CN101544873A - Cleaning-free external pasting film - Google Patents
Cleaning-free external pasting film Download PDFInfo
- Publication number
- CN101544873A CN101544873A CN200910117264A CN200910117264A CN101544873A CN 101544873 A CN101544873 A CN 101544873A CN 200910117264 A CN200910117264 A CN 200910117264A CN 200910117264 A CN200910117264 A CN 200910117264A CN 101544873 A CN101544873 A CN 101544873A
- Authority
- CN
- China
- Prior art keywords
- glue
- layer
- shares
- film
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
A cleaning-free external pasting film is composed of a basal layer, a glue layer and a film layer, wherein the basal layer is made of a smooth synthetic papers surface coating silicon oil layer with toughness; the film layer is made by dissolving 35 shares of HO-(CH2CH2O)18-COOH and 10 shares of EuCl2 6H2O into methanol to mix, a [HO-(CH2CH2O)18-COO]2Eu complexes is obtained through oil bath heating, inverse flow, filtrating, decompression rotary evaporation to remove dissolvent and cooling, then the film layer will be obtained by adding the complexes into polyethylene; for the glue layer, a suspending liquid is obtained by agitating 50 shares of graphite and 200 shares of N-2-hydroxyethylamino; a glue is obtained by agitating a mixture of 1 shares of the suspending liquid and 49 shares of polyurethane glue by weight, the glue layer will be obtained by jetting the glue on the film layer. The pasting film of the invention is economic and environment protection, operation is easy and safe. The film has characteristics of colorless transparent, water-proof, oil-proof, sun-prevention, high temperature resistant, chilliness resistance and easy operation, the glue may be applied at a temperature range from -30 DEG C to 110 DEG C, and it is capable of resisting summer sweltering high-temperature and winter chilliness low-temperature.
Description
Technical field
The present invention relates to the external protection film technical field of articles for use such as mechanical means, transportation means, is a kind of cleaning-free external pasting film that sticks on mechanical means, the transportation means outside surface specifically.
Background technology
In recent years, the machinery manufacturing industry fast development, the mechanical means of large quantities of various models, different style, difference in functionality, transportation means are constantly put goods on the market is applied to every field.These machineries in use because the effect of wind and weather can make the structural establishment of open work or operation, the appearance of transportation means sustain damage, even can have influence on the function of equipment.As operating automobile, train, construction machine equipment all can or be subjected to the influence of sandstorm because of wind and weather, appearance is subjected to the damage of certain program, people often are in clean and tidy state in order to make these equipment, director work-ing life, have under the very deficient situation of water resources aforesaid device be cleaned, maintains, accelerated the shortage of water resources, urban operating mechanisms such as town and country sewer line are stopped up, cause new pollution, directly influence resident's living environment.And water metallic contact direct and device outer surface can cause the oxidation corrosion of metal, the work-ing life of shortening equipment.In addition, agricultural mulching application at present is comparatively extensive, because the mulch film that existing market is sold and the peasant uses does not have degradation function, can cause a large amount of white pollutions after the use.
Summary of the invention
The present invention will solve the problems referred to above that exist in the surface protections outside such as mechanical means, transportation means; providing a kind of neither washes with water; can save time again, and can assurance equipment clean and tidy, increase the service life and degradable within a certain period of time cleaning-free external pasting film.
Technical problem of the present invention is resolved by following proposal:
A kind of cleaning-free external pasting film is manufactured for three layers by basic unit, glue-line and rete and to be formed, and wherein basic unit has flexible synthetic paper surface coated silicon layer and makes with slick:
Described rete is with 18 Vinyl Ether carboxylic acid HO-(CH
2CH
2O)
1835 parts and 10 parts Europium trichloride EuCl of-COOH
26H
2O is dissolved in respectively in the middle of 120 parts the methyl alcohol of 99% purity, mixes.Be heated to reflux state by oil bath, obtain a light yellow settled solution, in above-mentioned solution, add 80 weight part anhydrous sodium sulphate after continuing to reflux 2 hours, leave standstill B water pump filtration under diminished pressure after 5 hours, promptly remove sodium sulfate fully, filtrate is removed 2/3 solvent by the decompression rotary evaporation, obtains the white powder end after the cooling and is [HO-(CH
2CH
2O)
18-COO]
2The Eu title complex, purity is greater than 96%; Add above-mentioned gained [HO-(CH in the polyethylene of per 100 weight parts
2CH
2O)
18-COO]
2Eu title complex 1 weight part promptly obtains rete.
Described glue-line is to get 200 parts of 50 parts in graphite by 100 eye mesh screens and N-2-hydroxyethylamino amine, stirs and obtains the uniform suspension of black thickness after 10 minutes; Get above-mentioned suspension 1 weight part and add in the 49 weight part polyurethane adhesives, stir and promptly obtained light grey glue uniformly in 5 minutes, this glue is uniformly sprayed on rete, promptly form glue-line.
Film of the present invention has water white transparency, waterproof, grease proofing, sun-proof, high temperature resistant, anti-severe cold, easy-operating distinguishing feature, this film is affixed on can be plastic degradation in one month on equipment, the instrument, all the other compositions are just fallen by rain-out, so this film does not need to take off, have environment-friendly function.Glue temperature limit of the present invention can reach-30 ℃～110 ℃, can resist extremely hot high temperature and winter severe cold low temperature in summer, under the condition that temperature changes significantly, can keep not losing the cohesive force of glue, also can therefore not change the character and the form of glue, do not solidify, do not melt, thereby can not cause pad pasting to bubble, come off.Waterproof, anti-solvent ability are strong, in the environment that comprises water, alcohol, petrochemicals solvent, organic varnish, softening agent equal solvent, do not reduce cohesive force, wind resistance is strong, guarantee that pad pasting intactly is stripped from slave unit, the instrument, glue can not be retained in the surface, simultaneously can not cause any damage yet, can not cause any infringement environment and human body to enamelled coating, safe and reliable.Use this film can effectively avoid equipment, tool outer casing surface contamination, reduce scratching easy to operate, safety.The rete of this external pasting film also can use as mulch film in agriculture production, can prevent, alleviate white pollution effectively, economic environmental protection.
Embodiment
A kind of cleaning-free external pasting film is manufactured for three layers by basic unit, glue-line and rete and to be formed, and wherein basic unit has flexible synthetic paper surface coated silicon layer and makes with slick.
Described rete is 18 Vinyl Ether carboxylic acid HO-(CH with 35 weight parts
2CH
2O)
18The Europium trichloride EuCl of-COOH and 10 weight parts
26H
2O is dissolved in respectively in the middle of the methyl alcohol of 99% purity of 120 weight parts, is mixed.Be heated to reflux state by the silicone oil oil bath, (resulting product is homogeneous liquid, and is not stratified to obtain a light yellow settled solution.The anhydrous sodium sulphate that in above-mentioned solution, adds 80 weight parts after continuing to reflux 2 hours, leave standstill B water pump filtration under diminished pressure after 5 hours, can remove fully and remove sodium sulfate (sodium sulfate can be recycled after reclaiming drying), filtrate is removed 2/3 solvent (can be recycled after reclaiming drying) by the decompression rotary evaporation, obtains white powder end (a little a bit yellow is also normal) after the cooling and is [HO-(CH
2CH
2O)
18-COO]
2The Eu title complex, purity is greater than 96%; Add above-mentioned gained [HO-(CH in the polyethylene of per 100 weight parts
2CH
2O)
18-COO]
2Eu title complex 1 weight part promptly obtains rete;
Described glue-line is graphite 50 weight parts and N-2-hydroxyethylamino amine 200 weight parts of getting by 100 eye mesh screens, obtains the uniform suspension of black thickness behind the stirring 10min; Get above-mentioned suspension 1 weight part and add in the 49 weight part polyurethane adhesives, stir 5min and promptly obtain light grey glue uniformly, this glue is uniformly sprayed on rete, promptly form glue-line;
Glue-line and link base layer are crossed the adhesive bonding method that is similar to non-setting adhesive glue-line and basic unit and are combined, and obtaining the outside is rete, and the centre is a glue-line, and substrate is the product of basic unit.The user peels off glue-line and basic unit before use and gets final product.
When using, only get final product with rete as mulch film.
Below in conjunction with embodiment the present invention is described in further details:
Embodiment 1
(1) rete
Get the 18 Vinyl Ether carboxylic acid HO-(CH of 35g
2CH
2O)
18The Europium trichloride EuCl of-COOH and 10g
26H
2O is dissolved in respectively in the middle of the methyl alcohol of 99% purity of 120g, is mixed.Be heated to reflux state by the silicone oil oil bath, obtain light yellow settled solution, resulting product is homogeneous liquid, and is not stratified.Add the anhydrous sodium sulphate of 80g after continuing to reflux 2 hours in above-mentioned solution, leave standstill B water pump filtration under diminished pressure after 5 hours, can remove fully and remove sodium sulfate, sodium sulfate can be recycled after reclaiming drying.Filtrate is removed 2/3 solvent by the decompression rotary evaporation, can be recycled after the recovery drying, obtains white powder end (a little a bit yellow is also normal) after the cooling and is [HO-(CH
2CH
2O)
18-COO]
2The Eu title complex, purity is greater than 96%; Add above-mentioned gained [HO-(CH in the polyethylene of every 100g
2CH
2O)
18-COO]
2Eu title complex 1g promptly obtains rete;
(2), glue-line
Get graphite 50g and N-2-hydroxyethylamino amine 200g, obtain the uniform suspension of black thickness behind the stirring 10min by 100 eye mesh screens; Get above-mentioned suspension 1g and add in the 49g polyurethane adhesive, stir 5min and promptly obtain light grey glue uniformly, this glue is uniformly sprayed on rete, promptly form glue-line;
(3) basic unit
With the stronger synthetic paper of slick toughness, the surface coated silicon layer is made.
(4) finished product
Glue-line and link base layer are crossed the adhesive bonding method that is similar to non-setting adhesive glue-line and basic unit and are combined, and obtaining the outside is rete, and the centre is a glue-line, and substrate is the product of basic unit.
Claims (2)
1, a kind of cleaning-free external pasting film is manufactured for three layers by basic unit, glue-line and rete and to be formed, and wherein basic unit has flexible synthetic paper surface coated silicon layer and makes with slick, it is characterized in that:
Described rete is with 18 Vinyl Ether carboxylic acid HO-(CH
2CH
2O)
1835 parts and 10 parts Europium trichloride EuCl of-COOH
26H
2O is dissolved in respectively in the middle of 120 parts the methyl alcohol of 99% purity, mixes.Be heated to reflux state by oil bath, obtain light yellow settled solution, in above-mentioned solution, add 80 weight part anhydrous sodium sulphate after continuing to reflux 2 hours, leave standstill B water pump filtration under diminished pressure after 5 hours, promptly remove sodium sulfate fully, filtrate is removed 2/3 solvent by the decompression rotary evaporation, obtains the white powder end after the cooling and is [HO-(CH
2CH
2O)
18-COO]
2The Eu title complex, purity is greater than 96%; Add above-mentioned gained [HO-(CH in the polyethylene of per 100 weight parts
2CH
2O)
18-COO]
2Eu title complex 1 weight part promptly obtains rete;
Described glue-line is to get 200 parts of 50 parts in graphite by 100 eye mesh screens and N-2-hydroxyethylamino amine, stirs and obtains the uniform suspension of black thickness after 10 minutes; Get above-mentioned suspension 1 weight part and add in the 49 weight part polyurethane adhesives, stir and promptly obtained light grey glue uniformly in 5 minutes, this glue is uniformly sprayed on rete, promptly form glue-line.
2, cleaning-free external pasting film according to claim 1 is characterized in that the oil bath of described oil bath employing silicone oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910117264A CN101544873A (en) | 2009-04-26 | 2009-04-26 | Cleaning-free external pasting film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910117264A CN101544873A (en) | 2009-04-26 | 2009-04-26 | Cleaning-free external pasting film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101544873A true CN101544873A (en) | 2009-09-30 |
Family
ID=41192256
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910117264A Pending CN101544873A (en) | 2009-04-26 | 2009-04-26 | Cleaning-free external pasting film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101544873A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102039716A (en) * | 2010-11-02 | 2011-05-04 | 中科恒达石墨股份有限公司 | Method for manufacturing thermally and electrically conductive graphite ribbon |
| CN104228388A (en) * | 2014-09-30 | 2014-12-24 | 江苏奥力广告材料股份有限公司 | Advertising inkjet supply and production method thereof |
| CN104290423A (en) * | 2014-09-30 | 2015-01-21 | 江苏奥力广告材料股份有限公司 | Cold laminating film for protecting advertisement consumables and production method of cold laminating film |
-
2009
- 2009-04-26 CN CN200910117264A patent/CN101544873A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102039716A (en) * | 2010-11-02 | 2011-05-04 | 中科恒达石墨股份有限公司 | Method for manufacturing thermally and electrically conductive graphite ribbon |
| CN104228388A (en) * | 2014-09-30 | 2014-12-24 | 江苏奥力广告材料股份有限公司 | Advertising inkjet supply and production method thereof |
| CN104290423A (en) * | 2014-09-30 | 2015-01-21 | 江苏奥力广告材料股份有限公司 | Cold laminating film for protecting advertisement consumables and production method of cold laminating film |
| CN104228388B (en) * | 2014-09-30 | 2017-06-06 | 江苏奥力广告材料股份有限公司 | A kind of ink-jet advertisement consumptive material and its production method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106928901B (en) | Colorful environmental protection dust suppressant and its preparation and application | |
| CN107868616A (en) | One kind spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN103059347B (en) | Environmentally-friendly multifunctional dust suppressant and preparation method thereof | |
| CN104513561A (en) | Waterproof paint | |
| CN104497726A (en) | Sprayable diatom-based styrene-acrylic interior wall coating having humidity-regulating function and preparation method of sprayable diatom-based styrene-acrylic interior wall coating | |
| CN102409331B (en) | Chitosan modified surface treatment liquid for galvanized color-coated board and preparation method thereof | |
| CN103820020A (en) | Antiskid and antiseptic polyurea coating as well as preparation method and application method thereof | |
| CN105437691A (en) | Asphalt base pre-paved waterproof roll with protective bonding layer | |
| CN105153910A (en) | Preparing method for water-based strippable paint with modified silicon sol | |
| CN103773209A (en) | Waterproof asphalt-polyurethane paint | |
| CN101544873A (en) | Cleaning-free external pasting film | |
| CN103803854B (en) | A kind of anticorrosion waterproof rubber cement of acid and alkali-resistance and construction technology thereof | |
| CN105623336A (en) | Medical waterproof bactericidal paint and preparation method thereof | |
| CN103525216A (en) | Water-based plastic paint applicable to composite layer coating film, and preparation process thereof | |
| CN105462479A (en) | Environment-friendly weather-proof self-stratifying one-component waterproof paint and preparation method thereof | |
| CN107142014A (en) | A kind of ground anti-skid wearable coating and preparation method | |
| CN101948269A (en) | Silt adhesive and preparation method thereof | |
| CN105086807A (en) | Preparation method of nano ZnO petroleum asphalt polyurethane two-component affine waterproof paint | |
| CN101921562A (en) | Adhesive of self-adhesive layer adopting multielement monomer copolymerization and preparation method thereof | |
| CN103740183A (en) | Compound high-viscosity JS waterproof emulsion | |
| CN101429312A (en) | High-elasticity leak preventive for roofs | |
| CN103387358A (en) | Waterproof coating and preparation method thereof | |
| CN103666143A (en) | Anticracking water-based reflective road marking paint | |
| CN109608984A (en) | Anti-skidding floor coatings of Waterproof and preparation method thereof | |
| CN205439462U (en) | Asphalt base pre -paved waterproofing membrane of area protection anchor coat |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20090930 |