CN101724360A - Raw paper of pressure-sensitive adhesive paper, manufacturing method thereof and pressure-sensitive adhesive composite paint used in manufacturing method - Google Patents
Raw paper of pressure-sensitive adhesive paper, manufacturing method thereof and pressure-sensitive adhesive composite paint used in manufacturing method Download PDFInfo
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- CN101724360A CN101724360A CN200810175019A CN200810175019A CN101724360A CN 101724360 A CN101724360 A CN 101724360A CN 200810175019 A CN200810175019 A CN 200810175019A CN 200810175019 A CN200810175019 A CN 200810175019A CN 101724360 A CN101724360 A CN 101724360A
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- pressure
- sensitive adhesive
- paper
- mentioned
- epicholorohydrin
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- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 446
- 239000002131 composite material Substances 0.000 title claims description 165
- 239000003973 paint Substances 0.000 title claims description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 29
- 238000007639 printing Methods 0.000 claims abstract description 155
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 95
- 125000002091 cationic group Chemical group 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 150000003973 alkyl amines Chemical class 0.000 claims description 72
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 54
- 150000003839 salts Chemical class 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 30
- 239000011248 coating agent Substances 0.000 claims description 29
- 238000000576 coating method Methods 0.000 claims description 29
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 25
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 24
- 239000000853 adhesive Substances 0.000 claims description 22
- 230000001070 adhesive effect Effects 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 230000004048 modification Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract description 7
- 229920005989 resin Polymers 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 239000002245 particle Substances 0.000 abstract description 5
- 239000011247 coating layer Substances 0.000 abstract 4
- 239000000945 filler Substances 0.000 abstract 3
- 238000001454 recorded image Methods 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 421
- 239000000976 ink Substances 0.000 description 126
- 239000003921 oil Substances 0.000 description 58
- 230000015572 biosynthetic process Effects 0.000 description 30
- 238000005755 formation reaction Methods 0.000 description 30
- 230000000052 comparative effect Effects 0.000 description 25
- 238000011156 evaluation Methods 0.000 description 24
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 22
- 244000043261 Hevea brasiliensis Species 0.000 description 19
- 238000010023 transfer printing Methods 0.000 description 18
- 229920000126 latex Polymers 0.000 description 15
- 239000004816 latex Substances 0.000 description 15
- 229920003052 natural elastomer Polymers 0.000 description 15
- 229920001194 natural rubber Polymers 0.000 description 15
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 11
- 239000013530 defoamer Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 229920002647 polyamide Polymers 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 230000006870 function Effects 0.000 description 6
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- 238000009792 diffusion process Methods 0.000 description 5
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- 235000012239 silicon dioxide Nutrition 0.000 description 5
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- 229920002803 thermoplastic polyurethane Polymers 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 4
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000003044 adaptive effect Effects 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000002788 crimping Methods 0.000 description 2
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- 239000000428 dust Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002466 imines Chemical class 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
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- 229920006174 synthetic rubber latex Polymers 0.000 description 2
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
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- 229920002472 Starch Polymers 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 125000002339 acetoacetyl group Chemical group O=C([*])C([H])([H])C(=O)C([H])([H])[H] 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 230000000996 additive effect Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
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- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229950003988 decil Drugs 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
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- 230000002349 favourable effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
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- 239000000314 lubricant Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- XCVNDBIXFPGMIW-UHFFFAOYSA-N n-ethylpropan-1-amine Chemical compound CCCNCC XCVNDBIXFPGMIW-UHFFFAOYSA-N 0.000 description 1
- GVWISOJSERXQBM-UHFFFAOYSA-N n-methylpropan-1-amine Chemical compound CCCNC GVWISOJSERXQBM-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Credit Cards Or The Like (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides raw paper of pressure-sensitive adhesive paper, which is used in printing of an ink-jet printer, has no blur of recorded images, and has sufficient printing density and good printing adaptability of superfine images such as bar codes and the like. The raw paper of the pressure-sensitive adhesive paper suitable to be printed by the ink-jet printer is characterized by comprising base paper, and a coating layer for totally or partially forming a pressure-sensitive adhesive composition on one face or two faces of the base paper; the coating layer contains a base agent, a particle filling agent and a cationic ink fixing agent, wherein the particle filling agent contains amorphous silica of which oil absorption is 100 to 280 milliliters per 100 grams measured according to ISO787-5, and the amorphous silica of the particle filling agent contained in the coating layer accounts for 50 to 150 percent of the weight of the base agent; and the cationic ink fixing agent contains polyalkylamino epichlorohydrin resin, and the polyalkylamino epichlorohydrin resin contained in the coating layer accounts for 5 to 35 percent of the weight of the base agent.
Description
Technical field
The present invention relates to be suitable for body paper, its manufacture method of the paper of pressure-sensitive adhesive (for example, the paper of pressure-sensitive adhesive of postcard purposes, need to keep the paper of pressure-sensitive adhesive etc. of the various letter of information purposes of secret) with the ink jet printer printing and the pressure-sensitive adhesive composite paint that in this manufacture method, uses.In more detail, relate to body paper, its manufacture method of good paper of pressure-sensitive adhesive such as the printing adaptability of very thin image of barcode etc. and the pressure-sensitive adhesive composite paint that in this manufacture method, uses.
Background technology
In recent years, the paper of pressure-sensitive adhesive that developing the secret that similarly can keep communicating by letter, has the postcard purposes that in the notice of the postal service of personal information (for example, the savings amount of money, cost of use etc.), to use with personal delivery with sealed letter.In Japan, postcard is more cheap than the postage of sealed letter.Therefore, in Japan, people have developed the various secrets that can similarly keep communicating by letter with sealed letter, have the personal delivery disguise, can present the paper of pressure-sensitive adhesive with the postcard purposes of the same mode of appearance of postcard simultaneously, extensively are popularized for general use.
The paper of pressure-sensitive adhesive of postcard purposes can be made by the body paper that the special use that provides with drum is provided usually.This body paper comprises basic paper and the coat of the pressure-sensitive adhesive composite that forms on the whole or part on the one side of this base paper or two sides.Containing with non-separability pressure adhesive in the coat is the particulate weighting agent that the base of main component and being used to is adjusted the adhering state of this base.In addition, when the printing of using ink jet printer, also add the cationic printing ink fixing salt be used to make the printing ink photographic fixing etc.
In order to make the multi-joint document (continuous form) of the paper of pressure-sensitive adhesive of postcard purposes by body paper, need through following several procedures: with (fix informations) such as lines (ruled line), mark, designs with the operation of ultraviolet curable ink offset printing to the body paper of drum; The body paper of the drum that is printed with fix information is implemented to form the operation of the perforation processing (perforation process) of fold line or line of cut; The body paper of the drum of having processed by having implemented to bore a hole is in the longitudinal direction uniformly-spaced to be folded into the operation that the zigzag rugosity is finished multi-joint document along perforation.
When the multi-joint document that is used to complete, through following several procedures: by with multi-joint sheet feed to the non-printing on demand machine that impacts mode, printing addressee's address, name, the operation of the personal information (variable information) of the individual numbering of printing, the bill amount of money etc. on personal delivery face in addition on the addressee's name address face; The multi-joint document that has printed variable information is become the operation of the scraps of paper of 1 addressee's name address along perforation cuts; With personal delivery face is the inboard, with the cutting 1 addressee's name address the scraps of paper along perforation be folded into eighty percent discount or three the folding operations; The scraps of paper that folded are put into the operation that dry-type encapsulated machine (dry sealer) carries out the pressure-sensitive adhesive sealing.
The coat of pressure-sensitive adhesive composite does not have cementability under normal temperature, non-pressurized common state, by under making the state that is in subtend between the coat it being placed in the dry-type encapsulated machine with powerful pressure (for example, 50～150kg/cm
2About) clamp, constitute to present cementability for the first time thus.
On the other hand, after in a single day bonding, though the common external force of the imaginations such as automatic letter sorting machine in the time of can not be sent by post is peeled off, if but be exceeded the power of this common external force and the brute force of the degree that can be applied by the people is drawn back, will make 2 folding and bonding scraps of paper, peeling off at the interface between relative coat, thus the variable information of printing is exposed.
What illustrated is, about the use of paper of pressure-sensitive adhesive, the example as in Japan can exemplify postcard paper, also purposes can be expanded to letter of information, file of need to be keep secret etc.
Fig. 1 illustrates an example of the formation of this paper of pressure-sensitive adhesive.In the figure, 101 is paper of pressure-sensitive adhesive, and 110 is basic paper, and 120 is the pressure-sensitive adhesive composite coat.What illustrated is that in the figure, the ratio of each layer may not be the ratio of actual (real) thickness.
Example as the basic comprising of paper of pressure-sensitive adhesive 101 as the example of 1 figure (a), is provided with pressure-sensitive adhesive composite coat 120 on the one side of basic paper 110.In addition, as the example of Fig. 1 (b), pressure-sensitive adhesive composite coat 120 is set on the two sides of basic paper 110.
When the various information of printing on this postcard with personal delivery, all using electrophotographic printer or ink-jet printer up to now.Particularly in recent years, because the low reason that waits of running expense uses the printing of the ink-jet printer of water-based ink to be gazed at.Therefore, the paper of pressure-sensitive adhesive to the postcard that is used to have personal delivery also requires ink-vapor recording adaptability.
As the desired quality of paper of pressure-sensitive adhesive (ink-jet adaptability) that is used for high speed cycle type ink jet printer, require: (1) is even have the ink absorption (ink absorption of coat) that the printed images of peeling off personal delivery face after with the paper of pressure-sensitive adhesive pressure-sensitive adhesive with dry-type encapsulated machine also can not be transferred to the degree of subtend face; (2) has the sharpness (clarity) (the document image sharpness of coat) of the document image that can satisfy the adaptive bar code printing degree of OCR; (3) have under the situation of the paper of pressure-sensitive adhesive of making the postcard purposes, when printing lines or general information with form printing machine by UV curing printing ink etc., the composition of pressure-sensitive adhesive composite do not peel off, can not pollute the coat intensity (intensity of coat) of the degree such as version of printing press from coat.
On having the postcard of personal delivery, in the printed information, also has the fine image of barcode and so on.In the printing of barcode,, require the bright and sharp and printing density of printed barcode lines fully to wait in order correctly to read barcode.Therefore, with the ink jet printer printed bar code time, require used paper to have not the ink-vapor recording adaptability that can cause that track expands, the density of printed images can not reduce etc. owing to the bleeding of jetted ink etc.Particularly in the printing of the high high precise image of " EAN128 barcode " such recording density, require used paper to have the ink-vapor recording adaptability of height.
The technology that has the above-mentioned adaptive paper of pressure-sensitive adhesive of ink-vapor recording as manufacturing, be known that by in the pressure-sensitive adhesive composite coat of the printing surface that becomes various information, cooperating cationic printing ink fixing salt, make the method for jetted ink photographic fixing in the pressure-sensitive adhesive composite coat.As an example of this technology, the someone proposes to cooperate the technology (for example with reference to patent documentation 1) of the polyamide resin of weak cation in the pressure-sensitive adhesive composite coat of the paper of pressure-sensitive adhesive that ink-vapor recording is used.
In addition, also has following method: make the fine mineral dust that contains silicon-dioxide etc. in the pressure-sensitive adhesive composite coat, so that the pressure-sensitive adhesive composite coat can fully absorb jetted ink.As an example of this technology, the someone proposes to make the technology (for example with reference to patent documentation 2) that contains micropowders amorphous silica or fine mineral dust in the pressure-sensitive adhesive composite of the paper of pressure-sensitive adhesive that ink-vapor recording uses.
[patent documentation 1] spy opens flat 9-71758 (claim 1)
[patent documentation 2] spy opens flat 9-11669 number (claim 2)
Summary of the invention
The problem that invention will solve
Yet the ink-vapor recording paper of pressure-sensitive adhesive for record in the patent documentation 1,2 exists the inadequate problem of image definition when the fine image of printed bar code and so on.
In addition, as mentioned above, make postcard, paper of pressure-sensitive adhesive is folded into eighty percent discount or three foldings, apply 50～150kg/cm with personal delivery for the paper of pressure-sensitive adhesive that will implement image recording
2About suppress, with strippingly bonding between the personal delivery face.At this moment, when the photographic fixing of jetted ink on the pressure-sensitive adhesive composite coat is insufficient, exist owing to fold problem on the personal delivery face that the image that writes down on a side's who overlaps the personal delivery face can be transferred to the opposing party.
In addition, as mentioned above, for the postcard with personal delivery, the addressee is in order to confirm personal delivery information, strippingly bonding personal delivery face is peeled off mutually and used.When this is peeled off, in case the pressure-sensitive adhesive composite coat itself is stripped from, then can not ideally peel off, the result exists document image that damaged problem takes place.
The present invention carries out in view of this problem, its purpose is, provide a kind of with in the printing of ink-jet printer, fuzzy (blur), the printing density that does not have a document image fully, body paper, its manufacture method of the good paper of pressure-sensitive adhesive of the printing adaptability of fine image such as barcode and the pressure-sensitive adhesive composite paint that in this manufacture method, uses.
Other purpose of the present invention is, provide a kind of in using the printing of ink jet printer, the photographic fixing of jetted ink on the pressure-sensitive adhesive composite coat is abundant, when using paper of pressure-sensitive adhesive to form to have the postcard of personal delivery, owing to fold body paper, its manufacture method of the paper of pressure-sensitive adhesive on the personal delivery face that the image that is write down on a side's who overlaps the personal delivery face is difficult to be transferred to the opposing party and the pressure-sensitive adhesive composite paint that in this manufacture method, uses.
Other purpose of the present invention is, provides a kind of intensity of pressure-sensitive adhesive composite coat abundant, few paper of pressure-sensitive adhesive that comes off of pressure-sensitive adhesive composite coat such as when peeling off.
About other purposes of the present invention and action effect, by the following narration of reference, so long as those skilled in the art just can easily understand.
[solving the means of problem]
Can think that above-mentioned invention problem to be solved can solve by body paper, its manufacture method with paper of pressure-sensitive adhesive following formation, that be suitable for ink jet printer and the pressure-sensitive adhesive composite paint that uses in this manufacture method.
That is, the body paper that is suitable for the paper of pressure-sensitive adhesive of ink jet printer of the present invention comprises basic paper and the coat of the pressure-sensitive adhesive composite that forms on the whole or part on the one side of above-mentioned basic paper or two sides.
In above-mentioned coat, the base that to contain with non-separability pressure adhesive be main component, the particulate weighting agent and being used to that is used to adjust the adhering state of above-mentioned base make the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection.
As above-mentioned particulate weighting agent, containing the oil number of measuring according to ISO787-5 is the amorphous silica of 100～280ml/100g, contained above-mentioned amorphous silica is to be 50～150 weight % with respect to above-mentioned base 100 weight % with respect to the cooperation ratio of above-mentioned base in above-mentioned coat.
As above-mentioned cationic printing ink fixing salt, contain poly-alkylamine Epicholorohydrin resinoid, contained above-mentioned poly-alkylamine Epicholorohydrin resinoid is to be 5～35 weight % with respect to above-mentioned base 100 weight % with respect to the cooperation ratio of above-mentioned base in the above-mentioned coat.
What illustrated is, in the body paper of paper of pressure-sensitive adhesive of the present invention, as long as the pressure-sensitive adhesive composite coat of one side satisfies above-mentioned condition at least, another side can suit to adopt the pressure-sensitive adhesive composite coat of identical formation, different formations the pressure-sensitive adhesive composite coat, the formation of pressure-sensitive adhesive composite coat etc. is not set.
And, by this formation,, can print fuzzy, the sufficient very thin image of printing density that do not have document image aptly with in the printing of ink jet printer.And then it is abundant to obtain the photographic fixing of jetted ink on the pressure-sensitive adhesive composite coat, when formation has the postcard of personal delivery, can not be transferred to the body paper of the paper of pressure-sensitive adhesive on the opposing party's the personal delivery face at the image that is write down on the personal delivery face owing to a folding side who overlaps.
In a preferred embodiment of the invention, as above-mentioned amorphous silica, also can use the oil number of measuring according to ISO787-5 is the silicon-dioxide of 130～200ml/100g.By this formation, with in the printing of ink-jet printer, can print does not have that document image is fuzzy, the sufficient very thin image of printing density preferablyly.
In a preferred embodiment of the invention, as above-mentioned poly-alkylamine Epicholorohydrin resinoid, also can use poly-dimethylamine Epicholorohydrin and/or modification dimethylamine Epicholorohydrin condenses.By this formation, with in the printing of ink-jet printer, can print does not have that document image is fuzzy, the sufficient very thin image of printing density preferablyly.
In a preferred embodiment of the invention, as above-mentioned poly-alkylamine Epicholorohydrin resinoid, can use number-average molecular weight is poly-alkylamine Epicholorohydrin resinoid below 10000.By this formation, with in the printing of ink-jet printer, can print does not have that document image is fuzzy, the sufficient very thin image of printing density preferablyly.
According to the preferred embodiments of the invention, in the coat of above-mentioned pressure-sensitive adhesive composite, can also also cooperate every above-mentioned base 100 weight parts is the polyvinyl alcohol of 5～20 weight parts.By this formation, the intensity that can obtain the pressure-sensitive adhesive composite coat fully, when peeling off etc. the body paper of few paper of pressure-sensitive adhesive that comes off of pressure-sensitive adhesive composite coat.
Consider that from another point of view the present invention also can be used as the manufacture method of the body paper of the paper of pressure-sensitive adhesive that is suitable for ink jet printer and understands.That is, this manufacture method comprises: the 1st step of preparing basic paper; Prepare the 2nd step of pressure-sensitive adhesive composite paint; The pressure-sensitive adhesive composite paint of preparing in coating the 2nd step on the one side by the basic paper prepared in above-mentioned the 1st step or the whole or part on two sides forms the 3rd step of the coat of pressure-sensitive adhesive composite.
The particulate weighting agent and being used to that above-mentioned the 2nd step comprises by the base that will be main component with non-separability pressure adhesive, be used for adjusting the adhering state of above-mentioned base makes the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection add water to mix the coating that generates pressure-sensitive adhesive composite paint and generate step.
Generate in the step in above-mentioned coating, as above-mentioned particulate weighting agent, containing the oil number of measuring according to ISO787-5 is the amorphous silica of 100～280ml/100g, and above-mentioned amorphous silica with respect to the cooperation ratio of above-mentioned base is, is 50～150 weight % with respect to above-mentioned base 100 weight %.
In addition, as above-mentioned cationic printing ink fixing salt, contain poly-alkylamine Epicholorohydrin resinoid, above-mentioned poly-alkylamine Epicholorohydrin resinoid with respect to the cooperation ratio of above-mentioned base is, is 5～35 weight % with respect to above-mentioned base 100 weight %.
In preferred embodiments, in above-mentioned manufacture method, can also cooperate every above-mentioned base 100 weight parts in the above-mentioned pressure-sensitive adhesive composite paint is the polyvinyl alcohol of 5～20 weight parts.
Consider that from another point of view the present invention also can be used as in being suitable for the manufacture method of the body paper of the paper of pressure-sensitive adhesive of ink jet printer printing employed pressure-sensitive adhesive composite paint and understands.
That is, this pressure-sensitive adhesive composite paint is the base that will be main component with non-separability pressure adhesive, the particulate weighting agent and being used to that is used for adjusting the adhering state of above-mentioned base makes the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection add water to mix and form.
As above-mentioned particulate weighting agent, containing the oil number of measuring according to ISO787-5 is the amorphous silica of 100～280ml/100g, above-mentioned little amorphous silica with respect to the cooperation ratio of above-mentioned base is, is 50～150 weight % with respect to above-mentioned base 100 weight %.
As above-mentioned cationic printing ink fixing salt, contain poly-alkylamine Epicholorohydrin resinoid, above-mentioned poly-alkylamine Epicholorohydrin resinoid with respect to the cooperation ratio of above-mentioned base is, is 5～35 weight % with respect to above-mentioned base 100 weight %.
In preferred embodiments, also to cooperate every above-mentioned base 100 weight parts be the polyvinyl alcohol of 5～20 weight parts to above-mentioned pressure-sensitive adhesive composite paint.
In addition, the body paper of the paper of pressure-sensitive adhesive of the present invention pressure-sensitive adhesive postcard with personal delivery that also can be used as two fold-types uses with paper with the pressure-sensitive adhesive postcard with personal delivery of paper or three fold-types.At this moment, on strippingly by at least a portion of the pressure-sensitive adhesive composite coat of pressure-sensitive adhesive, use the ink-jet printer printing information.
The invention effect
According to the present invention, can provide a kind of with in the printing of ink-jet printer, do not have that document image is fuzzy, printing density fully, can print the body paper of the paper of pressure-sensitive adhesive of very thin image aptly.
In addition, body paper according to paper of pressure-sensitive adhesive of the present invention, have with in the printing of ink-jet printer, the photographic fixing of jetted ink on the pressure-sensitive adhesive composite coat be abundant, the pressure-sensitive adhesive postcard that has a personal delivery when formation during with paper, is difficult for being transferred to advantage owing on the personal delivery face that folds the opposing party who overlaps at the image that is write down on a side the personal delivery face.
In addition, in the present invention, by also cooperate every above-mentioned base 100 weight parts in the coat of pressure-sensitive adhesive composite is the polyvinyl alcohol of 5～20 weight parts, the intensity that the pressure-sensitive adhesive composite coat can be provided fully, few paper of pressure-sensitive adhesive that comes off of pressure-sensitive adhesive composite coat such as when peeling off.
Description of drawings
Fig. 1 is an example of the formation of paper of pressure-sensitive adhesive.
Fig. 2 for paper of pressure-sensitive adhesive is used for two fold-types have the postcard of personal delivery the time an example.
Fig. 3 is the sectional view of A-A line in Fig. 2.
The example of Fig. 4 when paper of pressure-sensitive adhesive is used for the pressure-sensitive adhesive postcard of three fold-types.
Fig. 5 during for the pressure-sensitive adhesive composite coat that the application is set on the two sides constitutes along the sectional view of B-B line among Fig. 4.
When Fig. 6 constitutes the pressure-sensitive adhesive composite coat of different formations for the pressure-sensitive adhesive composite coat that the application is set constitutes is provided with the application on another side on one side along the sectional view of B-B line among Fig. 4.
The serve as reasons body paper of the paper of pressure-sensitive adhesive that is suitable for ink jet printer of the present invention of Fig. 7 is made the schema of the pressure-sensitive adhesive postcard with personal delivery of two fold-types with the general manufacturing procedure of paper.
Fig. 8 is the evaluation result of each rerum natura of the body paper of the proportioning of the pressure-sensitive adhesive composite paint that uses among the embodiment 1～21 and the paper of pressure-sensitive adhesive that obtained.
Fig. 9 is the evaluation result of each rerum natura of the body paper of the proportioning of the pressure-sensitive adhesive composite paint that uses in the comparative example 1～9 and the paper of pressure-sensitive adhesive that obtained.
Nomenclature
The pressure-sensitive adhesive postcard paper with personal delivery of 1 two fold-types
1a pressure-sensitive adhesive postcard is used the paper surface
1b pressure-sensitive adhesive postcard is used the paper back side
2 addressee's name address face
3 pressure-sensitive adhesive faces
4 basic paper
5 pressure-sensitive adhesive composite coats
6 personal delivery information
7 addressee's name address informations
The pressure-sensitive adhesive postcard paper with personal delivery of 10 3 fold-types
The pressure-sensitive postcard of 10a is used the paper surface
10b pressure-sensitive adhesive postcard is used the paper back side
11 addressee's name address face
12 pressure-sensitive adhesive faces
13 basic paper
The pressure-sensitive adhesive composite coat that 14 the application constitute
15 constitute different pressure-sensitive adhesive composite coats with the application
16 personal delivery information
17 addressee's name address informations
101 paper of pressure-sensitive adhesive
110 basic paper
120 pressure-sensitive adhesive composite coats
Specific embodiments
Description the preferred embodiments of the invention, but the present invention is not subjected to the qualification of following narration.
When printing on used paper with ink-jet printer, at first, the jetted ink formation drop from the ejection of printing ink nozzle attached to on the paper surface, thereafter, is impregnated into the photographic fixing with paper inside immediately.In the process that is being impregnated into up to jetted ink with paper inside, jetted ink on one side along with become horizontal direction ground to spread with the paper surface, use paper inside Yi Bian be impregnated into, still, when the diffusion on this horizontal direction is excessive, just become the reason that document image blurs.In addition, though at jetted ink to the soaking under the fast inadequately situation of paper inside because jetted ink is being detained with the paper surface is long-time, the result also can become the fuzzy reason of document image.
On the other hand, if jetted ink is too to soaking into paper inside, then the amount of the jetted ink of photographic fixing reduces on the paper surface, and the result becomes the reason that printing density reduces.
Therefore, for make do not have document image fuzzy, printing density printing adaptability abundant, very thin image is good use paper, need appropriateness suppress attached to the lip-deep jetted ink of paper along with the surperficial diffusion that becomes horizontal direction of paper, quickening to soaking into and making as far as possible and use in the paper top layer with paper inside to stopping at soaking into of paper inside.
As mentioned above, the object of the present invention is to provide, do not have the fuzzy of document image, the body paper of the paper of pressure-sensitive adhesive that printing density is abundant, the printing adaptability of very thin image is good when the pressure-sensitive adhesive composite coat is used the printing of ink-jet printer.Therefore, in the body paper of paper of pressure-sensitive adhesive of the present invention, require pressure-sensitive adhesive composite coat in the printing of use ink-jet printer to have can appropriateness to suppress jetted ink in the pressure-sensitive adhesive composite coat along with surperficially become the function of the diffusion of horizontal direction with paper, absorb the function of jetted ink and make jetted ink rapidly to the function that stops at soaking into of paper inside in the pressure-sensitive adhesive composite coat.
And then, except above-mentioned purpose, the present invention also aims to, when the pressure-sensitive adhesive postcard that the body paper of paper of pressure-sensitive adhesive of the present invention has a personal delivery in formation was used paper, the image that can suppress to be write down on a side the personal delivery face was to the personal delivery face transfer printing owing to folding the opposing party who overlaps.
As mentioned above, when using paper of pressure-sensitive adhesive formation to have the postcard of personal delivery, apply 50～150kg/cm
2About suppress strippingly bonding between the personal delivery face.Therefore, if the photographic fixing of jetted ink on the pressure-sensitive adhesive composite coat is insufficient, then on the image that is write down on a side the personal delivery face will be owing to the personal delivery face of suppressing the opposing party who is transferred to coincidence.Therefore, also require the pressure-sensitive adhesive composite coat of the body paper of paper of pressure-sensitive adhesive of the present invention to have the function that fully makes the jetted ink photographic fixing.
Therefore, the body paper of paper of pressure-sensitive adhesive of the present invention adopts following formation.The body paper of the application's paper of pressure-sensitive adhesive comprises basic paper and the coat of the pressure-sensitive adhesive composite that forms on the whole or part on the one side of basic paper or two sides.The base that it is main component that coat contains with non-separability pressure adhesive, the particulate weighting agent and being used to that is used to adjust the adhering state of base make the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection.And, as the particulate weighting agent, containing the oil number of measuring according to ISO787-5 is the amorphous silica of 100～280ml/100g, is to be 50～150 weight % with respect to base 100 weight % as the amorphous silica of particulate weighting agent contained in the coat with respect to the cooperation ratio of base.As cationic printing ink fixing salt, contain poly-alkylamine Epicholorohydrin resinoid, contained poly-alkylamine Epicholorohydrin resinoid is to be 5～35 weight % with respect to base 100 weight % with respect to the cooperation ratio of base in the coat.
By forming this formation, when using the printing of ink jet printer, can obtain not have document image fuzzy, printing density printing adaptability abundant, very thin image is good and the photographic fixing of jetted ink fully, when formation has the postcard of personal delivery, can be suppressed at owing to fold the image that write down on a side's who overlaps the personal delivery face body paper to the paper of pressure-sensitive adhesive of the opposing party's personal delivery face transfer printing.
In the body paper of paper of pressure-sensitive adhesive of the present invention, implementing by ink jet printer in the pressure-sensitive adhesive composite coat of printing, in order to adjust the adhering state of base, in adhesive composite, add the particulate weighting agent.As the particulate weighting agent that is contained, use amorphous silica.Its reason is, because amorphous silica is a porous matter, has the high function that absorbs jetted ink, and therefore, the pressure-sensitive adhesive composite coat can absorb jetted ink rapidly.
As the amorphous silica that uses among the application, needing to use the oil number of measuring according to ISO787-5 is the silicon-dioxide of 100～280ml/100g.If the oil number of amorphous silica is lower than 100ml/100g, then the pressure-sensitive adhesive composite coat can not be fully and is promptly absorbed jetted ink, and document image might blur.In addition, jetted ink probably can not be guaranteed sufficient printing density to not stopping in the pressure-sensitive adhesive composite coat with soaking into of paper inside.On the other hand, surpass under the situation of 280ml/100g in the oil number of amorphous silica, can not be fully and promptly absorb jetted ink, document image might blur, and perhaps probably can not guarantee sufficient printing density.
As mentioned above, because amorphous silica is a porous matter, therefore, to the absorbing power height of jetted ink.And the degree of this absorbing power can estimate with oil number, it has been generally acknowledged that along with the increase of oil number, the absorptivity of jetted ink also improves.
But when containing amorphous silica in the pressure-sensitive adhesive composite coat, if the oil number of amorphous silica is excessive, then the absorptivity of the jetted ink in the pressure-sensitive adhesive composite coat surface reduces.Can infer, if it is excessive that the oil number of amorphous silica becomes, then in the stage of allocating pressure-sensitive adhesive composite paint, non-separability pressure adhesive or cationic printing ink fixing salt etc. are absorbed by amorphous silica, the receptivity of amorphous silica reduces, as a result, the absorptive capacity of the jetted ink of amorphous silica reduces.
Therefore, in the present invention, more preferably using the oil number of measuring according to ISO787-5 is the amorphous silica of 130～200ml/100g.By using oil number to be in the amorphous silica of above-mentioned scope, can fully guarantee the absorptivity of the jetted ink in the pressure-sensitive adhesive composite coat, fine image that can ground preferably printed bar code etc.
The use level of amorphous silica in the pressure-sensitive adhesive composite coat with respect to base 100 weight parts, need be 50～150 weight parts.If the use level of amorphous silica is less than 50 weight parts, then the pressure-sensitive adhesive composite coat can not be fully and is promptly absorbed jetted ink, and document image might blur.On the other hand, if the use level of amorphous silica surpasses 150 weight parts, then the ratio that contains of the base in the pressure-sensitive adhesive composite coat becomes too small relatively, can not fully guarantee the intensity of pressure-sensitive adhesive composite coat, the result, when peeling off the paper of pressure-sensitive adhesive of pressurization after bonding, coming off of pressure-sensitive adhesive composite coat might be taken place.And then, when offset printing etc., might on the blanket (blanket) of offset printing press, adhere to the pressure-sensitive adhesive composite that breaks away from from the body paper of paper of pressure-sensitive adhesive and pollute.
What illustrated is in the present invention, implementing with ink jet printer in the pressure-sensitive adhesive composite coat of printing, in the scope of not damaging purpose of the present invention, also can append amorphous silica particulate weighting agent in addition.As the particulate weighting agent beyond the amorphous silica, can suitablely from the mineral dye of organic class particle of starch particle or hollow polymer etc., kaolin, sintering kaolin, water-ground limestone, light calcium carbonate, titanium oxide, talcum, silicon-dioxide, mica, aluminum oxide, aluminium hydroxide, zinc oxide, calcium sulfate etc. etc. select more than a kind or 2 kinds.
In the present invention, implementing with ink jet printer in the pressure-sensitive adhesive composite coat of printing, as cationic printing ink fixing salt, every base 100 weight parts contain poly-alkylamine Epicholorohydrin resinoid 5～35 weight parts.
Herein, if the poly-resinoid content of alkylamine Epicholorohydrin is less than 5 weight parts, then can not moderately suppress jetted ink along with the surperficial diffusion that becomes horizontal direction of paper, document image might blur., as the resinoid content of poly-alkylamine Epicholorohydrin, as long as every base 100 weight parts are more than 5 weight parts, just do not have particular determination herein, every base 100 weight parts are to be an amount of about 5～35 weight parts.Contain and surpass 35 weight parts, make the effect of the jetted ink photographic fixing state that reaches capacity, aspect cost, become unfavorable.And then, if the ratio that contains of the base in the pressure-sensitive adhesive composite coat becomes too small relatively, then probably can not fully guarantee the intensity of pressure-sensitive adhesive composite coat.
What illustrated is, in paper of pressure-sensitive adhesive of the present invention, implementing with ink-jet printer in the pressure-sensitive adhesive composite coat of printing, in the scope of not damaging the object of the invention, also can append poly-alkylamine Epicholorohydrin resinoid cationic printing ink fixing salt in addition.As other cationic printing ink fixing salt, can suitablely from the cationic printing ink fixing salt of polyurethanes resin or polyamide-based resin, poly-imines resinoid etc. select more than a kind or 2 kinds.And then, also can and with the metal-salt of sal epsom etc.
In the present invention, importantly, implementing in the pressure-sensitive adhesive composite coat of printing, and be amorphous silica and the poly-alkylamine Epicholorohydrin resinoid of 100～280ml/100g with the oil number that contains according to ISO787-5 mensuration with ink-jet printer.
As mentioned above, be the amorphous silica of 100～280ml/100g by making the oil number that contains in the pressure-sensitive adhesive composite coat according to ISO787-5 mensuration, can make the pressure-sensitive adhesive composite coat that the absorption of jetted ink is become rapid.But, in order to prevent that jetted ink is along with the diffusion that becomes horizontal direction with paper surface, make printing ink be absorbed by the pressure-sensitive adhesive composite coat simultaneously, need when carrying out absorption of inks rapidly, the photographic fixing of jetted ink on the pressure-sensitive adhesive composite coat promptly be carried out.
Therefore, in the present invention, become rapidly, make and in the pressure-sensitive adhesive composite coat of implementing printing with ink jet printer, contain poly-alkylamine Epicholorohydrin resinoid in order to make the photographic fixing of jetted ink in the pressure-sensitive adhesive composite coat.Can think that compare with other cationic printing ink fixing salt of polyurethanes resin or polyamide-based resin, poly-imines resinoid etc., poly-alkylamine Epicholorohydrin resinoid makes jetted ink photographic fixing rapidly in the pressure-sensitive adhesive composite coat.
Like this, body paper for paper of pressure-sensitive adhesive of the present invention, by also use the oil number that contains according to ISO787-5 mensuration in the pressure-sensitive adhesive composite coat of implementing printing with ink jet printer is amorphous silica and the poly-alkylamine Epicholorohydrin resinoid of 100～280ml/100g, can obtain to make jetted ink in the pressure-sensitive adhesive composite coat, promptly to absorb and photographic fixing, even print fine image, the body paper of the paper of pressure-sensitive adhesive that document image also can not blur.
As mentioned above, when the pressure-sensitive adhesive postcard that has a personal delivery in formation is used paper, being suppressed at the image that write down on a side the personal delivery face to the personal delivery face transfer printing owing to folding the opposing party who overlaps, also is one of purpose of the application.By in the pressure-sensitive adhesive composite coat of implementing printing with ink jet printer, being amorphous silica and the poly-alkylamine Epicholorohydrin resinoid of 100～280ml/100g also, also can reach this purpose with containing the oil number of measuring according to ISO787-5.
The above-mentioned image that writes down on personal delivery face is to the transfer printing of the opposing party's personal delivery face, with in the polychrome printing of ink-jet printer, surpasses the setting-out portion that 100% varicolored printing ink overlaps in the site rate especially easily and takes place.Can infer thus, the transfer printing problem of printing ink be owing to the pressure-sensitive adhesive composite coat can not fully absorb or fully a large amount of jetted ink of photographic fixing cause.If adopt the formation of the body paper of paper of pressure-sensitive adhesive of the present invention,, therefore can prevent the generation of this transfer printing owing to can satisfy the sufficient absorptivity and the sufficient fixation performance of jetted ink simultaneously at the pressure-sensitive adhesive composite coat.
The poly-alkylamine Epicholorohydrin resinoid that uses in the body paper as paper of pressure-sensitive adhesive of the present invention, do not have particular determination, can use the poly-alkylamine Epicholorohydrin of for example from poly-dimethylamine Epicholorohydrin condenses, poly-diethylamine Epicholorohydrin condenses, poly-dipropyl amine Epicholorohydrin condenses, poly-methylethyl amine Epicholorohydrin condenses, poly-methyl-propyl amine Epicholorohydrin condenses, poly-ethyl propyl amine Epicholorohydrin condenses etc., selecting resinoid more than a kind or 2 kinds.
In the present invention, in these poly-alkylamine Epicholorohydrin resinoids, preferred poly-dimethylamine Epicholorohydrin condenses and/or the modification dimethylamine Epicholorohydrin condenses of using.As modification dimethylamine Epicholorohydrin condenses, can use poly-dimethylamine ammonia Epicholorohydrin condenses and poly-decil diamines Epicholorohydrin condenses etc.By using poly-dimethylamine Epicholorohydrin condenses and/or modification dimethylamine Epicholorohydrin condenses as poly-alkylamine Epicholorohydrin resinoid, can prevent the fuzzy of document image with comparalive ease, guarantee sufficient printing density.
The poly-alkylamine Epicholorohydrin resinoid that uses in the body paper as paper of pressure-sensitive adhesive of the present invention, preferably using number-average molecular weight is poly-alkylamine Epicholorohydrin resinoid below 10000.Can think that the number-average molecular weight of poly-alkylamine Epicholorohydrin is more little, the speed of response of jetted ink and poly-alkylamine Epicholorohydrin is fast more.Therefore, in order to prevent the fuzzy of document image, it is favourable using the little poly-alkylamine Epicholorohydrin resinoid of number-average molecular weight as far as possible.But little of as monomer if number-average molecular weight is too little, the operability of then handling etc. may produce difficulty, therefore, preferably at least also will reach the number-average molecular weight of multipolymer degree.
As the non-separability pressure adhesive that uses in the pressure-sensitive adhesive composite of the present invention, can enumerate natural rubber class latex or synthetic rubber latex etc.The mixture that natural rubber class latex, natural rubber class latex and the protective colloid class acrylate copolymer emulsion that can especially preferably use natural rubber class latex that natural rubber graft polymerization methyl methacrylate, vinylbenzene are obtained, has mixed with methyl methacrylate forms etc.In addition, as synthetic rubber latex, preferably use styrene-butadiene latex.These latex can use separately separately, perhaps use mixing more than 2 kinds.
In the body paper of paper of pressure-sensitive adhesive of the present invention, in the pressure-sensitive adhesive composite coat of implementing printing with ink jet printer, also can cooperate polyvinyl alcohol.As mentioned above, use the pressure-sensitive adhesive postcard with personal delivery of paper of pressure-sensitive adhesive to confirm the various information of on personal delivery face, printing by peeling off between will strippingly bonding personal delivery face.Yet if when the personal delivery face of peeling off, the personal delivery face that takes place is stripped to that the subtend face is first-class, the pressure-sensitive adhesive composite coat comes off, the various loss of learnings that sometimes print on personal delivery face etc., correctly identifying information.Therefore, in the present invention, preferably, when peeling off, be difficult to take place coming off of pressure-sensitive adhesive composite coat by in pressure-sensitive adhesive composite, cooperating polyvinyl alcohol to improve the intensity of pressure-sensitive adhesive composite coat.
In this application, as the use level of the polyvinyl alcohol that uses in pressure-sensitive adhesive composite, preferred every base 100 weight parts use 5～20 weight parts.Use level as pectin/polyvinyl alcohol is less than 5 weight parts, then lacks the effect of the intensity that improves the pressure-sensitive adhesive composite coat.On the other hand, surpass 20 weight parts as the use level of pectin/polyvinyl alcohol, then the ratio that contains of the pressure adhesive in pressure-sensitive adhesive composite becomes too small relatively, is difficult to control bonding force when pressurization is bonding.
Herein, the kind of employed polyvinyl alcohol does not have particular determination, can use fully saponified type polyvinyl alcohol or partly-hydrolysed type polyvinyl alcohol.In addition, can use silanol modification, carboxy-modified, acetoacetyl modification, cation-modified etc. various modified polyvinyl alcohols.
Pressure-sensitive adhesive composite of the present invention can also be as required, and suitable defoamer, tackifier, pH regulator agent, lubricant, dispersion agent, wetting agent, dyestuff, antiaging agent, the sanitas etc. of using are at the known additive that uses in the art.
In the body paper of paper of pressure-sensitive adhesive of the present invention, preferably on each face of basic paper, apply by solid part at 3～12g/m
2The pressure-sensitive adhesive composite of scope.In addition, the coating unit that is used for formation pressure-sensitive adhesive composite coat on basic paper does not have particular determination, can suit to use the known coating unit that uses in coated paper manufacturing field usually.For example, can use knife coater, air knife doctor knife coater, roller coating machine, contrary roll-coater, curtain coater, excellent coating machine, intaglio plate coating machine, size press coater, knife coater (Bill-blade coater) etc.
As the basic paper that in the body paper of paper of pressure-sensitive adhesive of the present invention, uses, can use kraft paper, tabulating paper, good quality paper, middle quality paper, OCR various information paper with paper etc.In addition, the fibrous material of basic paper is considered the environment aspect, except general paper pulp, can also use the waste paper that produces in operation, reclaims paper pulp and mestha, the non-wood material of bagasse, bamboo etc.
Quantitative (the g/m of the body paper of paper of pressure-sensitive adhesive of the present invention
2) be not particularly limited, consider and be processed into pressure-sensitive adhesive postcard paper with personal delivery, be preferably 60～200g/m
2If quantitatively be lower than 60g/m
2, then be difficult to satisfy opaqueness, when making postcard, might personal delivery information see through and see with personal delivery.On the other hand, if quantitatively surpass 200g/m
2, then rigidity improves, and flexibility of operation that thus might be when making the postcard with personal delivery is poor.
Below, specifically make use-case with reference to Fig. 2～6 explanation paper of pressure-sensitive adhesive that makes by the body paper of paper of pressure-sensitive adhesive of the present invention.Shown in Fig. 2 paper of pressure-sensitive adhesive is applied to the example of situation of the postcard with personal delivery of two fold-types, Fig. 3 is illustrated in the A-A line sectional view among Fig. 2.In Fig. 2 and Fig. 3,1 is the pressure-sensitive adhesive postcard paper with personal delivery of two fold-types; 1a uses the paper surface for the pressure-sensitive adhesive postcard; 1b uses the paper back side for the pressure-sensitive adhesive postcard; 2 is the addressee's name address face; 3 is the pressure-sensitive adhesive face; 4 is basic paper; 5 is the pressure-sensitive adhesive composite coat; 6 are personal delivery information; 7 is the addressee's name address information.What illustrated is, in Fig. 3, about the thickness of basic paper 4 and pressure-sensitive adhesive composite coat 5, actual (real) thickness with may not be proportional with the thickness shown in the figure.
The postcard with personal delivery 1 of two fold-types, with the addressee's name address face 2 that is printed with addressee's name address information 7 is that the outside, pressure-sensitive adhesive composite coat 5 are that the mode of inboard folds, Jie is by pressure-sensitive adhesive composite coat 5, will be printed with strippingly pressure-sensitive adhesive of the pressure-sensitive adhesive face 3a of personal delivery information 6 and pressure-sensitive adhesive face 3b.In this embodiment, though on the basic paper 4 surperficial 1a of addressee's name address face both sides, coat etc. is not set,, clay coating or jetted ink receiving layer, water-fast barrier layer etc. can be set in order to give various functions.What illustrated is, herein " personal delivery information " is meant the information of sending to the addressee, comprise the informing of various items etc., common cost charge, supervise, worry can to cause when other third parties see the information of inconvenience etc.
Use ink-jet printer on pressure-sensitive adhesive face 3a, to print personal delivery information 6, Jie is strippingly pressurizeed pressure-sensitive adhesive face 3a and pressure-sensitive adhesive face 3b bonding by pressure-sensitive adhesive composite coat 5, the image that prints on pressure-sensitive adhesive face 3a contacts with pressure-sensitive adhesive face 3b.When the photographic fixing of the jetted ink of the image of printing on the pressure-sensitive adhesive face 3a is insufficient, might be transferred on the pressure-sensitive adhesive face 3b at the image that prints on the pressure-sensitive adhesive face 3a, but, can prevent because the insufficient printed images transfer printing that causes of photographic fixing of jetted ink by taking formation of the present invention.
Then, the explanation paper of pressure-sensitive adhesive that will make by the body paper of paper of pressure-sensitive adhesive of the present invention be used for three fold-types have the postcard of personal delivery the time example.Example when shown in Fig. 4 paper of pressure-sensitive adhesive being applied to three fold-type pressure-sensitive adhesive postcards, in the figure, Fig. 4 (a) presentation surface, Fig. 4 (b) represents the back side, Fig. 4 (c) represents folded state.In addition, Fig. 5 for the two sides is provided with during pressure-sensitive adhesive composite coat 14 of the present invention in Fig. 4 the sectional view of B-B line; Fig. 6 for apply on the one side pressure-sensitive adhesive composite paint of the present invention when on another side, applying the pressure-sensitive adhesive composite paint of different formations in Fig. 4 the sectional view of B-B line.In Fig. 4～6,10 is the pressure-sensitive adhesive postcard paper with personal delivery of three fold-types; 10a uses the paper surface for the pressure-sensitive adhesive postcard; 10b uses the paper back side for the pressure-sensitive adhesive postcard; 11 is the addressee's name address face; 12 is each pressure-sensitive adhesive face; 13 is basic paper; 14 for adopting the pressure-sensitive adhesive composite coat of the application's formation; 15 for to constitute different pressure-sensitive adhesive composite coats with the application.What illustrated is, in Fig. 5 and Fig. 6, for the thickness of basic paper 13 and pressure-sensitive adhesive composite coat 14,15, actual (real) thickness with may not be proportional with the thickness shown in the figure.
In the time of will being processed into the quick bonding postcard 10 of three crimpings by the paper of pressure-sensitive adhesive that paper of pressure-sensitive adhesive body paper of the present invention makes, pressure-sensitive adhesive composite coat 14 is set on the two sides of basic paper 13, with addressee's name address face 11 is the outside, be folded into three foldings as shown in Figure 4, pressure-sensitive adhesive face 12a and pressure-sensitive adhesive face 12b, pressure-sensitive adhesive face 12c and pressure-sensitive adhesive face 12d are situated between respectively by pressure-sensitive adhesive composite coat 14 pressure-sensitive adhesive strippingly.In the quick bonding postcard of three such crimpings, also the both sides of the pressure-sensitive adhesive part that can form with the pressure-sensitive adhesive that formed by pressure- sensitive adhesive face 12a, 12b part with by pressure- sensitive adhesive face 12c, 12d are as personal delivery face, also can be with either party pressure-sensitive adhesive part as personal delivery face and with the opposing party's pressure-sensitive adhesive partly as advertising plane or can not release surface.
When two faces (the surperficial 10a and the back side 10b with pressure-sensitive adhesive face 12c that for example have pressure-sensitive adhesive face 12a) at paper of pressure-sensitive adhesive when upward printing with ink-jet printer, preferably use the body paper of the paper of pressure-sensitive adhesive of the pressure-sensitive adhesive composite coat 14 that is provided with the application's formation on the two sides as shown in Figure 5.On pressure-sensitive adhesive face 12a, pressure-sensitive adhesive face 12c, print personal delivery information 16 with ink-jet printer, the pressure-sensitive adhesive composite coat 14 that Jie is made of the application, with pressure-sensitive adhesive face 12a and pressure-sensitive adhesive face 12b and, strippingly pressurize pressure-sensitive adhesive face 12c and pressure-sensitive adhesive face 12d bonding.Thus, the image that prints on pressure-sensitive adhesive face 12a contacts with pressure-sensitive adhesive face 12b, and the image that prints on pressure-sensitive adhesive face 12c contacts with pressure-sensitive adhesive face 12d.Though might be transferred to respectively on pressure-sensitive adhesive face 12b, the pressure-sensitive adhesive face 12d at the image that prints on pressure-sensitive adhesive face 12a, the pressure-sensitive adhesive face 12c, but, just can prevent transfer printing owing to the insufficient printed images that causes of the photographic fixing of jetted ink by taking formation as shown in Figure 5.
In contrast, only go up with ink jet printer and print and (for example at another side at a face (the surperficial 10a that for example has pressure- sensitive adhesive face 12a, 12b), when not using the printing of ink jet printer the back side 10b with pressure- sensitive adhesive face 12c, 12d), only also can adopt a face to be provided with the formation of Fig. 6 of the pressure-sensitive adhesive composite coat 14 that the application constitutes.As this example, can enumerate with a side (for example pressure- sensitive adhesive face 12a, 12b) as personal delivery face, with the situation of opposite side (for example, pressure- sensitive adhesive face 12c, 12d) as the advertising plane use.In the pressure-sensitive adhesive composite coat 15 that uses on the pressure-sensitive adhesive face 12c that does not carry out printing with ink jet printer, pressure-sensitive adhesive face 12d, the employed pressure-sensitive adhesive composite paint of general paper of pressure-sensitive adhesive can suit to select to use.
But, will during as advertising plane, need to confirm the press printing of which kind of type of addressee's name address information 17 usefulness with the face (pressure-sensitive adhesive face 12c, pressure-sensitive adhesive face 12d among the figure) of addressee's name address face 11 the same sides as shown in Figure 6.With ink jet printer printing addressee's name address information 17 time,, can not produce bluring of printed images etc. by in pressure-sensitive adhesive composite coat 15, using the application's pressure-sensitive adhesive composite paint.
In addition, in the postcard with personal delivery of three fold-types of using paper of pressure-sensitive adhesive of the present invention, also can be only with the one side (the surperficial 10a that for example has pressure- sensitive adhesive face 12a, 12b) of paper of pressure-sensitive adhesive as personal delivery face, and with another side (back side 10b that for example, has pressure- sensitive adhesive face 12c, 12d) as the non-release surface do not peeled off.Even in this case, for the back side 10b that becomes non-release surface, not the pressure-sensitive adhesive composite paint that must use the application, the employed pressure-sensitive adhesive composite paint of general paper of pressure-sensitive adhesive can suit to select to use.
Then, with reference to the process picture sheet of Fig. 7, the pressure-sensitive adhesive postcard with personal delivery of being made two fold-types by the body paper of the paper of pressure-sensitive adhesive of the ink jet printer that the is suitable for the application general manufacturing procedure with paper is described.In the example of Fig. 7, the width W 1 of the body paper 20 of drum is equivalent to the length of eighty percent discount pressure-sensitive adhesive postcard with the expansion direction of paper.
At first, make body paper 20 in system paper company.The structure of the body paper 20 of manufacturing, the coat of the pressure-sensitive adhesive composite that comprises basic paper and form on the whole or part on the one side of basic paper or two sides, the base that it is main component that coat contains with non-separability pressure adhesive, the particulate weighting agent and being used to that is used to adjust the adhering state of base make the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection.The body paper 20 of Zhi Zaoing flows to processer (with reference to Fig. 7 (a)) with the state that coils into drum like this.
Then, at processer place, on the body paper 20 of drum, carry out the pattern that form printing is used to prevent that personal delivery information from seeing through or the fix information of general information, lines etc. with offset printing press etc.In this stage, unfolded 1 unitary eighty percent discount pressure-sensitive adhesive postcard forms the state (with reference to Fig. 7 (b)) that links to each other with the reel prolonging direction with the prospective region of paper on width.What illustrated is as mentioned above, under the situation of coat undercapacity, in the stage of this form printing, the printing press pollution problems to take place sometimes.
Then, the body paper 20 of the drum that form printing is finished implements to be used for cutting, and to be 1 unitary eighty percent discount pressure-sensitive adhesive postcard process with the perforation processing of the prospective region of paper and the perforation that is used to form eighty percent discount, simultaneously, as required, both sides of the edge portion along width implements feed holes (feedhole) processing, then, the body paper 20 of having implemented form printing and perforation processing etc. is so delivered to folding device, be folded into zigzag (with reference to Fig. 7 (c)).
Then, in folding device, implemented the body paper 20 of form printing and perforation processing etc., on the length direction of reel,, finished the eighty percent discount pressure-sensitive adhesive postcard paper 30 (with reference to Fig. 7 (d)) of the postcard purposes of form with multi-joint document uniformly-spaced to be folded into zigzag.The eighty percent discount pressure-sensitive adhesive postcard of the postcard purposes of the form with multi-joint document of Zhi Zaoing also flows to the printer from the processer sometimes with paper 30 like this.
Then, the eighty percent discount pressure-sensitive adhesive postcard of postcard purposes of form with multi-joint document is with paper 30, directly supply with high speed cycle type ink-jet printer, after the variable information of printing personal delivery information etc., be cut into each separate unit (with reference to Fig. 7 (e)) that the pressure-sensitive adhesive postcard with personal delivery is used paper.With being cut into the paper of pressure-sensitive adhesive 30 of postcard purposes of the form (cut sheet form) of the paper that having of each separate unit precut like this, deliver to folding device.
Then, pressure-sensitive adhesive postcard paper 30 with form of the paper that precuts, folding device with regulation, after being converted into eighty percent discount along perforation, with enforcement pressure-sensitive adhesive processing such as dry-type encapsulated machines, form the paper (hereinafter referred to as the pressure-sensitive adhesive postcard) 30 of the pressure-sensitive adhesive postcard with postcard form that sends usefulness.(with reference to Fig. 7 (f)).
[embodiment]
Below, specify the embodiment of the body paper of paper of pressure-sensitive adhesive of the present invention, but the present invention is not subjected to their qualification.What illustrated is that " part " among the embodiment and " % " unless otherwise specified, represent dry weight part and weight %.In addition, silicon-dioxide in embodiment and the comparative example and steatitic oil number, the oil number that expression is measured according to ISO787-5.
＜embodiment 1 〉
With the oil number as the particulate weighting agent is that amorphous silica 100 weight parts of 200ml/100g add in the water, fully disperse, add then as non-separability pressure adhesive pass through the mixed methyl methyl acrylate forms in natural rubber natural rubber class latex 100 weight parts, be 12000 poly-dimethylamine Epicholorohydrin condenses 15 weight parts as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt, mix, and then add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 2 〉
Except being that the amorphous silica of 200ml/100g changes to the amorphous silica that oil number is 130ml/100g, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the oil number among the embodiment 1.
＜embodiment 3 〉
Except being that the amorphous silica of 200ml/100g changes to the amorphous silica that oil number is 100ml/100g, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the oil number among the embodiment 1.
＜embodiment 4 〉
Except being that the amorphous silica of 200ml/100g changes to the amorphous silica that oil number is 280ml/100g, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the oil number among the embodiment 1.
＜embodiment 5 〉
Except making oil number in embodiment 1 is that the use level of the amorphous silica of 200ml/100g is 50 weight parts, obtains the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 6 〉
Except making oil number in embodiment 1 is that the use level of the amorphous silica of 200ml/100g is 150 weight parts, obtains the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 7 〉
Except making number-average molecular weight in embodiment 1 is that the use level of 12000 poly-dimethylamine Epicholorohydrin condenses is 5 weight parts, obtains the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 8 〉
Except making number-average molecular weight in embodiment 1 is that the use level of 12000 poly-dimethylamine Epicholorohydrin condenses is 35 weight parts, obtains the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 9 〉
With the oil number as the particulate weighting agent is that amorphous silica 50 weight parts of 100ml/100g add in the water, fully disperse, add then as non-separability pressure adhesive pass through the mixed methyl methyl acrylate forms in natural rubber natural rubber class latex 100 weight parts, be 12000 poly-methylethyl amine Epicholorohydrin condenses 5 weight parts as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt, mix, and then add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 10 〉
With the oil number as the particulate weighting agent is that amorphous silica 50 weight parts of 280ml/100g add in the water, fully disperse, add then as non-separability pressure adhesive pass through the mixed methyl methyl acrylate forms in natural rubber natural rubber class latex 100 weight parts, be 12000 poly-methylethyl amine Epicholorohydrin condenses 5 weight parts as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt, mix, and then add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 11 〉
With the oil number as the particulate weighting agent is that amorphous silica 150 weight parts of 100ml/100g add in the water, fully disperse, add then as non-separability pressure adhesive pass through the mixed methyl methyl acrylate forms in natural rubber natural rubber class latex 100 weight parts, be 12000 poly-methylethyl amine Epicholorohydrin condenses 35 weight parts as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt, mix, and then add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 12 〉
Except will the number-average molecular weight among the embodiment 1 be 12000 poly-dimethylamine Epicholorohydrin condenses to change to number-average molecular weight be 12000 the poly-diethylamine Epicholorohydrin condenses, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 13 〉
Except will the number-average molecular weight among the embodiment 1 be 12000 poly-dimethylamine Epicholorohydrin condenses to change to number-average molecular weight be 12000 the poly-dimethylamine ammonia Epicholorohydrin condenses, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 14 〉
Except will the number-average molecular weight among the embodiment 1 be 12000 poly-dimethylamine Epicholorohydrin condenses to change to number-average molecular weight be 10000 the poly-dimethylamine Epicholorohydrin condenses, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 15 〉
Except will the number-average molecular weight among the embodiment 1 be 12000 poly-dimethylamine Epicholorohydrin condenses to change to number-average molecular weight be 5000 the poly-dimethylamine Epicholorohydrin condenses, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 16 〉
Except will the number-average molecular weight among the embodiment 1 be 12000 poly-dimethylamine Epicholorohydrin condenses to change to number-average molecular weight be 1000 the poly-dimethylamine Epicholorohydrin condenses, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜embodiment 17 〉
With the oil number as the particulate weighting agent is that amorphous silica 100 weight parts of 200ml/100g add in the water, fully disperse, add natural rubber class latex 100 weight parts that the mixed methyl methyl acrylate forms in natural rubber that pass through then as non-separability pressure adhesive, as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt 12000 poly-methylethyl amine Epicholorohydrin condenses 15 weight parts, mix, add fully saponified type polyvinyl alcohol 5 weight parts again, mix, add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/
mThe one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 18 〉
With the oil number as the particulate weighting agent is that amorphous silica 100 weight parts of 200ml/100g add in the water, fully disperse, add natural rubber class latex 100 weight parts that the mixed methyl methyl acrylate forms in natural rubber that pass through then as non-separability pressure adhesive, as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt 12000 poly-dimethylamine Epicholorohydrin condenses 15 weight parts, mix, add fully saponified type polyvinyl alcohol 20 weight parts again, mix, add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 19 〉
With the oil number as the particulate weighting agent is that amorphous silica 100 weight parts of 200ml/100g add in the water, fully disperse, add natural rubber class latex 100 weight parts that the mixed methyl methyl acrylate forms in natural rubber that pass through then as non-separability pressure adhesive, as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt 12000 poly-dimethylamine Epicholorohydrin condenses 10 weight parts, adding as cationic printing ink fixing salt again is polyamide epichlorohydrin condenses 5 weight parts, mix, add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 20 〉
With the oil number as the particulate weighting agent is that amorphous silica 100 weight parts of 200ml/100g add in the water, fully disperse, add natural rubber class latex 100 weight parts that the mixed methyl methyl acrylate forms in natural rubber that pass through then as non-separability pressure adhesive, as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt 12000 poly-dimethylamine Epicholorohydrin condenses 10 weight parts, add cationic urethane resin 5 weight parts again, mix, add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜embodiment 21 〉
With the oil number as the particulate weighting agent is that amorphous silica 100 weight parts of 200ml/100g add in the water, fully disperse, add natural rubber class latex 100 weight parts that the mixed methyl methyl acrylate forms in natural rubber that pass through then as non-separability pressure adhesive, as the promptly poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin of cationic printing ink fixing salt 1000 poly-dimethylamine Epicholorohydrin condenses 15 weight parts, mix, add fully saponified type polyvinyl alcohol 15 weight parts again, mix, add organic silicon defoamer, be made as the coating of pressure-sensitive adhesive composite.With the coating made as quantitative 132g/m
2The one side of form with the personal delivery face of paper on, apply with the air knife doctor knife coater, make coated weight count 6.0g/m by solid part
2, the body paper of acquisition paper of pressure-sensitive adhesive.
＜comparative example 1 〉
Except being that the amorphous silica of 200ml/100g changes to the amorphous silica that oil number is 90ml/100g, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the oil number among the embodiment 1.
＜comparative example 2 〉
Except being that the amorphous silica of 200ml/100g changes to the amorphous silica that oil number is 300ml/100g, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the oil number among the embodiment 1.
＜comparative example 3 〉
Except making oil number in embodiment 1 is that the use level of the amorphous silica of 200ml/100g is 40 weight parts, obtains the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜comparative example 4 〉
Except making oil number in embodiment 1 is that the use level of the amorphous silica of 200ml/100g is 160 weight parts, obtains the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜comparative example 5 〉
Except making number-average molecular weight in embodiment 1 is that the use level of 12000 poly-dimethylamine Epicholorohydrin condenses is 2 weight parts, obtains the body paper of paper of pressure-sensitive adhesive similarly to Example 1.
＜comparative example 6 〉
Except will the number-average molecular weight in the comparative example 5 be 12000 poly-dimethylamine Epicholorohydrin condenses to change to number-average molecular weight be 1000 the poly-dimethylamine Epicholorohydrin condenses, similarly obtain the body paper of paper of pressure-sensitive adhesive with comparative example 5.
＜comparative example 7 〉
Except being that 12000 poly-dimethylamine Epicholorohydrin condenses changes to the polyamide epichlorohydrin condenses, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the number-average molecular weight among the embodiment 1.
＜comparative example 8 〉
Except being that 12000 poly-dimethylamine Epicholorohydrin condenses changes to the cationic urethane resin, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the number-average molecular weight among the embodiment 1.
＜comparative example 9 〉
Except being that the amorphous silica of 200ml/100g changes to the talcum that oil number is 60ml/100g, obtain the body paper of paper of pressure-sensitive adhesive similarly to Example 1 in the oil number among the embodiment 1.
On the face that the pressure-sensitive adhesive composite coat is set of the body paper of each paper of pressure-sensitive adhesive of in embodiment 1～21 and comparative example 1～9, making, with ink-jet printer (VersaMarkVantage/ サ イ テ Star Network ス society system), after carrying out panchromatic ink-vapor recording, carry out the evaluation of the fuzzy and printing density of document image.What illustrated is, jetted ink all uses 2003 (deceiving) of サ イ テ Star Network ス 2001 (green grass or young crops), サ イ テ Star Network ス 2002 (magentas), サ イ テ Star Network ス, サ イ テ Star Network ス 2004 (Huangs) 4 looks of サ イ テ Star Network ス society system.
Then, will be provided with between the personal delivery face of pressure-sensitive adhesive composite coat pressurization with dry-type encapsulated machine MS-9000 (Janpanese Printing Co., Ltd's system) bonding, is cut into the postcard size, obtains a plurality of pressure-sensitive adhesive postcards with personal delivery.What illustrated is, when pressurization is bonding, adjusts the sealer slit, and it is wide to make stripping strength after just bonding reach about 100g/25mm.Peel off between the personal delivery face with the pressure-sensitive adhesive postcard that obtains like this, the transfer printing and the coat intensity of document image are estimated with personal delivery.
The evaluation result of each rerum natura of the body paper of the cooperation of used pressure-sensitive adhesive composite paint and the paper of pressure-sensitive adhesive that obtains is shown in Fig. 8 among the embodiment; The evaluation result of each rerum natura of the body paper of the cooperation of used pressure-sensitive adhesive composite paint and the paper of pressure-sensitive adhesive that obtains is shown in Fig. 9 in the comparative example.The kind of the cationic printing ink fixing salt in the table is as follows respectively.
A: poly-dimethylamine Epicholorohydrin
B: poly-methylethyl amine Epicholorohydrin
C: poly-diethylamine Epicholorohydrin
D: poly-dimethylamine ammonia Epicholorohydrin
E: polyamide epichlorohydrin
F: urethane resin
G: amide resins
In addition, evaluation is carried out according to following method respectively.
[bluring]
Bluring of visual valuation document image.Evaluation is that 1～5 grade of branch is carried out.What illustrated is, with fuzzy maximum, problematic sample in practicality such as reading of barcode is evaluated as 1,, good sample fuzzy with not having is evaluated as 5, with more than 2 as level no problem in practicality, it is qualified to be evaluated as.
[printing density]
The printing density of visual valuation document image.Evaluation is that 1～5 grade of branch is carried out.What illustrated is, printing density is minimum, problematic sample in practicality such as reading of barcode is evaluated as 1, and printing density height, the best sample are evaluated as 5, with more than 2 as level no problem in practicality, it is qualified to be evaluated as.
[transfer printing]
Whether the document image of the side's that visual valuation has been peeled off personal delivery face is transferred on the opposing party's the personal delivery face.To be in not transfer printing, the sample of no problem qualified level is evaluated as zero in practicality owing to transfer printing takes place therefore problem is arranged in practicality, can not satisfy the sample of qualified level and be evaluated as *.
[coat intensity]
The condition of surface of the pressure-sensitive adhesive composite coat of the personal delivery face that visual valuation has been peeled off.
◎ pressure-sensitive adhesive composite coat smooth surface is because the document image that brought of coming off of pressure-sensitive adhesive composite coat damaged is not the best
Though some is coarse a little for zero pressure-sensitive adhesive composite coat surface, not because the document image that brought of coming off of pressure-sensitive adhesive composite coat damaged is good
△ pressure-sensitive adhesive composite coat surface irregularity, though find the damaged of document image that coming off of some because pressure-sensitive adhesive composite coat brought, no problem in practicality
The document image that * pressure-sensitive adhesive composite coat surface irregularity, the coming off of pressure-sensitive adhesive composite coat are brought damaged serious has problem in practicality
As can be seen from Figure 8, any fuzzy, printing density of the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1～21 is qualified level, do not have transfer printing, and coat intensity is also no problem.Following, be that benchmark is verified with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1.
[checking of the oil number of amorphous silica]
At first, the oil number of amorphous silica is verified.At the body paper of the paper of pressure-sensitive adhesive that uses oil number to obtain in as the embodiment 2 of the amorphous silica of 130ml/100g, has the equal rerum natura of body paper with the paper of pressure-sensitive adhesive of embodiment 1.
At the body paper of the paper of pressure-sensitive adhesive that uses oil number to obtain in as the embodiment 3 of the amorphous silica of 100ml/100g, to compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor slightly, but is no problem level.
At the body paper of the paper of pressure-sensitive adhesive that uses oil number to obtain in as the embodiment 4 of the amorphous silica of 280ml/100g, to compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor slightly, but is no problem level.
On the other hand, the body paper of the paper of pressure-sensitive adhesive that uses oil number to obtain in as the comparative example 1 of the amorphous silica of 90ml/100g and, is using oil number as the comparative example 2 of the amorphous silica of 300ml/100g in the body paper of paper of pressure-sensitive adhesive of acquisition, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor, and printing density is not for satisfying qualified level.
Can think from above result, as the oil number of amorphous silica, preferred 100～280ml/100g, more preferably 130～200ml/100g.
[checking of the use level of amorphous silica]
Then, the use level of amorphous silica is verified.With respect to base 100 weight parts, the use level of amorphous silica is the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 5 of 50 weight parts, compare with the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor slightly, but is that practical going up is no problem level.
With respect to base 100 weight parts, the use level of amorphous silica is the paper of pressure-sensitive adhesive that obtains among the embodiment 6 of 150 weight parts, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, the evaluation result of coat intensity is poor slightly, but is level no problem in practicality.
On the other hand, with respect to base 100 weight parts, the use level of amorphous silica is the body paper of the paper of pressure-sensitive adhesive that obtains in the comparative example 3 of 40 weight parts, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor, blurs and can not satisfy qualified level.In addition, even in the evaluation of transfer printing, can not satisfy qualified level.
With respect to base 100 weight parts, the use level of amorphous silica is the body paper of the paper of pressure-sensitive adhesive that obtains in the comparative example 4 of 160 weight parts, compares with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, and the coat intensity difference can not be supplied with practicality.
Can think from above result,,, be preferably 50～150 weight parts with respect to base 100 weight parts as the use level of amorphous silica.
[checking of the poly-resinoid use level of alkylamine Epicholorohydrin]
Below, the poly-resinoid use level of alkylamine Epicholorohydrin is verified.With respect to base 100 weight parts, cooperate body paper as the paper of pressure-sensitive adhesive that obtains among the embodiment 7 of poly-resinoid poly-dimethylamine Epicholorohydrin condenses 5 weight parts of alkylamine Epicholorohydrin, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor slightly, but is no problem level.
With respect to base 100 weight parts, cooperate body paper as the paper of pressure-sensitive adhesive that obtains among the embodiment 8 of poly-resinoid poly-dimethylamine Epicholorohydrin condenses 35 weight parts of alkylamine Epicholorohydrin, have with embodiment 1 in the equal rerum natura of body paper of the paper of pressure-sensitive adhesive that obtains.
On the other hand, with respect to base 100 weight parts, cooperate body paper as the paper of pressure-sensitive adhesive that obtains in the comparative example 5 of poly-resinoid poly-dimethylamine Epicholorohydrin condenses 2 weight parts of alkylamine Epicholorohydrin, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, fuzzy evaluation result is poor, can not supply with practicality.
In addition, the body paper of the paper of pressure-sensitive adhesive that in comparative example 6, obtains, be to be that to change to number-average molecular weight be 1000 poly-dimethylamine Epicholorohydrin condenses for 12000 poly-dimethylamine Epicholorohydrin condenses by the number-average molecular weight of will be in the comparative example 5 using, seek to prevent to blur, but compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, fuzzy evaluation result is poor, can not supply with practicality.
Can think from above result,,, be preferably more than 5 weight parts with respect to base 100 weight parts as the resinoid use level of poly-alkylamine Epicholorohydrin.
[checking of the poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin]
Below, the poly-resinoid number-average molecular weight of alkylamine Epicholorohydrin is verified.Using number-average molecular weight is 10000 the poly-dimethylamine Epicholorohydrin condenses body paper as the paper of pressure-sensitive adhesive that obtains among the poly-resinoid embodiment 14 of alkylamine Epicholorohydrin, using number-average molecular weight is 5000 the poly-dimethylamine Epicholorohydrin condenses body paper as the paper of pressure-sensitive adhesive that obtains among the poly-resinoid embodiment 15 of alkylamine Epicholorohydrin, using number-average molecular weight is 1000 the poly-dimethylamine Epicholorohydrin condenses body paper as the paper of pressure-sensitive adhesive that obtains among the poly-resinoid embodiment 16 of alkylamine Epicholorohydrin, compare any fuzzy with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, printing density all is evaluated as well.
Can think from above result, as the resinoid number-average molecular weight of poly-alkylamine Epicholorohydrin, more preferably below 10000.
[to the checking of the cooperation of polyvinyl alcohol]
Below the cooperation of polyvinyl alcohol is verified.Cooperate with respect to base 100 weight parts the paper of pressure-sensitive adhesive that obtains among the embodiment 17 of fully saponified type polyvinyl alcohol 5 weight parts body paper and, cooperate the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 18 of fully saponified type polyvinyl alcohol 20 weight parts with respect to base 100 weight parts, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, any coat intensity all is evaluated as good.
Can think that from above result the polyvinyl alcohol by every base 100 weight parts cooperation 5～20 weight parts can improve coat intensity.
[to the poly-resinoid checking of alkylamine Epicholorohydrin]
Below poly-alkylamine Epicholorohydrin resinoid is verified.Using poly-diethylamine Epicholorohydrin as the body paper that gathers the paper of pressure-sensitive adhesive that obtains among the resinoid embodiment 12 of alkylamine Epicholorohydrin, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor slightly, but is no problem level.
In addition, at the body paper of the paper of pressure-sensitive adhesive that uses poly-dimethylamine ammonia Epicholorohydrin condenses to obtain in as the poly-resinoid embodiment 13 of alkylamine Epicholorohydrin, have with embodiment 1 in the equal level of body paper of the paper of pressure-sensitive adhesive that obtains.
Can think from above result, as poly-alkylamine Epicholorohydrin resinoid, preferred poly-dimethylamine Epicholorohydrin condenses or the modification dimethylamine Epicholorohydrin condenses of using.
In addition, cooperating oil number with respect to base 100 weight parts is amorphous silica 50 weight parts of 100ml/100g, body paper as the paper of pressure-sensitive adhesive that obtains among the embodiment 9 of poly-resinoid poly-methylethyl amine Epicholorohydrin condenses 5 weight parts of alkylamine Epicholorohydrin, and, cooperating oil number with respect to base 100 weight parts is amorphous silica 50 weight parts of 280ml/100g, body paper as the paper of pressure-sensitive adhesive that obtains among the embodiment 10 of poly-resinoid poly-methylethyl amine Epicholorohydrin condenses 5 weight parts of alkylamine Epicholorohydrin, though be to find that among the body paper of the paper of pressure-sensitive adhesive that embodiment 1～21 is obtained it is fuzzy the most obvious, the evaluation result of printing density is also low, but is the level of anti-practicality.
In addition, body paper at the paper of pressure-sensitive adhesive that cooperate oil number with respect to base 100 weight parts be amorphous silica 150 weight parts of 100ml/100g, obtain in as the embodiment 11 of poly-resinoid poly-methylethyl amine Epicholorohydrin condenses 35 weight parts of alkylamine Epicholorohydrin, compare with the body paper of the paper of pressure-sensitive adhesive of embodiment 1, though the evaluation result of coat intensity is poor slightly, be the practical no problem level that.
In addition, using number-average molecular weight is 1000 poly-alkylamine Epicholorohydrin resinoid of poly-dimethylamine Epicholorohydrin condenses conduct and then the body paper that cooperates the paper of pressure-sensitive adhesive that obtains among the embodiment 21 of fully saponified type polyvinyl alcohol 15 weight parts with respect to base 100 weight parts, among the body paper of the paper of pressure-sensitive adhesive that embodiment 1～21 is obtained, be that evaluation to fuzzy, printing density, coat intensity all is the body paper of the best paper of pressure-sensitive adhesive.
In addition, and be used as the poly-resinoid poly-dimethylamine Epicholorohydrin condenses of alkylamine Epicholorohydrin and cooperate the body paper of the paper of pressure-sensitive adhesive that the polyamide epichlorohydrin condenses obtains in as the embodiment 19 of cationic printing ink fixing salt, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, evaluation result fuzzy and printing density is poor slightly, but is the practical no problem level that.
In addition, and be used as the poly-resinoid poly-dimethylamine Epicholorohydrin condenses of alkylamine Epicholorohydrin and cooperate the body paper of the paper of pressure-sensitive adhesive that the cationic urethane resin obtains in as the embodiment 20 of cationic printing ink fixing salt, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, its evaluation result fuzzy and printing density is poor slightly, but is the practical no problem level that.
In addition, do not use poly-alkylamine Epicholorohydrin resinoid but use separately the paper of pressure-sensitive adhesive that the polyamide epichlorohydrin condenses obtains in as the comparative example 7 of cationic printing ink fixing salt body paper and, do not using poly-alkylamine Epicholorohydrin resinoid but using the body paper of the paper of pressure-sensitive adhesive that the cationic urethane resin obtains in as the comparative example 8 of cationic printing ink fixing salt separately, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, fuzzy poor with printing density, concurrent existing transfer printing phenomenon can not be supplied with practicality.
In addition, at the body paper of the paper of pressure-sensitive adhesive that uses separately oil number to obtain in as the comparative example 9 of particulate weighting agent as the talcum of 60ml/100g, compare with the body paper of the paper of pressure-sensitive adhesive that obtains among the embodiment 1, fuzzy poor with printing density, concurrent existing transfer printing phenomenon can not be supplied with practicality.
Can think from above result, by and be that amorphous silica and the poly-alkylamine Epicholorohydrin resinoid of 100～280ml/100g closes with oil number, can obtain to prevent to blur, the printing density height, not have the body paper of the paper of pressure-sensitive adhesive of transfer printing problem.
Utilizability on the industry
As mentioned above, according to the present invention, can provide a kind of the fuzzy of document image that do not have in the printing with ink-jet printer, printing density is abundant, can be suitable for the body paper of the paper of pressure-sensitive adhesive of the very thin images such as printed bar code.
And then, the body paper of following paper of pressure-sensitive adhesive can be provided, namely, the photographic fixing of the pressure-sensitive adhesive composite coat of jetted ink on this body paper is abundant, when formation has the postcard of personal delivery, can be to the opposing party's personal delivery face transfer printing at the image that the personal delivery face owing to a folding side who overlaps records.
Claims (11)
1. be suitable for body paper, comprise basic paper and the coat of the pressure-sensitive adhesive composite that on the whole or part on the one side of above-mentioned basic paper or two sides, forms with the paper of pressure-sensitive adhesive of ink jet printer printing,
Above-mentioned coat contains:
With the non-separability pressure adhesive base that is main component,
Be used to adjust above-mentioned base adhering state the particulate weighting agent and
Be used to make the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection, and,
As above-mentioned particulate weighting agent, containing the oil number of measuring according to ISO787-5 is the amorphous silica of 100～280ml/100g,
As the amorphous silica of above-mentioned particulate weighting agent contained in above-mentioned coat with respect to the cooperation ratio of above-mentioned base being, is 50～150 weight % with respect to above-mentioned base 100 weight %,
As above-mentioned cationic printing ink fixing salt, contain poly-alkylamine Epicholorohydrin resinoid,
Contained above-mentioned poly-alkylamine Epicholorohydrin resinoid is to be 5～35 weight % with respect to above-mentioned base 100 weight % with respect to the cooperation ratio of above-mentioned base in the above-mentioned coat.
2. the body paper of the described paper of pressure-sensitive adhesive of claim 1, wherein, the oil number of measuring according to ISO787-5 of above-mentioned amorphous silica is 130～200ml/100g.
3. the body paper of claim 1 or 2 described paper of pressure-sensitive adhesive, wherein, above-mentioned poly-alkylamine Epicholorohydrin resinoid is poly-dimethylamine Epicholorohydrin condenses and/or modification dimethylamine Epicholorohydrin condenses.
4. the body paper of each described paper of pressure-sensitive adhesive of claim 1～3, wherein, the resinoid number-average molecular weight of above-mentioned poly-alkylamine Epicholorohydrin is below 10000.
5. the body paper of each described paper of pressure-sensitive adhesive of claim 1～4, wherein, in the coat of above-mentioned pressure-sensitive adhesive composite, also being combined with respect to above-mentioned base 100 weight parts is the polyvinyl alcohol of 5～20 weight parts.
6. the postcard that has personal delivery, this postcard is to be converted into eighty percent discount by the body paper with each described paper of pressure-sensitive adhesive of claim 1～5, be processed into the postcard size, on the part at least of the pressure-sensitive adhesive composite coat of pressure-sensitive adhesive strippingly, form then with the ink-jet printer printing information.
7. the postcard that has personal delivery, this postcard is to be converted into three foldings by the body paper with each described paper of pressure-sensitive adhesive of claim 1～5, be processed into the postcard size, on the part at least of the pressure-sensitive adhesive composite coat of pressure-sensitive adhesive strippingly, form then with the ink-jet printer printing information.
8. be suitable for the manufacture method of the body paper of the paper of pressure-sensitive adhesive that prints with ink jet printer, this method comprises:
Prepare basic paper the 1st step,
The 2nd step of preparation pressure-sensitive adhesive composite paint,
The pressure-sensitive adhesive composite paint of preparing in the one side by the basic paper prepared in above-mentioned the 1st step or whole or local coating the 2nd step on two sides forms the 3rd step of the coat of pressure-sensitive adhesive composite;
The particulate weighting agent and being used to that above-mentioned the 2nd step comprises by the base that will be main component with non-separability pressure adhesive, be used for adjusting the adhering state of above-mentioned base makes the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection add water to, mix, and generates the coating material production step of pressure-sensitive adhesive composite paint;
In the above-mentioned coating production stage,
As above-mentioned particulate weighting agent, containing the oil number of measuring according to ISO787-5 is the amorphous silica of 100～280ml/100g,
Above-mentioned amorphous silica with respect to the cooperation ratio of above-mentioned base is, is 50～150 weight % with respect to above-mentioned base 100 weight %;
As above-mentioned cationic printing ink fixing salt, contain poly-alkylamine Epicholorohydrin resinoid,
Above-mentioned poly-alkylamine Epicholorohydrin resinoid with respect to the cooperation ratio of above-mentioned base is, is 5～35 weight % with respect to above-mentioned base 100 weight %.
9. the manufacture method of the body paper of the described paper of pressure-sensitive adhesive of claim 8, wherein, also being combined with respect to above-mentioned base 100 weight parts in the above-mentioned pressure-sensitive adhesive composite paint is the polyvinyl alcohol of 5～20 weight parts.
10. pressure-sensitive adhesive composite paint, it uses in the manufacture method of the body paper of the paper of pressure-sensitive adhesive that is suitable for printing with ink jet printer, it be by the base that will be main component with non-separability pressure adhesive, the particulate weighting agent and being used to that is used for adjusting the adhering state of above-mentioned base makes the cationic printing ink fixing salt of the printing ink photographic fixing of ink jet printer ejection add water to and mixes;
As above-mentioned particulate weighting agent, containing the oil number of measuring according to ISO787-5 is the amorphous silica of 100～280ml/100g,
Above-mentioned amorphous silica with respect to the cooperation ratio of above-mentioned base is, is 50～150 weight % with respect to above-mentioned base 100 weight %;
As above-mentioned cationic printing ink fixing salt, contain poly-alkylamine Epicholorohydrin resinoid,
Above-mentioned poly-alkylamine Epicholorohydrin resinoid with respect to the cooperation ratio of above-mentioned base is, is 5～35 weight % with respect to above-mentioned base 100 weight %.
11. pressure-sensitive adhesive composite paint, it is used for the manufacture method of the body paper of the described paper of pressure-sensitive adhesive of claim 8, wherein, in above-mentioned pressure-sensitive adhesive composite paint, also being combined with respect to above-mentioned base 100 weight parts is the polyvinyl alcohol of 5～20 weight parts.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810175019 CN101724360B (en) | 2008-10-24 | 2008-10-24 | Raw paper of pressure-sensitive adhesive paper, manufacturing method thereof and pressure-sensitive adhesive composite paint used in manufacturing method |
| HK10110944.4A HK1144442A1 (en) | 2008-10-24 | 2010-11-25 | Base paper for pressure sensitive adhesive paper suitable for printing with inkjet printer, method for producing the same, and pressure-sensitive adhesive composition coating material used for the production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810175019 CN101724360B (en) | 2008-10-24 | 2008-10-24 | Raw paper of pressure-sensitive adhesive paper, manufacturing method thereof and pressure-sensitive adhesive composite paint used in manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101724360A true CN101724360A (en) | 2010-06-09 |
| CN101724360B CN101724360B (en) | 2013-05-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200810175019 Expired - Fee Related CN101724360B (en) | 2008-10-24 | 2008-10-24 | Raw paper of pressure-sensitive adhesive paper, manufacturing method thereof and pressure-sensitive adhesive composite paint used in manufacturing method |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN101724360B (en) |
| HK (1) | HK1144442A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105155342A (en) * | 2015-09-10 | 2015-12-16 | 江苏琛亚印材科技有限公司 | Crylic acid back coating emulsion applied to storage of coated paper |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09104167A (en) * | 1995-08-04 | 1997-04-22 | Tokushu Paper Mfg Co Ltd | Pressure bonding postcard for ink jet recording |
| WO2008010522A1 (en) * | 2006-07-20 | 2008-01-24 | Kishu Paper Co., Ltd. | Base paper for pressure-bonding postcard |
-
2008
- 2008-10-24 CN CN 200810175019 patent/CN101724360B/en not_active Expired - Fee Related
-
2010
- 2010-11-25 HK HK10110944.4A patent/HK1144442A1/en not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09104167A (en) * | 1995-08-04 | 1997-04-22 | Tokushu Paper Mfg Co Ltd | Pressure bonding postcard for ink jet recording |
| WO2008010522A1 (en) * | 2006-07-20 | 2008-01-24 | Kishu Paper Co., Ltd. | Base paper for pressure-bonding postcard |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105155342A (en) * | 2015-09-10 | 2015-12-16 | 江苏琛亚印材科技有限公司 | Crylic acid back coating emulsion applied to storage of coated paper |
Also Published As
| Publication number | Publication date |
|---|---|
| HK1144442A1 (en) | 2011-02-18 |
| CN101724360B (en) | 2013-05-22 |
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