CN101608494A - Environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall - Google Patents
Environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall Download PDFInfo
- Publication number
- CN101608494A CN101608494A CNA200810039005XA CN200810039005A CN101608494A CN 101608494 A CN101608494 A CN 101608494A CN A200810039005X A CNA200810039005X A CN A200810039005XA CN 200810039005 A CN200810039005 A CN 200810039005A CN 101608494 A CN101608494 A CN 101608494A
- Authority
- CN
- China
- Prior art keywords
- polyethers
- fire
- agent
- retardant
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 21
- 238000009413 insulation Methods 0.000 title claims abstract description 10
- 229920000570 polyether Polymers 0.000 claims abstract description 36
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012948 isocyanate Substances 0.000 claims abstract description 11
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 11
- 239000004604 Blowing Agent Substances 0.000 claims abstract description 10
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- 239000003381 stabilizer Substances 0.000 claims abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000001072 heteroaryl group Chemical group 0.000 claims abstract description 5
- 229920002545 silicone oil Polymers 0.000 claims abstract description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 3
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 claims abstract description 3
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims abstract description 3
- 235000011187 glycerol Nutrition 0.000 claims abstract description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 3
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 claims abstract description 3
- 229920002635 polyurethane Polymers 0.000 abstract description 7
- 239000004814 polyurethane Substances 0.000 abstract description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract description 3
- 150000002191 fatty alcohols Chemical class 0.000 abstract description 3
- 239000012774 insulation material Substances 0.000 abstract description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract description 3
- 235000011152 sodium sulphate Nutrition 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000000748 compression moulding Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- -1 therefore Substances 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
The present invention relates to a kind of environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall, its component and parts by weight comprise: blowing agent 20～40, isocyanates 130～500, polyethers 100～150, crosslinking agent 10～15, fire retardant 15～40, stabilizing agent 3～5, catalyzer 8～12, said blowing agent is an anion surfactant, comprise sodium sulfate of polyethenoxy ether of fatty alcohol or (with) neopelex etc.; Said polyethers comprises pentaerythrite ether, ethylenediamine polyethers, glycerin polyether or polyalcohol polyether etc.; Said crosslinking agent is that the heteroaromatic polyethers is or/and phenol is little molecule crosslinked dose.Said fire retardant is the polyethers of chloride element, can adopt commercially available back-fire relief polyethers, as the back-fire relief polyethers of new photochemical factory in Shanghai and Suzhou, Jiangsu evolution plant produced; Stabilizing agent is a silicone oil; Said catalyzer comprises triethylamine, triethyl group hydramine, tin acetate, dichloro dibutyl tin etc.; Polyurethane function admirable of the present invention, its fire resistance is more excellent, can be used for preparing the external-wall heat-insulation material with fire resistance.
Description
Technical field
The present invention relates to a kind of polyurethane sheet, relate in particular to a kind of environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall.Polyurethane plastics has purposes very widely, especially as heat insulating material, has obtained people's favor especially.At present existing many patents and document disclose the polyurethane plastics with various performances, reported a kind of base polyurethane prepolymer for use as that adds bromine class material and have fire resistance as Chinese patent CN1105676A, the part but the technology that this patent provided also comes with some shortcomings, its fire resistance is desirable not enough, oxygen index (OI) only is 26, can not satisfy the fire-retardant requirement of external-wall heat-insulation material.
Summary of the invention
The objective of the invention is to disclose a kind of environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall, to overcome the defective of prior art.The component and the parts by weight of the said environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall of the present invention comprise:
Blowing agent 20～40
Isocyanates 130～500
Polyethers 100～150
Crosslinking agent 10～15
Fire retardant 15～40
Stabilizing agent 3～5
Catalyzer 8～12
Preferably:
Blowing agent 30～35
Isocyanates 300～450
Polyethers 120～140
Crosslinking agent 10～13
Fire retardant 18～35
Stabilizing agent 3～4
Catalyzer 9～12
Be more preferably:
Blowing agent 30～32
Isocyanates 350～450
Polyethers 125～130
Crosslinking agent 10～12
Fire retardant 18～28
Stabilizing agent 3～4
Catalyzer 10～11
Said blowing agent is an anion surfactant, comprise sodium sulfate of polyethenoxy ether of fatty alcohol or (with) neopelex etc.; Said polyethers comprises pentaerythrite ether, ethylenediamine polyethers, glycerin polyether or polyalcohol polyether etc.; Said crosslinking agent is that the heteroaromatic polyethers is or/and phenol is little molecule crosslinked dose.Said fire retardant is the polyethers of chloride element, can adopt commercially available back-fire relief polyethers, as the back-fire relief polyethers of new photochemical factory in Shanghai and Suzhou, Jiangsu evolution plant produced; Stabilizing agent is a silicone oil; Said catalyzer comprises triethylamine, triethyl group hydramine, tin acetate, dichloro dibutyl tin etc.;
Each above-mentioned component is evenly mixed, in moulding press, adopt conventional method compression molding, be prepared into the required polyurethane plate that is used for exterior-wall heat insulation with fire resistance.Above-mentioned polyurethane has very excellent flame-retardant, adopts GB/T-2406.93 to carry out the test of fire resistance, and its result is as follows:
Oxygen index (OI): 34 ± 1.
By above-mentioned disclosed technical scheme as seen, because the present invention has adopted with isocyanates and has had the back-fire relief polyethers of reactivity worth preferably, and carry out structurally-modified to isocyanates, therefore, polyurethane function admirable of the present invention, especially fire resistance is more excellent, can be used for preparing the external-wall heat-insulation material with fire resistance.
Below will the present invention is further illustrated by embodiment.
The specific embodiment
Embodiment 1
Neopelex 26 grams, isocyanates 280 grams, back-fire relief polyethers 20 grams, heteroaromatic polyethers (how many grams), ethylenediamine polyethers 125 grams, triethylamine 9 grams and silicone oil 3 grams are mixed, and compression molding on moulding press cuts into sheet material.After tested, the result is as follows: oxygen index (OI): 34 ± 1.
Embodiment 2
With sodium sulfate of polyethenoxy ether of fatty alcohol 20 grams, isocyanates 250 grams, back-fire relief polyethers 25 grams, heteroaromatic polyethers (how many grams), ethylenediamine polyethers 125 grams, triethylamine 8 grams and silicone oil 3 grams, mix, compression molding on moulding press cuts into sheet material.After tested, the result is as follows: oxygen index (OI): 33 ± 1
Claims (3)
1. environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall is characterized in that, component and parts by weight are:
Blowing agent 20～40,
Isocyanates 130～500,
Polyethers 100～150,
Crosslinking agent 10～15,
Fire retardant 15～40,
Stabilizing agent 3～5,
Catalyzer 8～12,
Said blowing agent is an anion surfactant; Said polyethers comprises pentaerythrite ether, ethylenediamine polyethers, glycerin polyether or polyalcohol polyether; Said crosslinking agent is that the heteroaromatic polyethers is or/and phenol is little molecule crosslinked dose; Said fire retardant is the polyethers of chloride element; Stabilizing agent is a silicone oil; Said catalyzer is triethylamine, triethyl group hydramine, tin acetate or dichloro dibutyl tin.
2. environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall as claimed in claim 1 is characterized in that, component and parts by weight are:
Blowing agent 30～35,
Isocyanates 300～450,
Polyethers 120～140,
Crosslinking agent 10～13,
Fire retardant 18～35,
Stabilizing agent 3～4,
Catalyzer 9～12.
3. environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall as claimed in claim 1 is characterized in that, component and parts by weight are:
Blowing agent 30～32,
Isocyanates 350～450,
Polyethers 125～130,
Crosslinking agent 10～12,
Fire retardant 18～28,
Stabilizing agent 3～4,
Catalyzer 10～11.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200810039005XA CN101608494A (en) | 2008-06-16 | 2008-06-16 | Environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200810039005XA CN101608494A (en) | 2008-06-16 | 2008-06-16 | Environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101608494A true CN101608494A (en) | 2009-12-23 |
Family
ID=41482391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200810039005XA Pending CN101608494A (en) | 2008-06-16 | 2008-06-16 | Environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101608494A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911341A (en) * | 2012-11-08 | 2013-02-06 | 厦门纽优新型工艺有限公司 | Formula and process of fire retardance modified polyurethane insulation board |
| CN103130981A (en) * | 2013-03-20 | 2013-06-05 | 黎明化工研究设计院有限责任公司 | High-hardness thermoplastic polyurethane elastomer and preparation method thereof |
| CN103242647A (en) * | 2013-04-27 | 2013-08-14 | 大连理工大学 | A flame-retardant heat-resistant polyurethane foam and its preparation method |
| CN103242504A (en) * | 2013-04-27 | 2013-08-14 | 大连理工大学 | A kind of flame-retardant heat-resistant polyurethane resin and its aqueous emulsion preparation method |
| CN103265685A (en) * | 2013-05-28 | 2013-08-28 | 江苏华大新材料有限公司 | Microporous polyether urethane elastomer composite material and preparation method thereof |
| CN104211907A (en) * | 2014-09-05 | 2014-12-17 | 临夏市能成古典建筑装饰工程有限责任公司 | PU material for producing brick carvings and preparation method of PU material |
-
2008
- 2008-06-16 CN CNA200810039005XA patent/CN101608494A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911341A (en) * | 2012-11-08 | 2013-02-06 | 厦门纽优新型工艺有限公司 | Formula and process of fire retardance modified polyurethane insulation board |
| CN102911341B (en) * | 2012-11-08 | 2014-10-01 | 厦门纽优新型工艺有限公司 | Formula and process of fire retardance modified polyurethane insulation board |
| CN103130981A (en) * | 2013-03-20 | 2013-06-05 | 黎明化工研究设计院有限责任公司 | High-hardness thermoplastic polyurethane elastomer and preparation method thereof |
| CN103130981B (en) * | 2013-03-20 | 2015-01-21 | 黎明化工研究设计院有限责任公司 | High-hardness thermoplastic polyurethane elastomer and preparation method thereof |
| CN103242647A (en) * | 2013-04-27 | 2013-08-14 | 大连理工大学 | A flame-retardant heat-resistant polyurethane foam and its preparation method |
| CN103242504A (en) * | 2013-04-27 | 2013-08-14 | 大连理工大学 | A kind of flame-retardant heat-resistant polyurethane resin and its aqueous emulsion preparation method |
| CN103242647B (en) * | 2013-04-27 | 2015-06-17 | 大连理工大学 | A flame-retardant heat-resistant polyurethane foam and its preparation method |
| CN103242504B (en) * | 2013-04-27 | 2015-07-15 | 大连理工大学 | A kind of flame-retardant heat-resistant polyurethane resin and its aqueous emulsion preparation method |
| CN103265685A (en) * | 2013-05-28 | 2013-08-28 | 江苏华大新材料有限公司 | Microporous polyether urethane elastomer composite material and preparation method thereof |
| CN104211907A (en) * | 2014-09-05 | 2014-12-17 | 临夏市能成古典建筑装饰工程有限责任公司 | PU material for producing brick carvings and preparation method of PU material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101608494A (en) | Environment-friendly anti-seepage fire-retardant heat insulation super-strong decorative sheet for external wall | |
| CN103539932A (en) | Preparation method and applications of reaction type Mannich polyether polyol with permanent flame retardant effect | |
| CN101487297A (en) | Production method for multifunctional rigid foam polyurethane composite heat-conservation board | |
| CN102585138B (en) | Polyether polyol system for external wall spraying and preparation method | |
| CN101487299A (en) | Production method for multifunctional rigid foam polyurethane composite heat-conservation board | |
| CN107141435A (en) | The preparation method of polyesterether polyols, the polyurethane high-elastic foam plastic of its preparation method and its preparation and polyurethane high-elastic foam plastic | |
| CN104403075A (en) | Premixed polyether polyol for polyurethane insulation board for electrothermic floor heating system and application method of premixed polyether polyol | |
| CN101649653A (en) | Preparation method of modified phenolic foam composite insulation board | |
| CN104130368A (en) | Flame-retardant polyurethane cast rigid foamed plastic sheet | |
| CN105504204A (en) | Polyurethane heat preservation material | |
| CN105504203A (en) | Polyurethane rigid foam | |
| CN103113317A (en) | Trimethoxytripropanoloxy etherified amino resin, and preparation method and application thereof | |
| CN101280052A (en) | A solar insulation material | |
| CN113150236A (en) | Polyurethane foam product for ultralow temperature and preparation method thereof | |
| CN106478915A (en) | Polyurethane rigid foam exterior wall thermal insulation material and preparation method thereof | |
| CN102276778A (en) | Fire-retardant polyurethane hard foam material and preparation method thereof | |
| CN105542104A (en) | Polyurethane hard foam thermal-insulation material | |
| CN101139428B (en) | Method for preparing polyurethane foam plastics by using jatropha oil | |
| CN105601868A (en) | Rigid foam polyurethane thermal insulation material | |
| CN110157179B (en) | Environment-friendly heating material for floor and preparation method thereof | |
| CN104031358A (en) | Unsaturated resin fiberglass prepreg for low-temperature low-pressure molding as well as preparation method and application of unsaturated resin fiberglass prepreg | |
| CN115850862A (en) | Modified PP decorative film and preparation method thereof | |
| CN102060975A (en) | Preparation method of hard bubble polyurethane composition material for indoor door | |
| CN114940005A (en) | High-heat-insulation heat-preservation composite board and production process thereof | |
| CN105801839A (en) | Method for preparing cardanol modified flame-retardant polyether polyol |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20091223 |