CN101597509A - Method for desulfuration by recombination alkylate catalytic distillation - Google Patents
Method for desulfuration by recombination alkylate catalytic distillation Download PDFInfo
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Abstract
The present invention relates to a kind of method for desulfuration by recombination alkylate catalytic distillation, gasoline stocks to be desulfurization is separated into lighting end and last running, introduce the different positions of catalytic distillation tower respectively, the opening for feed of lighting end is lower than the opening for feed of last running, filling solid acid catalyst in the catalytic distillation tower, the working pressure of catalytic distillation tower is 0.1MPa～0.5MPa, and reaction zone temperature is 80 ℃～200 ℃, and the liquid air speed is 0.1h-1～20h-1; Make full use of alkene and the reaction of the sulfocompound in the gasoline that gasoline itself contains, significantly improve the boiling point of sulfocompound, the degree that sulphur is shifted is higher; Sulphur in the effective elimination gasoline and do not lose octane value; Reach desulfurization and the dual purpose of falling alkene; Construction investment is little, and operational condition gentleness, process are easy to control.
Description
Technical field
The present invention relates to a kind of is the sulfur method of alkylating agent with the alkene that contains in the gasoline.
Background technology
At present, catalytic cracking (FCC) gasoline accounts for more than 75% of China's gasoline composition, brings the sulphur impurity more than 90% in the gasoline product into.Therefore, production clean gasoline product needed reduces the sulfide content in the FCC gasoline significantly.Mercaptan and thioether class are less in the contained sulfide of FCC gasoline, and thiophene expects that class accounts for more than 80% of sulfide total amount.Hydrogenating desulfurization (HDS) is the FCC gasoline desulfur technology of present widespread use, and the sulfide kind that it can remove is many, the reaction conversion ratio height, but the alkene in the lighting end is easy to the while by saturated, and gasoline octane rating is reduced.Alkylating desulfurization is meant gasoline is contacted with an acidic catalyst, make thiophene-type sulfide that gasoline contains and the alkene generation alkylated reaction in the gasoline, generate the higher alkylated substituted thiazoline fen of boiling point, through distillment sulfide is transferred in the last running again and gone, thereby the sulphur content in the reduction gasoline fraction, alkylating desulfurization technological operation condition relaxes, sweetening effectiveness is good, the alkene loss is few, keep gasoline octane rating, need not consume hydrogen and hydrogenation catalyst, process cost is low, is a kind of very competitive desulfurization technology.
About the patent and the bibliographical information of alkylation desulfurization of gasoline as follows:
The US5599441 disclosed method is to be catalyzer with the solid acid, and thiophene-type sulfide in reactor in the catalytic gasoline and olefin alkylation reaction generate the sulfide of higher.The reactor discharging enters separation column again, tells doctor negative petroleum naphtha from cat head, and higher boiling sulfur compound is delivered to selective hydrogenation device with tower bottoms and carried out hydrogenating desulfurization.When this method was raw material with full cut, the thiophene transformation efficiency was lower.
The US6024865 disclosed method is earlier petroleum naphtha to be divided into four cuts in rectifying tower:＜60 ℃, 60 ℃-177 ℃, 177 ℃-221 ℃ and＞221 ℃, again two cuts of intermediary are introduced the alkylation reactor of two different conditions respectively, carry out the alkyl sulfur shift reaction, wherein lighter cut utilizes the alkene that self contains to carry out alkylated reaction under gentle relatively condition, heavier cut then needs additional low-carbon alkene or low-carbon alcohol as alkylating agent, is carrying out alkylated reaction under the exacting terms relatively.Fractionate out the heavy petrol of doctor negative petroleum naphtha and sulfur-bearing at last, the cut of sulfur-bearing is mixed with＞221 ℃ of cuts go hydrogenating desulfurization again.
US2003029776 discloses the method for a kind of two-stage alkyl sulfur shift reaction desulfurization.At first handle gasoline with acid solution, to deviate from basic nitrogen compound, then pretreated gasoline is introduced first step reactor, under 172 ℃ of conditions, carry out alkylated reaction, further reaction in second stage reactor (temperature is 122 ℃) again, separate light, heavy constituent at last, heavy constituent go hydrogenator to carry out hydrogenating desulfurization.
US6059962 discloses a kind of multistage alkylating desulfurization technology, at first with the raw material fractionation, the cut of drawing one 60 ℃-221 ℃ from side line enters first step alkylation reactor, allowing wherein, the part sulfocompound is converted into the higher alkylate of boiling point, product fractionation with first alkylation reactor is doctor negative lighting end and doctor positive last running then, second stage alkylation reactor is introduced in last running, sulfocompound is transferred in the heavier cut.
US20030042175 discloses a kind of sulfur method, and the first step is deviate from the diolefine in the gasoline earlier; Second step was carried out thioetherification reaction, made mercaptan and olefine reaction in the gasoline generate thioether; The 3rd step was fractionation, drew side line removal of alkylation reaction device at the rectifying section of tower, returned rectifying tower after the reaction again, and tower bottoms directly goes hydrogenating desulfurization.What the USP20020166798 disclosed method was different with it is to draw side line removal of alkylation reaction device at the stripping section of tower, does not return rectifying tower after the reaction, but goes hydrogenating desulfurization.
CN1267536 discloses a kind of method of distillate alkylating desulfurization, is in the presence of acid catalyst, and distillate is contacted with dry gas or liquefied gas, alkylated reaction takes place, and distill cutting.
CN101007965 discloses a kind of alkylated reaction device that is composed in parallel by a plurality of reactors, when the catalyzer in the reactor need be regenerated, stock oil is switched to regenerated solvent or gas, solvent after the regeneration is recyclable to be utilized again, switches to stock oil behind the catalyst regeneration and proceeds alkylated reaction.
The deficiency that prior art exists is the alkene that does not reasonably distribute in the raw material.The characteristics of alkene and thiophene-type sulfide alkylated reaction are, low-carbon alkene reacts than higher olefins is easier, and lower boiling thiophene sulfide is than the easier reaction of high boiling point thiophene sulfide.Existing technology is not all separated low-carbon alkene with lower boiling thiophene sulfide, low-carbon alkene is easy to react with lower boiling thiophene sulfide in this case, occupied the position of substitution, and the boiling point of the alkylthrophene derivative that is generated is not high enough, so the sulphur transfer effect is bad.
Summary of the invention
The purpose of this invention is to provide a kind of method that adopts the hydrocarbon reorganization to combine with catalytic distillation, good low-carbon alkene at first contacts with the thiophene sulfide of higher to allow reactive behavior, help generating more high boiling sulfide, on the other hand, allow more lower boiling thiophene sulfide contact with long-chain olefin, make remarkable raise simple to operate of boiling point of alkylate, mild condition, the method for the gasoline desulfur that sweetening effectiveness is good.
The present invention is realized by the following technical programs:
A kind of gasoline desulfating method comprises following process: 1. isolate light constituent from sour gasoline; 2. the rest part of described light constituent and gasoline stocks is introduced respectively in the catalytic distillation tower that solid acid catalyst is housed, the feed entrance point of light constituent is lower than the feed entrance point of rest part; 3. the alkene in the light constituent (as C5=) contacts at following reaction zone with the thiophene-type sulfide of higher, and alkylated reaction takes place under the solid acid catalyst effect, generates more high boiling sulfide; The alkene (as C6=) of 4. more lower boiling thiophene-type sulfide and middle runnings descends the low carbon olefin gas of reaction zone surplus also will rise to reaction zone participation reaction at last reaction zone generation alkylated reaction in addition; 5. low-sulphur oil is from the extraction of catalytic distillation cat head; 6. higher boiling sulfur compound is accompanyed or follow the tower bottoms extraction, a kind of gasoline desulfating method is characterized in that: gasoline stocks to be desulfurization is separated into lighting end and last running, introduce the different positions of catalytic distillation tower respectively, the opening for feed of lighting end is lower than the opening for feed of last running, filling solid acid catalyst in the reaction zone of catalytic distillation tower, the working pressure of catalytic distillation tower is 0.1MPa～0.5MPa, and reaction zone temperature is 80 ℃～200 ℃, and the liquid air speed is 0.1h-1～20h-1.
A kind of preferred version, it is characterized in that: at first gasoline is separated into gas phase and liquid phase by flash tank, then vapor phase stream thigh and liquid phase stream stock are not introduced from the different heights position of catalytic rectifying tower, the opening for feed of vapor phase stream thigh is positioned at the reaction zone bottom, the opening for feed of liquid phase stream thigh is positioned at the reaction zone middle part, cat head extraction low-sulphur oil, tower bottoms with enter separation column after the high boiling point hydrocarbon ils mixes, the fractionation overhead distillate mixes with catalytic distillation cat head distillate, the fractionation tower bottoms is partly recirculated to the separation column opening for feed, the part extraction.
A kind of preferred version, it is characterized in that: at first gasoline is separated into gas phase and liquid phase by flash tank, then vapor phase stream thigh and liquid phase stream stock are not introduced from the different heights position of catalytic rectifying tower, the opening for feed of vapor phase stream thigh is positioned at the reaction zone bottom, the opening for feed of liquid phase stream thigh is positioned at the reaction zone middle part, introduces high boiling point hydrocarbon ils, cat head extraction low-sulphur oil at the middle part of stripping section, tower bottoms is partly recirculated to the opening for feed of high boiling point hydrocarbon ils, the part extraction.
A kind of preferred version, it is characterized in that: at first gasoline is introduced preliminary fractionator (separation column 1), isolate lighting end from cat head, the boiling point of lighting end≤65 ℃, then lighting end and all the other cuts are introduced from the different heights position of catalytic rectifying tower respectively, the opening for feed of lighting end is in the reaction zone bottom, the opening for feed of all the other cuts is positioned at the reaction zone middle part, catalytic distillation cat head extraction low-sulphur oil, tower bottoms with enter separation column 2 after the high boiling point hydrocarbon ils mixes, the overhead distillate of separation column 2 mixes mutually with catalytic distillation cat head distillate, and the tower bottoms of separation column 2 is partly recirculated to opening for feed, the part extraction.
A kind of preferred version, it is characterized in that: at first gasoline is introduced preliminary fractionator (separation column 1), isolate lighting end from cat head, the boiling point of lighting end≤65 ℃, then lighting end and all the other cuts are introduced from the different heights position of catalytic rectifying tower respectively, the opening for feed of lighting end is positioned at the reaction zone bottom, the opening for feed of all the other cuts is positioned at the reaction zone middle part, the high boiling point hydrocarbon ils is introduced at middle part at stripping section, cat head extraction low-sulphur oil, tower bottoms is partly recirculated to the opening for feed of high boiling point hydrocarbon ils, the part extraction.
Described solid acid catalyst is selected from one or more in sulfonate resin, molecular sieve, the solid phosphoric acid.
The effect of invention
Compared with prior art, effect of the present invention is:
Make full use of alkene and the reaction of the sulfide in the gasoline that gasoline itself contains, significantly improve the boiling point of sulfide, the degree that sulphur is shifted is higher; Sulfide in the effective elimination gasoline and do not lose octane value; Reach desulfurization and the dual purpose of falling alkene; Construction investment is little, and operational condition gentleness, process are easy to control.
Description of drawings
Fig. 1 is the schematic flow sheet of the embodiment of the invention 1.
Fig. 2 is the schematic flow sheet of the embodiment of the invention 2.
Fig. 3 is the schematic flow sheet of the embodiment of the invention 3.
Fig. 4 is the schematic flow sheet of the embodiment of the invention 4.
Wherein: 10, pretreater 101, pipeline 102, pipeline 103, pipeline 104, pipeline 105, pipeline 106, pipeline 20, flash tank 201, pipeline 202, pipeline 203, pipeline 204, pipeline 205, pipeline 206, pipeline 30, catalytic distillation tower 31, last conversion zone 32, following conversion zone 33, rectifying section 34, stripping section 35, last conversion zone 2 36, intermediate fractionation section 40, separation column 50, preliminary fractionator
Embodiment
Embodiment 1
In conjunction with the accompanying drawings 1, technology of the present invention is further specified.
Catalytic distillation tower is divided into four parts: go up conversion zone 31, following conversion zone 32, rectifying section 33 and stripping section 34.The FCC gasoline stocks is connected with pretreater 10 through pipeline 101, is connected with flash tank 20 by pipeline 102 again.Flash drum overhead is connected with the conversion zone bottom of catalytic distillation tower 30 by pipeline 103, and C3～C5 olefin feedstock is connected by pipeline 106 conversion zones bottom.The bottom of flash tank by pipeline 104 and catalytic distillation tower 30 last conversion zone 31 and following conversion zone 32 between be connected.Cat head connects complete condenser by pipeline 201, and outlet is connected pipeline 202 with complete condenser with catalytic distillation column overhead extraction mouth.Converge the back by pipeline 203,204 and pipeline 105 at the bottom of the tower and be connected with the middle part of separation column 40, pipeline 105 is connected with diesel oil or high boiling hydrocarbon ils feedstock.The fractionation cat head is connected with catalytic distillation overhead line 202 by pipeline 205.Separation column bottom connection line 206.
The FCC gasoline stocks enters pretreater through pipeline 101 and removes basic nitrogen, enters flash tank 20 by pipeline 102 again.The conversion zone bottom that the vapor phase stream thigh that is come out by flash tank is introduced catalytic distillation towers by pipeline 103 optionally suitably replenishes C3～C5 alkene by pipeline 106 according to the difference that the FCC gasoline stocks is formed.Between last conversion zone 31 and following conversion zone 32, introduce catalytic distillation tower by pipeline 104 by the liquid phase stream thigh that flash tank comes out.Overhead vapours enters complete condenser by pipeline 201, and the part lime set refluxes, its as distillate from pipeline 202 extraction.Liquid portion vaporization at the bottom of the tower, remaining is by pipeline 204, mixes back introducing separation column 40 with diesel oil or high boiling hydrocarbon ils cut from pipeline 105.The fractionation overhead distillate mixes with catalytic distillation cat head distillate by pipeline 205, as low-sulphur oil.The fractionation tower bottoms is the diesel oil distillate of band sulphur.
The FCC gasoline stocks is added the pretreater that Zeo-karb is housed, and operational condition is 0.3MPa and 85 ℃; The gasoline of handling is fed flash tank, and pressure-controlling is at 0.12MPa; Introduce catalytic distillation tower respectively by gas and liquid that flash tank comes out, the liquid phase stream thigh enters tower from the centre of two conversion zones, the vapor phase stream thigh enters tower from the lower curtate of conversion zone, tower top temperature is 70 ℃, column bottom temperature is 161 ℃, working pressure is 0.1MPa, conversion zone filling macropore sulfuric acid resin and solid phosphoric acid catalyst, rectifying section and stripping section filling Stainless Steel Cloth filler; Sweet gasoline is from the cat head extraction; Tower bottoms and diesel oil mix the back and introduce separation column, and fractionation tower temperature is 170 ℃, and column bottom temperature is 230 ℃, and overhead distillate mixes as sweet gasoline with catalytic distillation cat head distillate, and tower bottoms partly is circulated to the separation column opening for feed, all the other extraction.
Embodiment 2
Knot and accompanying drawing 2 further specify technology of the present invention.
The FCC gasoline stocks enters pretreater through pipeline 101 and removes basic nitrogen, enters flash tank 20 by line 102 again.The conversion zone bottom that the vapor phase stream thigh that is come out by flash tank is introduced catalytic distillation towers by line 103 optionally suitably replenishes C3～C5 alkene by 106 according to the difference that the FCC gasoline stocks is formed.Between last conversion zone 31 and following conversion zone 32, introduce catalytic distillation tower by line 104 by the liquid phase stream thigh that flash tank comes out.Diesel oil or high boiling hydrocarbon ils cut are introduced the stripping section of catalytic distillation tower by line 105.Overhead vapours enters complete condenser by 201, and the part lime set refluxes, all the other as distillate from line 202 extraction.Liquid portion vaporization at the bottom of the tower, all the other are by 203,204 extraction.
The FCC gasoline stocks is added the pretreater that Zeo-karb is housed, and operational condition is 0.1MPa and 22 ℃; Feed flash tank after the gasoline of handling is heated to 120 ℃, pressure-controlling is at 0.12MPa; Introduce catalytic distillation tower respectively by gas and liquid that flash tank comes out, the liquid phase stream thigh enters tower from the centre of two conversion zones, the vapor phase stream thigh enters tower from the lower curtate of conversion zone, diesel oil is added from the stripping section middle part, tower top temperature is 86 ℃, and column bottom temperature is 232 ℃, and working pressure is 0.1MPa, conversion zone filling macropore sulfuric acid resin and solid phosphoric acid catalyst, rectifying section and stripping section filling Stainless Steel Cloth filler; Sweet gasoline is from the cat head extraction; The diesel oil that tower bottoms can partly be circulated to catalytic distillation tower adds inlet, all the other extraction.
Embodiment 3
In conjunction with the accompanying drawings 3, technology of the present invention is further specified.
Catalytic distillation tower is divided into six parts: rectifying section 33, stripping section 34, last conversion zone 31, last conversion zone 2 35, following conversion zone 32, intermediate fractionation section 36.The FCC gasoline stocks is connected with pretreater 10 through pipeline 101, is connected with preliminary fractionator 50 by pipeline 102 again.The preliminary fractionator top is connected with the conversion zone bottom of catalytic distillation tower 30 by pipeline 103, and C3～C5 olefin feedstock is connected by pipeline 106 conversion zones bottom.Preliminary fractionator bottom by pipeline 104 and catalytic distillation tower 30 last conversion zone 2 35 and following conversion zone 32 between be connected.Cat head connects complete condenser by pipeline 201, and outlet is connected pipeline 202 with complete condenser with catalytic distillation column overhead extraction mouth.Converge the back by pipeline 203,204 and pipeline 105 at the bottom of the tower and be connected with the middle part of separation column 40, pipeline 105 is connected with diesel oil or high boiling hydrocarbon ils feedstock.The fractionation cat head is connected with catalytic distillation overhead line 202 by pipeline 205.Separation column bottom connection line 206.
The FCC gasoline stocks enters pretreater through pipeline 101 and removes basic nitrogen, enters preliminary fractionator 50 by pipeline 102 again.Eject the stream thigh that comes by preliminary fractionator and introduce by pipeline 103 bottom the conversion zone of catalytic distillation tower, optionally suitably replenish C3～C5 alkene by pipeline 106 according to the difference that the FCC gasoline stocks is formed.Between conversion zone 35 and conversion zone 32, introduce catalytic distillation tower by pipeline 104 by the stream thigh that the preliminary fractionator still comes out.Overhead vapours enters complete condenser by pipeline 201, and the part lime set refluxes, its as distillate from pipeline 202 extraction.Liquid portion vaporization at the bottom of the tower, remaining is by pipeline 204, mixes back introducing separation column 40 with diesel oil or high boiling hydrocarbon ils cut from pipeline 105.The fractionation overhead distillate mixes with catalytic distillation cat head distillate by pipeline 205, as low-sulphur oil.The fractionation tower bottoms is the diesel oil distillate of band sulphur.
The FCC gasoline stocks is added the pretreater that Zeo-karb is housed, and operational condition is 0.3MPa and 30 ℃; The gasoline of handling is fed preliminary fractionator, and pressure-controlling is at 0.1MPa; Prefractionation cat head distillate and tower bottoms are introduced catalytic distillation tower respectively, the prefractionation tower bottoms enters tower from the centre of conversion zone 35 and conversion zone 32, prefractionation cat head liquid enters tower from the lower curtate of conversion zone 32, catalytic distillation cat head temperature is 99 ℃, column bottom temperature is 197 ℃, working pressure is 0.3MPa, conversion zone filling solid phosphoric acid catalyst, rectifying section and stripping section filling Stainless Steel Cloth filler; Sweet gasoline is from the cat head extraction; Tower bottoms and diesel oil mix the back and introduce separation column, and fractionation tower temperature is 170 ℃, and column bottom temperature is 230 ℃, and overhead distillate mixes as sweet gasoline with catalytic distillation cat head distillate, and tower bottoms partly is circulated to the separation column opening for feed, all the other extraction.
Embodiment 4
Knot and accompanying drawing 4 further specify technology of the present invention.
Catalytic distillation tower is divided into six parts: rectifying section 33, stripping section 34, last conversion zone 31, last conversion zone 2 35, following conversion zone 32, intermediate fractionation section 36.The FCC gasoline stocks connects pretreater 10 through pipeline 101, connects preliminary fractionator 50 by pipeline 102 again.The prefractionation cat head is by the conversion zone bottom of pipeline 103 connection catalytic distillation towers, and C3～C5 olefin feedstock is connected by pipeline 106 conversion zones bottom.Preliminary fractionator bottom by pipeline 104 and catalytic distillation tower 30 last conversion zone 2 35 and following conversion zone 32 between be connected.The catalytic distillation cat head connects complete condenser by pipeline 201, and outlet is connected pipeline 202 with complete condenser with cat head extraction mouth.Diesel oil or high boiling hydrocarbon ils cut are connected with the stripping section of catalytic distillation tower by pipeline 105.Be connected with pipeline, 203,204 at the bottom of the tower.
The FCC gasoline stocks enters pretreater through pipeline 101 and removes basic nitrogen, enters preliminary fractionator 50 by pipeline 102 again.Eject the conversion zone bottom that the stream thigh that comes is introduced catalytic distillation towers by line 103 by preliminary fractionator, can be according to the composition different choice of FCC gasoline stocks suitably replenish C3～C5 alkene by 106.Between conversion zone 35 and following conversion zone 32, introduce catalytic distillation tower by line 104 by the stream thigh that comes out at the bottom of the preliminary fractionator.Diesel oil or high boiling hydrocarbon ils cut are introduced the stripping section of catalytic distillation tower by line 105.Overhead vapours enters complete condenser by 201, and the part lime set refluxes, all the other as distillate from line 202 extraction.Liquid portion vaporization at the bottom of the tower, all the other are by 203,204 extraction.
The FCC gasoline stocks is added the pretreater that Zeo-karb is housed, and operational condition is 0.1MPa and 30 ℃; The gasoline of handling is fed preliminary fractionator, and pressure-controlling is at 0.1MPa; Prefractionation cat head distillate and tower bottoms are introduced catalytic distillation tower respectively, the prefractionation tower bottoms enters tower from the centre of two conversion zones 35 and 32, prefractionation cat head liquid enters tower from the lower curtate of conversion zone 32, kerosene is added from the stripping section top, tower top temperature is 93 ℃, and column bottom temperature is 236 ℃, and working pressure is 0.2MPa, reaction zone filling Y molecular sieve catalyzer, rectifying section and stripping section filling Stainless Steel Cloth filler; Sweet gasoline is from the cat head extraction; The kerosene that tower bottoms partly is circulated to catalytic distillation tower adds inlet, all the other extraction.
Be compared as follows table by the yield of embodiment gained sweet gasoline and with the performance of raw material:
Claims (6)
1. method for desulfuration by recombination alkylate catalytic distillation, it is characterized in that: gasoline stocks to be desulfurization is separated into lighting end and last running, introduce the different positions of catalytic distillation tower respectively, the opening for feed of lighting end is lower than the opening for feed of last running, filling solid acid catalyst in the conversion zone of catalytic distillation tower, the working pressure of catalytic distillation tower is 0.1MPa～0.5MPa, and reaction zone temperature is 80 ℃～200 ℃, and the liquid air speed is 0.1h-1～20h-1.
2. method for desulfuration by recombination alkylate catalytic distillation according to claim 1, it is characterized in that: at first gasoline is separated into gas phase and liquid phase by flash tank, then vapor phase stream thigh and liquid phase stream stock are not introduced from the different heights position of catalytic rectifying tower, the opening for feed of vapor phase stream thigh is positioned at the reaction zone bottom, the opening for feed of liquid phase stream thigh is positioned at the reaction zone middle part, cat head extraction low-sulphur oil, tower bottoms with enter separation column after high boiling hydrocarbon mixes, the fractionation overhead distillate mixes with catalytic distillation cat head distillate, the fractionation tower bottoms is partly recirculated to the separation column opening for feed, the part extraction.
3. method for desulfuration by recombination alkylate catalytic distillation according to claim 1, it is characterized in that: at first gasoline is separated into gas phase and liquid phase by flash tank, then vapor phase stream thigh and liquid phase stream stock are not introduced from the different heights position of catalytic rectifying tower, the opening for feed of vapor phase stream thigh is positioned at the reaction zone bottom, the opening for feed of liquid phase stream thigh is positioned at the reaction zone middle part, high boiling hydrocarbon is introduced at middle part at stripping section, cat head extraction low-sulphur oil, tower bottoms is partly recirculated to the high boiling hydrocarbon opening for feed, the part extraction.
4. method for desulfuration by recombination alkylate catalytic distillation according to claim 1, it is characterized in that: at first gasoline is introduced separation column, isolate lighting end from cat head, the boiling point of lighting end≤65 ℃, then lighting end and all the other cuts are introduced from the different heights position of catalytic rectifying tower respectively, the opening for feed of lighting end is in the reaction zone bottom, the opening for feed of all the other cuts is positioned at the reaction zone middle part, catalytic distillation cat head extraction low-sulphur oil, tower bottoms with enter separation column after high boiling hydrocarbon mixes, the overhead distillate of separation column mixes mutually with catalytic distillation cat head distillate, and the tower bottoms of separation column is partly recirculated to opening for feed, the part extraction.
5. method for desulfuration by recombination alkylate catalytic distillation according to claim 1, it is characterized in that: at first gasoline is introduced separation column, isolate lighting end from cat head, the boiling point of lighting end≤65 ℃, then lighting end and all the other cuts are introduced from the different heights position of catalytic rectifying tower respectively, the opening for feed of lighting end is positioned at the reaction zone bottom, the opening for feed of all the other cuts is positioned at the reaction zone middle part, high boiling hydrocarbon is introduced at middle part at stripping section, cat head extraction low-sulphur oil, tower bottoms is partly recirculated to the high boiling hydrocarbon opening for feed, the part extraction.
6. solid acid catalyst according to claim 1 is selected from one or more in sulfonate resin, molecular sieve, the solid phosphoric acid.
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| CN1267536C (en) * | 2003-08-20 | 2006-08-02 | 中国石油化工股份有限公司 | Desulfurizing method for distillate |
| CN100497538C (en) * | 2003-09-28 | 2009-06-10 | 中国石油化工股份有限公司 | Method for modifying poor gasoline |
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