CN101719563A - Novel lead carbon battery and manufacture method thereof - Google Patents
Novel lead carbon battery and manufacture method thereof Download PDFInfo
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- CN101719563A CN101719563A CN200910227199A CN200910227199A CN101719563A CN 101719563 A CN101719563 A CN 101719563A CN 200910227199 A CN200910227199 A CN 200910227199A CN 200910227199 A CN200910227199 A CN 200910227199A CN 101719563 A CN101719563 A CN 101719563A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention discloses a novel lead carbon battery and a preparation method thereof. The components of the battery comprise a PbO2 base anode, a sulfuric acid aqueous electrolytes, a baffle plate and a lead-carbon mixed cathode, wherein the lead-carbon mixing cathode comprises 55 % to 95% of lead, 1% to 40% of carbon with high specific surface and 0 to 4% of additives, and the carbon with high specific surface comprises super activated carbon, activated carbon fiber, carbon soot, activated carbon microspheres, carbon nanotube and graphite olefin.
Description
Technical field
The present invention relates to novel battery, the novel lead carbon battery of particularly a kind of long-life, high-energy-density, high power density.
Technical background
In recent years, petrochemical industry resource worsening shortages, environmental protection pressure increase severely, and the development of motor vehicle and solar wind-energy system etc. is trend of the times.In the battery that uses in motor vehicle and the solar wind-energy system, lead acid accumulator occupies critical role owing to advantages such as its low price, raw material are easy to get, dependable performances always in secondary battery industry.But along with the appearance and the extensive use of Ni-MH battery, lithium ion battery, further improving specific energy of lead acid battery, specific power and useful life is its main path that occupies a tiny space in battery industry.In order to improve the utilance of lead-acid battery active material, reduce the sulfation of negative plate, can in negative plate, add high surface area carbon.High surface area carbon has bigger specific area, higher conductance, advantage such as corrosion-resistant.
Announced a kind of high-performance energy storage device in the Chinese patent 200910002836.4, this device comprises at least one lead base negative pole, at least one lead dioxide based positive pole, at least one electrode for capacitors and the electrolyte that contacts with electrode.Compare with traditional lead acid batteries, this device has higher specific energy, specific power and useful life.But this device is compared with traditional lead acid batteries, have more an electrode for capacitors, and this electrode for capacitors cost is higher, answer this, and this device is more than the traditional lead acid batteries production process, internal structure is complicated, cost is higher.
On this basis, the present invention proposes a kind of novel lead carbon battery and preparation method thereof.A kind of novel lead carbon battery includes the lead dioxide based positive pole, aqueous sulfuric acid electrolyte, dividing plate, plumbous charcoal mixing negative pole.Described novel lead carbon battery is characterized in that: negative pole is mixed by lead, high surface area carbon and additive and forms.Described novel lead carbon battery is characterized in that: negative pole comprises the lead of 55%-95%, the high surface area carbon of 1%-40%, the additive of 0-4%.Described novel lead carbon battery is characterized in that: high surface area carbon comprises super-activated carbon, activated carbon fiber, carbon black, activated carbon microballon, carbon nano-tube, Graphene.Described novel lead carbon battery is characterized in that: the specific area of high surface area carbon is 1000-3000m
2/ g.
Compare with traditional lead acid batteries, the novel lead carbon battery that the present invention proposes has higher specific energy, specific power and useful life; Compare with the high-performance energy storage device that patent 200910002836.4 is mentioned, the novel lead carbon battery production process that the present invention proposes is few, internal structure simple, cost is lower.
Claims (6)
1. a novel lead carbon battery includes lead dioxide based positive pole, aqueous sulfuric acid electrolyte, dividing plate, plumbous charcoal mixing negative pole.
2. novel lead carbon battery according to claim 1 is characterized in that: negative pole is mixed by lead, high surface area carbon and additive and forms.
3. novel lead carbon battery according to claim 2 is characterized in that: negative pole comprises the lead of 55%-95%, the high surface area carbon of 1%-40%, the additive of 0-4%.
4. novel lead carbon battery according to claim 2 is characterized in that: high surface area carbon comprises super-activated carbon, activated carbon fiber, carbon black, activated carbon microballon, carbon nano-tube, Graphene.
5. novel lead carbon battery according to claim 2 is characterized in that: the specific area of high surface area carbon is 1000-3000m
2/ g.
6. novel lead carbon battery according to claim 2 is characterized in that: additive be plumbous oxide and (or) oxide of zinc.
Priority Applications (1)
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CN200910227199A CN101719563A (en) | 2009-12-11 | 2009-12-11 | Novel lead carbon battery and manufacture method thereof |
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CN200910227199A CN101719563A (en) | 2009-12-11 | 2009-12-11 | Novel lead carbon battery and manufacture method thereof |
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CN101719563A true CN101719563A (en) | 2010-06-02 |
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CN200910227199A Pending CN101719563A (en) | 2009-12-11 | 2009-12-11 | Novel lead carbon battery and manufacture method thereof |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102244300A (en) * | 2011-06-03 | 2011-11-16 | 界首市华宇电源有限公司 | Lead acid battery taking graphene as additive |
CN102299304A (en) * | 2011-07-29 | 2011-12-28 | 南京双登科技发展研究院有限公司 | Lead carbon battery for EV (electric vehicle) |
CN102709526A (en) * | 2012-06-18 | 2012-10-03 | 奇瑞汽车股份有限公司 | Negative lead plaster of lead-carbon battery and preparation method thereof, negative polar plate and lead-carbon battery |
CN102723466A (en) * | 2011-03-31 | 2012-10-10 | 湖南丰日电源电气股份有限公司 | Super Pb-C battery negative plate |
CN103219162A (en) * | 2013-03-27 | 2013-07-24 | 江苏华富储能新技术股份有限公司 | Nanometer carbon-lead super capacitor battery |
CN103493267A (en) * | 2010-12-21 | 2014-01-01 | 联邦科学和工业研究组织 | Electrode and electrical storage device for lead-acid system |
CN103762357A (en) * | 2013-12-30 | 2014-04-30 | 华为技术有限公司 | Lead-acid battery |
DE102015205726A1 (en) | 2014-03-31 | 2015-10-01 | Eternal Materials Co., Ltd. | electrolyte composition |
CN105280398A (en) * | 2014-07-14 | 2016-01-27 | 四川能宝电源制造有限公司 | Preparation method of anode of Pb/C super-capacitor battery |
CN105702921A (en) * | 2009-11-02 | 2016-06-22 | 卡博特公司 | Lead-acid batteries and pastes therefor |
CN106229492A (en) * | 2016-09-22 | 2016-12-14 | 北京工业大学 | A kind of preparation method of lead carbon battery negative pole based on ZIF 8 zeolite imidazole ester skeletal porous carbon nanomaterial |
KR20190051098A (en) * | 2017-11-06 | 2019-05-15 | 현대자동차주식회사 | An electrode active material, an anode including the same, a second battery including the same, the fabrication method of the electrode active material |
-
2009
- 2009-12-11 CN CN200910227199A patent/CN101719563A/en active Pending
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105702921A (en) * | 2009-11-02 | 2016-06-22 | 卡博特公司 | Lead-acid batteries and pastes therefor |
CN103493267A (en) * | 2010-12-21 | 2014-01-01 | 联邦科学和工业研究组织 | Electrode and electrical storage device for lead-acid system |
CN102723466A (en) * | 2011-03-31 | 2012-10-10 | 湖南丰日电源电气股份有限公司 | Super Pb-C battery negative plate |
CN102244300B (en) * | 2011-06-03 | 2014-04-02 | 界首市华宇电源有限公司 | Lead acid battery taking graphene as additive |
CN102244300A (en) * | 2011-06-03 | 2011-11-16 | 界首市华宇电源有限公司 | Lead acid battery taking graphene as additive |
CN102299304A (en) * | 2011-07-29 | 2011-12-28 | 南京双登科技发展研究院有限公司 | Lead carbon battery for EV (electric vehicle) |
CN102709526B (en) * | 2012-06-18 | 2015-06-10 | 奇瑞汽车股份有限公司 | Negative lead plaster of lead-carbon battery and preparation method thereof, negative polar plate and lead-carbon battery |
CN102709526A (en) * | 2012-06-18 | 2012-10-03 | 奇瑞汽车股份有限公司 | Negative lead plaster of lead-carbon battery and preparation method thereof, negative polar plate and lead-carbon battery |
CN103219162A (en) * | 2013-03-27 | 2013-07-24 | 江苏华富储能新技术股份有限公司 | Nanometer carbon-lead super capacitor battery |
CN103219162B (en) * | 2013-03-27 | 2016-04-06 | 江苏华富储能新技术股份有限公司 | A kind of nanometer carbon-lead super capacitor battery |
CN103762357A (en) * | 2013-12-30 | 2014-04-30 | 华为技术有限公司 | Lead-acid battery |
DE102015205726A1 (en) | 2014-03-31 | 2015-10-01 | Eternal Materials Co., Ltd. | electrolyte composition |
US9735449B2 (en) | 2014-03-31 | 2017-08-15 | Eternal Materials Co., Ltd. | Electrolyte composition |
CN105280398A (en) * | 2014-07-14 | 2016-01-27 | 四川能宝电源制造有限公司 | Preparation method of anode of Pb/C super-capacitor battery |
CN106229492A (en) * | 2016-09-22 | 2016-12-14 | 北京工业大学 | A kind of preparation method of lead carbon battery negative pole based on ZIF 8 zeolite imidazole ester skeletal porous carbon nanomaterial |
KR20190051098A (en) * | 2017-11-06 | 2019-05-15 | 현대자동차주식회사 | An electrode active material, an anode including the same, a second battery including the same, the fabrication method of the electrode active material |
KR102518691B1 (en) | 2017-11-06 | 2023-04-05 | 현대자동차주식회사 | An electrode active material, an anode including the same, a second battery including the same, the fabrication method of the electrode active material |
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Application publication date: 20100602 |