CN101517695A - Short wavelength ultraviolet discharge lamp and ultraviolet ray irradiator - Google Patents

Short wavelength ultraviolet discharge lamp and ultraviolet ray irradiator Download PDF

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Publication number
CN101517695A
CN101517695A CNA2007800357676A CN200780035767A CN101517695A CN 101517695 A CN101517695 A CN 101517695A CN A2007800357676 A CNA2007800357676 A CN A2007800357676A CN 200780035767 A CN200780035767 A CN 200780035767A CN 101517695 A CN101517695 A CN 101517695A
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CN
China
Prior art keywords
discharge lamp
short wavelength
lead
fluororesin
wavelength ultraviolet
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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CNA2007800357676A
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Chinese (zh)
Inventor
中野浩二
江村浩司
角谷祐公
辻中则子
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NIPPON PHOTOELECTRIC SCIENCE AND TECH Ltd
Photoscience Japan Corp
Kurita Water Industries Ltd
Original Assignee
NIPPON PHOTOELECTRIC SCIENCE AND TECH Ltd
Kurita Water Industries Ltd
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Application filed by NIPPON PHOTOELECTRIC SCIENCE AND TECH Ltd, Kurita Water Industries Ltd filed Critical NIPPON PHOTOELECTRIC SCIENCE AND TECH Ltd
Publication of CN101517695A publication Critical patent/CN101517695A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122Incoherent waves
    • B01J19/123Ultra-violet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325Irradiation devices or lamp constructions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J29/00Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
    • H01J29/02Electrodes; Screens; Mounting, supporting, spacing or insulating thereof
    • H01J29/10Screens on or from which an image or pattern is formed, picked up, converted or stored
    • H01J29/18Luminescent screens
    • H01J29/182Luminescent screens acting upon the lighting-up of the luminescent material other than by the composition of the luminescent material, e.g. by infra red or UV radiation, heating or electric fields
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J5/00Details relating to vessels or to leading-in conductors common to two or more basic types of discharge tubes or lamps
    • H01J5/50Means forming part of the tube or lamps for the purpose of providing electrical connection to it
    • H01J5/54Means forming part of the tube or lamps for the purpose of providing electrical connection to it supported by a separate part, e.g. base
    • H01J5/62Connection of wires protruding from the vessel to connectors carried by the separate part
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873Materials to be treated
    • B01J2219/0877Liquid
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2231/00Cathode ray tubes or electron beam tubes
    • H01J2231/50Imaging and conversion tubes
    • H01J2231/50005Imaging and conversion tubes characterised by form of illumination
    • H01J2231/5001Photons
    • H01J2231/50015Light
    • H01J2231/50021Ultra-violet

Abstract

The invention provides a short wavelength ultraviolet discharge lamp and an ultraviolet ray irradiator. In the ultraviolet discharge lamp comprising an insulated conductor coated with a fluororesin and radiating ultraviolet-rays having a wavelength of 220 nm or less, the generation of hydrogen fluoride and hydrofluoric acid harmful to the human body and causing reduction in quantity of radiation light is suppressed. The discharge lamp comprises a quartz glass tube (31), a pair of electrodes (32a, 32b) arranged at the opposite ends thereof, and a lead wire (60) extending along the outer wall of the quartz glass tube. The lead wire is obtained by covering an insulated conductor coated with an insulator composed of a fluororesin with a metal outer layer material. Since the fluororesin is not irradiated with ultraviolet rays while the lead wire is irradiated with ultraviolet-rays, hydrogen fluoride and hydrofluoric acid are not generated.

Description

Short wavelength ultraviolet discharge lamp and ultraviolet irradiation treatment device
Technical field
The present invention relates to the luminous short wavelength ultraviolet discharge lamp of the wave-length coverage below 220nm at least and be equipped with this discharge lamp and utilize from the ultraviolet ultraviolet irradiation treatment device that discharge lamp radiated.
Background technology
The ultraviolet ray of short wavelength range is used for nuisance, organic decomposition and sterilization etc.Especially, the ultraviolet ray of the following wave-length coverage of 220nm has the energy of decomposing H-OH, thereby is applied in being used for the organic ultraviolet irradiation treatment device that decomposition water comprises.
Fig. 7 shows the example of ultraviolet irradiation treatment device in the past.Fig. 7 is the cutaway view that schematically shows the structure of ultraviolet irradiation treatment device in the past.
In Fig. 7, symbol 1 expression stainless steel cylinders (cylinder), its two ends are sealed by ring flange 7a, 7b.Processed water 5 is from the ring flange 7d side flow of the ring flange 7c side direction delivery port of water inlet, but, in cylindrical shell 1, on its axis, dispose a plurality of discoid back flow plate 6a, 6b, 6c, 6d, the 6e of perforate for the short circuit (short pass) that prevents processed water 5 with separating predetermined space.
Symbol 4 is short wavelength ultraviolet discharge lamp (hereinafter referred to as discharge lamps), and radiation comprises the ultraviolet ray of the following wavelength of 220nm at interior light.As this discharge lamp, generally use discharge lamp with low pressure mercury vapour, this discharge lamp with low pressure mercury vapour is by constituting to the quartz glass tube that long wavelength's scope has permeability from the following wave-length coverage of 220nm.
Symbol 2 is to run through the hole of back flow plate 6a, 6b, 6c, 6d, 6e and the light-transmission tube that disposes.The two ends periphery of light-transmission tube 2 is kept by ring flange 7a, 7b watertight ground.Above-mentioned discharge lamp 4 is installed in the light-transmission tube 2, and space that discharge lamp 4 is disposed and processed water 5 are isolated.
In addition, light-transmission tube 2 and discharge lamp 4 are (many of light-transmission tube 2 and the discharge lamp 4 common configured in parallel, but only show 1 in Fig. 7) that are made of the quartz glass that has permeability from the following wave-length coverage of 220nm to long wavelength's scope equally.
See through light-transmission tube 2 and irradiation processed water 5 from the ultraviolet ray of discharge lamp 4 irradiations.
Hydrone H 2The bond energy of the H-OH of O is 499kJ/mol, and therefore, the ultraviolet ray of the following wavelength of 220nm can decomposition water molecule H 2O and generate the OH free radical.It is such that the OH free radical that is generated for example just is being shown below, and organic substance in the water is resolved into CO, CO 2, H 2O.
H 2O+hv (185nm) → H+OH free radical
C nH mO k+ OH free radical → CO, CO 2, H 2O
(n, m, k are positive integer)
Then, be described in detail with regard to the discharge lamp 4 among Fig. 7.
Discharge lamp 4 comprises body 31 that is made of quartz glass and pair of electrodes 32a, the 32b that is configured in the two ends of body 31.
In body 31, enclose and mercury is arranged as luminescent metal.And the electrode 32b of a side is directed into along the outer wall of discharge lamp 4 by lead 3 that another is distolateral, is accommodated in the lamp holder 37 with the lead 3 that is connected in opposite side electrode 32a, and the terminal that is made of predetermined conductor can be situated between and is electrically connected with power supply by lamp socket 38.
Lead 3 extends along the outer wall of discharge lamp 4, and its insulating material must be the heat proof material of ability from the heating of discharge lamp 4.Therefore, as the insulating material of lead 3, can use excellent heat resistance, for example ETFE (ethylene-tetrafluoroethylene copolymer), FEP (tetrafluoraoethylene-hexafluoropropylene copolymer), PFA (perfluoroalkyl vinyl ether copolymer), PTFE fluororesin such as (polyflons).
And in cylindrical shell 1, feeding predetermined processed water on one side, on one side predetermined power supply is supplied on the discharge lamp 4 and when it is lighted, then radiate comprise 185nm ultraviolet ray at distinctive ultraviolet ray of interior mercury and visible light, thereby above-mentioned organic decomposition reaction takes place, so that the organic substance in the processed water becomes CO, CO 2, H 2O etc. and being removed.
But, discharge lamp 4 is along with the reduction of ultraviolet power output, need probably in the period of half a year~1, to regularly replace, but use in the discharge lamp 4 of fluororesin as the insulation cladding, have penetrating odor during replacing and the stimulation pain of skin at lead 3 in the past.This is the distinctive problem of device of utilizing the following wave-length coverage of 220nm, be utilize the ultraviolet irradiation treatment device of the wave-length coverage of 240~280nm meet less than phenomenon.
Promptly, the C-F bond energy of fluororesin is 539kJ/mol, therefore, does not also become obstacle even be subjected to the ultraviolet irradiation of the wave-length coverage of 240~280nm, but be exposed on the ultraviolet following time of the following wave-length coverage of 220nm, then the fluorine composition decomposes from the fluororesin that constitutes lead 3.Can think that this fluorine and moisture on every side react, thereby generate harmful hydrogen fluoride or hydrofluoric acid.
When generating this hydrogen fluoride or hydrofluoric acid, there are the following problems: with the quartz glass reaction of the constituent material of light-transmission tube 2 and produce gonorrhoea (turning white) on light-transmission tube 2, under the effect of this gonorrhoea, to the irradiation light quantity reduction of object being treated, thereby treatment effeciency descends.In addition, hydrogen fluoride or hydrofluoric acid are harmful, therefore also exist to make operational environment worsen such problem.
Therefore, proposed the ultraviolet irradiation treatment device of following structure: as the lead of discharge lamp, the nonisulated lead that uses not insulation to coat is not as long as be cut off the supply power of discharge lamp power supply, then can not extract discharge lamp (for example, with reference to patent documentation 1) from light-transmission tube.
But, in the ultraviolet irradiation treatment device of patent documentation 1 described structure, and though can make this device novelly, the problem that exists is: and under the situation with the device of in the past constructing that has been provided with, repacking needs expense and time.In addition, also exist the operator to be difficult to manipulate nonisulated lead as the such problem of the discharge lamp of lead.
For fear of generating hydrogen fluoride or hydrofluoric acid, also can consider for example to use the macromolecular compound such as polyimides, polyamide-imides of non-halogen system and the inorganic insulator as mica insulator (for example, with reference to patent documentation 2) as the formation lead.
But, the insulator that so non-halogen is is compared with fluororesin, and dielectric constant is higher, and therefore the problem that exists is to increase leakage current easily.
That is, the dielectric constant of fluororesin is about 2.1, and for example the dielectric constant of polyimides and polyamide-imides is more than 3.2, and mica is more than 7.0, and the dielectric constant of the insulator of most halogen system has the tendency higher than fluororesin.
Dielectric capacitance is directly proportional with dielectric constant, if thereby dielectric constant higher, then over the ground between and the capacitance between contrary current potential just increase.
Therefore, from the relation of I=V * ω C (I is that electric current, V are that voltage, C are capacitances, and ω is a constant, ω=2 π f) as can be known, the leakage current that flows to ground or contrary current potential via electric capacity increases easily.
Usually, on ultraviolet irradiation treatment device, be equipped with the electric ballast that a plurality of discharge lamps, a plurality of high frequencies that are used to drive 20~100kHz are stably lighted these discharge lamps.Electric ballast has added following various functions: straighforward operations such as lighting, turn off the light, full luminous point is bright, light modulation is lighted, when discharge lamp does not work light that the temperature anomaly when overheated in abnormal show, the power operation dish shows so that for the protective circuit of the expansion that prevents accident in advance etc.
These functions Weak current signal manipulation of number mA level, even the increase of leakage current is very small, also might cause the misoperation of electric ballast, therefore, using high dielectric constant materials such as polyimides, polyamide-imides or mica may not be the best way as the insulator of lead.
Patent documentation 1: TOHKEMY 2002-282851 communique
Patent documentation 2: TOHKEMY 2007-220549 communique
Summary of the invention
The object of the present invention is to provide a kind of short wavelength ultraviolet discharge lamp and the ultraviolet irradiation treatment device that has used this short wavelength ultraviolet discharge lamp, wherein comprise in the ultraviolet short wavelength ultraviolet discharge lamp of the following wave-length coverage of 220nm in radiation, can prevent the reduction of the treatment effeciency of object being treated, to human body be safe and the reliability of running operation good.
The present invention relates to a kind of short wavelength ultraviolet discharge lamp, it constitutes: have pair of electrodes opposite one another at the two ends of quartz glass tube, enclosing in this quartz glass tube has at least at the luminous material of the following wave-length coverage of 220nm, outer wall along described quartz glass tube will be directed to opposite side with the lead that the described electrode of a side is electrically connected, be connected with supply power in a side identical with the lead of the described electrode that is electrically connected on opposite side, described short wavelength ultraviolet discharge lamp is characterised in that: near the lead that is directed into another electrode along the outer wall of described quartz glass tube has the metal outer member of adorning on the insulated electric conductor that is coated by the fluororesin insulator.
That is, this short wavelength ultraviolet discharge lamp is the discharge lamp that radiation comprises the ultraviolet single lamp holder type of the following wave-length coverage of 220nm, has the lead that extends along the outer wall of quartz glass tube.This lead on insulated electric conductor, have by fluororesin insulator coated wire metal outside the dress member.
Utilize this metal outer dress member, even the insulator of coated wire is made of the fluororesin insulator, also owing to be provided with metal outer dress member on this insulator, thereby under by the ultraviolet situation below the discharge lamp irradiation 220nm, fluororesin can't be directly exposed under the ultraviolet ray.
Like this, short wavelength ultraviolet discharge lamp of the present invention is not because the fluororesin of the insulator of lead is directly exposed to ultraviolet ray down, so can prevent the generation of hydrogen fluoride or hydrofluoric acid.
Therefore, short wavelength ultraviolet discharge lamp of the present invention is safe to human body, and then these hydrogen fluoride or hydrofluoric acid can not produce gonorrhoea with the quartz glass reaction that constitutes light-transmission tube on light-transmission tube, thereby can prevent the reduction to the irradiation light quantity of object being treated.
In addition, owing to use the insulator of the low fluororesin of dielectric constant, thereby can suppress the generation of leakage current, can prevent to be used to make the misoperation of the electric ballast of discharge tube lighting, thereby the reliability of running operation is improved as lead.
As the insulated electric conductor that is coated by above-mentioned fluororesin insulator of short wavelength ultraviolet discharge lamp of the present invention, for example can example illustrate that the extrusion molding, the tubulose that utilize fluororesin coat or the method for tape wrapping is coated on the conductor and the insulated electric conductor that forms.
In these insulated electric conductors, can easily the fluororesin insulator be coated on the conductor with low cost.
In addition, the above-mentioned metal outer dress member as short wavelength ultraviolet discharge lamp of the present invention for example can example illustrate stainless steel, aluminium, aluminium alloy, nickel or nickel alloy etc.
Thermal endurance, the ultra-violet resistance of these metals are good, the oxidative resistance excellence, and the durability of the outer dress member of being made by these metals is good.
In addition, the outer dress member of short wavelength ultraviolet discharge lamp of the present invention is that the method for evaporation, tubulose coating, tape wrapping, fibrage by these metals or these methods are made up is arranged on the above-mentioned insulated electric conductor.
These outer dress members can be easily positioned on the insulated electric conductor with low cost.
In addition, short wavelength ultraviolet discharge lamp of the present invention is characterised in that: the outer wall along above-mentioned quartz glass tube will be directed to opposite side with the lead that the above-mentioned electrode of a side is electrically connected, and end that this lead guided and the end that is electrically connected on the lead of above-mentioned opposite side electrode are accommodated in the lamp holder that becomes one.
This short wavelength ultraviolet discharge lamp easily carries out dismounting with supply power, and operation is very convenient.
Ultraviolet irradiation treatment device of the present invention is to have in the light-transmission tube of light transmission and constitute inserting in these short wavelength ultraviolet discharge lamps at least in the following wave-length coverage of 220nm.
According to this ultraviolet irradiation treatment device, will from ultraviolet irradiation that short wavelength ultraviolet discharge lamp radiated to object being treated, for example can be used for the organic decomposition reaction of water thus and handle via the wall of light-transmission tube.
In addition, the invention still further relates to a kind of ultraviolet irradiation treatment device, it constitutes: insert in the short wavelength ultraviolet discharge lamp with two lamp holder types at least and have in the light-transmission tube of light transmission in the following wave-length coverage of 220nm, the short wavelength ultraviolet discharge lamp of this two lamp holders type has pair of electrodes opposite one another at the two ends of quartz glass tube, and enclosing in this quartz glass tube has at least at the luminous material of the following wave-length coverage of 220nm, described ultraviolet irradiation treatment device is characterised in that: its formation is that metal outer dress member is arranged on the insulated electric conductor, described insulated electric conductor is to be coated via the lead that is electrically connected with the chimeric lamp socket of the lamp holder of a side of described short wavelength ultraviolet discharge lamp by the fluororesin insulator to form, wherein, this lead is directed to opposite side along the outer wall of described short wavelength ultraviolet discharge lamp, is connected with the supply power that is used to light short wavelength ultraviolet discharge lamp in a side identical with the chimeric lamp socket of the lamp holder of opposite side.
Promptly, ultraviolet irradiation treatment device of the present invention comprises radiation to insert in the following wave-length coverage of 220nm in the short wavelength ultraviolet discharge lamp of ultraviolet two-burner lamp type of the following wave-length coverage of 220nm to have in the light-transmission tube of light transmission, safeguarding becomes can be connected this discharge lamp in a side easily with supply power in order to make, and has the lead that extends in light-transmission tube for this reason.This lead is provided with the metal outer member of adorning on the insulated electric conductor that lead is coated by the fluororesin insulator.Thus, even the insulator of coated wire is made of fluororesin, fluororesin can not be directly exposed to ultraviolet ray down yet.Therefore, can prevent the generation of hydrogen fluoride or hydrofluoric acid, thereby be safe, nor can on the quartz glass that constitutes light transmission, produce gonorrhoea, so can prevent reduction to the irradiation light quantity of object being treated to human body.Moreover, owing to use the low fluororesin of dielectric constant, thereby can suppress the generation of leakage current as insulator, so can prevent to be used to make the misoperation of the electric ballast of discharge tube lighting, thus can seek the raising of running operation reliability.
As the insulated electric conductor that coats by above-mentioned fluororesin insulator of ultraviolet irradiation treatment device of the present invention, for example can example illustrate that the extrusion molding, the tubulose that utilize fluororesin coat or the method for tape wrapping is coated on the conductor and the insulated electric conductor that forms.
Thus, can easily the fluororesin insulator be coated on the conductor with low cost.
In addition, the above-mentioned metal outer dress member as ultraviolet irradiation treatment device of the present invention for example can example illustrate stainless steel, aluminium, aluminium alloy, nickel or nickel alloy etc.
Thermal endurance, the ultra-violet resistance of these metals are good, the oxidative resistance excellence, and the durability of the outer dress member of being made by these metals is good.
In addition, the outer dress member of the lead of ultraviolet irradiation treatment device of the present invention is that the method for evaporation, tubulose coating, tape wrapping, fibrage by these metals or these methods are made up is arranged on the above-mentioned insulated conductor.
These outer dress members can be easily positioned on the insulated conductor with low cost.
According to the present invention, a kind of reduction that can prevent the treatment effeciency of object being treated can be provided, be safe and the good short wavelength ultraviolet discharge lamp of the reliability of running operation and used the ultraviolet irradiation treatment device of this short wavelength ultraviolet discharge lamp human body.
Description of drawings
Fig. 1 is the cutaway view of structure that schematically shows the short wavelength ultraviolet discharge lamp of one embodiment of the present invention.
Fig. 2 is the cutaway view that schematically shows the structure of the lead that is used for discharge lamp shown in Figure 1.
Fig. 3 is the cutaway view that schematically shows the variation of discharge lamp shown in Figure 1.
Fig. 4 is the cutaway view of structure that schematically shows the ultraviolet irradiation treatment device of one embodiment of the present invention.
Fig. 5 schematically shows the cutaway view that the structure of ultraviolet irradiation treatment device is used in the test that is used for embodiments of the invention.
Fig. 6 is the cutaway view that schematically shows the structure of the test lead that is used for comparative example.
Fig. 7 is the cutaway view that schematically shows the structure of ultraviolet irradiation treatment device in the past.
Symbol description:
1, cylindrical shell 2, light-transmission tube
3,60, lead 4,100,100A, discharge lamp
5, processed water 6a, 6b, 6c, 6d, back flow plate
7a, 7b, 7c, 7d, ring flange 10a, 10b, power pin
21, conductor 22, fluororesin insulator
23a, 23b, adorn member 31, body outward
32a, 32b, filament 33a, 33b, 33c, 33d, inner lead
34a, 34b, 34c, 34d, molybdenum foil 35a, 35b, 35c, 35d, outer lead
36, cover 37,37a, 37b, lamp holder
38,50a, 50b, lamp socket 70, rubber cover
200, ultraviolet irradiation treatment device
Embodiment
Below describe with regard to embodiments of the present invention, but the present invention is not limited thereto.
Fig. 1 is the cutaway view of structure that schematically shows the short wavelength ultraviolet discharge lamp of one embodiment of the present invention.In addition, the component part identical with above-mentioned discharge lamp shown in Figure 7 put on identical symbol and simplify or omit its explanation.
Discharge lamp 100 has body 31, this body 31 be by have the external diameter 15mm of permeability from the following wave-length coverage of 220nm to long wavelength's scope, the quartz glass of total length 1.6m constitutes.The discharge lamp 100 that makes the relationship match of bore, discharging current and current potential gradient is high efficiency and high performance type.Interval at the two ends of body 31 with about 1.5m disposes a pair of filament (electrode) 32a, 32b opposed to each other.A pair of filament 32a, 32b only block respectively on inner lead 33a, 33b, 33c, 33d, are maintained in the body 31 via molybdenum foil 34a, 34b, 34c, 34d and outer lead 35a, 35b, 35c, 35d, and are exported to the outside of body 31 by electricity.In addition, inclosure has an amount of mercury and rare gas in body 31.In addition, the cover 36 that discharge lamp 100 has the ceramic that is used for the protection tube end in a side has lamp holder 37 as the ceramic with power pin 10a, 10b of conductive part at opposite side.
One end of lead 60 is crimped and is connected on the outer lead 35c that is electrically connected with the filament 32b of a side, near being directed into the filament 32a of opposite side along the outer wall of body 31, the other end of lead 60 is welded on the power pin 10b by solder in lamp holder 37.The outer lead 35b of filament 32a also is welded on the power pin 10a by solder in lamp holder 37, constitutes the form of so-called single lamp holder type discharge lamp.As shown in Figure 2, lead 60 is following formation: use 22 pairs of fluororesin insulators by the extrusion molding made of FEP (tetrafluoraoethylene-hexafluoropropylene copolymer) to be about 0.6mm by sectional area 2The conductor 21 that constitutes of strand lead made of copper insulate and obtain insulated electric conductor, on this insulated electric conductor be with thickness 150 μ m, width be 8mm aluminum tape wrapping curl as outside dress member 23a, and then this with on the braiding external diameter be that the aluminum fiber of 500 μ m is as adorning member 23b outward.At this, utilize the extrusion molding of FEP, fluororesin insulator 22 is coated on the conductor 21 that constitutes by the strand lead and insulate, but in addition, for example can utilize also that tubulose coats, tape wrapping coats.In addition, as fluororesin insulator 22, except above-mentioned FEP, for example also can use known fluororesin such as ETFE, PFA, PTFE.In addition, as the material of outer dress member 23a, 23b, used aluminium, but in addition, so long as thermal endurance, UV resistant characteristic good and the metal that is difficult to oxidation, just there is no particular limitation, for example preferably stainless steel, aluminium, aluminium alloy, nickel or nickel alloy.
Have in the light-transmission tube (not shown) of the known quartz glass system of light transmission and constitute ultraviolet irradiation treatment device inserting in this discharge lamp 100 in the following wave-length coverage of 220nm, when for example lighting with the discharging current of 1A via predetermined electric ballast (not shown), about 5% the 7.5W that then is equivalent to the electric power of discharge lamp 100 is used as the ultraviolet energy of 185nm and radiates, and this ultraviolet part also shines on the lead 60 that extends along the outer wall of body 31.At this moment, as outer dress member 23a, 23b, on the fluororesin insulator 22 that constitutes by FEP,, and then woven aluminum fiber on tape, so ultraviolet ray can not shine directly on the fluororesin insulator 22 with the tape wrapping curl of aluminum.Therefore, can prevent to produce harmful hydrogen fluoride or hydrofluoric acid, thereby these hydrogen fluoride or hydrofluoric acid can not produce gonorrhoea with the quartz glass reaction that constitutes light-transmission tube on light-transmission tube yet, can prevent reduction the irradiation light quantity of object being treated from lead 60.In addition, in lead 60, as the fluororesin insulator 22 that coats the conductor 21 that constitutes by strand lead made of copper, owing to use the low fluororesin such as for example FEP of dielectric constant, thereby be difficult to take place leakage current, thus can prevent the misoperation of electric ballast.
At this, prepare hundreds of discharge lamps 100, will insert in these discharge lamps 100 in the known light-transmission tube and make the ultraviolet irradiation treatment device running, the result does not have special unfavorable condition and has given play to satisfactory performance.In addition, confirmed this ultraviolet irradiation treatment device after having used 1 year, when changing discharge lamp 100, safety, environment, healthy aspect certainly much less, and change, handle, when the discarded operation all without any obstacle.
Therefore, according to present embodiment, the formation of the lead 60 that extends along body 31 outer walls of discharge lamp 100 is: on the fluororesin insulator 22 that constitutes by FEP with the tape wrapping curl of aluminum so that on this is with the braiding aluminum fiber as outside adorn member 23a, 23b, therefore, even from the ultraviolet ray below the discharge lamp 100 radiation 220nm, also can prevent the hydrogen fluoride that is harmful to or the generation of hydrofluoric acid, thereby be safe human body.In addition, these hydrogen fluoride or hydrofluoric acid can not produce gonorrhoea with the quartz glass reaction that constitutes light-transmission tube on light-transmission tube, thereby can prevent the reduction to the irradiation light quantity of object being treated.In addition, use the low fluororesin of dielectric constant, thereby can prevent the misoperation of electric ballast, thereby can seek the raising of running operation reliability as the fluororesin insulator 22 that coats the conductor 21 that constitutes by the strand lead.
In addition, in the present embodiment, use form power pin 10a, 10b as shown in Figure 1, that be connected with opposed electrode 32a, 32b are incorporated in the single lamp holder type discharge lamp in the lamp holder 37, be illustrated with regard to discharge lamp 100 and ultraviolet irradiation treatment device, but the present invention is not limited thereto.For example, also can be form as shown in Figure 3, lead 60 is drawn out to the place ahead of body 31, the discharge lamp 100A that is connected with the supply power connector.
Then, use Fig. 4 to describe with regard to the ultraviolet irradiation treatment device of one embodiment of the present invention.Fig. 4 is the cutaway view that only schematically shows the part of the discharge lamp of structure of the ultraviolet irradiation treatment device that is suitable for two-burner lamp type discharge lamp and light-transmission tube.Present embodiment is a two-burner lamp type discharge lamp, and this point and Fig. 1, discharge lamp shown in Figure 3 are different.In addition, the component part identical with Fig. 1 and discharge lamp shown in Figure 3 put on identical symbol and simplify or omit its explanation.
Ultraviolet irradiation treatment device 200 is to have in the light-transmission tube 2 of light transmission and constitute inserting in the discharge lamp 100B in the following wave-length coverage of 220nm.Discharge lamp 100B is the ultraviolet two-burner lamp type discharge lamp that radiation comprises the following wave-length coverage of 220nm.Its structure is: chimeric lamp socket 50a, 50b arranged respectively with on the electrode 32a at the two ends of discharge lamp 100B, lamp holder 37a, the 37b that 32b is electrically connected, the lead 60 that is connected with lamp socket 50b is extended lamp socket 50a side in light-transmission tube 2, can dismounting and being connected of the supply power that is used to light above-mentioned discharge lamp 100B in lamp socket 50a side.In addition, lead 60 as mentioned above, and is identical with Fig. 1, Fig. 2, lead shown in Figure 3.
In the ultraviolet irradiation treatment device 200 that is suitable for two such lamp holder type discharge lamp 100B, the formation of lead 60 (with reference to Fig. 2) also is: on by fluororesin insulator 22 coating conductors 21 resulting insulated electric conductors, with the tape wrapping curl of aluminum and then braiding aluminum fiber as adorning member 23a, 23b outward, therefore, even from the ultraviolet ray below the discharge lamp 100B radiation 220nm, ultraviolet ray can not shine directly on the fluororesin insulator 22 yet.Therefore, can prevent to produce harmful hydrogen fluoride or hydrofluoric acid, thereby be safe human body from lead 60, moreover, these hydrogen fluoride or hydrofluoric acid can not produce gonorrhoea with the quartz glass reaction that constitutes light-transmission tube on light-transmission tube, can prevent the reduction to the irradiation light quantity of object being treated.In addition, also be difficult to take place leakage current, thereby can prevent the misoperation of electric ballast.
(other execution mode)
In addition, the invention is not restricted to the record content of above-mentioned execution mode, in the scope that does not break away from purport of the present invention, can suitably change.
For example, present embodiment is in lead 60, and the conductor 21 that coats with fluororesin insulator 22 is made of the strand lead, but the form of conductor 21 is arbitrarily, for example also can use single line, line concentration or litzendraht wire.
In addition, in the present embodiment, the discharge lamp with low pressure mercury vapour that just has the OnNow type of the lamp holder 37 that separately one-sided of lead 60 and a pair of filament 32a, 32b is connected and is provided with power pin 10a, 10b, promptly the lead 60 that extends outside body 31 is that 1 situation is illustrated, but the present invention is not limited thereto.For example, also can be a pair of filament 32a, 32b are connected, make the preheating type that discharges again after filament 32a, the 32b preheating respectively with lead 60 discharge lamp with low pressure mercury vapour, promptly the lead 60 that extends outside body 31 is many.The shape of the lamp holder 37 of discharge lamp 100 also is arbitrarily.
In addition, discharge lamp 100,100A, 100B for example can be applicable to also that Excimer lamp (excimer lamp), xenon lamp etc. are in the following wave-length coverage luminous light source of 220nm except above-mentioned mercury vapour discharge lamp.This situation also can obtain the effect same with present embodiment.
In addition, in ultraviolet irradiation treatment device, the light-transmission tube 2 that inserts discharge lamp 100,100A, 100B is not limited to have at its two ends the shape of peristome, also can be that the one end is closed.In addition, this device is not only limited to horizontal type, can be longitudinal type yet.
Experimental example
Then, describe with regard to the experimental example of simulating ultraviolet irradiation treatment device of the present invention with reference to Fig. 5 and Fig. 6.In this experimental example, confirmed by experiment that in the lead 60 of the execution mode shown in Fig. 1~4 it is suitable coating the fluororesin insulator by metal outer dress member.Fig. 5 (a) schematically shows this to test the cutaway view of employed test with the structure of ultraviolet irradiation treatment device.Fig. 5 (b) is the A-Aa side cross sectional view at Fig. 5 (a).Fig. 6 is the cutaway view that schematically shows the structure of the employed test lead of comparative example.
(experimental example 1)
Use the test ultraviolet irradiation treatment device shown in Fig. 5 (a), Fig. 5 (b), carry out the UV-durability test of test lead 300 at intended duration, it the results are shown in the table 1.This test with the formation of ultraviolet irradiation treatment device is: the roughly total length of body that spreads all over the discharge lamp with low pressure mercury vapour 100B of two lamp holder types, around it boundling 12 identical test leads 300 and with nickel bare wire (not shown) tighten after, this discharge lamp with low pressure mercury vapour 100B is inserted in the light-transmission tube 2 of quartz glass system, two ends with rubber cover 70 sealing light-transmission tubes 2, this discharge lamp with low pressure mercury vapour 100B radiation comprises the wavelength of 185nm in interior ultraviolet ray, external diameter is 15mm, and total length is 1.6m.In addition, why with respect to 1 discharge lamp 100B, test lead 300 is set at 12, is because can quicken to produce hydrogen fluoride or hydrofluoric acid, thereby makes the phenomenon of the inner surface generation gonorrhoea of the light-transmission tube 2 that constitutes by quartz glass from the test lead 300 that outside body, extends.
Constituting of the employed test lead 300 of this experimental example: in lead shown in Figure 2 60,, use sectional area to be approximately 0.6mm as conductor 21 2Zinc-plated copper; As fluororesin insulator 22 (thickness is 0.15mm), use ETFE; As outer dress member 23a, 23b, the aluminum band of coiling thickness 20 μ m, and this with on the zinc-plated copper fiber of braiding.
(comparative example 1)
As test lead 300, use shown in Figure 6, separate the lead of thickness as the fluororesin insulator 22 that constitutes by FEP of 0.15mm, in addition, similarly carry out with experimental example 1, the results are shown in the table 1.
(comparative example 2)
As test lead 300, use shown in Figure 6, separate the lead of thickness as the fluororesin insulator 22 that constitutes by ETFE of 0.15mm, in addition, similarly carry out with experimental example 1, the results are shown in the table 1.
(comparative example 3)
As test lead 300, employed lead is: it is resulting to replace fluororesin insulator 22 shown in Figure 6 and to separate this insulator that to be suitable for by thickness be the insulator that constitutes of the PVC (Corvic) of 0.25mm, in addition, similarly carry out with experimental example 1, the results are shown in the table 1.
Figure A20078003576700161
As known from Table 1, among the embodiment 1 of dress member as test lead 300, though the outer surface of lead 300 becomes black, the outward appearance of light-transmission tube 2 is not seen variation, does not produce gonorrhoea outside use is metal.Black that it is generally acknowledged lead 300 outer surfaces is under the effect of the ozone that ultraviolet ray and oxygen by 185nm generate, and the tin that is woven in the outermost zinc-plated copper fiber has generated tin-oxide.Under the situation to the object being treated irradiation ultraviolet radiation, this tin-oxide can not become any obstacle.Therefore, the used use of experimental example 1 lead 300 of metal outer dress member also can be preferably as the lead use of single lamp holder type discharge lamp shown in Figure 1.
In addition, in lead 300 (with reference to Fig. 6) comparative example 1, that separate the fluororesin insulator 22 that constitutes by FEP, produced gonorrhoea at the inner surface of light-transmission tube 2.As mentioned above, under the situation to the object being treated irradiation ultraviolet radiation, this gonorrhoea causes the decay of ultraviolet illumination.In addition, it is harmful to become the generation of the hydrogen fluoride of main cause of gonorrhoea or hydrofluoric acid.Therefore, the comparative example 1 employed lead 300 that separates fluororesin insulator 22 is not suitable as the lead of single lamp holder type discharge lamp shown in Figure 1.
In addition, comparative example 2, separate in the lead 300 of the fluororesin insulator 22 that the ETFE by the UV resistant characteristic good constitutes fluororesin deterioration and lose insulating properties.Moreover the inner surface of light-transmission tube 2 is compared with the situation of having used the lead with the FEP shown in the comparative example 1, and the degree of gonorrhoea clearly.Therefore, the lead 300 that separates comparative example 2 employed fluororesin insulators 22 is not suitable as the lead of single lamp holder type discharge lamp shown in Figure 1.
In addition, comparative example 3, used in the lead of the insulator that constitutes by PVC, deterioration takes place in PVC, the conductor that is coated by PVC exposes.Therefore, the lead that separates comparative example 3 employed PVC insulators is not suitable as the lead of single lamp holder type discharge lamp shown in Figure 1.
Therefore, on the insulated electric conductor that conductor is insulated by the fluororesin insulator, be provided with metal outside the lead of dress member be preferred as the lead that outside the body of the ultraviolet discharge lamp of radiation below the 220nm, extends.

Claims (13)

1. short wavelength ultraviolet discharge lamp, it constitutes: have pair of electrodes opposite one another at the two ends of quartz glass tube, enclosing in this quartz glass tube has at least at the luminous material of the following wave-length coverage of 220nm, outer wall along described quartz glass tube will be directed to opposite side with the lead that the described electrode of a side is electrically connected, be connected with supply power in a side identical with the lead of the described electrode that is electrically connected on opposite side, described short wavelength ultraviolet discharge lamp is characterised in that:
Near the lead that is directed into another electrode along the outer wall of described quartz glass tube has the metal outer member of adorning on the insulated electric conductor that is coated by the fluororesin insulator.
2. short wavelength ultraviolet discharge lamp according to claim 1 is characterized in that: described is that the extrusion molding that utilizes fluororesin, tubulose coat or the method for tape wrapping is coated on the conductor and forms by the insulated electric conductor that the fluororesin insulator coated.
3. short wavelength ultraviolet discharge lamp according to claim 1 is characterized in that: described metal outer dress member is made by stainless steel, aluminium, aluminium alloy, nickel or nickel alloy.
4. short wavelength ultraviolet discharge lamp according to claim 1 is characterized in that: described metal outer dress member is made up by the method for evaporation, tubulose coating, tape wrapping, fibrage or with these methods to be arranged on the described insulated electric conductor.
5. short wavelength ultraviolet discharge lamp, it constitutes: have pair of electrodes opposite one another at the two ends of quartz glass tube, enclosing in this quartz glass tube has at least at the luminous material of the following wave-length coverage of 220nm, outer wall along described quartz glass tube will be directed to opposite side with the lead that the described electrode of a side is electrically connected, the end that this lead is directed is accommodated in the lamp holder that becomes one with the end of the lead of the electrode that is electrically connected on described opposite side, this lamp holder is connected with supply power in mode that can dismounting, and described short wavelength ultraviolet discharge lamp is characterised in that:
Near the lead that is directed into another electrode along the outer wall of described quartz glass tube has the metal outer member of adorning on the insulated electric conductor that is coated by the fluororesin insulator.
6. short wavelength ultraviolet discharge lamp according to claim 5 is characterized in that: described is that the extrusion molding that utilizes fluororesin, tubulose coat or the method for tape wrapping is coated on the conductor and forms by the insulated electric conductor that the fluororesin insulator coated.
7. short wavelength ultraviolet discharge lamp according to claim 5 is characterized in that: described metal outer dress member is made by stainless steel, aluminium, aluminium alloy, nickel or nickel alloy.
8. short wavelength ultraviolet discharge lamp according to claim 5 is characterized in that: described metal outer dress member is made up by the method for evaporation, tubulose coating, tape wrapping, fibrage or with these methods to be arranged on the described insulated electric conductor.
9. ultraviolet irradiation treatment device is characterized in that: it is to insert in each described short wavelength ultraviolet discharge lamp with claim 1~8 at least in the following wave-length coverage of 220nm has the light-transmission tube of light transmission to form.
10. ultraviolet irradiation treatment device, it constitutes: insert in the short wavelength ultraviolet discharge lamp with two lamp holder types at least and have in the light-transmission tube of light transmission in the following wave-length coverage of 220nm, the short wavelength ultraviolet discharge lamp of this two lamp holders type has pair of electrodes opposite one another at the two ends of quartz glass tube, and enclosing in this quartz glass tube has at least at the luminous material of the following wave-length coverage of 220nm, and described ultraviolet irradiation treatment device is characterised in that:
Its formation is that metal outer dress member is arranged on the insulated electric conductor, described insulated electric conductor is to be coated via the lead that is electrically connected with the chimeric lamp socket of the lamp holder of a side of described short wavelength ultraviolet discharge lamp by the fluororesin insulator to form, wherein, this lead is directed to opposite side along the outer wall of described short wavelength ultraviolet discharge lamp, is connected with the supply power that is used to light described short wavelength ultraviolet discharge lamp in a side identical with the chimeric lamp socket of the lamp holder of opposite side.
11. ultraviolet irradiation treatment device according to claim 10 is characterized in that: described is that the extrusion molding that utilizes fluororesin, tubulose coat or the method for tape wrapping is coated on the conductor and forms by the insulated electric conductor that the fluororesin insulator coated.
12. ultraviolet irradiation treatment device according to claim 10 is characterized in that: described metal outer dress member is made by stainless steel, aluminium, aluminium alloy, nickel or nickel alloy.
13. ultraviolet irradiation treatment device according to claim 10 is characterized in that: described metal outer dress member is made up by the method for evaporation, tubulose coating, tape wrapping, fibrage or with these methods to be arranged on the described insulated electric conductor.
CNA2007800357676A 2006-09-26 2007-09-19 Short wavelength ultraviolet discharge lamp and ultraviolet ray irradiator Pending CN101517695A (en)

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