CN101602976A - Anticorrosive oil composition that uses in a kind of metal processing and preparation method thereof - Google Patents
Anticorrosive oil composition that uses in a kind of metal processing and preparation method thereof Download PDFInfo
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- CN101602976A CN101602976A CNA2009100117052A CN200910011705A CN101602976A CN 101602976 A CN101602976 A CN 101602976A CN A2009100117052 A CNA2009100117052 A CN A2009100117052A CN 200910011705 A CN200910011705 A CN 200910011705A CN 101602976 A CN101602976 A CN 101602976A
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 18
- 239000002184 metal Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000003672 processing method Methods 0.000 title abstract description 4
- 239000003921 oil Substances 0.000 claims abstract description 54
- 239000000344 soap Substances 0.000 claims abstract description 24
- 239000003208 petroleum Substances 0.000 claims abstract description 18
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012964 benzotriazole Substances 0.000 claims abstract description 13
- 150000002148 esters Chemical class 0.000 claims abstract description 13
- 239000002199 base oil Substances 0.000 claims abstract description 8
- 239000010687 lubricating oil Substances 0.000 claims description 14
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 14
- 238000012545 processing Methods 0.000 claims description 12
- 239000004166 Lanolin Substances 0.000 claims description 11
- 229940039717 lanolin Drugs 0.000 claims description 11
- 235000019388 lanolin Nutrition 0.000 claims description 11
- 229910052788 barium Inorganic materials 0.000 claims description 9
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- 241000158728 Meliaceae Species 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- -1 alkenyl succinic acid ester Chemical class 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 4
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- QRHDSDJIMDCCKE-UHFFFAOYSA-N 4-ethyl-2h-benzotriazole Chemical compound CCC1=CC=CC2=C1N=NN2 QRHDSDJIMDCCKE-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 8
- 239000002131 composite material Substances 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000012360 testing method Methods 0.000 abstract description 5
- 210000004243 sweat Anatomy 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 230000000295 complement effect Effects 0.000 abstract description 2
- 238000011156 evaluation Methods 0.000 abstract description 2
- 238000006386 neutralization reaction Methods 0.000 abstract description 2
- 239000012266 salt solution Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- BQPPJGMMIYJVBR-UHFFFAOYSA-N (10S)-3c-Acetoxy-4.4.10r.13c.14t-pentamethyl-17c-((R)-1.5-dimethyl-hexen-(4)-yl)-(5tH)-Delta8-tetradecahydro-1H-cyclopenta[a]phenanthren Natural products CC12CCC(OC(C)=O)C(C)(C)C1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21C BQPPJGMMIYJVBR-UHFFFAOYSA-N 0.000 description 2
- CHGIKSSZNBCNDW-UHFFFAOYSA-N (3beta,5alpha)-4,4-Dimethylcholesta-8,24-dien-3-ol Natural products CC12CCC(O)C(C)(C)C1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21 CHGIKSSZNBCNDW-UHFFFAOYSA-N 0.000 description 2
- XYTLYKGXLMKYMV-UHFFFAOYSA-N 14alpha-methylzymosterol Natural products CC12CCC(O)CC1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21C XYTLYKGXLMKYMV-UHFFFAOYSA-N 0.000 description 2
- FPTJELQXIUUCEY-UHFFFAOYSA-N 3beta-Hydroxy-lanostan Natural products C1CC2C(C)(C)C(O)CCC2(C)C2C1C1(C)CCC(C(C)CCCC(C)C)C1(C)CC2 FPTJELQXIUUCEY-UHFFFAOYSA-N 0.000 description 2
- BKLIAINBCQPSOV-UHFFFAOYSA-N Gluanol Natural products CC(C)CC=CC(C)C1CCC2(C)C3=C(CCC12C)C4(C)CCC(O)C(C)(C)C4CC3 BKLIAINBCQPSOV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- LOPKHWOTGJIQLC-UHFFFAOYSA-N Lanosterol Natural products CC(CCC=C(C)C)C1CCC2(C)C3=C(CCC12C)C4(C)CCC(C)(O)C(C)(C)C4CC3 LOPKHWOTGJIQLC-UHFFFAOYSA-N 0.000 description 2
- CAHGCLMLTWQZNJ-UHFFFAOYSA-N Nerifoliol Natural products CC12CCC(O)C(C)(C)C1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21C CAHGCLMLTWQZNJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- QBSJHOGDIUQWTH-UHFFFAOYSA-N dihydrolanosterol Natural products CC(C)CCCC(C)C1CCC2(C)C3=C(CCC12C)C4(C)CCC(C)(O)C(C)(C)C4CC3 QBSJHOGDIUQWTH-UHFFFAOYSA-N 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- CAHGCLMLTWQZNJ-RGEKOYMOSA-N lanosterol Chemical compound C([C@]12C)C[C@@H](O)C(C)(C)[C@H]1CCC1=C2CC[C@]2(C)[C@H]([C@H](CCC=C(C)C)C)CC[C@@]21C CAHGCLMLTWQZNJ-RGEKOYMOSA-N 0.000 description 2
- 229940058690 lanosterol Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000003405 preventing effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Landscapes
- Lubricants (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Anticorrosive oil composition that uses in a kind of metal processing and preparation method thereof has solved problems such as existing slushing oil rust-proof effect is poor, oil film is too thick, be difficult to remove; It adopts ester class, 0.2-0.5% benzotriazole and the derivative of the polymeric carboxylic of sulfonated petro-leum, 26-35% of base oil, the 37.5%-52% of 15-20% and soap class, 4.5-7% is raw material, through heating, stir and make; The present invention adopts multiple inhibiter compound, on rustless property, brought into play and learnt from other's strong points to offset one's weaknesses, complementary super effect compound action, its use properties and effect have produced great breakthrough, its rustless property will be far superior to the performance of the synthetic slushing oil of single agent, and antirust bench testing and evaluation have been passed through to optimize fully, has the wet antirust function of excellent moisture resistance, and has an excellent anti-salt solution aggressiveness, the ability of water substituting, acid neutralization and sweat control has reached the specification of quality of film, multiple-effect, environment-friendly antirust oil composite additive.
Description
Technical field:
The present invention relates to a kind of inhibition tensio-active agent, anticorrosive oil composition that uses in particularly a kind of metal processing and preparation method thereof.
Background technology:
According to relevant medium statistics, at present, the iron and steel weight of losing because of the burn into corrosion every year is about as much as the 10-20% of metal annual production in the world.The U.S. is annual because the Direct Loss that steel corrosion causes are about 1,379 hundred million dollars, and the mechanical industry of China accounts for about 7.2% of the mechanical industry gross output value in the amount of loss aspect the corrosion, estimates annual hundred million yuan of 600-800.So, very important by the direct and indirect loss that metallic corrosion brings, caused the attention of all trades and professions, the protection against corrosion problem has become an important topic of China's metal processing industry.
At present, internal lube oil market slushing oil product category is various, but because slushing oil product technology development imbalances, mostly be the low-function slushing oil product of single agent modulation coupling, low, middle-grade slushing oil product category is more, high-grade slushing oil product category is less, and its low grade products mainly contains: sulfonate, lanolin magnesium soap, ester class, benzotriazole and derivative etc.Lanolin magnesium soap says it is the mixture of lanolin magnesium soap and unsaponifiables lanosterol from structure, has certain antirust function, but the oil soluble of lanolin magnesium soap is bad, dissolving not exclusively in oil, part lanosterol and small amount of hydroxyl groups acid soap do not dissolve and cause slushing oil opaque, turbid phenomenon is serious, time has been grown also and the layering and precipitating phenomenon can occur, influence rustless property, anti-rust-proof effect is undesirable, and oil film is too thick, influence profile, be difficult to remove, cost is higher, is difficult to satisfy cash and belongs to the requirement of processing with the slushing oil high speed development.
Summary of the invention:
The technical problem to be solved in the present invention is, overcome problems such as existing slushing oil rust-proof effect is poor, oil film is too thick, be difficult to remove, anticorrosive oil composition that uses in the metal processing thin, removing, favorable rust preventing effect easily of a kind of oil film thickness and preparation method thereof is provided, can satisfy except that the antirust function of lines of the hand inter process short term preservation, can satisfy again that the precision sizing of mantle is indoor seals the rustless property requirement for a long time up for safekeeping.
The anticorrosive oil composition that uses in the metal processing of the present invention is made of following substances according to mass percent:
Base oil: 15-20%
Sulfonated petro-leum: 37.5-52%
Polymeric carboxylic and soap class: 26-35%
Ester class: 4.5-7%
Benzotriazole and derivative: 0.2-0.5%
Get above-mentioned composition 2-17% and be diluted to 100%, can use with the 120# solvent oil.
Described base oil comprises lubricating oil 75SN or lubricating oil 150SN or lubricating oil 350SN or lubricating oil N15.
Described sulfonated petro-leum comprises barium mahogany sulfonate T701 or petroleum sodium sulfonate T702 or calcium mahogany sulfonate T101.
Described polymeric carboxylic and soap class comprise petroleum oxidate ester barium soap T743 or lanolin magnesium soap or lanolin aluminium soap.
Described ester class comprises sorbitol monooleate SP-80 or alkenyl succinic acid ester T747 or glycerol boric acid ester fatty acid ester.
Described benzotriazole and derivative thereof comprise benzotriazole T706 or tolyltriazole or ethyl benzotriazole.
The preparation method of the anticorrosive oil composition that uses in the above-mentioned metal processing is:
The base oil of 15-20% is added in the still, be warming up to 80-110 ℃, add the sulfonated petro-leum of 37.5%-52%, polymeric carboxylic and the soap class of 26-35% again, after treating its dissolving, add ester class, 0.2-0.5% benzotriazole and the derivative of 4.5-7%, stirred 2-3 hour, after the filtration, be anticorrosive oil composition of the present invention, get above-mentioned composition 2-17% and be diluted to 100%, can use with the 120# solvent oil.
The invention has the advantages that:
The present invention adopts multiple inhibiter composite synergistic to improve its rustless property, and base oil is the carrier of slushing oil recombiner, and the Van der Waals force and the antirust adsorption film of the common formation of rust-preventive agent molecule of oil molecule is provided simultaneously; Barium mahogany sulfonate T701 in the sulfonated petro-leum has excellent anti salt fog, the wet antirust function of moisture resistance, be that the soft film anti-rust oil recombiner is the indoor antirust major function agent of sealing up for safekeeping for a long time, petroleum sodium sulfonate T702 has in excellent replacement of human sweat and the moisture film and the metathetical antirust function, be to remove the antirust main antirust function agent of lines of the hand type inter process short-term, also better complex effect arranged simultaneously with other rust-preventive agent; Polymeric carboxylic and soap class are better membrane-forming agents, simultaneously, the antirust function of good resistance salt fog are arranged also; Ester class rust-preventive agent has antirust function preferably, bigger solubleness is arranged and surpass the antirust function of imitating with the compound generation of host; Though benzotriazole and derivative oil soluble are slightly poor, non-ferrous metal is had good antirust and corrosion inhibition, particularly improve rustless property to copper with cupric ion formation inner complex, also can produce the composite synergistic effect with sulfonated petro-leum; The present invention adopts multiple inhibiter compound, on rustless property, brought into play and learnt from other's strong points to offset one's weaknesses, complementary super effect compound action, its use properties and effect have produced great breakthrough, formed a kind of higher-grade, many performances composite type anti-rust oil, its rustless property will be far superior to the performance of the synthetic slushing oil of single agent, and antirust bench testing and evaluation have been passed through to optimize fully, has the wet antirust function of excellent moisture resistance, the rust prevention test data value all＞720h, the 720h that is equivalent to U.S. MIL-C-standard A level, the salt fog resistance test can reach 188h, the 168h that is equivalent to Japanese 7IS-K-standard A level, and has an excellent anti-salt solution aggressiveness, water substituting, the ability of acid neutralization and sweat control, simultaneously, it is evenly thin to have film again, remove well, transparent attractive in appearance and to be in harmonious proportion technology simple, lower-cost characteristics, its rustless property can satisfy the antirust function that removes lines of the hand type of displacement of people's sweat and operation short term preservation, reach the indoor dilution type soft film anti-rust oil performance of sealing up for safekeeping for a long time of the higher metal products of working accuracy again, reached film, multiple-effect, the specification of quality of environment-friendly antirust oil composite additive.
Embodiment:
Embodiment 1:
The lubricating oil 75SN of 30kg is added in the still, be warming up to 80 ℃, the petroleum oxidate ester barium soap T743 that adds barium mahogany sulfonate T701, the 52kg of 104kg again, after treating its dissolving, add the benzotriazole T706 of sorbitol monooleate SP-80, the 1kg of 13kg, stirred 2 hours, after the filtration, be the A product of anticorrosive oil composition of the present invention, get A product 4kg, can use with the dilution of 196kg 120# solvent oil.
Embodiment 2:
The lubricating oil 150SN of 32kg is added in the still, be warming up to 90 ℃, add the petroleum sodium sulfonate T702 of 102kg, the lanolin magnesium soap of 56.6kg again, after treating its dissolving, add the alkenyl succinic acid ester T747 of 9kg, the tolyltriazole of 0.4kg, stirred 3 hours, after the filtration, be the B product of anticorrosive oil composition of the present invention, get B product 6kg, can use with the dilution of 194kg 120# solvent oil.
Embodiment 3:
The lubricating oil 350SN of 40kg is added in the still, be warming up to 100 ℃, the lanolin aluminium soap that adds calcium mahogany sulfonate T101, the 70kg of 75kg again, after treating its dissolving, add the glycerol boric acid ester fatty acid ester of 14kg, the ethyl benzotriazole of 1kg, stirred 2.5 hours, after the filtration, be the C product of anticorrosive oil composition of the present invention, get C product 8kg, can use with the dilution of 192kg120# solvent oil.
Embodiment 4:
The lubricating oil N15 of 36kg is added in the still, be warming up to 105 ℃, the lanolin aluminium soap that adds barium mahogany sulfonate T701, the 68kg of 84kg again, after treating its dissolving, add the sorbitol monooleate SP-80 of 11.2kg, the tolyltriazole of 0.8kg, stirred 2 hours, after the filtration, be the D product of anticorrosive oil composition of the present invention, get D product 32kg, can use with the dilution of 168kg 120# solvent oil.
Embodiment 5:
The lubricating oil 350SN of 34kg is added in the still, be warming up to 110 ℃, the petroleum oxidate ester barium soap T743 that adds petroleum sodium sulfonate T702, the 70kg of 86kg again, after treating its dissolving, add alkenyl succinic acid ester T747, the benzotriazole T706 of 0.6kg of 9.4kg, stirred 2 hours, after the filtration, be the E product of anticorrosive oil composition of the present invention, get E product 34kg, can use with the dilution of 166kg 120# solvent oil.
The application test for rust preventing ability data of the multiple agent of the various embodiments described above and reference are as follows:
Claims (7)
1, the anticorrosive oil composition that uses in a kind of metal processing is characterized in that it is to be made of following substances according to mass percent:
Base oil: 15-20%
Sulfonated petro-leum: 37.5-52%
Polymeric carboxylic and soap class: 26-35%
Ester class: 4.5-7%
Benzotriazole and derivative: 0.2-0.5%
Get above-mentioned composition 2-17% and be diluted to 100%, can use with the 120# solvent oil.
2, the anticorrosive oil composition that uses in the metal processing according to claim 1 is characterized in that described base oil comprises lubricating oil 75SN or lubricating oil 150SN or lubricating oil 350SN or lubricating oil N15.
3, the anticorrosive oil composition that uses in the metal processing according to claim 1 is characterized in that described sulfonated petro-leum comprises barium mahogany sulfonate T701 or petroleum sodium sulfonate T702 or calcium mahogany sulfonate T101.
4, the anticorrosive oil composition that uses in the metal processing according to claim 1 is characterized in that described polymeric carboxylic and soap class comprise petroleum oxidate ester barium soap T743 or lanolin magnesium soap or lanolin aluminium soap.
5, the anticorrosive oil composition that uses in the metal processing according to claim 1 is characterized in that described ester class comprises sorbitol monooleate SP-80 or alkenyl succinic acid ester T747 or glycerol boric acid ester fatty acid ester.
6, the anticorrosive oil composition that uses in the metal processing according to claim 1 is characterized in that described benzotriazole and derivative thereof comprise benzotriazole T706 or tolyltriazole or ethyl benzotriazole.
7, the preparation method of the anticorrosive oil composition that uses in a kind of metal processing as claimed in claim 1 is characterized in that it is undertaken by following step:
The base oil of 15-20% is added in the still, be warming up to 80-110 ℃, add the sulfonated petro-leum of 37.5%-52%, polymeric carboxylic and the soap class of 26-35% again, after treating its dissolving, add ester class, 0.2-0.5% benzotriazole and the derivative of 4.5-7%, stirred 2-3 hour, after the filtration, be anticorrosive oil composition of the present invention, get above-mentioned composition 2-17% and be diluted to 100%, can use with the 120# solvent oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100117052A CN101602976B (en) | 2009-05-26 | 2009-05-26 | Antirust oil composition used for metal processing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100117052A CN101602976B (en) | 2009-05-26 | 2009-05-26 | Antirust oil composition used for metal processing and preparation method thereof |
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| CN101602976A true CN101602976A (en) | 2009-12-16 |
| CN101602976B CN101602976B (en) | 2012-03-14 |
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| CN101824355A (en) * | 2010-03-25 | 2010-09-08 | 上海九盛实业有限公司 | Machinery seal vapor phase anti-rust and preparation method thereof |
| CN102533404A (en) * | 2011-07-11 | 2012-07-04 | 布兰诺工业包装材料(上海)有限公司 | Efficient lubrication type anti-rust oil and preparation method thereof |
| CN103103010A (en) * | 2012-11-07 | 2013-05-15 | 洛阳轴研科技股份有限公司 | Preparation method of dehydrated anti-rust oil |
| CN103937583A (en) * | 2014-01-14 | 2014-07-23 | 湖北诚祥科技有限公司 | Long-acting quick-drying film rust-preventive oil |
| CN103980988A (en) * | 2014-05-23 | 2014-08-13 | 启东尤希路化学工业有限公司 | High-performance environment-friendly anti-fingerprint anti-rust oil |
| CN103980999A (en) * | 2014-04-17 | 2014-08-13 | 天长市润达金属防锈助剂有限公司 | Lubricating oil-type rust preventive oil |
| CN103992850A (en) * | 2014-04-17 | 2014-08-20 | 天长市润达金属防锈助剂有限公司 | Environmentally-friendly multi-effect antirust oil |
| CN104388148A (en) * | 2014-11-14 | 2015-03-04 | 无锡信大气象传感网科技有限公司 | Long-acting metal rust inhibitor for transformer and preparation method of long-acting metal rust inhibitor |
| CN104388150A (en) * | 2014-05-29 | 2015-03-04 | 上海施能科技有限公司 | Water-replacement anti-emulsion calcium-based petrolatum antirust additive, preparation method thereof and antirust oil |
| CN105623806A (en) * | 2014-11-20 | 2016-06-01 | 无锡市德林环保工程有限公司 | Mechanical rust-proof oil |
| CN109385325A (en) * | 2017-08-08 | 2019-02-26 | 上海洁安精细化工有限公司 | Super thin anti-rust oil and preparation method thereof |
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| CN110343561A (en) * | 2019-06-06 | 2019-10-18 | 浙江威隆润滑油科技股份有限公司 | A kind of salt fog resistance antirust oil compound additive, antirust oil and preparation method thereof |
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