CN101613567A - A kind of environment-friendly healthy matt floor paint - Google Patents
A kind of environment-friendly healthy matt floor paint Download PDFInfo
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- CN101613567A CN101613567A CN200910112220A CN200910112220A CN101613567A CN 101613567 A CN101613567 A CN 101613567A CN 200910112220 A CN200910112220 A CN 200910112220A CN 200910112220 A CN200910112220 A CN 200910112220A CN 101613567 A CN101613567 A CN 101613567A
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Abstract
A kind of environment-friendly healthy matt floor paint, be selected most advanced world starting material, by the first component: vegetables oil short-oil alkyd, solvent, dispersion agent, anti-settling agent, flatting silica, glass powder, defoamer, flow agent, wetting agent, second component polyisocyanate curing agent is formulated through science.The invention belongs to no purified petroleum benzin health type, have the high solid low viscosity, good leveling property; Strong adhesion, the hardness height, feel is good, impact resistance; Characteristics such as wear-resisting, water-fast, anti-various household cleaning agents.This invention price ratio height is applicable to that wood surfaces such as indoor luxurious floorboards of wood, stair cover with paint, lacquer, colour wash, etc., and can brush, spraying application, has vast market prospect.
Description
[affiliated technical field]
The present invention relates to a kind of plant oil environment-friendly type matt floor paint, particularly a kind of plant oil environment-friendly type matt floor paint.
[background technology]
According to incompletely statistics, every year is nearly hundreds thousand of because of the number of being poisoned to death that the indoor furniture finishing takes place, as seen, select healthy finishing material, especially Jian Kang paint healthy most important to the household, but at present in the many paint in domestic market benzene, exceeding standard of VOC (volatile organic compounds) have a strong impact on health.Benzene, VOC exceed standard and will cause the room organic contamination, and symptoms such as the occupant has a headache in serious causing, throat pain are detrimental to health.Free toluene diisocyanate (TDI) is the organic compound with intense stimulus gas.Skin, eyes and respiratory tract are had the intense stimulus effect, and the TDI steam of contact or high density can cause bronchitis, allergic asthma, pneumonia, pulmonary edema for a long time.Therefore in paint, adopt new vegetables oil system, not only meet the requirement of environment protection health, and have high performance film performance, satisfy the construction requirement of hard floor paint.
[summary of the invention]
The purpose of this invention is to provide a kind of vegetable oil type, cost performance height, meet the environment protection health requirement, have the high solid low viscosity, good leveling property; Strong adhesion, hardness height, impact resistance; The matt floor paint of characteristics such as wear-resisting, water-fast, anti-various household cleaning agents.
The present invention adopts following technical scheme to realize:
A kind of environment-friendly healthy matt floor paint, this paint are to be prepared in 1: 1 ratio by first, second component, form with the production technique manufacturing by general floor paint, wherein concrete composition of first, second component and proportioning following (mass ratio):
The first component:
Fatty acid modified high hydroxyl short-oil alkyd 40-50%
Fatty acid modified low viscosity short-oil alkyd 15-25%
Dispersion agent 0.1-0.3%
Anti-settling agent 0.3-0.5%
Antiwear assistant 0.3-0.7%
Flatting silica 1-3%
Glass powder 3-5%
Defoamer 0.1-0.7%
Flow agent 0.1-0.5%
Wetting agent 0.1-1%
Composite environmental-friendly solvent 20-30%
Second component: polyisocyanate curing agent.
Wherein raw material is described as follows:
Defoamer adopts powerful non-silicon defoaming agent, consists of polymer Vinyl Ether modification acrylic acid interpolymer solution.
Flow agent adopts polyether-modified polydimethylsiloxane interpolymer solution.
Wetting agent adopts the interpolymer solution with pigment affinity groups.
Antiwear assistant: the organic wax of fluorine modification.
Flatting silica: through 10% cured processing, median size 5.5-6.5um.
Glass powder: the VX-SP product that adopts Japanese TATSUMORI (dragon is gloomy) company to produce.
Anti-settling agent: hydrophobic type fumed silica.
The composite environmental-friendly solvent adopts methylcarbonate, n-butyl acetate, nitration mixture methyl esters, propylene glycol monomethyl ether amyl acetate to form, and wherein methylcarbonate 20%, n-butyl acetate 60%, nitration mixture methyl esters 10%, propylene glycol monomethyl ether amyl acetate 10%.
Polyisocyanate curing agent adopts the aromatic diisocyanate class.
The present invention is directed to the defective of existing floor paint and improved, from most advanced, up-to-date in the world industrial chemicals, select various material assembly through a large amount of testing sieves, adopt the experiment of many factor method of design, orthogonal experimental design method is determined component and weight percent thereof.The present invention has following major advantage:
1) adopted fatty acid modified high hydroxyl short-oil alkyd tool viscosity height, fullness ratio is good, anti scuffing, and cold-resistant thermal cycling excellence, fatty acid modified low viscosity short-oil alkyd tool hardness height, snappiness is good, and two kinds of resin collocation film qualities are better, and performance is good.
2) adopt most advanced in the world defoamer, flow agent, wetting agent auxiliary agent, satisfied the production and the construction requirement of current floor lacquer.
3) adopted most advanced in the world antiwear assistant, flatting silica, glass powder, guaranteed that the matte floor board paint wear resistance is good, feel is good.
4) the composite environmental-friendly solvent toxicity is low, smell is little, nontoxicity, and fully biodegradable does not definitely have benzene and VOC content meets health requirements.
5) second component: polyisocyanate curing agent and first component be in 1: 1 ratio, guaranteed the hard floor paint high-performance of filming.Solidifying agent free TDI content＜0.2% reaches European Union's standard, is higher than that national GB18581-2001 industry standard is leading has passed through the CCEL authentication, and its VOC and benzene content are lower than national standard, are the first-selections of Modern Family decoration.
[embodiment]
Below the invention will be further described:
A kind of environment-friendly healthy matt floor paint, this paint are to be prepared in 1: 1 ratio by first, second component, form with the production technique manufacturing by general floor paint, wherein concrete composition of first, second component and proportioning following (mass ratio):
The first component:
Fatty acid modified high hydroxyl short-oil alkyd 40-50%
Fatty acid modified low viscosity short-oil alkyd 15-25%
Dispersion agent 0.1-0.3%
Anti-settling agent 0.3-0.5%
Antiwear assistant 0.3-0.7%
Flatting silica 1-3%
Glass powder 3-5%
Defoamer 0.1-0.7%
Flow agent 0.1-0.5%
Wetting agent 0.1-1%
Composite environmental-friendly solvent 20-30%
Second component: polyisocyanate curing agent.
Embodiments of the invention one are as follows:
A kind of environment-friendly healthy matt floor paint, this paint are to be prepared in 1: 1 ratio by first, second component, form with the production technique manufacturing by general floor paint, wherein concrete composition of first, second component and proportioning following (mass ratio):
The first component:
Fatty acid modified high hydroxyl short-oil alkyd 40%
Fatty acid modified low viscosity short-oil alkyd 25%
Dispersion agent 0.1%
Anti-settling agent 0.3%
Antiwear assistant 0.7%
Flatting silica 1%
Glass powder 5%
Defoamer 0.7%
Flow agent 0.1%
Wetting agent 0.1%
Composite environmental-friendly solvent 27%
Second component: polyisocyanate curing agent.
Embodiments of the invention two are as follows:
A kind of environment-friendly healthy matt floor paint, this paint are to be prepared in 1: 1 ratio by first, second component, form with the production technique manufacturing by general floor paint, wherein concrete composition of first, second component and proportioning following (mass ratio):
The first component:
Fatty acid modified high hydroxyl short-oil alkyd 50%
Fatty acid modified low viscosity short-oil alkyd 15%
Dispersion agent 0.3%
Anti-settling agent 0.5%
Antiwear assistant 0.3%
Flatting silica 3%
Glass powder 3%
Defoamer 0.1%
Flow agent 0.5%
Wetting agent 1%
Composite environmental-friendly solvent 26.3%
Second component: polyisocyanate curing agent.
Embodiments of the invention three are as follows:
A kind of environment-friendly healthy matt floor paint, this paint are to be prepared in 1: 1 ratio by first, second component, form with the production technique manufacturing by general floor paint, wherein concrete composition of first, second component and proportioning following (mass ratio):
The first component:
Fatty acid modified high hydroxyl short-oil alkyd 42%
Fatty acid modified low viscosity short-oil alkyd 20%
Dispersion agent 0.2%
Anti-settling agent 0.4%
Antiwear assistant 0.4%
Flatting silica 2%
Glass powder 4%
Defoamer 0.5%
Flow agent 0.3%
Wetting agent 0.2%
Composite environmental-friendly solvent 30%
Second component: polyisocyanate curing agent.
Embodiments of the invention four are as follows:
The first component:
Vegetables oil short-oil alkyd A 48%
Vegetables oil short-oil alkyd B 24%
Dispersion agent 0.2%
Anti-settling agent 0.4%
Antiwear assistant 0.5%
Flatting silica 2%
Glass powder 4%
Defoamer 0.3%
Flow agent 0.2%
Wetting agent 0.4%
Composite environmental-friendly solvent 20%
Second component: polyisocyanate curing agent.
A preferred embodiment of the present invention is as follows:
A kind of environment-friendly healthy matt floor paint, this paint are to be prepared in 1: 1 ratio by first, second component, form with the production technique manufacturing by general floor paint, wherein concrete composition of first, second component and proportioning following (mass ratio):
The first component:
Vegetables oil short-oil alkyd A 40%
Vegetables oil short-oil alkyd B 24%
Dispersion agent 0.3%
Anti-settling agent 0.5%
Antiwear assistant 0.5%
Flatting silica 2%
Glass powder 3%
Defoamer 0.3%
Flow agent 0.3%
Wetting agent 0.1%
Composite environmental-friendly solvent 29%
Second component: polyisocyanate curing agent.
Every performance index of environment-friendly healthy matt floor paint of the present invention and explanation thereof, specifically see as following table one and table two:
Table one: environment-friendly healthy matt floor lacquer performance index
| Project | Unit | Technical indicator in the HG/T2454-2006 standard | Measured value |
| At condition in container | Stir evenly no lump of back | Symbol contains | |
| Application property | Apply accessible | Meet | |
| Time of drying | ??H | Surface drying≤1H does solid work≤24H | Surface drying≤1H does solid work≤8H |
| Appearance of film | Normally | Normally | |
| Package stability (50 ℃/7d) | No abnormal | No abnormal | |
| Gloss (60 °) | Decide through consultation | ||
| Pencil hardness (scratch) 〉= | ??H | ??2H | |
| Sticking power (drawing compartment) apart from 2mm≤ | ??1 | ??1 |
| Dry heat resistance ((90 ± 2) ℃, 15min)≤ | Level | ??2 | ??2 |
| Wear resistance (750g/500r)≤ | ??g | ??0.040 | ??0.036 |
| Shock-resistance | Film not have and come off, do not have cracking | Normally | |
| Water tolerance (24h) | No abnormal | No abnormal | |
| Alkali resistance (2h) | No abnormal | No abnormal | |
| Alcohol resistance (8h) | No abnormal | No abnormal | |
| Stain resistance (1h) tea and vinegar | No abnormal | No abnormal |
Can find out obviously that from table one every performance of the present invention all reaches or is higher than the GB standard, has confirmed high-performance of the present invention.
Table two: environment-friendly healthy matt floor lacquer technical requirements
The first component
| Project | Technical requirements |
| Solid content | ??43％ |
| Outward appearance | Pale yellow full impregnated is bright |
| Viscosity (rotational viscosimeter, 25 ℃) | ??450±100mpas |
| The construction ratio | First component: second component=1: 1 |
| Gel time (30 ℃, 75%) | More than 4 hours |
The second component
| Project | Technical requirements |
| Solid content | ??40％ |
| Outward appearance | Limpid transparent |
| Viscosity (being coated with-4,30 ℃) | 10.8 second |
| Free TDI content | ??0.1％ |
Table two technical requirements shows, VOC content and free TDI content are higher than the GB18581-2001 standard, take the lead to have passed through the CCEL authentication, and its VOC and benzene content are lower than national standard, the first-selection that is the Modern Family decoration meets the environment protection health requirement, and is safe and reliable.
Although the present invention has been done detailed explanation and some specific exampless is provided, to those skilled in the art, only otherwise leave that the spirit and scope of the present invention can be done various variations or correction is obvious.
Claims (10)
1, a kind of environment-friendly healthy matt floor paint is characterized in that: prepared in 1: 1 ratio by first, second component, form with the production technique manufacturing by general floor paint, wherein concrete composition of first, second component and proportioning following (mass ratio):
The first component:
Fatty acid modified high hydroxyl short-oil alkyd 40-50%
Fatty acid modified low viscosity short-oil alkyd 15-25%
Dispersion agent 0.1-0.3%
Anti-settling agent 0.3-0.5%
Antiwear assistant 0.3-0.7%
Flatting silica 1-3%
Glass powder 3-5%
Defoamer 0.1-0.7%
Flow agent 0.1-0.5%
Wetting agent 0.1-1%
Composite environmental-friendly solvent 20-30%
Second component: isocyanate curing agent.
2, a kind of environment-friendly healthy matt floor paint according to claim 1 is characterized in that described first component is specific as follows:
The first component:
Vegetables oil short-oil alkyd A 40%
Vegetables oil short-oil alkyd B 24%
Dispersion agent 0.3%
Anti-settling agent 0.5%
Antiwear assistant 0.5%
Flatting silica 2%
Glass powder 3%
Defoamer 0.3%
Flow agent 0.3%
Wetting agent 0.1%
Composite environmental-friendly solvent 29%.
3, a kind of environment-friendly healthy matt floor paint according to claim 1, it is characterized in that: described defoamer adopts powerful non-silicon defoaming agent, consists of polymer Vinyl Ether modification acrylic acid interpolymer solution.
4, a kind of environment-friendly healthy matt floor paint according to claim 1 is characterized in that: flow agent adopts polyether-modified polydimethylsiloxane interpolymer solution.
5, a kind of environment-friendly healthy matt floor paint according to claim 1 is characterized in that: wetting agent adopts the interpolymer solution with pigment affinity groups.
6, a kind of environment-friendly healthy matt floor paint according to claim 1 is characterized in that: antiwear assistant adopts the organic wax of fluorine modification.
7, a kind of environment-friendly healthy matt floor paint according to claim 1 is characterized in that: described flatting silica is through 10% cured processing, median size 5.5-6.5um.
8, a kind of environment-friendly healthy matt floor paint according to claim 1 is characterized in that: described anti-settling agent adopts the hydrophobic type fumed silica.
9, a kind of environment-friendly healthy matt floor paint according to claim 1, it is characterized in that: described composite environmental-friendly solvent adopts methylcarbonate, n-butyl acetate, nitration mixture methyl esters, propylene glycol monomethyl ether amyl acetate to form, wherein methylcarbonate 20%, n-butyl acetate 60%, nitration mixture methyl esters 10%, propylene glycol monomethyl ether amyl acetate 10%.
10, a kind of environment-friendly healthy matt floor paint according to claim 1 is characterized in that: described polyisocyanate curing agent adopts the aromatic diisocyanate class.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910112220 CN101613567B (en) | 2009-07-21 | 2009-07-21 | Environment-friendly healthy matt floor paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910112220 CN101613567B (en) | 2009-07-21 | 2009-07-21 | Environment-friendly healthy matt floor paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101613567A true CN101613567A (en) | 2009-12-30 |
| CN101613567B CN101613567B (en) | 2013-03-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910112220 Active CN101613567B (en) | 2009-07-21 | 2009-07-21 | Environment-friendly healthy matt floor paint |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948646A (en) * | 2010-09-29 | 2011-01-19 | 上海富臣化工有限公司 | Oil stain used for coloring wood lacquer, preparation method and coating method thereof |
| CN103555189A (en) * | 2013-10-22 | 2014-02-05 | 三棵树涂料股份有限公司 | Healthy and environment-friendly dual-component wear-resisting floor paint and preparation method thereof |
| CN103602235A (en) * | 2013-11-12 | 2014-02-26 | 惠州市长润发涂料有限公司 | PU (Polyurethane) quick-drying electrostatic spraying paint |
| CN104263232A (en) * | 2014-09-28 | 2015-01-07 | 三棵树涂料股份有限公司 | Healthy, environment-friendly and scratch-resistant matte top-coat paint and preparation method thereof |
| CN109852211A (en) * | 2019-01-15 | 2019-06-07 | 湖南康瑞涂料科技有限公司 | A kind of dumb light thixotropic coating |
| CN114149738A (en) * | 2021-11-12 | 2022-03-08 | 鹤山市君子兰涂料有限公司 | Polyurethane primer applied to melamine board |
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| CN1603374A (en) * | 2003-09-29 | 2005-04-06 | 上海富臣化工有限公司 | Polyurethane (PU polyester) antibacterial wood varnish (dull, clear) |
| CN101260634A (en) * | 2008-04-15 | 2008-09-10 | 陈伟 | Abrasion-proof insoluble glazing type furniture decorating paper and its method of production |
| CN101353552A (en) * | 2008-08-26 | 2009-01-28 | 佛山市顺德图业涂料有限公司 | Anti-scratching wood lacquer |
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2009
- 2009-07-21 CN CN 200910112220 patent/CN101613567B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1603374A (en) * | 2003-09-29 | 2005-04-06 | 上海富臣化工有限公司 | Polyurethane (PU polyester) antibacterial wood varnish (dull, clear) |
| CN101260634A (en) * | 2008-04-15 | 2008-09-10 | 陈伟 | Abrasion-proof insoluble glazing type furniture decorating paper and its method of production |
| CN101353552A (en) * | 2008-08-26 | 2009-01-28 | 佛山市顺德图业涂料有限公司 | Anti-scratching wood lacquer |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948646A (en) * | 2010-09-29 | 2011-01-19 | 上海富臣化工有限公司 | Oil stain used for coloring wood lacquer, preparation method and coating method thereof |
| CN103555189A (en) * | 2013-10-22 | 2014-02-05 | 三棵树涂料股份有限公司 | Healthy and environment-friendly dual-component wear-resisting floor paint and preparation method thereof |
| CN103555189B (en) * | 2013-10-22 | 2016-11-09 | 三棵树涂料股份有限公司 | Healthy and environment-friendlydual-component dual-component wear-resisting floor paint and preparation method thereof |
| CN103602235A (en) * | 2013-11-12 | 2014-02-26 | 惠州市长润发涂料有限公司 | PU (Polyurethane) quick-drying electrostatic spraying paint |
| CN103602235B (en) * | 2013-11-12 | 2016-02-10 | 惠州市长润发涂料有限公司 | The japanning of a kind of PU quick-drying electrostatic |
| CN104263232A (en) * | 2014-09-28 | 2015-01-07 | 三棵树涂料股份有限公司 | Healthy, environment-friendly and scratch-resistant matte top-coat paint and preparation method thereof |
| CN109852211A (en) * | 2019-01-15 | 2019-06-07 | 湖南康瑞涂料科技有限公司 | A kind of dumb light thixotropic coating |
| CN114149738A (en) * | 2021-11-12 | 2022-03-08 | 鹤山市君子兰涂料有限公司 | Polyurethane primer applied to melamine board |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101613567B (en) | 2013-03-20 |
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