CN101695466A - Pigment composition and use in cosmetic, food and pharmaceutical preparations - Google Patents

Pigment composition and use in cosmetic, food and pharmaceutical preparations Download PDF

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Publication number
CN101695466A
CN101695466A CN200910148890A CN200910148890A CN101695466A CN 101695466 A CN101695466 A CN 101695466A CN 200910148890 A CN200910148890 A CN 200910148890A CN 200910148890 A CN200910148890 A CN 200910148890A CN 101695466 A CN101695466 A CN 101695466A
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layer
sheet glass
tio
sio
component
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CN101695466B (en
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V·霍克斯坦
S·舍恩
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Merck Patent GmbH
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Merck Patent GmbH
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0024—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0024—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index
    • C09C1/003—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index comprising at least one light-absorbing layer
    • C09C1/0039—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index comprising at least one light-absorbing layer consisting of at least one coloured inorganic material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0051—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0051—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index
    • C09C1/0057—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer
    • C09C1/0066—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer consisting of at least one coloured inorganic material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0051—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index
    • C09C1/0057—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer
    • C09C1/0066—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer consisting of at least one coloured inorganic material
    • C09C1/0069—Sub-stoichiometric inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/10—Interference pigments characterized by the core material
    • C09C2200/1004—Interference pigments characterized by the core material the core comprising at least one inorganic oxide, e.g. Al2O3, TiO2 or SiO2
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/10—Interference pigments characterized by the core material
    • C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/10—Interference pigments characterized by the core material
    • C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/301—Thickness of the core

Abstract

The mixture comprises mixed pigments comprising at least two components; component A contains an effective pigment based on glass flakes, and component B contains a coloring agent and/or a filler in flake, needle, sphere, or crystal shape. The mixture is particularly used in cosmetic formulations, for product coloring in a food and medicament field, or as a coating agent of a product.

Description

Pigment composition and in the application of cosmetics, food and pharmaceutical preparations
The application is for dividing an application, and the applying date of its female case application is on March 26th, 2004, and application number is 200410045125.2, and denomination of invention is " pigment composition and in the application of cosmetics, food and pharmaceutical preparations ".
The present invention relates to the pigment composition formed by at least two kinds of components, component A comprises the effect pigment based on thin glass sheet, B component comprises lamellar, aciculiform, sphere or lenticular coloring agent and/or filler, with and in the application of cosmetic formulations and food, pharmaceutical preparations.
Coating and uncoated sheet glass are known, with reference to WO 97/46624, WO 03/006558 and WO 02/090448.For flake pigment, be difficult to make covering power and gloss to reach gratifying degree simultaneously usually.Therefore, for instance, the mica sheet or the titanium dioxide silicon chip that have one or more metal oxide thin coatings just can be distinguished by interference colours and strong gloss, but simultaneously, owing to have a transparent matrix, they also can by high transparency with thereby the relative low covering power that has distinguish.
Based on sheet glass effect pigment can distinguish by high glossiness, excitation and tinting strength, tinting power, thereby should be able to cause people's interest, particularly aspect cosmetics.
The object of the present invention is to provide effect pigment based on sheet glass, they have high relatively covering power, can well be mixed in various application systems, the optical property that does not influence system simultaneously fully is concrete as gloss and excitation, and perhaps effect is inessential.
Unexpectedly, had been found that a kind of pigment composition that does not have above-mentioned shortcoming now.Pigment composition of the present invention is made up of at least two kinds of components, and wherein component A comprises the effect pigment based on thin glass sheet, and B component comprises lamellar, aciculiform, sphere or lenticular coloring agent and/or filler.
One or more coloring agent mixtures of the sheet glass that applies can make the system of application produce the rainbow effect, and the effect of color is enhanced and reaches new color effects.In addition, this pigment composition can also by high glaze, the flash of light put the fruit and dermal sensation distinguish.
Therefore the present invention relates to a kind of pigment composition of being made up of at least two kinds of components, wherein component A comprises the effect pigment based on thin glass sheet, and B component comprises lamellar, aciculiform, sphere or lenticular coloring agent and/or filler.
The present invention relates to cosmetic formulations equally, for example comprise pigment composition of the present invention as makeup, muffin, talcum powder (loose powder), lipstick, distillate medicinal water, emulsion etc.This pigment composition also is suitable for colored coating painted and food and medicine, as the medical coating of tablet, coated tablet, gelatine capsule etc.
The sheet glass that applies can be so that ratio and coloring agent or filler mix arbitrarily.The ratio of component A and B component is preferably 95: 5 to 5: 95, and particularly 80: 20 to 20: 80, especially preferred 70: 30 to 30: 70.
Preferred effect pigment has following structure:
Sheet glass+TiO 2Layer
Sheet glass+SiO 2Layer+TiO 2Layer
Sheet glass+Fe 2O 3Layer
Sheet glass+SiO 2Layer+Fe 2O 3Layer
Sheet glass+Fe 3O 4Layer
Sheet glass+SiO 2Layer+Fe 3O 4Layer
Sheet glass+TiFe 2O 3Layer
Sheet glass+SiO 2Layer+TiFe 2O 3Layer
Sheet glass+Cr 2O 3Layer
Sheet glass+SiO 2Layer+Cr 2O 3Layer
Sheet glass+TiO 2Layer+Cr 2O 3Layer
Sheet glass+SiO 2Layer+TiO 2Layer+Cr 2O 3Layer
The protoxide of sheet glass+titanium
Sheet glass+SiO 2The protoxide of layer+titanium
Sheet glass+TiO 2Layer+Fe 2O 3Layer
Sheet glass+SiO 2Layer+TiO 2Layer+Fe 2O 3Layer
Sheet glass+TiO 2Layer+Berlin blue
Sheet glass+SiO 2Layer+TiO 2Layer+Prussian blue
Sheet glass+TiO 2Layer+carmine
Sheet glass+SiO 2Layer+TiO 2Layer+carmine
Sheet glass+TiO 2Layer+DC red 30
Sheet glass+SiO 2Layer+TiO 2Layer+DC red 30
Sheet glass+Fe 2O 3Layer+SiO 2Layer+Fe 2O 3Layer
Sheet glass+Fe 2O 3Layer+SiO 2Layer+TiO 2Layer
Sheet glass+TiO 2Layer+SiO 2Layer+Fe 2O 3Layer
Sheet glass+TiO 2Layer+SiO 2Layer+TiO 2/ Fe 2O 3Layer
Sheet glass+TiO 2/ Fe 2O 3Layer+SiO 2Layer+TiO 2/ Fe 2O 3Layer
Sheet glass+TiO 2Layer+SiO 2Layer+Cr 2O 3Layer
TiO 2Layer can be that rutile-type or anatase modification form.
Particularly preferably be and apply one deck SiO earlier 2Layer, and then apply the sheet glass of one or more layers metal-oxide and optional coating carmine, Prussian blue or organic dyestuff.Metal-oxide is preferably selected from TiO 2, the protoxide of titanium, Fe 2O 3, Fe 3O 4With their mixture.
The outer layer metal oxide skin(coating) can also adopt the metal semitransparent layer to replace.The metal that is applicable to this for example is chromium, titanium, molybdenum, tungsten, aluminum, copper, silver, gold and nickel.
Sheet glass thickness is μ m preferably≤1, particularly≤0.8 μ m, especially preferred≤0.6 μ m.
The sheet glass that applies be purchased, such as buying with trade (brand) name Ronastar by Merck KGaA company.
In order to obtain specific color effects.The granule of nanoscale size of segmentation can also be incorporated in the layer of high index of refraction or low-refraction.Verified suitable this purpose example is that granular size is the titanium dioxide or the carbon (white carbon black) of the segmentation of 10-250nm.These particulate light scattering properties can make gloss and covering power specifically be affected.
In order to improve light, weather and chemical stability or, can also on this effect pigment, to provide layer protective layer in order to improve the compatibility in different medium.Suitable back coating or post processing be silane, polysiloxanes, adsorptivity polysiloxanes, metallic soap, aminoacid, lecithin, fluorine component, polyethylene, collagen or the technology described in DE2215191, DE3151354, DE3235017 or DE3334598 for example.The material that adds only accounts for about 0.1-5% of pigment weight in addition, is preferably 0.5-3.0%.
The B component that is applicable to pigment composition of the present invention is that all lamellars well known to those skilled in the art, aciculiform, sphere and crystalline coloring agent or filler, particularly those particle sizes are 0.001-10 μ m, coloring agent or the filler of preferred 0.01-1 μ m.Pigment composition of the present invention preferably comprise adsorptivity pigment as coloring agent and lamellar or spherical powder as filler.B component preferably comprises coating or uncoated SiO 2Globule is with the SiO of one or more metal oxide-coated 2Globule is open, as EP0803550 A2.
Preferred pigment composition except component A, also contain especially comprise multi-layer pigments or coated interference pigment pearlescent pigment as coloring agent (B component).Used pearlescent pigment is based on flaky, the transparent or semitransparent substrate that comprises leaf silicate (phyllosilicates) for example natural or synthetic mica, Talcum, sericite, Kaolin or other silicate material, with colored or colourless metal-oxide such as TiO 2, the protoxide of titanium, oxynitriding titanium, Fe 2O 3, Fe 3O 4, SnO 2, Cr 2O 3, ZnO, CuO, NiO and other metal-oxide separately or be blended in monolayer or the continuous multilayer and apply.
Pearlescent pigment is open in as Deutsche Bundespatent and patent application 1467468,1959998,2009566,2214454,2215191,2244298,2313331,2522572,3137808,3137809,3151343,3151354,3151355,3211602,3235017 and P3842330, and be commercially available, as the trade (brand) name of the Merck KGaA Darmstadt Germany and/or the Rona U.S.
Figure G200910148890XD00041
With
Figure G200910148890XD00043
Particularly preferred color compositions comprises TiO 2/ Muscovitum, Fe 2O 3/ Muscovitum and/or TiO 2/ Fe 2O 3/ pigments, mica.
Further preferred the coating or uncoated BiOCI pigment, TiO 2-and/or Fe 2O 3The SiO of-coating 2Or Al 2O 3Sheet.With one kind of multiple metal-oxides to SiO 2The coating of sheet can be as the carrying out described at WO93/08237 (wet-chemical coating) or DE-A 19614637 (CVD method).
As disclosed multi-layer pigments in DE-A 19618563, DE-A 19618566, DE-A 19618569, DE-A 19707805, DE-A 19707806 and DE-A 19746067, be based on lamellar, transparent, colored or colourless substrate, this substrate is by Muscovitum (synthetic or natural), SiO 2Sheet, sheet glass, Al 2O 3Sheet or polymer sheet are formed, and its thickness is generally the 0.3-5 micron, particularly the 0.4-2.0 micron.Other two sizes are the 1-250 micron normally, and preferred 2-100 micron is the 5-40 micron especially.This multi-layer pigments is made up of the substrate that is coated with metal-oxide (two kinds) (substrate) at least.At substrate tablet Muscovitum, SiO 2Sheet, sheet glass or Al 2O 3The multiple coating of sheet is performed such, and has promptly formed the layer structure of alternately being made up of high index of refraction and low-index layer.This multi-layer pigments preferably contains 2,3,4,5,6 or 7 layers, particularly 3,4 or 5 layers.Suitable high refractive index metal oxide is titanium dioxide, zirconium oxide, zinc oxide, iron oxides, ferrum/titanium oxide (iron titanate) and/or chromated oxide, particularly TiO for example 2And/or Fe 2O 3Used low-refraction metal-oxide is SiO 2And Al 2O 3Yet, also can use MgF 2Or organic polymer (as acrylate) reaches this purpose.Substrate tablet can be with for example applying in the method described in WO 93/08237 (wet-chemical coating) or the DE-A-19614637 (CVD method).
Coated interference pigment is preferably based on Muscovitum, sheet glass or SiO 2Sheet also is coated with colour or colourless metallic oxide such as TiO 2, the protoxide of titanium, oxynitriding titanium, Fe 2O 3, Fe 3O 4, SnO 2, Cr 2O 3, ZnO, CuO, NiO and other metal-oxide pigment, these metal-oxides are separately or mix and be coated in monolayer or the continuous multilayer.
Mixture of the present invention also comprise based on glass effect pigment (=component A) and based on the mixture of the coated interference pigment (=B component) of glass.
The slice colouring agent that is fit to comprises pearlescent pigment, and particularly those are based on Muscovitum, SiO 2Sheet or Al 2O 3Sheet and only apply the pearlescent pigment of layer of metal oxide, metal effect pigments (Al sheet, bronze), optically variable pigments (OVPs), liquid crystal polymer pigment (LCPs) or holographic pigment.
Spherical coloring agent is particularly including TiO 2, painted SiO 2, CaSO 4, iron oxides, chromated oxide, white carbon black, organic color pigment, as anthraquinone pigment, quinacridone pigment, diketo-pyrrolo pyrrole pigments, phthalocyanine color, AZOpigments and xylylenimine pigment.This aciculiform pigment optimization is BiOCl, painted glass fibre, alpha-feooh, organic color pigment, as AZOpigments, blue PD56 (Ciba-Geigy), the azomethine copper complex CI yellow 129 of yellow 8GN (Ciba-Geigy), Irgalith of β-phthalocyanine Cl indigo plant 15.3, Cromophtal or the yellow 5GT (Ciba-Geigy) of Irgazine.
Simple and the easy operating of pigment composition of the present invention.This pigment composition can be sneaked into application system by simple stirring.Do not need pigment is carried out complicated grinding and dispersion.
Pigment composition of the present invention can be used as food coloring pigment, is used for handling food, such as a large amount of painted or as a kind of coating; Also can be used for medication coat, such as the tablet and the tablet that apply; Perhaps be used for cosmetic formulations, such as frost before lip pomade, lip gloss, eyeliner, eye shadow, carmine, sunscreen cream, the solarization and solarization back frost (pre-sun and after-sun compositions), cosmetics, body and function distillate medicinal water (body lotions), bath gel (ath gels), soap, bath salt, toothpaste, hair jelly, mascara, nial polish, muffin, shampoo, talcum powder (loose powder) and gel etc.This pigment composition want the concentration in the painted application system to be generally 0.1-70% weight based on the total solid content meter of this system, preferably 0.1-50% weight, particularly 1.0-10% weight.This concentration depends on specific purposes usually, can be up to 100% in talcum powder.
Pigment composition of the present invention can also perform well in ornamental and nursing property cosmetics.Its working concentration and coated glass sheet and B component particularly natural or synthetic organic and inorganic coloring pigment and dyestuff, for example chromated oxide, ultramarine, spherical SiO 2Or TiO 2The mixed proportion of pigment depends on working medium and the effect that will reach.
The sheet glass that applies can with other pigment or dyestuff with any mixed, preferred ratio is 1: 10-10: 1.0.01% weight of this working concentration scope from shampoo is until 70% weight in the muffin.At coated glass sheet and Ball-type packing such as SiO 2Mixture in, the concentration in the preparation can be 0.01-70% weight.Cosmetic product such as nial polish, lip pomade, muffin, shampoo, talcum powder and gel can be distinguished by interesting luster effect.The nial polish that utilizes pigment composition of the present invention is significantly improved than the flash effect of common nial polish.
Pigment composition of the present invention can also further mix with the filler that is purchased.Described filler is such as oxide or hydroxide, BiOCl, barium sulfate, calcium sulfate, calcium carbonate, magnesium carbonate, carbon and their physics or the Chemical composition that of natural and synthetic mica, bead or glass dust, nylon powder, melmac, Talcum, glass, Kaolin, aluminum, magnesium, calcium or zinc pure or that fill.
For the grain shape of filler without limits.As required, it can be such as lamellar, sphere, aciculiform, crystal form or amorphism.
Pigment of the present invention can certainly combine with various types of cosmetic materials or adjuvant in preparation.They comprise oil, fat, wax, film former, surfactant, antioxidant such as vitamin C or vitamin E, stabilizing agent, abnormal smells from the patient reinforcing agent, silicone oil, emulsifying agent, solvent such as ethanol, ethyl acetate or butyl acetate, antiseptic and can determine the adjuvant of serviceability usually, such as thickening agent and rheologic additive, as bentonite, Strese Hofmann's hectorite., silicon dioxide, calcium silicates, gelatin, high molecular carbohydrate and/or surface activity auxiliary agent etc.
The preparation that comprises pigment composition of the present invention can be lipophilic, hydrophilic or hydrophobic type.For containing the heterogeneous of discontinuous water and nonaqueous phase, pigment composition of the present invention can only appear at biphase one mutually in, also can be distributed in biphase in.
The pH value of preparation can be between 1-14, preferably 2-11, especially preferably 5-8.
The concentration of pigment composition of the present invention in preparation without limits.Depend primarily on application, can be at 0.001 (drip washing product such as bath gel) with between 100% (such as the gloss specially good effect product of special-purpose).
Pigment composition of the present invention can also further combine with the cosmetic active component.Suitable active component is such as being anthelmintic, inorganic UV light filter such as TiO 2, UV A/BC protectiveness light filter (such as OMC, B3 and MBC); and anti-aging active component, vitamin and the derivant thereof of capsule form (as vitamin A, C, E etc.), self-tanning agent (as DHA, Erythrulose) and more cosmetic active component such as bisabolol, LPO, VTA, ectoin, emblic (emblica), allantoin, bioflavonoid and derivant thereof.
The consumption of organic UV light filter in cosmetic formulations is generally 0.5-10% weight, is preferably 1-8%, and the consumption of inorganic light filter is 0.1-30%.
Preparation of the present invention can also comprise more skin care commonly used or skin care active component in addition.They can be any active components well known by persons skilled in the art in principle.
Particularly preferred active component is close pyridine carboxylic acid and/or aryl oxime.
For the application of cosmetics, what will mention especially is to use ectoin and ectoin derivant to come the skin of aging, drying or irriate is nursed.Just as what describe among European patent application EP-A-0671161, particularly this ectoin and hydroxyectoin are used for cosmetic formulations, as powder, soap, the cleaning product that contains surfactant, lipstick, carmine, cosmetics, nursing frost and sunscreen cream.
The application form of the cosmetic formulations that can mention is such as solution, suspension, emulsion, PIT emulsion, paste, ointment, gel, frost, distillate medicinal water, powder, soap, the cleaning agent that contains surfactant, oil preparation, aerosol and spray.Other application mode also has rod, shampoo and body wash formulations.The conventional excipients of any needs, adjuvant and more active component if desired can join in the preparation.
Ointment, paste, frost and gel can comprise excipient commonly used, as the mixture of animal and plant fat, wax, paraffin, starch, tragacanth, cellulose derivative, Polyethylene Glycol, polysiloxanes, bentonite, silicon dioxide, Talcum and zinc oxide or these materials.
Powder and spray can comprise excipient commonly used such as lactose, Talcum, silicon dioxide, aluminium hydroxide, calcium silicates and polyamide powder or their mixture.Spray can also comprise promoter commonly used such as CFC, propane/butane or dimethyl ether in addition.
Solution and emulsion can comprise excipient commonly used such as solvent, cause solvent (solubilisers) and emulsifying agent, mixture as water, ethanol, isopropyl alcohol, ethyl carbonate, ethyl acetate, benzyl alcohol, benzoic acid phenyl ester, propylene glycol, 1,3 butylene glycol, oil, particularly Oleum Gossypii semen, Oleum Arachidis hypogaeae semen, Semen Tritici aestivi oil (wheatgerm oil), olive oil, Oleum Ricini and Oleum sesami, fatty glyceride, Polyethylene Glycol and fatty acid esters of sorbitan or above-mentioned substance.
Suspension can comprise excipient commonly used such as liquid diluent such as water, ethanol or propylene glycol, the mixture of suspending agent such as ethoxylation isooctadecane alcohol, polyoxyethylene sorbitan ester and Sorbitan ethoxylate, microcrystalline Cellulose, algeldrate, bentonite, agar and tragacanth or above-mentioned substance.
Soap can comprise excipient commonly used such as fatty acid alkali metal salt, fatty-acid monoester salt, fatty acid protein matter hydrolyzate, isethionate, lanoline, aliphatic alcohol, vegetable oil, plant extraction liquid, glycerol, sugar, or the mixture of above-mentioned substance.
The cleaning product that contains surfactant can comprise usual excipients, as the mixture of salt, aliphatic alcohol ether sulfate, sulfosuccinic acid monoesters, fatty acid protein matter hydrolyzate, isethionate, imidazoline salt derivant, N-methyltaurine ester, sarcosinate, fatty acid amide ether sulfate, alkyl amido betanin (alkylamidobetaines), aliphatic alcohol, fatty glyceride, fatty diglycollic amide, plant and artificial oil, lanolin derivative, ethoxylated glycerol fatty acid ester or the above-mentioned substance of aliphatic alcohol sulfate.
Facial and health can comprise usual excipients with oil, such as artificial oil such as fatty acid ester, aliphatic alcohol, silicone oil, the extracting solution of natural oil such as vegetable oil and oil plant, paraffin oil, lanolin oil, or the mixture of above-mentioned substance.
Cosmetic formulations can exist with various forms.Such as they can be the microemulsion of solution, anhydrous formulation, emulsion or Water-In-Oil (W/O) or oil-in-water (O/W) type, as complex emulsions, gel, solid bar, ointment or the aerosol of W/O/W (W/O/W) type.Also can easily ectoins be made capsular form, as wrap into collagen matrix and other conventional bag capsule material such as cellulose capsule, wrap into gelatin, wax shape matrix or ester matter capsule.Special at the wax shape matrix described in the DE-A4308282, confirmed it is very favorable.Preferred emulsion.Preferred especially O/W emulsion.Emulsion, W/O emulsion and O/W emulsion all can obtain by traditional method.
More embodiment is based on the oiliness distillate medicinal water of natural or artificial oil and wax, lanoline, fatty acid ester, particularly fatty acid triglycercide, or based on the oil-pure distillate medicinal water of lower alcohol such as ethanol, glycerol, propylene glycol and/or polyhydric alcohol (as glycerol) and oily, wax and fatty acid ester such as fatty acid triglycercide.
Solid bar is made up of natural or synthetic wax and oil, aliphatic alcohol, fatty acid, fatty acid ester, lanoline and other fatty substances.
If preparation is made into aerosol, can use traditional promoter so usually, as alkane, fluoric ether and chlorofluoro-alkane.
This cosmetic formulations can also be used to protecting hair to avoid the injury of photochemical action, prevents the hair variable color, fades or be subjected to mechanical injury.In this case, the appropriate formulation form is rinse shampoo, distillate medicinal water, gel or emulsion, and said preparation can be used for before and after hair washing front and back, dyeing or the decolouring or the hair-waving front and back.Equally also can select the preparation of distillate medicinal water or gel form to come, dye method or blow boiling hotly, perhaps select to be used for permanent hair-waving compositions, coloring agent or the depigmenting agent of the hair dye form of hair with the preparation of distillate medicinal water or gel form to hair fixing or processing.Preparation with light-protection energy can contain auxiliary agent, as surfactant, thickening agent, polymer, softening agent, antiseptic, foam stabiliser, electrolyte, organic solvent, silicone derivative, oil, wax, anti-fat agent, the dyestuff that makes compositions self or hair coloring and/or pigment or other hair nursing component commonly used.
Medicine and food also can be painted by adding pigment composition, preferred pigment composition is made up of pigment and coloring agent, as natural or be equal to natural dyestuff, described mixture blending ratio on demand mixes with color-tinted product, its amount is preferably 0.01-10% weight for 0.005-15% weight.
Coating on the particularly various food of the suitable pigmented product that can mention, especially painted sugar and the coating of lac (contain alcohol or aqueous), oil and wax coating, the Radix Acaciae senegalis coating, sugar product is mixed or be applied to cellulose level coating (as the HPMC=hydroxypropyl emthylcellulose), the cake ornament, compressed foods, coated tablets, chewing gum, gum navel stores, the soft sweet product, the kernel syrupy product, filled compositions, cocoa and fatty glaze, chocolate and the product that contains chocolate, ice cream, cereals, fast food, application composition, the cake glaze, dispersive sugared ornament; Superfine product(nonpareils), fruit jelly and gelatin product, confection, Radix Glycyrrhizae, sugar-coat, sugar silk (candyfloss), fat, sugar and cheese compositions, blancmange, dessert, pie glaze, freeze fruit juice, soda and soda pop, contain the beverage of stabilization additives such as carboxymethyl cellulose, as the acidify of quark, yoghourt, cheese, cheese crust, sausage clothing etc. and non-acidizing milk product or the like.
Further main application fields is medicine and OTC aspect, is used for painted or coated tablets, gelatine capsule, coated tablets, ointment, antitussive etc.By combining with traditional coating such as polymethacrylates and cellulose level such as HPMC, this pigment composition can be used for the painted of variety of way.
The invention still further relates to the preparation that comprises pigment composition of the present invention.
The following examples are used to illustrate the present invention, but do not limit the present invention.
Embodiment
The embodiment 1:-cream base that glistens
Phase A
Figure G200910148890XD00091
Phase B
Figure G200910148890XD00101
Phase C
Figure G200910148890XD00102
Phase D
Raw material Raw material sources ??INCI ??[％]
Oleum sesami 200529 ??Fragrance?Resource ??Parfum ??0.20
??Euxyl?K400 ??Schülke?&?Mayr?GmbH Phenyl phenol, methyl dibromo glutaronitrile ??0.20
Preparation:
All components at about 75 ℃ of fusing phase C stirs, simultaneously up to whole fusings.At first the cold water of phase B is incorporated among the Blanose, and makes its homogenize, be distributed to then and also make its homogenize among the Veegum once more with Turrax.Be heated to 75 ℃, simultaneously other component of stirring and dissolving.Stir the component of phase A.Under 75 ℃ of stirring states, add phase C, make its homogenize 2 minutes.Under agitation mixture is cooled to 40 ℃, adds phase D.Stir simultaneously, further cool to room temperature, and adjusting pH value is 6.0-6.5 (such as using citric acid solution).
Embodiment 2: bath gel
Phase A
Figure G200910148890XD00111
Phase B
Raw material Raw material sources ??INCI ??[％]
??Plantacare?2000?UP ??Cognis?GmbH The decyl glucosides ??20.00
??Texapon?ASV?50 ??Cognis?GmbH Lauryl polyoxyethylene groups ether sodium sulfate, lauryl polyoxyethylene groups ether 8-sodium sulfate, lauryl polyoxyethylene groups ether magnesium sulfate, lauryl polyoxyethylene groups ether 8-magnesium sulfate, oil base polyoxyethylene groups ether sodium sulfate, oil base polyoxyethylene groups ether magnesium sulfate ??3.60
??Bronidox?L ??Cognis?GmbH Propylene glycol, 5-bromo-5-nitro-1,3-diox ??0.20
Oleum sesami Everest 79658 SB ??Haarmann?&?Reimer??GmbH ??Parfum ??0.05
FD ﹠ CBlue No.1 1% aqueous solution ??BASFAG Water preparation (water), CI 42090 (FD ﹠ C Blue No.1) ??0.20
Phase C
Figure G200910148890XD00121
Preparation:
For phase A, stir in the pigment entry, stir down and in Keltrol T, slowly disperse, and continue to stir up to dissolving.Phase B is added in succession and slowly stirs up to all components homodisperse with C mutually.Regulating pH value at last is 6.0-6.4.
Embodiment 3: eyeliner
Phase A
Figure G200910148890XD00122
Figure G200910148890XD00131
Phase B
Figure G200910148890XD00132
Preparation:
With pearlescent pigment with
Figure G200910148890XD00133
Be dispersed in the water of phase A, reducing viscosity, and under agitation be distributed among the Carbopol with several citric acid acidifys.After the dissolving, slowly stirring joins among the dissolved in advance phase B fully, and re-adjustment pH is 7.0-7.5.
Embodiment 4: eye shadow
Phase A
Figure G200910148890XD00141
Phase B
Figure G200910148890XD00142
Preparation:
Each component of merging, pre-mixed phase A.The phase B that under agitation will melt is added drop-wise in the mixture of powders then.With the compacting under the 40-50 crust of this powder.
Embodiment 5: eye shadow cream
Phase A
Figure G200910148890XD00143
Phase B
Figure G200910148890XD00151
Preparation:
With pearlescent pigment with
Figure G200910148890XD00152
Be dispersed in the water of phase A, reducing viscosity, and under agitation be distributed among the Carbopol with several citric acid acidifys.After the dissolving, slowly stirring joins among the dissolved in advance phase B fully.
Embodiment 6: eye shadow
Phase A
Figure G200910148890XD00153
Phase B:
Figure G200910148890XD00161
Preparation:
Each component of merging, pre-mixed phase A.The phase B that under agitation will melt is added drop-wise in the mixture of powders then.With the compacting under the 40-50 crust of this powder.
Embodiment 7:-nial polish
Figure G200910148890XD00162
Preparation:
Weigh up pigment and nial polish base material and painted dispersion, good with the scraper manual mixing, stirred 10 minutes with 1000rpm then.
Embodiment 8: lip gloss
Phase A
Phase B:
Figure G200910148890XD00181
Phase C
Raw material Raw material sources ??INCI ??[％]
?Fragrance?Tendresse?#75418C ?Haarmann?&?Reimer?GmbH ??Parfum ??0.10
Preparation:
The all components to 80 ℃ (except the Foral 85-E) of heating phase B.Stir and add Foral 85-E.Then phase A is joined among the fused phase B with C mutually.Uniform melt is poured in the casting die that is heated to 50 ℃ in advance.
Embodiment 9: shampoo
Phase A
Figure G200910148890XD00182
Phase B:
Phase C:
Raw material Raw material sources ??INCI ??[％]
??Plantacare?2000?UP ?Cognis?GmbH Decyl sugar is sweet ??20.00
??Texapon?ASV ?Cognis?GmbH Oil base polyoxyethylene groups ether magnesium sulfate, oil base polyoxyethylene groups ether sodium sulfate, lauryl polyoxyethylene groups ether 8-magnesium sulfate, lauryl polyoxyethylene groups ether 8-sodium sulfate, lauryl polyoxyethylene groups ether magnesium sulfate, lauryl polyoxyethylene groups ether sodium sulfate ??8.00
??Bronidox?L ?Cognis?GmbH Propylene glycol, 5-bromo-5-nitro-1,3-diox ??0.20
Oleum sesami Everest 79658 SB ?Haarmann?&?Reimer?GmbH ??Parfum ??0.05
Preparation:
For phase A, pigment is stirred in the entry., slowly be dispensed into then among the Carbopol to reduce viscosity with several citric acids (10%) acidify, stir simultaneously.After dissolving fully, slowly add phase B.And then add the component of phase C continuously.
Embodiment 10: twinkler powder (Shimmering body powder)
Phase A
Figure G200910148890XD00192
Phase B:
Figure G200910148890XD00201
Phase C
Figure G200910148890XD00202
Preparation:
Weigh up all components of phase B together, uniform mixing in blender.Add phase C then, further mix, then add phase A and brief the grinding, up to the pearlescent pigment uniform distribution.
Embodiment 11: twinkler frost (Sparkling body cream) (O/W)
Phase A
Figure G200910148890XD00211
Phase B
Figure G200910148890XD00212
Phase C
Figure G200910148890XD00213
Figure G200910148890XD00221
Phase D
Figure G200910148890XD00222
Phase E
Raw material Raw material sources ??INCI ??[％]
Oleum sesami 72979 ??Haarmann?&?Reimer??GmbH ??Parfum ??0.10
Preparation:
Pearlescent pigment is distributed in the water of phase A.If desired, with several citric acid acidifys to reduce viscosity.Dispersed with stirring after dissolving fully, slowly is stirred among the dissolved in advance phase B in Carbopol.Phase A/B is heated to 80 ℃ with C mutually, phase C is stirred among the phase A/B, with D uniform mixing mutually, neutralization, cooling are stirred simultaneously again.Add Oleum sesami at 40 ℃, be cooled to room temperature and stirring.
Embodiment 12: lip gloss
Phase A
Phase B
Figure G200910148890XD00231
Preparation:
Weigh up all components of phase B, be heated to 70 ℃ and stirring, up to forming a kind of uniform mixture.Add pigment then, and stir the mixture once more.Then with homogeneous mixture 50-60 ℃ of packing.
Embodiment 12: Margarita soap (pearlescent soap)
Phase A
Figure G200910148890XD00232
Phase B
Raw material Raw material sources ??INCI ??[％]
Transparent soap base material (plant) ??Dreiring-Seifen?seit??1771 Sodium palmitate, water, coconut oil sodium, glycerol, propylene glycol, sorbitol, sodium chloride, sodium hydroxide, EDTA tetrasodium salt, etidronic acid tetrasodium salt ??95.00
Raw material Raw material sources ??INCI ??[％]
Take off fossil water Water preparation (water) ??3.50
Aromatic oil Soft touch50-40 ??Cognis?GmbH ??PARFUM ??1.00
Preparation:
The component of all phase B is mixed three times with the screen cloth of soap extruder by a 0.2mm aperture, no longer directly is transformed into granule by screen cloth then.Subsequently, add phase A, and simply mix with B mutually.The soap composition that obtains is extruded on the soap production line once more, extrudes by a broken plate (breakerplate) (approximately 2.5mm), is cut into certain-length.
Embodiment 13: the Margarita soap
Phase A
Figure G200910148890XD00241
Phase B:
Raw material Raw material sources INCI ??[％]
??Prisavon?1984 ??Uniqema Sodium palmitate, Petiolus Trachycarpi sodium nucleinate, water preparation (water), glycerol, sorbitol, Palmic acid, Petiolus Trachycarpi nucleic acid, EDTA tetrasodium salt, etidronic acid tetrasodium salt ??98.50
Preparation:
Weigh up the soap base material and transfer in the mixer.In same container, take by weighing spice and pearlescent pigment.Then they are carried out pre-dispersed to avoid producing dust, the soap bar that the while, acquisition evenly applied in pre-composition.Incorporation time is approximately 5 minutes.Then the component that obtains is transferred to the feed shaft of grinder, carries out purification step 3 times.The uniform soap composition that will obtain then is transformed into bar-shaped soap.In this process, the temperature of soap composition need reach 45 ℃, to obtain maximum pearl effect.

Claims (12)

1. compositions, it comprises:
Component A, this component A comprises the effect pigment based on sheet glass, and the layer thickness of described sheet glass≤1 μ m and described effect pigment have following layer structure:
Sheet glass+TiO 2Layer
Sheet glass+SiO 2Layer+TiO 2Layer
Sheet glass+Fe 2O 3Layer
Sheet glass+SiO 2Layer+Fe 2O 3Layer
Sheet glass+Fe 3O 4Layer
Sheet glass+SiO 2Layer+Fe 3O 4Layer
Sheet glass+TiFe 2O 3Layer
Sheet glass+SiO 2Layer+TiFe 2O 3Layer
Sheet glass+Cr 2O 3Layer
Sheet glass+SiO 2Layer+Cr 2O 3Layer
Sheet glass+TiO 2Layer+Cr 2O 3Layer
Sheet glass+SiO 2Layer+TiO 2Layer+Cr 2O 3Layer
The protoxide of sheet glass+titanium
Sheet glass+SiO 2The protoxide of layer+titanium
Sheet glass+TiO 2Layer+Fe 2O 3Layer
Sheet glass+SiO 2Layer+TiO 2Layer+Fe 2O 3Layer
Sheet glass+TiO 2Layer+Berlin blue
Sheet glass+SiO 2Layer+TiO 2Layer+Prussian blue
Sheet glass+TiO 2Layer+carmine
Sheet glass+SiO 2Layer+TiO 2Layer+carmine
Sheet glass+TiO 2Layer+DC red 30
Sheet glass+SiO 2Layer+TiO 2Layer+DC red 30
TiO wherein 2Layer is that rutile-type or anatase modification form;
B component, this B component comprise organic and inorganic lamellar, aciculiform, sphere or lenticular coloring agent and/or filler; With
The cosmetic active component.
2. according to the compositions of claim 1, wherein the coloring agent of B component is pearlescent pigment, multi-layer pigments and coated interference pigment.
3. according to the compositions of claim 1 or 2, the layer thickness of the sheet glass of the effect pigment of component A≤0.6 μ m wherein.
4. according to the compositions of claim 1 or 2, also be included in additive commonly used in the cosmetics.
5. according to the compositions of claim 1 or 2, wherein component A and B component are 95 with ratio: 5-5: 95 mix.
6. according to the compositions of claim 1 or 2, wherein said cosmetic active component is anti-aging active component, vitamin, self-tanning agent, bisabolol, LPO, VTA, ectoin, hydroxyectoin, emblic, allantoin or the bioflavonoid of anthelmintic, inorganic UV light filter and capsule form.
7. according to the compositions of claim 1 or 2, wherein said cosmetic active component is ectoin or hydroxyectoin.
8. according to the compositions of claim 1 or 2, wherein B component is to be selected from TiO 2, painted SiO 2, CaSO 4, iron oxides, chromated oxide and sooty spherical coloring agent or be selected from the organic color pigment of anthraquinone pigment, quinacridone pigment, diketo-pyrrolo pyrrole pigments, phthalocyanine color, AZOpigments and xylylenimine pigment.
9. according to the compositions of claim 1 or 2, its form is frost and solarization back frost, cosmetics, body and function distillate medicinal water, bath gel, soap, bath salt, toothpaste, hair jelly, mascara, nial polish, muffin, shampoo, talcum powder, gel, the cleaning agent that contains surfactant or a nursing frost before lip pomade, lip gloss, eyeliner, eye shadow, carmine, sunscreen cream, the solarization.
10. according to the compositions of claim 1 or 2, also comprise and be selected from following cosmetic material or adjuvant: oil, fat, wax, film former, surfactant, antioxidant such as vitamin C or vitamin E, stabilizing agent, abnormal smells from the patient reinforcing agent, silicone oil, emulsifying agent, solvent, antiseptic, thickening agent, rheologic additive, as bentonite, Strese Hofmann's hectorite., silicon dioxide, calcium silicates, gelatin, high molecular carbohydrate and surface activity auxiliary agent.
11. according to the compositions of claim 1 or 2, wherein said cosmetic active composition activity component is pyrimidine carboxylic or aryl oxime.
12. according to the compositions of claim 1 or 2, its form is solution, suspension, emulsion, PIT emulsion, paste, ointment, gel, frost, distillate medicinal water, powder, soap, the cleaning agent that contains surfactant, oil preparation, aerosol, spray, rod, shampoo or body wash formulations.
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