CN101705438A - X70 hot-rolled steel coil for pipeline steel and manufacturing method thereof - Google Patents

Abstract

An X70 hot-rolled steel coil for pipeline steel and a manufacturing method thereof belong to the technical field of the pipeline steel. The hot-rolled steel coil contains the following chemical constituents: 0.04-0.08wt% of C, 0.10-0.30wt% of Si, 1.40-1.75wt% of Mn, 0.03-0.06wt% of Nb, 0.020-0.050wt% of V, 0.010-0.020wt% of Ti, 0.10-0.15wt% of Mo, 0.15-0.20wt% of Cu, 0.10-0.15wt% of Ni, 0.20-0.30wt% of Cr, less than or equal to 0.018wt% of P, less than or equal to 0.003wt% of S, less than or equal to 0.006wt% of N, 0.0003-0.0005wt% of B, less than or equal to 0.0003wt% of H, and the balance of Fe and micro-impurities, wherein Nb plus V plus Ti accounts for 0.06-0.15 wt%. 230 mm continuously cast bloom is adopted and subjected to recrystallization zone rolling of R1 and R2 rough mill, non-recrystallization zone rolling of six tandem-rolling finish mills, as well as followed laminar cooling control and cold deformation low-temperature coiling technology, thus producing the hot-rolled steel coil with specification of X70 and the thickness of 10-19mm. The hot-rolled steel coil is applicable to gas transmission pipelines with high pressure, long distance and heavy calibers.

Description

A kind of X 70 hot-rolled steel coil for pipeline steel and manufacture method thereof

Technical field

The invention belongs to the pipe line steel technical field, particularly relate to a kind of X 70 hot-rolled steel coil for pipeline steel and manufacture method thereof, be applicable to high pressure, heavy caliber and long apart from transport gas, petroleum pipe line engineering.

Background technology

The wide-scale adoption of following " line of transferring natural gas from the west to the east " pipeline to use the 17.5mmX70 hot-rolled coil with production domesticization and " gas east, river is sent " pipeline of 14.6mmX70 roll bending, it is ripe that the production technology of high strength, high tenacity X 70 hot-rolled steel coil for pipeline steel is tending towards.But because the rising suddenly and sharply of alloy raw material price, production cost pressure is increasing, is 0.25% such as transfering natural gas from the west to the east one line with the addition of 14.6mmX70 roll bending Mo alloy, and the Ni addition is 0.25%, and cost of alloy is too high; " gas east, river is sent " the pipework wide-scale adoption 17.5mmX70 roll bending that put into operation in 2006, the Mo alloy addition level is 0.25%, and the Ni alloy addition level is 0.16%, and cost of alloy is too high.

Consult domestic and foreign literature and patent, Baoshan Iron ﹠ Steel Co., Ltd applies for a patent: acicular ferrite type X70 pipe line steel and manufacture method thereof with high arrest toughness.Application number: 200410066297.8.The subject matter that exists is that alloy content is higher, is 0.22% such as the Mo addition, and the Ni addition is 0.15%, and the Cu addition is 0.25%, and cost of alloy is too high.Institutes Of Technology Of Hebei applies for a patent: a kind of low cost high performance X 70 pipeline steel and production method.Application number: 200810079325.8, subject matter X70 product specification is thin, only is 7.9mm such as embodiment 1 product thickness, secondly be to have added the B alloying element, and domestic great pipework clearly proposes not allow to add the B element, and B content is less than 0.0005%.Baoshan Iron ﹠ Steel Co., Ltd applies for a patent in addition: a kind of economical X 70 pipeline steel and production method thereof, and application number: 200710038397.3, the problem of existence is at first not indicate product specification, next implements coiling temperature is 550 ℃.

At the technical qualification of domestic " transfering natural gas from the west to the east two wires " engineering of implementing with the 17.5mmX70 roll bending, the Shoudu Iron and Steel Co technician has optimized the composition system of X70 roll bending, has reduced the alloy content of expensive alloys Mo and Ni; And by optimizing coiling technique, coiling temperature is reduced to below 420 ℃, actual coiling temperature is controlled to be 400 ℃, and γ → α phase transformation is finished substantially, and low temperature coiling process subsequently is equivalent to working hardening and further improves strength property.

At present, Shoudu Iron and Steel Co production transfering natural gas from the west to the east two wires pipeline is with nearly 100,000 tons of 17.5mmX70 roll bending, and according to user's reflection, the 17.5mmX70 roll bending cost of alloy of Shoudu Iron and Steel Co production is minimum, stable mechanical property, and use properties is good, is worthy to be popularized.

The invention technology contents:

The object of the present invention is to provide a kind of X 70 hot-rolled steel coil for pipeline steel and manufacture method thereof, the problem that needs to solve is, at transfering natural gas from the west to the east two wires 17.5mmX70 roll bending, develop high strength, high tenacity and the thick specification X70 hot-rolled sheet coil of a kind of production cost economy, stable mechanical property.The thinking of this invention is: by reasonable, economic composition design, with the steel rolling process that matches, adopt the 230mm continuously cast bloom, rolling and 6 rolling finishing mills is not rolling at crystallizing field by the recrystallization zone of R1 and R2 roughing mill, and laminar flow cooling control subsequently, with the low temperature coiling technique based on cold deformation, production specification thickness is 10-19mm specification X70 hot-rolled coil.

The chemical ingredients scope of high strength of the present invention, high tenacity and economy X70 hot-rolled coil is as shown in table 1:

Table 1. chemical ingredients, wt%

The basic chemical composition design of X70 hot-rolled coil be the reasons are as follows:

C: most economical, the most basic strengthening element in the steel, improve intensity by solution strengthening and precipitation strength, it is obvious particularly to improve tensile strength, but it is unfavorable to ductility, toughness and welding property to improve C content, and therefore the C content control ratio of high strength, high tenacity pipe line steel is lower at present.C content of the present invention is controlled to be 0.04-0.09%.

Mn:, reduce the loss of strength that causes because of C content in the compensation pipes steel by the intensity of solution strengthening raising steel.Mn stable austenite in addition enlarges the element of γ phase region, significantly reduces γ → α transformation temperature, helps obtaining tiny low temperature phase change product, improves the low-temperature flexibility of steel.Mn addition of the present invention is 1.40-1.75%.

Ti: adopt little Ti to be treated as the necessary condition of high-strength line-pipe steel, the main strengthening effect of Ti microalloy is as follows:

1) strong solid N element reduces steel grade free state N content, improves toughness.

2) TiN that forms in the heat-processed hinders the thick of heat-processed austenite crystal, improves toughness, and helps the Nb solid solution, the performance strengthening effect.

3) it is thick that welding process suppresses crystal grain, improves the impelling strength of welded heat affecting zone.

Ti content of the present invention is designed to 0.010-0.020%.

The Mo:Mo element enlarges the γ phase, obviously suppresses the formation of proeutectoid ferrite in γ → α phase transition process, promotes the principal element that acicular ferrite and low-carbon bainite form.Because the Mo alloy costs an arm and a leg, Mo content is reduced to target value 0.10% by traditional 0.25%.

Cu, Ni: have certain solid solution strengthening effect, add Cu and can improve the hydrogen sulfide corrosion resistant ability; The adding of Ni mainly is to improve the red brittleness of Cu and improve low temperature impact properties.Cu of the present invention and Ni addition are≤0.20%.

Cr: improve hardening capacity, suppress the generation of polygonal ferrite and pearlitic structure, add a certain amount of expensive Mo alloy of a certain amount of Cr alloy replacing.

Economy X70 hot-rolled coil innovation point:

1) adds a certain amount of Cr alloy replacing Mo alloy.The Cr alloy improves hardening capacity, obtains to substitute the strengthening effect of Mo alloy to a certain extent.

2) non-recrystallization rolling sequence, i.e. finish rolling adopt 6 frames rolling, improve non-recrystallization low temp area reduction in pass, strengthen low temperature controlled rolling effect.

3) coupling laminar flow refrigerative low temperature coiling technique.Coiling temperature is that the metallographic structure of 550 ℃ of quenching samples can be found that γ → α changes and carried out 20%, basically based on austenite structure; The target coiling temperature is that the metallographic structure of 400 ℃ of quenching samples can be found, batches preceding γ → α and changes and finish substantially, with room temperature texture's indifference almost.(seeing accompanying drawing 1) operational path:

Raw material preparation → hot metal pretreatment → converter smelting → external refining → sheet billet continuous casting → slab reheat → controlled rolling → controlled chilling → laminar flow cools off → batches → checks, puts in storage.It is as follows that key is to control the steel rolling main technologic parameters:

1, Heating temperature: 1150-1220 ℃;

2, roughing final temperature: 1020-1080 ℃;

3, finish rolling final temperature: 800 ± 30 ℃;

4, coiling temperature: 350 ℃-420 ℃;

5, finish rolling compression ratio: finishing stand adopts 6 frames rolling, and intermediate blank thickness/finish rolling exit thickness 3.5-4 is strengthened passage low temperature gross distortion controlled rolling effect.

Economic implications of the present invention and social effect:

At transfering natural gas from the west to the east two wires pipework wide-scale adoption 17.5mm X70 roll bending, estimate that total amount reaches more than 1,000,000 tons, 10.3 ten thousand tons of the 17.5mmX70 of Shoudu Iron and Steel Co acceptance of the bid at present roll bendings, 100,000 tons of low-cost 17.5mmX70 roll bendings have been produced in batches, the user reflects that the X70 roll bending cost of alloy of Shoudu Iron and Steel Co production is minimum, stable mechanical property, use properties is good.Compare with the 17.5mmX70 roll bending with " gas east, river is sent " pipeline, the Mo alloy has reduced by 0.15%, and the Ni alloy has reduced by 0.06%, the Nb alloy has reduced by 0.02%, calculates according to present cost of alloy, and ton Steel Alloy cost reduces by 854 yuan, increase income and economize on spending 8,540 ten thousand yuan, be worthy of popularization.

Description of drawings

Fig. 1 is 550 ℃ of quenching metallographic structures for coiling temperature.

Fig. 2 is 400 ℃ of quenching metallographic structures for coiling temperature.

Fig. 3 is the metallographic structure photo of X70 roll bending.

Embodiment

17.5mm X70 hot-rolled coil

Chemical ingredients (wt%)

Heat (batch) number	??C	??Si	??Mn	??P	??S	??Ni	??Cr	??Cu
									??09102960	??0.062	??0.2	??1.61	??0.008	??0.0014	??0.10	??0.24	??0.15
??09102963	??0.068	??0.2	??1.58	??0.01	??0.0011	??0.10	??0.24	??0.15
									??09203005	??0.069	??0.19	??1.56	??0.01	??0.0022	??0.10	??0.24	??0.15
??09203006	??0.063	??0.19	??1.6	??0.009	??0.0015	??0.10	??0.24	??0.16
									??09203007	??0.068	??0.21	??1.58	??0.01	??0.0011	??0.09	??0.23	??0.14
??09102964	??0.073	??0.2	??1.6	??0.01	??0.0011	??0.10	??0.24	??0.15
									??09202994	??0.070	??0.19	??1.56	??0.008	??0.0022	??0.10	??0.25	??0.16

Heat (batch) number	??C	??Si	??Mn	??P	??S	??Ni	??Cr	??Cu
									??09303205	??0.069	??0.19	??1.61	??0.01	??0.0025	??0.10	??0.24	??0.17
??09102989	??0.061	??0.21	??1.6	??0.012	??0.0011	??0.10	??0.24	??0.16
									??09102991	??0.062	??0.2	??1.58	??0.008	??0.0011	??0.11	??0.24	??0.16
	??Alt	??Als	??Ca	??Mo	??V	??B	??Nb	??Ti
									??09102960	??0.035	??0.035	??0.0034	??0.107	??0.028	??0.0003	??0.045	??0.013
??09102963	??0.036	??0.034	??0.0031	??0.104	??0.029	??0.00025	??0.047	??0.014
									??09203005	??0.032	??0.030	??0.0035	??0.104	??0.028	??0.00027	??0.044	??0.013
??09203006	??0.035	??0.034	??0.0034	??0.107	??0.028	??0.00023	??0.046	??0.013
									??09203007	??0.034	??0.033	??0.0028	??0.105	??0.028	??0.00026	??0.047	??0.013
??09102964	??0.036	??0.034	??0.003	??0.107	??0.029	??0.00022	??0.046	??0.014
									??09202994	??0.034	??0.031	??0.0032	??0.106	??0.028	??0.00024	??0.046	??0.014
??09303205	??0.043	??0.041	??0.0034	??0.102	??0.029	??0.00025	??0.045	??0.013
									??09102989	??0.036	??0.034	??0.0031	??0.103	??0.029	??0.0003	??0.046	??0.014
??09102991	??0.035	??0.025	??0.0035	??0.107	??0.028	??0.00021	??0.048	??0.014

Operational path

Raw material preparation → hot metal pretreatment → converter smelting → external refining → sheet billet continuous casting → slab reheat → controlled rolling → controlled chilling → laminar flow cools off → batches → checks, puts in storage

The steel rolling process main points

Slab heating temperature: 1150-1220 ℃; Roughing final temperature: 1020-1080 ℃;

Finish rolling temperature in :≤980 ℃; Finish rolling final temperature: 800 ± 30 ℃;

Coiling temperature :≤420 ℃; Finish rolling compression ratio: intermediate blank thickness/finish rolling exit thickness 〉=3.5.

Results of property

1) stretching of X70 hot-rolled coil, clod wash and hardness performance

2) X70 hot-rolled coil fracture toughness property

3) metallographic structure

Metallographic structure is an acicular ferrite structure, and contains the M/A constituent element of disperse.Specifically see accompanying drawing 2.

Claims (2)

1. an X 70 hot-rolled steel coil for pipeline steel is characterized in that, chemical ingredients is: carbon: 0.04-0.08wt%; Silicon: 0.10-0.30%; Manganese: 1.40wt%-1.75wt%; Niobium: 0.03-0.06wt%; Vanadium: 0.020-0.050wt%; Titanium: 0.010-0.020wt%; Molybdenum: 0.10-0.15wt%; Copper: 0.15-0.20wt%; Nickel: 0.10-0.15wt%; Cr:0.20-0.30wt%; Phosphorus :≤0.018wt%; Sulphur :≤0.003wt%; Nitrogen :≤0.006wt%; Boron: 0.0003-0.0005wt%; Hydrogen :≤0.0003wt%; Other is iron and trace impurity; And Nb+V+Ti:0.06-0.15wt%.

2. the manufacture method of the described X70 hot-rolled coil of claim 1, technology is: raw material preparation → hot metal pretreatment → converter smelting → external refining → sheet billet continuous casting → slab reheat → controlled rolling → controlled chilling → laminar flow cools off → batches → checks, puts in storage; It is characterized in that control steel rolling process parameter is as follows:

Heating temperature: 1140-1220 ℃;

Roughing final temperature: 980-1060 ℃;

Finish rolling final temperature: 800 ± 30 ℃;

Coiling temperature: 350 ℃-420 ℃; The finish rolling compression ratio: finishing stand adopts 6 frames rolling, intermediate blank thickness/finish rolling exit thickness 3.5-4.

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