CN101717247B - Novel material for processing water into small molecular group water and preparation method and application thereof - Google Patents
Novel material for processing water into small molecular group water and preparation method and application thereof Download PDFInfo
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- CN101717247B CN101717247B CN2009101029646A CN200910102964A CN101717247B CN 101717247 B CN101717247 B CN 101717247B CN 2009101029646 A CN2009101029646 A CN 2009101029646A CN 200910102964 A CN200910102964 A CN 200910102964A CN 101717247 B CN101717247 B CN 101717247B
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Abstract
The invention provides a novel material for processing water into small molecular group water and a preparation method and application thereof, which relate to the fields of human health, chemical engineering and environmental protection. The novel material is a hard, fragile and slightly water-soluble alkaline ceramic material which is prepared by using limestone or lime and feldspar as raw materials, or using potassium and sodium carbonates or oxides, calcium carbonate or oxide, SiO2 and Al2O3 as the raw materials; the main chemical components of the material are K2O or Na2O, CaO, SiO2, Al2O3 and a small quantity of other elements such as magnesium and iron; and the primary phase structure of the material is K2O.Al2O3.2SiO2 or Na2O.Al2O3.2SiO2, and the secondary phase structure is CaO.SiO2 and a small quantity of 2CaO.SiO2. The material is non-toxic, non-corrosive and non-hygroscopic, the powder of the material cannot be agglomerated after a long time of placement, and the material cannot generate gelatinization after reacting with water, and can make the water alkalescent and release elements beneficial to a human body. The invention also discloses the preparation method of the novel material and extensive application of the novel material in the aspect of water treatment. The novel material has the advantages of abundant raw materials, simple process, low production cost, wide production uses and large water treatment capacity.
Description
Technical field: the present invention relates to HUMAN HEALTH, relevant with fields such as chemical industry environmental protections, specifically a kind of novel material that water treatment is become small-micelle water.
Background technology: 2003; Nobel chemistry Prize winner U.S. scientist Pi Tealei and Rhoderick Mai Jinlong find the aquaporin of cell; Narrow cellular water passage only selectivity allows small-micelle water to pass through, and has disclosed the small-micelle water secret useful to HUMAN HEALTH.For a long time, scientists is investigated the geographic crowd of longevity residence, finds that the water that they drink all is alkalescent waters, and for example, the water pH of China's Guangxi crust horse Changshou village is 7.5-8, and the water of Russian Transcaucasia Changshou village also presents weakly alkaline.Simultaneously, the body fluid of healthy subjects also is weakly alkaline, and pH is 7.35-7.45.Therefore, drink weakly alkaline small-micelle water be a kind of obtained universally acknowledged long-lived useful to HUMAN HEALTH.China is called remedies or refreshing stone with medical stone since ancient times.Modern scientific research discloses, and medical stone is a kind of aluminosilicate mineral, and it can slowly dissolve at water and make water be weakly alkaline.Chemical knowledge is told us, and water molecules has hydrogen bond, because the effect of hydrogen bond, water molecules produces association, forms bigger molecular grouping, so general water comprises the tap water of our daily life, all is macromolecular mass water; Water is under the weakly alkaline state, and the association of hydrogen bond receives certain destruction, and macromolecular mass water has become the water of subset.In alkalescent water, OH
-Concentration is greater than H
+Concentration can make many bacteriums not generate.In addition, under weak basic condition, many heavy metallic salts produce hydrolysis; Be easy to be filtered and dispose, make the water of subset, not only mouthfeel is good; And healthy value is also high, so many new technologies that makes the water activation become to be rich in high-octane subset are emerged in large numbers one after another.These technology comprise magnetization, electrolysis, Ceramic Balls infrared technique, nanotechnology etc., and patented claim is also a lot, like " Nano water purification device " application number 200410047863.0; " oxygenation activated water treatment agent ", application number 200410054122.5; " is that medium is produced subset running water with the ceramic particle ", application number 03124726.1.In above-mentioned numerous technology, all fundamentally do not invent stablizing a large amount of water of a kind of ability suitability for industrialized production and become weakly alkaline effective material, be about to the novel material that water treatment becomes small-micelle water.Utilize modern science and technology, make the water subsetization like infrared rays, magnetic field, electrolysis or nano material, not only cost is high; Complicated operation, effect also differ and reserve, and many exchanging container exchange capacities are very low; Be processed into water treating device; Beginning can make water become weakly alkaline, has crossed not how long promptly to have lost efficacy, and its reason is that current material is not a kind of permanently effective material.A kind of good material for water treatment, should satisfy the following points requirement: 1, big water treatment capacity must be arranged, promptly be the material of using seldom, can make a lot of water become small-micelle water; 2, suitable speed of response must be arranged, make the water that is processed become weakly alkaline very soon, make the water of macromolecular mass become water very soon for subset; 3, must be very stable, do not produce pectisation, promptly stand the long period of soaking of water, do not influence its hydrolysis property; 4, performance good and the water reaction must be arranged, long-term and water effect, and can control pH, make water can become small-micelle water.In above-mentioned technology, there is not a kind of technology can perfectly satisfy above-mentioned requirements simultaneously.
Summary of the invention: to above-mentioned existing problems, the object of the invention is: 1, invention is a kind of becomes the novel material of small-micelle water with water treatment, and this material can meet above-mentioned requirements.2, openly invent the preparation method of novel material.3, indicate the extensive use of material of the present invention in water treatment.
According to above-mentioned purpose, product of the present invention is that a kind of water treatment is become the novel material of small-micelle water, this material is to be raw material or with potassium, sodium carbonate or oxide compound by Wingdale or lime and feldspar, calcium carbonate or oxide compound, SiO
2And Al
2O
3Be raw material, a kind of hard of processing, frangible, the alkaline ceramic material that is slightly soluble in water, main chemical is K
2O or Na
2O, CaO, SiO
2, Al
2O
3With other a spot of other elements such as magnesium, iron, main phase structure is K
2OAl
2O
32SiO
2Or Na
2OAl
2O
32SiO
2, secondly be CaOSiO
2With a spot of 2CaOSiO
2, this material non-toxic, there is not corrosion, non-hygroscopic, the long-term placement of its powder is not lumpd, and does not produce gelling with the water effect, can make water become weakly alkaline and discharges the element to the human body beneficial.
Water treatment is become the method for making of the novel material of small-micelle water: method one---after respectively raw material limestone or lime, feldspar being pulverized, press CaO in the raw material: SiO
2Mol ratio be to prepare burden at 0.85～1: 1, mixing, and grinding to 100～180 orders add water machine-shaping then, burn till product at 1100～1350 ℃; Method two---with potassium, sodium carbonate or oxide compound, calcium carbonate or oxide compound, SiO
2And Al
2O
3Be raw material, press material molar ratio Me
2O: Al
2O
3: SiO
2: CaO=1: 1: 6: 6 mixing and grinding, add water and machine-shaping, burn till product at 1100～1350 ℃, Me is K or Na.
Water treatment is become the feldspar of preparing method's indication of the novel material of small-micelle water comprise potash feldspar and plagioclase.
Water treatment is become the described machine-shaping of method for making of the novel material of small-micelle water refer to be processed into various section bars and comprise fragment of brick, tubing, wire rod, sheet material, particle and various water container.
Water treatment becomes the novel material of small-micelle water to be mainly used in all kinds of water treatment device equipment and the various water container; Material and the application in all alkalescent waters are handled as filtered water; Big handles like well water, Running-water Company's water treatment, little of being used in various water containers such as family's tank, water dispenser, teacup.
Description of drawings: figure is the X diffractogram of ore novel material of producing and the novel material of producing with chemical reagent: the X diffraction peak that description of drawings pure reagent material product produces has in the material with natural matter production, particularly main peak K
2OAl
2O
32SiO
2Show consistence.
The novel material X diffractogram that 1# produces with chemical reagent
The novel material X diffractogram that 2# produces with ore
Effect: 1, product of the present invention is a raw material with Wingdale or lime and feldspar, abundant raw material, exploitation easily; Technology is simple, and production cost is low, and end-use is extensive; Big handles like well water; Running-water Company's water treatment, little of being used in various water containers such as family's tank, water dispenser, teacup can generally be applied, and makes most of people can drink cheap and good-quality small-micelle water and has economic benefit and social benefit widely; 2, product treatment water volume of the present invention is big, and promptly useful material seldom can make a lot of water become small-micelle water, and experiment shows that 1 kilogram of product can be handled 1.5 tons of water; 3, product is stable, and the shelf time is long, and experiment shows, under state of nature, deposits the product in 2 years, and the performance of treating water does not change; 4, product is done water-sol experiment, does not produce pectisation; 5, product and water have good for a long time slow releasing effect, and experiment shows that 10 gram products are used the processing of 100 ml waters instead every day, and its timeliness can reach 1 year.6, material of the present invention can be widely used on the various water treatment device and make filtering material, and water was both played a role in filtering, and also plays to make water become weakly alkaline effect.
Embodiment:
Embodiment 1,
Material name: potassium felspar sand, the place of production: Guizhou.Through analyzing, each composition is seen table 1
Table 1 potassium felspar sand component list
| Analysis project | K 2O | SiO 2 | Al 2O 3 | CaO | MgO | Fe 2O 3 | Loss on ignition | Add up to |
| Massfraction (%) | 11.09 | 57.63 | 16.30 | 1.67 | 2.46 | 5.54 | 4.62 | 99.31 |
Material name: Wingdale, the place of production: Guizhou.Through analyzing, each composition is seen table 2
Table 2 Wingdale component list
| Analysis project | CaO | MgO | Fe 2O 3 | SiO 2 | ?Al 2O 3 | K 2O | Loss on ignition | Add up to |
| Massfraction (%) | 54.89 | 1.26 | 0.48 | 0.23 | ?/ | / | 42.80 | 99.66 |
Press CaO and SiO in the raw material
20.95: 1 batching of mol ratio, through calculating, the batching mass ratio of limestone mine and potash feldspar ore is 1: 1.07.Take by weighing limestone mine 2000kg, take by weighing potash feldspar ore 2140kg, be crushed to 1～15mm particle respectively, mixing, with compound with ball mill with its grinding to 150 order, screen over-size is 5%.Add 14% water then, process block with block-making machine, be placed in the Industrial Stoves controlled temperature and under 1210 ± 30 ℃ high temperature, calcine 2h, obtain the 2956kg product, product is the frangible material piece of yellow hard.Through fragmentation, the 10g that draws materials adds water 100mL immersion, and surveying water pH value is 8.43, continues to soak 24h, behind the 100mL water taking-up 50mL of every day with immersion, adds the fresh water of 50mL more then, has done experiment in 30 days so repeatedly.Every day, the pH of water was stabilized in 8.3～8.5, after 30 days, with the material of putting into weighing after filtering, drying, surplus 9g product.But extrapolating every kg product treating water capacity thus is 1.5T.The product powder is placed on and does not produce gelling in the water, is placed in the natural air, through one-year age, does not also see caking.Powder or the small-particle of placement after 1 year is immersed in the water, still has the above-mentioned water that makes and become performance for the weakly alkaline small-micelle water.
Embodiment 2, with chemical reagent preparation, raw material is K in molar ratio
2CO
3: Al
2O
3: SiO
2: CaCO
3=1: preparation in 1: 6: 6 takes by weighing K respectively
2CO
3130g, Al
2O
3102g, SiO
2360g, CaCO
3600g is grinding to 120 order respectively, and screen over-size is 3%, abundant mixing, and it is agglomerating to add the water kneading; And then be processed into plurality of small blocks, and in retort furnace, 1230 ℃ of sintering 1h of controlled temperature; Get white hard friable material piece, made the X diffraction with embodiment 1 material contrast, X diffractogram such as Figure of description 1; The peak of the X diffraction of pure reagent material production is described, in material, is had, special main peak K with natural matter production
2OAl
2O
32SiO
2Show consistence.
Above embodiment, only in order to technical scheme of the present invention to be described, and unrestricted technical scheme of the present invention.
Claims (5)
1. one kind becomes the material of micromolecular water with water treatment, it is characterized in that material is a raw material or with potassium, sodium carbonate or oxide compound by Wingdale or lime and feldspar, calcium carbonate or oxide compound, SiO
2And Al
2O
3Be raw material, a kind of hard of processing, frangible, the alkaline ceramic material that is slightly soluble in water, main chemical is K
2O or Na
2O, CaO, SiO
2, Al
2O
3With a spot of other element magnesium, iron, main phase structure is K
2OAl
2O
32SiO
2Or Na
2OAl
2O
32SiO
2, secondly be CaOSiO
2With a spot of 2CaOSiO
2, this material non-toxic, there is not corrosion, non-hygroscopic, the long-term placement of its powder is not lumpd, and does not produce gelling with the water effect, can make water become weakly alkaline and discharges the element to the human body beneficial.
2. a kind of water treatment is become the preparation methods of micromolecular water according to claim 1 is described, it is characterized in that method one---after respectively raw material limestone or lime, feldspar being pulverized, press CaO in the raw material: SiO
2Mol ratio be to prepare burden at 0.85～1: 1, mixing, and grinding to 100～180 orders add water machine-shaping then, burn till product at 1100～1350 ℃; Method two---with potassium, sodium carbonate or oxide compound, calcium carbonate or oxide compound, SiO
2And Al
2O
3Be raw material, press material molar ratio Me
2O: Al
2O
3: SiO
2: CaO=1: 1: 6: 6 mixing and grinding, add water and machine-shaping, burn till product at 1100～1350 ℃, Me is K or Na.
3. according to claim 2ly a kind of water treatment is become the preparation methods of micromolecular water, it is characterized in that the feldspar of indication comprises potash feldspar and plagioclase.
4. describedly a kind of water treatment is become the preparation methods of micromolecular water according to claim 2 or 3, it is characterized in that above-mentioned machine-shaping refers to be processed into various section bars and to comprise fragment of brick, tubing, wire rod, sheet material, particle and various water container.
5. according to the described a kind of application that water treatment is become the material of micromolecular water of claim 1; It is characterized in that being applied in all kinds of water treatment device equipment and the various water container; Material and the application in all alkalescent waters are handled as filtered water; The big well water that is used in is handled, Running-water Company's water treatment, little family's tank, water dispenser, the various water containers of teacup of being used in.
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|---|---|---|---|
| CN2009101029646A CN101717247B (en) | 2009-12-22 | 2009-12-22 | Novel material for processing water into small molecular group water and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101029646A CN101717247B (en) | 2009-12-22 | 2009-12-22 | Novel material for processing water into small molecular group water and preparation method and application thereof |
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|---|---|
| CN101717247A CN101717247A (en) | 2010-06-02 |
| CN101717247B true CN101717247B (en) | 2012-04-18 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101393158B1 (en) * | 2012-05-03 | 2014-05-08 | 박기춘 | Moulding compound and device for generating alkaline reduced water |
| CN102765798A (en) * | 2012-07-18 | 2012-11-07 | 罗放明 | Particle energy water preparation method |
| CN105130401A (en) * | 2015-09-01 | 2015-12-09 | 王化頔 | Ceramic material with function of treating water into alkalescent small molecular group water, preparing method and application |
| CN108408866A (en) * | 2017-02-09 | 2018-08-17 | 朱洪立 | Three clear anion waters |
| CN111718057A (en) * | 2020-06-30 | 2020-09-29 | 潘凯峰 | Preparation process of small molecular group water |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1473776A (en) * | 2003-08-06 | 2004-02-11 | 孙汝英 | Process for producing small molecular group running water by using ceramic particles as medium |
| CN101264435A (en) * | 2008-04-27 | 2008-09-17 | 讷文波 | Pottery fragments capable of adsorbing, purifying, mineralizing and generating alkalescence food |
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2009
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1473776A (en) * | 2003-08-06 | 2004-02-11 | 孙汝英 | Process for producing small molecular group running water by using ceramic particles as medium |
| CN101264435A (en) * | 2008-04-27 | 2008-09-17 | 讷文波 | Pottery fragments capable of adsorbing, purifying, mineralizing and generating alkalescence food |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平11-387A 1999.01.06 |
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