CN101671547B - Phase-change thermal-storage material taking waste engine oil as main material - Google Patents
Phase-change thermal-storage material taking waste engine oil as main material Download PDFInfo
- Publication number
- CN101671547B CN101671547B CN2009101907848A CN200910190784A CN101671547B CN 101671547 B CN101671547 B CN 101671547B CN 2009101907848 A CN2009101907848 A CN 2009101907848A CN 200910190784 A CN200910190784 A CN 200910190784A CN 101671547 B CN101671547 B CN 101671547B
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- CN
- China
- Prior art keywords
- parts
- storage material
- phase
- used oil
- change thermal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000011232 storage material Substances 0.000 title claims abstract description 27
- 239000002699 waste material Substances 0.000 title abstract description 6
- 239000000463 material Substances 0.000 title abstract description 3
- 239000010705 motor oil Substances 0.000 title abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000012188 paraffin wax Substances 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 8
- 239000000292 calcium oxide Substances 0.000 claims abstract description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 4
- 239000010935 stainless steel Substances 0.000 claims abstract description 4
- 238000005338 heat storage Methods 0.000 claims description 25
- 239000010913 used oil Substances 0.000 claims description 25
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 11
- 238000009635 antibiotic susceptibility testing Methods 0.000 claims description 8
- 235000010265 sodium sulphite Nutrition 0.000 claims description 7
- 229960001866 silicon dioxide Drugs 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 1
- 229940088990 ammonium stearate Drugs 0.000 abstract 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 229910052979 sodium sulfide Inorganic materials 0.000 abstract 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 1
- 238000004781 supercooling Methods 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The invention relates to a phase-change thermal-storage material taking waste engine oil as a main material. The phase-change thermal-storage material is prepared by the following raw materials by parts by weight: 40-60 parts of waste engine oil, 4-6 parts of paraffin wax, 18-22 parts of ammonium stearate, 10-13 parts of sodium sulfide, 9-10 parts of white clay, 1-2 parts of quicklime and 1.8-2.2parts of silicon dioxide. The raw materials are mixed and stirred, and then the temperature is increased, thereby synthesizing the phase-change thermal-storage material. When in use, the phase-changethermal-storage material is packaged in a PE plastic ball or a plate or a stainless steel ball and arranged in a thermal-storage water tank for being applied. The phase-change thermal-storage material can recycle waste resources, reduce the environmental pollution caused by wastes, and simultaneously manufacture a good product with low price, stable performance and no super-cooling or separation.The phase-change thermal-storage material can also better solve the difficult problems of super-large size and pressure-bearing of the water tank in the thermal energy-saving transformation and simultaneously open a new way for entering household energy-saving products.
Description
Technical field:
The present invention relates to energy-accumulation material, being specifically related to a kind of is the phase change heat storage material of major ingredient with the used oil.
Background technology:
In existing energy structure, heat energy is one of most important energy.But the most energy like sun power, wind energy, low heat energy and industrial exhaust heat used heat etc., all exists discontinuity and instable characteristics; People also are ignorant of how making full use of the energy in many cases, and it can not in time provide again when hot like needs, but and a large amount of when not required output produces; Inexhaustible but store seldom like its energy of sun power, can not satisfy during urgent need, so how to absorb waste heat, absorb renewable energy source; Especially store it, the energy is promoted and stable heating, deal with the usefulness of urgent need; Give its actual value, become everybody urgent problem.
Summary of the invention:
The present invention is for solving the accumulation of heat problem, and providing a kind of is the phase change heat storage material of major ingredient with the used oil.Of the present invention is the phase change heat storage material of major ingredient with the used oil; Raw material by following weight part makes: a kind of is the phase change heat storage material of major ingredient with the used oil, it is characterized in that, is made by the raw material of following weight part: 40～60 parts of used oil; 4～6 parts in paraffin; 18～22 parts of ASTs, 10～13 parts in sodium sulphite, 9～10 parts of carclazytes, 1～2 part of unslaked lime, silica 1 .8～2.2 part.
For better realization the present invention, of the present invention is the phase change heat storage material of major ingredient with the used oil, and more preferably the raw material by following weight part makes: 50 parts of used oil; 5 parts in paraffin; 20 parts of ASTs, 12 parts in sodium sulphite, 10 parts of carclazytes, 1 part of unslaked lime, 2 parts of silicon-dioxide.
Described used oil is the used oil that is preferably after hydrogenation carries out hydrogen treatment.
Of the present invention is that the preparation method of the phase change heat storage material of major ingredient is with the used oil: used oil, aluminum oxide, AST, paraffin and silicon-dioxide are mixed, stir, heat and can synthesize said phase change heat storage material.Put into phase change heat storage material in PE baton round or PE plastic plate or the Stainless Steel Ball during use, put heat storage water tank into after finishing and use.Also can put into the container of patent 200820092232.4, and then this container put into heat storage water tank use.
The present invention proposes a kind of useless resource regeneration that how to use, and reduces the waste pollution environment, and it is low to make a kind of price simultaneously, stable performance, but the isolating superior prod of cold-peace.Phase change heat storage material of the present invention is applied on the actual energy-conserving product, makes existing sun power, and the product of heat pump, waste heat recovery ability aspect accumulation of energy is more than doubled, and original water tank is significantly reduced.Solved water tank super large and the difficult problem of pressure-bearing during thermal center can be transformed preferably, broken a new path for the energy-conserving product that gets into family simultaneously.
Energy-conserving product of the present invention can be used for northern heating and reclaims and utilization with heat and industrial waste heat, also for using energy-conserving product to break a new path than cold district, for energy-saving and emission-reduction bring new revolution.
Embodiment:
Below in conjunction with specific embodiment the present invention is described further, to help understanding the present invention, but protection scope of the present invention is not limited in this.
Embodiment 1
Get the raw material of following weight part: 40 parts of used oil, 4 parts in paraffin, 20 parts of ASTs, 13 parts in sodium sulphite, 9 parts of carclazytes, 1 part of unslaked lime, silica 1 .8 part.Then above-mentioned raw materials is mixed, stirs, heat again, promptly synthetic said phase change heat storage material to 80 ℃.
Embodiment 2
Earlier the used oil hydrogenation is carried out hydrogen treatment, get the raw material of following weight part then: 50 parts of the used oil after the hydrogenation, 5 parts in paraffin, 18 parts of ASTs, 10 parts in sodium sulphite, 10 parts of carclazytes, 2 parts of unslaked limes, 2 parts of silicon-dioxide.With these raw materials mix, stirring, heat to 70 ℃ promptly synthetic said phase change heat storage material again.
The phase change heat storage material of gained is put into the PE plastic plate, put in the heat storage water tank then and use.
Embodiment 3
Get the raw material of following weight part: 60 parts of used oil, 6 parts in paraffin, 22 parts of ASTs, 12 parts in sodium sulphite, 10 parts of carclazytes, 1 part of unslaked lime, 2.2 parts of silicon-dioxide.Then above-mentioned raw materials is mixed, stirs, heat 55 ℃ again, promptly synthetic said phase change heat storage material.
The phase change heat storage material of gained is put in the Stainless Steel Ball, put in the heat storage water tank then and use.
Claims (4)
1. one kind is the phase change heat storage material of major ingredient with the used oil, it is characterized in that, is made by the raw material of following weight part: 40～60 parts of used oil; 4～6 parts in paraffin; 18～22 parts of ASTs, 10～13 parts in sodium sulphite, 9～10 parts of carclazytes, 1～2 part of unslaked lime, silica 1 .8～2.2 part.
2. according to claim 1 a kind of be the phase change heat storage material of major ingredient with the used oil, it is characterized in that, make by the raw material of following weight part: 50 parts of used oil; 5 parts in paraffin; 20 parts of ASTs, 12 parts in sodium sulphite, 10 parts of carclazytes, 1 part of unslaked lime, 2 parts of silicon-dioxide.
3. according to claim 1 a kind of be the phase change heat storage material of major ingredient with the used oil, it is characterized in that described used oil is for through hydrotreated used oil, the used oil after the hydrogen treatment is gel or solid-like.
Claim 1,2 or 3 described be the method for use of the phase change heat storage material of major ingredient with the used oil, it is characterized in that, may further comprise the steps: phase change heat storage material is put in PE baton round or PE plastic plate or the Stainless Steel Ball, put into heat storage water tank then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101907848A CN101671547B (en) | 2009-09-30 | 2009-09-30 | Phase-change thermal-storage material taking waste engine oil as main material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101907848A CN101671547B (en) | 2009-09-30 | 2009-09-30 | Phase-change thermal-storage material taking waste engine oil as main material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101671547A CN101671547A (en) | 2010-03-17 |
| CN101671547B true CN101671547B (en) | 2012-06-27 |
Family
ID=42018972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101907848A Expired - Fee Related CN101671547B (en) | 2009-09-30 | 2009-09-30 | Phase-change thermal-storage material taking waste engine oil as main material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101671547B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108552558A (en) * | 2018-03-21 | 2018-09-21 | 鲁东大学 | A kind of solar energy vegetable-fruit drying device |
| CN111423161B (en) * | 2020-03-27 | 2021-05-04 | 广东鑫隆管业有限公司 | Steam curing-free process for cement product |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587340A (en) * | 2004-07-09 | 2005-03-02 | 清华大学 | High heat conductive fixed phase change heat storage material suitable for large scale industrial production |
| CN101284986A (en) * | 2008-06-06 | 2008-10-15 | 天津工业大学 | Preparation method of macrocapsule of wax shaping phase-change material |
-
2009
- 2009-09-30 CN CN2009101907848A patent/CN101671547B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587340A (en) * | 2004-07-09 | 2005-03-02 | 清华大学 | High heat conductive fixed phase change heat storage material suitable for large scale industrial production |
| CN101284986A (en) * | 2008-06-06 | 2008-10-15 | 天津工业大学 | Preparation method of macrocapsule of wax shaping phase-change material |
Non-Patent Citations (4)
| Title |
|---|
| 张仁元 |
| 毛凌波.《石蜡类相变材料的研究及应用进展》.《料研究与应用》.2008,全文. |
| 陈枭 |
| 陈枭;张仁元;毛凌波.《石蜡类相变材料的研究及应用进展》.《料研究与应用》.2008,全文. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101671547A (en) | 2010-03-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: SHENZHEN HUITEN HEAT + ENERGY EQUIPMENTS CO., LTD. Free format text: FORMER OWNER: LIN GUANGSHUN Effective date: 20121214 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20121214 Address after: 518000, 907, Minmetals building, No. 61 Spring Road, Shenzhen, Guangdong, Luohu District Patentee after: Shenzhen cascade heat energy equipment Co., Ltd. Address before: 518000 Guangdong city of Shenzhen province Luohu District Yongxin Street Mall 4H Bada Patentee before: Lin Guangshun |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120627 Termination date: 20170930 |
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| CF01 | Termination of patent right due to non-payment of annual fee |