CN101538729A - Method for quickly restoring partial oxidation film of aluminum alloy surface - Google Patents

Method for quickly restoring partial oxidation film of aluminum alloy surface Download PDF

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Publication number
CN101538729A
CN101538729A CN200910021558A CN200910021558A CN101538729A CN 101538729 A CN101538729 A CN 101538729A CN 200910021558 A CN200910021558 A CN 200910021558A CN 200910021558 A CN200910021558 A CN 200910021558A CN 101538729 A CN101538729 A CN 101538729A
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CN
China
Prior art keywords
aluminum alloy
repaired
restored
oxidation film
electric brush
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Pending
Application number
CN200910021558A
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Chinese (zh)
Inventor
马宗耀
费敬银
谢红霞
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Northwestern Polytechnical University
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Northwestern Polytechnical University
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Priority to CN200910021558A priority Critical patent/CN101538729A/en
Publication of CN101538729A publication Critical patent/CN101538729A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a method for quickly restoring a partial oxidation film of an aluminum alloy surface. The method is characterized in that firstly, the surface of a part to be restored of an aluminum alloy piece is finished and chemically carried out oil removing; the surface of the part which is not restored of the aluminum alloy piece is shaded; the surface of the aluminum alloy piece to be restored is electrically cleaned to remove the oil; oxidation film restoration is carried out on the surface of the aluminum alloy piece to be restored by an electric brush coating pen; and after being washed with tap water, the restored surface is sprayed with polyurethane paint and is aired. Because the part to be restored of the aluminum alloy piece is used as an anode and the electric brush coating pen is used as a cathode and dips into an electrolytic solution, direct current voltage is applied between the anode and the cathode so as to ensure that the anode on the surface of the aluminum alloy piece, which is to be restored is oxidized so as to form an oxidation film, thereby partially and quickly restoring the oxidation film of the aluminum alloy surface. The piece to be restored does not need to be disassembled and a special oxidation tank is not needed.

Description

Method for quickly restoring partial oxidation film of aluminum alloy surface
Technical field
The present invention relates to a kind of surface repairing method, particularly method for quickly restoring partial oxidation film of aluminum alloy surface.
Background technology
Artificial oxidation's rete on large aluminum alloy surfaces such as aircraft skin, freight container or billboard; because scratch or other reasons; phenomenons such as the partial fracture of regular meeting's generation oxide film, damage; directly influence protection against corrosion or decorative effect on the one hand; can cause structure deteriorate on the other hand; and therefore can constitute potential safety hazard, threaten the safe handling of aircraft or Al-alloy products parts.
Existing solution partial oxidation film of aluminum alloy surface breaks, damages the method that adopts, and with Al-alloy parts dismounting to be repaired, oxidation again in special-purpose oxidation trough forms complete oxidation film layer.This method is treated repair member dismantles except needs, also needs a special-purpose oxidation trough.
Summary of the invention
Need treat the deficiency that repair member is dismantled, needed complex processes such as special-purpose oxidation trough in order to overcome prior art, the invention provides a kind of method for quickly restoring partial oxidation film of aluminum alloy surface, with position to be repaired as anode, the electric brush plating pen is as negative electrode and dip in and get electrolytic solution, between cathode and anode, apply volts DS, can make aluminum alloy surface anode electrolysis to be repaired oxidation and form oxidation film layer, repair the aluminum alloy surface oxide film fast thereby reach local, and need not treat repair member and dismantle, do not need special-purpose oxidation trough.
The technical solution adopted for the present invention to solve the technical problems: a kind of method for quickly restoring partial oxidation film of aluminum alloy surface is characterized in comprising the steps:
(a) also clean Al-alloy parts part surface to be repaired repeatedly with the organic solvent infiltration, remove the remained on surface coat of painting; Successively with 600# and 800 #Abrasive paper for metallograph polishes off Al-alloy parts part surface corrosion layer to be repaired, cleans with raw spirit then and removes surface and oil contaminant and dust;
(b) with terylene adhesive tape or chlorinated polyvinyl chloride adhesive tape firmly, closely overlay masking is lived the non-reparation part surface of Al-alloy parts, reserves position to be repaired;
(c) to be repaired of aluminium alloy is linked to each other with power cathode, the electric brush plating pen links to each other with positive source, voltage of supply 8~10V, the electric brush plating pen dip in get degreasing fluid on to be repaired surface of aluminium alloy and around move repeatedly, translational speed keeps 10~12m/min, operation 0.5~1.5min, and the degreasing fluid of aluminum alloy surface being detained with tap water is rinsed well repeatedly then, require the surface good, no fluidization tower or extension globule phenomenon to the wettability of water;
(d) to be repaired of aluminium alloy is connect positive source, the electric brush plating pen connects power cathode, voltage of supply 16~20V, dip in brush electric brush plating pen and to get sulfuric acid oxidation solution, move repeatedly on to be repaired surface of aluminium alloy, translational speed keeps 3~6m/min, operation 15~20min; In this process, the electric brush plating pen must maintain competent sulfuric acid oxidation solution;
(e) behind the EO, rinse out the residual sulphur acid oxidase solution on to be repaired surface of aluminium alloy, and dip in the distilled water wipe surfaces, dry in the shade with soft cloth with tap water;
(f) the aluminum alloy surface spraying polyurethane after the oxide film reparation coats with lacquer and dries.
Described degreasing fluid is prepared by first water, and wherein each component content: NaOH is 20~30g/l, Na 2CO 3Be 20~35g/l.
Described sulfuric acid oxidation solution is the first water preparation, H 2SO 4Mass percent concentration is 18~20%.
The invention has the beneficial effects as follows: since with position to be repaired as anode, the electric brush plating pen is as negative electrode and dip in and get electrolytic solution, between cathode and anode, apply volts DS, can make aluminum alloy surface anode electrolysis to be repaired oxidation and form oxidation film layer, repair the aluminum alloy surface oxide film fast thereby reach local, and need not treat repair member and dismantle, do not need special-purpose oxidation trough.
Below in conjunction with embodiment the present invention is elaborated.
Embodiment
Certain many airplane in aeroshow shop, many places, aircraft skin surface occur that coat of painting comes off, lead-covering surface film oxide disrepair phenomenon, this not only influences the specious of aircraft, and if do not carry out repair process timely, corrosion can further expand makes that covering penetrates, aircraft structure connects that causing lost efficacy causes destroying.For this reason, aircraft skin superficial film destruction place needs oxidation again to repair rotproofing.Adopt conventional restorative procedure, to be repaired need be disassembled and send producer in special oxidation trough, to carry out oxide treatment.Owing to aircraft structure aspect reason, actually operating dismantling technology difficulty is on the one hand had relatively high expectations, and has inevitably damage, distortion on the other hand in the process of dismounting, oxidation and installation subsequently again; And this process cycle is longer, needs finish in 8~12 days at least; And must guarantee non-reparation position good insulation operation in the oxidising process, otherwise can cause to be repaired to scrap.
The present invention adopts the electric brush plating pen to carry out partial oxidation film and repairs fast, has realized the reparation to aluminium alloy aircraft skin partial oxidation film, and is time saving and energy saving.
The first step, position to be repaired surfacing and electrochemical deoiling: dip in gasoline or organic solvents such as alcohol or lacquer thinner with cotton yarn, soak into also and clean Al-alloy parts part surface to be repaired repeatedly, remove the remained on surface coat of painting; Successively with 600# and 800 #Abrasive paper for metallograph polishes off Al-alloy parts part surface corrosion layer to be repaired, dips in degreasing cotton then and gets raw spirit scouring removal surface and oil contaminant and dust.
In second step, cover: according to required reparation size, that firmly, closely overlay masking is lived non-reparation is surperficial with terylene adhesive tape or chlorinated polyvinyl chloride adhesive tape, to carry out insulation protection, reserves position to be repaired, causes pollution to prevent that water solution from trickling to non-reparation surface.
The 3rd step, the clean oil removing of electricity: to be repaired of aluminium alloy is linked to each other with power cathode, the electric brush plating pen links to each other with positive source, voltage of supply 8~10V, electric brush plating pen dip in get degreasing fluid on to be repaired surface of aluminium alloy and around move repeatedly, translational speed keeps 10~12m/min, operation 0.5~1.5min gets final product, the degreasing fluid of aluminum alloy surface being detained with tap water is rinsed well repeatedly then, and deoiling effect requires the surface good to the wettability of water, no fluidization tower or extension globule phenomenon.
Degreasing fluid is prepared by first water, and wherein each component content is: sodium hydroxide (NaOH) 20~30g/l, yellow soda ash (Na 2CO 3) 20~35g/l.
The 4th step, the brush oxide film is repaired: to be repaired of aluminium alloy is connect positive source, the electric brush plating pen connects power cathode, voltage of supply 16~20V, dip in brush electric brush plating pen and to get sulfuric acid oxidation solution, move repeatedly on to be repaired surface of aluminium alloy, translational speed keeps 3~6m/min, operation 15~20min.In this process, the electric brush plating pen must maintain competent sulfuric acid oxidation solution.
Sulfuric acid oxidation solution is the first water preparation, H 2SO 4Mass percent concentration is 18~20%.
In the 5th step, clean and dry: after the brush oxidation operation finishes, rinse out the residual sulphur acid oxidase solution on to be repaired surface of aluminium alloy, and dip in the distilled water wipe surfaces, dry in the shade with soft cloth with tap water.
In the 6th step, japanning: the aluminum alloy outer cover surface after the brush anodic oxidation is coated with lacquer twice processing and is dried through spraying polyurethane.
Used power supply is a D.C. regulated power supply, output current scope 0~10A, voltage 0~50V.In clean oil removing of above-mentioned electricity and brush oxide film repair process, possesses the positive and negative electrode commutation function.
Brush is coated with pen and is the pure stereotype of bar shaped, and the surface coats with polypropylene fabric or terylene tire.

Claims (3)

1, a kind of method for quickly restoring partial oxidation film of aluminum alloy surface is characterized in that comprising the steps:
(a) also clean Al-alloy parts part surface to be repaired repeatedly with the organic solvent infiltration, remove the remained on surface coat of painting; Successively with 600# and 800 #Abrasive paper for metallograph polishes off Al-alloy parts part surface corrosion layer to be repaired, cleans with raw spirit then and removes surface and oil contaminant and dust;
(b) with terylene adhesive tape or chlorinated polyvinyl chloride adhesive tape firmly, closely overlay masking is lived the non-reparation part surface of Al-alloy parts, reserves position to be repaired;
(c) to be repaired of aluminium alloy is linked to each other with power cathode, the electric brush plating pen links to each other with positive source, voltage of supply 8~10V, the electric brush plating pen dip in get degreasing fluid on to be repaired surface of aluminium alloy and around move repeatedly, translational speed keeps 10~12m/min, operation 0.5~1.5min, and the degreasing fluid of aluminum alloy surface being detained with tap water is rinsed well repeatedly then, require the surface good, no fluidization tower or extension globule phenomenon to the wettability of water;
(d) to be repaired of aluminium alloy is connect positive source, the electric brush plating pen connects power cathode, voltage of supply 16~20V, dip in brush electric brush plating pen and to get sulfuric acid oxidation solution, move repeatedly on to be repaired surface of aluminium alloy, translational speed keeps 3~6m/min, operation 15~20min; In this process, the electric brush plating pen must maintain competent sulfuric acid oxidation solution;
(e) behind the EO, rinse out the residual sulphur acid oxidase solution on to be repaired surface of aluminium alloy, and dip in the distilled water wipe surfaces, dry in the shade with soft cloth with tap water;
(f) the aluminum alloy surface spraying polyurethane after the oxide film reparation coats with lacquer and dries.
2, according to the described method for quickly restoring partial oxidation film of aluminum alloy surface of claim 1, it is characterized in that: described degreasing fluid is prepared by first water, and wherein each component content: NaOH is 20~30g/l, Na 2CO 3Be 20~35g/l.
3, according to the described method for quickly restoring partial oxidation film of aluminum alloy surface of claim 1, it is characterized in that: described sulfuric acid oxidation solution is the first water preparation, H 2SO 4Mass percent concentration is 18~20%.
CN200910021558A 2009-03-17 2009-03-17 Method for quickly restoring partial oxidation film of aluminum alloy surface Pending CN101538729A (en)

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CN200910021558A CN101538729A (en) 2009-03-17 2009-03-17 Method for quickly restoring partial oxidation film of aluminum alloy surface

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Application Number Priority Date Filing Date Title
CN200910021558A CN101538729A (en) 2009-03-17 2009-03-17 Method for quickly restoring partial oxidation film of aluminum alloy surface

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CN101538729A true CN101538729A (en) 2009-09-23

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102605406A (en) * 2012-04-01 2012-07-25 哈尔滨飞机工业集团有限责任公司 Surface local electric brushing anodization film pre-treatment method for aluminum alloy parts
CN103556202A (en) * 2013-11-20 2014-02-05 沈阳工业大学 Implementation method of anodic oxidation employing titanium alloy contact method
CN104070000A (en) * 2013-03-29 2014-10-01 东莞市永强汽车制造有限公司 Coating method capable of maintaining original color of aluminum alloy tanker
CN104947168A (en) * 2015-06-18 2015-09-30 哈尔滨工程大学 Repair method of zirconium base film on surface of magnesium alloy
CN105683423A (en) * 2013-09-26 2016-06-15 弗劳恩霍夫应用研究促进协会 Method for structuring layers of oxidizable materials by means of oxidation and substrate having a structured coating
CN105696053A (en) * 2016-04-11 2016-06-22 中国南方航空工业(集团)有限公司 Protection method for non-cemented anodized surface of aluminum alloy part
CN109402698A (en) * 2018-12-26 2019-03-01 无锡市五十五度科技有限公司 A kind of method of aluminium workpiece surface local anodic oxidation
CN109440161A (en) * 2018-12-20 2019-03-08 贵州航天南海科技有限责任公司 A kind of parts locally sulphuric acid anodizing device and its use technique
CN111560639A (en) * 2019-02-13 2020-08-21 日本爱发科泰克能株式会社 Method for regenerating oxide film of aluminum member
CN114411136A (en) * 2021-12-17 2022-04-29 东北大学 Device and method for smearing and repairing phosphate conversion film
CN114789323A (en) * 2022-04-26 2022-07-26 广东长盈精密技术有限公司 Reworking and repairing method for keyboard surface of notebook computer

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102605406A (en) * 2012-04-01 2012-07-25 哈尔滨飞机工业集团有限责任公司 Surface local electric brushing anodization film pre-treatment method for aluminum alloy parts
CN104070000B (en) * 2013-03-29 2016-02-03 东莞市永强汽车制造有限公司 A kind of coating process keeping aluminium alloy tank car primary colors
CN104070000A (en) * 2013-03-29 2014-10-01 东莞市永强汽车制造有限公司 Coating method capable of maintaining original color of aluminum alloy tanker
CN105683423B (en) * 2013-09-26 2018-06-29 弗劳恩霍夫应用研究促进协会 The method for building oxidizable material layer by aoxidizing and the substrate with constructed coating
CN105683423A (en) * 2013-09-26 2016-06-15 弗劳恩霍夫应用研究促进协会 Method for structuring layers of oxidizable materials by means of oxidation and substrate having a structured coating
CN103556202A (en) * 2013-11-20 2014-02-05 沈阳工业大学 Implementation method of anodic oxidation employing titanium alloy contact method
CN104947168A (en) * 2015-06-18 2015-09-30 哈尔滨工程大学 Repair method of zirconium base film on surface of magnesium alloy
CN104947168B (en) * 2015-06-18 2017-08-08 哈尔滨工程大学 The restorative procedure of zirconium base film on Mg alloy surface
CN105696053A (en) * 2016-04-11 2016-06-22 中国南方航空工业(集团)有限公司 Protection method for non-cemented anodized surface of aluminum alloy part
CN105696053B (en) * 2016-04-11 2019-04-16 中国南方航空工业(集团)有限公司 The guard method of the non-rigid anodized surface of aluminum alloy part
CN109440161A (en) * 2018-12-20 2019-03-08 贵州航天南海科技有限责任公司 A kind of parts locally sulphuric acid anodizing device and its use technique
CN109402698A (en) * 2018-12-26 2019-03-01 无锡市五十五度科技有限公司 A kind of method of aluminium workpiece surface local anodic oxidation
CN111560639A (en) * 2019-02-13 2020-08-21 日本爱发科泰克能株式会社 Method for regenerating oxide film of aluminum member
JP2020132895A (en) * 2019-02-13 2020-08-31 アルバックテクノ株式会社 Method for regenerating oxide film of component made of aluminum
JP7218201B2 (en) 2019-02-13 2023-02-06 アルバックテクノ株式会社 Method for regenerating oxide film on aluminum parts
CN114411136A (en) * 2021-12-17 2022-04-29 东北大学 Device and method for smearing and repairing phosphate conversion film
CN114789323A (en) * 2022-04-26 2022-07-26 广东长盈精密技术有限公司 Reworking and repairing method for keyboard surface of notebook computer
CN114789323B (en) * 2022-04-26 2023-09-29 广东长盈精密技术有限公司 Reworking and repairing method for keyboard surface of notebook computer

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Open date: 20090923