CN101642928A - Manufacturing method of anti-radiation marble wood-based panel - Google Patents
Manufacturing method of anti-radiation marble wood-based panel Download PDFInfo
- Publication number
- CN101642928A CN101642928A CN200910072706A CN200910072706A CN101642928A CN 101642928 A CN101642928 A CN 101642928A CN 200910072706 A CN200910072706 A CN 200910072706A CN 200910072706 A CN200910072706 A CN 200910072706A CN 101642928 A CN101642928 A CN 101642928A
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- CN
- China
- Prior art keywords
- radiation
- marble
- phi
- barite
- polyester resin
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 230000003471 anti-radiation Effects 0.000 title claims abstract description 13
- 241000342393 Zygia racemosa Species 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 23
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 21
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 15
- 239000004579 marble Substances 0.000 claims abstract description 14
- 239000010428 baryte Substances 0.000 claims abstract description 13
- 229910052601 baryte Inorganic materials 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 238000000465 moulding Methods 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 5
- 239000008187 granular material Substances 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 230000005855 radiation Effects 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 5
- 239000002245 particle Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 238000003825 pressing Methods 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002928 artificial marble Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000783 metal toxicity Toxicity 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses a manufacturing method of an anti-radiation marble wood-based panel. The anti-radiation marble wood-based panel can effectively block rays. The anti-radiation marble wood-basedpanel has good aesthetic feeling of the panel and can prevent the harm of strong radiation to human body. The process can realize environmental protection and energy conservation. The manufacturing method comprises the following process: mixing materials: 92-95% of barite material, 5-7% of unsaturated polyester resin and the balance of dry promoter. The barite material is formed by mixing three types of small particles with different sizes and barite powder with 150-200 meshes, wherein, 45% of the particles with phi 6-phi 8mm, 15%-18% of the particles with phi 3-phi 5mm, 15% of the particleswith phi 0.6-phi 2mm and the balance of the powder with 150-200 meshes. The materials are evenly stirred, then arranged in a mold, sent to the place under a press for molding, arranged in a drying boxfor heating after vacuum pumping while pressing, discharged out of a furnace with temperature keeping, placed and naturally cooled, thereby preparing the standard marble panel. The barite panel can not only be beautiful, but also block the harmful rays which harm the human body.
Description
Technical field
What the present invention relates to is a kind of novel environment friendly building and ornament materials, a kind of specifically novel environment friendly radiation proof multipurpose artificial marble ornament materials.
Background technology
Barite is the most common mineral of barium, and composition is barium sulfate (chemical name BaSO
4), be a kind of very important nonmetallic ore raw material, have the wide industrial purposes.For example, adopt barite particle to mix cement in pharmaceuticals industry and do the barrier shield material to hospital's x ray room, but radiation-resistant weak effect; Another purposes is to do the barium meal of perspective usefulness to the stomach patient.Industrial use is that oil exploitation enterprise water use mud mixing blanc fixe is made kill-job material etc.At present China to be used for doing the anti-ray material overwhelming majority of indoor shielding material be to adopt poisonous metal stereotype.Big and the energy natural evaporation of plumbous this heavy metal toxicity has very big injury, not environmental protection to human body.Particularly the radiation proof engineering of national defense industry of China and military installations more should be taken precautions against.
Summary of the invention
The objective of the invention is to disclose a kind of manufacturing method of anti-radiation marble wood-based panel.It can effectively stop ray.The sheet material aesthetic feeling is good, can stop the harm of intense radiation to human body again.Technology environmental protection, energy-conservation.
Manufacture method of the present invention comprises following technology: (following is weight ratio)
One, batch mixing: barite material, 92-95%; Unsaturated polyester resin 5-7%; All the other are drying promoter.
The barite material is to be mixed by 3 kinds of granules that differ in size and 150-200 purpose blanc fixe, and wherein: Φ 6-Φ 8 mm granules 45%, Φ 3-Φ 5 mm granules 15%-18%, Φ 0.6-Φ 2 mm granules 15%, all the other are 150-200 order powder.
Two, the mould of packing into after above-mentioned material is stirred is sent under 1200 tons of press and carries out moulding, vacuum is inhaled in the limit flanging, redundant stones is sucked out, then mould being put into constant temperature with the marble slab of the not demoulding is heating 4 hours in 115 ℃-120 ℃ the drying baker, insulation after coming out of the stove, placement is cooled off naturally, with anti-deformation.Treat the thoroughly cooling back demoulding, polish again, polish, cut and slot, make the marble slab of standard.
Described unsaturated polyester resin can be a kind of among unsaturated polyester resin CB.M.9605 or the unsaturated polyester resin CB.U.606.
Described drying promoter can be a kind of in colourless cobalt accelerator or the methyl ethyl ketone peroxide.
Anti-radiation marble wood-based panel of the present invention is not only attractive in appearance but also can block the harm ray that injures human body.
The specific embodiment
Embodiment 1
One, batch mixing: barite material, 92%; Unsaturated polyester resin 7%; All the other are drying promoter.
The barite material is to be mixed by 3 kinds of granules that differ in size and 150-200 purpose blanc fixe, and wherein: Φ 6-Φ 8 mm granules 45%, Φ 3-Φ 5 mm granules 15%-18%, Φ 0.6-Φ 2 mm granules 15%, all the other are 150-200 order powder.
Two, the mould of packing into after above-mentioned material is stirred is sent under 1200 tons of press and carries out moulding, vacuum is inhaled in the limit flanging, redundant stones is sucked out, then mould being put into constant temperature with the marble slab of the not demoulding is heating 4 hours in 115 ℃-120 ℃ the drying baker, insulation after coming out of the stove, placement is cooled off naturally, with anti-deformation.Treat the thoroughly cooling back demoulding, polish again, polish, cut and slot, make the marble slab of standard.
Described unsaturated polyester resin is unsaturated polyester resin CB.M.9605.
Described drying promoter is colourless cobalt accelerator.
Embodiment 2
One, batch mixing: barite material, 95%; Unsaturated polyester resin 4.9%; All the other are drying promoter.
The barite material is to be mixed by 3 kinds of granules that differ in size and 150-200 purpose blanc fixe, and wherein: Φ 6-Φ 8 mm granules 45%, Φ 3-Φ 5 mm granules 15%-18%, Φ 0.6-Φ 2 mm granules 15%, all the other are 150-200 order powder.
Two, the mould of packing into after above-mentioned material is stirred is sent under 1200 tons of press and carries out moulding, vacuum is inhaled in the limit flanging, redundant stones is sucked out, then mould being put into constant temperature with the marble slab of the not demoulding is heating 4 hours in 115 ℃-120 ℃ the drying baker, insulation after coming out of the stove, placement is cooled off naturally, with anti-deformation.Treat the thoroughly cooling back demoulding, polish again, polish, cut and slot, make the anti-radiation marble plate of standard.
Described unsaturated polyester resin is unsaturated polyester resin CB.U.606.
Described drying promoter is a methyl ethyl ketone peroxide.
Anti-radiation marble plate of the present invention is carried out the X ray transillumination test, and effect is very good.
1, experiment utensil: RF300EGS3X ray flaw detector, steel step bar.
2, experimental principle: under the identical parameters condition, the X ray transillumination is carried out in anti-radiation marble plate and step bar simultaneously and obtains egative film, relatively the blackness of egative film with determine the anti-radiation marble plate under a certain transillumination condition with the equivalent thickness of steel.
3, test sample; 1# sample: thickness t=22mm
4, experiment parameter: 1# sample: 210KV, 2.5min,
5, experimental data such as following table
As above shown in the table, thickness is that anti-radiation marble plate and the thickness of 22mm is that the steel plate radiation proof effect of 29mm is identical.
Claims (1)
1, a kind of manufacturing method of anti-radiation marble wood-based panel comprises following technology: (following is weight ratio)
One, batch mixing: barite material, 92-95%; Unsaturated polyester resin 5-7%; All the other are drying promoter;
The barite material is to be mixed by 3 kinds of granules that differ in size and 150-200 purpose blanc fixe, and wherein: Φ 6-Φ 8 mm granules 45%, Φ 3-Φ 5 mm granules 15%-18%, Φ 0.6-Φ 2 mm granules 15%, all the other are 150-200 order powder;
Two, the mould of packing into after above-mentioned material is stirred is sent under 1200 tons of press and carries out moulding, vacuum is inhaled in the limit flanging, redundant stones is sucked out, then mould being put into constant temperature with the marble slab of the not demoulding is heating 4 hours in 115 ℃-120 ℃ the drying baker, insulation after coming out of the stove, placement is cooled off naturally, with anti-deformation; Treat the thoroughly cooling back demoulding, polish again, polish, cut and slot, make the marble slab of standard; Described unsaturated polyester resin can be a kind of among unsaturated polyester resin CB.M.9605 or the unsaturated polyester resin CB.U.606; Described drying promoter can be a kind of in colourless cobalt accelerator or the methyl ethyl ketone peroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100727068A CN101642928B (en) | 2009-08-20 | 2009-08-20 | Manufacturing method of anti-radiation marble wood-based panel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100727068A CN101642928B (en) | 2009-08-20 | 2009-08-20 | Manufacturing method of anti-radiation marble wood-based panel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101642928A true CN101642928A (en) | 2010-02-10 |
| CN101642928B CN101642928B (en) | 2012-01-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100727068A Active CN101642928B (en) | 2009-08-20 | 2009-08-20 | Manufacturing method of anti-radiation marble wood-based panel |
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| CN (1) | CN101642928B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102298981A (en) * | 2011-05-18 | 2011-12-28 | 孙鹏 | Protective material and method for eliminating radiation of building material |
| CN102765901A (en) * | 2012-07-04 | 2012-11-07 | 四川省青川红源石业有限责任公司 | Novel high-performance hydrofluoric acid-resistance artificial functional composite plate and preparation method thereof |
| CN103042755A (en) * | 2012-11-15 | 2013-04-17 | 冷文魁 | Physical radiation-resistant wave-absorption artificial brocatelle slab and manufacturing method thereof |
| WO2014008726A1 (en) * | 2012-07-11 | 2014-01-16 | 北京珠峰天宫玉石科技发展有限公司 | Stone floor tile manufacturing method |
| CN103601422A (en) * | 2013-12-06 | 2014-02-26 | 王晓云 | Production method of anti-radiation artificial quartz stone plate |
| CN107089813A (en) * | 2017-03-25 | 2017-08-25 | 杭州科安辐射防护工程有限公司 | A kind of radiation-proof plate |
| CN107601969A (en) * | 2017-09-13 | 2018-01-19 | 河南双辐科技有限公司 | A kind of high-strength artificial barite plate of chopped carbon fiber and preparation method thereof |
| CN109483899A (en) * | 2017-09-13 | 2019-03-19 | 河南双辐科技有限公司 | A kind of high-strength artificial barite plate of carbon cloth and preparation method thereof |
| CN115572150A (en) * | 2022-09-29 | 2023-01-06 | 贵州大学 | Barite radiation-proof ceramic plate and preparation method thereof |
-
2009
- 2009-08-20 CN CN2009100727068A patent/CN101642928B/en active Active
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102298981A (en) * | 2011-05-18 | 2011-12-28 | 孙鹏 | Protective material and method for eliminating radiation of building material |
| CN102765901B (en) * | 2012-07-04 | 2014-02-12 | 四川省青川红源石业有限责任公司 | High-performance hydrofluoric acid-resistance artificial functional composite plate and preparation method thereof |
| CN102765901A (en) * | 2012-07-04 | 2012-11-07 | 四川省青川红源石业有限责任公司 | Novel high-performance hydrofluoric acid-resistance artificial functional composite plate and preparation method thereof |
| WO2014008726A1 (en) * | 2012-07-11 | 2014-01-16 | 北京珠峰天宫玉石科技发展有限公司 | Stone floor tile manufacturing method |
| CN103042755B (en) * | 2012-11-15 | 2014-12-10 | 冷文魁 | Physical radiation-resistant wave-absorption artificial brocatelle slab and manufacturing method thereof |
| CN103042755A (en) * | 2012-11-15 | 2013-04-17 | 冷文魁 | Physical radiation-resistant wave-absorption artificial brocatelle slab and manufacturing method thereof |
| CN103601422A (en) * | 2013-12-06 | 2014-02-26 | 王晓云 | Production method of anti-radiation artificial quartz stone plate |
| CN107089813A (en) * | 2017-03-25 | 2017-08-25 | 杭州科安辐射防护工程有限公司 | A kind of radiation-proof plate |
| CN107089813B (en) * | 2017-03-25 | 2019-06-14 | 科安环境工程技术有限公司 | A kind of radiation-proof plate |
| CN107601969A (en) * | 2017-09-13 | 2018-01-19 | 河南双辐科技有限公司 | A kind of high-strength artificial barite plate of chopped carbon fiber and preparation method thereof |
| CN109483899A (en) * | 2017-09-13 | 2019-03-19 | 河南双辐科技有限公司 | A kind of high-strength artificial barite plate of carbon cloth and preparation method thereof |
| CN115572150A (en) * | 2022-09-29 | 2023-01-06 | 贵州大学 | Barite radiation-proof ceramic plate and preparation method thereof |
| CN115572150B (en) * | 2022-09-29 | 2023-09-01 | 贵州大学 | Barite radiation-proof ceramic plate and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101642928B (en) | 2012-01-04 |
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Denomination of invention: Manufacturing method of anti-radiation marble wood-based panel Effective date of registration: 20180919 Granted publication date: 20120104 Pledgee: Hunan SME credit Company Limited by Guarantee Pledgor: HUNAN KND MEDICAL TECHNOLOGY CO.,LTD. Registration number: 2018430000068 |
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