CN101676350A - Water soluble flocking glue and preparation method thereof - Google Patents
Water soluble flocking glue and preparation method thereof Download PDFInfo
- Publication number
- CN101676350A CN101676350A CN200810200134A CN200810200134A CN101676350A CN 101676350 A CN101676350 A CN 101676350A CN 200810200134 A CN200810200134 A CN 200810200134A CN 200810200134 A CN200810200134 A CN 200810200134A CN 101676350 A CN101676350 A CN 101676350A
- Authority
- CN
- China
- Prior art keywords
- water soluble
- initiator
- acid
- water
- functional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a water soluble flocking glue for static flocking, which is mainly prepared from crylic acid, methacrylic acid, butyl acrylate, ethyl acrylate, styrene, functional monomers, initiator, emulsifier, buffering agent, functional accessory agent, pH regulator and softened water through reactions, and provides a preparation method for the water soluble flocking glue. The water soluble flocking glue reduces solidification temperature, saves energy consumption and has smaller influence to raw base materials. The product is prevented from size separation, has good levelling property, strong dirt resistance, easy spray and easy flocking, strong adhesive force, good water resistance, acid and basic resistance. The product is anti-aging, non-toxic and odorless, safe and reliable.
Description
Technical field
The present invention relates to composite gum of a kind of static flocking and preparation method thereof, relate in particular to a kind of water soluble flocking glue and preparation method thereof.
Background technology
Static flocking is on the bar-shaped electrode of staple fibre fine hair in electric field because after electrostatic effect obtains an electric charge, can move to and correspondingly extremely go up, because dipole nature, fine hair can be arranged in rows according to the direction of power line, and it is, bonding and fixing by means of tackiness agent perpendicular to corresponding substrate surface.Be widely used in: body surfaces such as plastic uptake, toy, jewel case, artificial floriculture, christmas crafts, five metals, sponge, woodwork, eva foam, backboard, stamp, non-woven fabrics.
Adopt flocking technology can develop and the similar lining of other weaving face fabric appearance styles, such as linings such as corduroy, etched-out velvet, plushes, but because the limitation of technology, quality product is subjected to the restriction of tackiness agent, therefore compare with other weaving face fabrics, lack competitiveness.In the face of wide weaving face fabric market, implanted article only is penetrated into the weaving other field, utilize the static flocking special technique, production environment-friendly type, functional type, compound, higher-grade, high quality, many kinds static flocking product innovation just can make the static flocking product have bigger development space.
Summary of the invention
Purpose of the present invention provides a kind of water soluble flocking glue exactly in order to address the above problem.
Another object of the present invention is to provide a kind of method for preparing water soluble flocking glue of the present invention.
The object of the present invention is achieved like this:
The invention discloses a kind of water soluble flocking glue, form by prepared in reaction: vinylformic acid, methacrylic acid, butyl acrylate, ethyl propenoate by following component, vinyl acetate between to for plastic, functional monomer, initiator, emulsifying agent, buffer reagent, functional aid, pH adjusts agent, softening water;
Described functional monomer is selected from least a in Phthalic acid, diallyl ester, Hydroxyethyl acrylate and the N hydroxymethyl acrylamide;
Described initiator is an ammonium persulphate;
Described emulsifying agent is selected from least a in sulfosuccinate and the phenolic ether sulphate;
Described buffer reagent is selected from least a in bicarbonate of ammonia and the sodium bicarbonate;
Described functional aid is selected from least a among OT75, mineral oil and the water soluble acrylic resin;
It is ammoniacal liquor that described pH adjusts agent;
The shared weight percent of above-mentioned each component is respectively: vinylformic acid 1～5%, methacrylic acid 1～5%, butyl acrylate 10～15%, ethyl propenoate 10～15%, vinyl acetate between to for plastic 10～20%; Functional monomer comprises Phthalic acid, diallyl ester 0～5%, Hydroxyethyl acrylate 0～5%, N hydroxymethyl acrylamide 0～5%; Initiator comprises ammonium persulphate 0～2%; Emulsifying agent comprises sulfosuccinate 0～2%, phenolic ether sulphate 0～5%; Buffer reagent comprises bicarbonate of ammonia 0～2%, sodium bicarbonate 0～1%; Functional aid comprises OT75 0～3%, mineral oil 0～1%, and the water soluble acrylic resin 0～2%; PH adjusts agent: ammoniacal liquor 0～5%; Softening water 25～40%.
Raw material of the present invention is that general raw material gets by market purchasing.
The present invention also provides a kind of preparation method of water soluble flocking glue of the present invention, realizes by following steps:
(a) quantitative emulsifying agent, buffer reagent, softening water are joined in the reactor, obtain mixing raw material after stirring and be warming up to 75～90 ℃;
(b) quantitative vinylformic acid, methacrylic acid, butyl acrylate, ethyl propenoate, vinyl acetate between to for plastic, functional monomer, emulsifying agent, buffer reagent are joined in the pre-emulsification still, stir and obtain mixing raw material after 30 minutes, emit wherein 1～15% as seed liquor;
(c) mixing raw material in the step a reactor is warming up to 80～90 ℃, drop into the seed liquor among the step b after, add initiator and softening water again, control temperature of reaction kettle to 80～90 ℃;
(d) with in the remaining mixing raw material in quantitative initiator, functional monomer and the pre-emulsification still of softening water adding step b, stir and obtain compound;
(e) compound that steps d is obtained splashes in the reactor, and temperature is controlled at 80～90 ℃, and the dropping time is 2～4 hours;
(f) dropwise after, maintain the temperature at 80～90 ℃, react after 1～3 hour, be cooled to 50～60 ℃;
(g) add functional aid, treat that temperature reduces to 40 ℃, adjust discharging after the viscosity.
Compared with prior art, the invention has the beneficial effects as follows: reduce solidification value, save energy consumption, and less to former base material influence.Product is not walked slurry, good leveling property, and stronger pollution resistance is arranged, and easily sprays Yi Shangmao, strong adhesion, and water-acid resistance is good.Anti-aging, nontoxic free from extraneous odour, safe and reliable.
Embodiment
The following examples can make those skilled in the art more fully understand the present invention, but do not limit the present invention in any way.
Embodiment 1 (unit: kilogram)
Prescription:
Reactor:
1. softening water 180 phenolic ether sulphates 2 bicarbonate of ammonia 0.2 sodium bicarbonate 0.3
2. softening water 17 ammonium persulphates 4
Pre-emulsification still:
3. softening water 115 phenolic ether sulphates 4 sulfosuccinates 1 bicarbonate of ammonia 0.2
4. butyl acrylate 140 ethyl propenoates 120 vinyl acetate between to for plastics 140 Phthalic acid, diallyl esters 5 Hydroxyethyl acrylates 5 vinylformic acid 8 methacrylic acids 7
5. softening water 8 N hydroxymethyl acrylamides 2
6. softening water 18 ammonium persulphates 4
7. mineral oil 1
8.OT75?3
9. the water soluble acrylic resin 10
10. ammoniacal liquor 8
Operation steps:
Reactor is joined rebasing liquid 1 in order, starts then to stir to be warming up to 88 ℃; Start pre-emulsification still and stir, join pre-emulsification kettle base solution 3; Be sequentially added into monomer 4 then, stir after 30 minutes, emit 30 kilograms of seed liquor; When the rebasing liquid 1 of reactor rises to 88 ℃, drop into seed liquor; And then add reactor towards still liquid 2; 85～86 ℃ of control temperature of reaction kettle; After raw material added 5,6 in the pre-emulsification still, beginning dripped in reactor, and temperature is controlled at 83～84 ℃, and the dropping time is 3～3.5 hours; After dripping end, be warming up to 88 ℃, be incubated 2 hours; Cool the temperature to 60 ℃ then, add 7, temperature is reduced to 50 ℃, adds 8 and 9, when temperature is reduced to 40 ℃, adds 10 back dischargings.
Embodiment 2 (unit: kilogram)
Prescription:
Reactor:
1. softening water 200 sulfosuccinates 3 bicarbonate of ammonia 0.2 sodium bicarbonate 0.3
2. softening water 17 ammonium persulphates 4
Pre-emulsification still:
3. softening water 95 phenolic ether sulphates 4 sulfosuccinates 1 bicarbonate of ammonia 0.2
4. butyl acrylate 160 ethyl propenoates 120 vinyl acetate between to for plastics 120 Phthalic acid, diallyl esters 3 Hydroxyethyl acrylates 3 vinylformic acid 3 methacrylic acids 7
5. softening water 8 N hydroxymethyl acrylamides 2
6. softening water 18 ammonium persulphates 4
7. mineral oil 1
8.OT75?3
9. the water soluble acrylic resin 10
Operation steps
Reactor is joined rebasing liquid 1 in order, starts then to stir to be warming up to 88 ℃; Start pre-emulsification still and stir, join pre-emulsification kettle base solution 3; Be sequentially added into monomer 4 then, stir after 30 minutes, emit 30 kilograms of seed liquor; When the rebasing liquid 1 of reactor rises to 88 ℃, drop into seed liquor; And then add reactor towards still liquid 2; 85～86 ℃ of control temperature of reaction kettle; After raw material added 5,6 in the pre-emulsification still, beginning dripped in reactor, and temperature is controlled at 83～84 ℃, and the dropping time is 3～3.5 hours; After dripping end, be warming up to 88 ℃, be incubated 2 hours; Cool the temperature to 60 ℃ then, add 7, temperature is reduced to 50 ℃, adds 8 and 9, discharging after temperature is reduced to 40 ℃.
Claims (3)
1. water soluble flocking glue is formed by prepared in reaction by following component: vinylformic acid, and methacrylic acid, butyl acrylate, ethyl propenoate, vinyl acetate between to for plastic, functional monomer, initiator, emulsifying agent, buffer reagent, functional aid, pH adjusts agent, softening water;
Described functional monomer is selected from least a in Phthalic acid, diallyl ester, Hydroxyethyl acrylate and the N hydroxymethyl acrylamide;
Described initiator is a persulphate;
Described emulsifying agent is selected from least a in sulfosuccinate and the phenolic ether sulphate;
Described buffer reagent is selected from least a in bicarbonate of ammonia and the sodium bicarbonate;
Described functional aid is selected from least a among OT75, mineral oil and the water soluble acrylic resin;
It is ammoniacal liquor that described pH adjusts agent;
The shared weight percent of above-mentioned each component is respectively: vinylformic acid 1～5%, methacrylic acid 1～5%, butyl acrylate 10～15%, ethyl propenoate 10～15%, vinyl acetate between to for plastic 10～20%; Functional monomer comprises Phthalic acid, diallyl ester 0～5%, Hydroxyethyl acrylate 0～5%, N hydroxymethyl acrylamide 0～5%; Initiator comprises ammonium persulphate 0～2%; Emulsifying agent comprises sulfosuccinate 0～2%, phenolic ether sulphate 0～5%; Buffer reagent comprises bicarbonate of ammonia 0～2%, sodium bicarbonate 0～1%; Functional aid comprises OT750～3%, mineral oil 0～1%, and the water soluble acrylic resin 0～2%; PH adjusts agent: ammoniacal liquor 0～5%; Softening water 25～40%.
2. water soluble flocking glue as claimed in claim 1 is characterized in that, described initiator is an ammonium persulphate.
3. one kind prepares the method for water soluble flocking glue according to claim 1, may further comprise the steps:
(a) quantitative emulsifying agent, buffer reagent, softening water are joined in the reactor, obtain mixing raw material after stirring and be warming up to 75～90 ℃;
(b) quantitative vinylformic acid, methacrylic acid, butyl acrylate, ethyl propenoate, vinyl acetate between to for plastic, functional monomer, emulsifying agent, buffer reagent are joined in the pre-emulsification still, stir and obtain mixing raw material after 30 minutes, emit wherein 1～15% as seed liquor;
(c) mixing raw material in the step a reactor is warming up to 80～90 ℃, drop into the seed liquor among the step b after, add initiator and softening water again, control temperature of reaction kettle to 80～90 ℃;
(d) with in the remaining mixing raw material in quantitative initiator, functional monomer and the pre-emulsification still of softening water adding step b, stir and obtain compound;
(e) compound that steps d is obtained splashes in the reactor, and temperature is controlled at 80～90 ℃, and the dropping time is 2～4 hours;
(f) dropwise after, maintain the temperature at 80～90 ℃, react after 1～3 hour, be cooled to 50～60 ℃;
(g) add functional aid, treat that temperature reduces to 40 ℃, adjust discharging after the viscosity.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810200134A CN101676350A (en) | 2008-09-19 | 2008-09-19 | Water soluble flocking glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810200134A CN101676350A (en) | 2008-09-19 | 2008-09-19 | Water soluble flocking glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101676350A true CN101676350A (en) | 2010-03-24 |
Family
ID=42029066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810200134A Pending CN101676350A (en) | 2008-09-19 | 2008-09-19 | Water soluble flocking glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101676350A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880349A (en) * | 2010-08-16 | 2010-11-10 | 上海东和胶粘剂有限公司 | Cross linking type methyl acrylate and vinyl acetate emulsion and preparation method thereof |
| CN103642436A (en) * | 2013-11-26 | 2014-03-19 | 江苏波波熊纺织品有限公司 | Water-borne electrostatic flocking glue for textiles and preparation method thereof |
| CN104263256A (en) * | 2014-08-29 | 2015-01-07 | 湖州天鑫皮革涂饰剂厂 | Flocking adhesive and preparation method thereof |
| CN104312499A (en) * | 2014-09-29 | 2015-01-28 | 中山市宝泰化工有限公司 | Glue and preparation method thereof |
| CN105950082A (en) * | 2016-04-01 | 2016-09-21 | 合肥第六元素光电科技有限公司 | Colored pressure-sensitive adhesive, manufacturing method thereof, and manufactured pressure-sensitive adhesive tape |
| CN105950075A (en) * | 2016-04-01 | 2016-09-21 | 合肥第六元素光电科技有限公司 | UV-cured high-binding-power water-resistant flame-retardant pressure-sensitive adhesive tape and manufacturing method of adhesive tape |
| CN105294925B (en) * | 2015-11-24 | 2017-04-19 | 辽宁恒星精细化工有限公司 | Electrostatic flocking adhesive for high fastness carpet and preparation method thereof |
-
2008
- 2008-09-19 CN CN200810200134A patent/CN101676350A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880349A (en) * | 2010-08-16 | 2010-11-10 | 上海东和胶粘剂有限公司 | Cross linking type methyl acrylate and vinyl acetate emulsion and preparation method thereof |
| CN103642436A (en) * | 2013-11-26 | 2014-03-19 | 江苏波波熊纺织品有限公司 | Water-borne electrostatic flocking glue for textiles and preparation method thereof |
| CN104263256A (en) * | 2014-08-29 | 2015-01-07 | 湖州天鑫皮革涂饰剂厂 | Flocking adhesive and preparation method thereof |
| CN104312499A (en) * | 2014-09-29 | 2015-01-28 | 中山市宝泰化工有限公司 | Glue and preparation method thereof |
| CN105294925B (en) * | 2015-11-24 | 2017-04-19 | 辽宁恒星精细化工有限公司 | Electrostatic flocking adhesive for high fastness carpet and preparation method thereof |
| CN105950082A (en) * | 2016-04-01 | 2016-09-21 | 合肥第六元素光电科技有限公司 | Colored pressure-sensitive adhesive, manufacturing method thereof, and manufactured pressure-sensitive adhesive tape |
| CN105950075A (en) * | 2016-04-01 | 2016-09-21 | 合肥第六元素光电科技有限公司 | UV-cured high-binding-power water-resistant flame-retardant pressure-sensitive adhesive tape and manufacturing method of adhesive tape |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101676350A (en) | Water soluble flocking glue and preparation method thereof | |
| CN100537619C (en) | Method for preparing carboxylic styrene butadiene latex for carpet back coating | |
| CN102533186B (en) | Adhesive for alkali resistant acrylate glass fiber mesh cloth shaping, and preparation method thereof | |
| CN101974194B (en) | Epoxy modified styrene-acrylate emulsion and preparation method thereof | |
| CN101280035B (en) | Wet-rub resistant styrene-acrylic emulsion and preparation thereof | |
| CN104004477B (en) | A kind of room-temperature self crosslinking polyacrylate pressure-sensitive and preparation method thereof and application | |
| CN104356287B (en) | A kind of pure acrylic emulsion of stone-like coating and preparation method of the high water-whitening resistance of exterior crosslinked type | |
| CN102516470B (en) | Aqueous acrylate electrostatic flocking bonding agent and preparation method thereof | |
| CN102408853B (en) | Water-based body flame-resistant acrylate adhesive and preparation method thereof | |
| CN109627375A (en) | A kind of vac-veova emulsion and preparation method thereof | |
| CN101343525B (en) | Watersoluble adhesive agent used in imitation leather electrostatic real leather embedding product and preparation thereof | |
| CN101492594A (en) | Chloroprene rubber latex adhesive, preparation and uses thereof | |
| CN101585894B (en) | Preparation method of vinyl acetate-acrylate copolymerization emulsion | |
| JPS6356250B2 (en) | ||
| CN101864025B (en) | Preparation method of polyacrylate microgel emulsion and application thereof | |
| CN102925085B (en) | Water emulsion type plant adhesive and preparation method thereof | |
| CN101704913A (en) | Styrene-acrylic emulsion for priming paint as well as preparation method and application thereof | |
| CN102199241B (en) | Preparation method and application of water-based fluorine-containing acrylate emulsion | |
| CN102140320A (en) | Water-based polyacrylic emulsion laminating adhesive and preparation method thereof | |
| CN101982494A (en) | Method for preparing hollow microsphere emulsion with covering power for printing paint | |
| CN105950082A (en) | Colored pressure-sensitive adhesive, manufacturing method thereof, and manufactured pressure-sensitive adhesive tape | |
| CN103374090B (en) | A kind of soap-free polymerization prepares the method for artificial turf back painting carboxylic styrene butadiene latex | |
| CN108314947B (en) | Preparation method of graphene coating adhesive | |
| CN105602494A (en) | Organosilicone modified waterborne acrylate electrostatic flocking formaldehyde-free adhesive and preparation method thereof | |
| CN100381530C (en) | Prossure sensitive glue and its compounding method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20100324 |