CN101735735B - Acrylic ester adhesive - Google Patents
Acrylic ester adhesive Download PDFInfo
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- CN101735735B CN101735735B CN2010100183574A CN201010018357A CN101735735B CN 101735735 B CN101735735 B CN 101735735B CN 2010100183574 A CN2010100183574 A CN 2010100183574A CN 201010018357 A CN201010018357 A CN 201010018357A CN 101735735 B CN101735735 B CN 101735735B
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Abstract
The invention discloses an acrylic ester adhesive comprising an A component and a B component, wherein the A component comprises the following constituents in percentage by weight: 40 to 60 parts of acrylic ester monomers, 30 to 40 parts of elastomers, 0.05 part of accelerating agents, 0.01 part of polymerization inhibitors, 5 parts of flexibilizers, 0.05 part of defoaming agents and 0.05 part of coupling agents; the B component comprises 50 to 70 parts of hyperoxide, 30 to 40 parts of plasticiser and 2 to 4 parts of thickener gaseous white carbon black; and after mixing the A component with the B component, the acrylic ester adhesive is obtained, and the consumption ratio of A component to B component is A:B=10:1. The acrylic ester adhesive is prepared from the special raw materials according to special raw material proportion and has excellent adhesion performance, capabilities of longtime aging resistance and corrosion prevention, no stone pollution, no volatile matter after solidification, contribution to environmental protection and convenient construction and transportation.
Description
Technical field
The present invention relates to a kind of tackiness agent that is used for the stone material bonding repairing, be specifically related to a kind ofly can effectively improve bonding strength, not pollute stone material, and the acrylic ester adhesive of room temperature fast-curing.
Background technology
At present, tackiness agent commonly used has acrylic ester adhesive, epoxy resin and urethane adhesives in building trade.Wherein, acrylic ester adhesive has obtained using widely because of its original characteristic, and the market requirement of thermofixation acrylic ester adhesive is still in quick growth.
The thermofixation acrylic ester adhesive belongs to rubber toughened system, and at room temperature fast setting forms crosslinking structure, is suitable for all kinds of stone materials and acrylic goods.Acrylic ester adhesive majority on the market is that two components mix or dispersion system now, and basic component can impose on the one side of bonding base material, and active constituent is applied to another side; Perhaps component imposes on the one side of adhesives, and another component imposes on another side.Acrylic ester adhesive has different constructional methods, and set time can be longer relatively from being short to very much.But the proportioning raw materials of acrylic ester adhesive whether suitable with mix the state that whether evenly seriously all can influence after the curing.
Summary of the invention
Goal of the invention: in order to overcome the deficiency that exists in the prior art, the present invention provides a kind of can effectively improve bonding strength, do not pollute stone material, and the acrylic ester adhesive of room temperature fast-curing.
Technical scheme: for realizing above-mentioned purpose; A kind of acrylic ester adhesive of the present invention; Comprise A component and B component, comprise 0.05 part of 40～60 parts of acrylic ester monomers, 30～40 parts on elastomerics, 0.05 part of promotor, 0.01 part of stopper, 5 parts of toughner, 0.05 part of skimmer and coupling agent by mass fraction A component; The B component comprises 50～70 parts of superoxide, 30～40 parts in softening agent, 2～4 parts of thickening materials; A component and B component promptly get said acrylic ester adhesive after mixing, and the amount ratio of A component and B component is A: B=10: 1.
Said acrylic ester monomer is formed by wantonly 3 kinds in TEB 3K, Jia Jibingxisuanyizhi, ethyl propenoate, Bing Xisuandingzhi, the methylacrylic acid 2-ethylhexyl.
Said elastomerics be in SBS, ABS, chlorosuphonated-polyethylene, paracril, the X 050 any two or multiple.
Said promotor is one or more in amine, aldehyde-amine condensate, the Thiourea.
Said stopper is one or more in Resorcinol, benzoquinones, nitrophenols, the DBPC 2,6 ditertiary butyl p cresol.
Said toughner is one or more in liquid polysulfide rubber, liquid polybutadiene rubber, LNBR and the styrene-butadiene rubber(SBR).
Said superoxide is one or more in peroxo-phthalyl, lauroyl peroxide, the hydrogen phosphide cumene.
Said softening agent is one or more in dimethyl phthalate, diethyl phthalate, Witcizer 300, the DOP.
Said skimmer is methyl-silicone oil or YKA-555.
Said coupling agent is KH-550 or KH-560.
The preparation method of said A component: by proportioning raw materials, in joining the glue still, drop into acrylate monomer, drop into promotor, stopper, skimmer, coupling agent and toughner again; Stir then, make each material dissolution and mix; Drop into elastomerics at last, room temperature was placed 12 hours.After treating the elastomerics swelling, keep 60 ℃～70 ℃ of temperature in the kettle, 4～6 hours time.Stop heating after elastomerics fully dissolves, discharging makes the A component.
The preparation method of said B component: by proportioning raw materials, with superoxide, the meteorological WHITE CARBON BLACK of softening agent and thickening material adds in the Scattered Kettle, and stirring to make the B group.
At last A component and B component are mixed and promptly get said esters of acrylic acid tackiness agent, the amount ratio of said A component and B component is A: B=10: 1.
Beneficial effect: esters of acrylic acid tackiness agent of the present invention adopts specific raw material and proportioning raw materials to be prepared from, and has excellent adhesiveproperties, can anti-aging for a long time, anticorrosion, not pollute stone material, solidifies the no volatile matter in back, helps environmental protection; Convenient construction and transportation simultaneously.
Embodiment
Below in conjunction with embodiment the present invention is done explanation further.
Embodiment 1
A kind of esters of acrylic acid tackiness agent comprises A component and B component, presses mass fraction, and each component composition is following:
A B component component
TEB 3K: 10 parts of peroxo-phthalyls: 50 parts
Jia Jibingxisuanyizhi: 20 parts of dimethyl phthalates: 15 parts
Methylacrylic acid 2-ethylhexyl: 10 parts of Witcizer 300s: 15 parts
SBS:15 part gas-phase silica: 2 parts
ABS:15 part
N, accelerine: 0.05 part
Nitrophenols: 0.01 part
Styrene-butadiene rubber(SBR): 5 parts
BYKA-555:0.05 part
KH-550:0.05 part
The preparation method of A component: in joining the glue still, drop into 10 parts of TEB 3Ks, 20 parts of Jia Jibingxisuanyizhis, 10 parts of methylacrylic acid 2-ethylhexyls; N; 0.05 part of accelerine, 0.01 part of nitrophenols, 0.05 part of BYKA-555,0.05 part of KH-550,5 parts in styrene-butadiene rubber(SBR) behind the stirring and dissolving mixing, drop into 15 parts of SBS; 15 parts of ABS, room temperature was placed 12 hours.After treating the elastomerics swelling, keep 60 ℃ of temperature in the kettle, 4 hours time.Stop heating after elastomerics fully dissolves, discharging makes the A component.The preparation of B component is that the various batchings in the said scope are added in the Scattered Kettle in definite ratio, and stirring to be worth B component product.At last A component and B component are mixed and promptly get the esters of acrylic acid tackiness agent, the amount ratio of A component and B component is A: B=10: 1.
Embodiment 2
A kind of esters of acrylic acid tackiness agent comprises A component and B component, presses mass fraction, and each component composition is following:
A B component component
TEB 3K: 20 parts of peroxo-phthalyls: 30 parts
Ethyl propenoate: 20 portions of dicumyl peroxides: 30 parts
Methylacrylic acid 2-ethylhexyl: 10 parts of Witcizer 300s: 20 parts
SBS:15 part diethyl phthalate: 15 parts
ABS:10 part gas-phase silica: 3 parts
Chlorosuphonated-polyethylene: 10 parts
N, accelerine: 0.025 part
Substituting group thiocarbamide: 0.025 part
Resorcinol: 0.01 part
LNBR: 5 parts
Methyl-silicone oil: 0.05 part
KH-560:0.05 part
The preparation method of A component: in joining the glue still, drop into 20 parts of TEB 3Ks; 20 parts of ethyl propenoates, 10 parts of methylacrylic acid 2-ethylhexyls, N; 0.025 part of accelerine, 0.025 part of substituting group thiocarbamide, 0.01 part of Resorcinol, 0.05 part of methyl-silicone oil, 0.05 part of KH-560,5 parts of LNBRs; Behind the stirring and dissolving mixing, drop into 15 parts of SBS, 10 parts of chlorosuphonated-polyethylenes, 10 parts of ABS, room temperature was placed 12 hours.After treating the elastomerics swelling, keep 65 ℃ of temperature in the kettle, 5 hours time.Stop heating after elastomerics fully dissolves, discharging makes the A component.The preparation of B component is that the various batchings in the said scope are added in the Scattered Kettle in definite ratio, and stirring to be worth B component product.At last A component and B component are mixed and promptly get the esters of acrylic acid tackiness agent, the amount ratio of A component and B component is A: B=10: 1.
Embodiment 3
A kind of esters of acrylic acid tackiness agent comprises A component and B component, presses mass fraction, and each component composition is following:
A B component component
TEB 3K: 10 parts of peroxo-phthalyls: 60 parts
Bing Xisuandingzhi: 20 parts of dimethyl phthalates: 20 parts
Methylacrylic acid 2-ethylhexyl: 20 parts of Witcizer 300s: 20 parts
SBS:10 part gas-phase silica: 4 parts
Paracril: 20 parts
X 050: 10 parts
N, N-Diethyl Aniline: 0.05 part
DBPC 2,6 ditertiary butyl p cresol: 0.01 part
Liquid polybutadiene rubber: 5 parts
Methyl-silicone oil: 0.05 part
KH-550:0.05 part
The preparation method of A component: in joining the glue still, drop into 10 parts of TEB 3Ks, 20 parts of Bing Xisuandingzhis, 20 parts of methylacrylic acid 2-ethylhexyls; N; 0.05 part of N-Diethyl Aniline, 0.01 part of DBPC 2,6 ditertiary butyl p cresol, 0.05 part of methyl-silicone oil, 0.05 part of KH-550,5 parts of liquid polybutadiene rubbers are behind the stirring and dissolving mixing; Drop into 10 parts of SBS, 20 parts of paracrils, 10 parts of X 050s, room temperature was placed 12 hours.After treating the elastomerics swelling, keep 70 ℃ of temperature in the kettle, 4 hours time.Stop heating after elastomerics fully dissolves, discharging makes the A component.The preparation of B component is that the various batchings in the said scope are added in the Scattered Kettle in definite ratio, and stirring to be worth B component product.At last A component and B component are mixed and promptly get the esters of acrylic acid tackiness agent, the amount ratio of A component and B component is A: B=10: 1.
Embodiment 4
A kind of esters of acrylic acid tackiness agent comprises A component and B component, presses mass fraction, and each component composition is following:
A B component component
TEB 3K: 20 parts of peroxo-phthalyls: 70 parts
Jia Jibingxisuanyizhi: 20 parts of Witcizer 300s: 20 parts
Methylacrylic acid 2-ethylhexyl: 20 parts of DOPs: 20 parts
ABS:10 part gas-phase silica: 4 parts
Chlorosuphonated-polyethylene: 10 parts
X 050: 20 parts
N, N-dimethyl-p-toluidine: 0.05 part
Benzoquinones: 0.01 part
Liquid polysulfide rubber: 5 parts
Methyl-silicone oil: 0.05 part
KH-550:0.05 part
The preparation method of A component: in joining the glue still, drop into 20 parts of TEB 3Ks; 20 parts of Jia Jibingxisuanyizhis, 20 parts of methylacrylic acid 2-ethylhexyls, N; 0.05 part of N-dimethyl-p-toluidine, 0.01 part of benzoquinones, 0.05 part of methyl-silicone oil, 0.05 part of KH-550,5 parts of liquid polysulfide rubbers; Behind the stirring and dissolving mixing, drop into 10 parts of ABS, 10 parts of chlorosuphonated-polyethylenes, 20 parts of X 050s, room temperature was placed 12 hours.After treating the elastomerics swelling, keep 70 ℃ of temperature in the kettle, 6 hours time.Stop heating after elastomerics fully dissolves, discharging makes the A component.The preparation of B component is that the various batchings in the said scope are added in the Scattered Kettle in definite ratio, and stirring to be worth B component product.At last A component and B component are mixed and promptly get the esters of acrylic acid tackiness agent, the amount ratio of A component and B component is A: B=10: 1.
The above only is a preferred implementation of the present invention; Be noted that technician for the present technique field; Under the prerequisite that does not break away from the principle of the invention, can also make some improvement and retouching, these improvement and retouching also should be regarded as protection scope of the present invention.
Claims (8)
1. acrylic ester adhesive; It is characterized in that: comprise A component and B component, comprise 0.05 part of 40～60 parts of acrylic ester monomers, 30～40 parts on elastomerics, 0.05 part of promotor, 0.01 part of stopper, 5 parts of toughner, 0.05 part of skimmer and coupling agent by mass fraction A component; The B component comprises 50～70 parts of superoxide, 30～40 parts in softening agent, 2～4 parts of thickening material gas-phase silicas; A component and B component promptly get said acrylic ester adhesive after mixing, and the amount ratio of A component and B component is A: B=10: 1;
Said acrylic ester monomer is formed by wantonly 3 kinds in TEB 3K, Jia Jibingxisuanyizhi, ethyl propenoate, Bing Xisuandingzhi, the methylacrylic acid 2-ethylhexyl;
Said elastomerics be in SBS, ABS, chlorosuphonated-polyethylene, paracril, the X 050 any two or multiple.
2. acrylic ester adhesive according to claim 1 is characterized in that: said promotor is one or more in amine, aldehyde-amine condensate, the Thiourea.
3. acrylic ester adhesive according to claim 1 is characterized in that: said stopper is one or more in Resorcinol, benzoquinones, nitrophenols, the DBPC 2,6 ditertiary butyl p cresol.
4. acrylic ester adhesive according to claim 1 is characterized in that: said toughner is one or more in liquid polysulfide rubber, liquid polybutadiene rubber, LNBR and the styrene-butadiene rubber(SBR).
5. acrylic ester adhesive according to claim 1 is characterized in that: said superoxide is one or more in peroxo-phthalyl, lauroyl peroxide, the hydrogen phosphide cumene.
6. acrylic ester adhesive according to claim 1 is characterized in that: said softening agent is one or more in dimethyl phthalate, diethyl phthalate, Witcizer 300, the DOP.
7. acrylic ester adhesive according to claim 1 is characterized in that: said skimmer is a methyl-silicone oil.
8. acrylic ester adhesive according to claim 1 is characterized in that: said coupling agent is KH-550 or KH-560.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010100183574A CN101735735B (en) | 2010-01-14 | 2010-01-14 | Acrylic ester adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010100183574A CN101735735B (en) | 2010-01-14 | 2010-01-14 | Acrylic ester adhesive |
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| Publication Number | Publication Date |
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| CN101735735A CN101735735A (en) | 2010-06-16 |
| CN101735735B true CN101735735B (en) | 2012-05-09 |
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| CN2010100183574A Active CN101735735B (en) | 2010-01-14 | 2010-01-14 | Acrylic ester adhesive |
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Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| GB201006427D0 (en) | 2010-02-26 | 2010-06-02 | Scott Bader Co | Methacrylate-based adhesive compositions |
| TWI509007B (en) * | 2010-10-06 | 2015-11-21 | Vanderbilt Chemicals Llc | Elastomer product and method of making thereof |
| CN102382233B (en) * | 2011-08-09 | 2013-09-11 | 重庆市智翔铺道技术工程有限公司 | Light colored cementitious material and application thereof |
| CN102433093B (en) * | 2011-09-13 | 2013-04-24 | 北京高盟新材料股份有限公司 | Water-emulsion plant adhesive and its preparation method |
| CN102807715A (en) * | 2012-07-27 | 2012-12-05 | 苏州市兴吴工程塑胶有限公司 | Formula of toughened polystyrene plastic |
| CN103497692A (en) * | 2013-09-29 | 2014-01-08 | 苏州华周胶带有限公司 | Powerful acrylate adhesive |
| CN105950031A (en) * | 2016-06-28 | 2016-09-21 | 哈尔滨永淇化工有限公司 | Sealant for storage battery |
| CN108395850B (en) * | 2018-03-27 | 2021-04-27 | 绍兴市林森五金化工有限公司 | Adhesive, two-component adhesive containing same, bonding method and combination |
| CN112646499B (en) * | 2019-10-11 | 2022-05-24 | 3M创新有限公司 | Two-component acrylic structural adhesive with improved storage stability |
| CN111234745A (en) * | 2020-03-25 | 2020-06-05 | 昆明金水龙橡胶制品有限公司 | Environment-friendly high-temperature-resistant conveying belt binder and preparation method thereof |
| CN111675796B (en) * | 2020-05-29 | 2022-04-22 | 万华化学集团股份有限公司 | Preparation method of polybutadiene rubber dispersion |
| CN113388347B (en) * | 2021-07-06 | 2023-02-03 | 长春工业大学 | Preparation method of high-adaptability solid adhesive |
| JP7176599B1 (en) * | 2021-08-12 | 2022-11-22 | 横浜ゴム株式会社 | (Meth)acrylic adhesive composition, laminate and tire |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3221829B2 (en) * | 1995-06-09 | 2001-10-22 | 大倉工業株式会社 | Two-component acrylic adhesive |
| CN101165133A (en) * | 2006-10-17 | 2008-04-23 | 湖北回天胶业股份有限公司 | Bi-component acrylic ester structure adhesive and preparation method thereof |
| CN101392153A (en) * | 2008-09-28 | 2009-03-25 | 广东恒大新材料科技有限公司 | Bi-component acrylic ester adhesive |
-
2010
- 2010-01-14 CN CN2010100183574A patent/CN101735735B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3221829B2 (en) * | 1995-06-09 | 2001-10-22 | 大倉工業株式会社 | Two-component acrylic adhesive |
| CN101165133A (en) * | 2006-10-17 | 2008-04-23 | 湖北回天胶业股份有限公司 | Bi-component acrylic ester structure adhesive and preparation method thereof |
| CN101392153A (en) * | 2008-09-28 | 2009-03-25 | 广东恒大新材料科技有限公司 | Bi-component acrylic ester adhesive |
Non-Patent Citations (1)
| Title |
|---|
| JP特许第3221829号B2 2001.08.17 |
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