CN101584957A - Integrated coupling device for flue gas desulfurization and dedusting - Google Patents
Integrated coupling device for flue gas desulfurization and dedusting Download PDFInfo
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Abstract
一种锅炉烟气脱硫技术领域的烟气脱硫除尘一体化耦合装置,包括:塔体、切向进气口、烟气出口、底层旋流板、内向喷射板、喷淋层、下除雾板和上除雾器,中心溢流管位于内向喷射板的中央,若干片喷射叶片以正多边形方式斜向逐层固定设置于中心溢流管的外沿,支撑板筋与每一片喷射叶片的两端固定连接。本发明利用独特设计的内向喷射板,将喷淋、旋流方法有机耦合起来,内向喷射板兼具脱硫除尘、改善气流分布以及汇集脱硫液的多重功效,使所发明的装置具有高效脱硫除尘作用,并明显降低液气比及气流阻力。
An integrated coupling device for flue gas desulfurization and dust removal in the technical field of boiler flue gas desulfurization, comprising: a tower body, a tangential air inlet, a flue gas outlet, a bottom swirl plate, an inward spray plate, a spray layer, and a lower defogging plate And the upper mist eliminator, the central overflow pipe is located in the center of the inward spraying plate, and several spraying blades are fixed on the outer edge of the central overflowing pipe in an oblique and layer-by-layer manner in the form of a regular polygon. End fixed connection. The invention utilizes a uniquely designed inward jetting plate to organically couple spraying and swirling flow methods. The inward jetting plate has multiple functions of desulfurization and dust removal, improvement of air distribution and collection of desulfurization liquid, so that the invented device has high-efficiency desulfurization and dust removal. , and significantly reduce the liquid-gas ratio and airflow resistance.
Description
技术领域 technical field
本发明涉及的是一种锅炉烟气脱硫技术领域的装置,具体是一种烟气脱硫除尘一体化耦合装置。The invention relates to a device in the technical field of boiler flue gas desulfurization, in particular to an integrated coupling device for flue gas desulfurization and dust removal.
背景技术 Background technique
我国是世界上煤炭消耗量最大的国家,因燃煤所排放的二氧化硫总量位居世界第一,同时我国的烟尘排放总量也处于世界前列。因此,我国政府正逐步实行严格的燃煤烟气排放标准,推行电站锅炉、工业锅炉及窑炉的烟气脱硫和除尘处理。my country is the country with the largest coal consumption in the world, and the total amount of sulfur dioxide emitted by coal burning ranks first in the world. Therefore, the Chinese government is gradually implementing strict coal-fired flue gas emission standards, and implementing flue gas desulfurization and dust removal treatment for power plant boilers, industrial boilers and kilns.
烟气脱硫方法多种多样,目前广泛应用的湿法脱硫装置有底层旋流板塔、喷淋塔、鼓泡塔、文丘里吸收器等;大型火电脱硫大多采用喷淋塔,因其气路阻力最小,能适应不同的锅炉负荷,但需采用较高的液气比,且除尘效果不理想。底层旋流板塔的优点是具有高效除尘作用,并能在低液气比下能实现高效率;但在锅炉负荷低时,单板效率较低、脱硫效率不够高。将喷淋洗涤与旋流技术结合起来则有利于发挥二者的优势。There are various flue gas desulfurization methods. Currently, wet desulfurization devices widely used include bottom swirl plate tower, spray tower, bubble tower, Venturi absorber, etc.; large-scale thermal power desulfurization mostly uses spray tower, because of its gas path It has the least resistance and can adapt to different boiler loads, but it needs to adopt a higher liquid-gas ratio, and the dust removal effect is not ideal. The advantage of the bottom swirling plate tower is that it has high-efficiency dust removal and can achieve high efficiency at low liquid-to-gas ratio; but when the boiler load is low, the efficiency of the single plate is low and the desulfurization efficiency is not high enough. The combination of spray washing and swirl technology is beneficial to play the advantages of both.
经对现有技术文献的检索发现:张广新《75t/h锅炉烟气脱硫装置设计与应用》(冶金动力,2003,3:637-639)对水膜除尘器进行了改造(张广新,75t/h锅炉烟气脱硫装置设计与应用.冶金动力,2003,3:637-639),将喷淋段和底层旋流板分别置于两个塔内,使烟气先在喷淋塔气液顺流接触后,再引入底层旋流板塔进行气液逆流接触。但是,这种方法仅是将二者简单结合,其流程较长,需要多级供液,循环液一次利用率低。After searching the existing technical literature, it was found that Zhang Guangxin's "Design and Application of 75t/h Boiler Flue Gas Desulfurization Device" (Metallurgical Power, 2003, 3: 637-639) modified the water film dust collector (Zhang Guangxin, 75t/h Design and application of boiler flue gas desulfurization device. Metallurgical Power, 2003, 3: 637-639), the spray section and the bottom swirl plate are respectively placed in two towers, so that the flue gas first flows in the spray tower gas-liquid After the contact, it is introduced into the bottom swirl plate column for gas-liquid countercurrent contact. However, this method is only a simple combination of the two, the process is long, multi-stage liquid supply is required, and the primary utilization rate of circulating liquid is low.
专利申请号:200810120375,公开号CN101342455A,记载了一种“喷淋旋流组合脱硫装置”,该装置将喷淋和底层旋流板在同一个塔内分两段进行——上层喷淋、下层旋流,两段的进液由两组相互独立的泵供给。这种脱硫装置比较紧凑,在保证脱硫效率的同时,气流阻力可明显降低。但是由于喷淋下来的脱硫液在到达下层底层旋流板前大多沿塔壁流到底层旋流板的溢流槽,使这部分液体无法再继续利用,从而导致循环液一次利用率也相对较低。同时,旋流而上的气流在塔内的流场分布不均,影响喷淋洗涤效果。Patent application number: 200810120375, publication number CN101342455A, which records a "spray swirl combined desulfurization device", which divides the spray and bottom swirl plates into two sections in the same tower - the upper spray, the lower Swirling flow, the liquid inlet of the two stages is supplied by two sets of independent pumps. This kind of desulfurization device is relatively compact, and while ensuring the desulfurization efficiency, the airflow resistance can be significantly reduced. However, since the sprayed desulfurization liquid mostly flows along the tower wall to the overflow tank of the bottom swirl plate before reaching the lower bottom swirl plate, this part of the liquid cannot be used any longer, resulting in a relatively low primary utilization rate of the circulating liquid . At the same time, the flow field of the swirling upward airflow in the tower is unevenly distributed, which affects the spray washing effect.
发明内容 Contents of the invention
本发明针对现有技术存在的上述不足,提供一种烟气脱硫除尘一体化耦合装置,采用内向喷射板,将旋流与喷淋方法有机结合起来,形成新型一体化脱硫除尘装置,从而在保证高效率脱硫、除尘的情况下,降低浆液的循环量,降低能耗,且操作范围更宽。Aiming at the above-mentioned deficiencies in the prior art, the present invention provides an integrated coupling device for flue gas desulfurization and dust removal, which uses an inward injection plate to organically combine swirling flow and spraying methods to form a new integrated desulfurization and dust removal device, thereby ensuring In the case of high-efficiency desulfurization and dust removal, the circulation volume of slurry is reduced, energy consumption is reduced, and the operating range is wider.
本发明是通过以下技术方案实现的,本发明包括:塔体、切向进气口、烟气出口、底层旋流板、内向喷射板、喷淋层、下除雾板和上除雾器,其中:切向进气口位于塔体的下端侧面,底层旋流板、内向喷射板、喷淋层、下除雾板和上除雾器依次由下而上平行设置于塔体内部,烟气出口位于塔体的顶端。The present invention is achieved through the following technical solutions, the present invention includes: a tower body, a tangential air inlet, a flue gas outlet, a bottom swirl plate, an inward injection plate, a spray layer, a lower demister plate and an upper demister, Among them: the tangential air inlet is located on the side of the lower end of the tower body, the bottom swirl plate, the inward injection plate, the spray layer, the lower demister plate and the upper demister are arranged in parallel in the tower body from bottom to top, and the flue gas The outlet is located at the top of the tower body.
所述旋流板位于内向喷射板的下方,去除了常规旋流板的异型溢流管,其外缘与塔壁之间留有3-10mm的空隙;The swirl plate is located below the inward spray plate, and the special-shaped overflow pipe of the conventional swirl plate is removed, leaving a gap of 3-10mm between its outer edge and the tower wall;
所述的内向喷射板上设有:喷射叶片、中心溢流管以及支撑板筋,其中:中心溢流管位于内向喷射板的中央,若干片喷射叶片以正多边形方式斜向逐片固定设置于中心溢流管的外沿,支撑板筋与每一片喷射叶片的两端固定连接。The inward jetting plate is provided with: jetting blades, a central overflow pipe and a support rib, wherein: the central overflow pipe is located in the center of the inward jetting plate, and several jetting blades are fixedly arranged on the The outer edge of the central overflow pipe and the supporting rib are fixedly connected with the two ends of each spray blade.
所述的中心溢流管的直径为支撑板筋直径的20%~40%。The diameter of the central overflow pipe is 20%-40% of the diameter of the support plate.
所述的喷射叶片与水平面所呈仰角为20°~60°,使气流喷射方向指向中心;该喷射叶片的宽度为20~120mm,喷射叶片为整板切割、钣金或多叶片组合焊接制成,根据每板直径的大小,叶片所组成的正多边形边数为3-12个。The elevation angle between the spray blade and the horizontal plane is 20°~60°, so that the jet direction of the airflow points to the center; the width of the spray blade is 20~120mm, and the spray blade is made of whole plate cutting, sheet metal or multi-blade combination welding , according to the diameter of each plate, the number of sides of the regular polygon formed by the blades is 3-12.
所述的支撑板筋的宽度为20~120mm;The width of the support rib is 20-120mm;
该内向喷射板将喷淋到该板上脱硫液以及沿塔壁流下的脱硫液重新内向喷射,达到脱硫除尘的效果,其单板脱硫、除尘效率与底层旋流板接近;The inward injection plate sprays the desulfurization liquid sprayed on the plate and the desulfurization liquid flowing down the tower wall inward again to achieve the effect of desulfurization and dust removal, and its desulfurization and dust removal efficiency of the single plate is close to that of the bottom swirl plate;
与现有技术相比,本发明利用独特设计的内向喷射板,将喷淋、旋流方法有机耦合起来,内向喷射板兼具脱硫除尘、改善气流分布以及汇集脱硫液的多重功效,使所发明的装置具有高效脱硫除尘作用,并明显降低液气比及气流阻力。Compared with the prior art, the present invention utilizes the uniquely designed inward jetting plate to organically couple the spraying and swirling flow methods. The inward jetting plate has multiple functions of desulfurization and dust removal, improvement of air distribution and collection of desulfurization liquid, making the invention The device has high-efficiency desulfurization and dust removal, and significantly reduces the liquid-gas ratio and airflow resistance.
附图说明 Description of drawings
图1为本发明结构示意图;Fig. 1 is a structural representation of the present invention;
图2为内向喷射板结构示意图;Fig. 2 is a schematic diagram of the structure of the inward injection plate;
图中:a为内向喷射板仰视图;b为内向喷射板侧视图;In the figure: a is the bottom view of the inward jetting plate; b is the side view of the inward jetting plate;
其中:1切向烟气进口、2塔体、3水膜除尘段、4底层旋流板、5内向喷射板、6喷淋层及喷嘴、7下除雾板、8备用喷淋管、9上除雾器、10烟气出口、11脱硫液排放口、12脱硫循环泵、13中心溢流管(带有水封)、14喷射叶片和15支撑板筋。Among them: 1 tangential flue gas inlet, 2 tower body, 3 water film dust removal section, 4 bottom swirl plate, 5 inward spray plate, 6 spray layer and nozzle, 7 lower defogging plate, 8 spare spray pipe, 9 Upper demister, 10 flue gas outlet, 11 desulfurization liquid discharge outlet, 12 desulfurization circulation pump, 13 central overflow pipe (with water seal), 14 spray vanes and 15 support ribs.
具体实施方式 Detailed ways
下面对本发明的实施例作详细说明,本实施例在以本发明技术方案为前提下进行实施,给出了详细的实施方式和具体的操作过程,但本发明的保护范围不限于下述的实施例。The embodiments of the present invention are described in detail below. This embodiment is implemented on the premise of the technical solution of the present invention, and detailed implementation methods and specific operating procedures are provided, but the protection scope of the present invention is not limited to the following implementation example.
实施例1Example 1
如图1所示,本实施例包括:切向烟气进口1、塔体2、水膜除尘段3、底层旋流板4、内向喷射板5、喷淋层及喷嘴6、下除雾板7、备用喷淋管8、上除雾器9、烟气出口10、脱硫液排放口11和脱硫循环泵12,其中:切向进气口位于塔体的下端侧面,底层旋流板、内向喷射板、喷淋层、第一除雾板和第二除雾板依次由下而上平行设置于塔体内部,烟气出口位于塔体的顶端。As shown in Figure 1, this embodiment includes: tangential
所述的底层旋流板去除了常规旋流板的异型溢流管,其外缘与塔壁之间留有6mm的空隙。The special-shaped overflow pipe of the conventional swirl plate is removed from the bottom swirl plate, and a gap of 6mm is left between its outer edge and the tower wall.
如图2所示,所述的内向喷射板5上设有:中心溢流管13、喷射叶片14和支撑板筋15,其中:中心溢流管13位于内向喷射板5的中央,42片喷射叶片14以六边形方式斜向分为7层,逐层固定设置于中心溢流管13的外沿,支撑板筋15与每一片喷射叶片14的两端固定连接。由叶片所组成的正多边形的边数为6个。As shown in Figure 2, the
所述的中心溢流管13的直径为支撑板筋15直径的30%。The diameter of the
所述的喷射叶片14与水平面所呈仰角为30°,使气流喷射方向指向中心;该喷射叶片14的宽度为100mm,喷射叶片14为多叶片组合焊接制成。The elevation angle between the
所述的支撑板筋15的宽度为100mm;The width of described
该内向喷射板5将喷淋到该板上脱硫液以及沿塔壁流下的脱硫液重新内向喷射,达到脱硫除尘的效果,其单板脱硫、除尘效率与底层旋流板4接近;The
本实施例通过以下流程实现烟气脱硫:This embodiment realizes flue gas desulfurization through the following process:
含有烟尘及二氧化硫的烟气通过入口烟道1切向进入吸收塔,并在吸收塔的水膜区3进行预除尘,其中脱硫液水膜经由上层底层旋流板四周与塔壁之间的环隙所形成的。接着,气流通过底层的底层旋流板4,并与底层旋流板上的液体薄层进行喷射式接触进行脱硫除尘,底层旋流板上的脱硫液是通过上层内向喷射板的中心溢流管流到其盲板上的,再向四周喷射扩散。之后,气流再经过内向喷射板5继续上升,并将该板上的脱硫液层向内喷射,在喷射过程中继续进行脱硫除尘。内向喷射板上脱硫液主要来自与喷淋层的直接喷洒以及有沿塔壁留下的液体,脱硫液经内向喷射汇集到中心溢流管,并流到下层底层旋流板的盲板上。其后,气流经过喷淋段,与喷淋层喷嘴所喷洒的脱硫液滴进行气液逆流接触,继续脱硫过程。此后,烟气再经过下除雾板以及除雾板进行充分除雾,并经过气体出口流出吸收塔。在上述过程中,脱硫液是使用专用脱硫循环泵向喷淋层进行输送到。The flue gas containing soot and sulfur dioxide enters the absorption tower tangentially through the
本实施例技术效果验证具体如下:The technical effect verification of this embodiment is as follows:
利用一内径300mm的试验塔体,按图1所示组合成喷淋旋流一体化装置。试验所用烟气量为1000m3/h,烟气温度为90℃,入口烟气SO2浓度为2600mg/Nm3,烟尘含量1400mg/Nm3。Using a test tower body with an inner diameter of 300 mm, it is combined into a spray and swirl integrated device as shown in Figure 1. The flue gas volume used in the test is 1000m 3 /h, the flue gas temperature is 90°C, the inlet flue gas SO 2 concentration is 2600mg/Nm 3 , and the dust content is 1400mg/Nm 3 .
先将内向板去掉,仅使用一层喷淋层和一层底层旋流板,通过喷淋层向塔内供脱硫液,在液体pH值为9、液气比为2.0L/m3的情况下,测得的脱硫效率约为82%,除尘效率为95%。全塔气流阻力仅在780Pa左右。Remove the inward plate first, use only one spray layer and one bottom swirl plate, and supply desulfurization liquid to the tower through the spray layer, when the pH value of the liquid is 9 and the liquid-gas ratio is 2.0L/ m3 The measured desulfurization efficiency is about 82%, and the dust removal efficiency is 95%. The airflow resistance of the whole tower is only about 780Pa.
同样情况下,若将内向喷射板置入底层旋流板与喷淋层之间,则相近条件下的脱硫效率降低到96%左右,且全塔气流阻力升至900左右Pa。由此可见,将内向喷射板与底层旋流板及喷淋技术结合使用,可显著提高烟气的净化程度.In the same situation, if the inward injection plate is placed between the bottom swirl plate and the spray layer, the desulfurization efficiency under similar conditions will be reduced to about 96%, and the airflow resistance of the whole tower will rise to about 900 Pa. It can be seen that the combination of the inward injection plate and the bottom swirl plate and spraying technology can significantly improve the purification degree of flue gas.
实施例2Example 2
针对1台20t/h蒸发量的燃煤锅炉,设计烟气量为55000m3/h,烟气温度为150℃,入口烟气SO2浓度达2200mg/Nm3,烟尘含量1200mg/Nm3。本发明装置根据实际工况采用了图1所示的装置,塔内径为2200mm。采用钠-钙双碱法烟气脱硫工艺。底层旋流板的叶片仰角为28°,开孔率为32%;内向喷射板的仰角为32°,开孔率为36%。For a coal-fired boiler with an evaporation capacity of 20t/h, the designed flue gas volume is 55000m 3 /h, the flue gas temperature is 150°C, the inlet flue gas SO 2 concentration is 2200mg/Nm 3 , and the smoke dust content is 1200mg/Nm 3 . The device of the present invention adopts the device shown in Fig. 1 according to actual working conditions, and the inner diameter of the tower is 2200mm. Sodium-calcium double-alkali flue gas desulfurization process is adopted. The vane elevation angle of the bottom swirl plate is 28°, and the opening ratio is 32%; the elevation angle of the inward jet plate is 32°, and the opening ratio is 36%.
当锅炉负荷为90%时,在液气比为1.8L/m3的情况下,测得的脱硫效率为96.3%,除尘效率大于97%(出口烟气含尘浓度低于50mg/Nm3)。全塔气流阻力仅在800Pa左右。When the boiler load is 90%, and the liquid-gas ratio is 1.8L/m 3 , the measured desulfurization efficiency is 96.3%, and the dust removal efficiency is greater than 97% (the dust concentration of the outlet flue gas is lower than 50mg/Nm 3 ) . The airflow resistance of the whole tower is only about 800Pa.
实施例3采用与实施例1相同的结构处理40t/h燃煤锅炉的燃煤烟气,烟气先利用多管除尘器进行预除尘,采用氧化镁脱硫工艺进行脱硫及进一步除尘。处理的烟气量为120000m3/h,二氧化硫浓度3500mg/Nm3。吸收塔的直径为3500mm。结果表明,当液气比为2.2L/m3时,脱硫率为97%。设备连续运行6个月中未出现结垢及堵塞现象。Example 3 adopts the same structure as that of Example 1 to treat the coal-fired flue gas of a 40t/h coal-fired boiler. The flue gas is pre-dusted by a multi-tube dust collector, and then desulfurized and further dusted by a magnesium oxide desulfurization process. The flue gas volume to be treated is 120000m 3 /h, and the sulfur dioxide concentration is 3500mg/Nm 3 . The diameter of the absorption tower is 3500mm. The results show that when the liquid-gas ratio is 2.2L/m 3 , the desulfurization rate is 97%. No fouling and clogging occurred during the continuous operation of the equipment for 6 months.
Claims (8)
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| Application Number | Priority Date | Filing Date | Title |
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| CN2009100537400A CN101584957B (en) | 2009-06-25 | 2009-06-25 | Flue gas desulfurization and dust removal integrated coupling device |
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| CN2009100537400A CN101584957B (en) | 2009-06-25 | 2009-06-25 | Flue gas desulfurization and dust removal integrated coupling device |
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| CN101584957A true CN101584957A (en) | 2009-11-25 |
| CN101584957B CN101584957B (en) | 2011-01-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2009100537400A Expired - Fee Related CN101584957B (en) | 2009-06-25 | 2009-06-25 | Flue gas desulfurization and dust removal integrated coupling device |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102941010A (en) * | 2012-11-26 | 2013-02-27 | 广东依科电力技术有限公司 | Swirl board scrubber desulfurization system and working method thereof |
| CN103239982A (en) * | 2013-05-24 | 2013-08-14 | 上海交通大学 | Method for dedusting and desulfurizing catalytic-cracking oil refining regenerated flue gas |
| CN105056679A (en) * | 2015-08-11 | 2015-11-18 | 中国五环工程有限公司 | Method and device for removing PM2.5 (particulate matter) in WFGD (wet flue gas desulfurization) process |
| CN105435610A (en) * | 2015-12-03 | 2016-03-30 | 上海交通大学 | Integrated multiple-effect device meeting requirements for deep desulfurization and denitrification and dust removal of industrial flue gas |
| CN108465324A (en) * | 2018-03-30 | 2018-08-31 | 朱茂祖 | A kind of metallurgical factory's emission-control equipment |
| CN112619377A (en) * | 2020-12-18 | 2021-04-09 | 广东惠智通能源环保发展有限公司 | Exhaust gas purification system |
| CN115873641A (en) * | 2021-09-28 | 2023-03-31 | 中国石油天然气集团有限公司 | A device and method for dedusting and purifying crude gas |
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2009
- 2009-06-25 CN CN2009100537400A patent/CN101584957B/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102941010A (en) * | 2012-11-26 | 2013-02-27 | 广东依科电力技术有限公司 | Swirl board scrubber desulfurization system and working method thereof |
| CN103239982A (en) * | 2013-05-24 | 2013-08-14 | 上海交通大学 | Method for dedusting and desulfurizing catalytic-cracking oil refining regenerated flue gas |
| CN103239982B (en) * | 2013-05-24 | 2015-05-20 | 上海交通大学 | Method for dedusting and desulfurizing catalytic-cracking oil refining regenerated flue gas |
| CN105056679A (en) * | 2015-08-11 | 2015-11-18 | 中国五环工程有限公司 | Method and device for removing PM2.5 (particulate matter) in WFGD (wet flue gas desulfurization) process |
| CN105056679B (en) * | 2015-08-11 | 2017-03-01 | 中国五环工程有限公司 | PM in process of wet desulphurization2.5Removal methods and its device |
| CN105435610A (en) * | 2015-12-03 | 2016-03-30 | 上海交通大学 | Integrated multiple-effect device meeting requirements for deep desulfurization and denitrification and dust removal of industrial flue gas |
| CN108465324A (en) * | 2018-03-30 | 2018-08-31 | 朱茂祖 | A kind of metallurgical factory's emission-control equipment |
| CN112619377A (en) * | 2020-12-18 | 2021-04-09 | 广东惠智通能源环保发展有限公司 | Exhaust gas purification system |
| CN115873641A (en) * | 2021-09-28 | 2023-03-31 | 中国石油天然气集团有限公司 | A device and method for dedusting and purifying crude gas |
| CN115873641B (en) * | 2021-09-28 | 2025-03-07 | 中国石油天然气集团有限公司 | A crude gas dust removal and purification device and method |
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| CN101584957B (en) | 2011-01-26 |
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