CN101607796B - Method for producing low alkali cement by using high alkali raw materials - Google Patents
Method for producing low alkali cement by using high alkali raw materials Download PDFInfo
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- CN101607796B CN101607796B CN2009101574799A CN200910157479A CN101607796B CN 101607796 B CN101607796 B CN 101607796B CN 2009101574799 A CN2009101574799 A CN 2009101574799A CN 200910157479 A CN200910157479 A CN 200910157479A CN 101607796 B CN101607796 B CN 101607796B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/60—Methods for eliminating alkali metals or compounds thereof, e.g. from the raw materials or during the burning process; methods for eliminating other harmful components
Abstract
The invention provides a method for producing low alkali cement by using high alkali raw materials, which includes the steps of: putting the raw material limestone with alkali equivalent about 0.80% into a dry cement rotary kiln through a normal channel for putting the raw material into the kiln; adding chlorine-containing substances into the rotary kiln at the locations of a kiln head, a kiln head fuel burner, a flue chamber at kiln tail end, a pre-decomposition kiln or a pre-burning furnace; opening holes at the positions of the bottom part of the pre-decomposition kiln, an ascending flue channel, the flue chamber at kiln tail end or the tail grade cylinder of a pre-heater and inducting the chlorine-containing smoke gas enriched in the positions into a smoke dust collection system and collecting the smoke dust in the smoke gas. The smoke dust collection system comprises a mixing room. The method for producing low alkali cement by using high alkali raw materials uses the special property that alkali metal ions, chloride ions and sulfate ions mutually affect the melting point temperature under the high temperature coexistence condition, adds the chlorine-containing substances during the production process, and leads the chlorine in wastes to be reacted with the alkali in the raw materials by controlling the proportion between the alkali metal ions, chloride ions and sulfate ions entering the cement kiln, thereby achieving the double effects of reducing the alkali in the cement and processing high-chlorine wastes.
Description
Technical field
The present invention relates to a kind of method of producing cement and disposing waste, in particular, be that a kind of dry cement production line of band suspended preheater and predecomposition furnace and high alkalinity Wingdale of utilizing produced low alkali cement, and the method for high chlorine contents waste such as cooperative disposal PCB.
Background technology
In manufacture of cement, the alkali equivalent of raw material has direct influence to the quality of cement products.If (Na K), can improve the burn-ability of raw material, improves the early strength of raw material to contain micro-alkali in the raw material.If but the alkali equivalent in the raw material is too high, cause the alkali equivalent in the grog to surpass certain scope, for example greater than about 0.80% o'clock, can make that the free ca in the grog improves, cause strength of cement and folding strength to reduce, and influence the work-ing life of buildings.
According to statistics,, cause concrete generation alkali, can make the lost of life of buildings to 1/4th of normal buildings because the alkali equivalent is too high, in addition shorter.Therefore, using low alkali cement is an essential condition that guarantees the buildings life-span.
Produce low alkali cement,, certain requirement is arranged, generally need to use low alkali raw material produce low alkali cement as the alkali equivalent of clay and sandstone etc. just to Wingdale and other raw materials.But in China, a large amount of high-alkali normal limestone resources is arranged, these Wingdales are thrown aside because the alkali equivalent is too high, and this has not only wasted a large amount of resources, has also taken a large amount of soils.
At present, mostly concentrate on both at home and abroad and utilize on the low alkali raw material production low alkali cement, though high-alkali raw material production low alkali cement is had certain research, but research is not deeply, technology is still immature, and the process energy consumption of the high-alkali raw material production low alkali cement of existing use is very big, and technique controlling difficulty is also very big.When utilizing traditional technology, need carry out certain transformation to the production technique of cement clinker with high-alkali raw material production low alkali cement, will be to the deleterious element of cement clinker, as, excessive N a and K separate from kiln system, to reduce the alkali equivalent in the grog.But this need leak informaton from system in a large number, and the amount of leaking informaton can reach the 20-30% of systematic air flow usually, has increased the energy consumption of producing cement clinker greatly, has also increased the difficulty of technology controlling and process simultaneously.Nonetheless, make also to differ in this way and produce qualified low alkali cement surely.Therefore, this technology is not used on a large scale.
Need a large amount of low alkali cements on the market on the one hand, the deficiency of low alkali raw material makes the supply of low alkali cement can not satisfy the demand of low alkali cement far away on the other hand.So, press for a kind of method effective, energy-conservation, that can utilize high-alkali raw material production low alkali cement now.
Summary of the invention
The invention provides the method for the high-alkali raw material production low alkali cement of a kind of usefulness, comprising step:
(1) the alkali equivalent being gone into the kiln channel greater than about 0.80% raw material limestone by raw material drops in the dry method cement rotary kiln;
(2) at kiln hood, kiln hood fuel burner, kiln tail smoke-box, nsp kiln or pre-burner place chlorine-bearing compound is added in the dry method cement rotary kiln, so that the chlorine in the described chlorine-bearing compound consumes the potassium in the raw material;
(3) in the nsp kiln bottom, funnel uptake, kiln tail smoke-box or preheater final stage tube position opening, the chloride flue gas of these position enrichments is introduced in the flue dust collecting system, collect flue dust wherein.
This method mainly utilizes KCl can be converted into solid-state this characteristic by gaseous state in 760 ℃, content by the suitable increase cement kiln Cl of system makes free K combine with Cl, for example, add the Cl that is enough in conjunction with alkali excessive in the high-alkali raw material (K), make it participate in reaction, solid-state KCl is drawn in suitable position in kiln system then, reaches the purpose of K content in the reduction system, thereby realizes utilizing high-alkali raw material production low alkali cement.The flue dust of collecting contains a large amount of KCl, can reclaim use, for example as compound products etc.
Comprise mixing section in this flue dust collecting system, at first enter mixing section after the above-mentioned chloride flue gas of pyritous takes out, mix, flue-gas temperature is descended fast with the freezing air of introducing.Therefore, can make the KCl in the flue gas become solid-state separating out fast.
Preferred used chlorine-bearing compound is high chloride waste, for example is rich in the useless transformer insulated wet goods of polychlorobiphenyl PCB.Like this, the low alkali cement of not only having used high-alkali raw material production can also reach the technique effect of the high chlorine-containing waste of associated treatment.
The chlorinity of the chlorine-bearing compound that uses in preferred this method is greater than about 10%, to reduce to add the volume of material.More preferably, the amount of the chlorine-bearing compound that adjust to add, in mole, the amount of chlorine that makes adding is greater than (amount of potassium sodium amount sum-2 * sulfate radical in the system), and less than the molar weight of potassium in the system, described system comprises the chlorine-bearing compound of high-alkali raw material and adding.Do not contain potassium, sodium and sulfate ion in the preferred chlorine-bearing compound that adds.Because the molten boiling point of sodium sulfate and vitriolate of tartar is higher than Repone K, the gaseous bases metal ion preferentially combines with sulfate ion, so,, the molar weight of chlorine can be adjusted into poor greater than potassium sodium amount sum and twice sulphate amount in the system for the basic metal in the removal system more effectively.In this scope, both the basic metal in the effectively removal system can not introduced excessive chlorine again, avoided causing secondary pollution and tail gas to exceed standard.The alkali equivalent of the low alkali cement of preferably, producing is lower than about 0.60%.
In the nsp kiln bottom, the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position can account for about 1-10% of systematic air flow.Get the gas choice of location in the nsp kiln bottom, funnel uptake, kiln tail smoke-box or preheater final stage tube, be because chloride flue gas, mainly be that wherein Repone K composition reaches enrichment herein, so only need take out a fraction of flue gas that accounts for systematic air flow, 1-10% for example, can reach the purpose that reduces alkali equivalent and cl content in the production system, and can not influence the operation of whole manufacture of cement, and energy consumption also reduces greatly.More preferably, the flue gas that only need in nsp kiln bottom, funnel uptake, kiln tail smoke-box or the taking-up of preheater final stage tube position accounts for the about 1-4% of systematic air flow can be realized above-mentioned purpose, has further reduced energy consumption.More preferably, when bleed off passage is positioned at funnel uptake, get tolerance be not more than about 3%, the purpose that can realize producing low alkali cement and cooperative disposal chlorine-containing waste.
The high-temperature flue gas that takes out after treatment, temperature is at 300-450 ℃, these high temperature wind can be used to dry the crude fuel of producing cement or reclaim by special equipment, with the thermal source as other purposes.Especially when the flue gas that takes out accounts for the 4-10% of systematic air flow, the heat recuperation of flue gas can be used, for example be used for generating electricity, heat, dry crude fuel or other purposes, thereby can further save the energy.
Description of drawings
Fig. 1 is the schematic flow sheet of explanation an embodiment of the invention.
Embodiment
Below in conjunction with description of drawings the specific embodiment of the present invention; should understand; these embodiments all are exemplary; the present invention is not limited to embodiment disclosed herein, and those skilled in the art can suitably revise according to disclosing herein and not deviate from spirit of the present invention and protection domain.
As shown in Figure 1, as the raw material of producing cement, enter dry method cement rotary kiln by 1 feed system with high-alkali raw material, this dry method cement rotary kiln is a kind of dry method cement rotary kiln with suspended preheater and predecomposition furnace.The alkali equivalent is higher than 0.80% in the raw material in the adding kiln system, generally is not suitable for producing low alkali cement, and wherein the alkali equivalent is with Na
2O+0.658K
2The O meter.According to the alkali equivalent in the high-alkali raw material that adds, a place or many places in kiln hood, kiln hood fuel burner, kiln tail smoke-box, nsp kiln or pre-burner add an amount of chlorine-bearing compound in the kiln as (equipment that feed intake such as spray gun or feeding pump) with 2 chlorine-bearing compound throwing devices.The amount of the chlorine-bearing compound that is added should be enough to reduce the level that the alkali equivalent in the finished product cement extremely allows, and for example less than 0.6%, obtains the low alkali cement product.Simultaneously, because Na
2SO
4And K
2SO
4Molten boiling point be higher than KCl, the gaseous bases metal ion has precedence over the sulfate ion combination, more up hill and dale alkalimetal ion is removed from kiln system for more effective, the amount of the chlorine-bearing compound that may command adds, make wherein the difference of amount that deducts the sulfate radical of twice in the amount of the chlorine of mole greater than the amount of sodium potassium in the whole kiln system that comprises high-alkali raw material and chlorine-bearing compound, that is the amount of chlorine＞(amount of the amount of sodium potassium-2 * sulfate radical).Make its amount (in mole) simultaneously, exceed standard with secondary pollution and the tail gas of avoiding excessive chlorine to cause less than potassium in the described system.Also should control the kind of the chlorine-bearing compound of adding, in system, not introduce sulfate ion and basic ion again, as far as possible as sodium and potassium.The preferably high chlorine-containing waste of chlorine-bearing compound, for example (PCB is one of 12 kinds of persistence organic pollutants paying close attention in the world at present to polychlorobiphenyl PCB, once be widely used in transformer and capacitor insulation oil, easer, dye dispersant and the agent of agricultural chemicals prolongation of effect etc.), or domestic garbage incineration flyash (flying dust is in the burning city domestic garbage process, residual substance in that flue gas purification system is collected wherein often contains a large amount of chlorine), pesticide D-D T and phenyl-hexachloride etc.When utilizing high-alkali raw material production low alkali cement, also dispose high chloride waste, further realized the technique effect of environmental protection of the present invention.
High chlorine-bearing compound can be liquid in the adding kiln system, also can be solid-state, and preferred cl content is more than 10%.The chlorine-bearing compound that adds and the reaction equation of the alkali in the high-alkali raw material are as follows:
When adding PCB:
mK
2O+(29-0.5m)O
2+2C
12H
10-mCl
m→2mKCl+24CO
2+(10-m)H
2O (1)
When adding other chlorinated organics:
zK
2O+(2x+0.5y-0.5z)O
2+2C
xH
yCl
z→2zKCl+2xCO
2+yH
2O (2)
zK
2O+(2x+0.5y-0.5z-r)O
2+2C
xH
yCl
zO
r→2zKCl+2xCO
2+yH
2O (3)
As described in above-mentioned chemical formula, the chlorine-bearing compound that adds enters in the kiln and the high-alkali raw material reaction that has participated in the manufacture of cement, K in the high-alkali raw material combines with Cl in the chlorine-bearing compound of adding, because temperature is higher in the kiln, KCl with gaseous form in the flue gas of cement system in the nsp kiln bottom, funnel uptake, kiln tail smoke-box or preheater final stage tube (the about 900-1000 of the flue-gas temperature of these positions ℃) position enrichment.As shown in Figure 1, in 3 nsp kilns bottom, funnel uptake, kiln tail smoke-box or preheater final stage tube position opening, the chloride flue gas of enrichment is herein introduced in 4 mixing sections, in 4 mixing sections, flue gas is cooled to below 760 ℃, preferred below 700 ℃, utilize KCl in 760 ℃, can be converted into solid-state this characteristic by gaseous state, KCl is cooled to solid-state separating out, collection contains the ash of KCl, reclaims chemical substance wherein.
The flue dust collecting system can comprise cooling system and dust-removal system.Cooling system can comprise various devices that can fast cooling known in the art such as settling pocket, mixing section, and for example, the chloride flue gas of taking-up is introduced into and mixes with freezing air in the mixing section, and temperature descends fast, and KCl becomes solid-state separating out; The flue dust that settles down is delivered in the ash-storing bin by spiral conveyer.Dust-removal system can comprise the various devices that can be used for collecting flue dust known in the art such as cyclone, bag filter and dust precipitator.The flue dust of collecting can be by pipeline transportation to special storing device, and the potassium sodium content in the flue dust is higher, is used as the chemical industry raw material after can reclaiming and uses.
As shown in Figure 1, chloride flue gas is lowered the temperature in 4 mixing sections, and KCl is cooled to solid-state separating out, and the flue dust that settles down is delivered in 8 ash-storing bins by spiral conveyer.Simultaneously, the flue dust of collecting in 6 tornado dust collector and 7 sack cleaners is also delivered in 8 ash-storing bins by spiral conveyer.KCl in 8 ash-storing bins can reclaim and fully utilize.
The chloride flue gas that takes out can be with its heat recovery and utilization because temperature is higher.When the exhaust gas volumn of taking out is about 1-4% of systematic air flow, can and reclaim the oven dry that flue dust flue gas afterwards is used for the manufacture of cement crude fuel with the cooling dedusting, also can enter atmosphere by total blowdown system.For example, shown in Fig. 1, remaining hot blast is sent to the oven dry crude fuel after 6 tornado dust collector dedustings.When the amount of the flue gas that takes out is about 4-10% of systematic air flow, can use 5 interchanger when in 4 mixing sections, collecting the flue dust that contains KCl and/or after collecting flue dust, heat in the flue gas of drawing stored or be transferred in the other system and use by heating agent, for example afterheat generating system can also be used for waste heat heating.Flue gas after the dedusting can also be sent to and be used to dry crude fuel in the crude fuel preparation system.
The heat that interchanger obtains can further be delivered in the system that can utilize waste heat by medium such as water or thermal oil, for example heating installation or device for generating power by waste heat.In the cement kiln system, the temperature of gas reduces from front to back gradually in the kiln, and temperature of charge raises from front to back gradually.But from the inside flue gas chlorinity of cement kiln system, the place of enrichment in the nsp kiln bottom, position, particularly funnel uptake such as funnel uptake, kiln tail smoke-box or preheater final stage tube.So the present invention is from collecting the angle of Repone K, the place of taking out flue gas is chosen in positions such as nsp kiln bottom, funnel uptake, kiln tail smoke-box or preheater final stage tube to reach the purpose of the wherein unnecessary alkali of removal.Collect after the Repone K, residue has the words of heat to recycle.That is to say, be not main purpose of the present invention for the recovery of waste heat, and only be to attach a technique effect that obtains.Even in the embodiment that reclaims surplus heat, mixing section also should be installed in before the interchanger, that is to say that high-temperature flue gas after most of flue dust is removed in the mixing section cooling, enters interchanger earlier again, and surplus heat is reclaimed.This is because if be introduced into interchanger, though reclaimed heat more fully, the flue dust of a large amount of sedimentary KCl of containing is easy to stop up interchanger, causes the damage of equipment, increases production cost.
In addition, volatile matter circulation enrichments such as alkali, chlorine, sulphur in precalcining system, the skinning that causes easily decomposing pre-heating system cooling melting knot stops up, in technical scheme of the present invention, by leaking informaton, the KCl that not only can get rid of its middle and high concentration can also get rid of easy cooling and melt the objectionable impurities that knot causes skinning.
In brief, the present invention has compared following advantage with traditional technology of utilizing high-alkali raw material production low alkali cement:
1. can utilize high-alkali raw material production low alkali cement, solve a large amount of environmental problems of bringing such as occupation of land on the shelf of high-alkali raw material simultaneously;
2. energy consumption is low, and is less to the cement kiln influence.Because the hot blast rate that will take out from kiln system required for the present invention seldom, only accounts for the 1-10% of system's total blast volume, even still less, 1-4%, be significantly less than the 20-30% of the extraction air quantity that needs in the conventional art, reduced energy consumption, and the adding of chlorine makes the removal of excessive alkali more effective;
3. do not increase the technique controlling difficulty of cement kiln.The air quantity that takes out from cement kiln is more little, just more little to the influence of whole cement industry.Therefore, present method is compared with traditional method, and technique controlling difficulty reduces greatly;
4. the kind of all right cooperative disposal waste when utilizing high-alkali raw material production low alkali cement, and increase cement kiln disposal waste.Because Cl can produce adverse influence to the cement kiln system, as, cause system jams, influence product performance.Therefore, general cement kiln system can not dispose and contain the higher waste of Cl amount.And method provided by the present invention makes Cl play the effect of " catalyzer ", therefore neither can have a negative impact to cement kiln system and cement products itself, and the disposal for high chlorine-containing waste provides a new method again;
5. solve the problem of oven dry crude fuel shortage of heat.In the conventional art, after the cement kiln synergic processing waste, can cause the hot blast water content of oven dry crude fuel to raise, influence drying effect.In preferred implementation of the present invention, can utilize and extract the entrained heat oven dry raw materials and fuel of flue gas out, even the heat that reclaims can be used for generating, heating etc.;
6. reduced the formation of skinning to a certain extent, prolonged the duration of service of equipment, reduced production cost from another angle.
Be example with PCB and flying dust below, exemplary illustration the present invention.
Embodiment 1
3000 tons of certain cement mill production line daily output cement clinkers are (about 3000 tons in hectic fever raw material, about 4500 tons in raw material) (using the dry method cement rotary kiln of band suspended preheater and nsp kiln), in cement kiln extra add the Cl element before the constituent content of raw material and cement products see the following form 1 and table 2.
Table 1 is gone into each constituent content (%) in the hot raw material of kiln
| SiO 2 | Al 2O 3 | Fe 2O 3 | CaO | MgO | K 2O | Na 2O | P 2O 5 | Cl | SO 3 |
| 16.19 | 4.99 | 3.02 | 69.72 | 2.40 | 1.72 | 0.22 | 0.124 | 0.511 | 0.62 |
Each constituent content (%) in table 2 cement
| SiO 2 | Al 2O 3 | Fe 2O 3 | CaO | MgO | K 2O | Na 2O | SO 3 |
| 23.48 | 7.87 | 3.16 | 57.06 | 2.53 | 1.16 | 0.14 | 2.53 |
Under this condition, the alkali equivalent of cement products is 0.14%+0.658 * 1.16%=0.90328%, greater than 0.60%, does not meet the requirement of low alkali cement.
The amount that calculates the chlorine of adding should be greater than 14.7 tons, less than 38.97 tons, and formula (4) and (5) as follows.In kiln system, add PCB30 ton, Cl content 60% by kiln hood.2% of systematic air flow is extracted out from the nsp kiln tip position by the system of leaking informaton, and the flue gas of extracting out is handled, gather up KCl wherein.Add after the PCB, each constituent content of the cement products of producing sees Table 3.
3000 * [35.5 (1.72% ÷, 94 * 2+0.22% ÷, 62 * 2-2 * 0.62% ÷ 80)-0.511%]=14.7. ton (4)
3000 * 35.5 * 1.72% ÷, 94 * 2=38.97 ton (5)
Each constituent content (%) in the cement after the table 3 interpolation Cl
| SiO 2 | Al 2O 3 | Fe 2O 3 | CaO | MgO | K 2O | Na 2O | SO 3 |
| 24.67 | 8.26 | 3.21 | 57.46 | 2.45 | 0.63 | 0.13 | 2.73 |
The alkali equivalent that adds the cement products of producing behind the PCB is 0.13%+0.658 * 0.63%=0.54454%, less than 0.60%, meets the requirement of low alkali cement.
Embodiment 2
3000 tons of cement clinkers of certain cement mill production line daily output (dry method cement rotary kiln of band suspended preheater and nsp kiln), in the cement kiln extra add the Cl element before the constituent content of raw material and cement products shown in table 4, table 5.
Table 4 is gone into each constituent content (%) in the hot raw material of kiln
| SiO 2 | Al 2O 3 | Fe 2O 3 | CaO | MgO | K 2O | Na 2O | P 2O 5 | Cl | SO 3 |
| 16.29 | 5.29 | 3.12 | 68.91 | 2.35 | 1.82 | 0.27 | 0.12 | 0.471 | 0.65 |
Each constituent content (%) in table 5 cement
| SiO 2 | Al 2O 3 | Fe 2O 3 | CaO | MgO | K 2O | Na 2O | SO 3 |
| 23.38 | 7.88 | 3.19 | 57.06 | 2.63 | 1.26 | 0.16 | 2.73 |
The amount that calculates the chlorine of adding should be greater than 19.07 tons, less than 41.24 tons of formula (6) and (7) as follows.
In kiln system, per hour add 7.5 tons of flying dusts, Cl content 12% by kiln hood.And by 10% extraction of device provided by the invention with systematic air flow, through entering interchanger after the mixing section cooling, with heat-conducting oil heating in the interchanger, thermal oil provides heat for other heat-needing facility to hot flue gas more earlier.Flue gas after coming out from interchanger is through the cyclone dedusting, and collects the dust that contains KCl.Part gas is used for oven dry preparation cement raw fuel, and other other enter qualified discharge after the sack cleaner purifying treatment.Add after the flying dust, each constituent content of the cement products of producing is as shown in table 6.
3000 * [35.5 (1.82% ÷, 94 * 2+0.27% ÷, 65 * 2-2 * 0.65% ÷ 80)-0.511%]=19.07 tons (6)
3000 * 35.5 * 1.82% ÷, 94 * 2=41.24 ton (7)
Each constituent content (%) in the cement after the table 6 interpolation Cl
| SiO 2 | Al 2O 3 | Fe 2O 3 | CaO | MgO | K 2O | Na 2O | SO 3 |
| 23.58 | 8.19 | 3.18 | 59.06 | 2.50 | 0.60 | 0.12 | 2.68 |
The alkali equivalent that adds the cement products of producing behind the flying dust is 0.12%+0.658 * 0.60%=0.5148%, less than 0.60%, meets the requirement of low alkali cement.
Though described the present invention in conjunction with specific embodiments at this; but be understood that the present invention is not limited to these disclosed embodiments; on the contrary, the present invention's scope required for protection contains various changes and the equivalent in the spirit and scope that are included in claims.
Claims (16)
1. method with high-alkali raw material production low alkali cement, comprising step:
(1) the alkali equivalent being gone into the kiln channel greater than 0.80% raw material limestone by raw material drops in the dry method cement rotary kiln;
(2) place or the many places in kiln hood, kiln hood fuel burner, kiln tail smoke-box, nsp kiln or pre-burner add chlorine-bearing compound in the dry method cement rotary kiln, so that the chlorine in the described chlorine-bearing compound consumes the potassium in the raw material;
(3) in the nsp kiln bottom, funnel uptake, kiln tail smoke-box or preheater final stage tube position opening, the chloride flue gas of these position enrichments is introduced in the flue dust collecting system, collect flue dust wherein,
Wherein, comprise mixing section in the described flue dust collecting system, described chloride flue gas at first enters in the mixing section and mixes with freezing air, so that described chloride flue-gas temperature descends fast.
2. the method for claim 1, the chlorinity of wherein said chlorine-bearing compound is greater than 10%.
3. method as claimed in claim 1 or 2, wherein, adjust the amount of the described chlorine-bearing compound that adds, in mole, the amount of chlorine that makes adding is greater than (amount of potassium sodium amount sum-2 * sulfate radical in the system), and less than the amount of potassium in the system, described system comprises the chlorine-bearing compound of described high-alkali raw material and adding.
4. method as claimed in claim 1 or 2, the alkali equivalent of wherein said low alkali cement is lower than 0.60%.
5. method as claimed in claim 3, the alkali equivalent of wherein said low alkali cement is lower than 0.60%.
6. as claim 1,2 or 5 described methods, wherein in the nsp kiln bottom, the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position accounts for the 1-10% of systematic air flow.
7. method as claimed in claim 3, wherein in the nsp kiln bottom, the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position accounts for the 1-10% of systematic air flow.
8. method as claimed in claim 4, wherein in the nsp kiln bottom, the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position accounts for the 1-10% of systematic air flow.
9. method as claimed in claim 6, wherein in the nsp kiln bottom, the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position accounts for the 1-4% of systematic air flow.
10. as claim 7 or 8 described methods, wherein in the nsp kiln bottom, the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position accounts for the 1-4% of systematic air flow.
11. method as claimed in claim 6 is wherein got gas at funnel uptake, the chloride flue gas of taking-up accounts for the 1-3% of systematic air flow.
12. as claim 7 or 8 described methods, wherein get gas at funnel uptake, the chloride flue gas of taking-up accounts for the 1-3% of systematic air flow.
13. method as claimed in claim 6, wherein in the nsp kiln bottom, when the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position accounts for the 4-10% of systematic air flow, with the heat recovery and utilization in the chloride flue gas that takes out.
14. as claim 7 or 8 described methods, wherein in the nsp kiln bottom, when the chloride flue gas that takes out of funnel uptake, kiln tail smoke-box or preheater final stage tube position accounts for the 4-10% of systematic air flow, with the heat recovery and utilization in the chloride flue gas that takes out.
15. method as claimed in claim 13, wherein said recycling comprises: with the crude fuel of described heat generating, heating and oven dry cement production.
16. method as claimed in claim 14, wherein said recycling comprises: with the crude fuel of described heat generating, heating and oven dry cement production.
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| CN101785953B (en) * | 2010-03-19 | 2012-02-22 | 东南大学 | Device and method for removing harmful components from gas in cement kiln by utilizing cross-flow moving bed |
| CN102121704A (en) * | 2010-11-10 | 2011-07-13 | 中国建材装备有限公司 | Method for using rice hulls as fuel of cement kiln |
| CN105130225A (en) * | 2015-07-30 | 2015-12-09 | 铜陵海源超微粉体有限公司 | Cracking-resistant low-alkali environment-friendly gel material |
| CN105110665A (en) * | 2015-07-30 | 2015-12-02 | 铜陵海源超微粉体有限公司 | Anti-crack low-alkali environmental-friendly cement and preparation method therefor |
| CZ306932B6 (en) * | 2016-07-07 | 2017-09-20 | Miloš Faltus | A method of obtaining soluble salts of precious alkali metals of Li, Rb and Cs from silicate minerals |
| CZ307465B6 (en) * | 2017-06-16 | 2018-09-19 | Vysoká škola chemicko-technologická v Praze | A method for obtaining Li compounds |
| CN111635153B (en) * | 2020-05-25 | 2022-05-13 | 南阳中联卧龙水泥有限公司 | Cement firing kiln system |
| CN112608049B (en) * | 2020-12-16 | 2022-08-23 | 天津水泥工业设计研究院有限公司 | Cyclic preheating low-energy-consumption carbon-enriched cement production system and method |
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| CN87108216A (en) * | 1987-12-29 | 1988-12-21 | 天津碱厂 | The method of making cement from ammonia-soda fag-end |
| CN1223626A (en) * | 1996-05-24 | 1999-07-21 | 桑杰瑞克国际有限公司 | Systematic method for making shotcrete and the like cementitious compositions and such compositions |
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Effective date of registration: 20161124 Address after: Du Village in Shanxi province 037500 Datong Guangling County Jiao Shan Patentee after: GUANGLING BBMG CEMENT CO., LTD. Address before: 102202 Beijing Changping District City, Ma Chi Kou Zhen Bei Xiao Ying Cun East Beijing cement limited liability company Patentee before: Beijing Jinyu Hongshulin Environment Protecting Techn Co., Ltd. Patentee before: Beijing Xinbeishui Cement Co., Ltd. |