CN101559028A - Composition, useful for coloring human keratin fibers, comprises one or more oxidation dyes, ammonia and ammonium chloride - Google Patents

Abstract

The present invention provides a dyeing composition comprising, in a cosmetically acceptable medium, one or more oxidation dyes, aqueous ammonia, ammonium chloride and one or more additives selected from ceramides, silicas, ascorbic acid and/or its salts, fatty acids and/or salts thereof, alkanolamines and/or salts thereof, crosslinked homopolymers of acrylic acid, copolymers of dialkyldiallylammonium chloride and acrylic acid, and particular cationic polymers, or mixtures thereof. It likewise provides a method of colouring human keratin fibres, employing the said composition in the presence of a composition comprising one or more oxidizing agents. The invention further provides a multiple-compartment device appropriate to the implementation of the said method, comprising in a first compartment a dyeing composition according to the invention and in another compartment a composition comprising one or more oxidizing agents.

Description

Contain the colouring compositions of ammonium chloride, the method and apparatus of dyeing keratin fibres

The present invention relates to compositions, it contains one or more oxidation dyes (oxidation dyes), ammonia, ammonium chloride and at least a specific additive in acceptable medium on cosmetics.The invention still further relates to the method for using described compositions dyeing human keratin fiber, and relate to the multicell device that is suitable for implementing described method.

The method of dyeing human keratin fiber such as hair comprises permanent or oxidising dyeing.This staining method more particularly uses one or more oxidation dyes, and more particularly one or more oxidation bases randomly make up with one or more colour couplers (coupler).

Typically, oxidation base is selected from neighbour-or p-phenylenediamine class, adjacent-or right-aminophenols and heterocyclic compound.These oxidation bases are colourless or coloured a little chemical compounds, and it can make up with oxygenated products, can obtain the type to be obtained (species) be colored by the oxidative condensation process.

Utilize tone (shade) that these oxidation bases obtain frequently by they and one or more colour couplers combinations are changed, the latter be colour coupler be selected from especially aromatic-diamidogen ,-amino phenols, between-diphenol and some heterocyclic compound, for example benzazolyl compounds.

The change that is used for the molecule of oxidation base and colour coupler can obtain abundant color (arich palette of colours) to be obtained.

Colouring method is included in one or more oxidation dyes is contacted with oxidant, and described oxidant is hydrogen peroxide preferably.

During the time of application of colouring compositions, exist under the situation of oxidant, two kinds of phenomenons take place.A kind of compound action lightening keratin fiber that relates to by alkaline agent and oxidant in them; Another kind relates to the oxidative dimerization that takes place after dyestuff spreads to fibrous inside, it causes the type that is colored.

Common time of application be about about 30 minutes levels other, although current trends are thought this excessive cycle.

In order to address this problem, only consider that the time of application of minimizing conventional compositions may be quite impossible.In fact, be significantly,, then be difficult to keep the identical effect level of this compositions under the condition in these shortening cycles, be difficult to keep gratifying blast and dye level especially if this compositions is to use.

In addition, can consider by using, for example, the oxidant of persalt type, and/or randomly improve the ability of oxidant and alkaline reagent by the pH that increases the compositions of using.But such selection is not satisfied relatively, because the means that adopted will increase the risk of keratin fiber degraded.

Therefore, what really need is to use oxidation dye to make colouring compositions to use, thereby the degraded of the restriction keratin fiber of handling, and keep simultaneously, perhaps even improve obtainable dyeing and desalination level in the conventional method, wherein, possible service time, advantageously, can be to reach 20 minutes rank at the most, and more particularly about 15 minutes.

The target of these and other, can obtain by the present invention, the invention provides the compositions of the human keratin fiber that is used to dye, it contains in receivable medium on cosmetics, and one or more oxidation dyes, ammonia and ammonium chloride and one or more are selected from following additive:

-the cationic polymer formed by the repetitive of following formula A:

R ' wherein ₁, R ' ₂, R ' ₃And R ' ₄Represent the group of the aliphatic that contains 1-6 carbon atom, alicyclic or aromatic yl aliphat identical or differently, or aliphatic hydroxyl (C ₁-C ₆) alkyl; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄The nitrogen-atoms of can be jointly or connecting with their is respectively formed 5 yuan or 6 yuan of saturated heterocyclics, and it randomly comprises second hetero atom (for example oxygen or sulfur) that is different from nitrogen; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄Representative by nitrile, ester, acyl group, amide or-CO-O-R ' ₅-D or-CO-NH-R ' ₅The straight or branched C that-D group replaces ₁-C ₆Alkyl, wherein R ' ₅Be C ₁-C ₆Alkylidene, and D contains identical or different C ₁-C ₆The quaternary ammonium group of alkyl;

A ₁And B ₁Representative contains the polymethylene (polymethylene) of 2-6 carbon atom, and it can be a straight or branched, saturated or undersaturated, and can contain the C that is connected (replacement) or embeds main chain ₆Aromatic ring or oxygen or sulphur atom, or sulfoxide, sulfone, disulphide, amino, alkyl amino, hydroxyl, quaternary ammonium group, urea groups or ester group, or its combination and

X ^-Representative comes from the anion of organic acid or mineral acid;

A ₁, R ' ₁And R ' ₃Two nitrogen-atoms that can be connected with them form piperazine ring; And the mixture of these additives

-dialkyl diallyl ammonium chloride and acrylic acid copolymer,

-acrylic acid cross-linked homopolymer,

-ceramide,

-silicon dioxide,

-ascorbic acid and/or its salt,

-alkanolamine and/or its salt.

The present invention also provides the method for dyeing human keratin fiber, wherein uses aforesaid colouring compositions under the condition of oxidant existing.

The present invention provides a kind of multicell device at last, and it comprises aforesaid compositions and does not have oxidant in first Room, and the compositions that contains one or more oxidants in another chamber.

In fact be noted, allow in intensity (power), rise (rise) and institute obtains acquisition improvement on the painted uniformity according to compositions according to the present invention, even when reach 20 minutes rank the service time of compositions at the most.

Other characteristics of the present invention and advantage can more clearly manifest by reading description and embodiment.

It should be noted that in following content, under without any opposite situation about describing, the end points of numerical range is included in this scope.

And the human keratin fiber of handling by the inventive method is preferably hair.

As described above, compositions according to the present invention contains ammonium chloride.

Preferably, the content of the ammonium chloride in the compositions is at least 1 weight % with respect to the weight of compositions.

According to another kind of the present invention embodiment more particularly, the content of ammonium chloride is at least 1.5 weight %, preferably at least 3 weight % with respect to the weight of compositions.

Advantageously, the amount of ammonium chloride is 1 weight %-15 weight % with respect to the weight of compositions, more particularly is 1.5 weight %-10 weight % and is preferably 3 weight %-7 weight %.

Further comprise ammonia according to colouring compositions of the present invention.

More particularly, the content of ammonia in the compositions is represented with the form of gaseous ammonia, is at least 0.5 weight % with respect to the weight of compositions.

According to a kind of favourable substitute mode of the present invention, ammonia content is represented with the form of gaseous ammonia, is 0.5 weight %-4 weight % with respect to the weight of compositions, more particularly is 0.7 weight %-2.5 weight % and is preferably 1 weight %-2 weight %.

According to a kind of embodiment preferred of the present invention, the weight ratio that the content separately of ammonium chloride and ammonia reaches ammonium chloride/ammonia (form with gaseous ammonia is represented) in the compositions is at least 2.According to a kind of substitute mode that is more preferably, this weight ratio is between 2 to 10, more preferably between 2.3 to 8, preferably between 2.5 to 5.

Further contain one or more oxidation dyes according to compositions of the present invention.More particularly, described one or more oxidation dyes randomly combine with one or more colour couplers corresponding to one or more oxidation bases.

As the example of oxidation base, the latter is selected from p-phenylenediamine class, hexichol Alkylenediamine class, para-aminophenol class (para-aminophenols), O-aminophenol class (ortho-aminophenols), heterocyclic bases and their addition salts.

The p-phenylenediamine class comprises for example p-phenylenediamine, right-toluenediamine, 2-chloro-p-phenylenediamine, 2,3-dimethyl-p-phenylenediamine, 2,6-dimethyl-p-phenylenediamine, 2,6-diethyl-p-phenylenediamine, 2,5-dimethyl-p-phenylenediamine, N, N-dimethyl-p-phenylenediamine, N, N-diethyl-p-phenylenediamine, N, N-dipropyl-p-phenylenediamine, 4-amino-N, N-diethyl-3-monomethylaniline., N, two (the beta-hydroxyethyl)-p-phenylenediamines of N-, 4-N, two (beta-hydroxyethyl) amino-2-methyl aniline of N-, 4-N, two (beta-hydroxyethyl) amino of N--2-chloroaniline, 2-beta-hydroxyethyl-p-phenylenediamine, 2-fluoro-p-phenylenediamine, 2-isopropyl-p-phenylenediamine, N-(β-hydroxypropyl)-p-phenylenediamine, 2-methylol-p-phenylenediamine, N, N-dimethyl-3-methyl-p-phenylenediamine, N, N-(ethyl-beta-hydroxyethyl)-p-phenylenediamine, N-(β, γ-dihydroxypropyl)-p-phenylenediamine, N-(4 '-aminophenyl)-p-phenylenediamine, N-phenyl-p-phenylenediamine, 2-beta-hydroxy ethyoxyl-p-phenylenediamine, 2-β-acetylamino ethyoxyl-p-phenylenediamine, N-('beta '-methoxy ethyl)-p-phenylenediamine, 4-aminophenyl pyrrolidine, 2-thienyl-p-phenylenediamine, 2-beta-hydroxyethyl amino-5-amino toluene, the addition salts of 3-hydroxyl-1-(4 '-aminophenyl) pyrrolidine and they and acid.

At above-mentioned p-phenylenediamine apoplexy due to endogenous wind, particularly preferably be p-phenylenediamine (PPD), right-toluenediamine, 2-isopropyl-p-phenylenediamine, 2-beta-hydroxyethyl-p-phenylenediamine, 2-beta-hydroxy ethyoxyl-p-phenylenediamine, 2,6-dimethyl-p-phenylenediamine, 2,6-diethyl-p-phenylenediamine, 2,3-dimethyl-p-phenylenediamine, N, two (the beta-hydroxyethyl)-p-phenylenediamines of N-, 2-chloro-p-phenylenediamine, 2-β-acetylamino ethyoxyl-p-phenylenediamine and they and sour addition salts.

Hexichol Alkylenediamine class, comprise for example N, N '-two (beta-hydroxyethyl)-N, N '-two (4 '-aminophenyl)-1, the 3-diamino-propanol, N, N '-two (beta-hydroxyethyl)-N, N '-two (4 '-aminophenyl) ethylenediamine, N, N '-two (4-aminophenyl)-tetra-methylenedimine, N, N '-two (beta-hydroxyethyl)-N, N '-two (4-aminophenyl) tetra-methylenedimine, N, N '-two (4-methylamino phenyl) tetra-methylenedimine, N, N '-two (ethyl)-N, N '-two (4 '-amino-3 '-aminomethyl phenyl) ethylenediamine, 1, two (2, the 5-diamino phenoxy)-3 of 8-, 6-two oxa-octane (dioxaoctane) and their addition salts.

The para-aminophenol class comprises for example para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, the addition salts of 4-amino-3-hydroxymethylphenol, 4-amino-2-methyl phenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxy phenol, 4-amino-2-amino methyl phenol, 4-amino-2-(beta-hydroxyethyl amino methyl) phenol, 4-amino-2-fluorophenol and they and acid.

The O-aminophenol class comprises for example 2-amino-phenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 5-acetylaminohydroxyphenylarsonic acid 2-amino-phenol and their addition salts.

Heterocyclic bases (bases) comprises for example pyridine derivate, pyrimidine derivatives and pyrazole derivatives.

Pyridine derivate for example comprises the chemical compound of describing in patent GB1 026 978 and GB1 153 196, for example 2, and 5-diamino-pyridine, 2-(4-methoxyphenyl) amino-3-aminopyridine and 3,4-diamino-pyridine and their addition salts.

Other the pyridine oxidation base of the present invention that can be used for is also [1,5-a] pyridine oxidation base or their addition salts of the 3-amino-pyrazol for example described in patent FR2801308.Example comprises: pyrazolo [1,5-a] pyridin-3-yl amine; 2-acetylamino pyrazolo [1,5-a]-pyridin-3-yl amine; 2-beautiful jade-4-base pyrazolo [1,5-a]-pyridin-3-yl amine; The 3-amino-pyrazol is [1,5-a]-pyridine-2-formic acid also; 2-methoxyl group pyrazolo [1,5-a]-pyridin-3-yl amine; (the 3-amino-pyrazol is [1,5-a]-pyridine-7-yl also) methanol; 2-(the 3-amino-pyrazol is [1,5-a]-pyridine-5-yl also)-ethanol; 2-(the 3-amino-pyrazol is [1,5-a]-pyridine-7-yl also) ethanol; (the 3-amino-pyrazol is [1,5-a]-pyridine-2-yl also) methanol; 3, the 6-diamino-pyrazole is [1,5-a]-pyridine also; 3, the 4-diamino-pyrazole is [1,5-a]-pyridine also; Pyrazolo [1,5-a]-pyridine-3, the 7-diamidogen; 7-beautiful jade-4-base pyrazolo [1,5-a] pyridin-3-yl amine; Pyrazolo [1,5-a]-pyridine-3, the 5-diamidogen; 5-beautiful jade-4-base pyrazolo [1,5-a] pyridin-3-yl amine; The 2-[(3-amino-pyrazol is [1,5-a]-pyridine-5-yl also)-(2-ethoxy) amino] ethanol; The 2-[(3-amino-pyrazol is [1,5-a]-pyridine-7-yl also)-(2-ethoxy) amino] ethanol; The 3-amino-pyrazol is [1,5-a] pyridine-5-alcohol also; The 3-amino-pyrazol is [1,5-a]-pyridine-4-alcohol also; The 3-amino-pyrazol is [1,5-a]-pyridine-6-alcohol also; The 3-amino-pyrazol is [1,5-a]-pyridine-7-alcohol also, and their addition salts.

Pyrimidine derivatives comprises the chemical compound of describing as in patent DE2359399, JP88-169571, JP05-63124 and EP0770375 or patent application WO96/15765, for example, and 2,4,5,6-tetraminopyrimidine, 4-hydroxyl-2,5,6-three aminomethyl pyrimidines, 2-hydroxyl-4,5,6-Triaminopyrimidine, 2,4-dihydroxy-5,6-di-amino-pyrimidine, 2,5, the addition salts of 6-Triaminopyrimidine and they and the tautomer when having tautomeric equilibrium.

Pyrazole compound is included in patent DE3843892 and DE4133957 and patent application WO94/08969, WO94/08970, the chemical compound of describing among FR-A-2 733 749 and the DE195 43 988, for example 4,5-diaminostilbene-methyl-pyrazoles, 4,5-diaminostilbene-(beta-hydroxyethyl) pyrazoles, 3, the 4-diamino-pyrazole, 4,5-diaminostilbene-(4 '-benzyl chloride base) pyrazoles, 4, the 5-diaminostilbene, the 3-dimethyl pyrazole, 4,5-diaminourea-3-methyl 1-Phenylpyrazole, 4,5-diaminostilbene-methyl-3-Phenylpyrazole, 4-amino-1,3 dimethyl-5-diazanyl pyrazoles, 1-benzyl-4,5-diaminourea-3-methylpyrazole, 4,5-diaminourea-3-tert-butyl-1-methylpyrazole, 4,5-diaminostilbene-tert-butyl-3-methylpyrazole, 4,5-diaminostilbene-(beta-hydroxyethyl)-3-methylpyrazole, 4,5-diaminostilbene-ethyl-3-methylpyrazole, 4,5-diaminostilbene-ethyl-3-(4 '-methoxyphenyl) pyrazoles, 4,5-diaminostilbene-ethyl-3-methylol pyrazoles, 4,5-diaminourea-3-methylol-1-methylpyrazole, 4,5-diaminourea-3-methylol-1-isopropyl pyrazoles, 4,5-diaminourea-3-methyl isophthalic acid-isopropyl pyrazoles, 4-amino-5-(2 '-amino-ethyl) amino-1, the 3-dimethyl pyrazole, 3,4,5-triamido pyrazoles, 1-methyl-3,4,5-triamido pyrazoles, 3,5-diaminostilbene-methyl 4-methylamino pyrazoles, 3,5-diaminourea-4-(beta-hydroxyethyl) amino-1-methylpyrazole, and their addition salts.Equally also may use 4,5-diaminostilbene-('beta '-methoxy ethyl) pyrazoles.

Other pyrazole derivatives comprise diamino-N, N-dihydro-pyrazolo pyrazolone and following those chemical compounds in application FR2886136, described especially and their addition salts: 2,3-diaminourea-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone, 2-amino-3-ethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone, 2-amino-3-isopropyl amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone, 2-amino-3-(pyrrolidine-1-yl)-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone, 4, the 5-diaminostilbene, 2-dimethyl-1,2-pyrazoline-3-ketone, 4,5-diaminostilbene, 2-diethyl-1,2-pyrazoline-3-ketone, 4, the 5-diaminostilbene, 2-two (2-ethoxy)-1,2-pyrazoline-3-ketone, 2-amino-3-(2-ethoxy) amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone, 2-amino-3-dimethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone, 2,3-diaminourea-5,6,7,8-tetrahydrochysene-1H, 6H-pyridazine be [1,2-a] pyrazoles-1-ketone also, 4-amino-1,2-diethyl-5-(pyrrolidine-1-yl)-1,2-pyrazoline-3-ketone, 4-amino-5-(3-dimethylamino pyrrolidine-1-yl)-1,2-diethyl-1,2-pyrazoline-3-ketone, 2,3-diaminourea-6-hydroxyl-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone.

Preferably use 4 as heterocyclic bases, 5-diaminostilbene-(beta-hydroxyethyl) pyrazoles and/or 2,3-diaminourea-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazoles-1-ketone and their addition salts.

About colour coupler, between should be mentioned that especially-phenylenediamine ,-amino phenols ,-hexichol phenols, by the deutero-colour coupler of naphthalene, heterocyclic coupler agent and their addition salts.

Example comprises 1, the 3-dihydroxy benzenes, 1,3-dihydroxy 2-methylbenzene, 4-chloro-1, the 3-dihydroxy benzenes, 2,4-diaminostilbene-(beta-hydroxy ethyoxyl) benzene, 2-amino-4-(beta-hydroxy ethylamino)-1-methoxybenzene, 1, the 3-diaminobenzene, 1,3-two (2, the 4-diamino phenoxy) propane, 3-urea groups aniline, 3-urea groups-1-dimethylamino benzene, sesamol, 1-beta-hydroxyethyl amino-3,4-methylenedioxybenzenes (methy lenedioxy benzene), alpha-Naphthol, 2-methyl isophthalic acid-naphthols, the 6-oxyindole, the 4-oxyindole, 4-hydroxy-n-methylindole, 2-amino-3-pyridone, 6-hydroxy benzo morpholine, 3,5-diaminourea-2, the 6-dimethoxy-pyridine, 1-N-(beta-hydroxyethyl) amino-3, the 4-methylenedioxybenzenes, 2,6-two (beta-hydroxy-ethylamino) toluene, 6-hydroxyl indoline, 2,6-dihydroxy-4-picoline, 1H-3-methylpyrazole-5-ketone, 1-phenyl-3-methylpyrazole-5-ketone, 2,6-dimethyl pyrazole [1,5-b]-1,2, the 4-triazole, 2,6-dimethyl [3,2-c]-1,2,4-triazole, 6-methyl-pyrazolo [1,5-a] benzimidazole, they and the addition salts and composition thereof of acid.

Usually, the oxidation base that can use in the present invention and the addition salts of colour coupler are selected from and sour addition salts, for example hydrochlorate, hydrobromate, sulfate, citrate, succinate, tartrate, lactate, toluene fulfonate, benzene sulfonate, phosphate and acetate especially.

The content that exists of one or more oxidation bases advantageously is 0.0001 weight %-10 weight % with respect to the weight of compositions, and more preferably the weight with respect to compositions is 0.005 weight %-5 weight %.

When one or more colour couplers existed, there is content in it advantageously was 0.0001 weight %-10 weight % with respect to the weight of compositions, and preferably the weight with respect to compositions is 0.005 weight %-5 weight %.

As mentioned above, compositions according to the present invention contains one or more additives, and it is selected from: ceramide, silicon dioxide, ascorbic acid and/or its salt, alkanolamine and/or its salt, acrylic acid cross-linked homopolymer, dialkyl diallyl ammonium chloride and acrylic acid copolymer, the cationic polymer of being made up of the repetitive of following formula A:

R ' wherein ₁, R ' ₂, R ' ₃And R ' ₄Represent the group of the aliphatic that contains 1-6 carbon atom, alicyclic or aromatic yl aliphat identical or differently, or aliphatic hydroxyl (C ₁-C ₆) alkyl; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄Can be jointly or the nitrogen-atoms that is connected with them respectively, form 5 yuan or 6 yuan of saturated heterocyclics, it randomly comprises second hetero atom (for example oxygen or sulfur) that is different from nitrogen; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄Representative by nitrile, ester, acyl group, amide or-CO-O-R ' ₅-D or-CO-NH-R ' ₅The straight or branched C that-D group replaces ₁-C ₆Alkyl, wherein R ' ₅Be C ₁-C ₆Alkylidene, and D contains identical or different C ₁-C ₆The quaternary ammonium group of alkyl;

A ₁And B ₁Representative contains the polymethylene of 2-6 carbon atom, and it can be a straight or branched, saturated or undersaturated, and can contain the C that is connected (replacement) or embeds main chain ₆Aromatic ring or oxygen or sulphur atom, or sulfoxide, sulfone, disulphide, amino, alkyl amino, hydroxyl, quaternary ammonium group, urea groups or ester group, or its combination and

X ^-Representative comes from the anion of organic acid or mineral acid;

A ₁, R ' ₁And R ' ₃Can form piperazine ring with two nitrogen-atoms that are connected with them; And the mixture of these additives.

The amount of aforesaid each additive more particularly is 0.001 weight %-10 weight % with respect to the weight of compositions, is preferably 0.005 weight %-5 weight %.

The chemical compound corresponding to following formula (B) represented especially in term " ceramide ":

Wherein:

R ₁Expression:

-selectively, saturated or undersaturated, straight or branched C ₁-C ₅₀, preferred C ₅-C ₅₀Hydrocarbyl group, described hydrocarbyl group can be by one or more, and preferred 1 to 6 hydroxyl replaces, and described hydroxyl can be randomly and sour R ₇COOH esterification, wherein R ₇Be selected from straight or branched, saturated or undersaturated, the C of monohydroxylated or polyhydroxylated (preferred 1-6 hydroxyl) randomly ₁-C ₃₅Hydrocarbyl group, and R ₇Alkyl can with saturated or unsaturated, straight or branched, the C of monohydroxylated or polyhydroxylated (preferred 1-6 hydroxyl) alternatively ₁-C ₃₅Fatty acid esterification,

-or R " (NR-CO)-R ' group, wherein R represent that hydrogen atom is saturated or undersaturated, straight or branched, by the C of preferred 1-6 hydroxyl monohydroxylated or polyhydroxylated (preferably monohydroxylated) ₁-C ₂₀Alkyl, R ' and R " be saturated or undersaturated, straight or branched, the hydrocarbyl group of the total number of carbon atoms in the 9-30 scope, and R ' is divalent group,

-or R ₈-O-CO-(CH ₂) _pGroup, wherein R ₈Represent saturated or undersaturated, straight or branched C ₁-C ₂₀Hydrocarbyl group, and p is the integer in the 1-12 scope;

R ₂Be selected from hydrogen atom, carbohydrate group, particularly (glycosyl) _n, (galactosyl) _mOr sulfo group galactosyl, sulfate or phosphate residue, phosphoryl ethylamine or phosphoryl ethyl ammonium group, wherein n is the integer in the 1-4 scope, and m is the integer in the 1-8 scope;

R ₃Saturated or undersaturated, the straight or branched C of expression hydrogen atom ₁-C ₃₃Hydrocarbyl group, preferably by 1 to 6 hydroxyl hydroxylating or non-hydroxylated, described one or more hydroxyls can be selected from mineral acid or formula R for it ₇The acid estersization of COOH, R ₇Have definition same as described above, described one or more hydroxyls can be by (glycosyl) _n, (galactosyl) _m, sulfo group galactosyl, phosphoryl ethylamine or phosphoryl ethyl ammonium group etherificate, n is the integer in the 1-4 scope, and m is the integer in the 1-8 scope, R ₃Also can be by one or more C ₁-C ₁₄Alkyl replaces;

R ₄Expression hydrogen atom, methyl or ethyl, straight or branched, saturated or undersaturated, optional hydroxylated C ₃-C ₅₀Hydrocarbyl group, or-CH ₂-CHOH-CH ₂-O-R ₆Group, wherein R ₆Represent saturated or undersaturated, straight or branched C ₁₀-C ₂₆Hydrocarbyl group or R ₈-O-CO-(CH ₂) _pGroup, R ₈Represent saturated or undersaturated, straight or branched C ₁-C ₂₀Hydrocarbyl group, and p is the integer in the 1-12 scope,

R ₅Saturated or undersaturated, the straight or branched of expression hydrogen atom, randomly by the C of monohydroxylated and polyhydroxylated (preferred 1-6 hydroxyl) ₁-C ₃₀Hydrocarbyl group, wherein hydroxyl can be by (glycosyl) _n, (galactosyl) _mThe group etherificate, wherein n is the integer in the 1-4 scope, and m is the integer in the 1-8 scope, perhaps by sulfo group galactosyl, phosphoryl ethylamine or phosphoryl ethyl ammonium group etherificate,

Prerequisite is to work as R ₃And R ₅The expression hydrogen atom, or work as R ₃Be hydrogen atom and R ₅When being methyl, R ₄Do not represent hydrogen atom or methyl or ethyl.

In the chemical compound of above-mentioned formula (B), comprise Dowing very especially at Journal ofLipid Research, 35 volumes, the 2060th page, 1994, or those ceramides and/or the glucose ceramide chemical compound described among the french patent application FR-2 673 179.

Preferred ceramide comprises those of formula (A), R ₁Expression is by hydroxylated C randomly ₁₄-C ₂₂The alkyl or alkenyl of fatty acid derived; R ₂Represent hydrogen atom; And R ₃Represent randomly hydroxylated C ₁₁-C ₁₇Saturated straight chain base, and C preferably ₁₃-C ₁₅Group.

This compounds is selected from following compounds singlely or as mixture for instance:

The inferior oleoyl dihydrosphingosine (1inoleoyldihydrosphingosine) of-N-,

-N-oleoyl dihydrosphingosine or 2-oleoyl amido-1, the 3-octacosanol,

-N-palmityl dihydrosphingosine,

-N-stearoyl dihydrosphingosine,

-N-Shan Yu acyl dihydrosphingosine,

-N-2-hydroxyl palmityl dihydrosphingosine,

-N-stearyl phytosphingosine (stearoylphytosphingosine),

-N-palmityl amido hexadecane glycol.

Also can use particular mixtures, for example according to the ceramide 2 of Downing classification and the mixture of ceramide 5.

Also can use the chemical compound of formula (B), wherein R ₁Expression is derived from C ₁₄-C ₂₂The alkyl or alkenyl of fatty acid; R ₂Expression galactosyl or sulfo group galactosyl; And R ₃Represent saturated or undersaturated C ₁₂-C ₂₂Alkyl, and preferred-CH=CH-(CH ₂) ₁₂-CH ₃Group.

The ceramide chemical compound for example is described among patent application DE4424530, DE4424533, DE4402929, DE4420736, WO95/23807, WO94/07844, EP646572, WO95/16665, FR2673179, EP227994 and WO94/07844, WO94/24097 and the WO94/10131, uses for referencial use herein.

Example comprises by Waitaki International Biosciences with trade name Glycocer

The mixture of the glucose ceramide of selling is formed.

Also can use disclosed chemical compound in patent application EP227994, EP647617, EP736522 and WO94/07844.

For example, these chemical compounds are the Questamide H that sold by Quest

, be also referred to as two (N-ethoxy-N-cetyl) Malondiamides and palmitic acid N-(2-ethoxy)-N-(3-hexadecane oxygen base-2-hydroxypropyl) amide.

Also can use N-docosane acyl group-N-methyl D-glycosamine of describing in the International Patent Application WO 94/24097.

Preferably, if compositions contains one or more ceramides, their content is between the 0.001 weight %-1 weight % with respect to the weight of compositions, is preferably 0.005 weight %-0.1 weight %.

According to a kind of particularly advantageous substitute mode of the present invention, and when compositions contained one or more ceramides, the weight ratio of ceramide (class)/ammonium chloride was preferably between 0.001 to 0.05.

Possible additive comprises silicon dioxide.Therefore compositions can contain one or more hydrophilic or hydrophobic silica or its mixture more especially.

Hydrophilic silicon dioxide on meaning of the present invention, not only refers to pure hydrophilic silicon dioxide, also refers to wrap up wholly or in part the granule of hydrophilic silicon dioxide.

The hydrophilic silicon dioxide that can use in the present invention is preferably unbodied.

Usually, they are Powdered.

They can be pyrolytic or the precipitation source equally.

Typically by Silicon chloride. (SiCl ₄) 1000 ℃ temperature, there are continuous calcining pyrolysis acquisition steam (pyrolysis) deposition of silica down in hydrogen and oxygen.

More particularly obtain sedimentary silicon dioxide by preferred sodium silicate of the solution of alkali silicate and acid reaction.

According to the preferred embodiments of the invention, it is 30-500m that hydrophilic silicon dioxide is selected from specific surface area ²/ g and number average bead diameter are the silicon dioxide of 3-50nm.

More specifically there is the hydrophilic silicon dioxide of describing in following table (1) and the table (2), and composition thereof.

Table (1)

Trade name	AEROSIL 90 (Degussa-Hüls)	AEROSIL 130 (Degussa-Hüls)	AEROSIL 150 (Degussa-Hüls)	AEROSIL200 (Degussa-Hüls)
					Preparation method	Pyrolysis	Pyrolysis	Pyrolysis	Pyrolysis
BET specific surface area (m 2/g)	90±15	130±25	150±15	200±15
					Mean diameter (nm)	20	16	14	12
Remarks				The size of aggregation: 10-30 μ m and 200 μ m

Table (2)

Trade name	AEROSIL 300 (Degussa-Hüls)	AEROSIL 380 (Degussa-Hüls)	AEROSIL OX 50 (Degussa-Hüls)	SILICAFK 320DS (Degussa-Hüls)
					Preparation method	Pyrolysis	Pyrolysis	Pyrolysis	Pyrolysis
BET specific surface area (m 2/g)	300±30	380±30	50±25	170±25
					Mean diameter (nm)	7	7	40	18

NB:+/-excursion of BET specific surface area provided.

The hydrophilic silicon dioxide that in the present composition, uses also can by by silicon dioxide wholly or in part coated pellet form inorganic particle particularly.

Can should be mentioned that especially, by Toray with title Torayceram S-IT

The silica beads that contains titanium oxide of selling; By Zeelan with title Z-LIGHT-SPHERE W 1012 The silica-alumina microsphere that the contains titanium oxide (size: 150 μ m) of selling; By Crosfield with title Neosil PC20S

Synthetic silica/titan oxide particles (size: 106-500 μ m) of the amorphous as deposited of selling; By Wackherr with title Fiberlon Y2

Nylon 6/ silicon dioxide/titanium dioxide fiber of selling (long 2mm, and thickness is 2 dawn (denier)); By SACI-CFPA with title ACS-0050510 Silicon dioxide (the 85/5/10) (size: 0.6 μ m) that scribbles titanium dioxide and coat of selling with porous silica; By Rhodia Chimie with title Mirasun TIW 60

The anatase type titanium oxide nano material with aluminium oxide and silica-treated of selling, content is 40% in the water, (size: 60nm, the single dispersion); By the MirasunTIW 160 of Rhodia Chimie with the title sale

, it is 32% aqueous dispersion with the anatase type titanium oxide nano material (60nm) of 15/5/3 silica/alumina/caesium IV coating; By the Tioveil AQ-N of Uniqema with the title sale

, it is 40% aqueous dispersion with the anatase type titanium oxide nano material (34/4.3/1.7) of aluminium oxide and silica-treated; By Nichimen Europe PLC with title Maxlight TS-04

Titanium dioxide nano material (66/33) (particle diameter of titanium dioxide: 30nm, the thickness of silicon dioxide: 4nm) of the usefulness silica-coating of selling; And by Nichimen Europe PLC with title Maxlight TS-042

Titanium dioxide nano material (80/20) (particle diameter of titanium dioxide: 30nm, the thickness of silicon dioxide: 2nm) of the usefulness silica-coating of selling.

As hydrophilic silicon dioxide, the advantageous applications pyrolytic silicon dioxide, and particularly with title Aerosil (the INCI name: silicon dioxide) those of Chu Shouing and more particularly by Degussa-H ü ls with title Aerosil200

Those that sell.

Significant in the present invention hydrophobic silica is not only pure silicon dioxide, also refers to coated by hydrophobic silica granules wholly or in part.

The hydrophobic silica that can use in the present composition is preferably from amorphous and pyrolysis source.

Its institute is powder type preferably.

The amorphous hydrophobic silica in pyrolysis source is more particularly obtained by hydrophilic silicon dioxide.The latter is when hydrogen and oxygen exist, at 1000 ℃ of continuous flame pyrolysis Silicon chloride. (SiCl ₄) obtain.Subsequently it is handled and hydrophobic property with halogenated silane, alkoxy silane or silazane.On quality, the difference of hydrophobic silica and the initial silicon dioxide of hydrophilic comprises that the absorption lower and water vapour of the density of silanol is littler.

According to a preferred embodiment of the invention, to be selected from specific surface area be 50-500m to hydrophobic silica ²/ g and number average bead diameter are the silicon dioxide of 3-50nm.

More in particular, as those hydrophobic silicas of following table (3) description, and composition thereof:

Table (3):

Trade name	AEROSIL R202 (Degussa-Hüls)	AEROSIL R805 (Degussa-Hüls)	AEROSILR812 (Degussa-Hüls)	AEROSIL R972 (Degussa-Hüls)	AEROSIL R974 (Degussa-Hüls)
						BET specific surface area (m 2/g)	90±20	150±25	260±30	110±20	170±20
Mean diameter (nm)	14	12	7	16	12

Employed hydrophobic silica can also contain (consist of) granule, particularly inorganic particle in compositions of the present invention, for example pigment and metal-oxide, and it is completely or partially coated by hydrophobic silica.

These granules also have optical effect in product, for example on hair; For example, their effects of having dimness or slightly brightening.

Preferably carried out the surface-treated hydrophobic fumed silica with dimethyl siloxane as hydrophobic silica, for example Degussa-H ü ls is with title Aerosil R972 (INCI name: those of the Chu Shouing silicon dioxide of dimethylsilylization).

The preferred hydrophobic silica of the applied silicon dioxide of the present invention.

Preferably, if compositions contains silicon dioxide, its content is 0.1 weight %-10 weight % with respect to the weight of compositions, more particularly is 0.5 weight %-5 weight %, and is more preferably 1 weight %-3 weight %.

According to a kind of particularly advantageous modification of the present invention, and when compositions contains silicon dioxide, the weight ratio of silicon dioxide/ammonium chloride is preferably between 0.01 to 2, advantageously between 0.1 to 1 and be more preferably between 0.2 to 0.8.

These can be comprised ascorbic acid and salt thereof by the additive of mature deliberation, and for example, alkali-metal salt is sodium and potassium salt for example, the salt of alkaline-earth metal for example calcium salt, ammonium salt, contain 1-3 the identical or different optional C that carries hydroxyl ₁-C ₄The primary amine of alkyl, secondary amine or tertiary ammonium salt.

Preferably, if compositions contains the ascorbic acid that exists with acid and/or salt form, its content is represented with sour form, weight with respect to compositions is 0.01 weight %-10 weight %, is 0.05 weight %-5 weight % more especially and is preferably 0.1 weight %-1 weight %.

According to a kind of particularly advantageous substitute mode of the present invention, and when compositions contains the ascorbic acid that exists with acid and/or salt form, ascorbic acid (representing with sour the form)/weight ratio of ammonium chloride and is more preferably between 0.2 to 0.01 preferably between 0.5 to 0.005.

Compositions of the present invention contains one or more alkanolamines alternatively as additive.

Alkanolamine on meaning of the present invention is the chemical compound that contains the hydrocarbon chain of a straight or branched, and described hydrocarbon chain carries one or more hydroxyls and one or more amino, and the latter may randomly be replaced.

The alkanolamine of preferred structure (C)

R wherein _aAnd R _bRepresent mutual hydrogen atom, straight or branched C respectively ₁-C ₁₀And preferred C ₁-C ₄Alkyl or straight or branched C ₁-C ₁₀And preferred C ₁-C ₄List or multi-hydroxy alkyl;

A represents straight or branched C ₁-C ₁₀, preferred C ₁-C ₄, the thiazolinyl that it is randomly replaced by one or more hydroxyls.

Alkanolamine comprises monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, two isopropanolamine, triisopropanolamine, N, N-dimethylethanolamine, N, N-diethyl ethylene diamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, ammediol and 2-amino-2-methylol-1, ammediol.

Preferred alkanolamine is a monoethanolamine.

It should be noted that alkanolamine can be free form or with the form of the salt of acid compound, for example, aforesaid ascorbic acid and fatty acid, with cross linked polyacrylate described in detail below, and also have hydrochloric acid, hydrobromic acid, sulphuric acid, phosphoric acid, acetic acid, citric acid, succinic acid, tartaric acid, lactic acid, toluenesulfonic acid and benzenesulfonic acid.

Especially, if compositions contains one or more alkanolamines, their total amount is in free form, weight with respect to compositions is 0.1 weight %-15 weight %, is 0.5 weight %-12 weight % more especially and is preferably 1 weight %-10 weight %.

According to a kind of preferred substitute mode of the present invention, when compositions contained one or more alkanolamines, the content of ammonium chloride was 2 weight %-5 weight % with respect to the weight of compositions.

In addition, according to this substitute mode, the content of ammonia in the content of gaseous ammonia, is 0.5 weight %-2 weight % with respect to the weight of compositions.

According to a kind of particularly advantageous substitute mode of the present invention, and when compositions contains one or more alkanolamines, the weight ratio of alkanolamine (representing with salt-independent shape)/ammonium chloride is preferably between 0.01 to 5, more especially between 0.05 to 1 and be more preferably between 0.1 to 0.5.

Can contain according to compositions of the present invention, one or more acrylic acid cross-linked homopolymer as additive, with free form or with the salt form, for example, alkali-metal salt is sodium and potassium salt for example, the salt of alkaline-earth metal is calcium salt, ammonium salt for example, contains 1-3 identical or different, the optional C that carries hydroxyl ₁-C ₄The primary amine of alkyl, secondary amine or tertiary ammonium salt, preferred monoethanolamine salt.

For example can be crosslinked wholly or in part with allyl ether.

For example can be a kind of acrylate homopolymer and pentaerythrite allyl ether, with cane sugar allyl ether or crosslinked with the propylidene allyl ether.This base polymer is at the CTFA dictionary, the 9th edition, in 2002 especially with the Carbomer classification of running after fame.They are sold with following title, comprise the Carbopol of Noveon and the Synthalen of 3V Inc.

The molecular weight of the described acrylate homopolymer of the context of the invention is more particularly more than or equal to 100000g/mol.Be preferably greater than or equal 500000g/mol and, more advantageously, more than or equal to 1000000g/mol.Very in particular between 1000000g/mol and 10000000g/mol.

Advantageously, if compositions contains one or more acrylate homopolymers, their content is in polyacrylic acid, weight with respect to compositions is 0.05 weight %-5 weight %, more advantageously is 0.1 weight %-3 weight % and is preferably 0.2 weight %-1 weight %.

According to a kind of particularly advantageous substitute mode of the present invention, and when compositions contains one or more acrylate homopolymers, the weight ratio of acrylate homopolymer (in polyacrylic acid)/ammonium chloride is preferably between 0.01 to 1, more especially between 0.05 to 0.75 and more preferably between 0.1 to 0.5.

Compositions also can contain one or more dialkyl diallyl ammonium chloride and acrylic acid copolymer.

Especially, described polymer contains at least one unit of following formula

Wherein k and t are 0 or 1, k+t's and be 1;

R ₉And R ₁₀Represent C identical or differently ₁-C ₂₆Alkyl, hydroxyalkyl (C ₁-C ₅) group, alkyl (C ₁-C ₂) aminoalkyl (C ₁-C ₄) group, perhaps R ₉And R ₁₀Represent piperidyl or morpholinyl jointly with the nitrogen-atoms that is being connected with them;

R ₁₁Expression hydrogen atom or methyl free radicals; And

X ^-It is anion.

Preferably, R ₉And R ₁₀The expression methyl.

These polymer can randomly comprise the unit that obtains from other monomer, for example acrylamide on its structure.

This base polymer is at the CTFA dictionary, the 9th edition, in 2002 especially with Polyquaternium-22 and the Polyquaternium-39 classification of running after fame.

They are, for example Polyquaternium-22 that is sold with title Merquat 295 and Merquat 280 by Onder Nalco and the Polyquaternium-39 that sells with Merquat Plus 3330 and Merquat Plus3331.

Advantageously, if compositions contains one or more this analog copolymers, their total amount is 0.1 weight %-10 weight % with respect to the weight of compositions, is 0.2 weight %-5 weight % more especially and is preferably 0.5 weight %-2 weight %.

According to a kind of particularly advantageous substitute mode of the present invention, when compositions contains one or more dialkyl diallyl ammonium chloride and acrylic acid copolymer, the weight ratio of described copolymer/ammonium chloride is preferably between 0.05 to 1, more especially between 0.1 to 0.8 and be more preferably between 0.2 to 0.5.

Also can contain the cationic polymer that one or more are made of the repetitive of following formula (A) according to compositions of the present invention.

R ' wherein ₁, R ' ₂, R ' ₃And R ' ₄Represent the group of the aliphatic that contains 1-6 carbon atom, alicyclic or aromatic yl aliphat identical or differently, or aliphatic hydroxyl (C ₁-C ₆) alkyl; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄Can be jointly or the nitrogen-atoms that is connected with them respectively form 5 yuan or 6 yuan of saturated heterocyclics, it comprises second hetero atom (for example oxygen or sulfur) that is different from nitrogen alternatively; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄Representative by nitrile, ester, acyl group, amide or-CO-O-R ' ₅-D or-CO-NH-R ' ₅The C of the straight or branched that-D group replaces ₁-C ₆Alkyl, wherein R ' ₅Be C ₁-C ₆Alkylidene, and D contains identical or different C ₁-C ₆The quaternary ammonium group of alkyl;

A ₁And B ₁Representative contains the polymethylene of 2-6 carbon atom, and it can be a straight or branched, saturated or undersaturated, and can contain the C that is connected (replacement) or embeds main chain ₆Aromatic ring or oxygen or sulphur atom, or sulfoxide, sulfone, disulphide, amino, alkyl amino, hydroxyl, quaternary ammonium group, urea groups or ester group, or its combination and

X ^-Representative comes from the anion of organic acid or mineral acid;

A ₁, R ' ₁And R ' ₃Can form piperazine ring with two nitrogen-atoms that are connected with them.

In following formula, preferably, X ^-Be the anion that is selected from bromide ion, chloride ion, acetate, borate, citrate, tartrate anion, bisulfate ion (bisulphate), bisulfite (bisulphite), sulfate radical and phosphate anion, and preferably chlorine and bromide ion.

French Patent (FRP) 2 320 330,2 270 846,2 316 271,2 336 434 and 2 413 907 and United States Patent (USP) 2 273 780,2 375 853,2 388 614,2 454 547,3 206 462,2 261 002,2,271 378,3 874 870,4 001 432,3 929 990,3 966 904,4 005 193,4 025 617,4,025 627,4 025 653,4 026 945 and 4 027 020 this base polymer has been described especially.

Can also more particularly use the polymer of forming by the following formula repetitive:

R wherein ₁, R ₂, R ₃And R ₄Represent the alkyl or the hydroxyalkyl of 1-4 the carbon atom of having an appointment, n and p are the integers between about 2-6, and X identical or differently ^-Be to come from as above the anion of described organic acid or mineral acid before.

Particularly preferred chemical compound of formula (a) is R ₁, R ₂, R ₃And R ₄Represent methylidene and n=3, p=6 and X=Cl say that in another way this chemical compound is called " extra large U.S. oronain (Hexadimethrine chloride) " according to INCI (CTFA) nomenclature.

According to a special embodiment, the condensation polymer that uses among the present invention has the cationic charge above 5meq/g, preferably surpasses 6meq/g.Charge density can be determined from calculating polymer architecture, or determine by the experiment of Kjeldahl method.

Advantageously, if compositions contains one or more cationic polymers with repetitive (A), their total amount is 0.1 weight %-10 weight % with respect to the weight of compositions, is 0.2 weight %-5 weight % more especially and is preferably 0.5 weight %-3 weight %.

According to a kind of particularly advantageous substitute mode of the present invention, when compositions contains one or more these base polymers, the weight ratio of described cationic polymer/ammonium chloride with repetitive (A) is preferably between 0.05 to 10, more especially between 0.1 to 5 and preferably between 0.2 to 1.

According to a kind of special more embodiment of the present invention, compositions contains one or more additives, it is selected from cationic polymer, dialkyl diallyl ammonium chloride and the acrylic acid copolymer with (composed of) formula A repetitive, acrylic acid cross-linked homopolymer, ceramide and silicon dioxide, and, more specifically, the cationic polymer, dialkyl diallyl ammonium chloride and acrylic acid copolymer and the ceramide that have (composed of) formula A repetitive.

Compositions of the present invention preferably contains one or more additives, the cationic polymer that it is selected from dialkyl diallyl ammonium chloride and acrylic acid copolymer and has the repetitive of (composed of) above-mentioned formula A.

Can also contain one or more fatty acids according to compositions of the present invention.

Term " fatty acid " " chemical compound of representative contains the carboxyl functional group of at least one ionic species; and straight or branched, saturated or undersaturated carbochain, described carbochain contains 840, preferred 8-30 the optional carbon atom that carries one or more hydroxyls, preferred 1 or 2 hydroxyl.If described fatty acid is undersaturated, it can contain, especially, and 1-4 conjugation or unconjugated carbon-to-carbon double bond.

That possible fatty acid comprises is sad, lauric acid, myristic acid, Palmic acid, palmitic acid, stearic acid, behenic acid, arachidic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid and erucic acid, perhaps its mixture, for example cetyl octadecanoid acid.

Preferably, fatty acid is a saturated acid.

These fatty acids can be converted to salt form.These salt comprise that especially alkali-metal salt is sodium and potassium salt for example, and the salt of alkaline-earth metal is calcium salt, ammonium salt for example, contain 1-3 identical or different, the optional C that carries hydroxyl ₁-C ₄The primary amine of alkyl, secondary amine or tertiary ammonium salt.

Advantageously, if compositions contains one or more fatty acids, form with acid and/or salt, their total amount, form in acid, their total amount is 0.1 weight %-20 weight % with respect to the weight of compositions, is 0.5 weight %-15 weight % more especially and is preferably 1 weight %-10 weight %.

According to a kind of particularly advantageous substitute mode of the present invention, when compositions contains one or more fatty acids, described fatty acid (in the form of the acid)/weight ratio of ammonium chloride is preferably between 0.01 to 10, more especially between 0.1 to 5 and more preferably between 0.2 to 2.

According to a special embodiment, described compositions contains one or more surfactants.These surfactants can be selected from anion, both sexes, nonionic, amphion and cationic surfactant separately or as mixture, more preferably anion or non-ionic surface active agent.

About anion surfactant, general independent or use the salt of following chemical compound as mixture, particularly alkali-metal salt is the salt magnesium salt for example of sodium salt, ammonium salt, amine salt, amino alkoxide or alkaline-earth metal for example:

-alkyl sulfate, alkyl ether sulfate, alkyl amido ether sulfate and alkyl aryl polyether sulfate;

-alkylsulfonate, alkylamide sulfonate, alkylaryl sulfonates;

-alkyl sulfo succinate, alkyl ether sulfo succinate, alkylamide sulfosuccinate;

-alkyl sulfoacetate;

-acyl sarcosinates; And acyl glutamate;

-alkyl polyglucoside-carboxylate, for example alkyl androstanediol citrate, alkyl polyglucoside tartrate and alkyl polyglucoside sulfosuccinate;

-alkyl sulphosuccinamate;

-acyl group isethionic acid ester, N-acyl taurate; Acyl lactylates;

-alkyl-D-galactoside glycuronate;

-polyoxy thiazolinyl alkyl ether carboxylate, polyoxy thiazolinyl alkylaryl ether carboxylate and polyoxy thiazolinyl alkylamidoalkyl ether carboxylate;

In these chemical compounds, alkyl or acyl group (RCO-) contain 10-24 carbon atom and aryl preferably phenyl or benzyl; Oxy alkylene preferably the quantity of oxyethylene group between 2-50.

The preferred anionic surfactants surfactant, if present, be selected from alkyl sulfate, alkyl ether sulfate, alkyl amido ether sulfate, alkylsulfonate, acyl isethinate, N-acyl taurine salt, polyoxy thiazolinyl alkyl ether carboxy acid salt and polyoxy thiazolinyl alkylamidoalkyl ether carboxylate; In these chemical compounds, alkyl or acyl group (RCO-) contain 10-24 carbon atom and aryl preferably phenyl or benzyl; The quantity of oxy alkylene, and oxyethylene group preferably are between 2-50.

About non-ionic surface active agent, they can advantageously be selected from following chemical compound separately or as mixture:

The aliphatic alcohol of-polyethoxylated, poly-propoxylation and/or bound to polyglycerol,

α-the dihydroxylic alcohols of-polyethoxylated, poly-propoxylation and/or bound to polyglycerol,

The quantity of oxirane or propylene oxide group is in 2 to 50 scope, and glyceryl quantity is in 2 to 30 scope;

-have 2 fatty acid amides to the polyethoxylated of the oxirane of 30mol;

-contain the fatty acid amide of 1 to 5 glyceryl bound to polyglycerol;

The ethoxylated ester of the fatty acid of-sorbitan has the oxirane of 2-30mol and the fatty acid ester of sucrose;

The derivant of-alkyl polyglycoside, N-alkylated glucamine;

These chemical compounds contain the aliphatic chain of at least one alkyl or alkenyl type or the alkyl or alkenyl chain that at least one contains 10-24 carbon atom;

The copolymer of-oxirane and expoxy propane.

Preferably, non-ionic surface active agent if present, is selected from the aliphatic alcohol that gathers ethoxyquin or bound to polyglycerol, the fatty acid amide with poly-ethoxyquin of 2-30mol oxirane; Have 1-5 glyceryl bound to polyglycerol fatty acid amide; These chemical compounds contain the aliphatic chain of at least one alkyl or alkenyl type or the alkyl or alkenyl chain that at least one contains 10-24 carbon atom.

Typically, if present, the content of one or more surfactants is 0.01 weight %-50 weight % with respect to the weight of compositions, preferably 0.1 weight %-25 weight %.

Colouring compositions of the present invention can also contain the adjuvant that multiple routine is applied to composition for hair dying, the thickening agent that for example is different from acrylic acid cross-linked homopolymer, cellulose thickener (for example hydroxyethyl-cellulose, hydroxypropyl cellulose, carboxymethyl cellulose) for example, guar gum and derivant thereof (for example hydroxypropyl guar gum), microbe-derived colloid (particularly xanthan gum or scleroglucan glue); Inorganic thickening agent, for example clay especially; The antioxidant or the Reducing agent that are different from ascorbic acid, for example arabo-ascorbic acid, ammonium sulfite, bisulfites or metabisulfite and 2-mercaptopropionic acid ammonium; Penetrating agent, chelating agen be ethylenediaminetetraacetic acid or its salt for example; Aromatic; Titanium oxide; Buffer agent; Dispersant; The film former that is different from the above cationic polymer; The direct dyes of synthetic or natural origin; And antiseptic.

The roughly content of above-mentioned adjuvant is, for they each, is 0.01 weight %-20 weight % with respect to the weight of compositions.

Acceptable medium on the cosmetics of compositions is the medium of the human keratin fiber that is suitable for dyeing, and preferably contains water and one or more solvents.

The example of such solvent comprises straight or branched C ₂-C ₄Alkanol, for example ethanol and isopropyl alcohol; Polyhydric alcohol and polyol ethers be butoxy ethanol, hexanediol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, diglycol monotertiary ethyl and monomethyl ether for example, and glycerol and also have aromatic alcohols for example benzyl alcohol, benzene methoxy alcohol or benzene oxygen alcohol and composition thereof.

The ratio that exists of solvent is 1 weight %-40 weight % with respect to the weight of compositions, is preferably 5 weight %-30 weight %.

According to the pH of compositions of the present invention, lacking under the situation of oxidant, usually between 6 and 11.5.

Under particularly advantageous situation, it is more than or equal to 9.2.This pH is preferably between 9.2-11, more particularly between the 9.3-10 and more preferably between 9.4-9.9.

According to purpose of the present invention, described dyeing (perhaps dyeing) compositions does not comprise that oxidant is meant and does not contain any chemical oxidizing agent, and do not contain any hydrogen peroxide, urea peroxide, alkali-metal bromate or ferricyanate of being selected from especially, and alkali metal or the alkaline-earth metal for example peroxide salt of sodium, potassium and magnesium, for example chemical oxidizing agent of persulfate, perborate and percarbonate.

PH can be adjusted to suitable value, by use ammonium chloride and ammonia and, randomly, use normally used one or more acidulant in this area or one or more basifiers.

Acidulant comprises, for example, organic acid or mineral acid, for example hydrochloric acid, orthophosphoric acid, sulphuric acid, carboxylic acid is acetic acid, tartaric acid, citric acid and lactic acid and sulfonic acid for example.

Basifier comprises, for example, alkali-metal carbonate, aforesaid alkanolamine, sodium hydroxide or potassium hydroxide, and as shown in the formula chemical compound:

Wherein W is optional by hydroxyl or C ₁-C ₆The propylene residues that alkyl replaces, R _x, R _y, R _zAnd R _t, it represents hydrogen atom or C identical or differently ₁-C ₆Alkyl or C ₁-C ₆Hydroxy alkyl.

Can mix with one or more oxidants according to compositions of the present invention.It refers to the compositions of a kind of available at any time (ready-to-use) in this case.

Especially, this compound of available set at any time is the interim above-mentioned composition that mixes the oxygen-free agent before using, and obtains with the compositions that contains one or more oxidants.

Oxidant is preferably selected from hydrogen peroxide, urea peroxide, and alkali-metal bromate or ferricyanate, peroxide salt such as alkaline-earth metal or alkaline-earth metal be persulfate, perborate and the percarbonate of sodium, potassium and magnesium for example.

The particularly preferred hydrogen peroxide that is to use.

Advantageously, this oxidant is made up of the hydrogen peroxide in the aqueous solution, and its content can be, very especially between 1 to 40 volume, and more preferably changes between 5 to 40 volumes.

Can obtain according to compositions of the present invention by two or more compositionss of interim mixing.

Therefore, the present invention further provides the method for under the situation that has one or more oxidants, using above-claimed cpd dyeing human keratin fiber.

First substitute mode according to this embodiment, the compound of available set at any time that has described in detail above, and the compositions that the interim above-mentioned composition that mixes the oxygen-free agent obtains with containing the compositions of one or more oxidants before therefore using, be used on the fiber.

The colouring compositions that does not have oxidant, and oxidising composition is to mix between the 2-0.25 time there not being the colouring compositions of oxidant/oxidising composition weight ratio preferably, and preferably between 1-0.5.

The pH of the compound of available set at any time that obtains by mixing is preferably between 7.5-10, better between the 8-9.8 and even be more preferably between the 8.5-9.5.

According to second substitute mode of this embodiment, according to the compositions and the oxidising composition of oxygen-free agent of the present invention, at continuously (in succession) and under the non-washed situation in centre, use.

The oxidising composition that is adopted contains one or more above-mentioned oxidants.

About the optional organic solvent that is present in the oxidising composition, can be with reference to the tabulation that in the description of the present composition, provides.

Usually the pH of oxidising composition is less than 7.

Oxidizing agent composition can exist with solution, emulsion or gel form.

It can randomly contain one or more additives that uses in dyeing human keratin fiber field usually, and this depends on the required form of expression.Equally, can be with reference to tabulating at aforesaid additive.

Irrelevant with employing embodiment (while or continuous use), the mixture that is applied on the fiber temporarily is left on original position a period of time, substantially, keeps 5-60 minute rank, preferred 5-30 minute and even more preferably 5-20 minute.

Conventional Temperature in the method is 10-200 ℃, and more particularly in room temperature (between 15-25 ℃) with between 80 ℃, more preferably between room temperature and 60 ℃.

When processing finished, randomly water flushing human keratin fiber randomly washed once more with shampoo and water, then drying or put dried.

The present invention provides the multicell device at last, wherein contains compositions of the present invention at least one chamber, the oxygen-free agent, and contain at least a oxidising composition at least one second Room, it contains one or more oxidants.

Provide specific embodiment now, but it does not limit the present invention.

Embodiment

In the following embodiments, under the situation without any opposite explanation, the equal operating weight % of content of active substance represents.

Embodiment 1:

This embodiment has described the compositions of the present invention that contains the ceramide additive.

Be prepared as follows compositions:

The lauric acid monoisopropanolamine	3
		Ethoxylation dodecanol (12EO)	7
Ethoxylation oleoyl hexadecanol (30EO)	4
		Ethoxylation decanol (3EO)	10
Cetostearyl alcohol (C16-C18-50/50)	11.5
		The diethylene-triamine pentaacetic acid five sodium-salt, 40% aqueous solution	4

Kaolin	1.2
		1, the 3-diaminopropanes	0.4
Poly-(dimethyl diallyl ammonium chloride) (Polyquaternium 6)	4
		2-oleoyl amido-1,3-octacosanol (ceramide)	0.01
Propylene glycol	7
		Carbopol ETD 2020	0.6
Ammonium chloride	3.78
		Titanium oxide	0.15
Chelating agen	In right amount
		Reducing agent	In right amount
Antioxidant	In right amount
		Aromatic	0.6
Ammonia (containing 20.5% ammonia)	6
		Right-toluenediamine	1.8
1-beta-hydroxyethyl oxygen base-2,4-diaminobenzene dihydrochloride	0.03
		The 2-methyl isophthalic acid, the 3-dihydroxy benzenes	0.6
Between-amino-phenol	0.4
		Resorcinol	1
Deionized water (in right amount)	100

Then compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Final mixture is applied to a thread to be contained on the natural hair of 90% poliosis.

Said mixture was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in time of application, water washes this thread hair, cleans dry then with the standard shampoo.

This provides the tone (shade) of the light brown with fiber good quality.

Embodiment 2:

This embodiment has described the compositions that contains particular cationic polymers (Mexomere PO).

Be prepared as follows compositions:

The lauric acid monoisopropanolamine	3
		Ethoxylation dodecanol (12EO)	7
Ethoxylation oleoyl hexadecanol (30EO)	4
		Ethoxylation decanol (3EO)	10
Cetostearyl alcohol (C16-C18-50/50)	11.5
		Kaolin	1.2
1, the 3-diaminopropanes	0.4
		The diethylene-triamine pentaacetic acid five sodium-salt, 40% aqueous solution	4
Mexomere PO	3
		Propylene glycol	7
Cross linked polyacrylate	0.6
		Ammonium chloride	3.78
Titanium oxide	0.15
		Chelating agen	In right amount
Reducing agent	In right amount
		Antioxidant	In right amount
Aromatic	0.6
		Ammonia (containing 20.5% ammonia)	6
N, two (2-hydroxyethyl) the p-phenylenediamine sulfate 1H of N- 2O	0.25
		Resorcinol	1.3
1-hydroxyl-3-aminobenzene	0.3
		P-phenylenediamine	1.8
Deionized water (in right amount)	100

Then compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Final mixture is applied to a thread to be contained on the natural hair of 90% poliosis.

Said mixture was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in time of application, water washes this thread hair, cleans dry then with the standard shampoo.

This provides the brown tone with fiber good quality.

Embodiment 3:

This embodiment has described the compositions that contains silicon dioxide.

Be prepared as follows compositions:

The lauric acid monoisopropanolamine	3
		Ethoxylation dodecanol (12EO)	7
Ethoxylation oleoyl hexadecanol (30EO)	4
		Ethoxylation decanol (3EO)	10
Cetostearyl alcohol (C16-C18-50/50)	11.5
		The hydrophobicity pyrolytic silicon dioxide	1.2
1, the 3-diaminopropanes	0.4
		The diethylene-triamine pentaacetic acid five sodium-salt, 40% aqueous solution	4
Poly-(dimethyl diallyl ammonium chloride) (Polyquaternium 6)	4
		Propylene glycol	7
Carbopol ETD 2020	0.6
		Ammonium chloride	3.78
Titanium oxide	0.15
		Chelating agen	In right amount
Reducing agent	In right amount
		Antioxidant	In right amount
Aromatic	0.6
		Ammonia (containing 20.5% ammonia)	6
N, two (2-hydroxyethyl) the p-phenylenediamine sulfate 1H of N- 2O	0.2
		Resorcinol	1.3
1-hydroxyl-3-aminobenzene	0.3
		P-phenylenediamine	1.8
Deionized water (in right amount)	100

Then compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Final mixture is applied to a thread to be contained on the natural hair of 90% poliosis.

Said mixture was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in time of application, water washes this thread hair, cleans dry then with the standard shampoo.

This provides the brown tone with fiber good quality.

Embodiment 4:

This embodiment has described the compositions that contains Polyquaternium 22.

Be prepared as follows compositions:

The lauric acid monoisopropanolamine	3
		Ethoxylation dodecanol (12EO)	7
Ethoxylation oleoyl hexadecanol (30EO)	4
		Ethoxylation decanol (3EO)	10
Cetostearyl alcohol (C16-C18-50/50)	11.5
		The diethylene-triamine pentaacetic acid five sodium-salt, 40% aqueous solution	4
Hydrophobic fumed silica	1.2
		1, the 3-diaminopropanes	0.4
Polyquaternium 22	3
		Propylene glycol	7
Carbopol ETD 2020	0.6
		Ammonium chloride	3.78
Titanium oxide	0.15
		Chelating agen	In right amount
Reducing agent	In right amount
		Antioxidant	In right amount
Aromatic	0.6
		Ammonia (containing 20.5% ammonia)	6
P-phenylenediamine (PPD)	1.1

The 2-methylresorcinol	0.3
		The 6-oxyindole	0.03
Resorcinol	0.6
		Between-amino-phenol	0.1
Para-aminophenol	0.09
		Deionized water (in right amount)	100

Then compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Final mixture is applied to a thread to be contained on the natural hair of 90% poliosis.

Said mixture was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in time of application, water washes this thread hair, cleans dry then with the standard shampoo.

This provides the very shallow brown tone with fiber good quality.

Embodiment 5:

This embodiment has described the compositions that contains the acrylic acid cross-linked homopolymer.

The preparation compositions is as follows:

The lauric acid monoisopropanolamine	3
		Ethoxylation dodecanol (12EO)	7
Ethoxylation oleoyl hexadecanol (30EO)	4
		Ethoxylation decanol (3EO)	10
Cetostearyl alcohol (C16-C18-50/50)	11.5
		The diethylene-triamine pentaacetic acid five sodium-salt, 40% aqueous solution	4
Kaolin	1.2
		1, the 3-diaminopropanes	0.4
Poly-(dimethyl diallyl ammonium chloride) (Polyquaternium 6)	4
		Propylene glycol	7
Cross linked polyacrylate (Carbomer 980)	0.6
		Ammonium chloride	3.78

Titanium oxide	0.15
		Chelating agen	In right amount
Reducing agent	In right amount
		Antioxidant	In right amount
Aromatic	0.6
		Ammonia (containing 20.5% ammonia)	6
P-phenylenediamine (PPD)	2
		2,4-diaminobenzene oxyethanol hydrochlorate	0.02
The 2-methylresorcinol	0.76
		Between-amino-phenol	0.3
Resorcinol	1
		Para-aminophenol	0.2
Deionized water (in right amount)	100

Then compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Final mixture is applied to a thread to be contained on the natural hair of 90% poliosis.

Said mixture was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in time of application, water washes this thread hair, cleans dry then with the standard shampoo.

This provides the tone of the golden brown with fiber good quality.

Embodiment 6:

This embodiment has described two kinds of compositionss that contain monoethanolamine.

Be prepared as follows compositions:

The lauric acid monoisopropanolamine	3	3
			Ethoxylation dodecanol (12EO)	7	7
Ethoxylation oleoyl hexadecanol (30EO)	4	4
			Ethoxylation decanol (3EO)	10	10
Cetostearyl alcohol (C16-C18-50/50)	11.5	11.5
			The diethylene-triamine pentaacetic acid five sodium-salt, 40% aqueous solution	4	4

Kaolin	1.2	1.2
			Pure monoethanolamine	0.4	1.6
Poly-(dimethyl diallyl ammonium chloride) (Polyquaternium 6)	4	4
			Propylene glycol	7	7
Carbopol ETD 2020	0.6	0.6
			Ammonium chloride	3.78	3.78
Titanium oxide	0.15	0.15
			Chelating agen	In right amount	In right amount
Reducing agent	In right amount	In right amount
			Antioxidant	In right amount	In right amount
Aromatic	0.6	0.6
			Ammonia (containing 20.5% ammonia)	6	6
P-phenylenediamine (PPD)	0.9	0.9
			2,4-diaminobenzene oxyethanol hydrochlorate	0.05	0.05
The 2-methylresorcinol	0.6	0.6
			Para-aminophenol	0.8	0.8
Between-amino-phenol	0.15	0.15
			Resorcinol	0.5	0.5
The 6-oxyindole	0.15	0.15
			2-methyl-5-hydroxyethyl amino-phenol	0.3	0.3
Deionized water (in right amount)	100	100

Then each compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Each final mixture is applied to a thread to be contained on the natural hair of 90% poliosis.

Said mixture was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in time of application, water washes this thread hair, cleans dry then with the standard shampoo.

Two kinds of situations all provide the tone of the coppery with fiber good quality.

Embodiment 7:

This embodiment has described and has contained ascorbic acid composition.

Be prepared as follows compositions:

The lauric acid monoisopropanolamine	3
		Ethoxylation dodecanol (12EO)	7
Ethoxylation oleoyl hexadecanol (30EO)	4
		Ethoxylation decanol (3EO)	10
Cetostearyl alcohol (C16-C18-50/50)	11.5
		The diethylene-triamine pentaacetic acid five sodium-salt, 40% aqueous solution	4
Kaolin	1.2
		1, the 3-diaminopropanes	0.4
Poly-(dimethyl diallyl ammonium chloride) (Polyquaternium 6)	4
		Propylene glycol	7
Carbopol ETD 2020	0.6
		Ammonium chloride	3.78
Titanium oxide	0.15
		Chelating agen	0.25
Ascorbic acid	0.25
		Reducing agent	In right amount
Aromatic	0.6
		Ammonia (containing 20.5% ammonia)	6
P-phenylenediamine (PPD)	0.9
		2,4-diaminobenzene oxyethanol hydrochlorate	0.05
The 2-methylresorcinol	0.6
		Para-aminophenol	0.8
Between-amino-phenol	0.15
		Resorcinol	0.5
The 6-oxyindole	0.15
		2-methyl-5-hydroxyethyl amino-phenol	0.3

Deionized water (in right amount)

An amount of 100

Then compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Final mixture is applied to a thread to be contained on the natural hair of 90% poliosis.

Said mixture was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in time of application, water washes this thread hair, cleans dry then with the standard shampoo.

This provides the tone of the coppery with fiber good quality.

Embodiment 8:

This embodiment has described the influence of the existence of cationic polymer to the end product dyeability.

Be prepared as follows compositions (content of active substance is g%):

Each compositions is mixed with the oxidising composition (1 to 1 dilution by weight) of 30 volumes.

Each final mixture is applied to a thread to have on the hair of average sensitivity (alkali solubility 20%).

This thread hair of so handling was placed 10 minutes down in room temperature (23 ℃+/-3 ℃).

Last in this time of application, water washes this thread hair, uses standard shampoo cleaning-drying then.

Dye after 24 hours, in laboratory system, carry out colorimetric measurement with Minolta CM-2600D tintometer.

Record dynamics and rising value between compositions A and the B:

Use L ^*The evaluation dynamics.

L ^*Low more, the dynamics of the gained that then dyes is strong more.

Rise corresponding be undyed thread with dyeing after send out the difference of thread on color.

Calculate according to following equation:

DE＝[(L ^*-L ^* ₀) ²+(a ^*+a ^* ₀) ²+(b ^*-b ^* ₀) ²] ^1/2

L wherein ^*, a ^*And b ^*Be with dyeing after send out relevant coefficient of thread and L ^* ₀, a ^* ₀And b ^* ₀Be and undyed the coefficient that thread is relevant.

The DE value is high more, and it is big more that color rises.

The result

Compositions	L *	DE
			Be unstained and send out thread	59.78	-
Compositions A is according to the present invention	22.64	43.76
			Compositions B, contrast	26.05	40.24

Can observe from these results, the reference composition of cation-containing copolymer obtains the result than using not, and the dyeing that compositions of the present invention obtains is more powerful, and has shown bigger lifting.

Claims (15)

1. the compositions that is used for dyeing keratin fibres, it contains one or more oxidation dyes, ammonia in acceptable medium on cosmetics, with respect to composition weight, and content is selected from following additive more than the ammonium chloride of 1 weight % and one or more:

-by the cationic polymer of forming corresponding to the repetitive of following formula A:

Wherein, R ' ₁, R ' ₂, R ' ₃And R ' ₄Represent the group of the aliphatic that contains 1-6 carbon atom, alicyclic or aromatic yl aliphat identical or differently, or aliphatic hydroxyl (C ₁-C ₆) alkyl; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄Jointly or the nitrogen-atoms that is connected with them respectively form 5 yuan or 6 yuan of saturated heterocyclics, it randomly comprises second hetero atom (for example oxygen or sulfur) that is different from nitrogen; Perhaps, R ' ₁, R ' ₂, R ' ₃And R ' ₄Representative by nitrile, ester, acyl group, amide or-CO-O-R ' ₅-D or-CO-NH-R ' ₅The straight or branched C that-D group replaces ₁-C ₆Alkyl, wherein R ' ₅Be C ₁-C ₆Alkylidene, D are to contain identical or different C ₁-C ₆The quaternary ammonium group of alkyl;

A ₁And B ₁Representative contains the polymethylene of 2-6 carbon atom, and it can be a straight or branched, saturated or undersaturated, and can contain the C that is connected (replacement) or embeds main chain ₆Aromatic ring or oxygen or sulphur atom, or sulfoxide, sulfone, disulphide, amino, alkyl amino, hydroxyl, quaternary ammonium group, urea groups or ester group, or its combination and

X ^-Represent an anion that comes from organic acid or mineral acid;

A ₁, R ' ₁And R ' ₃Can with two nitrogen-atoms that are connected with them, form piperazine ring; And the mixture of these additives

-dialkyl diallyl ammonium chloride and acrylic acid copolymer,

-acrylic acid cross-linked homopolymer,

-ceramide,

-silicon dioxide,

-ascorbic acid and/or its salt,

-alkanolamine and/or its salt.

2. as the described compositions of pro-claim, the content that is characterised in that ammonium chloride is at least 1.5 weight % with respect to the weight of compositions.

3. as the described compositions of each claim of pro-, the content that is characterised in that ammonium chloride is at least 3 weight % with respect to the weight of compositions.

4. as the described compositions of each claim of pro-, be characterised in that the content of ammonia, represent, be at least 0.5 weight % with respect to the weight of compositions with the form of gaseous ammonia.

5. as the described compositions of each claim of pro-, be characterised in that the weight ratio of ammonium chloride/ammonia (form with gaseous ammonia is represented) is at least 2.

6. as the described compositions of each claim of pro-, be characterised in that each content of additive is 0.001 weight %-10 weight % with respect to the weight of compositions.

7. as the described compositions of each claim of pro-, be characterised in that cationic polymer, dialkyl diallyl ammonium chloride and acrylic acid copolymer, acrylic acid cross-linked homopolymer, ceramide and silicon dioxide that additive or multiple additives select the repetitive of free style A to form.

8. as the described compositions of each claim of pro-, be characterised in that cationic polymer, dialkyl diallyl ammonium chloride and acrylic acid copolymer and ceramide that additive or multiple additives select the repetitive of free style A to form.

9. as the described compositions of each claim of pro-, be characterised in that it contains one or more oxidants.

10. as the described compositions of pro-claim, be characterised in that oxidant is a hydrogen peroxide.

11. as each described compositions among the pro-claim 1-8, the pH that is characterised in that compositions is more than or equal to 9.2, more particularly between 9.2-11.

12. the method for dyeing human keratin fiber comprises in existence under the situation of compositions of one or more oxidants, uses each described colouring compositions among the pro-claim 1-8.

13. method as claimed in claim 12 is characterised in that, in turn and under the non-washed situation in centre, with colouring compositions, then contain the compositions of one or more oxidants, or vice versa, is applied on the keratin fiber,

14. colouring method as claimed in claim 12, be characterised in that and use available set compound at any time, its be will be before using as claim 1-8 in each described colouring compositions and obtaining at least a interim mixing of compositions of containing one or more oxidants.

15. the multicell device, it contains in first Room just like each described compositions among the claim 1-8, contains the compositions of one or more oxidants in another chamber.