CN101503766A - Hollow porous tubular structured gold nano material and preparation thereof - Google Patents
Hollow porous tubular structured gold nano material and preparation thereof Download PDFInfo
- Publication number
- CN101503766A CN101503766A CNA2009100198539A CN200910019853A CN101503766A CN 101503766 A CN101503766 A CN 101503766A CN A2009100198539 A CNA2009100198539 A CN A2009100198539A CN 200910019853 A CN200910019853 A CN 200910019853A CN 101503766 A CN101503766 A CN 101503766A
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- gold
- gold nano
- porous tubular
- hollow
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 71
- 239000010931 gold Substances 0.000 title claims abstract description 71
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims description 40
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000000137 annealing Methods 0.000 claims abstract description 13
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 11
- 229910021642 ultra pure water Inorganic materials 0.000 claims abstract description 9
- 239000012498 ultrapure water Substances 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 238000005119 centrifugation Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 230000035484 reaction time Effects 0.000 claims description 8
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
- 230000002829 reductive effect Effects 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- 229960005070 ascorbic acid Drugs 0.000 claims description 3
- 235000010323 ascorbic acid Nutrition 0.000 claims description 3
- 239000011668 ascorbic acid Substances 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000004917 polyol method Methods 0.000 claims description 3
- 239000001508 potassium citrate Substances 0.000 claims description 3
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 3
- 239000012279 sodium borohydride Substances 0.000 claims description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 3
- 235000015870 tripotassium citrate Nutrition 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 6
- 230000003287 optical effect Effects 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 206010028980 Neoplasm Diseases 0.000 abstract description 2
- 201000011510 cancer Diseases 0.000 abstract description 2
- 238000006555 catalytic reaction Methods 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- PQTCMBYFWMFIGM-UHFFFAOYSA-N gold silver Chemical compound [Ag].[Au] PQTCMBYFWMFIGM-UHFFFAOYSA-N 0.000 abstract 5
- 239000002131 composite material Substances 0.000 abstract 3
- 229910001316 Ag alloy Inorganic materials 0.000 abstract 2
- 239000002042 Silver nanowire Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 239000013598 vector Substances 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 230000005540 biological transmission Effects 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 8
- 239000011148 porous material Substances 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 229940100890 silver compound Drugs 0.000 description 3
- 150000003379 silver compounds Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000011258 core-shell material Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000005649 metathesis reaction Methods 0.000 description 2
- 239000002070 nanowire Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- UGWRVHSFESMVND-UHFFFAOYSA-N silver;ethane-1,2-diol;nitrate Chemical compound [Ag+].OCCO.[O-][N+]([O-])=O UGWRVHSFESMVND-UHFFFAOYSA-N 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000002390 Pandanus odoratissimus Species 0.000 description 1
- 235000005311 Pandanus odoratissimus Nutrition 0.000 description 1
- 206010061380 Therapeutic reaction time decreased Diseases 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229960000074 biopharmaceutical Drugs 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003937 drug carrier Substances 0.000 description 1
- 229910001254 electrum Inorganic materials 0.000 description 1
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910021505 gold(III) hydroxide Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000002091 nanocage Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
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CN2009100198539A CN101503766B (en) | 2009-03-18 | 2009-03-18 | Hollow porous tubular structured gold nano material and preparation thereof |
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CN2009100198539A CN101503766B (en) | 2009-03-18 | 2009-03-18 | Hollow porous tubular structured gold nano material and preparation thereof |
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CN101503766A true CN101503766A (en) | 2009-08-12 |
CN101503766B CN101503766B (en) | 2010-08-11 |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103805972A (en) * | 2014-01-17 | 2014-05-21 | 北京航空航天大学 | Ultra-light hollow pipe microarray metal material built by adopting template method and preparation method thereof |
CN104070177A (en) * | 2014-06-28 | 2014-10-01 | 内蒙古工业大学 | Simple and novel preparation method for silver and gold nano-particles |
WO2014161501A1 (en) * | 2013-04-05 | 2014-10-09 | Nuovo Film Inc. | Transparent conductive electrodes comprising surface functionalized metal nanowires, their structure design, and method of making such structures |
CN104259451A (en) * | 2014-09-16 | 2015-01-07 | 南京航空航天大学 | Tubular structure gold nanometer materials and production method thereof |
CN104874790A (en) * | 2015-06-10 | 2015-09-02 | 苏州冷石纳米材料科技有限公司 | Gold nano material adopting porous tubular hollow structure and preparation method of gold nano material |
CN104942281A (en) * | 2015-07-01 | 2015-09-30 | 清华大学 | Porous gold nanowire and manufacturing method and application thereof |
CN105149611A (en) * | 2015-09-18 | 2015-12-16 | 温州大学 | Hollow precious metal nanowire as well as preparation method and application thereof |
CN105689733A (en) * | 2014-11-27 | 2016-06-22 | 中国科学院大连化学物理研究所 | Hierarchical porous silver and preparation method thereof |
CN105879027A (en) * | 2014-05-16 | 2016-08-24 | 中国科学院苏州纳米技术与纳米仿生研究所 | Aptamer-modified gold nanoparticle-graphene composite material and preparation method and application thereof |
CN106735296A (en) * | 2016-12-13 | 2017-05-31 | 上海理工大学 | A kind of method for preparing gold-silver alloy nano particle |
CN108941532A (en) * | 2018-07-24 | 2018-12-07 | 宝鸡文理学院 | A kind of gold nano-material and preparation method thereof of hollow porous tubes shape structure |
CN112023890A (en) * | 2020-08-31 | 2020-12-04 | 江南大学 | Nanometer hollow tube material derived from covalent organic framework and preparation method thereof |
WO2021072631A1 (en) * | 2019-10-15 | 2021-04-22 | 诸暨易联众创企业管理服务有限公司 | Nickel nano material having porous tubular hollow structure, and manufacturing method therefor |
Families Citing this family (1)
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CN103990793B (en) * | 2014-05-09 | 2017-03-29 | 北京华纳高科科技有限公司 | Hollow real wall gold/gold silver nanotube of a kind of high length-diameter ratio and preparation method thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6833019B1 (en) * | 2003-01-31 | 2004-12-21 | The United States Of America As Represented By The Secretary Of The Navy | Microwave assisted continuous synthesis of nanocrystalline powders and coatings using the polyol process |
CN100571865C (en) * | 2007-09-26 | 2009-12-23 | 山东大学 | A kind of nucleocapsid type nanometer stephanoporate metal catalyst as well and preparation method thereof |
CN101332425B (en) * | 2008-08-04 | 2010-12-01 | 山东大学 | Nano porous gold-loaded ultrathin platinum metallic film catalyst and preparation method thereof |
-
2009
- 2009-03-18 CN CN2009100198539A patent/CN101503766B/en not_active Expired - Fee Related
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014161501A1 (en) * | 2013-04-05 | 2014-10-09 | Nuovo Film Inc. | Transparent conductive electrodes comprising surface functionalized metal nanowires, their structure design, and method of making such structures |
CN104285261A (en) * | 2013-04-05 | 2015-01-14 | 苏州诺菲纳米科技有限公司 | Transparent conductive electrodes comprising surface functionalized metal nanowires, their structure design, and method of making such structures |
CN103805972B (en) * | 2014-01-17 | 2015-12-30 | 北京航空航天大学 | A kind of template that adopts constructs ultralight open tube microarray metallic substance and preparation method thereof |
CN103805972A (en) * | 2014-01-17 | 2014-05-21 | 北京航空航天大学 | Ultra-light hollow pipe microarray metal material built by adopting template method and preparation method thereof |
CN105879027A (en) * | 2014-05-16 | 2016-08-24 | 中国科学院苏州纳米技术与纳米仿生研究所 | Aptamer-modified gold nanoparticle-graphene composite material and preparation method and application thereof |
CN105879027B (en) * | 2014-05-16 | 2020-03-27 | 中国科学院苏州纳米技术与纳米仿生研究所 | Nucleic acid ligand modified gold nano-graphene composite material and preparation method and application thereof |
CN104070177A (en) * | 2014-06-28 | 2014-10-01 | 内蒙古工业大学 | Simple and novel preparation method for silver and gold nano-particles |
CN104259451A (en) * | 2014-09-16 | 2015-01-07 | 南京航空航天大学 | Tubular structure gold nanometer materials and production method thereof |
CN105689733A (en) * | 2014-11-27 | 2016-06-22 | 中国科学院大连化学物理研究所 | Hierarchical porous silver and preparation method thereof |
CN104874790A (en) * | 2015-06-10 | 2015-09-02 | 苏州冷石纳米材料科技有限公司 | Gold nano material adopting porous tubular hollow structure and preparation method of gold nano material |
CN104942281A (en) * | 2015-07-01 | 2015-09-30 | 清华大学 | Porous gold nanowire and manufacturing method and application thereof |
CN105149611B (en) * | 2015-09-18 | 2017-08-22 | 温州大学 | A kind of hollow noble metal nano wire and its preparation and application |
CN105149611A (en) * | 2015-09-18 | 2015-12-16 | 温州大学 | Hollow precious metal nanowire as well as preparation method and application thereof |
CN106735296A (en) * | 2016-12-13 | 2017-05-31 | 上海理工大学 | A kind of method for preparing gold-silver alloy nano particle |
CN108941532A (en) * | 2018-07-24 | 2018-12-07 | 宝鸡文理学院 | A kind of gold nano-material and preparation method thereof of hollow porous tubes shape structure |
WO2021072631A1 (en) * | 2019-10-15 | 2021-04-22 | 诸暨易联众创企业管理服务有限公司 | Nickel nano material having porous tubular hollow structure, and manufacturing method therefor |
CN112023890A (en) * | 2020-08-31 | 2020-12-04 | 江南大学 | Nanometer hollow tube material derived from covalent organic framework and preparation method thereof |
CN112023890B (en) * | 2020-08-31 | 2021-12-28 | 江南大学 | Nanometer hollow tube material derived from covalent organic framework and preparation method thereof |
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CN101503766B (en) | 2010-08-11 |
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Effective date of registration: 20130428 Address after: 250100, Hong Lou, 22, Licheng District, Shandong, Ji'nan Patentee after: Wang Jian Address before: 250100 Ji'nan Province, Lixia District, Shandong City, South Hill Road, No. 27 Patentee before: Shandong University Effective date of registration: 20130428 Address after: 250100, Ji'nan, Shandong Province, Hong Lou home office hung House No. 5 Patentee after: Ding Die Patentee after: Wang Zhengyuan Address before: 250100, Hong Lou, 22, Licheng District, Shandong, Ji'nan Patentee before: Wang Jian |
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