CN101643268A - Water treatment method for killing red worms with ultrasound-ozone - Google Patents

Water treatment method for killing red worms with ultrasound-ozone Download PDF

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CN101643268A
CN101643268A CN200910187238A CN200910187238A CN101643268A CN 101643268 A CN101643268 A CN 101643268A CN 200910187238 A CN200910187238 A CN 200910187238A CN 200910187238 A CN200910187238 A CN 200910187238A CN 101643268 A CN101643268 A CN 101643268A
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water
ozone
red worms
treatment method
ultrasonic
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潘晶
张阳
李光哲
王艳
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Shenyang Normal University
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Shenyang Normal University
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Abstract

The invention discloses a water treatment method for killing red worms with ultrasound-ozone, which is designed in order to solve the technical problems of low red worm death rate, increasing contentof carcinogen and mutagenic compounds such as disinfection by-products and the like in effluent and difficult insurance on safety water supply of a water works in the current water treatment method ofkilling red worms with a prechlorination process. The method is realized by the following steps: pre-introducing ozone to raw water before conventional processing; simultaneously utilizing ultrasonicwave with the frequency of 50HZ and the power of 120W to act on the raw water for 10-20min, thus all red worms in the treated raw water are killed and are completely and effectively removed in sequent coagulation, precipitation and filter water supply treatment processes. In addition, the introducing amount of ozone in raw water is 1-2mg per liter. The invention has the beneficial effects that the technique can effectively control the red worms in water, thereby ensuring the qualification of water quality index of effluent water. Compared with the current prechlorination process, the invention improves the security of water quality of water supply, and reduces the generation of three genicity compounds such as high-concentration chloride or trihalomethane and the like, thus effectively controlling the red worms and having better effects on the aspect of removing micropollutants.

Description

超声-臭氧杀灭红虫的水处理方法 Ultrasonic-Ozone Water Treatment Method for Killing Red Worms

技术领域: Technical field:

本发明涉及一种水处理方法,特别涉及一种杀灭水中红虫以便于其被有效去除的超声-臭氧杀灭红虫的水处理方法。The invention relates to a water treatment method, in particular to a water treatment method for killing bloodworms in water so as to be effectively removed by ultrasonic-ozone.

背景技术: Background technique:

我国南方城市气候常年温暖潮湿,适于昆虫繁殖,在地表水体普遍受到污染的情况下,水源容易滋生红虫,进入供水系统,成为困扰国内供水界的一个难题。红虫在用户水中出现,不仅违反了生活饮用水的卫生标准,更重要的是大多数红虫是水中致病生物的中间宿主,从而成为传播疾病的一个重要媒介,给人们的用水安全带来了很大的威胁。针对上述问题,多数水厂采用预氯化工艺来进行控制,但是在10mg/L投氯量下,接触30min,红虫只有28.9%的死亡率,同时存在以下缺点:一是采用预投氯的工艺增加了出水中的消毒副产物,如三卤甲烷、卤代乙酸等致癌、致突变物质的含量,对饮用水安全造成了影响;另一方面此工艺不能对红虫进行完全有效的去除,在滤池出水中仍能检测到有少量红虫的存在,使水厂的安全供水难以保证。The climate in southern cities in my country is warm and humid all year round, which is suitable for insect breeding. When surface water bodies are generally polluted, bloodworms are easy to breed in water sources and enter the water supply system, which has become a problem that plagues the domestic water supply industry. The appearance of red worms in user water not only violates the sanitary standards for drinking water, but more importantly, most red worms are the intermediate hosts of pathogenic organisms in water, thus becoming an important medium for spreading diseases and bringing great harm to people's water safety. a great threat. In response to the above problems, most water plants use pre-chlorination technology to control, but at 10mg/L chlorine dosage, after 30 minutes of exposure, bloodworms only have a 28.9% mortality rate, and there are the following disadvantages at the same time: First, the use of pre-chlorination The process increases the disinfection by-products in the effluent, such as the content of carcinogenic and mutagenic substances such as trihalomethanes and haloacetic acids, which affects the safety of drinking water; on the other hand, this process cannot completely and effectively remove red worms. A small amount of red worms can still be detected in the effluent from the filter, which makes it difficult to guarantee the safe water supply of the water plant.

发明内容: Invention content:

本发明为了解决采用预氯化工艺来进行控制,在10mg/L投氯量的情况下,接触30min,红虫只有28.9%的死亡率,同时存在增加了出水中的消毒副产物,如三卤甲烷、卤代乙酸等致癌、致突变物质的含量,对饮用水安全造成了影响及不能对红虫进行完全有效的去除,在滤池出水中仍能检测到有少量红虫的存在,使水厂的安全供水难以保证的技术问题,提供一种高效、安全的超声-臭氧杀灭红虫的水处理方法,该方法是通过以下步骤实现的:向常规处理前的原水中预通臭氧,每升原水中臭氧通入量为1-2mg,同时使用频率为50Hz的超声波,超声功率为120W,作用时间为10-20min,被处理原水中的红虫全部死亡,并在后续的混凝、沉淀、过滤给水处理工艺中得到彻底有效的去除。In order to solve the problem of using the prechlorination process to control the present invention, in the case of 10mg/L chlorine dosage, the red worm has only 28.9% mortality rate after contacting for 30 minutes, and there are disinfection by-products in the effluent, such as three halides. The content of carcinogenic and mutagenic substances such as methane and haloacetic acid has affected the safety of drinking water and cannot completely and effectively remove red worms. A small amount of red worms can still be detected in the effluent of the filter, making the water To solve the technical problem that it is difficult to guarantee the safe water supply of the plant, an efficient and safe ultrasonic-ozone water treatment method for killing red worms is provided. The amount of ozone in 1 liter of raw water is 1-2mg. At the same time, ultrasonic waves with a frequency of 50Hz are used. The ultrasonic power is 120W and the action time is 10-20min. , Filtration and water treatment process to be thoroughly and effectively removed.

本发明的有益效果:该技术能够有效的控制水中的红虫,保证出厂水的水质指标合格,具有现有工艺无法比拟的优越性。采用超声-臭氧的水处理技术比现行预投氯化工艺在供水水质安全性方面有了进一步的提高,减少了高浓度氯化物或三卤甲烷等“三致”化合物的生成。操作安全、方便。本发明不仅能够有效地控制红虫,而且在除微污染物方面也具有较好的效果。Beneficial effects of the present invention: the technology can effectively control the red worms in the water, ensure the water quality index of the factory water is qualified, and has the incomparable superiority of the existing technology. Compared with the current pre-chlorination process, the water treatment technology using ultrasonic-ozone has further improved the safety of water supply and reduced the formation of high-concentration chlorides or trihalomethanes. The operation is safe and convenient. The invention not only can effectively control bloodworms, but also has good effect in removing micro-pollutants.

超声降解水体中的有机污染物是一种极具发展潜力的水处理技术,具有良好的应用前景。Ultrasonic degradation of organic pollutants in water is a water treatment technology with great development potential and has a good application prospect.

附图说明: Description of drawings:

图1是超声-臭氧杀灭红虫的实验装置示意图。Figure 1 is a schematic diagram of an experimental device for killing red worms by ultrasonic-ozone.

图2是采用本发明方法对红虫的杀灭效果示意图。Fig. 2 is a schematic diagram of the effect of killing red worms by the method of the present invention.

具体实施方式: Detailed ways:

超声-臭氧杀灭红虫的水处理方法,是通过下述步骤实现的:首先向常规处理前的原水中预通臭氧,每升原水中臭氧通入量为1-2mg,同时使用频率为50Hz的超声波,超声功率为120W,作用时间为10-20min。The water treatment method of ultrasonic-ozone killing red worms is realized through the following steps: first, pre-pass ozone into the raw water before conventional treatment, the amount of ozone per liter of raw water is 1-2mg, and the use frequency is 50Hz at the same time Ultrasound, the ultrasonic power is 120W, and the action time is 10-20min.

实施例1:结合附图1、图2,超声-臭氧杀灭红虫的水处理方法,是通过下述步骤实现的:首先通过与氧气瓶1连接的臭氧发生器2向常规处理前的反应器3中的原水4中预通臭氧,每升原水中臭氧通入量为1mg,同时使用频率为50Hz的超声探头5向原水中放射超声波,超声功率为120W,作用时间为20min。被处理原水中的红虫全部死亡。并在后续的混凝、沉淀、过滤给水处理工艺中得到彻底有效的去除。Embodiment 1: in conjunction with accompanying drawing 1, Fig. 2, ultrasonic-ozone kills the water treatment method of red worm, realizes by following steps: at first by the reaction before the conventional treatment to the ozone generator 2 that is connected with oxygen bottle 1 The raw water 4 in the device 3 is pre-passed with ozone, and the amount of ozone per liter of raw water is 1 mg. At the same time, an ultrasonic probe 5 with a frequency of 50 Hz is used to radiate ultrasonic waves into the raw water. The ultrasonic power is 120 W and the action time is 20 minutes. Bloodworms in the treated raw water all died. And in the follow-up coagulation, sedimentation, filtration feed water treatment process to be thoroughly and effectively removed.

实施例2:结合附图1、图2,超声-臭氧杀灭红虫的水处理方法,是通过下述步骤实现的:首先通过与氧气瓶1连接的臭氧发生器2向常规处理前的反应器3中的原水4中预通臭氧,每升原水中臭氧通入量为2mg,同时使用频率为50Hz的超声探头5向原水中放射超声波,超声功率为120W,作用时间为10min。被处理原水中的红虫全部死亡。并在后续的混凝、沉淀、过滤给水处理工艺中得到彻底有效的去除。Embodiment 2: in conjunction with accompanying drawing 1, Fig. 2, the water treatment method that ultrasonic-ozone kills red worm is realized by following steps: first by the reaction before the conventional treatment to the ozone generator 2 that is connected with oxygen bottle 1 The raw water 4 in the device 3 is pre-passed with ozone, and the amount of ozone per liter of raw water is 2 mg. At the same time, an ultrasonic probe 5 with a frequency of 50 Hz is used to radiate ultrasonic waves into the raw water. The ultrasonic power is 120 W and the action time is 10 minutes. Bloodworms in the treated raw water all died. And in the follow-up coagulation, sedimentation, filtration feed water treatment process to be thoroughly and effectively removed.

实施例1-2中的氧气瓶1、臭氧发生器2和超声探头5为市售产品,试验中采用的采用氧气瓶1为40升(沈阳烨驰气体有限公司),臭氧发生器2为CHYF-3A臭氧发生器(杭州荣欣电子设备有限公司),超声探头5为88-1型探头式超声波发生器(中国科学院声学研究所)。Oxygen cylinder 1, ozone generator 2 and ultrasonic probe 5 among the embodiment 1-2 are commercially available products, adopting oxygen cylinder 1 in the test is 40 liters (Shenyang Yechi Gas Co., Ltd.), and ozone generator 2 is CHYF -3A ozone generator (Hangzhou Rongxin Electronic Equipment Co., Ltd.), ultrasonic probe 5 is a 88-1 type probe type ultrasonic generator (Institute of Acoustics, Chinese Academy of Sciences).

Claims (3)

1、超声-臭氧杀灭红虫的水处理方法,是通过下述步骤实现的:首先向常规处理前的原水中预通臭氧,每升原水中臭氧通入量为1-2mg,同时使用频率为50Hz的超声波,超声功率为120W,作用时间为10-20min。1. The water treatment method of ultrasonic-ozone killing red worms is realized through the following steps: first, pre-pass ozone into the raw water before conventional treatment, and the amount of ozone per liter of raw water is 1-2mg, and the frequency of use at the same time The ultrasonic wave is 50Hz, the ultrasonic power is 120W, and the action time is 10-20min. 2、根据权利1要求所述的超声-臭氧杀灭红虫的水处理方法,其特征在于:每升原水中臭氧通入量为1mg,同时使用频率为50Hz的超声波,超声功率为120W,作用时间为20min。2. The ultrasonic-ozone water treatment method for killing red worms according to claim 1, characterized in that: the amount of ozone per liter of raw water is 1 mg, and the ultrasonic wave with a frequency of 50 Hz is used at the same time, and the ultrasonic power is 120 W. The time is 20 minutes. 3、根据权利1要求所述的超声-臭氧杀灭红虫的水处理方法,其特征在于:每升原水中臭氧通入量为2mg,同时使用频率为50Hz的超声波,超声功率为120W,作用时间为10min。3. The ultrasonic-ozone water treatment method for killing red worms according to claim 1, characterized in that: the amount of ozone per liter of raw water is 2 mg, and the ultrasonic frequency is 50 Hz, and the ultrasonic power is 120 W. The time is 10 minutes.
CN200910187238A 2009-09-04 2009-09-04 Water treatment method for killing red worms with ultrasound-ozone Pending CN101643268A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103848491A (en) * 2014-03-27 2014-06-11 山东建筑大学 Killing method of red nematodes in biological aerated filter

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103848491A (en) * 2014-03-27 2014-06-11 山东建筑大学 Killing method of red nematodes in biological aerated filter

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Open date: 20100210