CN101503243A - Device for treating oilfield sulfur-containing sewage - Google Patents

Device for treating oilfield sulfur-containing sewage Download PDF

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Publication number
CN101503243A
CN101503243A CNA2009100259852A CN200910025985A CN101503243A CN 101503243 A CN101503243 A CN 101503243A CN A2009100259852 A CNA2009100259852 A CN A2009100259852A CN 200910025985 A CN200910025985 A CN 200910025985A CN 101503243 A CN101503243 A CN 101503243A
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China
Prior art keywords
aeration opening
inlet pipe
water
cylindrical shell
barrel
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Granted
Application number
CNA2009100259852A
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Chinese (zh)
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CN101503243B (en
Inventor
邵校君
赵进官
孙俊良
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Shaanxi Hai Ji Ya Environmental Protection Technology Co., Ltd.
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AMETHYST YIXING ENVIRONMENTAL PROTECTION EQUIPMENT Co Ltd
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Priority to CN2009100259852A priority Critical patent/CN101503243B/en
Publication of CN101503243A publication Critical patent/CN101503243A/en
Application granted granted Critical
Publication of CN101503243B publication Critical patent/CN101503243B/en
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Abstract

The invention discloses an oil field sulphur-bearing waste water treatment device, which comprises a barrel. The upper end of the barrel is openmouthed and the barrel is internally provided with a water collection weir groove, a guide shell, stuffing, an upper part aeration opening and an under part aeration opening; wherein, an inlet tube stretches into the guide shell of the barrel from the upper part of the barrel; the under part aeration opening is arranged below the guide shell and is communicated with an under-part inlet pipe which extends out of the barrel; the upper part aeration opening is arranged peripherally outside the guide shell in the barrel and is communicated with an upper part inlet pipe which extends out of the upper part of the shell; the stuffing is arranged between the upper part aeration opening and the under part aeration opening; the upper part of the barrel is provided with an overflow drain; the water collection weir groove is arranged below the overflow drain; the position of the barrel, which is as high as the top edge of the water collection weir groove, is provided with an oil drainage port; a water outlet is arranged below the oil drainage port; and the lower end of the barrel is provided with a vent. The oil field sulphur-bearing waste water treatment device greatly reduces the consumption of polymer and saves the treatment cost.

Description

Device for treating oilfield sulfur-containing sewage
Technical field
The present invention openly comes a kind of desulfurizer, particularly utilizes the device for treating oilfield sulfur-containing sewage of airborne oxygen treatments applied sour water.
Background technology
Along with Oilfield developing, crude oil water containing constantly raises.In order to protect environment, to keep Oil extraction and stratum production capacity, become conventional with carrying out re-injection after the sewage disposal for many years.Part oil field block causes the water quality instability owing to sulfide content in the water raises gradually, has jeopardized the water flooding effect.According to the data that geology department provides, water injection well, the layer short or do not absorb water and list in 60% of retrofit work amount be because of injection water quality defective due to, this is seriously restricting the oil-field development benefit.Do not remove the sulfide function and design in the existing water conditioning process.Sulphur and sulfide in the output sewage of oil field with S, S 2-, SO 4 2-For principal mode exists, S and SO 4 2-Can both under the effect of sulphate reducing bacteria, be reduced into S 2-, S in the water 2-Because its out-shell electron very easily is out of shape, penetrativity is strong, and iron and steel is had the Cl of ratio -Stronger corrodibility forms local corrosion or pitting corrosion at steel surface, finally makes the tube wall perforation, destroys sewage and water injection equipment.Because the corrosive product gluey FeS suspended substance that is water-fast black, excellent stability makes the rapid blackening of water quality after the processing smelly, and suspended substance increases; FeS is again a kind of oil in water emulsion stablizer simultaneously, and the oil removing difficulty is increased; Inject underground obstruction stratum, the oil reservoir water-retaining capacity is descended, water injection pressure constantly raises, and influences intensified injection of wells measure validity period and reduces, and increases measure cost.
Research and test in place show both at home and abroad, join poly-degraded of injecting with sewage to the polymers soln various degrees, sewage is to the major cause of polymkeric substance degraded, the high problem of the saltiness of sewage still not, main is the severely degrade that the active substance in the on-the-spot high-pressure sealed sewage produces polymkeric substance, cause the injection fluid viscosity not reach requirement, reduced the effect of polymer flooding.Along with the rising of reservoir temperature and salinity,, thereby obtain needed solution viscosity value in requisition for the implantation concentration that increases polymkeric substance.Can improve viscosity in aqueous solution though increase the implantation concentration of polymkeric substance, the corresponding production operation cost that increased makes polymer flooding be difficult to bring into play due value.If utilize oilfield sewage prepared polymer solution, will take appropriate measures and technology comes oilfield sewage is handled, to improve the viscosity of polymers soln, reach the requirement of injection.
In the prior art, for removing S 2-Following two kinds of methods are arranged: 1, chemical precipitation method, cost are too high, and the new metal ion of introducing to the reduction of polymkeric substance viscosity greater than S 2-Reduction to the polymkeric substance viscosity; 2, dioxygen water law, effect are with good, but hydrogen peroxide is a hazardous chemical, and cost is also up to 0.6 yuan/ton; 3, ozone method, effective but facility investment is big, processing cost is too up to 1.6 yuan/ton.
For this reason, the applicant utilizes air oxidation process to adopt three tower parallel connections, and handling the water yield is 11000-12000 ton/sky, S 2-Content drops to 0-1.5mg/l from 15-30mg/l, and poly-viscosity raising 30-40% is joined in the not desulfurization of ratio of viscosities of joining after gathering, and reduces the consumption of polymkeric substance greatly, and processing cost is 0.07 yuan/ton, and how to realize that the key equipment of this method becomes the research key point.
Summary of the invention
Goal of the invention: technical problem to be solved by this invention is at the deficiencies in the prior art, and a kind of device for treating oilfield sulfur-containing sewage is provided.
Technical scheme: the invention discloses a kind of device for treating oilfield sulfur-containing sewage, comprise that the upper end for open cylindrical shell, is provided with the weir notch that catchments, guide shell, filler, top aeration opening and bottom aeration opening in the cylindrical shell; There is a water inlet pipe to stretch into the intravital guide shell of tube from cylindrical shell top; Described bottom aeration opening is positioned at the guide shell below, and is communicated with a bottom inlet pipe of stretching out cylindrical shell; Described top aeration opening is positioned at the intravital guide shell of tube periphery, and is communicated with a top inlet pipe of stretching out cylindrical shell; Described filler is positioned in the middle of top aeration opening and the bottom aeration opening; Simplified upper end is provided with an overflow port; The described weir notch that catchments is positioned at the overflow port below, and contour position, simplified the upper edge last and weir notch that catchments is provided with oil discharge outlet; The oil discharge outlet below is provided with water port; The cylindrical shell lower end is provided with a drain; Described water inlet pipe is connected with a water pump, and top aeration opening and bottom aeration opening are connected with an air compressor machine respectively; Be provided with a water quality detection sensor that is connected with online water quality controller in the described rising pipe, the input signal of described online water quality controller control water pump and air compressor machine.
Among the present invention, preferably, the described water inlet pipe in ground is connected with a water pump, and top aeration opening and bottom aeration opening are connected with an air compressor machine respectively; Be provided with a water quality detection sensor that is connected with online water quality controller in the described water port, the input signal of described online water quality controller control water pump and air compressor machine.Can control the power of air compressor machine in real time according to the difference of water quality thus, and then the ratio of control vapor content, thereby realize optimum aerated reaction.
Among the present invention, preferably, the top and bottom of described guide shell are set to hydraucone, and described water inlet pipe stretches in the hydraucone of upper end.The water inlet that can guarantee the upper end thus flows into the below fully in the guide shell and carries out aeration, guarantees that simultaneously the water of guide shell below scatters, and increases aeration area.The more important thing is simultaneously, in use, because the flooding quantity of water inlet pipe is big, flow velocity is fast, formed the guide shell inner chamber from top to bottom, the outer water circulation from the bottom to top of guide shell, the feed water flow of part is through behind aeration, along with current, hydraucone from the guide shell upper end enters once more, form the secondary aeration, this is arranged so that simple intravital water inlet is can aeration complete, and effect is remarkable.
Among the present invention, preferably, described bottom aeration opening is provided with and is provided with air diffusion aerator.Can increase the aeration effect of inlet mouth.
Among the present invention, preferably, described filler is the PVC filter ball.Through experiment, use the PVC filter ball can increase the area of aerated reaction time and aerated reaction, make the aeration effect increase more than 20% in general.
Among the present invention, preferably, the below of described cylinder lateral wall is provided with inspection port.Be convenient to safeguard and failure testing.
Among the present invention, the described weir notch that catchments, air diffusion aerator can use this area structure comparatively commonly used, need not particular design.
Beneficial effect: device for treating oilfield sulfur-containing sewage of the present invention is through experimental calculation, and handling the water yield is 11000-12000 ton/sky, S 2-Content drops to 0-1.5mg/l from 15-30mg/l, and poly-viscosity raising 30-40% is joined in the not desulfurization of ratio of viscosities of joining after gathering, and reduces the consumption of polymkeric substance greatly, and processing cost is 0.07 yuan/ton.
The experiment of device for treating oilfield sulfur-containing sewage of the present invention, separated sulfide in the sink drainage of determining to the difficult problem that influences of polymer viscosity, system is improved along sulfide in the journey and well head polymer viscosity, sulfide content is from testing about preceding 20mg/L, be reduced to below the present 2mg/L, polymer viscosity is brought up to 80mpa.s from original 65mpa.s.Experiment showed, that utilizing airborne oxygen is most economical and effective means as oxygenant.Contain s in the oil field reinjection water 2-, and s 2-Viscosity influence to polymkeric substance is very big, s 2-Content be that the polymkeric substance that the sewage of 2mg/L is joined compares s 2-Content be that the viscosity of the sewage of the 12mg/L polymkeric substance of joining improves about 20%, have very big economic benefit.
Description of drawings
Below in conjunction with the drawings and specific embodiments the present invention is done further to specify, above-mentioned and/or otherwise advantage of the present invention will become apparent.
Be illustrated as structural representation of the present invention.
Embodiment
As shown in the figure, the invention discloses a kind of device for treating oilfield sulfur-containing sewage, comprise the upper end for open cylindrical shell 1, described being provided with in simplified and cylindrical shell 1 inwall fixed catchment weir notch, guide shell 3, filler 4, top aeration opening 5 and bottom aeration opening 6.Have a water inlet pipe 7 to stretch into the intravital guide shell 3 of tube from cylindrical shell 1 top, described guide shell is connected with simplified 1 inwall by anchor.Described bottom aeration opening 6 is positioned at the below of guide shell 3, and is communicated with a bottom inlet pipe 15 of stretching out cylindrical shell 1.Described top aeration opening 5 is positioned at the intravital guide shell of tube 1 periphery, and is communicated with a top inlet pipe 8 of stretching out cylindrical shell 1.Described PVC filter ball 4 is positioned at top aeration opening 5 and bottom aeration opening 6 intermediary part space, and the channel-section steel fixed position by being connected with cylindrical shell 1 inwall and guide shell 3 outer walls up and down.The upper end of cylindrical shell 1 is provided with an overflow port 9; The described weir notch 2 that catchments is positioned at overflow port 9 belows, and contour position, on the cylindrical shell 1 and upper edge of the weir notch 2 that catchments is provided with oil discharge outlet 10; Oil discharge outlet 10 belows are provided with water port 11; The lower end of cylindrical shell 1 is provided with a drain 12.Described water inlet pipe 7 is connected with a water pump 17, and top inlet pipe 8 and bottom inlet pipe 15 are connected with an air compressor machine 18,19 respectively; Be provided with a water quality detection sensor 16 that is connected with online water quality controller 20 in the described water port 11, the input signal of described online water quality controller 20 control water pumps 17 and air compressor machine 18,19.Described water pump, air compressor machine, line water quality controller and the water quality detection sensor all general equipment in this this area get final product, as long as wherein online water quality controller and connected water quality detection sensor can detect S ion content in the water outlet.The top and bottom of described guide shell 3 are set to hydraucone, and described water inlet pipe 7 stretches in the hydraucone of upper end.Shown in dotted arrow among the figure, the inside and outside current of guide shell form eddy flow, have increased the aeration number of times of water inlet.Described bottom aeration opening 6 is provided with and is provided with air diffusion aerator 13.The below of described cylinder lateral wall is provided with inspection port 14.
The invention provides a kind of thinking and method of device for treating oilfield sulfur-containing sewage; the method and the approach of this technical scheme of specific implementation are a lot; the above only is a preferred implementation of the present invention; should be understood that; for those skilled in the art; under the prerequisite that does not break away from the principle of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.The all available prior art of each component part not clear and definite in the present embodiment is realized.

Claims (5)

1, a kind of device for treating oilfield sulfur-containing sewage is characterized in that, comprises that the upper end for open cylindrical shell (1), is provided with the weir notch that catchments (2), guide shell (3), filler (4), top aeration opening (5) and bottom aeration opening (6) in the cylindrical shell (1); There is a water inlet pipe (7) to stretch into tube intravital guide shell (3) from cylindrical shell (1) top; Described bottom aeration opening (6) is positioned at the below of guide shell (3), and is communicated with a bottom inlet pipe (15) of stretching out cylindrical shell (1); Described top aeration opening (5) is positioned at tube intravital guide shell (1) periphery, and is communicated with a top inlet pipe (8) of stretching out cylindrical shell (1); Described filler (4) is positioned in the middle of top aeration opening (5) and the bottom aeration opening (6); The upper end of cylindrical shell (1) is provided with an overflow port (9); The described weir notch that catchments (2) is positioned at overflow port (9) below, and the position that cylindrical shell (1) is gone up and the upper edge of the weir notch (2) that catchments is contour is provided with oil discharge outlet (10); Oil discharge outlet (10) below is provided with water port (11); The lower end of cylindrical shell (1) is provided with a drain (12); Described water inlet pipe (7) is connected with a water pump (17), and top inlet pipe (8) and bottom inlet pipe (15) are connected with an air compressor machine respectively; Be provided with a water quality detection sensor (16) that is connected with online water quality controller (20) in the described water port (11), the input signal of described online water quality controller (20) control water pump (17) and air compressor machine.
2, device for treating oilfield sulfur-containing sewage according to claim 1 is characterized in that, the top and bottom of described guide shell (3) are set to hydraucone, and described water inlet pipe (7) stretches in the hydraucone of upper end.
3, device for treating oilfield sulfur-containing sewage according to claim 1 and 2 is characterized in that, described bottom aeration opening (6) is provided with and is provided with air diffusion aerator (13).
4, device for treating oilfield sulfur-containing sewage according to claim 3 is characterized in that, described filler is the PVC filter ball.
5, device for treating oilfield sulfur-containing sewage according to claim 3 is characterized in that, the below of described cylinder lateral wall is provided with inspection port (14).
CN2009100259852A 2009-03-16 2009-03-16 Device for treating oilfield sulfur-containing sewage Expired - Fee Related CN101503243B (en)

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CN2009100259852A CN101503243B (en) 2009-03-16 2009-03-16 Device for treating oilfield sulfur-containing sewage

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CN101503243B CN101503243B (en) 2011-05-11

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058309A (en) * 2013-02-01 2013-04-24 北京市龙源科创石油技术有限公司 Device and method for treating acidic water
CN103241873A (en) * 2013-04-18 2013-08-14 宁波大学 Reactor capacity expansion method with upgraded catalyst interception mechanism for photocatalytic degradation of wastewater
CN103241874B (en) * 2013-04-18 2015-12-02 宁波大学 The Microwave photocatalytic wastewater degradation device expansion method that catalyst interception link is perfect again
CN103241875B (en) * 2013-04-18 2015-12-09 宁波大学 The High-capacity waste water degradation reactor that photocatalyst interception reuse mechanism is improved again

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3963611A (en) * 1973-10-26 1976-06-15 Chevron Research Company Oxidation process for improving the environmental quality of water containing sulfur and/or inorganic sub-six-sulfur-containing impurities
US4076621A (en) * 1976-03-15 1978-02-28 Air Resources, Inc. Chelate oxidation of hydrogen sulfide in sour water
CN201415955Y (en) * 2009-03-16 2010-03-03 宜兴市紫晶环保设备有限公司 Oilfield sulfur-containing sewage treatment device

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058309A (en) * 2013-02-01 2013-04-24 北京市龙源科创石油技术有限公司 Device and method for treating acidic water
CN103241873A (en) * 2013-04-18 2013-08-14 宁波大学 Reactor capacity expansion method with upgraded catalyst interception mechanism for photocatalytic degradation of wastewater
CN103241874B (en) * 2013-04-18 2015-12-02 宁波大学 The Microwave photocatalytic wastewater degradation device expansion method that catalyst interception link is perfect again
CN103241875B (en) * 2013-04-18 2015-12-09 宁波大学 The High-capacity waste water degradation reactor that photocatalyst interception reuse mechanism is improved again
CN103241873B (en) * 2013-04-18 2016-05-11 宁波大学 The reactor expansion method of its catalyst interception mechanism upgrading of waste water photocatalytic degradation

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Effective date of registration: 20160906

Address after: 214237 Wuxi, Jiangsu City, Yixing Province Zhang Zhu industrial concentration area

Patentee after: Jiangsu, Environmental Engineering Co. Ltd.

Address before: District Yixing Zijing Environmental Protection Equipment Co Ltd 214231 Jiangsu city of Yixing Province Zhang Zhu Zhen Industrial

Patentee before: Amethyst Yixing Environmental Protection Equipment Co., Ltd.

CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: Zhang Zhu Zhen 214231 Jiangsu city in Wuxi Province, Yixing City, South Gate Village

Patentee after: Jiangsu Dakai Environmental Engineering Co. Ltd.

Address before: 214237 Wuxi, Jiangsu City, Yixing Province Zhang Zhu industrial concentration area

Patentee before: Jiangsu, Environmental Engineering Co. Ltd.

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Effective date of registration: 20180528

Address after: 710077 Xi'an, Yanta District, Shaanxi, north of Jinye two Road North yycui garden first a 6 unit, 21 floors 62102 rooms.

Patentee after: Shaanxi Hai Ji Ya Environmental Protection Technology Co., Ltd.

Address before: 214231 South Gate Village, Zhang Zhu Town, Yixing City, Wuxi, Jiangsu

Patentee before: Jiangsu Dakai Environmental Engineering Co. Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110511

Termination date: 20190316