CN101537680A - Preparation method of conveyor belt disrepair patch - Google Patents

Preparation method of conveyor belt disrepair patch Download PDF

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Publication number
CN101537680A
CN101537680A CN200910083210A CN200910083210A CN101537680A CN 101537680 A CN101537680 A CN 101537680A CN 200910083210 A CN200910083210 A CN 200910083210A CN 200910083210 A CN200910083210 A CN 200910083210A CN 101537680 A CN101537680 A CN 101537680A
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China
Prior art keywords
parts
sheet rubber
rubber
wear
resistant surface
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CN200910083210A
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CN101537680B (en
Inventor
刘洁
王兵
李印柏
林新松
翟海潮
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Beijing Tianshan New Material Technology Co ltd
BEIJING TONSAN ADHESIVES Inc
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BEIJING TIANSHAN NEW MATERIALS AND TECHNOLOGY Co Ltd
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Publication of CN101537680A publication Critical patent/CN101537680A/en
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Publication of CN101537680B publication Critical patent/CN101537680B/en
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Abstract

The invention provides a preparation method of a conveyor belt disrepair patch. Vulcanization is employed to prepare sheet rubber with wear-resistant surface and sheet rubber with adhesive surface; the sheet rubber with wear-resistant surface is placed in a die of a vulcanizing machine and the temperature of the vulcanizing machine is set at 150 DEG C while the pressure of the vulcanizing machine is adjusted at 5MPa; the sheet rubber with wear-resistant surface in the die is vulcanized for 5 minutes; the sheet rubber with adhesive surface is then placed under the sheet rubber with wear-resistant surface and the temperature of the vulcanizing machine is set at 150 DEG C while the pressure of the vulcanizing machine is set at 5MPa, and the sheet rubber with adhesive surface is vulcanized for 5 minutes; the pressure of the vulcanizing machine is then set at 15MPa and the vulcanizing temperature is kept at 150 DEG C for vulcanizing continuously for 5 minutes. The reaction between a semi-cure layer and a rubber cementing compound is used for improving the adherence intensity of cold sticking repair while obtaining the repair effect as excellent as hot sticking.

Description

A kind of preparation method of conveyor belt disrepair patch
Technical field
The present invention relates to a kind of preparation method of conveyor belt disrepair patch.
Background technology
The method of repairing the conveyer belt breakage in the market mainly contains: vulcanize hot sticky method and cold bonding method for repairing and mending.The method of wherein vulcanizing hot sticky repairing is the place that is placed on the conveyer belt breakage with the raw stock that mixes in advance, uses the vulcanizer baking, thereby reaches the repairing purpose.But hot sticky repairing exists shortcomings such as curing temperature height, length of bonding time, complex process, cost height.The method that cold bonding is repaired mainly is several all over bottoming in the breakage brushing with rubber adhesive, be placed on breakage with the rubber skin (brushing rubber adhesive) of conveyer belt cover layer material or with high-strength rubber repair sheets stick then, can reach the repairing purpose in several hours according to instructions for use curing, but because the adhesive strength of its repairing is less than the hot sticky method of sulfuration, conveyer belt will lack in service life after the repairing with respect to hot sticky method, sheet rubber or the rubber healant of repairing breakage in 3 months even shorter time will come off, damaged place still need be repaired, influence user's production efficiency, increased user's maintenance cost.
Summary of the invention
The present invention is in order to overcome the deficiencies in the prior art, a kind of utilization sulfuration preparation method is provided, make the conveyor belt disrepair patch that bonding plane is the semi-cure layer, utilize the reaction between semi-cure layer and the rubber based adhesives, improved the adhesive strength that cold bonding is repaired, and reached preparation method with the conveyor belt disrepair patch of the identical repair efficiency of hot sticky method.
In order to realize above-mentioned purpose, the present invention is that wear-resistant surface sheet rubber and bonding plane sheet rubber overlay up and down in the mould of vulcanizer and vulcanize, and concrete steps are:
(a) successively acrylonitrile-butadiene rubber, sulphur, magnesia, zinc oxide, anti-aging agent RD, semi-reinforcing furnace black, softening agent, terpene phenolic resin, accelerant CZ, promoter TT are added the roller temperature and be set in 40~50 ℃ the rubber mixing machine evenly that mixing 20~25min generates described wear-resistant surface sheet rubber;
(b) successively neoprene, acrylonitrile-butadiene rubber, magnesia, antioxidant A, pigment, white carbon, softening agent, fine particle calcium carbonate, terpene phenolic resin, accelerant N A22, zinc oxide are added the roller temperature and be set in 40~45 ℃ of rubber mixing machines evenly that mixing 15~20min generates described bonding plane sheet rubber;
(c) getting above-mentioned wear-resistant surface sheet rubber is placed in the mould of vulcanizer, transfer to the vulcanizer temperature and be arranged on 150 ℃, pressure transfers to 5MPa, behind wear-resistant surface sheet rubber sulfuration 5min in the mould, gets above-mentioned bonding plane sheet rubber again and is placed on wear-resistant surface sheet rubber below, the vulcanizer temperature is set at 150 ℃, pressure is provided with 5MPa, and sulfuration 5min transfers vulcanizer pressure to 15MPa again, keep curing temperature at 150 ℃, proceed to vulcanize 5min.
The composition of above-mentioned wear-resistant film is made up of following material by weight: 80~100 parts of acrylonitrile-butadiene rubbers, 1~3 part in sulphur, 2~6 parts in magnesia, 2~6 parts in zinc oxide, 1~2 part of anti-aging agent RD, 70~100 parts of semi-reinforcing furnace black, 10~20 parts of softening agents, 10~20 parts of terpene phenolic resins, 0.2~0.7 part of accelerant CZ, 0.2~0.7 part of promoter TT.
The composition of above-mentioned bonding plane sheet rubber is made up of following material by weight: 2~6 parts in 60~80 parts of neoprenes, 20~40 parts of acrylonitrile-butadiene rubbers, 2~6 parts in magnesia, 1~5 part of antioxidant A, 0.2~0.6 part of pigment, 10~20 parts of white carbons, 5~10 parts of softening agents, 30~70 parts of fine particle calcium carbonates, 10~20 parts of terpene phenolic resins, accelerant N A220.3~0.8 part, zinc oxide.
Above-mentioned softening agent is a kind of in dibutyl phthalate, o-phthalic acid dibutyl ester, dioctyl adipate, di-n-octyl sebacate, dibutyl sebacate, tricresyl phosphate and the tricresyl phosphate butyl 2-ethoxyethyl acetate.
The invention has the beneficial effects as follows the rubber skin or the high-strength rubber repair sheets stick that substitute the conveyer belt cover layer material in the cold bonding repairing with the patch among the present invention, rubber adhesive of bonding plane brushing is placed on the conveyer belt breakage.Can reach the cold bonding repair technology simple, easy to operate, need not that large-scale vulcanizing equipment, bonding expense are low, the time short, the efficient advantages of higher time, also can guarantee with the suitable repairing adhesive strength of the hot sticky method of sulfuration, thereby can prolong conveyer belt service life, can improve user's production efficiency and save certain maintenance cost.
The specific embodiment
Below in conjunction with specific embodiment, further the present invention is made detailed description:
Embodiment 1
The first step adds 100 parts of acrylonitrile-butadiene rubbers, 3 parts in sulphur, 2 parts in magnesia, 2 parts in zinc oxide, 1 part of anti-aging agent RD, 70 parts of semi-reinforcing furnace black, 10 parts of softening agents, 10 parts of terpene phenolic resins, 0.2 part of accelerant CZ, promoter TT0.4 part the roller temperature successively and is set in that even mixing 25min generates described wear-resistant surface sheet rubber in 40~50 ℃ the rubber mixing machine.
In second step, successively 6 parts of 60 parts of neoprenes, 40 parts of acrylonitrile-butadiene rubbers, 3 parts in magnesia, 3 parts of antioxidant As, 0.6 part of pigment, 20 parts of white carbons, 10 parts of softening agents, 70 parts of fine particle calcium carbonates, 20 parts of terpene phenolic resins, accelerant N A220.4 part, zinc oxide are added the roller temperature and be set in that even mixing 15min generates described bonding plane sheet rubber in 40~45 ℃ of rubber mixing machines.
The 3rd step got above-mentioned first step generation wear-resistant surface sheet rubber and is placed in the mould of vulcanizer, transfer to the vulcanizer temperature and be arranged on 150 ℃, pressure transfers to 5MPa, behind wear-resistant surface sheet rubber sulfuration 5min in the mould, get the above-mentioned second step bonding plane sheet rubber again and be placed on wear-resistant surface sheet rubber below, the vulcanizer temperature is set at 150 ℃, pressure 5MPa is set, sulfuration 5min, transfer vulcanizer pressure to 15MPa again, keep curing temperature at 150 ℃, proceed to vulcanize 5min, generate described conveyor belt disrepair patch.
Embodiment 2
The first step adds 80 parts of acrylonitrile-butadiene rubbers, 2 parts in sulphur, 6 parts in magnesia, 6 parts in zinc oxide, 2 parts of anti-aging agent RDs, 90 parts of semi-reinforcing furnace black, 15 parts of softening agents, 20 parts of terpene phenolic resins, 0.3 part of accelerant CZ, promoter TT0.4 part the roller temperature successively and is set in that even mixing 20min generates described wear-resistant surface sheet rubber in 40~50 ℃ the rubber mixing machine.
In second step, successively 2 parts of 80 parts of neoprenes, 20 parts of acrylonitrile-butadiene rubbers, 3 parts in magnesia, antioxidant A l part, 0.2 part of pigment, 12 parts of white carbons, 8 parts of softening agents, 30 parts of fine particle calcium carbonates, 10 parts of terpene phenolic resins, accelerant N A220.5 part, zinc oxide are added the roller temperature and be set in that even mixing 20min generates described bonding plane sheet rubber in 40~45 ℃ of rubber mixing machines.
The 3rd step is the same with three step process method in the above-mentioned example 1.
Embodiment 3
The first step adds 90 parts of acrylonitrile-butadiene rubbers, 2 parts in sulphur, 4 parts in magnesia, 4 parts in zinc oxide, 1.5 parts of anti-aging agent RDs, 85 parts of semi-reinforcing furnace black, 15 parts of softening agents, 15 parts of terpene phenolic resins, 0.5 part of accelerant CZ, promoter TT0.3 part the roller temperature successively and is set in that even mixing 23min generates described wear-resistant surface sheet rubber in 40~50 ℃ the rubber mixing machine.
In second step, successively 4 parts of 70 parts of neoprenes, 30 parts of acrylonitrile-butadiene rubbers, 4 parts in magnesia, 3 parts of antioxidant As, 0.4 part of pigment, 15 parts of white carbons, 8 parts of softening agents, 55 parts of fine particle calcium carbonates, 15 parts of terpene phenolic resins, accelerant N A220.3 part, zinc oxide are added the roller temperature and be set in that even mixing 17min generates described bonding plane sheet rubber in 40~45 ℃ of rubber mixing machines.
The 3rd step is the same with three step process method in the foregoing description 1.

Claims (4)

1, a kind of preparation method of conveyor belt disrepair patch, comprising that wear-resistant surface sheet rubber and bonding plane sheet rubber overlay up and down in the mould of vulcanizer vulcanizes, and concrete steps are:
(a) successively acrylonitrile-butadiene rubber, sulphur, magnesia, zinc oxide, anti-aging agent RD, semi-reinforcing furnace black, softening agent, terpene phenolic resin, accelerant CZ, promoter TT are added the roller temperature and be set in 40~50 ℃ the rubber mixing machine evenly that mixing 20~25min generates described wear-resistant surface sheet rubber;
(b) successively neoprene, acrylonitrile-butadiene rubber, magnesia, antioxidant A, pigment, white carbon, softening agent, fine particle calcium carbonate, terpene phenolic resin, accelerant N A22, zinc oxide are added the roller temperature and be set in 40~45 ℃ of rubber mixing machines evenly that mixing 15~20min generates described bonding plane sheet rubber;
(c) getting above-mentioned wear-resistant surface sheet rubber is placed in the mould of vulcanizer, transfer to the vulcanizer temperature at 150 ℃, pressure transfers to 5MPa, behind wear-resistant surface sheet rubber sulfuration 5min in the mould, gets above-mentioned bonding plane sheet rubber again and is placed on wear-resistant surface sheet rubber below, the vulcanizer temperature is set at 150 ℃, pressure 5MPa is set, and sulfuration 5min transfers sulfide stress to 15MPa again, keep curing temperature at 150 ℃, continue sulfuration 5min and generate described conveyor belt disrepair patch.
2, according to the preparation method of the described a kind of conveyor belt disrepair patch of claim 1, it is characterized in that: the composition of described wear-resistant surface sheet rubber is made up of following material by weight:
80~100 parts of acrylonitrile-butadiene rubbers, 1~3 part in sulphur, 2~6 parts in magnesia, 2~6 parts in zinc oxide, 1~2 part of anti-aging agent RD, 70~100 parts of semi-reinforcing furnace black, 10~20 parts of softening agents, 10~20 parts of terpene phenolic resins, 0.2~0.7 part of accelerant CZ, 0.2~0.7 part of promoter TT.
3,, it is characterized in that the composition of described bonding plane sheet rubber is made up of following material by weight according to the preparation method of the described a kind of conveyor belt disrepair patch of claim 1:
2~6 parts in 60~80 parts of neoprenes, 20~40 parts of acrylonitrile-butadiene rubbers, 2~6 parts in magnesia, 1~5 part of antioxidant A, 0.2~0.6 part of pigment, 10~20 parts of white carbons, 5~10 parts of softening agents, 30~70 parts of fine particle calcium carbonates, 10~20 parts of terpene phenolic resins, accelerant N A220.3~0.8 part, zinc oxide.
4, according to the preparation method of claim 1 or 2 or 3 described a kind of conveyor belt disrepair patch, it is characterized in that: described softening agent is a kind of in dibutyl phthalate, o-phthalic acid dibutyl ester, dioctyl adipate, di-n-octyl sebacate, dibutyl sebacate, tricresyl phosphate and the tricresyl phosphate butyl 2-ethoxyethyl acetate.
CN2009100832100A 2009-04-29 2009-04-29 Preparation method of conveyor belt disrepair patch Expired - Fee Related CN101537680B (en)

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CN101537680B CN101537680B (en) 2010-12-08

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102211411A (en) * 2011-03-03 2011-10-12 新兴铸管股份有限公司 Method for repairing broken belt with large inclination angle
CN102863665A (en) * 2012-09-27 2013-01-09 青岛开世密封工业有限公司 Chloroprene rubber mixed compound nonstick to rolls and method for preparing chloroprene rubber mixed compound
CN103465482A (en) * 2013-08-23 2013-12-25 石家庄德乃福科技有限公司 Method for repairing mechanical damage of radial tire
CN103694509A (en) * 2013-10-28 2014-04-02 北京天山新材料技术股份有限公司 Conveyer belt damage repairing strip with reinforcing layer and preparation method thereof
CN104249465A (en) * 2013-06-30 2014-12-31 周中平 Repairing technology for rubber crawler belt
CN108638544A (en) * 2018-04-16 2018-10-12 湖北三江航天江北机械工程有限公司 Solid Rocket Motor Fiber Composite Material Shell internal insulation cold bonding method for repairing and mending
CN109834953A (en) * 2017-11-28 2019-06-04 邢台岭森耐磨材料有限公司 A kind of process producing cold cure layer polyurethane repair strip
CN115350885A (en) * 2022-08-25 2022-11-18 奇瑞汽车股份有限公司 Process for repairing rusted through hole of automobile body

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102211411A (en) * 2011-03-03 2011-10-12 新兴铸管股份有限公司 Method for repairing broken belt with large inclination angle
CN102863665A (en) * 2012-09-27 2013-01-09 青岛开世密封工业有限公司 Chloroprene rubber mixed compound nonstick to rolls and method for preparing chloroprene rubber mixed compound
CN102863665B (en) * 2012-09-27 2014-10-29 青岛开世密封工业有限公司 Chloroprene rubber mixed compound nonstick to rolls and method for preparing chloroprene rubber mixed compound
CN104249465A (en) * 2013-06-30 2014-12-31 周中平 Repairing technology for rubber crawler belt
CN103465482A (en) * 2013-08-23 2013-12-25 石家庄德乃福科技有限公司 Method for repairing mechanical damage of radial tire
CN103694509A (en) * 2013-10-28 2014-04-02 北京天山新材料技术股份有限公司 Conveyer belt damage repairing strip with reinforcing layer and preparation method thereof
CN103694509B (en) * 2013-10-28 2015-09-23 北京天山新材料技术有限公司 A kind of band enhancement Layer damages of conveyor belt repairs bar and preparation method thereof
CN109834953A (en) * 2017-11-28 2019-06-04 邢台岭森耐磨材料有限公司 A kind of process producing cold cure layer polyurethane repair strip
CN108638544A (en) * 2018-04-16 2018-10-12 湖北三江航天江北机械工程有限公司 Solid Rocket Motor Fiber Composite Material Shell internal insulation cold bonding method for repairing and mending
CN115350885A (en) * 2022-08-25 2022-11-18 奇瑞汽车股份有限公司 Process for repairing rusted through hole of automobile body

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Granted publication date: 20101208

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