the present embodiment reaches 3.8MPa, detects its anti-cracking performance according to ASTM C475/C475M-02 requirement of experiment, and caulking desulphurization gypsum of the present invention is without any crackle.
In sum; being preferred embodiment of the present invention only below, is not for restriction protection scope of the present invention, therefore; all any modifications of doing within the spirit and principles in the present invention, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (2)
1. a caulking desulphurization gypsum is characterized in that, comprises following component: adjusting agent 0.1~8%, flyash 1~25%, water-holding agent 0.3~1%, caking agent 0.01~0.2%, retardant 0.01~0.5%, and surplus is the building desulfurated plaster; Wherein, described per-cent is weight percentage; Wherein, described adjusting agent is sulfonate, and described water-holding agent is methylcellulose gum, Xylo-Mucine or ether of cellulose, and described caking agent is rubber powder, and described retardant is citric acid.
2. caulking desulphurization gypsum as claimed in claim 1 is characterized in that, the granularity of described flyash is greater than 80 orders.
Priority Applications (1)
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CN2008102402668A CN101747012B (en) | 2008-12-18 | 2008-12-18 | Caulking desulphurization gypsum |
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CN2008102402668A CN101747012B (en) | 2008-12-18 | 2008-12-18 | Caulking desulphurization gypsum |
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CN101747012A CN101747012A (en) | 2010-06-23 |
CN101747012B true CN101747012B (en) | 2013-03-27 |
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CN2008102402668A Active CN101747012B (en) | 2008-12-18 | 2008-12-18 | Caulking desulphurization gypsum |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103642295B (en) * | 2013-11-26 | 2016-06-22 | 上海第二工业大学 | A kind of method preparing filleting gypsum putty powder from desulfurized gesso of flue gas |
CN107434391A (en) * | 2016-05-25 | 2017-12-05 | 北新集团建材股份有限公司 | A kind of water-fast bonding gypsum powder and preparation method thereof |
CN107434390A (en) * | 2016-05-25 | 2017-12-05 | 镇江北新建材有限公司 | A kind of water-fast filleting land plaster and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101250038A (en) * | 2007-02-21 | 2008-08-27 | 孙晋东 | Gypsum-based building adhesive (bonding gypsum) |
CN101265068A (en) * | 2008-04-28 | 2008-09-17 | 长沙归一建材科技有限公司 | Gelatinization material gypsum-cement and producing method thereof |
-
2008
- 2008-12-18 CN CN2008102402668A patent/CN101747012B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101250038A (en) * | 2007-02-21 | 2008-08-27 | 孙晋东 | Gypsum-based building adhesive (bonding gypsum) |
CN101265068A (en) * | 2008-04-28 | 2008-09-17 | 长沙归一建材科技有限公司 | Gelatinization material gypsum-cement and producing method thereof |
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CN101747012A (en) | 2010-06-23 |
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Effective date of registration: 20230403 Address after: 315600 Tuanjie Tang, Qiangjiao Town, Ninghai County, Ningbo City, Zhejiang Province Patentee after: BNBM NINGBO Co.,Ltd. Address before: 100037, Beijing, Haidian District, Three Mile Road, No. 11, China building materials building, 16 floor Patentee before: BEIJING NEW BUILDING MATERIALS PLC |