CN101691510A - Novel compound gasoline antiknock agent - Google Patents

Novel compound gasoline antiknock agent Download PDF

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Publication number
CN101691510A
CN101691510A CN200910019448A CN200910019448A CN101691510A CN 101691510 A CN101691510 A CN 101691510A CN 200910019448 A CN200910019448 A CN 200910019448A CN 200910019448 A CN200910019448 A CN 200910019448A CN 101691510 A CN101691510 A CN 101691510A
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Prior art keywords
gasoline
novel compound
ferrocene
antiknock agent
tert
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CN200910019448A
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CN101691510B (en
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张成如
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SHANDONG TAIDE NEW ENERGY CO Ltd
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Jinan Development Zone Xinghuo Technology Research Institute
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Abstract

The invention discloses a novel compound gasoline antiknock agent comprising the following raw materials in weight ratio: 0.25-0.75% of ferrocene, 2.0-5.5% of tert-butyl acetate, 10-15% of diphenyl benzyl phosphate, 0.30-0.70% of 2,6-di-tert-butyl-p-cresol, 5-13% of calcium petroleum sulfonate with middle based value, 0.04-0.08% of N,N'- bis(salicylidene)-propane diamine, 2-6% of polyisobutylene butanedioic acid pentaerythritol ester and the balance methylbenezene. The novel compound gasoline antiknock agent of the invention can not only obviously improve the octane number of the gasoline and improve combustion performance of the gasoline, but also effectively remove the combustion residues and reduce the exhaust emission, thus having good application prospect.

Description

A kind of novel compound gasoline antiknock agent
Technical field
The present invention relates to a kind of gasoline dope, relate in particular to a kind of novel compound gasoline antiknock agent, belong to field of fuel additives.
Background technology
No lead antiknock compound commonly used at present has methyl cyclopentadiene three carboxyl manganese (being called for short MMT), methyl tertiary butyl ether (being called for short MTBE), ferrocene, tert amyl methyl ether(TAME) (being called for short TAME), the trimethyl carbinol (being called for short TBA), methyl alcohol, ethanol etc.MTBE generally uses in worldwide as gasoline dope, it can not only effectively improve gasoline octane rating, and can also improve automotive performance, reduces content in the exhaust, reduce the gasoline production cost simultaneously, but its use pollutes to water resources easily but.Ferrocene also is uprising dose of the more white gasoline of research at present, but the ferric oxide that gasoline and ferrocene burning back produce easily is deposited on the part of engine, particularly is deposited on the petrolic sparking plug or on the petrolic portfire.Methyl alcohol, the alcoholic acid octane value is very high, nor need other to make cosolvent than macromolecular alcohol, can make the processed oil octane value improve 2 ~ 3 units, but methyl alcohol and alcoholic acid cost are higher, make their use be subjected to certain restriction, simultaneously when gasoline is moisture, can be separated, and methyl alcohol and alcoholic acid vapour pressure height, use this improving agent to environmental protection and economic unfavorable.
Technology contents
The present invention is for solving the deficiency of present gasoline antiknock, a kind of octane value that not only can significantly improve gasoline is provided, improved the gasoline combustion performance, and can effectively remove combustion residue, reduce the novel compound gasoline antiknock agent of exhaust gas emission.
For achieving the above object, compound gasoline antiknock agent of the present invention is made up of the following weight proportion raw material:
Ferrocene 0.25%-0.75%
Tert.-butyl acetate 2.0%-5.5%
Phosphate toluene diphenyl ester 10%-15%
2,6 ditertiary butyl p cresol 0.30%-0.70%
Middle base number calcium mahogany sulfonate 5%-13%
N, the inferior bigcatkin willow propylene diamine of N '-two 0.04%-0.08%
Polyisobutene Succinic Acid pentaerythritol ester 2%-6%
The toluene surplus.
For making novel compound gasoline antiknock agent of the present invention reach best result of use, raw material preferred weight proportioning of the present invention is:
Ferrocene 0.55%
Tert.-butyl acetate 3.0%
Phosphate toluene diphenyl ester 13%
2,6 ditertiary butyl p cresol 0.45%
Middle base number calcium mahogany sulfonate 10%
N, the inferior bigcatkin willow propylene diamine 0.06% of N '-two
Polyisobutene Succinic Acid pentaerythritol ester 5%
The toluene surplus.
Taking by weighing above desired raw material normal temperature and pressure mixes and gets final product.
The ferrocene that uses among the present invention has the good capability of antidetonance, but the temperature of the gentle in-cylinder combustion of fusing point of the products of combustion ferric oxide of ferrocene is close, ferric oxide can be deposited on the part of engine when room temperature like this, particularly be deposited on the petrolic sparking plug, influence the startup of engine.More seriously can cause the wearing and tearing of engine, the present invention has well solved this problem, kept the good capability of antidetonance of ferrocene simultaneously, detergent-dispersant additive polyisobutene Succinic Acid pentaerythritol ester among the present invention, can effectively remove combustion residue, the cleaning that has kept fuel system, the sediment that forms in the dispersion oil product has reduced the loss of engine and the probability that breaks down; Used oxidation inhibitor 2,6-di-t-butyl-p-cresol can delay the oxidation of oil product, has reduced colloid and heavy matter, has improved the storing and transporting security and the stability of gasoline, the accumulating phase of having improved gasoline; Base number calcium mahogany sulfonate (T in the smoke suppressor that adds among the present invention 102), can reduce exhaust of some harmful pollutants, effectively reduced pollution to environment, to preserve the ecological environment and the society Sustainable development have positive effect; Added metal passivator N, N`-two inferior bigcatkin willow propylene diamine (T 1201) and metal corrosion inhibitor phosphate toluene diphenyl ester (CDP), avoided fuel oil in combustion processes, the formaldehyde of generation, organic acids such as formic acid have prolonged the work-ing life of automobile and engine to the corrosion of engine and trolley part.
The fine integrated outstanding capability of antidetonance of ferrocene of additive of the present invention; simultaneously under the synergy of promoter additives such as detergent-dispersant additive; can remove the combustion residue of gasoline and ferrocene; effectively guaranteed the combustion-supporting property of antiknock of ferrocene; the burning and the accumulating stability of gasoline have been strengthened; to the playing a very good protection of engine, prolonged the work-ing life of engine simultaneously, had a good application prospect.
Embodiment
Embodiment 1
With the additive total mass is benchmark, gets ferrocene 0.25%, tert.-butyl acetate 2.0%, phosphate toluene diphenyl ester 10%, 2,6-di-t-butyl-p-cresol 0.35%, middle base number calcium mahogany sulfonate (T 102) 5%, N, N`-two inferior bigcatkin willow propylene diamine 0.05%, polyisobutene Succinic Acid pentaerythritol ester 2%, join mix under the normal temperature and pressure in 80.35% the toluene a kind of novel compound gasoline antiknock agent of the present invention.
Embodiment 2
With the additive total mass is benchmark, gets ferrocene 0.55%, tert.-butyl acetate 3.0%, phosphate toluene diphenyl ester 13%, 2,6-di-t-butyl-p-cresol 0.45%, middle base number calcium mahogany sulfonate (T 102) 10%, N, N`-two inferior bigcatkin willow propylene diamine 0.06%, polyisobutene Succinic Acid pentaerythritol ester 5%, join mix under the normal temperature and pressure in 67.94% the toluene a kind of novel compound gasoline antiknock agent of the present invention.
Embodiment 3
With the additive total mass is benchmark, gets ferrocene 0.75%, tert.-butyl acetate 5.5%, phosphate toluene diphenyl ester 15%, 2,6-di-t-butyl-p-cresol 0.7%, middle base number calcium mahogany sulfonate (T 102) 13%, N, N`-two inferior bigcatkin willow propylene diamine 0.07%, polyisobutene Succinic Acid pentaerythritol ester 6%, join mix under the normal temperature and pressure in 58.98% the toluene a kind of novel compound gasoline antiknock agent of the present invention.
With gasoline weight is benchmark, the addition according to 0.5% the compound octane promoter of the embodiment of the invention 2 is joined in the gasoline and with common commercially available quality of gasoline index contrast, as table 1:
Table 1: use regular gasoline, contain the quality of gasoline index contrast of additive of the present invention
Figure G2009100194487D0000031
The engine that uses DongFeng Automobile Co., Ltd to produce, regular gasoline, the gasoline that contains additive of the present invention have been carried out the test of engine exhaust emission, testing method adopts idling to measure, find to use the gasoline of additive of the present invention to reduce 20%-30% than the quantity discharged of regular gasoline tail gas HC, CO, burning back line clear does not have residue substantially simultaneously.

Claims (2)

1. novel compound gasoline antiknock agent is characterized in that it is made up of the following weight proportion raw material:
Ferrocene 0.25%-0.75%
Tert.-butyl acetate 2.0%-5.5%
Phosphate toluene diphenyl ester 10%-15%
2,6 ditertiary butyl p cresol 0.30%-0.70%
Middle base number calcium mahogany sulfonate 5%-13%
N, the inferior bigcatkin willow propylene diamine of N '-two 0.04%-0.08%
Polyisobutene Succinic Acid pentaerythritol ester 2%-6%
The toluene surplus.
2. compound gasoline antiknock agent according to claim 1 is characterized in that described raw material weight proportioning is:
Ferrocene 0.55%
Tert.-butyl acetate 3.0%
Phosphate toluene diphenyl ester 13%
2,6 ditertiary butyl p cresol 0.45%
Middle base number calcium mahogany sulfonate 10%
N, the inferior bigcatkin willow propylene diamine 0.06% of N '-two
Polyisobutene Succinic Acid pentaerythritol ester 5%
The toluene surplus.
CN 200910019448 2009-10-20 2009-10-20 Novel compound gasoline antiknock agent Active CN101691510B (en)

Priority Applications (1)

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CN 200910019448 CN101691510B (en) 2009-10-20 2009-10-20 Novel compound gasoline antiknock agent

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CN101691510B CN101691510B (en) 2012-07-04

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212401A (en) * 2011-05-10 2011-10-12 湖南未名创林生物能源有限公司 Alcohol-based fuel composite addition agent for engine and preparation method thereof
CN102827666A (en) * 2012-09-20 2012-12-19 赵冠军 Liquid coal combustion improver
WO2013010309A1 (en) * 2011-07-15 2013-01-24 深圳市泓耀环境科技发展股份有限公司 High-efficiency and environmentally-friendly gasoline antiknock
WO2013023372A1 (en) * 2011-08-17 2013-02-21 湖南中创化工股份有限公司 A gasoline composition and its preparation method
CN103074126A (en) * 2013-01-31 2013-05-01 北京泰龙万达节能技术研究所 Ash-free gasoline antiknock
CN103695056A (en) * 2013-12-15 2014-04-02 山西华顿实业有限公司 Low-carbon diesel additive
CN103789056A (en) * 2014-01-16 2014-05-14 宁夏宝塔石化科技实业发展有限公司 Novel gasoline compound antiknock agent
CN108251169A (en) * 2017-12-19 2018-07-06 宁夏宝塔化工中心实验室(有限公司) A kind of new polymers Compound gasoline antiknock
CN109022065A (en) * 2018-08-14 2018-12-18 齐广浩 A kind of gasoline compounding agent

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642544B (en) * 2013-12-25 2015-09-23 济南开发区星火科学技术研究院 A kind of Lead-free gasoline composite antiknock agent and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1123829A (en) * 1994-11-23 1996-06-05 中国科学院大连化学物理研究所 Additive for catalyzing combustion of gasoline
US6102975A (en) * 1999-10-01 2000-08-15 Marr; Wesley D. Fuel conditioner and improver compositions
CN1796508A (en) * 2004-12-21 2006-07-05 上海中油企业集团有限公司 Composition of multifunctional additive for diesel oil

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212401A (en) * 2011-05-10 2011-10-12 湖南未名创林生物能源有限公司 Alcohol-based fuel composite addition agent for engine and preparation method thereof
CN102212401B (en) * 2011-05-10 2013-05-15 湖南未名创林生物能源有限公司 Alcohol-based fuel composite adjuvant for engine and preparation method thereof
WO2013010309A1 (en) * 2011-07-15 2013-01-24 深圳市泓耀环境科技发展股份有限公司 High-efficiency and environmentally-friendly gasoline antiknock
WO2013023372A1 (en) * 2011-08-17 2013-02-21 湖南中创化工股份有限公司 A gasoline composition and its preparation method
CN102827666A (en) * 2012-09-20 2012-12-19 赵冠军 Liquid coal combustion improver
CN102827666B (en) * 2012-09-20 2014-02-05 赵冠军 Liquid coal combustion improver
CN103074126A (en) * 2013-01-31 2013-05-01 北京泰龙万达节能技术研究所 Ash-free gasoline antiknock
CN103695056A (en) * 2013-12-15 2014-04-02 山西华顿实业有限公司 Low-carbon diesel additive
CN103695056B (en) * 2013-12-15 2016-05-04 山西华顿实业有限公司 A kind of low carbon diesel additive
CN103789056A (en) * 2014-01-16 2014-05-14 宁夏宝塔石化科技实业发展有限公司 Novel gasoline compound antiknock agent
CN108251169A (en) * 2017-12-19 2018-07-06 宁夏宝塔化工中心实验室(有限公司) A kind of new polymers Compound gasoline antiknock
CN109022065A (en) * 2018-08-14 2018-12-18 齐广浩 A kind of gasoline compounding agent

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