CN101669699A - Preparation method of paper hat brim - Google Patents

Preparation method of paper hat brim Download PDF

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Publication number
CN101669699A
CN101669699A CN200910180053A CN200910180053A CN101669699A CN 101669699 A CN101669699 A CN 101669699A CN 200910180053 A CN200910180053 A CN 200910180053A CN 200910180053 A CN200910180053 A CN 200910180053A CN 101669699 A CN101669699 A CN 101669699A
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paper
hat
brim
preparation
latex
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CN101669699B (en
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仰午正
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Bitu Special Paperboard Co Ltd, Jiangyin
Shanghai Linzhan Trade Development Co., Ltd.
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BITU SPECIAL PAPERBOARD CO LTD JIANGYIN
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Abstract

The invention discloses a preparation method of paper hat brims. The method comprises the following steps: selecting long fiber wood pulp to beat in a pulper while controlling beating degree and wet weight, then using a millstone to grind, then placing grinded paper pulp in a dosing tank, adding dye and wet strength agent in the dosing tank, simultaneously adding cationic starch, wax emulsion andneutral sizing agent, introducing prepared slurry a sizing tank, adding paper pulp in the sizing tank in a fourdrinier to perform papermaking through one-step molding technology, using a vacuum pressing equipment to remove moisture, soaking the obtained wet hat brim paper in emulsion mixed liquor, then treating the obtained wet hat brim paper through drying, vulcanizing and calendering, finally cutting the hat brim paper into hat brims, packaging and warehousing. The method of the invention adopts renewable and easily degradable raw material as base material to prepare environmental hat brimswhich are easy to process, is hard to deform and has moderate hardness through simple processing method.

Description

A kind of preparation method of paper hat brim
Technical field
The present invention relates to a kind of preparation method of paper products, be specifically related to a kind of preparation method of paper hat brim.
Background technology
Along with increasingly sharpening of global economic integration and the reorganization of world's product integration, the more and more incompatible survival and development of labour-intensive cap series products in developed country.The production pattern of whole world hatting industry is just progressively shifted to developing country, China's hatting industry is brought into play more and more important position with distinctive advantage in accepting world's industrial pattern reorganization, the cap series products is with distinctive industrial advantage, vigorous vitality and development potentiality have been manifested, from market prospects, along with cap kind and function enriching constantly and progressive, people consume improving constantly of grade, dress ornament theory, health care and philosophy of life, and the requirement quality of cap material is also progressively manifested.The brim of a hat of using as cap in the prior art, cheap common hardboard paper and the plastic materials such as PVC, PET of the general employing of traditional material, these materials can not satisfy market demand, because the remarkable defective of these materials is plastic product and can't degrades in natural environment, not environmental protection, and be difficult for to sew up processing, and bad, the soaked weakness such as yielding of the intensity difference of common hardboard paper, deflection soft or hard discomfort, typing.Therefore, be necessary the existing the brim of a hat is improved with material.
Summary of the invention
The objective of the invention is to overcome the defective that exists in the prior art, design a kind of preparation method of paper hat brim.This method is a base material with raw material renewable, easy degraded, promptly can be made into the moderate the brim of a hat of environment-friendly type, that be easy to process, on-deformable, stiff degree by simple machining process.
For achieving the above object, technical scheme of the present invention provides a kind of preparation method of paper hat brim, and described preparation method comprises the steps:
S1: select for use the long fibre wood pulp to pull an oar in pulper, control beating degree and weight in wet base in pulping process, and then grind through mill, the paper pulp after will grinding is again put into dosing chamber;
S2: in dosing chamber, add a certain amount of dyestuff, wet strength agent again, add 3%~6% cationic starch simultaneously, add 0.3%~0.8% wax emulsion and neutral sizing agent;
S3: the slurries that prepare in the S2 step are imported sizing compartment, and the concentration of paper pulp in the stock tank is transferred to 0.8%~1%;
S4: the paper pulp that obtains in the S3 step joined in the long mesh paper making machine manufacture paper with pulp, and one-shot forming, in one-shot forming, several thes brim of a hat are linked to be integral body for sheet or drum;
S5: with the brim of a hat paper that obtains in the S4 step, with the most of moisture in the suction press equipment removal the brim of a hat paper;
S6: it is in 20%~35% the latex mixed liquor that the wet the brim of a hat paper that obtains in the S5 step is immersed concentration, satisfies simultaneously to suck 60%~70% latex mixed liquor in finished product the brim of a hat paper;
S7: with the wet the brim of a hat paper that obtains in the S6 step dry, sulfuration, press polish handle;
S8: the brim of a hat paper that obtains in the S7 step is cut into the single the brim of a hat, then the packing warehouse-in.
Wherein, described latex mixed liquor is mixed by carboxylic styrene butadiene latex and high-phenylethylene latex, and the content of described high-phenylethylene latex is 10%~20%.
Wherein, described neutral sizing agent is a cationoid reaction type glue used in paper-making.
Wherein, in described 0.3%~0.8% wax emulsion and neutral sizing agent, the content of wax emulsion is 0.05%~0.08%.
Wherein, in described pulping process, beating degree is controlled at 15-18 ° of SR, weight in wet base is controlled at 15g~20g.
Wherein, the addition of described dyestuff is 20g~100g, and the addition of described wet strength agent is 1.5%~4.0%.
Wherein, the time that described wet the brim of a hat paper is immersed in the latex mixed liquor was controlled between 10~20 seconds.
Wherein, described long mesh paper making machine is Haber's formula long mesh paper making machine.
Wherein, described pulping process adopts hydrabrusher to pull an oar.
Wherein, add in the process of manufacturing paper with pulp of long mesh paper making machine, paper hat brim quantitatively is controlled at 1000g/m at described paper pulp 2~1600g/m 2Between, with the paper hat brim THICKNESS CONTROL between 2.3mm~2.5mm.
Advantage of the present invention and beneficial effect are: owing to adopted raw material paper renewable, easy degraded in the present invention is base material, promptly can be made into the moderate the brim of a hat of environment-friendly type, that be easy to process, on-deformable, stiff degree by simple machining process.
Description of drawings
Fig. 1 is the preparation method process chart of paper hat brim of the present invention.
The specific embodiment
Below in conjunction with drawings and Examples, the specific embodiment of the present invention is further described.Following examples only are used for technical scheme of the present invention more clearly is described, and can not limit protection scope of the present invention with this.
The concrete technical scheme of implementing of the present invention is: a kind of preparation method of paper hat brim, described preparation method comprises the steps:
The first step: select for use the long fibre wood pulp to pull an oar in pulper, control beating degree and weight in wet base in pulping process, and then grind through mill, the paper pulp after will grinding is again put into dosing chamber;
Second step: in dosing chamber, add a certain amount of dyestuff, wet strength agent again, add 3%~6% cationic starch simultaneously, add 0.3%~0.8% wax emulsion and neutral sizing agent;
The 3rd step: the slurries that prepare in second step are imported sizing compartment, and the concentration of paper pulp in the stock tank is transferred to 0.8%~1%;
The 4th step: the paper pulp that obtains in the third step joined in the long mesh paper making machine manufacture paper with pulp, and one-shot forming, in one-shot forming, several thes brim of a hat are linked to be integral body for sheet or drum;
The 5th step: with the brim of a hat paper that obtains in the 4th step, with the most of moisture in the suction press equipment removal the brim of a hat paper;
The 6th step: it is in 20%~35% the latex mixed liquor that the wet the brim of a hat paper that obtains in the 5th step is immersed concentration, satisfies simultaneously to suck 60%~70% latex mixed liquor in finished product the brim of a hat paper;
The 7th step: the oven dry of wet the brim of a hat paper, sulfuration, the press polish that obtain in the 6th step are handled;
The 8th step: the brim of a hat paper that obtains in the 7th step is cut into the single the brim of a hat, then the packing warehouse-in.
Optimized technical scheme is in the present invention, and described latex mixed liquor is mixed by carboxylic styrene butadiene latex and high-phenylethylene latex, and the content of described high-phenylethylene latex is 10-20%.
Optimized technical scheme is in the present invention, and described neutral sizing agent is a cationoid reaction type glue used in paper-making.
Optimized technical scheme is in the present invention, and in described 0.6% wax emulsion and neutral sizing agent, the content of wax emulsion is 0.07%.
Optimized technical scheme is in the present invention, in described pulping process beating degree is controlled at 15-18 ° of SR, and weight in wet base is controlled at 15-20g.
Optimized technical scheme is in the present invention, and the addition of described dyestuff is 20-100g, and the addition of described wet strength agent is 1.5-4.0%.
Optimized technical scheme is in the present invention, and the time that described wet the brim of a hat paper is immersed in the latex mixed liquor was controlled between 10~20 seconds.
Optimized technical scheme is in the present invention, and described long mesh paper making machine has used Haber's formula long mesh paper making machine.
Optimized technical scheme is in the present invention, and described pulping process adopts hydrabrusher to pull an oar.
Optimized technical scheme is in the present invention, adds in the process of manufacturing paper with pulp of long mesh paper making machine at described paper pulp, and paper hat brim quantitatively is controlled at 1000-1600g/m 2, with the paper hat brim THICKNESS CONTROL at 2.3-2.5mm.
Paper hat brim paper board material of the present invention is with distinctive performance: both quantitative cardboard 1000-1600g/m 2, thickness 2.3mm~2.5mm, tensile strength 〉=1.8kn/cm 2, immersion after 4 hours tensile strength 〉=0.8kn/cm2, interlaminar strength 〉=0.40kn/m, deflection be controlled at 235mn.m~315mn.m scope, has good performance when guaranteeing the cap cardboard as the brim of a hat, easily processing, processing back product is indeformable, the advantage that deflection is moderate.
The theoretical foundation of adding various auxiliary materials in the present invention is:
1, the interpolation of cationic starch
At first determine the use of cationic starch.Starch is converted starch extensive use papermaking enterprise particularly, it generally can be divided into following several types (1) cationic starch is under the existence with starch and cationic etherifying agent, anticoagulant, add thermal response and generate quaternary amine type, tertiary amine-type starch, strong suction-operated takes place owing to itself have the fibrous particle of cation energy and electronegative property in the solution.Therefore, it is added in the slurry, can be used as retention, filter aid and reinforcing agent; (2) anionic starch is that chemical reactions such as starch and phosphate, acetate generate, but presents negative electrical charge because of it in solution, and is poor with fiber knot and property, so additive effect is not good in the slurry, generally is coated with as surperficial; (3) nonionic starch, be starch and epoxy alkyl etherifying agent be blended in add anticoagulant under the alkali condition after, heating makes, and generally is not used in the slurry to add.At this principle, for considering manufacturing paper with pulp of heavu weights, improve water filtering performance, improve the l Water Paper mass dryness fraction, and strengthen the cardboard splitting, so select 3%~6% cationic starch for use.Therefore, one of this basic foundation that designs for the present invention.
2, the interpolation of carboxylic styrene butadiene latex and high-phenylethylene emulsion mixed impregnant liquor
Synthetic latex obtains develop rapidly in recent years, its reason can fully remedy the source deficiency of natural rubber, and some specific function of giving goods, as intensity, oil resistant, tear-resistant etc., its major product has styrene-butadiene latex, polychloroprene latex, NBR latex, carboxylated latex, butadiene latex, isoprene rubber latex, butyl latex, ethylene propylene rubber latex, acrylic latex, polyvinylchloride latex, polyvinyl acetate latex, polystyrene latex, high styrene latex etc., and wherein carboxylic styrene butadiene latex is most widely used general in paper conversion, it is on the basis of styrene-butadiene latex, add suitable unsaturated carboxylic acid, and the formation ternary polymerization, thereby carboxylic styrene butadiene latex stability and aspect of performance have been had significantly to be improved, its mechanism: the carboxyl that (1) is aggregated on the macromolecular chain is hydrophilic, and main chain is hydrophobic, and this structure can form interparticle " barrier " makes latex obtain to stablize.(2) because carboxyl combines with main chain with chemical bond, can not disconnect because of external shearing force or other factors.(3) even carboxyl generation ionization repels each other with latex particle because of it is electronegative and to separate, thereby improves its stability.Therefore, carboxylic styrene butadiene latex infilters in the paper in that the papermaking process is easier, while carboxylic styrene butadiene latex mechanical stability height, can bear the shear action of process, excellent machinability is arranged, simultaneously with the paper of this dipping, by extremely strong stretching, tear-resistant, folding and moderate hardness and water repelling property.But the carboxylic styrene butadiene latex overall hardness is on the low side, at this, the present invention considers that molecule increases with styrene-content in the styrene-butadiene latex, the characteristics that its glued membrane hardening, intensity improve, the present invention suitably selects the 10-20% high styrene latex for use, reaching reinforcement and to improve moderate soft durometer index, two of the basic foundation that this designs for the present invention.
3, the interpolation of wax emulsion and neutral sizing agent
Heavu weights is opened and will be satisfied extremely strong water repelling property, the most critical paper surface must have certain hydrophobicity material, could stop entering of hydrone and obtain certain water repelling property, the tradition water repellent agent has gum rosin, sizing agent (AKD), the wax emulsion, paraffin, organosilicon etc., therefore the present invention has selected the wax emulsion for use, this is efficient hydrocarbon mixture, refuse water, anti-water electrode is strong, but consider the infiltration of dipping portion latex, the present invention has only added 0.05%~0.08% on a small quantity, select cationoid reaction type glue used in paper-making (SR) in a large number for use, this is epoxychloropropane and triethylene tetramine copolymer, starches interior interpolation, helps to combine with fiber, improve sizing efficiency, this for the present invention designs basic foundation three.
With the technical scheme in the foregoing description is example, and made paper hat brim can reach following technical indicator:
Index Unit Regulation
Thickness ??Mm ??2.4±0.20
Tightness ??g/cm 3 ??0.56±0.20
Tensile strength ??kN/cm 2 ??≥1.8
Immersion 4H tensile strength ??kN/cm 2 ??≥0.8
Splitting ??kN/cm ??≥0.40
Deflection (mean value) ??mN.m ??235--315
Immersion 1H percentage elongation ??% ??≤1.8
High temperature drying 1H shrinkage factor ??% ??≤1.5
The above only is a preferred implementation of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (10)

1, a kind of preparation method of paper hat brim is characterized in that, described preparation method comprises the steps:
S1: select for use the long fibre wood pulp to pull an oar in pulper, control beating degree and weight in wet base in pulping process, and then grind through mill, the paper pulp after will grinding is again put into dosing chamber;
S2: in dosing chamber, add a certain amount of dyestuff, wet strength agent again, add 3%~6% cationic starch simultaneously, add 0.3%~0.8% wax emulsion and neutral sizing agent;
S3: the slurries that prepare in the S2 step are imported sizing compartment, and the concentration of paper pulp in the stock tank is transferred to 0.8%~1%;
S4: the paper pulp that obtains in the S3 step joined in the long mesh paper making machine manufacture paper with pulp, and one-shot forming, in one-shot forming, several thes brim of a hat are linked to be integral body for sheet or drum;
S5: with the brim of a hat paper that obtains in the S4 step, with the most of moisture in the suction press equipment removal the brim of a hat paper;
S6: it is in 20%~35% the latex mixed liquor that the wet the brim of a hat paper that obtains in the S5 step is immersed concentration, satisfies simultaneously to suck 60%~70% latex mixed liquor in finished product the brim of a hat paper;
S7: with the wet the brim of a hat paper that obtains in the S6 step dry, sulfuration, press polish handle;
S8: the brim of a hat paper that obtains in the S7 step is cut into the single the brim of a hat, then the packing warehouse-in.
2, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, described latex mixed liquor is mixed by carboxylic styrene butadiene latex and high-phenylethylene latex, and wherein the content of high-phenylethylene latex is 10%~20%.
3, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, described neutral sizing agent is a cationoid reaction type glue used in paper-making.
4, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, in described 0.3%~0.8% wax emulsion and neutral sizing agent, the content of wax emulsion is 0.05%~0.08%.
5, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, in described pulping process beating degree is controlled at 15 °~18 ° SR, and weight in wet base is controlled at 15%~20g.
6, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, the addition of described dyestuff is 20g~100g, and the addition of described wet strength agent is 1.5%~4.0%.
7, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, the time that described wet the brim of a hat paper is immersed in the latex mixed liquor was controlled between 10~20 seconds.
8, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, described long mesh paper making machine is Haber's formula long mesh paper making machine.
9, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, described pulping process adopts hydrabrusher to pull an oar.
10, the preparation method of paper hat brim as claimed in claim 1 is characterized in that, adds in the process of manufacturing paper with pulp of long mesh paper making machine at described paper pulp, and paper hat brim quantitatively is controlled at 1000g/m 2~1600g/m 2Between, with the paper hat brim THICKNESS CONTROL between 2.3mm~2.5mm.
CN2009101800535A 2009-10-26 2009-10-26 Preparation method of paper hat brim Active CN101669699B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103215845A (en) * 2013-03-25 2013-07-24 江阴比图特种纸板有限公司 Black photo album page paper and preparation method thereof
CN103266530A (en) * 2013-04-15 2013-08-28 广东华凯特种纤维板科技有限公司 Brim material made from plant fiberboard and preparation method thereof
CN104631190A (en) * 2014-12-18 2015-05-20 温岭市得利纸业工艺有限公司 Craft paper processing craft
CN109736130A (en) * 2018-12-11 2019-05-10 广东华凯科技股份有限公司 A kind of jeans mark and preparation method thereof and handsheet steep glue detection method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB460102A (en) * 1935-10-17 1937-01-21 Victor Walter Webb Improvements in the production of blocks for hat manufacture
US7000553B1 (en) * 2004-12-27 2006-02-21 Tai-Kuang Wang Method for manufacturing headgear of a peeling off effect

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103215845A (en) * 2013-03-25 2013-07-24 江阴比图特种纸板有限公司 Black photo album page paper and preparation method thereof
CN103215845B (en) * 2013-03-25 2014-12-10 江阴比图特种纸板有限公司 Black photo album page paper and preparation method thereof
CN103266530A (en) * 2013-04-15 2013-08-28 广东华凯特种纤维板科技有限公司 Brim material made from plant fiberboard and preparation method thereof
CN103266530B (en) * 2013-04-15 2015-05-20 广东华凯特种纤维板科技有限公司 Brim material made from plant fiberboard and preparation method thereof
CN104631190A (en) * 2014-12-18 2015-05-20 温岭市得利纸业工艺有限公司 Craft paper processing craft
CN109736130A (en) * 2018-12-11 2019-05-10 广东华凯科技股份有限公司 A kind of jeans mark and preparation method thereof and handsheet steep glue detection method

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