CN101597359A - A kind of anti-corrosion resin of preparing phosphoric acid by solvent extraction and production method thereof and purposes - Google Patents
A kind of anti-corrosion resin of preparing phosphoric acid by solvent extraction and production method thereof and purposes Download PDFInfo
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- CN101597359A CN101597359A CNA200910062939XA CN200910062939A CN101597359A CN 101597359 A CN101597359 A CN 101597359A CN A200910062939X A CNA200910062939X A CN A200910062939XA CN 200910062939 A CN200910062939 A CN 200910062939A CN 101597359 A CN101597359 A CN 101597359A
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Abstract
The present invention relates to a kind of anti-corrosion product and technology, particularly a kind of anti-corrosion resin of preparing phosphoric acid by solvent extraction and production method thereof and purposes.Belong to chemical technology field.The anti-corrosion resin of a kind of preparing phosphoric acid by solvent extraction of the present invention, wherein, the component of described anti-corrosion resin is: 100 parts of resins, linking agent 20-50 part, initiator 0.5-2.5 part, promotor 0.05-1 part, wherein, 15~25 ℃ of solidification values, 8~24 hours set times.Extraction agent and organic and inorganic corrosion thing such as phosphoric acid, sulfuric acid all there are anticorrosion ability preferably, are suitable on the phosphoric acid extraction equipment and mold, using.
Description
Technical field
The present invention relates to a kind of anti-corrosion product and technology, particularly a kind of anti-corrosion resin of preparing phosphoric acid by solvent extraction and production method thereof and purposes.Belong to chemical technology field.
Background technology:
In traditional phosphoric acid by wet process factory, use many, such as rubber, plastics, impermeable graphite, general universal resin, special stainless steel (316L, 904L) or the like material, because they are during as inner lining material or material of main part, tolerate comparatively single corrosive environment, can not influence quality product, so be the leaching that to satisfy phosphoric acid by wet process, concentrate and produce phosphate fertilizer or the like and require the slight corrosion of equipment.But, factory the inside at the refining phosphoric acid by wet process of solvent extration, because can't satisfy the corrosion-resistant requirement to phosphoric acid, sulfuric acid, etching acid and extraction agent simultaneously, the use of these materials brings the corrosion of equipment, will cause the product industrial phosphoric acid seriously defective.Such as, do the liner of equipment with rubber, plastics or general universal resin, can be extracted solvent swell, cause inner lining material distortion, lose strong, peel off, some in addition dissolved.And the resin for as dihydroxyphenyl propane, furans, these several classes of phenolic aldehyde not only is unable to undergo the corrosion of solvent, also can not stand corrosion equally in containing hexafluorophosphoric acid.Though the Resbon block excellent anti-corrosion performance,, they are by phenolic aldehyde or furan mastic joint filling and collude embedding, and these two kinds of clay are the corrosive that are unable to undergo extraction agent.Special stainless steel 316L is the corrosive that is unable to undergo phosphoric acid in the time of 〉=65 ℃.In the technology of wet phosphoric acid refining, it is very high requiring for the control of various impurity.Such as, the content of iron ion and heavy metal must not be above 0.005% in the product industrial phosphoric acid.This just requires very high to the protection against corrosion of equipment.Rubber, plastics, general universal resin and the seam crossing of graphite block are corroded, and liner body material (as carbon steel) also is corroded, and cause iron ion to be brought in the product industrial phosphoric acid.Special stainless steel 316L is corroded, and except bringing iron into, also brings heavy metals such as chromium, manganese, molybdenum into, causes the defective of product industrial phosphoric acid.Though 904L can satisfy the corrosion of tolerate P-levels acid, sulfuric acid, etching acid, organic solvent simultaneously, its price is very expensive, and 145 yuan/Kg is 3 times of resin material price of product of the present invention, with 24 times of resin material expense under the volume.
Summary of the invention
Goal of the invention of the present invention is at above-described problem, and by a series of corrosion-resistant experiments, exploitation has obtained a kind of resin, and it can be in the application under the phosphoric acid by wet process extraction system, and cost is low, good corrosion resistance.
In numerous impregnating material, vinyl ester resin also has the operative weldability of unsaturated polyester resin excellence except keeping or having surpassed the performance of Resins, epoxy aspect mechanical property, electrical property, cementability and chemical-resistant.Good as chemical resistant properties, especially powerful oxidation corrosion resistance acid and solvent resistance are good; Have good adhesiveproperties, the mechanical property height, resistance to fatigue is good or the like.
Vinyl ester resin can carry out esterification by Resins, epoxy and monobasic unsaturated carboxylic acid (vinylformic acid or methacrylic acid) and obtain.Phenolic aldehyde epoxy vinyl ester resin wherein, phenol aldehyde modified vinyl ester resin and high crosslink density type vinyl ester resin are adapted at the anticorrosion application under phosphoric acid, sulfuric acid, etching acid and the organic extractant environment.
As the equipment liner time, need carry out sandblasting to the steel matrix surface, remove iron rust and remove surface and oil contaminant, be beneficial to the adhesion of resin.Being coated with one deck resin primer earlier on treated matrix, being coated with structural sheet again after solidifying, is that the 0.2mm glasscloth alternately pastes with thickness, and gel content is about 50%, and thickness is about 2mm; Be exactly impervious barrier then, strengthen gel content 70%, thickness 1.6mm by chopped mat; Be anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90%, thickness 0.4mm; Outermost layer then is to paste with resin.
When using mould to make, paste with resin earlier, be anticorrosion layer then, be by surperficial felt enhanced resin-rich layer, gel content 90% is exactly impervious barrier then, strengthened by chopped mat, gel content 70% is exactly to be coated with structural sheet then, with thickness is that the 0.2mm glasscloth alternately pastes, and gel content is about 50%, is exactly thereafter impervious barrier, strengthened by chopped mat, gel content 70% is anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90% then is to paste with resin at last; Need to adjust the thickness of structural sheet, impervious barrier and anticorrosion layer according to finish size.
The anti-corrosion resin of a kind of preparing phosphoric acid by solvent extraction of the present invention, wherein, the components by weight percent of described anti-corrosion resin is: 100 parts of resins, linking agent 20-50 part, initiator 0.5-2.5 part, promotor 0.05-1.5 part, wherein, 15~25 ℃ of solidification values, 8~24 hours set times.
Above-mentioned resin is a kind of of phenolic aldehyde epoxy vinyl ester resin, phenol aldehyde modified vinyl ester resin or high crosslink density type vinyl ester resin.
Above-mentioned linking agent is vinylbenzene or acetone.
Above-mentioned initiator is a kind of of methylethyl ketone peroxide, cyclohexanone peroxide or benzoyl peroxide.
Above-mentioned promotor is a kind of of naphthoic acid cobalt, cobalt octoate, cobalt naphthenate or xylidine.
The following weight part combination of the formula optimization of above-mentioned anti-corrosion resin:
100 parts of phenolic aldehyde epoxy vinyl ester resins, vinylbenzene 20-50 part, methylethyl ketone peroxide 0.5-3 part, cobalt naphthenate 0.05-1.5 part;
100 parts of phenol aldehyde modified vinyl ester resins, vinylbenzene 20-50 part, cyclohexanone peroxide 0.5-3 part, cobalt naphthenate 0.05-1.5 part;
100 parts of high crosslink density type vinyl ester resins, vinylbenzene 20-50 part, benzoyl peroxide 0.5-3 part, xylidine 0.05-1.5 part;
100 parts of phenolic aldehyde epoxy vinyl ester resins, vinylbenzene 20-50 part, benzoyl peroxide 0.5-3 part, Diethyl Aniline 0.05-1.5 part;
100 parts of phenol aldehyde modified vinyl ester resins, acetone 20-50 part, methylethyl ketone peroxide 0.5-3 part, naphthoic acid cobalt 0.05-1.5 part;
100 parts of high crosslink density type vinyl ester resins, acetone 20-50 part, cyclohexanone peroxide 0.5-3 part, cobalt octoate 0.05-1.5 part;
Above-mentioned anti-corrosion resin is adapted at using in the extraction equipment that the solvent extration wet method prepares phosphoric acid.
Above-mentioned anti-corrosion resin is under phosphoric acid by wet process extraction system, and the application method when using mould to make: concrete steps are as follows:
1) the preparation mould pastes with resin earlier;
2) apply anticorrosion layer then;
3) apply impervious barrier then;
4) coated structure layer then;
5) apply impervious barrier then;
6) apply anticorrosion layer then;
7) last coated with resins;
Wherein, need to adjust the thickness of structural sheet, impervious barrier and anticorrosion layer, 15~25 ℃ of solidification values, 8~24 hours set times according to finish size.
Described step 2) be by surperficial felt enhanced resin-rich layer, gel content 90%.
Described step 3) is strengthened by chopped mat, gel content 70%;
Described step 4) is that the 0.2mm glasscloth alternately pastes with thickness, gel content about 50%;
Described step 5) is strengthened by chopped mat, gel content 70%;
Described step 6) is by surperficial felt enhanced resin-rich layer, gel content 90%.
Above-mentioned anti-corrosion resin is under phosphoric acid by wet process extraction system, and the application method during as the equipment liner: concrete steps are as follows:
1) the steel matrix surface to equipment carries out sandblasting, removes iron rust and removes surface and oil contaminant;
2) paste with resin earlier;
3) coated structure layer then;
4) apply impervious barrier then;
5) apply anticorrosion layer then;
6) last coated with resins;
Described structural sheet is to be that the 0.2mm glasscloth alternately pastes with thickness, and gel content is about 50%, and thickness is 2mm; Described impervious barrier is to be strengthened by chopped mat, gel content 70%, and thickness is 1.6mm; Described anticorrosion layer is by surperficial felt enhanced resin-rich layer, gel content 90%, and thickness is 0.4mm, 15~25 ℃ of solidification values, 8~24 hours set times.
The invention has the beneficial effects as follows:
1, used material source is wide, and is inexpensive, easy to process, quick;
2, use the equipment of rotproofing of the present invention or processing, the good corrosion resistance in solvent extraction purification of phosphoric acid system, the life-span is long;
3, this anti-corrosion resin all has anticorrosion ability preferably to extraction agent and organic and inorganic corrosion thing such as phosphoric acid, sulfuric acid, is suitable for using on the phosphoric acid extraction equipment and mold.
Embodiment:
Embodiment one
By weight with 100 parts of phenolic aldehyde epoxy vinyl ester unsaturated polyester resins, 50 parts of crosslinking styrenes, 2.5 parts of initiator methylethyl ketone peroxides, 1 part of promotor cobalt naphthenate mixes, in mould during the making equipment member, pasting with resin earlier, is anticorrosion layer, by surperficial felt enhanced resin-rich layer then, gel content 90%, be exactly impervious barrier then, strengthen gel content 70% by chopped mat, be exactly to be coated with structural sheet then, with thickness is that the 0.2mm glasscloth alternately pastes, and gel content is about 50%, is exactly thereafter impervious barrier, strengthen by chopped mat, gel content 70% is anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90% then is to paste with resin at last; Solidified 24 hours at 20 ℃.At medium is water: 258g/L H3PO4+295g/LH2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table one example one.
Embodiment two
By weight with 100 parts of phenol aldehyde modified vinyl ester unsaturated polyester resins, 35 parts of crosslinking styrenes, 2.5 parts of initiator cyclohexanone peroxides, 0.5 part of promotor cobalt naphthenate mixes, in mould during the making equipment member, pasting with resin earlier, is anticorrosion layer, by surperficial felt enhanced resin-rich layer then, gel content 90%, be exactly impervious barrier then, strengthen gel content 70% by chopped mat, be exactly to be coated with structural sheet then, with thickness is that the 0.2mm glasscloth alternately pastes, and gel content is about 50%, is exactly thereafter impervious barrier, strengthen by chopped mat, gel content 70% is anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90% then is to paste with resin at last; Solidified 20 hours at 20 ℃.At medium is water: 258g/L H3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table one example two.
Embodiment three
High crosslink density type vinyl ester resin is 100 parts by weight, 20 parts of vinylbenzene, 0.5 part of benzoyl peroxide, 0.05 part of xylidine mixes, in mould during the making equipment member, pasting with resin earlier, is anticorrosion layer, by surperficial felt enhanced resin-rich layer then, gel content 90%, be exactly impervious barrier then, strengthen gel content 70% by chopped mat, be exactly to be coated with structural sheet then, with thickness is that the 0.2mm glasscloth alternately pastes, and gel content is about 50%, is exactly thereafter impervious barrier, strengthen by chopped mat, gel content 70% is anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90% then is to paste with resin at last; Solidified 20 hours at 20 ℃.At medium is water: 258g/LH
3PO
4+ 295g/L H
2SO
4+ 17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃,, the results are shown in Table one example three through the immersion in 1 year.
Embodiment four
By weight with 100 parts of phenolic aldehyde epoxy vinyl ester resins, 20 parts of vinylbenzene, 2.5 parts of benzoyl peroxides, 1 part of Diethyl Aniline mixes, in mould during the making equipment member, pasting with resin earlier, is anticorrosion layer, by surperficial felt enhanced resin-rich layer then, gel content 90%, be exactly impervious barrier then, strengthen gel content 70% by chopped mat, be exactly to be coated with structural sheet then, with thickness is that the 0.2mm glasscloth alternately pastes, and gel content is about 50%, is exactly thereafter impervious barrier, strengthen by chopped mat, gel content 70% is anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90% then is to paste with resin at last; Solidified 20 hours at 20 ℃.At medium is water: 258g/LH3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table one example four.
Embodiment five
By weight with 100 parts of phenol aldehyde modified vinyl ester resins, 20 parts in acetone, 0.5 part of methylethyl ketone peroxide, 0.05 part of naphthoic acid cobalt mixes, in mould during the making equipment member, pasting with resin earlier, is anticorrosion layer, by surperficial felt enhanced resin-rich layer then, gel content 90%, be exactly impervious barrier then, strengthen gel content 70% by chopped mat, be exactly to be coated with structural sheet then, with thickness is that the 0.2mm glasscloth alternately pastes, and gel content is about 50%, is exactly thereafter impervious barrier, strengthen by chopped mat, gel content 70% is anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90% then is to paste with resin at last; Solidified 20 hours at 20 ℃.At medium is water: 258g/LH3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table one example five.
Embodiment six
By weight with 100 parts of high crosslink density type vinyl ester resins, 20 parts in acetone, 0.5 part of cyclohexanone peroxide, 0.05 part of cobalt octoate mixes, in mould during the making equipment member, pasting with resin earlier, is anticorrosion layer, by surperficial felt enhanced resin-rich layer then, gel content 90%, be exactly impervious barrier then, strengthen gel content 70% by chopped mat, be exactly to be coated with structural sheet then, with thickness is that the 0.2mm glasscloth alternately pastes, and gel content is about 50%, is exactly thereafter impervious barrier, strengthen by chopped mat, gel content 70% is anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90% then is to paste with resin at last; Solidified 20 hours at 20 ℃.At medium is water: 258g/LH3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table one example six.
Embodiment seven
After the plain steel surface is removed iron rust and is removed degreasing through sandblasting, by weight with 100 parts of phenolic aldehyde epoxy vinyl ester unsaturated polyester resins, 50 parts of crosslinking styrenes, 2.5 parts of initiator methylethyl ketone peroxides, 1 part of promotor cobalt naphthenate, mix, being coated with one deck resin primer earlier on treated matrix, being coated with structural sheet again after solidifying, is that the 0.2mm glasscloth alternately pastes with thickness, gel content is about 50%, and thickness is about 2mm; Be exactly impervious barrier then, strengthen gel content 70%, thickness 1.6mm by chopped mat; Be anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90%, thickness 0.4mm; Outermost layer then is to paste with resin.Solidified 24 hours at 20 ℃.At medium is water: 258g/L H3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table two example seven.
Embodiment eight
After the plain steel surface is removed iron rust and is removed degreasing through sandblasting, by weight with 100 parts of phenol aldehyde modified vinyl ester unsaturated polyester resins, 40 parts of crosslinking styrenes, 2.5 parts of initiator cyclohexanone peroxides, 0.6 part of promotor cobalt naphthenate, mix, being coated with one deck resin primer earlier on treated matrix, being coated with structural sheet again after solidifying, is that the 0.2mm glasscloth alternately pastes with thickness, gel content is about 50%, and thickness is about 2mm; Be exactly impervious barrier then, strengthen gel content 70%, thickness 1.6mm by chopped mat; Be anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90%, thickness 0.4mm; Outermost layer then is to paste with resin.Solidified 24 hours at 20 ℃.At medium is water: 258g/L H3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table two example eight.
Embodiment nine
After the plain steel surface is removed iron rust and is removed degreasing through sandblasting, by weight with 100 parts of high crosslink density type vinyl ester resins, 30 parts of vinylbenzene, 0.75 part of benzoyl peroxide, xylidine 0.25, mix, being coated with one deck resin primer earlier on treated matrix, being coated with structural sheet again after solidifying, is that the 0.2mm glasscloth alternately pastes with thickness, gel content is about 50%, and thickness is about 2mm; Be exactly impervious barrier then, strengthen gel content 70%, thickness 1.6mm by chopped mat; Be anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90%, thickness 0.4mm; Outermost layer then is to paste with resin.Solidified 24 hours at 20 ℃.At medium is water: 258g/LH3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table two example nine.
Embodiment ten
After the plain steel surface is removed iron rust and is removed degreasing through sandblasting, by weight with 100 parts of phenolic aldehyde epoxy vinyl ester resins, 25 parts of vinylbenzene, 0.8 part of benzoyl peroxide, 0.16 part of Diethyl Aniline, mix, being coated with one deck resin primer earlier on treated matrix, being coated with structural sheet again after solidifying, is that the 0.2mm glasscloth alternately pastes with thickness, gel content is about 50%, and thickness is about 2mm; Be exactly impervious barrier then, strengthen gel content 70%, thickness 1.6mm by chopped mat; Be anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90%, thickness 0.4mm; Outermost layer then is to paste with resin.Solidified 24 hours at 20 ℃.At medium is water: 258g/LH3PO4+295g/L H2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table two example ten.
Embodiment 11
After the plain steel surface is removed iron rust and is removed degreasing through sandblasting, by weight with 100 parts of phenol aldehyde modified vinyl ester resins, 40 parts in acetone, 0.5 part of methylethyl ketone peroxide, 0.3 part of naphthoic acid cobalt, mix, being coated with one deck resin primer earlier on treated matrix, being coated with structural sheet again after solidifying, is that the 0.2mm glasscloth alternately pastes with thickness, gel content is about 50%, and thickness is about 2mm; Be exactly impervious barrier then, strengthen gel content 70%, thickness 1.6mm by chopped mat; Be anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90%, thickness 0.4mm; Outermost layer then is to paste with resin.Solidified 24 hours at 20 ℃.At medium is water: 258g/L H3PO4+295g/LH2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table two example 11.
Embodiment 12
After the plain steel surface is removed iron rust and is removed degreasing through sandblasting, by weight with 100 parts of high crosslink density type vinyl ester resins, 45 parts in acetone, 2 parts of cyclohexanone peroxides, 0.5 part of cobalt octoate, mix, being coated with one deck resin primer earlier on treated matrix, being coated with structural sheet again after solidifying, is that the 0.2mm glasscloth alternately pastes with thickness, gel content is about 50%, and thickness is about 2mm; Be exactly impervious barrier then, strengthen gel content 70%, thickness 1.6mm by chopped mat; Be anticorrosion layer then, by surperficial felt enhanced resin-rich layer, gel content 90%, thickness 0.4mm; Outermost layer then is to paste with resin.Solidified 24 hours at 20 ℃.At medium is water: 258g/L H3PO4+295g/LH2SO4+17g/L HF, organic phase: under the environment of ZL200510019734.5 patent extraction agent and 50 ℃, through the immersion in 1 year, the results are shown in Table two example 12.
Above-mentioned the first six kind embodiment makes the experiment test piece according to the Mold Making mode respectively and carries out corrosion-resistant experiment, and testing circumstance is a water: 258g/L H
3PO
4+ 295g/L H
2SO
4+ 17g/L HF, organic phase: ZL200510019734.5 patent extraction agent, water and organic phase all remain on 50 ℃, and soak time 1 year obtains test-results as shown in Table 1.
Table one erosion resistance experimental result:
Above-mentioned back six kinds of embodiment make experiment test piece (steel disc is wrapped up fully with resin) according to equipment liner production method respectively and carry out corrosion-resistant experiment, and testing circumstance is a water: 258g/L H
3PO
4+ 295g/L H
2SO
4+ 17g/L HF, organic phase: ZL200510019734.5 patent extraction agent, water and organic phase all remain on 50 ℃, and soak time 1 year obtains test-results as shown in Table 2.
Table two erosion resistance experimental result:
Above-described specific embodiment; purpose of the present invention, technical scheme and beneficial effect are further described; institute is understood that; the above is only own for specific embodiments of the invention; be not limited to the present invention; all within claim of the present invention, any modification of being made, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. the anti-corrosion resin of a preparing phosphoric acid by solvent extraction, it is characterized in that: the components by weight percent of described anti-corrosion resin is: 100 parts of resins, linking agent 20-50 part, initiator 0.5-2.5 part, promotor 0.05-1.5 part, wherein, 15~25 ℃ of solidification values, 8~24 hours set times.
2. anti-corrosion resin as claimed in claim 1 is characterized in that: described resin is a kind of of phenolic aldehyde epoxy vinyl ester resin, phenol aldehyde modified vinyl ester resin or high crosslink density type vinyl ester resin.
3. anti-corrosion resin as claimed in claim 1 is characterized in that: described linking agent is vinylbenzene or acetone.
4. anti-corrosion resin as claimed in claim 1 is characterized in that: described initiator is a kind of of methylethyl ketone peroxide, cyclohexanone peroxide or benzoyl peroxide.
5. anti-corrosion resin as claimed in claim 1 is characterized in that: described promotor is a kind of of naphthoic acid cobalt, cobalt octoate, cobalt naphthenate or xylidine.
6. anti-corrosion resin as claimed in claim 1 is characterized in that: the following weight part combination of the formula optimization of described anti-corrosion resin:
100 parts of phenolic aldehyde epoxy vinyl ester resins, vinylbenzene 20-50 part, methylethyl ketone peroxide 0.5-3 part, cobalt naphthenate 0.05-1.5 part;
100 parts of phenol aldehyde modified vinyl ester resins, vinylbenzene 20-50 part, cyclohexanone peroxide 0.5-3 part, cobalt naphthenate 0.05-1.5 part;
100 parts of high crosslink density type vinyl ester resins, vinylbenzene 20-50 part, benzoyl peroxide 0.5-3 part, xylidine 0.05-1.5 part;
100 parts of phenolic aldehyde epoxy vinyl ester resins, vinylbenzene 20-50 part, benzoyl peroxide 0.5-3 part, Diethyl Aniline 0.05-1.5 part;
100 parts of phenol aldehyde modified vinyl ester resins, acetone 20-50 part, methylethyl ketone peroxide 0.5-3 part, naphthoic acid cobalt 0.05-1.5 part;
100 parts of high crosslink density type vinyl ester resins, acetone 20-50 part, cyclohexanone peroxide 0.5-3 part, cobalt octoate 0.05-1.5 part;
7. with preparing application in the equipment of phosphoric acid in the solvent extration wet method as any described anti-corrosion resin among the claim 1-6.
8. use as the application method of anti-corrosion resin under phosphoric acid by wet process extraction system as described among the claim 1-6 any, it is characterized in that: when using mould to make, concrete steps are as follows:
1) the preparation mould pastes with resin earlier;
2) apply anticorrosion layer then;
3) apply impervious barrier then;
4) coated structure layer then;
5) apply impervious barrier then;
6) apply anticorrosion layer then;
7) last coated with resins;
Wherein, need to adjust the thickness of structural sheet, impervious barrier and anticorrosion layer, 15~25 ℃ of solidification values, 8~24 hours set times according to finish size.
9. method as claimed in claim 8: it is characterized in that:
Described step 2) be by surperficial felt enhanced resin-rich layer, gel content 90%.
Described step 3) is strengthened by chopped mat, gel content 70%;
Described step 4) is that the 0.2mm glasscloth alternately pastes with thickness, gel content about 50%;
Described step 5) is strengthened by chopped mat, gel content 70%;
Described step 6) is by surperficial felt enhanced resin-rich layer, gel content 90%.
10. use as the application method of anti-corrosion resin under phosphoric acid by wet process extraction system as described among the claim 1-6 any, it is characterized in that: as the equipment liner time, concrete steps are as follows:
1) the steel matrix surface to equipment carries out sandblasting, removes iron rust and removes surface and oil contaminant;
2) paste with resin earlier;
3) coated structure layer then;
4) apply impervious barrier then;
5) apply anticorrosion layer then;
6) last coated with resins;
Described structural sheet is to be that the 0.2mm glasscloth alternately pastes with thickness, and gel content is about 50%, and thickness is 2mm; Described impervious barrier is to be strengthened by chopped mat, gel content 70%, and thickness is 1.6mm; Described anticorrosion layer is by surperficial felt enhanced resin-rich layer, gel content 90%, and thickness is 0.4mm, 15~25 ℃ of solidification values, 8~24 hours set times.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110372259A (en) * | 2019-07-08 | 2019-10-25 | 杭州三耐环保科技股份有限公司 | A kind of extraction tank and preparation method thereof |
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2009
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110372259A (en) * | 2019-07-08 | 2019-10-25 | 杭州三耐环保科技股份有限公司 | A kind of extraction tank and preparation method thereof |
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