CN101549511A - Preparing method for non-formaldehyde intensified wooden floor - Google Patents

Preparing method for non-formaldehyde intensified wooden floor Download PDF

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Publication number
CN101549511A
CN101549511A CNA200910143363XA CN200910143363A CN101549511A CN 101549511 A CN101549511 A CN 101549511A CN A200910143363X A CNA200910143363X A CN A200910143363XA CN 200910143363 A CN200910143363 A CN 200910143363A CN 101549511 A CN101549511 A CN 101549511A
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formaldehyde
base material
methanal
burst size
preparation
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CNA200910143363XA
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CN101549511B (en
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朱君山
朱勇
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Hubei Aosen Wood Industry Ltd By Share Ltd
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Individual
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Abstract

The invention relates to preparing technology field of upholstery intensified wooden floor, especially a preparing method for intensified floor without free formaldehyde released. The preparing method includes the steps of sorting, preparing formaldehyde clearing liquor and processing basic materials. Compared to the non-processed intensified wooden floor, various physical index of the intensified wooden floor processed with the method in this invention does not fall down by employing GB/T11718-1999 detecting the various physical index of the intensified wooden floor, which principally because formaldehyde clearing liquor reacting with formaldehyde not only removes formaldehyde, but also intensifies the bonding strength and resistance to water for formaldehyde clearing liquor is principally macromolecule substance.

Description

A kind of preparation method of non-formaldehyde intensified wooden floor
Technical field
The present invention relates to the manufacture technology field of indoor decoration laminated flooring, especially a kind of preparation method of not having the consolidated floor of free formaldehyde release, and the preparation method that is used for the formaldehyde removing liquid of this consolidated floor base material treatment.
Background technology
At present the adhesive that uses of composite floor board is still based on Lauxite, in the floor the residual formaldehyde that has neither part nor lot in reaction can with gaseous form towards periphery environment discharge gradually.Formaldehyde is a kind of colourless and have the irritative gas of overpowering odor, and its aqueous solution is called formalin, can make protein denaturation, is commonly used for anticorrisive agent in the medical science.When people are in the higher environment of concentration of formaldehyde, uncomfortable symptom, the health that tends to endanger health will take place in eyes, nasal cavity and respiratory tract.In daily life, formaldehyde is a healthy big killer, is the allergen of generally acknowledging, is in second on China's toxic chemical control list.
Consolidated floor has had the history of more than ten years in China, and 2.5 hundred million square metres of consolidated floors were produced in the whole nation in 2008, can be rated as consolidated floor big producing country.Our family and the public place consolidated floor of mating formation does not have other harmful thing at present, is exactly the problem that a free formaldehyde discharges.In the middle of the expansion of consolidated floor technology, China become the development of consolidated floor big export country day by day,,, all be a kind of contribution undoubtedly to various countries consumer's health if can both produce with no aldehyde standard.
China national health authorities find according to actual measurement, if the air concentration of formaldehyde in the people room is greater than 0.08mg/m 3, the airborne concentration of formaldehyde of public area is greater than 0.12mg/m 3, people's eyes or sense of smell just can have been experienced the stimulation of formaldehyde, if the people is in the environment that formaldehyde exceeds standard for a long time, health can be affected and injure.Smelling influenced, the inhereditary material in the damaging cells also of heavy unusual, stimulation, allergy, abnormal pulmonary function, dysfunction of liver, immunologic dysfunction, central nervous system but formaldehyde mainly comprises health effects, is suspect carcinogen.Formaldehyde gas discharges quality: the quality that means the formaldehyde gas that the compoiste wood floor of unit are when 25 ℃ of normal temperature discharges.16 kinds of reinforced composite floorboard formaldehyde gas burst sizes are all at 0.056mg/m after tested 2-0.226mg/m 2Between.
The present invention does not have aldehyde level consolidated floor standard-required burst size of methanal≤0.5 mg/litre (drier method), and this standard has suitable leading and advanced in the world.Entirely the class of panel products is significant to improving us for this, and in protection consumer physical and mental health, protection production line worker's is healthy, protects our life and living space, air quality etc. that good effect is all arranged especially.
Summary of the invention
Purpose of the present invention just is to provide at the weak point that has the consolidated floor manufacturing technology now a kind of preparation method of consolidated floor of formaldehydeless release.
Another object of the present invention provides a kind of processing method of improved consolidated floor, and has proposed to be used to improve the technical scheme of this consolidated floor.
A kind of preparation method of non-formaldehyde intensified wooden floor is characterized in that: the preparation method of non-formaldehyde intensified wooden floor of the present invention is to realize by following step:
A. selection:
1. the selection of base material selects every indexs such as bonding strength, expansion rate of water absorption, MOR, density to meet or be better than the medium density fibre board (MDF) of GB, and thickness is selected by necessary requirement.
2. burst size of methanal is selected the base material of burst size of methanal (drier method)≤1.5mg/L, (perforation extraction)≤9mg/100g as far as possible, and is low more good more.
B. formaldehyde removing liquid preparation: (mass parts 100)
Oxidizing process acidolysis soybean protein 15-20,
Citric acid 3-5,
Tea Polyphenols 1-2,
Bleeding agent 0.2-0.5,
Biology enzyme 0.2-0.5,
The pure water surplus
C. base material treatment:
1. liquid is removed in spray.The formaldehyde removing liquid that is mixed with by the b step evenly is sprayed on the two sides anyway of base material with the high-pressure ion spray, and consumption can be controlled in 8ml/m according to the height of base material burst size of methanal 2-20ml/m 2Between.
2. heat treatment.Sprayed the base material of removing liquid, be placed in 60 ℃-85 ℃ the constant temperature drying kiln and heat-treat, the processing time all reaches requirement with moisture content and burst size of methanal and is as the criterion.
3. detect.Using GB18580-2001 drier method, Japanese JAS, U.S. CARB to carry out burst size of methanal respectively detects, burst size of methanal is respectively the highest 0.5mg/L, minimum 0.1mg/L, on average≤0.4mg/L, this shows that the sheet material burst size of methanal of handling well reaches the no aldehyde level wood-based plate standard of Japanese JAS, can carry out next step operation.
Wherein, the base material of selecting for use reaches the no aldehyde grade standard of Japanese JAS, U.S. CARB regulation after formaldehyde removing liquid of the present invention is handled.
Wherein, the used paint of each operation, wear-resisting low, dyestuff, inserts etc. all must not contain formaldehyde.
The specific embodiment
Embodiment 1.
Selecting thickness is the long 2440mm of 9mm, and the medium density fibre board (MDF) of wide 1220mm, burst size of methanal are the medium density fibre board (MDF) of 1.41mg/L, presses 8ml/m with the high-pressure ion spraying 2Consumption evenly be sprayed at medium density fibre board (MDF) two sides anyway, send drying kiln oven dry then, bake out temperature is selected 60 ℃~75 ℃, the general 0.5h~1.5h of drying time, general 55 ℃~65 ℃ of kiln discharge temperature, pile then, health is more than 15 days.The burst size of methanal that same drier method with GB18580-2001 detects medium density fibre board (MDF) is 0.23mg/L, and detects with California, USA air administrative administration (CARB) climate box method, and burst size of methanal only is 0.02PPM.
Embodiment 2.
Selecting thickness is the long 2440mm of 12mm, and the medium density fibre board (MDF) of wide 1220mm, burst size of methanal are the medium density fibre board (MDF) of 1.82mg/L, presses 12ml/m with the high-pressure ion spraying 2Consumption evenly be sprayed at medium density fibre board (MDF) two sides anyway, send drying kiln oven dry then, bake out temperature is selected 65 ℃~81 ℃, the general 0.5h~1.5h of drying time, general 60 ℃~71 ℃ of kiln discharge temperature, pile then, health is more than 15 days.The burst size of methanal that same drier method with GB18580-2001 detects medium density fibre board (MDF) is 0.21mg/L, and detects with California, USA air administrative administration (CARB) climate box method, and burst size of methanal only is 0.01PPM.
Embodiment 3.
Selecting thickness is the long 2440mm of 15mm, and the medium density fibre board (MDF) of wide 1220mm, burst size of methanal are the medium density fibre board (MDF) of 1.97mg/L, presses 20ml/m with the high-pressure ion spraying 2Consumption evenly be sprayed at medium density fibre board (MDF) two sides anyway, send drying kiln oven dry then, bake out temperature is selected 68 ℃~85 ℃, the general 0.5h~1.5h of drying time, general 65 ℃~73 ℃ of kiln discharge temperature, pile then, health is more than 15 days.The burst size of methanal that same drier method with GB18580-2001 detects medium density fibre board (MDF) is 0.19mg/L, and detects with California, USA air administrative administration (CARB) climate box method, and burst size of methanal only is 0.01PPM.
Consolidated floor base material through above method processing, adopt every physical index of GB/T11718-1999 detection enhancement floor base material, we find and the consolidated floor base material of not handling to compare, every physical index does not reduce than before handling, this mainly is because formaldehyde removing liquid mainly is polymer substance, not only play the purpose of removing formaldehyde with formolite reaction, also play the purpose that increases bonding strength and resistance to water.

Claims (3)

1. the preparation method of a non-formaldehyde intensified wooden floor, it is characterized in that: the preparation method of non-formaldehyde intensified wooden floor of the present invention is to realize by following step:
A, selection:
(1) selection of base material selects bonding strength to meet the medium density fibre board (MDF) of GB, and thickness is selected by necessary requirement.
(2) burst size of methanal is selected the base material of burst size of methanal (drier method)≤1.5mg/L, (perforation extraction)≤9mg/100g, and is low more good more.
B, the preparation of formaldehyde removing liquid: (mass parts 100)
Oxidizing process acidolysis soybean protein 15-20,
Citric acid 3-5,
Tea Polyphenols 1-2,
Bleeding agent 0.2-0.5,
Biology enzyme 0.2-0.5,
The pure water surplus
C, base material treatment:
1. liquid is removed in spray.The formaldehyde removing liquid that is mixed with by the b step evenly is sprayed on the two sides anyway of base material with the high-pressure ion spray, and consumption can be controlled in 8ml/m according to the height of base material burst size of methanal 2-20ml/m 2Between.
2. heat treatment.Sprayed the base material of removing liquid, be placed on constant temperature drying in 60 ℃ of-85 ℃ of drying kilns then, drying time reaches requirement with moisture content and is as the criterion, and pile, health are more than 15 days then.
3. detect.Use the drier method to carry out burst size of methanal and detect, burst size of methanal is the highest 0.5mg/L, minimum 0.1mg/L, on average≤0.4mg/L, this shows the sheet material first of handling well, and the aldehyde burst size reaches the no aldehyde level wood-based plate standard of Japanese JAS, can carry out next step operation.
2. the preparation method on non-formaldehyde intensified floor according to claim 1, the base material that it is characterized in that selecting for use reach the no aldehyde grade standard of Japanese JAS regulation after formaldehyde removing liquid of the present invention is handled.
3. the preparation method on non-formaldehyde intensified floor according to claim 1 is characterized in that the used paint of each operation, wear-resisting low, dyestuff, inserts etc. all must not contain formaldehyde.
CN200910143363XA 2009-05-22 2009-05-22 Preparing method for non-formaldehyde intensified wooden floor Expired - Fee Related CN101549511B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102744757A (en) * 2012-07-05 2012-10-24 陆勇军 Method for producing formaldehyde-free floor
CN103306445A (en) * 2013-06-23 2013-09-18 封海云 Methanal-free decoration and fitment method
CN103341250A (en) * 2013-06-20 2013-10-09 赵杰 Method for treating indoor decoration formaldehyde pollution
CN103978536A (en) * 2014-05-18 2014-08-13 张永刚 Formaldehyde-free level laminated floor production technology
CN105563600A (en) * 2015-12-18 2016-05-11 文安县天华密度板有限公司 Production method for decreasing formaldehyde of density board
CN106883799A (en) * 2015-12-16 2017-06-23 湖南福湘木业有限责任公司 One kind is without aldehyde level wood-based plate adhesive and its production technology
CN106914961A (en) * 2017-03-17 2017-07-04 济南舜景医药科技有限公司 A kind of method that artificial board removes formaldehyde
CN112025891A (en) * 2020-08-29 2020-12-04 成都市美康三杉木业有限公司 Aldehyde-reducing and VOC-removing method for graphene heating artificial board
CN114311175A (en) * 2021-12-30 2022-04-12 龙岩市锐美家装饰材料有限公司 Preparation method of aldehyde-free fire-resistant decorative panel

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1404891A (en) * 2002-11-04 2003-03-26 江苏省环境科学研究院 Formol eliminating agent for artificial plate and preparation method
CN101195037A (en) * 2007-12-10 2008-06-11 诸城市良丰化学有限公司 Biological aldehydrase preparation prescription and its preparation technique
CN101362049A (en) * 2008-09-27 2009-02-11 苏继章 Preparation method of natural formaldehyde remover
CN101418636B (en) * 2008-11-17 2011-12-14 江苏宏耐木业有限公司 Intensified wooden floor capable of reaching EO grade standard

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102744757A (en) * 2012-07-05 2012-10-24 陆勇军 Method for producing formaldehyde-free floor
CN102744757B (en) * 2012-07-05 2014-08-06 陆勇军 Method for producing formaldehyde-free floor
CN103341250A (en) * 2013-06-20 2013-10-09 赵杰 Method for treating indoor decoration formaldehyde pollution
CN103306445A (en) * 2013-06-23 2013-09-18 封海云 Methanal-free decoration and fitment method
CN103978536A (en) * 2014-05-18 2014-08-13 张永刚 Formaldehyde-free level laminated floor production technology
CN106883799A (en) * 2015-12-16 2017-06-23 湖南福湘木业有限责任公司 One kind is without aldehyde level wood-based plate adhesive and its production technology
CN105563600A (en) * 2015-12-18 2016-05-11 文安县天华密度板有限公司 Production method for decreasing formaldehyde of density board
CN106914961A (en) * 2017-03-17 2017-07-04 济南舜景医药科技有限公司 A kind of method that artificial board removes formaldehyde
WO2018165782A1 (en) * 2017-03-17 2018-09-20 济南舜景医药科技有限公司 Method for removing formaldehyde from artificial boards
CN106914961B (en) * 2017-03-17 2019-01-15 南京海象地板有限公司 A kind of method that artificial board removes formaldehyde
CN112025891A (en) * 2020-08-29 2020-12-04 成都市美康三杉木业有限公司 Aldehyde-reducing and VOC-removing method for graphene heating artificial board
CN114311175A (en) * 2021-12-30 2022-04-12 龙岩市锐美家装饰材料有限公司 Preparation method of aldehyde-free fire-resistant decorative panel

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Owner name: HUBEI AOSEN WOOD INDUSTRY CO., LTD.

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Address after: 437000 Xianning province Hubei City Haman District Phoenix Industrial Park

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