CN101602858B - Water soluble acrylic acid epoxy resin and preparation method thereof - Google Patents
Water soluble acrylic acid epoxy resin and preparation method thereof Download PDFInfo
- Publication number
- CN101602858B CN101602858B CN 200910089362 CN200910089362A CN101602858B CN 101602858 B CN101602858 B CN 101602858B CN 200910089362 CN200910089362 CN 200910089362 CN 200910089362 A CN200910089362 A CN 200910089362A CN 101602858 B CN101602858 B CN 101602858B
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- epoxy
- epoxy resin
- mol
- resins
- acrylic acid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Component | Raw material | Consumption A1 | Consumption A2 | Consumption A3 |
Hydroxy acryl acid class monomer | Propylene glycol monoacrylate | 92.7 | 92.7 | 92.7 |
Contain carboxy acrylic class monomer | Vinylformic acid | 51.3 | 102.7 | 160.5 |
Other acrylic monomers | Butyl acrylate | 186 | 164.3 | 141.8 |
Styrene monomer | Vinylbenzene | 155 | 120 | 90 |
Peroxide initiator | Peroxidation two tert-pentyl esters | 15 | 15 | 15 |
Alcohol ethers solubility promoter | The butyl glycol ether propylene glycol monomethyl ether | 273 60 | 273 60 | 273 60 |
Acrylic resin | Acid value (mgKOH/g) | Number-average molecular weight (g/mol) |
A1 | 80 | 35081 |
A2 | 160 | 29195 |
A3 | 250 | 37820 |
Salient features | 1# | 2# | 3# | 4# | 5# | 6# | 7# | 8# | 9# |
The pH value | 8.5 | 8.5 | 8.3 | 8.8 | 8.3 | 8.6 | 8.6 | 8.6 | 8.5 |
Solids constituent, % | 38 | 35 | 35 | 40 | 40 | 30 | 35 | 28 | 30 |
Be coated with-4 glasss of viscosity, s | 165 | 124 | 109 | 225 | 256 | 153 | 198 | 110 | 128 |
Store and be coated with-4 glasss of viscosity, s after 6 months | 171 | 125 | 114 | 227 | 265 | 155 | 201 | 109 | 130 |
Project | 1# | 2# | 3# | 4# | 5# | 6# | 7# | 8# | 9# |
Sticking power, level | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
Impact Kg.cm | 50 | 40 | 40 | 50 | 50 | 40 | 40 | 40 | 40 |
Snappiness, mm | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 |
Gloss, 60 ° | 88 | 89 | 89 | 88 | 88 | 94 | 89 | 92 | 92 |
Pencil hardness | 2H | 3H | 3H | 2H | 2H | 3H | 3H | 3H | 3H |
Anti-butanone wiping, inferior | 200 | 200 | 200 | 100 | 100 | 200 | 200 | 200 | 200 |
Alkaline-resisting (10% sodium hydroxide solution), day | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
Salt spray resistance, hour | 120 | 240 | 240 | 120 | 120 | 240 | 240 | 240 | 240 |
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910089362 CN101602858B (en) | 2009-07-17 | 2009-07-17 | Water soluble acrylic acid epoxy resin and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910089362 CN101602858B (en) | 2009-07-17 | 2009-07-17 | Water soluble acrylic acid epoxy resin and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101602858A CN101602858A (en) | 2009-12-16 |
CN101602858B true CN101602858B (en) | 2011-04-13 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN 200910089362 Active CN101602858B (en) | 2009-07-17 | 2009-07-17 | Water soluble acrylic acid epoxy resin and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN101602858B (en) |
Families Citing this family (20)
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---|---|---|---|---|
CN101817930A (en) * | 2010-04-28 | 2010-09-01 | 常州市科祥化工有限公司 | Waterborne epoxy modified acrylic resin specific for tape measure and preparation method thereof |
CN101974194B (en) * | 2010-09-29 | 2012-05-16 | 江苏科技大学 | Epoxy modified styrene-acrylate emulsion and preparation method thereof |
CN101974115A (en) * | 2010-10-26 | 2011-02-16 | 复旦大学 | Preparation method for low-molecular weight polymer with yellowing resistance |
CN102391743B (en) * | 2011-09-01 | 2013-09-25 | 中国海洋石油总公司 | Aqueous primer used for bicycles |
CN102399350B (en) * | 2011-09-16 | 2013-02-13 | 北京红狮漆业有限公司 | Aqueous epoxy acrylate resin and preparation method thereof |
CN102731798B (en) * | 2012-07-05 | 2013-09-11 | 中国海洋石油总公司 | Self-emulsifying water-borne epoxy resin emulsion and preparation method thereof |
CN102875741A (en) * | 2012-10-18 | 2013-01-16 | 海洋化工研究院有限公司 | Anticorrosive paint used for aluminum evaporator of refrigerator |
CN102964535B (en) * | 2012-11-22 | 2014-12-10 | 上海涂料有限公司技术中心 | Preparation method and application of composite emulsion for alkali-resistant wine label coating |
CN103849372A (en) * | 2012-11-30 | 2014-06-11 | 亿利资源集团有限公司 | Fracturing propping agent and its preparation method |
CN103910825B (en) * | 2014-03-28 | 2016-11-23 | 江门市三木化工有限公司 | A kind of resin and preparation method thereof |
CN104513344A (en) * | 2014-12-04 | 2015-04-15 | 北京金汇利应用化工制品有限公司 | Waterborne epoxy modified acrylic resin and aqueous dispersion thereof |
CN104877086B (en) * | 2015-05-29 | 2017-11-28 | 佛山市华立龙科技有限公司 | A kind of high-performance environment protection type soluble epoxide acrylic resin |
CN105885609A (en) * | 2016-04-23 | 2016-08-24 | 徐挺 | Water-based epoxy coating and method for preparing same |
CN106854285A (en) * | 2016-12-22 | 2017-06-16 | 徐州海太新材料科技有限公司 | A kind of water-based hydroxyl acrylic acid dispersion and preparation method thereof |
CN107163256B (en) * | 2017-06-02 | 2020-04-03 | 广东深展实业有限公司 | Epoxy modified water-based acrylic resin and water-based vacuum coating primer prepared from same |
CN107244063A (en) * | 2017-08-02 | 2017-10-13 | 合肥英源新材料科技有限公司 | Inflation film manufacturing machine |
CN107297887A (en) * | 2017-08-02 | 2017-10-27 | 合肥英源新材料科技有限公司 | A kind of processing method of the coiler of inflation film manufacturing machine |
CN109294407B (en) * | 2018-09-14 | 2020-09-01 | 广东华科新材料研究院有限公司 | Water-based anticorrosive paint and preparation method thereof |
CN113698838B (en) * | 2021-08-13 | 2023-02-10 | 成都杰晟蜀邦新材料科技有限公司 | Resin for water-based glass baking varnish and preparation method thereof |
CN114106386A (en) * | 2021-12-07 | 2022-03-01 | 合肥乐凯科技产业有限公司 | Anti-static polyester film and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1445255A (en) * | 2003-04-17 | 2003-10-01 | 中山大学 | Method for catalysis synthesizing methylic metlbond epoxy acryl resin |
CN101012301A (en) * | 2006-12-15 | 2007-08-08 | 深圳市深赛尔实业有限公司 | Epoxy acrylic resin and preparing method thereof |
-
2009
- 2009-07-17 CN CN 200910089362 patent/CN101602858B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1445255A (en) * | 2003-04-17 | 2003-10-01 | 中山大学 | Method for catalysis synthesizing methylic metlbond epoxy acryl resin |
CN101012301A (en) * | 2006-12-15 | 2007-08-08 | 深圳市深赛尔实业有限公司 | Epoxy acrylic resin and preparing method thereof |
Non-Patent Citations (2)
Title |
---|
JP特开2004-341517A 2004.12.02 |
郭秀兰等.丙烯酸-环氧阳离子树脂的合成研究.《广东化工》.2001,(第4期),第18-20页. * |
Also Published As
Publication number | Publication date |
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CN101602858A (en) | 2009-12-16 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CI01 | Correction of invention patent gazette |
Correction item: Patentee|Address|Co-patentee Correct: China Marine Petroleum & Chemical Co., Ltd. | 100010 Beijing City Higashiro-ku, Chaoyoang Kitakami-shi No. 25 4705 Shinkansen|CNOOC Changzhou coatings chemical research institute CNOOC energy development Limited by Share Ltd False: CNOOC Changzhou Paint & Coatings Industry Research Institute|213016 Changzhou Zhong Road, Jiangsu Province, No. 22 Longjiang Road Number: 15 Volume: 27 |
|
CI03 | Correction of invention patent |
Correction item: Patentee|Address|Co-patentee Correct: China Marine Petroleum & Chemical Co., Ltd. | 100010 Beijing City Higashiro-ku, Chaoyoang Kitakami-shi No. 25 4705 Shinkansen|CNOOC Changzhou coatings chemical research institute CNOOC energy development Limited by Share Ltd False: CNOOC Changzhou Paint & Coatings Industry Research Institute|213016 Changzhou Zhong Road, Jiangsu Province, No. 22 Longjiang Road Number: 15 Page: The title page Volume: 27 |
|
ERR | Gazette correction |
Free format text: CORRECT: PATENTEE; ADDRESS; CO-PATENTEE; FROM: CNOOC CHANGZHOU PAINT + COATINGS INDUSTRY RESEARCH INSTITUTE;213016 NO. 22, LONGJIANG MIDDLE ROAD, ZHONGLOU DISTRICT, CHANGZHOU CITY, JIANGSU PROVINCE TO: CHINA MARINE PETROLEUM GENERAL CO.;100010 MAILBOX 4705, NO. 25, CHAOYANGMEN NORTH STREET, DONGCHENG DISTRICT, BEIJING; CNOOC CHANGZHOU PAINT + COATINGS INDUSTRY RESEARCH INSTITUTE CNOOC ENERGY DEVELOPMENT CO., LTD. |
|
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 100010 Dongcheng District, Chaoyangmen, North Street, No. 4705, No. 25, box office, Beijing Patentee after: China National Offshore Oil Corporation Patentee after: CNOOC CHANGZHOU PAINT CHEMICAL RESEARCH INSTITUTE CO., LTD. Patentee after: CNOOC Energy Development Co., Ltd. Address before: 100010 Dongcheng District, Chaoyangmen, North Street, No. 4705, No. 25, box office, Beijing Patentee before: China National Offshore Oil Corporation Patentee before: CNOOC Changzhou Paint & Coatings Industry Research Institute Patentee before: CNOOC Energy Development Co., Ltd. |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20161227 Address after: 213016 Changzhou Zhong Road, Jiangsu Province, No. 22 Longjiang Road Patentee after: CNOOC CHANGZHOU PAINT CHEMICAL RESEARCH INSTITUTE CO., LTD. Patentee after: CNOOC Energy Technology Co., Ltd. Address before: 100010 Dongcheng District, Chaoyangmen, North Street, No. 4705, No. 25, box office, Beijing Patentee before: China National Offshore Oil Corporation Patentee before: CNOOC CHANGZHOU PAINT CHEMICAL RESEARCH INSTITUTE CO., LTD. Patentee before: CNOOC Energy Technology Co., Ltd. |