CN101649072B - Full-degradable biological material and film product thereof - Google Patents
Full-degradable biological material and film product thereof Download PDFInfo
- Publication number
- CN101649072B CN101649072B CN2009100927238A CN200910092723A CN101649072B CN 101649072 B CN101649072 B CN 101649072B CN 2009100927238 A CN2009100927238 A CN 2009100927238A CN 200910092723 A CN200910092723 A CN 200910092723A CN 101649072 B CN101649072 B CN 101649072B
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- biological material
- degradable biological
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- 239000012620 biological material Substances 0.000 title claims abstract description 35
- 239000000463 material Substances 0.000 claims abstract description 37
- 229920002472 Starch Polymers 0.000 claims abstract description 19
- 239000008107 starch Substances 0.000 claims abstract description 19
- 235000019698 starch Nutrition 0.000 claims abstract description 19
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims abstract description 9
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 25
- 239000002994 raw material Substances 0.000 claims description 24
- 229920001610 polycaprolactone Polymers 0.000 claims description 22
- 239000004632 polycaprolactone Substances 0.000 claims description 22
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 20
- -1 polybutylene terephthalate Polymers 0.000 claims description 12
- 229920001896 polybutyrate Polymers 0.000 claims description 11
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 10
- 239000008116 calcium stearate Substances 0.000 claims description 10
- 235000013539 calcium stearate Nutrition 0.000 claims description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 10
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 10
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 235000012424 soybean oil Nutrition 0.000 claims description 10
- 239000003549 soybean oil Substances 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 230000004927 fusion Effects 0.000 claims description 5
- 239000011344 liquid material Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000002203 pretreatment Methods 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 abstract description 7
- 230000015556 catabolic process Effects 0.000 abstract description 4
- 238000006731 degradation reaction Methods 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 239000002361 compost Substances 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 238000006467 substitution reaction Methods 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 2
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000010408 film Substances 0.000 description 34
- 229920003023 plastic Polymers 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 230000003413 degradative effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000747 poly(lactic acid) Polymers 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Landscapes
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100927238A CN101649072B (en) | 2009-09-22 | 2009-09-22 | Full-degradable biological material and film product thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100927238A CN101649072B (en) | 2009-09-22 | 2009-09-22 | Full-degradable biological material and film product thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101649072A CN101649072A (en) | 2010-02-17 |
CN101649072B true CN101649072B (en) | 2011-03-16 |
Family
ID=41671411
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009100927238A Expired - Fee Related CN101649072B (en) | 2009-09-22 | 2009-09-22 | Full-degradable biological material and film product thereof |
Country Status (1)
Country | Link |
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CN (1) | CN101649072B (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102276906B (en) * | 2011-07-07 | 2012-11-28 | 刘立文 | Modified ethane-vinyl alcohol copolymer composite material and preparation technology thereof |
CN102796286A (en) * | 2012-08-28 | 2012-11-28 | 广东益德环保科技有限公司 | Full-biodegradable material and preparation method thereof |
CN102977565A (en) * | 2012-11-23 | 2013-03-20 | 金发科技股份有限公司 | Starch-containing biodegradable barrier-property film as well as preparation method and application thereof |
CN103881338B (en) * | 2012-12-19 | 2018-10-09 | 上海载和实业投资有限公司 | A kind of antistatic biodegradation material of novel flame-retardant and preparation method thereof |
CN104695135A (en) * | 2013-12-04 | 2015-06-10 | 上海杰事杰新材料(集团)股份有限公司 | Biodegradable non-woven fabric and preparation method thereof |
CN105273376B (en) * | 2014-08-29 | 2017-08-15 | 陈再荣 | A kind of biodegradation material and preparation method thereof and purposes |
CN105150510B (en) * | 2015-07-08 | 2018-03-16 | 内蒙古农业大学 | A kind of Wholly-degradable pla-pcl film and its production method and its purposes |
CN105295109A (en) * | 2015-10-19 | 2016-02-03 | 界首市佳宝包装材料有限公司 | Biodegradable instant noodle packaging bag |
CN107722570A (en) * | 2016-08-11 | 2018-02-23 | 汉达精密电子(昆山)有限公司 | Bioerodible starch membrane material and its film |
CN107189367A (en) * | 2017-06-12 | 2017-09-22 | 新疆蓝山屯河型材有限公司 | Pbs modification biological whole degrading film proprietary materials |
CN110157045A (en) * | 2018-03-12 | 2019-08-23 | 苏州睿烁环境科技有限公司 | A kind of plastics and preparation method thereof that degradation property is good |
CN111793332B (en) * | 2020-07-23 | 2022-07-29 | 宁夏中原塑业科技有限公司 | Biodegradable film material |
CN112759901A (en) * | 2020-12-29 | 2021-05-07 | 四川坤源杰环保科技有限公司 | Micro-crystallization toughening modified PBS or PBAT biodegradable composite material |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1037515C (en) * | 1993-08-24 | 1998-02-25 | 北京市星辰现代控制工程研究所 | Biodegradable composition containing starch and its producing method and its use |
CN1563162A (en) * | 2004-03-29 | 2005-01-12 | 郭志伟 | Starch based biodegradable flexible packing materials, and preparation method |
CN1622970A (en) * | 2002-03-29 | 2005-06-01 | 罗先高科技株式会社 | Biodegradable resin composition and manufacturing method thereof |
US20050288399A1 (en) * | 2004-06-25 | 2005-12-29 | Ming-Tung Chen | Biodegradable plastic composition and producing method thereof |
-
2009
- 2009-09-22 CN CN2009100927238A patent/CN101649072B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1037515C (en) * | 1993-08-24 | 1998-02-25 | 北京市星辰现代控制工程研究所 | Biodegradable composition containing starch and its producing method and its use |
CN1622970A (en) * | 2002-03-29 | 2005-06-01 | 罗先高科技株式会社 | Biodegradable resin composition and manufacturing method thereof |
CN1563162A (en) * | 2004-03-29 | 2005-01-12 | 郭志伟 | Starch based biodegradable flexible packing materials, and preparation method |
US20050288399A1 (en) * | 2004-06-25 | 2005-12-29 | Ming-Tung Chen | Biodegradable plastic composition and producing method thereof |
Also Published As
Publication number | Publication date |
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CN101649072A (en) | 2010-02-17 |
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Free format text: FORMER OWNER: SUN APIN ZHANG CHENGWEN Effective date: 20120718 |
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Effective date of registration: 20120718 Address after: 100061 Beijing city Chongwen district south street leading international building No. 3 room 1203 Patentee after: Ren Wei Address before: 100061 Beijing city Chongwen district south street leading international building No. 3 room 1203 Co-patentee before: Sun Apin Patentee before: Ren Wei Co-patentee before: Zhang Chengwen |
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