CN101591786B - Electrolysis chlorine dioxide generator and electrolytic bath - Google Patents
Electrolysis chlorine dioxide generator and electrolytic bath Download PDFInfo
- Publication number
- CN101591786B CN101591786B CN2009100998089A CN200910099808A CN101591786B CN 101591786 B CN101591786 B CN 101591786B CN 2009100998089 A CN2009100998089 A CN 2009100998089A CN 200910099808 A CN200910099808 A CN 200910099808A CN 101591786 B CN101591786 B CN 101591786B
- Authority
- CN
- China
- Prior art keywords
- barrier film
- inner room
- salt
- negative electrode
- electrolyzer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention discloses an electrolysis chlorine dioxide generator and an electrolytic bath. The electrolytic bath comprises an outer chamber for accommodating clear water, an inner chamber arranged in the outer chamber and used for accommodating electrolysis brine, and a membrane arranged between the inner chamber and the outer chamber; the side wall of the inner chamber is provided with at least two combined cathodes which are symmetrically arranged and combined by a cathode and the membrane together; an anode is placed at the middle position of the inner chamber; the clear water is put into the outer chamber of the electrolytic bath, while the electrolysis brine is put into the inner chamber; and the electrolysis brine consists of water, salt and chlorite, wherein the salt accounts for 10 portions by weight, the chlorite accounts for 0.5 to 8 portions by weight, and 30 percent of saturated salt is dissolved in the formed electrolysis brine. The electrolytic bath has the characteristics of low electricity loss, long service life, simple structure, high service efficiency and the like.
Description
Technical field
What the present invention relates to is a kind of electrolysis chlorine dioxide generator and electrolyzer that produces sterilizing agent, belongs to a kind of producer technical field that is used to produce disinfection sanitizer.
Background technology
In the prior art, electrolyzer is the core component of electrolysis chlorine dioxide generator, and it is mainly by inner room (anolyte compartment), mistress's (cathode compartment), negative electrode, neutral pole, anode and barrier film are formed, and barrier film thereby has the gap between barrier film and negative electrode between anode and negative electrode usually, the inside has water to exist, therefore do not produce electric current, thus the electrolyzer that this structure is formed for the clear water electrolysis, efficient is not high; At inner room, the electrolytic brine of just putting in the anolyte compartment does not add the agent of any dioxide peroxide synergistic agent for conventional salt solution in addition, so the content that the effect of chlorine dioxide generator reaches in sterilizing agent is had a greatly reduced quality.
Summary of the invention
The objective of the invention is to overcome the deficiency that prior art exists, and it is low to provide a kind of electricity to decrease, long service life, simple in structure, electrolysis chlorine dioxide generator that service efficiency is high and electrolyzer.
The objective of the invention is to finish by following technical solution, described electrolyzer includes the mistress of dress clear water in, place this outer indoor, in the inner room of electrolytic brine is housed and is arranged on barrier film between inner room, the mistress, described inner room sidewall be provided with at least two symmetric arrangement, by the cathode assembly that negative electrode and barrier film combine, described anode is placed in the mid-way of inner room.
Described negative electrode is combined by hot melt by the press box on cathode screen and the barrier film; Described barrier film is that ion-exchange membrane constitutes.
Described negative electrode also is fixed together by the plastics screw with a neutral pole, and compresses described barrier film, and makes barrier film, negative electrode and neutral pole form zero pole span.
Net is also arranged on the described neutral pole and be welded on the housing of inner room, make neutral pole and inner room form one, described negative electrode, barrier film, neutral pole and inner room form one.
A kind of electrolysis chlorine dioxide generator that uses above-mentioned electrolyzer, the outer indoor clear water of having put into of described electrolyzer, and put into electrolytic brine at inner room; Described electrolytic brine is made up of water, salt and chlorite, and wherein salt and chloritic weight part proportioning are 10 parts of salt, chlorite 0.5-8 part, and be dissolved with 30% saturated salt in the hydrolysis salt solution that forms.
The invention belongs to a kind of improvement, mainly comprise the improvement of electrolyzer and electrolysis generator, thereby it is low to have the electricity damage prior art, long service life, simple in structure, characteristics such as service efficiency height.
Description of drawings
Fig. 1 is a structural representation of the present invention.
Embodiment
Below in conjunction with specific embodiments and the drawings the present invention is done detailed introduction: shown in the accompanying drawing 1, electrolyzer of the present invention includes the mistress 2 of dress clear water 1 in, also be referred to as cathode compartment, place in this mistress 2, in the inner room 4 of electrolytic brine 3 is housed, also be referred to as the anolyte compartment, and be arranged on inner room 4, barrier film 5 between the mistress 2, described inner room 4 sidewalls are provided with at least two symmetric arrangement, the cathode assembly that combines by negative electrode 6 and barrier film 5, described anode 8 is placed in the mid-way of inner room 4, both sides all use barrier film and cathode compartment to separate, and help improving the anodic working efficiency.Negative electrode 6 shown in the figure is combined by hot melt by the press box on cathode screen and the barrier film 5; Described barrier film 5 constitutes for ion-exchange membrane.
Described negative electrode 6 also is fixed together by the plastics screw with a neutral pole; and compress described barrier film 5, and make barrier film 5, negative electrode 6 form zero pole span with neutral pole, help protecting better barrier film like this; improve its work-ing life, can greatly improve the performance of electrolyzer simultaneously.
Net is also arranged on the described neutral pole and be welded on the housing of inner room 4, make neutral pole and inner room 4 form one, described negative electrode 6, barrier film 5, neutral pole and inner room 4 form one, and it helps modular design.
Above-mentioned electrolyzer is the core component of electrolysis chlorine dioxide generator, and it is determining gas producing efficiency, stability, life-span and the processing property etc. of chlorine dioxide generator.
Electrolysis chlorine dioxide generator of the present invention, it is the outer indoor clear water of having put at described electrolyzer, can use the clear water electrolysis, the efficient height; And put into electrolytic brine at inner room; Described electrolytic brine is made up of water, salt and chlorite, wherein salt and chloritic weight part proportioning are 10 parts of salt, chlorite 0.5-8 part, and be dissolved with 30% saturated salt in the hydrolysis salt solution that forms, described weight part proportioning all can realize in specific embodiment one by one, no longer launches explanation for this reason.Chlorite described here can increase the chlorine dioxide content in the electrolysis generation sterilizing agent effectively, and mechanism is: the chlorion electrolysis produces chlorine, and chlorine and chlorite reaction produce dioxide peroxide.
Claims (3)
1. electrolyzer that is used for electrolysis chlorine dioxide generator, described electrolyzer includes the mistress of dress clear water in, place this outer indoor, in the inner room of electrolytic brine is housed and is arranged on barrier film between inner room, the mistress, it is characterized in that described inner room sidewall be provided with at least two symmetric arrangement, by the cathode assembly that negative electrode and barrier film combine, described anode is placed in the mid-way of inner room; Described negative electrode is combined by hot melt by the press box on cathode screen and the barrier film; Described barrier film is that ion-exchange membrane constitutes; Described negative electrode also is fixed together by the plastics screw with a neutral pole, and compresses described barrier film, and makes barrier film, negative electrode and neutral pole form zero pole span.
2. electrolyzer according to claim 1 is characterized in that net also being arranged on the described neutral pole and being welded on the housing of inner room, and makes neutral pole and inner room form one, and described negative electrode, barrier film, neutral pole and inner room form one.
3. one kind is used the electrolysis chlorine dioxide generator of electrolyzer as claimed in claim 1 or 2, and it is the outer indoor clear water of having put at described electrolyzer, and has put into electrolytic brine at inner room; It is characterized in that described electrolytic brine is made up of water, salt and chlorite, wherein salt and chloritic weight part proportioning are 10 parts of salt, chlorite 0.5-8 part, and be dissolved with 30% saturated salt in the hydrolysis salt solution that forms.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100998089A CN101591786B (en) | 2009-06-22 | 2009-06-22 | Electrolysis chlorine dioxide generator and electrolytic bath |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100998089A CN101591786B (en) | 2009-06-22 | 2009-06-22 | Electrolysis chlorine dioxide generator and electrolytic bath |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101591786A CN101591786A (en) | 2009-12-02 |
| CN101591786B true CN101591786B (en) | 2011-03-16 |
Family
ID=41406660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100998089A Expired - Fee Related CN101591786B (en) | 2009-06-22 | 2009-06-22 | Electrolysis chlorine dioxide generator and electrolytic bath |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101591786B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101710223B1 (en) * | 2010-03-19 | 2017-02-24 | 다이꼬 야꾸힝 가부시끼가이샤 | Electrolyzer |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201427998Y (en) * | 2009-06-22 | 2010-03-24 | 陈维军 | Electrolytic cell for electrolytic method chlorine dioxide generator |
-
2009
- 2009-06-22 CN CN2009100998089A patent/CN101591786B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201427998Y (en) * | 2009-06-22 | 2010-03-24 | 陈维军 | Electrolytic cell for electrolytic method chlorine dioxide generator |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101591786A (en) | 2009-12-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Foller et al. | Processes for the production of mixtures of caustic soda and hydrogen peroxide via the reduction of oxygen | |
| CN205151853U (en) | Electrolysis trough that contains salt waste water and retrieve acid -base is simultaneously handled to two units negative pole altogether | |
| WO2007075865A3 (en) | Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes | |
| BR0207222A (en) | High efficiency electrolysis cell for the generation of oxidants in solutions. | |
| US20130228459A1 (en) | Electrolyzed water producing apparatus | |
| CN101956206B (en) | Electrolytic device and technology for preparing hydrogen and oxygen through seawater electrolysis | |
| CN107428567A (en) | Electrolytic water generating device | |
| DK201370805A (en) | Aluminum smelter including cells with cathode output at the bottom of the pot shell and cell stabilizing means | |
| WO2017018441A1 (en) | Molten salt electrolytic cell, metallic magnesium production method using same, and sponge titanium production method | |
| CN101591786B (en) | Electrolysis chlorine dioxide generator and electrolytic bath | |
| KR101312879B1 (en) | Three-Compartment-Cell and One-Port typed Electrolysis Apparatus | |
| CN201427998Y (en) | Electrolytic cell for electrolytic method chlorine dioxide generator | |
| JP2007284730A5 (en) | ||
| CN201901710U (en) | System for preparing sodium hypochlorite | |
| KR20140035687A (en) | A electrolysis apparatus | |
| JP2000515106A (en) | Method for producing polysulfide by electrolytic oxidation | |
| CN101922014A (en) | Diaphragm process chlorine generator and preparation method of sodium hypochlorite | |
| KR20130077099A (en) | Apparatus for providing purified water and ionized water with the ability to sterilize tanks | |
| CN213538117U (en) | Electrolytic tank structure for producing lithium hydroxide by electrolyzing water to produce hydrogen by membrane method | |
| KR100651654B1 (en) | A water purifier using an electrolysis | |
| JP2007014828A (en) | Apparatus for producing strong alkaline electrolytic water and strong alkaline electrolytic water generated by its apparatus | |
| JP2008119578A (en) | Electrolyzer | |
| JP2001191079A (en) | Electrolytic water forming device | |
| CN201738014U (en) | Electrolytic cell for efficient electrolytic method chlorine dioxide generator | |
| CN105271481A (en) | Electrolytic cell for treating salt-bearing wastewater with double-unit common cathode while recycling acid and alkali |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110316 Termination date: 20150622 |
|
| EXPY | Termination of patent right or utility model |