CN101597483A - A kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant - Google Patents

A kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant Download PDF

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Publication number
CN101597483A
CN101597483A CNA2009100694670A CN200910069467A CN101597483A CN 101597483 A CN101597483 A CN 101597483A CN A2009100694670 A CNA2009100694670 A CN A2009100694670A CN 200910069467 A CN200910069467 A CN 200910069467A CN 101597483 A CN101597483 A CN 101597483A
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CN
China
Prior art keywords
refrigerator
c2h4f2
trimethylmethane
energy
mixed refrigerant
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Pending
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CNA2009100694670A
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Chinese (zh)
Inventor
张于峰
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Tianjin University
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Tianjin University
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Publication date
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Priority to CNA2009100694670A priority Critical patent/CN101597483A/en
Publication of CN101597483A publication Critical patent/CN101597483A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant, composed of the following components, its quality percentage composition is: Trimethylmethane 1-70%, C2H4F2 C2H4F2 30-99%.By pure Trimethylmethane being replaced with the different mass fractional refrigeration agent that Trimethylmethane and C2H4F2 C2H4F2 are formed, can make refrigerator and refrigerator power consumption reduce by 20~50%, to atmospheric ozone layer destroying gesture (ODP) is 0, and the global warming potential that causes (GWP) is between 100~190%.

Description

A kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant
Technical field
The present invention relates to a kind of refrigeration agent, particularly relate to the mix refrigerant that a kind of energy-conservation refrigerator and refrigerator are used.
Background technology
Refrigerator and the used refrigeration agent of refrigerator are mainly Trimethylmethane (HC)-600a at present.Along with the attention of countries in the world to energy-saving and emission-reduction and environment protection, the research of energy saving refrigerating agent has become focus.But from existing achievement in research, Trimethylmethane-600a environmental protection effect is good, and power consumption is moderate, but safety performance is relatively poor, and potential safety hazard such as set off an explosion easily.Refrigerator and refrigerator are because consumption is very big, and a year electrisity consumption also is extremely huge.If can seek out more energy-conservation refrigeration agent, will bring very big effect to the index of energy-saving and emission-reduction.
Summary of the invention
In order to solve problems of the prior art, the invention provides a kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant, under the prerequisite that obtains identical refrigerating duty, can obviously reduce refrigerator and refrigerator power consumption.
Energy-saving mixed refrigerant of the present invention, composed of the following components, its quality percentage composition is: Trimethylmethane 1-70%, C2H4F2 C2H4F2 99-30%.
The quality percentage composition of described Trimethylmethane is that 1-50%, C2H4F2 C2H4F2 quality percentage composition are 50-99%.
Adopt refrigeration agent of the present invention to have the following advantages: by pure Trimethylmethane being replaced with the different mass fractional refrigeration agent that Trimethylmethane and C2H4F2 C2H4F2 are formed, can make refrigerator and refrigerator power consumption reduce by 20~50%, to atmospheric ozone layer destroying gesture (ODP) is 0, and the global warming potential that causes (GWP) is between 100~190%.The top pressure operating mode is lower than 0.1Mpa.Compressor oil is ester class refrigeration oil.
Embodiment
Below in conjunction with specific embodiment the present invention is done to describe in detail.
Mix refrigerant of the present invention uses Trimethylmethane (HC) and C2H4F2 C2H4F2 (HFC) double base component, and its quality percentage composition is: the quality percentage composition of Trimethylmethane is that 1-70%, C2H4F2 C2H4F2 quality percentage composition are 30-99%.
In said components, the molecular formula of Trimethylmethane-600a is CH (CH3) 2-CH3, and molecular weight is 58.12, its ozone layer destroying gesture (ODP) 0.0; Its global warming potential (GWP) is 11; The molecular formula of C2H4F2 C2H4F2-152a is CH3CHF2, and molecular weight is 66.05, does not wherein contain the chlorine atom, and its ozone layer destroying gesture (ODP) is 0, and Greenhouse effect (GWP) are 190.
The preparation method of this mix refrigerant is as follows: at normal temperatures Trimethylmethane-600a and C2H4F2 C2H4F2-152a are carried out physical mixed by predetermined mass ratio, form refrigeration agent.Specific practice is, the Trimethylmethane in refrigerator and refrigerator and the refrigerator-600a working medium is all extracted recovery out, and system is vacuumized, and successively Trimethylmethane-600a and C2H4F2 C2H4F2-152a directly poured in refrigerator and the refrigerator system to scale then to get final product.
For the energy-saving effect of more different refrigeration agents with to the influence degree of environment, under envrionment temperature (30 ℃ of room temperatures), compressor, vaporizer and all identical condition of condenser, use pure Trimethylmethane-600a and single and mix refrigerant (as following table 1) to calculate respectively, its energy-conservation data are as shown in table 2 below.
Scale is formed and contained to table 1 mix refrigerant
Calculated example Component (mass percent)
1 Trimethylmethane-600a1%+ C2H4F2 C2H4F2 99%
2 Trimethylmethane-600a10%+ C2H4F2 C2H4F2 90%
3 Trimethylmethane-600a20%+ C2H4F2 C2H4F2 80%
4 Trimethylmethane-600a50%+ C2H4F2 C2H4F2 50%
5 Trimethylmethane-600a60%+ C2H4F2 C2H4F2 40%
6 Trimethylmethane-600a70%+ C2H4F2 C2H4F2 30%
The performance comparison sheet of the refrigeration agent in pure HC-600a of table 2 and the table 1
Pure Trimethylmethane Embodiment 1 Embodiment 2 Embodiment 3
ODP (ozone layer destroying gesture) 0.0 0.0 0.0 0.0
GWP (global warming potential) 11 190 172 154
The press pressure P of giving vent to anger o(MPa) 0.477 0.816 0.84 0.85
Press back pressure P in(MPa) 0.046 0.08 0.08 0.09
Compression ratio k=P o/P in 10.4 10.4 10.5 9.5
Evaporation enthalpy kJ/kg 411.5 365.6 367.1 365.2
Air tightness kg/m3 6.614 13.38 13.59 13.77
Density enthalpy kJ/kg 2721.7 4771.3 4988.9 5028.8
The refrigerating duty comparative figure 1 1.75 1.833 1.848
Pure Trimethylmethane Embodiment 4 Embodiment 5 Embodiment 6
ODP (ozone layer destroying gesture) 0.0 0.0 0.0 0.0
GWP (global warming potential) 11 100 83 40
The press pressure P of giving vent to anger o(MPa) 0.477 0.8 0.76 0.56
Press back pressure P in(MPa) 0.046 0.08 0.08 0.08
Compression ratio k=P o/P in 10.4 10.0 9.5 7.0
Evaporation enthalpy kJ/kg 411.5 386.9 394.5 402.8
Air tightness kg/m3 6.614 11.3 9.93 8.9
Density enthalpy kJ/kg 2721.7 4372 3917.4 3583.3
The refrigerating duty comparative figure 1 1.610 1.44 1.32
By last table experimental data as can be known, under all identical situation of other conditions, compare with pure HC-600a, use novel energy-conserving two-unit-system cryogen that refrigerating duty is significantly increased, corresponding energy consumption will obviously reduce, its safety performance is better than Trimethylmethane-600a, atmospheric ozone layer destroying gesture is suitable with Trimethylmethane-600a, global warming potential is slightly high, be a kind of energy-saving preferably refrigerator and refrigerator-freezer refrigeration agent, compression ratio descends quite or to some extent, and pressure working condition improves, but remain in the equipment strength range (<1.0Mpa).

Claims (2)

1. refrigerator and refrigerator-freezer energy-saving mixed refrigerant is characterized in that it is composed of the following components, and its quality percentage composition is: Trimethylmethane 1-70%, C2H4F2 C2H4F2 30-99%.
2. refrigerator according to claim 1 and refrigerator-freezer energy-saving mixed refrigerant is characterized in that, the quality percentage composition of described Trimethylmethane is that 1-50%, C2H4F2 C2H4F2 quality percentage composition are 50-99%.
CNA2009100694670A 2009-06-26 2009-06-26 A kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant Pending CN101597483A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2009100694670A CN101597483A (en) 2009-06-26 2009-06-26 A kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2009100694670A CN101597483A (en) 2009-06-26 2009-06-26 A kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant

Publications (1)

Publication Number Publication Date
CN101597483A true CN101597483A (en) 2009-12-09

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Application Number Title Priority Date Filing Date
CNA2009100694670A Pending CN101597483A (en) 2009-06-26 2009-06-26 A kind of refrigerator and refrigerator-freezer energy-saving mixed refrigerant

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CN (1) CN101597483A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106762645A (en) * 2016-11-16 2017-05-31 西安交通大学 The rotary compressor for main refrigerant and application using R600a or R600

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106762645A (en) * 2016-11-16 2017-05-31 西安交通大学 The rotary compressor for main refrigerant and application using R600a or R600
CN106762645B (en) * 2016-11-16 2020-06-26 西安交通大学 Method for determining viscosity grade of lubricating oil of rotary compressor

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Open date: 20091209