CN101721910A - Cross-flow biotrickling filter device for treating gaseous pollutant - Google Patents
Cross-flow biotrickling filter device for treating gaseous pollutant Download PDFInfo
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- 239000003344 environmental pollutant Substances 0.000 title abstract description 6
- 231100000719 pollutant Toxicity 0.000 title abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 122
- 239000007921 spray Substances 0.000 claims abstract description 56
- 238000012856 packing Methods 0.000 claims abstract description 30
- 230000003068 static effect Effects 0.000 claims abstract description 23
- 239000000945 filler Substances 0.000 claims abstract description 7
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- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000009826 distribution Methods 0.000 abstract description 26
- 238000005070 sampling Methods 0.000 abstract description 7
- 238000009827 uniform distribution Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 32
- 239000012855 volatile organic compound Substances 0.000 description 8
- 244000005700 microbiome Species 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000002912 waste gas Substances 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000002028 Biomass Substances 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明涉及一种处理气态污染物的错流生物滴滤装置,属于气态污染物的处理领域。本装置包括由进气挡板(12)通过法兰与上部箱体(3)相连构成的进气静压区,由底部挡板(13)、支撑板(11)及法兰固定的填料支撑架(10)构成的填料区,以及排气收集管(14)、喷淋系统、喷淋液循环系统、进气口(1)、出气口(22)、采样口(2)。本发明中的结构形式利于气流在进气静压区内均匀分布,提高了填料的利用率,喷淋液由喷淋系统均匀布液,使气、液分布一致,气流经过填料方向与液体喷淋方向呈错流式,喷淋液循环系统使喷淋液充分利用。
The invention relates to a cross-flow biological trickle filter device for treating gaseous pollutants, which belongs to the field of gaseous pollutants treatment. The device includes an air intake static pressure zone formed by connecting the air intake baffle (12) to the upper box (3) through flanges, supported by the bottom baffle (13), the support plate (11) and the packing fixed by the flange The packing area that frame (10) constitutes, and exhaust collection pipe (14), spray system, spray liquid circulation system, air inlet (1), air outlet (22), sampling port (2). The structural form in the present invention is conducive to the uniform distribution of the airflow in the air intake static pressure area, which improves the utilization rate of the filler. The spray liquid is evenly distributed by the spray system, so that the distribution of gas and liquid is consistent. The spray direction is cross-flow, and the spray liquid circulation system makes full use of the spray liquid.
Description
技术领域technical field
本发明涉及一种处理气态污染物的错流生物滴滤装置,属于环保领域。The invention relates to a cross-flow biological trickle filter device for treating gaseous pollutants, which belongs to the field of environmental protection.
背景技术Background technique
生物滴滤法是近年来研究最为活跃的一种挥发性有机物(Volatile OrganicCompounds,简称VOCs)净化方法。与常规VOCs控制技术相比,它具有生物量多,反应条件(pH值、湿度)易于控制,净化效率高,费用低且能耗少等特点。Biological trickling filtration is the most active research in recent years as a purification method for volatile organic compounds (Volatile Organic Compounds, referred to as VOCs). Compared with conventional VOCs control technology, it has the characteristics of large biomass, easy control of reaction conditions (pH value, humidity), high purification efficiency, low cost and low energy consumption.
生物滴滤法净化VOCs废气的传统工艺流程,VOCs气体由塔底进入,在流动过程中与生物膜接触而被净化,净化后的气体由塔顶排出。循环喷淋液从填料层上方进入滤塔,流经生物膜表面后在滤塔底部沉淀,喷淋液加入N、P、pH调节剂等循环使用,沉淀物排出系统。The traditional process of purifying VOCs exhaust gas by biological trickling filtration, VOCs gas enters from the bottom of the tower, is purified by contact with biofilm during the flow process, and the purified gas is discharged from the top of the tower. The circulating spray liquid enters the filter tower from the top of the packing layer, flows through the surface of the biofilm and settles at the bottom of the filter tower. The spray liquid is added with N, P, pH regulator, etc. for recycling, and the sediment is discharged out of the system.
生物滴滤塔的填料上方喷淋液的作用主要是:提供微生物所需的除碳源以外的其他营养物质;调节微生物生长环境的pH值;保证微生物生存的湿度环境;带走代谢产物;通过水力冲刷保持生物膜的厚度,防止生物膜内厌氧。喷淋液对生物滴滤塔的净化效果有十分重要的影响,主要表现在:①喷淋液的流量:喷淋液的流量太小,微生物生存的湿度环境不能保证,生物活性低;喷淋液的流量过大,则不利于微生物在填料表面的附着生长,形成稳定的生物膜。②喷淋液的分布:喷淋液在填料层上层和下层分布不均,会严重影响生物滴滤塔的净化效果。The main functions of the spray liquid above the filler of the biological trickling filter are: to provide nutrients other than carbon sources required by microorganisms; to adjust the pH value of the growth environment of microorganisms; to ensure the humidity environment for the survival of microorganisms; to take away metabolites; Hydroscouring maintains the thickness of the biofilm and prevents anaerobic conditions within the biofilm. The spray liquid has a very important influence on the purification effect of the biological trickling filter tower, which is mainly manifested in: ①The flow rate of the spray liquid: the flow rate of the spray liquid is too small, the humidity environment for the survival of microorganisms cannot be guaranteed, and the biological activity is low; If the flow rate of the liquid is too large, it is not conducive to the attachment and growth of microorganisms on the surface of the filler, forming a stable biofilm. ②Distribution of spray liquid: The uneven distribution of spray liquid in the upper and lower layers of the packing layer will seriously affect the purification effect of the biological trickling filter tower.
生物滴滤法采用的设备为传统的生物滴滤塔,气、液在滴滤塔内顺流或逆流接触。喷淋液中营养物质随着塔高被微生物吸收利用,营养盐浓度分布也将会随着塔轴线而显著降低,这导致了滴滤塔内湿度和生物量分布的不均匀,降低了滴滤塔的有效降解空间,影响了其去除效果,且容易产生压降高、易堵塞的问题,这些问题的存在增大了设备体积和投资费用,给操作管理带来不便,极大地限制了生物滴滤法在工业实际中的进一步应用。The equipment used in the biological trickling filter method is a traditional biological trickling filter tower, and the gas and liquid are in contact with each other in the trickling filter tower either downstream or countercurrent. Nutrients in the spray liquid are absorbed and utilized by microorganisms along with the height of the tower, and the distribution of nutrient salt concentration will also be significantly reduced along the axis of the tower, which leads to uneven distribution of humidity and biomass in the trickling filter tower and reduces the efficiency of trickling filtration. The effective degradation space of the tower affects its removal effect, and it is prone to problems of high pressure drop and easy clogging. The existence of these problems increases the equipment volume and investment costs, brings inconvenience to operation and management, and greatly limits the biological drop rate. Further application of filtration method in industrial practice.
发明内容Contents of the invention
为了克服现有装置的上述缺陷,本发明提供一种错流生物滴滤装置,让废气能够均匀地通过生物膜,可以高效地处理气态污染物的。In order to overcome the above-mentioned defects of the existing devices, the present invention provides a cross-flow bio-trickling filter device, which allows waste gas to pass through the biofilm evenly, and can efficiently treat gaseous pollutants.
为了实现上述目的,本发明采取了如下技术方案:设计一种生物处理箱,让废气进入箱体后形成均匀稳定的进气区,附着生物膜的填料区设置在进气区外围,使废气能够均匀通过填料区,成为清洁气体后进入气体收集区,然后经排气收集管排出。并且设计一种喷淋机构,使喷淋液能够均匀流过填料区。还设置有喷淋液循环系统,使喷淋液能够充分利用。下面介绍实现方案:In order to achieve the above object, the present invention adopts the following technical scheme: design a biological treatment box, let the exhaust gas enter the box to form a uniform and stable intake area, and the filler area with biofilm attached is arranged on the periphery of the intake area, so that the exhaust gas can Evenly pass through the packing area, become a clean gas, enter the gas collection area, and then be discharged through the exhaust collection pipe. And design a spray mechanism, so that the spray liquid can evenly flow through the packing area. It is also equipped with a spray liquid circulation system to make full use of the spray liquid. The following describes the implementation plan:
该处理气态污染物的错流生物滴滤装置由生物处理箱、与生物处理箱上部相连的进气口、以及与生物处理箱上部和下部相连的喷淋液循环系统构成。其中,生物处理箱中设有进气静压区、填料区、进气区、气体收集区、排气收集管、出气口及喷淋系统;并且,进气静压区位于生物处理箱上部区域的中间部位,由围挡隔出,与进气口相通;填料区位于生物处理箱中、下部,呈围挡形设置,将生物处理箱中、下部区域分为中央区域和外围区域,前者形成进气区,与进气静压区相通,后者形成气体收集区,连接有排气收集管,在排气收集管尾端设有出气口;喷淋系统位于生物处理箱上部区域的与进气静压区隔绝的外围部位,为与填料区顶部相对的与喷淋液循环系统相连的喷淋机构。The cross-flow biological trickling filter device for treating gaseous pollutants is composed of a biological treatment box, an air inlet connected to the upper part of the biological treatment box, and a spray liquid circulation system connected to the upper part and the lower part of the biological treatment box. Among them, the biological treatment box is provided with an intake static pressure area, a packing area, an air intake area, a gas collection area, an exhaust collection pipe, an air outlet, and a spray system; and, the intake static pressure area is located in the upper area of the biological treatment box The middle part of the bioprocessing box is separated from the enclosure and communicated with the air inlet; the filling area is located in the middle and lower part of the biological treatment box, which is arranged in the shape of an enclosure, and the middle and lower areas of the biological treatment box are divided into a central area and a peripheral area. The former forms The air intake area communicates with the air intake static pressure area, which forms a gas collection area, connected with an exhaust collection pipe, and has an air outlet at the end of the exhaust collection pipe; the spray system is located in the upper area of the biological treatment box and the inlet The peripheral part isolated by the aerostatic pressure zone is the spray mechanism connected with the spray liquid circulation system opposite to the top of the filling zone.
所述喷淋机构为底部设置均匀小孔的环形的布液槽及位于布液槽上方的与喷淋液循环系统相连的布液支管,其中布液支管设置两个以上,且在布液槽上方均匀布置。The spray mechanism is an annular liquid distribution tank with uniform small holes at the bottom and a liquid distribution branch pipe connected to the spray liquid circulation system above the liquid distribution tank. Evenly distributed above.
所述喷淋液循环系统包括位于生物处理箱底部的设有均匀小孔的支撑板、位于支撑板下面与生物处理箱底部连接的集液槽、与集液槽底部相通的液封管、与液封管连通的循环液槽、位于循环液槽内的循环液泵、与循环液泵出口连接的循环液管、与循环液管连通的高位液槽、位于高位液槽中上部并与高位液槽和循环液槽相通的溢流管、与高位液槽底部出口连接的电磁阀、与循环液泵相通的分液槽,其中分液槽的出口与布液支管连通。The spray liquid circulation system includes a support plate with uniform small holes at the bottom of the biological treatment tank, a liquid collection tank connected to the bottom of the biological treatment tank under the support plate, a liquid-sealed pipe communicating with the bottom of the liquid collection tank, and The circulating liquid tank connected by the liquid seal pipe, the circulating liquid pump located in the circulating liquid tank, the circulating liquid pipe connected to the outlet of the circulating liquid pump, the high-level liquid tank connected with the circulating liquid pipe, the upper middle part of the high-level liquid tank and the high-level liquid The tank is connected to the overflow pipe of the circulating liquid tank, the solenoid valve is connected to the bottom outlet of the high-level liquid tank, and the liquid distribution tank is connected to the circulating liquid pump, wherein the outlet of the liquid distribution tank is connected to the liquid distribution branch pipe.
所述进气口、出气口均设置采样口。Both the air inlet and the air outlet are provided with sampling ports.
所述生物处理箱可以由环形的进气挡板、环形的底部挡板、上部箱体、下部箱体、填料支撑架、布液槽、排气收集管、进气口、出气口组成,其中,进气挡板位于上部箱体内,将上部箱体分为中央区域和外围区域,中央区域作为进气静压区与进气口连通,外围区域设置喷淋系统;上部箱体与下部箱体通过法兰连接;下部箱体由内到外分为三个区域,内层区域为进气区,与进气静压区相通,中层区域为与上部箱体的外围区域对应的填料区,该区域放置有填料支撑架,填料支撑架由底部挡板、支撑板支撑并由法兰固定,外层区域为气体收集区;气体收集区与排气收集管、出气口依次连接。其中,生物处理箱外形可以为筒状罐体,其中排气收集管与下部箱体相切连接。The biological treatment box can be composed of an annular intake baffle, an annular bottom baffle, an upper box, a lower box, a packing support frame, a liquid distribution tank, an exhaust collection pipe, an air inlet, and an air outlet, wherein , the air intake baffle is located in the upper box, which divides the upper box into a central area and a peripheral area, the central area is used as the air intake static pressure area and communicates with the air inlet, and the peripheral area is equipped with a spray system; the upper box and the lower box Connected by flanges; the lower box is divided into three areas from the inside to the outside, the inner area is the air intake area, which communicates with the air intake static pressure area, and the middle area is the packing area corresponding to the outer area of the upper box body. A packing support frame is placed in the area, and the packing support frame is supported by the bottom baffle and the support plate and fixed by the flange. The outer area is the gas collection area; the gas collection area is connected with the exhaust collection pipe and the gas outlet in sequence. Wherein, the shape of the biological treatment box can be a cylindrical tank, wherein the exhaust gas collection pipe is connected tangentially to the lower box.
本发明利用进气静压区使气流速度下降,动压转换为静压,VOCs废气在内部均匀分布后从进气区通过填料区到达气体收集区,成为清洁气体。清洁气体经排气收集管从出气口排出。喷淋液经过循环液泵经循环液管泵入高位水槽,通过电磁阀控制喷淋液量,由分液槽经过分流支管进入布液槽。布液槽位于填料区顶部,且底部设置均匀小孔。喷淋液通过填料区后,通过支撑板上的圆孔进入集液槽。那些未经电磁阀进入喷淋系统的多余喷淋液经溢流管回流到循环液槽。在进、出气口都设置采样口。The invention utilizes the air inlet static pressure area to reduce the airflow velocity, and the dynamic pressure is converted into static pressure. After the VOCs waste gas is uniformly distributed inside, it passes from the air inlet area through the packing area to the gas collection area and becomes clean gas. The clean gas is discharged from the gas outlet through the exhaust collection pipe. The spray liquid is pumped into the high-level water tank through the circulating liquid pump and the circulating liquid pipe, and the amount of the spray liquid is controlled by the solenoid valve, and enters the liquid distribution tank from the liquid separation tank through the branch pipe. The liquid distribution tank is located on the top of the filling area, and uniform small holes are set at the bottom. After the spray liquid passes through the filling area, it enters the liquid collection tank through the round hole on the support plate. The excess spray liquid that enters the spray system without the solenoid valve returns to the circulating liquid tank through the overflow pipe. Sampling ports are provided at the air inlet and outlet.
本发明比现有装置相比进步之处是:设置专门的静压区,进入到生物处理箱内部的气体有足够的空间将动压转换为静压,使气流在内部空间内均匀分布。喷淋液由分液槽及分流支管实现第一次布液,再由圆环形布液槽上第二次布液后,均匀布液到填料区各处,填料气液分布一致,气流经过填料方向与液体喷淋方向呈错流式。本装置能够降低传统生物滴滤装置的高度,减少喷淋液分布的高度差异,同时,喷淋液在气流通过填料方向上分布一致,气流分布均匀,增加接触高浓度气体的填料面积。Compared with the existing device, the present invention is improved in that: a special static pressure area is set, and the gas entering the biological treatment box has enough space to convert the dynamic pressure into static pressure, so that the air flow is evenly distributed in the internal space. The spray liquid is distributed through the liquid distribution tank and branch pipe for the first time, and after the second liquid distribution from the circular liquid distribution tank, the liquid is evenly distributed to all parts of the packing area. The gas and liquid distribution of the packing is uniform, and the air flow passes through The filling direction and the liquid spraying direction are cross-flow. The device can reduce the height of the traditional biological trickling filter device and reduce the height difference of the spray liquid distribution. At the same time, the spray liquid is uniformly distributed in the direction of the air flow through the packing, the air flow is evenly distributed, and the packing area exposed to high-concentration gas is increased.
附图说明Description of drawings
图1为本发明中生物处理箱结构示意图;Fig. 1 is the structural representation of biological treatment box among the present invention;
图2为本发明装置主体结构的俯视图;Fig. 2 is the top view of the main structure of the device of the present invention;
图3为本发明装置的结构及工作原理示意图。Fig. 3 is a schematic diagram of the structure and working principle of the device of the present invention.
图中:A、进气静压区,B、进气区,C、填料区,D、气体收集区,E、喷淋系统,1、进气口,2、采样口,3、上部箱体,4、下部箱体,5、集液槽,6、分液槽,7、布液支管,8、直连管,9、布液槽,10、填料支撑架,11、支撑板,12、进气挡板,13、底部挡板,14、排气收集管,15、液封管,16、循环液槽,17、循环液泵,18、循环液管,19、高位液槽,20、电磁阀,21、溢流管,22、出气口。In the figure: A, air intake static pressure area, B, air intake area, C, packing area, D, gas collection area, E, spray system, 1, air inlet, 2, sampling port, 3, upper box , 4. Lower box body, 5. Liquid collection tank, 6. Liquid separation tank, 7. Liquid distribution branch pipe, 8. Direct connection pipe, 9. Liquid distribution tank, 10. Packing support frame, 11. Support plate, 12, Intake baffle, 13. Bottom baffle, 14. Exhaust collection pipe, 15. Liquid seal pipe, 16. Circulating liquid tank, 17. Circulating liquid pump, 18. Circulating liquid pipe, 19. High level liquid tank, 20, Electromagnetic valve, 21, overflow pipe, 22, air outlet.
具体实施方式Detailed ways
下面结合附图对本发明的具体实施例加以说明:Specific embodiments of the present invention are described below in conjunction with accompanying drawing:
本装置主要包括进气静压区A、进气区B、填料区C、气体收集区D、排气管14,喷淋系统E和喷淋液循环系统。如图1所示,进气静压区A与进气口1相通,利于气流速度下降,动压转换为静压,气体在内部均匀分布后形成进气区B,然后通过填料区C。经填料区C处理后的清洁气体进入气体收集区D,经排气管14由出气口22排出。喷淋系统E位于填料区C上方,与喷淋液循环系统相连。进、出气口均设置采样口。The device mainly includes air intake static pressure area A, air intake area B, packing area C, gas collection area D,
本装置主要由筒罐形生物处理箱和喷淋液循环系统构成(如图2、3)。生物处理箱如下构成:生物处理箱主要包括上部箱体3和下部箱体4,上部箱体3与下部箱体4通过法兰连接,下部箱体4与集液槽5通过法兰连接,之间设有支撑板11。上部箱体3顶部中心与进气口1连接,且进气口1设置采样口2;进气挡板12通过法兰与上部箱体3相连构成进气静压区A;下部箱体4中包括由填料支撑架10构成的填料区C,填料区C以内的进气区B,填料区C以外的气体收集区D;填料支撑架10由底部挡板13与支撑板11支撑,底部挡板13与支撑板11通过法兰固定;支撑板11与填料支撑架10对应的区域设置有许多均匀的小孔,可以使喷淋液流出到集液槽5;集液槽5底部中心与液封管15相连。集液槽5和液封管15以及下面的现有喷淋液循环系统中所用的器件构成本发明中的喷淋液循环系统:循环液槽16、循环液泵17、循环液管18、高位液槽19、溢流管21、电磁阀20、分液槽6、布液支管7、布液槽9。生物处理箱还设置有:由布液槽9与布液支管7通过直连管8相连构成的喷淋系统E,布液支管7均匀布置四套,布液槽9底部设置均匀小孔,形成均匀的喷淋液均匀流到填料区C;与气体收集区D相连的排气收集管14,排气收集管14与下部箱体4相切连接(如图3),并设置出气口22及采样口2。The device is mainly composed of a tank-shaped biological treatment tank and a spray liquid circulation system (as shown in Figures 2 and 3). The biological treatment box is composed as follows: the biological treatment box mainly includes an
液体经喷淋系统E均匀流到填料区C,VOCs废气经进气静压区A可均匀通过填料区C,填料气液分布一致,气流经过填料方向与液体喷淋方向呈错流式。本装置可保持填料区生物膜活性均匀,可高效处理废气。本发明适用于大气量低浓度难溶性难降解有机废气和恶臭气体的处理,具有广泛的实用性。The liquid flows evenly through the spray system E to the filling area C, and the VOCs waste gas can pass through the filling area C evenly through the inlet static pressure area A. The device can maintain uniform biofilm activity in the filling area and can efficiently treat waste gas. The invention is applicable to the treatment of insoluble and refractory organic waste gas and malodorous gas with low air volume and low concentration, and has wide practicability.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107051183A (en) * | 2016-11-11 | 2017-08-18 | 云南大学 | Simultanously desulfurizing and denitrification gas-liquid vertical interlaced streaming biomembrane filled tower new device and application |
CN108579400A (en) * | 2018-06-22 | 2018-09-28 | 福建路驰环保科技股份有限公司 | A kind of bio-trickling filter |
CN109173609A (en) * | 2018-09-27 | 2019-01-11 | 无锡星亿智能环保装备股份有限公司 | A kind of small-sized packed absorber for gas purification |
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CN100431671C (en) * | 2006-12-21 | 2008-11-12 | 北京工业大学 | Bio-trickling device for processing volatile organic waste gas and method thereof |
CN100500269C (en) * | 2007-06-15 | 2009-06-17 | 北京工业大学 | A biological trickling filter bed for treating volatile organic waste gas |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107051183A (en) * | 2016-11-11 | 2017-08-18 | 云南大学 | Simultanously desulfurizing and denitrification gas-liquid vertical interlaced streaming biomembrane filled tower new device and application |
CN108579400A (en) * | 2018-06-22 | 2018-09-28 | 福建路驰环保科技股份有限公司 | A kind of bio-trickling filter |
CN108579400B (en) * | 2018-06-22 | 2023-10-03 | 福建路驰环境科技股份有限公司 | Biological trickling filter |
CN109173609A (en) * | 2018-09-27 | 2019-01-11 | 无锡星亿智能环保装备股份有限公司 | A kind of small-sized packed absorber for gas purification |
CN109173609B (en) * | 2018-09-27 | 2024-07-19 | 无锡星亿智能环保装备股份有限公司 | Small-sized filler absorption tower for gas purification |
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