CN101501174B

CN101501174B - Perfume delivery systems for consumer goods

Info

Publication number: CN101501174B
Application number: CN200780018848.5A
Authority: CN
Inventors: R·R·戴克斯特拉
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 2006-05-23
Filing date: 2007-05-21
Publication date: 2013-08-21
Anticipated expiration: 2027-05-21
Also published as: ZA200808873B; CN101501174A

Abstract

The present invention relates to perfume delivery systems, products comprising such systems and the use of same. Unfortunately current perfume delivery systems do not always provide the most preferred or ideal sensory experience. Thus there is a need for one or more perfume delivery systems that obviate the short comings of the current perfume delivery technologies. The systems of the present invention meet the aforementioned need as they employ symbiotic combinations.

Description

The perfume delivery systems that is used for the consumer's goods

Background of invention

Product such as the consumer's goods are designed usually and/or are mixed with and comprise perfume systems.Select and use at least three crucial moments of the common experience of human consumer of this series products.Normally buy for first crucial moment constantly, with product application and use beginning, begin with using the back and follow hard on product application the 3rd crucial moment usually for second crucial moment usually.Regrettably, present perfume delivery systems did not always provide most preferably or desirable sensory experience during this type of crucial moment.Therefore, need one or more can overcome the perfume delivery systems of the shortcoming of present perfume delivery technology.Perfume systems of the present invention has satisfied the demand.

Summary of the invention

The present invention relates to perfume delivery systems, comprise product of this type of system and uses thereof.

Detailed Description Of The Invention

Definition

As used herein, " FMOT " referred to for first crucial moment.

As used herein, " SMOT " referred to for second crucial moment.

As used herein, " TMOT " referred to for the 3rd crucial moment.

As used herein, " PRM " refers to perfume base.

As used herein, " perfume delivery systems " comprises the combination of single perfume delivery technology and/or perfume delivery technology.

As used herein, term " perfume systems " and " perfume delivery systems " are synonyms.

Except as otherwise noted, as used herein, " consumer's goods " comprise goods, Baby Care product, beauty care items, fabric and care and household product, home care product, feminine care product, Health Care, snack and/or drink product or are intended to and be used or consume and be not intended to for industrial production or improved device subsequently with its sale form.This series products includes but not limited to diaper, bib, cleaning piece; For the treatment of product and/or the methods involving of hair (people, dog and/or cat), comprise that bleaching, painted, dyeing, conditioning, shampoo send out, finalize the design; Reodorant and antiperspirant; Personal cleansing product comprises sanitising agent, preserve moisture sanitising agent and their combination; Makeup; Skin care comprises and uses white cream, lotion, mousse, facial mask, strips off composition, decorticating agent and their combination; The hair removing product comprises the hair removing product that device is auxiliary; The shaving product; And other topical application product that uses for the human consumer; For the treatment of any other surperficial product and/or methods involving in fabric, hard surface and fabric and the household care field, comprising: air nursing product, car care product, dish washing product, fabric conditioner (comprising softener), clothes washing washing agent, clothes washing and rinsing additive and/or nursing agent, hard surface cleaners and/or treatment agent and other sanitising agent for human consumer or public place use; The product and/or the method that relate to toilet paper, medicated napkin, paper handkerchief and/or paper handkerchief; Tampon, sanitary napkin; The product and/or the method that relate to mouth care comprise toothpaste, gutta-percha, tooth cough lotion, adhesive of tooth, brightener for tooth; The OTC (over-the-counter) healthcare products comprise cough and cold medicine, analgesic agent, pet care and nutritious prod and desalt product; Mainly be intended to for edible between habitual meals or as the processed food of going with rice or bread (limiting examples comprises potato chips, tortilla chips, puffed rice, spiced salt cracknel, corn flakes, cereal bar, vegetables slice or crisp, mixes dessert, mixes party food, many cereal sheet, dessert rusk, cheese dessert, pork rind, corn dessert, ball shape dessert, extruding puffing dessert and bagel sheet); And coffee and cleaning and/or treatment compositions.

Except as otherwise noted, as used herein, term " cleaning and/or treatment compositions " comprises multi-functional or " heavy duty type " washing composition, the especially cleaning detergent of sheet, particulate state or powdery; Liquid, gel or pasty state multifunctional detergent, especially usually said heavy duty type liquid type; Liquid high-count fabric washing composition; Detergent for washing dishware with hand or light-duty dishwashing agent, those of especially high alveolitoid; The machine washing dish washing detergent comprises various sheet, particulate state, liquid and rinse aid type washing composition for family and public place use; Liquid cleaner and sterilizing agent comprise antibiotic hand washing type, cleansing soap, collutory, denture cleanser, automobile or carpet cleaner, bathroom detergent; Shampoo and hair conditioner; Bath gels and bubble bath and metal detergent; And the cleaning assistant agent, such as bleaching assistant and " decontamination rod " or pre-treatment type auxiliary agent, substrate loading stocks, for example be added with thin slice, drying and wetting cleaning piece and pad, nonwoven substrate and the cavernous body of siccative; And spray and propellant.

Except as otherwise noted, as used herein, term " fabric " care composition " comprise fabric softening compositions, fabric enhancing compositions, the pure and fresh composition of fabric and their combination.

As used herein, term " solid " comprises particle, powder, bar-shaped and tablet product form.

As used herein, term " zone " comprises paper product, fabric, clothes, hard surface, hair and skin.

When being used for claim, article used herein "/a kind of " is understood to mean one or more things that is subjected to claims protection or describes.

Except as otherwise noted, for purpose of the present invention, term " monomer assisted delivery " and " material assisted delivery " are in the category of term " molecule assisted delivery ".

Except as otherwise noted, for the purposes of this invention, term " molecule " and " non-polymer " are in the category of term " monomer ".

Except as otherwise noted, for the purposes of this invention, term " perfumery nano capsule " and " microcapsule " are in the category of term " perfume microcapsule ".

Except as otherwise noted, all components or composition levels all are the activity substance contents about this component or composition, do not comprise the impurity in the source that may be present in commercially available acquisition, for example residual solvent or byproduct.

Except as otherwise noted, all per-cents and ratio are all calculated by weight.Except as otherwise noted, all per-cents and ratio all calculate based on whole packaged products, and it comprises product and product substrate composition.

Should be appreciated that each the greatest measure limit that provides in whole specification sheets comprises each than low numerical value limit, just low numerical value limit like this is to write out clearly equally in this article.Each the minimum value limit that provides in whole specification sheets comprises each high value limit, and just high value limit like this is to write out clearly equally in this article.Each numerical range that provides in whole specification sheets comprises each the narrower numerical range that drops in this broader numerical, and just narrower numerical range like this is to write out clearly equally in this article.

Dimension disclosed herein and value are not intended to be understood that strictly to be limited to described exact value.On the contrary, except as otherwise noted, each such dimension refers to the numerical value of quoting and centers on the scope that is equal on the function of this numerical value.For example, the dimension that is disclosed as " 40mm " is intended to expression " about 40mm ".

Perfume delivery systems

The human consumer who selects and use this type of incense products makes important judge for his or her satisfactory degree at a plurality of point of contact place of product use pattern for product.Though known have numerous point of contact, the applicant finds, they advantageously can be sorted out and state as common human consumer experiences three product crucial moments.FMOT is normally buying constantly, and SMOT is usually with product application with use beginning, and TMOT follows hard on product application usually and use the back and begin.The applicant recognizes, because the packing of product has suppressed sensory experience, has therefore influenced human consumer's FMOT unfriendly; For example, the packing of product can make product be difficult to open, and the product that may spill is exposed.In addition, preparation becomes branch to suppress and/or twist the smell of straight product.In addition, the applicant recognizes, because volatile PRM loses during product stock, thereby causes the reduction of strong degree between the usage period, therefore influenced human consumer's SMOT unfriendly.By adding the scent experience of high load of perfume when compensating above-mentioned these not enough can distortion uses at TMOT, so that spices is strong spends in pungent or strong, and/or fragrance characteristics can become more not preferred.The applicant also recognizes, since spices in long time from treatment zone particularly dry fabric discharge scent experience during flavour content the product that needs will twist for first and second crucial moments, therefore influenced human consumer's FMOT unfriendly.In addition, the spices that adds high-content at SMOT and TMOT can twist the smell of straight product, and still can not cause by washing enough spices depositions being arranged.In addition, the spices volatilization that takes place between dry epoch can cause the flavour content on the fabric to reduce; And/or the spices that remains on the dry fabric can provide initial dry fabric smell beneficial effect, and is too fast but this type of spices dissipates, and sufficient lasting fragrance beneficial effect can't be provided.In addition, being present in the speed that the spices on the fabric discharges from fabric may be too slow.As mentioned above, perfume delivery to and discharge from other zone such as hair and skin, situation is identical.The ability of noticing spices release is subjected to multiple factor such as hair length, is through the influence of the clothes on the skin, regional washing frequency etc.Washing or rinsing or use during unsettled deposition and release be another defective that influences scent experience during different crucial moments unfriendly.Processing or application times also are influential, for example wherein to comparing after the washing first time of specific region with after the subsequent wash, can obtain different intensity and/or characteristic.In addition, compares with the arid region with containing the wetting zones that spice product handles, can feel different perfume intensity and/or characteristic.Not bound by theory, except between dry epoch, owing to evaporation makes the perfume loss, owing in being written into or being doped to such as zones such as cotton fibre, hair, skins, also can cause the spices availability to reduce at some point of contact place.The zone moisture content also can be used for changing release characteristics or the rate of release of spices.

At last, the applicant finds that the problem terms of settlement relevant with one or two crucial moment is not enough to solve the problem relevant with remaining crucial moment, or can influence other crucial moment unfriendly.

Below also be known as the form that the perfume delivery technology (PDT) of perfume delivery systems can arbitrary combination and be used for any kind consumer's goods:

Polymkeric substance assisted delivery (PAD): this perfume delivery technology uses polymeric material to send fragrance material.Some examples are classical condensation product, water-soluble or part water-soluble extremely undissolved charged or neutral polymer, liquid crystal, heat fusing thing, hydrogel, fragrant plastics, microcapsule, nano rubber latex and fine latex, polymer film-forming agent and polymer absorbing agent, polymer absorbant etc.PAD includes but not limited to:

Matrix system: perfume compound dissolves and is scattered in polymeric matrix or the particle.For example, spices can 1) be dispersed in the polymkeric substance before in being formulated into product, or 2) during the product preparation or afterwards, separate adding with described polymkeric substance.Though known many other trigger mechanisms that spices discharges of controlling, but the diffusion of spices from described polymkeric substance is a kind of common trigger mechanism, it can make and discharge in the spices autohemagglutination compound matrix system or increase rate of release, described polymeric matrix system sedimentation or be applied on the desired surface (zone), the feature of this technology be absorb and/or be adsorbed within polymer beads, film, the solution etc. or on.Example is nano particle or the particulate that is made of organic materials (for example latex).Suitable particle comprises multiple material, include but not limited to polyoxymethylene, polyacrylic ester, polyacrylic acid, polyacrylonitrile, polymeric amide, polyaryletherketone, polyhutadiene, polybutene, poly-terephthalic acid butanediol ester, sovprene, polyethylene, polyethylene terephthalate, the poly terephthalic acid hexanaphthene is to the diformazan alcohol ester, polycarbonate, sovprene, polyhydroxyalkanoatefrom, polyketone, polyester, polyethylene, polyetherimide, polyethersulfone, chlorinatedpolyethylene, polyimide, polyisoprene, poly(lactic acid), polymethylpentene, polyphenylene oxide, polyphenylene sulfide, polyphthalamide, polypropylene, polystyrene, polysulfones, polyvinyl acetate, polyvinyl chloride, and based on acrylonitrile-butadiene, cellulose ethanoate, ethane-acetic acid ethyenyl ester, ethylene-vinyl alcohol, styrene butadiene, the polymkeric substance of vinyl-acetic ester-ethene or multipolymer, and their mixture.

" standard " system refers to " preload " being intended to keep the preload spices with described polymer associate, discharges constantly or some constantly those of discharging until spices.This base polymer also can suppress the straight product smell, and can provide strong property and/or persistence beneficial effect according to the spices rate of release.A challenge of this type of system is 1) product internal stability (keep spices in carrier, need it until you) and 2) regularly discharge between (between the usage period or from the arid region) and obtain optimum balance.In product, during storage and the aging of product, obtain this type of stability and be even more important.For the water based product that comprises tensio-active agent such as heavy duty type liquid laundry detergent, this challenge is especially obvious.When being mixed with water based product, many " standard " matrix systems that can effectively obtain can become " balance " system.Can select " balance " system or storage system, it has acceptable product internal diffusion stability and available release trigger mechanism (as friction)." balance " system is wherein spices and polymkeric substance to be joined balance interaction in the product and between spices and polymkeric substance respectively to produce those of beneficial effect (with respect to the free spice contrast of no polymkeric substance assisted delivery technology) at one or more human consumer's point of contact place.But described polymkeric substance is preload spices also, yet part or all of spices can diffusion reach balance between the shelf lives in product, and it comprises the desired perfume base (PRM) that has with described polymer associate.Follow described polymkeric substance spices is carried into the surface, and spread to discharge via spices usually.The use of this type of equilibrium system polymkeric substance has the possibility (usually under preload standards system situation more likely) of the straight product odor intensity that reduces straight product.The deposition of this base polymer can be used for " evening up " release characteristics and persistent increase is provided.As mentioned above, can obtain this persistence by suppressing initial strength, and can make formulator use the PRM of higher sense or low odor detection threshold (ODT) or low Kovats index (KI) to obtain the FMOT beneficial effect, and not have the initial strength of too strong or distortion.Importantly, spices is released in the time of application section and takes place, to influence desired human consumer's point of contact or a plurality of point of contact.Suitable particulate and fine latex and preparation method thereof can be referring to USPA 2005/0003980A1.Matrix system also comprises hotmelt and fragrant plastics.In addition, the polysaccharide of hydrophobically modified can be formulated into and send out in the incense products, discharge to increase the spices deposition and/or to improve spices.All these type of matrix systems comprise for example polysaccharide and nano rubber latex, can mix with other PDT, comprise other PAD system, such as the PAD storage system of perfume microcapsule (PMC) form.Polymkeric substance assisted delivery (PAD) matrix system can comprise below with reference to described in the document those: U.S. Patent application 2004/0110648 A1; 2004/0092414 A1; 2004/0091445 A1 and 2004/0087476 A1; With United States Patent (USP) 6,531,444; 6,024,943; 6,042,792; 6,051,540; 4,540,721 and 4,973,422.

Siloxanes also is the examples of polymer that can be used as PDT, and the mode that can be similar to polymkeric substance assisted delivery " matrix system " provides fragrant beneficial effect.This type of PDT is called as siloxanes assisted delivery (SAD).But preload contains the siloxanes of spices, perhaps uses them as the equilibrium system described in PAD.Suitable siloxanes and preparation thereof can be referring to WO2005/102261; USPA 20050124530A1; USPA 20050143282A1; And WO2003/015736.Described in USPA 2006/003913 A1, also can use functionalized silicone.The example of siloxanes comprises polydimethylsiloxane and poly-alkyl-dimethyl radical siloxane.Other example comprises those with amine functional group, and it can be used to provide the beneficial effect relevant with amine assisted delivery (AAD) and/or polymkeric substance assisted delivery (PAD) and/or amine reaction product (ARP).Other this type of example can be referring to USP 4,911,852; USPA 2004/0058845 A1; USPA2004/0092425 A1 and USPA 2005/0003980 A1.

The storage system: the storage system also is called as core-shell-type technology, and perhaps wherein the perfume compound spices that be can be used as the protectiveness shell discharges the membrane-enclosed technology of control.Material in the microcapsule is called as core, interior phase or weighting material, and sometimes wall is called shell, dressing or film.Particulate or pressure-sensitive capsule or microcapsule are examples of this technology.Microcapsule of the present invention can be formed by several different methods, include but not limited to be coated with, extrude, spraying drying, interfacial polymerization, polymerization in situ and matrix polymerization.Possible sheating material is very different to tool aspect water stable at them.The most stable material that is based on polyoxymethylene urea (PMU) wherein, it can keep considerable time with some PRM in the aqueous solution (or product).This type of system includes but not limited to melocol and/or carbamide.Can prepare the microcapsule based on gelatin, to make them be dissolved in the water fast or lentamente according to for example degree of crosslinking.Can obtain many other capsule wall material and its apparent spices diffusion stability differences.Not bound by theory, after for example being deposited on the surface, the speed that spices discharges from capsule usually and in the product spices spread stable inverse correlation.Equally, for example, melocol and carbamide microcapsule need be different from diffusion release or the releasing mechanism except diffusion discharges usually, such as the mechanical force (as friction, extruding, shear-stress) that is used for making capsules break and increases spices (perfume compound) rate of release.Other trigger mechanism comprises fusion, dissolving, hydrolysis or other chemical reaction, electromagnetic radiation etc.The adequate rate of (on the zone) release is gone up on when the use of preload microcapsule needs the interior stability of product and application and/or surface, and the suitable selection of PRM.Microcapsule based on melocol and/or carbamide are more stable, especially in almost neutral group water solution.These material requires may not be suitable for the friction trigger mechanism of all product application.Other microencapsulation material (for example gelatin) may be unsettled in water based product, and when aging in the product, may even can provide weakened beneficial effect (with respect to the free spice contrast).Another example that it is PAD that fragrant technology is given birth in scraping.Perfume microcapsule (PMC) comprises and is described in the following reference those: U.S. Patent application: 2003/0125222 A1; 2003/215417 A1; 2003/216488 A1; 2003/158344 A1; 2003/165692 A1; 2004/071742 A1; 2004/071746 A1; 2004/072719 A1; 2004/072720 A1; 2006/0039934 A1; 2003/203829 A1; 2003/195133 A1; 2004/087477 A1; 2004/0106536 A1; With United States Patent (USP) 6,645,479 B1; 6,200,949 B1; 4,882,220; 4,917,920; 4,514,461; 6,106,875 and 4,234,627,3,594,328 and US RE 32713.

Molecule assisted delivery (MAD): non-cohesive material or molecule also can be used for improving perfume delivery.Not bound by theory, spices can with the organic materials noncovalent interaction, thereby cause the change that deposits and/or discharge.The limiting examples of this type of organic materials includes but not limited to hydrophobic material such as organic oil, wax, mineral oil, Vaseline, fatty acid or ester, sugar, tensio-active agent, liposome and other perfume base (spice oil) and comprises body and/or the natural oil of other dirt.Perfume fixative is another example.In one aspect, non-cohesive material or molecule have the CLogP greater than about 2.Molecule assisted delivery (MAD) also comprises and is described in USP7, those in 119,060 and USP5,506,201.

Fiber assisted delivery (FAD): select or use the regional perfume delivery that self can be used for improving.In fact, the zone self can be the perfume delivery technology.For example, different fabric type such as cotton or polyester are for attracting and/or keeping and/or the ability that discharges spices has different characteristics.Can be by the selection of fiber, and origin or processing by fiber, and by any fiber coat or handle change be deposited on the fiber or within amount of flavorants.Fiber can be woven material and nonwoven material and natural or synthetic materials.Natural fiber comprises those that are produced by plant, animal and geologic function, and includes but not limited to cellulose materials such as cotton, linen, hemp, jute, flax, ramie and sisal hemp and for the manufacture of the fiber of paper and cloth.The fiber assisted delivery can comprise the use wood fibre, such as thermodynamics wood pulp and bleaching or unbleached kraft pulp or sulfite pulp.Animal fibre mainly is made of particular proteins, such as silk, muscle, gutstring and hair (comprising wool).Polymer fiber based on synthetic chemistry includes but not limited to polyamide nylon, PET or PBT polyester, P-F (PF), polyvinyl alcohol fiber (PVOH), thermovyl (PVC), polyolefine (PP and PE) and acrylic polymers.But this all fibrids is preload spices all, joins then in the product that comprises or do not comprise free spice and/or one or more perfume delivery technology.In one aspect, before load spices, fiber is joined in the product, come load spices by in product, adding the spices that can be diffused in the fiber then.Not bound by theory, during product stock for example, described spices can be adsorbed on the fiber or absorbs in the fiber, then discharges at one or more crucial moments or human consumer's point of contact place.

Amine assisted delivery (AAD): amine assisted delivery technological method uses the material that comprises amido, discharges to increase the spices deposition at product between the usage period or to improve spices.In this method, need not in joining product before with the pre-compound or pre-reaction of perfume base and amine.In one aspect, be applicable to that the amine AAD material that contains of this paper can be non-aromatic, for example poly-alkyl imines such as polymine (PEI) or polyvinylamine (PVAm) maybe can be aromatics, for example cinnamyl o-aminobenzoate.This type of material can also be polymerization or non-polymeric.In one aspect, this type of material comprises at least a primary amine.This technology can also increase persistence and controllable release to low ODT aromatic (for example aldehyde, ketone, ketenes) via amine functional group, and is not bound by theory, and can send other PRM via the polymkeric substance assisted delivery relevant with polymeric amine.There is not this technology, the too fast forfeiture of a volatile top group of Buddhists going together on a pilgrimage, thus ratio fragrant and bottom note and top perfume is higher in making.The use of polymeric amine can make top content fragrant and other stand-by PRM higher, can not cause the straight product smell stronger than desired to obtain lasting fresh scent, maybe can make the top fragrant and other stand-by PRM is more effective.In one aspect, the AAD system can be sent PRM effectively under the pH that is higher than about neutrality.Not bound by theory, therein in the AAD system more polyamines can be caused increasing for the deprotonation amine avidity of PRM such as aldehyde and ketone (comprising that undersaturated ketone and ketenes are such as damascone) by the situation of deprotonation.In yet another aspect, polymeric amine can be sent PRM effectively under the pH that is lower than about neutrality.Not bound by theory, therein in the AAD system the more protonated situation of polyamines can cause reducing for the protonated amines avidity of PRM such as aldehyde and ketone, and the polymer architecture avidity that is used for numerous PRM strengthens.In this regard, the polymkeric substance assisted delivery can be sent and more be sent out beneficial effect fragrant; This type of system is the subclass of AAD, and can be called as amine-polymkeric substance-assisted delivery or APAD.In some cases, be lower than 7 composition when APAD is used for pH, this type of APAD system also can be considered to polymkeric substance assisted delivery (PAD).On the other hand, AAD and PAD system can with other material such as anion surfactant or interpolymer interaction to form coacervate and/or cohesion layered system.On the other hand, comprise denitrogenate beyond heteroatoms for example the material of sulphur, phosphorus or selenium can be used as the surrogate of amine compound.On the other hand, above-mentioned alternative compounds can be united use with amine compound.On the other hand, individual molecule can comprise amine moiety and one or more alternative heteroatom moiety, for example mercaptan, phosphine and selenol.Suitable AAD system and preparation method thereof can be referring to U.S. Patent application 2005/0003980 A1,2003/0199422A1,2003/0036489 A1,2004/0220074 A1 and USP6,103,678.

Cyclodextrin (CD): this technological method uses cyclic oligosaccharide or cyclodextrin to improve perfume delivery.Usually can form the mixture of spices and cyclodextrin (CD).This type of mixture can be preformed, form on the spot or on the zone or within form.Not bound by theory, dehydration can be used for making balance to shift to CD-spices mixture, does not especially exist with spices competition cyclodextrin cavity the time with high density when other ancillary component (as tensio-active agent).If take place to contact with water or increase water content at later time point, then can obtain strong property beneficial effect.In addition, cyclodextrin can increase the handiness that the spices formulator is selected PRM.But cyclodextrin preload spices, or separate adding with spices, to obtain desired spices stability, deposition or to discharge beneficial effect.Suitable CD and preparation method thereof can be referring to USPA2005/0003980 A1 and 2006/0263313 A1 and United States Patent (USP) 5,552,378; 3,812,011; 4,317,881; 4,418,144 and 4,378,923.

The starch capsule is sealed temper (SEA): using the starch capsule to seal temper (SEA) technology can be by for example being transformed into the characteristic that solid improves spices via adding composition such as starch with liquid perfume.Described beneficial effect comprise increase product stock during, the retention of spices during the product stock under the especially non-aqueous condition.Contacting with moisture can the strong release of triggering spices.Because starch can make the product formulator be chosen in the concentration of one or more PRM that can not use usually when not having SEA, therefore also can locate to obtain beneficial effect at other crucial moment.Another kind of technical examples comprises uses other organic and inorganic materials such as silicon-dioxide, so that spices is transformed into solid from liquid.Suitable SEA and preparation method thereof can be referring to USPA2005/0003980 A1 and USP6,458,754 B1.

Zeolite and inorganic carrier (ZIC): this technology relates to uses porous zeolite or other inorganic materials to send spices.Be loaded with spices zeolite can with or do not use with ancillary component, described ancillary component is used for the zeolite (PLZ) that for example coating is loaded with spices, to change it during the product stock or between the usage period or discharged the characteristic of spices by the arid region.Suitable zeolite and inorganic carrier and preparation method thereof can be referring to USPA2005/0003980 A1 and United States Patent (USP)s 5,858,959; 6,245,732 B1; 6,048,830 and 4,539,135.Silicon-dioxide is the another kind of form of ZIC.Another example of suitable inorganic carrier comprises inorganic tubule, and wherein spices or other active substance are contained in the tube chamber of nanotube or microtubule.Preferably, inorganic tubule tubule or the PLT of spices (or be loaded with) that is loaded with spices is mineral substance nanotube or microtubule, such as the mixture of halloysite or halloysite and other inorganic materials (comprising other clay).The PLT technology also comprises the supplementary component on tubule inboard and/or the outside, the product internal diffusion stability of load spices, the deposition on desired zone or control rate of release to improve.Monomer and/or polymeric material (comprising starch capsule encapsulation object) can be used for coating, obstruction, cap seal or in other words capsule seal PLT.Suitable PLT system and preparation method thereof can be referring to USP5, and 651,976.

Preceding spices (PP): this technology relates to the spices technology, and described technology causes fragrance material and other matrix or chemicals reaction, to be formed on the material that has covalent linkage between one or more PRM and one or more carriers.Described PRM is transformed into the novel substance that is called preceding PRM (namely before spices), and then with after trigger mechanism such as water or light contact, it can discharge original PRM.Preceding spices can provide the perfume delivery characteristic of enhancing, such as the spices deposition that strengthens, persistence, stability, retention etc.Preceding spices is included as those of monomer (non-polymer) or polymkeric substance, and can be preformed or formation on the spot under equilibrium conditions, such as being present in those between the shelf lives or on wetting or the arid region in the product.The limiting examples of preceding spices comprises Michael-adduct (for example beta-amino ketones), aromatics or non-aromatic imines (Schiff's base), oxazolidine, 'beta '-ketoester or ortho ester.Comprise the compound that comprises one or more β-oxos or β-thiocarbonyl part on the other hand, described compound can discharge PRM, for example alpha, beta-unsaturated ketone, aldehyde or carboxylicesters.The typical trigger mechanism that is used for spices release is contact water; Yet other trigger mechanism can comprise that enzyme, heat, light, pH variation, natural oxidation, balance move, concentration or ionic strength change etc.For water based product, light-triggered preceding spices especially suits.This type of light-preceding spices (PPP) discharges those of coumarin derivatives and spices and/or preceding spices when including but not limited to trigger.The preceding spices that discharges can discharge one or more PRM via above-mentioned any trigger mechanism.In one aspect, when contact light and/or moisture trigger mechanism, light-preceding spices discharges the preceding spices based on nitrogen.On the other hand, the preceding spices based on nitrogen that is discharged by light-preceding spices discharges one or more PRM, and described PRM is selected from for example aldehyde, ketone (comprising ketenes) and alcohol.On the other hand, described PPP also discharges the dihydroxycoumarin derivative.Spices can also be ester before described light triggered, and it can discharge coumarin derivatives and perfume alcohol.In one aspect, described preceding spices is the dimethoxy st-yrax derivative described in USPA 2006/0020459 A1.On the other hand, described preceding spices is 3 ', 5 '-dimethoxy st-yrax (DMB) derivative that discharges alcohol when the contact electricity magnetic radiation.Aspect another, described preceding spices discharges the PRM of one or more low ODT, comprises the tertiary alcohol such as linalool, Tetrahydrolinalool or dihydromyrcenol.Suitable preceding spices and preparation method thereof can be referring to United States Patent (USP) 7,018,978 B2; 6,987,084 B2; 6,956,013 B2; 6,861,402 B1; 6,544,945 B1; 6,093,691; 6,277,796 B1; 6,165,953; 6,316,397 B1; 6,437,150 B1; 6,479,682 B1; 6,096,918; 6,218,355 B1; 6,133,228; 6,147,037; 7,109,153B2; 7,071,151 B2; 6,987,084 B2; 6,610,646 B2 and 5,958,870, and can be referring to USPA 2005/0003980 A1 and USPA 2006/0223726 A1.

Amine reaction product (ARP): for the present patent application purpose, ARP is subclass or the type of PP.Also can use " reactivity " polymeric amine, wherein with one or more PRM pre-treatment amine functionality to form amine reaction product (ARP).Usually, reactive amine is primary amine and/or secondary amine, and can be the part of polymkeric substance or monomer (non-polymer).This type of ARP also can mix to provide polymkeric substance assisted delivery and/or amine assisted delivery beneficial effect with extra PRM.The limiting examples of polymeric amine comprises the polymkeric substance based on poly-alkyl imines, such as polymine (PEI) or polyvinylamine (PVAm).The limiting examples of monomer (non-polymeric) amine comprises: azanol, such as 2-monoethanolamine and alkyl-substituted derivatives; And arylamine, such as anthranilate.Described ARP can with the spices premix, perhaps can join separately during leave or washing-off type use.On the other hand, comprise denitrogenate beyond heteroatoms for example the material of oxygen, sulphur, phosphorus or selenium can be used as the surrogate of amine compound.Aspect another, above-mentioned alternative compounds can be united use with amine compound.Aspect another, individual molecule can comprise amine moiety and one or more alternative heteroatom moiety, for example mercaptan, phosphine and selenol.Described beneficial effect comprises and improves perfume delivery and control spices discharges.Suitable ARP and preparation method thereof can be referring to USPA 2005/0003980 A1 and USP 6,413,920 B1.

Spices design (PD): wherein utilize the physical property of perfume base to produce the spices of functional spices and/or the appropriate design of spices fragrant-inner agent also is considered to the perfume delivery technology.The design of this type of spices can with or do not use with above-mentioned one or more technology.When with or when not using with above-mentioned one or more technology, described technology also is called as " free spice ".Can be used for surface-area that non-restrictive characteristic in the spices design includes but not limited to that octanol-water partition coefficient (LogP or CLopP), water solubility parameter, boiling point (bp), Kovats index (KI) value, solvent can contact etc.Odor detection threshold (ODT) value also can be used for designing spices or the spices fragrant-inner agent with preferred sense of smell characteristic, and it can replenish or allow to use one or more other perfume delivery technology.Suitable spices design (PD) volume and preparation method thereof can be referring to United States Patent (USP) 2007/0042934 A1,2005/0003980 A1,2007/0071780 A1 and USP6,998,382.

Though during FMOT, SMOT and/or TMOT, can be used alone or in combination the sense organ beneficial effect that above-mentioned technology is improved product, especially can be used for improving the combination of the whole sensory experience that product provides below the applicant discloses.

Other side is identical with disclosed aspect in the last table 1, and different is that this other side does not comprise the FMOT technology, does not for example comprise packing and/or the demonstration that comprises spices and/or one or more perfume delivery systems in this respect.

Therefore, the packaged products aspect can comprise following these:

All aspects 1

In one aspect, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: free spice, one or more perfume delivery systems and their mixture; And described product matrix can comprise free spice and/or one or more perfume delivery systems.In this regard, described packing can comprise about 0.001% to about 10% based on overall package weight, about 0.03% to about 3%, or even about 0.03% to about 0.3% free spice and/or about 0.001% to about 50%, about 0.01% to about 20%, or even one or more spices package delivery systems of about 0.01% to about 5%, and described product matrix can comprise about 0.001% to about 30% based on total product matrix weight, about 0.05% to about 10%, or even about 0.1% to about 3% free spice and/or about 0.001% to about 60%, about 0.05% to about 25%, or even one or more perfume delivery systems of about 0.1% to about 8%.Aspect above-mentioned, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

All aspects 2

On the other hand, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: heat fusing delivery system, the plastics that are loaded with spices and their mixture; And described product matrix can comprise sends out material fragrant, describedly sends out material fragrant and is selected from the group of being made up of following: free spice, polymkeric substance assisted delivery (PAD), molecule assisted delivery (MAD), amine assisted delivery (AAD), fiber assisted delivery (FAD), cyclodextrin (CD), starch capsule are sealed temper (SEA), zeolite/inorganic carrier system (ZIC) and preceding spices (PP) system and their mixture.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

All aspects 3

On the other hand, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: heat fusing delivery system, the plastics that are loaded with spices and their mixture; And described product matrix can comprise sends out material fragrant, describedly sends out material fragrant and is selected from the group of being made up of following: spices, nano rubber latex, siloxanes assisted delivery (SAD), polymeric amine assisted delivery before free spice, perfume microcapsule (PMC), cyclodextrin, starch capsule are sealed temper, water and triggered, capsule is sealed or wrap the zeolite that is loaded with spices of quilt, the tubule (PLT) that is loaded with spices, amine reaction product (ARP), light-preceding spices (PPP) and their mixture.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Fluid aspect 1

On the other hand, disclose packaged products, wherein said packing can comprise spices and pack/show delivery system, and described system is selected from the group of being made up of following: free spice, one or more perfume delivery systems and their mixture; And described product matrix can comprise fluid, and described fluid can comprise free spice and/or one or more perfume delivery systems.In this regard, described packing can comprise about 0.001% to about 10% based on overall package weight, about 0.03% to about 3%, or even about 0.03% to about 0.3% free spice and/or about 0.001% to about 50%, about 0.01% to about 20%, or even one or more spices package delivery systems of about 0.01% to about 5%, and described product matrix can comprise about 0.001% to about 30% based on total product matrix weight, about 0.05% to about 10%, or even about 0.1% to about 3% free spice and/or about 0.001% to about 30%, about 0.05% to about 15%, or even one or more perfume delivery systems of about 0.1% to about 5%.Aspect above-mentioned, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Aqueous fluid aspect 1

On the other hand, packaged products is disclosed, wherein said packing can comprise spices package delivery system, described system is selected from the group of being made up of following: free spice and/or one or more perfume delivery systems, and described product matrix can comprise about 2% to about 99.9% based on total product matrix weight, about 5% to about 99%, about 10% to about 98%, about 20% to about 95%, or even about 25% to about 90% water and send out material fragrant, describedly send out material fragrant and be selected from the group of being formed by following: free spice, the polymkeric substance assisted delivery, the amine assisted delivery, preceding spices, the molecule assisted delivery, zeolite/inorganic carrier system, and their mixture.In this regard, described packing can comprise about 0.001% to about 10% based on overall package weight, about 0.03% to about 3%, or even about 0.03% to about 0.3% free spice and/or about 0.001% to about 50%, about 0.01% to about 20%, or even one or more spices package delivery systems of about 0.01% to about 5%, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Aqueous fluid aspect 2

On the other hand, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: heat fusing delivery system, the plastics that are loaded with spices and their mixture; And described product matrix can comprise about 2% to about 99.9% based on total product matrix weight, about 5% to about 99%, about 10% to about 98%, about 20% to about 95%, or even about 25% to about 90% water and send out material fragrant, describedly send out material fragrant and be selected from the group of being made up of following: the Kovats index value is less than about 1500, less than about 1500 to about 800, or even less than about 1400 to about 1000 the free spice with PRM, cyclodextrin, the starch capsule is sealed temper, spices before water triggers, microcapsule, be loaded with the zeolite of spices, be loaded with the tubule of spices, amine reaction product, light-preceding perfume delivery systems, and their mixture.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, described product matrix can comprise 0.0001% to about 60% based on total product matrix weight, about 0.005% to about 25%, or even about 0.01% to about 8% Kovats index value less than about 1500, less than about 1500 to about 800, or even less than about 1400 to about 1000 described spices.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Non-aqueous fluid aspect 1

On the other hand, packaged products is disclosed, wherein said packing can comprise spices package delivery system, described system is selected from the group of being made up of following: free spice and/or one or more perfume delivery systems, and described product matrix can comprise non-aqueous fluid and send out material fragrant, describedly sends out material fragrant and is selected from the group of being made up of following: free spice, cyclodextrin, the starch capsule is sealed temper, the polymkeric substance assisted delivery, preceding spices, the polymkeric substance assisted delivery, the molecule assisted delivery, the amine assisted delivery, zeolite/inorganic carrier delivery system, and their mixture.In this regard, described packing can comprise about 0.001% to about 10% based on overall package weight, about 0.03% to about 3%, or even about 0.03% to about 0.3% free spice and/or about 0.001% to about 50%, about 0.01% to about 20%, or even one or more spices package delivery systems of about 0.01% to about 5%, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Non-aqueous fluid aspect 2

On the other hand, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: heat fusing delivery system, the plastics that are loaded with spices and their mixture; And described product matrix can comprise about 2% to about 99.9% based on total product matrix weight, about 5% to about 99%, about 10% to about 98%, about 20% to about 95%, or even about 25% to about 90% non-aqueous fluid and send out material fragrant, describedly send out material fragrant and be selected from the group of being made up of following: the Kovats index value is less than about 1500, less than about 1500 to about 800, or even less than about 1400 to about 1000 the free spice with PRM, cyclodextrin, the starch capsule is sealed temper, spices before water triggers, microcapsule, be loaded with the zeolite of spices, be loaded with the tubule of spices, amine reaction product, light-preceding perfume delivery systems, and their mixture.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, described product matrix can comprise 0.0001% to about 60% based on total product matrix weight, about 0.005% to about 25%, or even about 0.01% to about 8% Kovats index value less than about 1500, less than about 1500 to about 800, or even less than about 1400 to about 1000 described spices.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Solid aspect 1

In yet another aspect, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: free spice, one or more perfume delivery systems and their mixture; And described product matrix can comprise solid, free spice and/or one or more perfume delivery systems.The described free spice of all or part and/or one or more perfume delivery systems can be present in the described solid.In this regard, described packing can comprise about 0.001% to about 10% based on overall package weight, about 0.03% to about 3%, or even about 0.03% to about 0.3% free spice and/or about 0.001% to about 50%, about 0.01% to about 20%, or even one or more spices package delivery systems of about 0.01% to about 5%, and described product matrix can comprise about 0.001% to about 30% based on total product matrix weight, about 0.05% to about 10%, or even about 0.1% to about 3% free spice and/or about 0.001% to about 30%, about 0.05% to about 15%, or even one or more perfume delivery systems of about 0.1% to about 5%.Aspect above-mentioned, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Solid aspect 2

On the other hand, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: heat fusing delivery system, the plastics that are loaded with spices and their mixture; And described product matrix can comprise solid and send out material fragrant, describedly sends out material fragrant and is selected from the group of being made up of following: free spice, cyclodextrin, starch capsule are sealed temper, polymkeric substance assisted delivery, preceding spices, molecule assisted delivery, amine assisted delivery, zeolite/inorganic carrier delivery system and their mixture.All or part is described to be sent out material fragrant and can be present in the described solid.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Solid aspect 3

On the other hand, disclose packaged products, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: heat fusing delivery system, the plastics that are loaded with spices and their mixture; And described product matrix can comprise solid and send out fragrant material, describedly send out material fragrant and be selected from the group of being made up of following: the Kovats index value is less than about 1500, less than about 1500 to about 800, or even seal temper, water and trigger less than about 1400 to about 1000 the free spice with PRM, cyclodextrin, starch capsule before spices, microcapsule, the zeolite that is loaded with spices, the tubule that is loaded with spices, amine reaction product, light-preceding spices and their mixture.All or part is described to be sent out material fragrant and can be present in the described solid.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described product matrix can comprise about 0.001% to about 60% based on total product matrix weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, described product matrix can comprise 0.0001% to about 60% based on total product matrix weight, about 0.005% to about 25%, or even about 0.01% to about 8% Kovats index value less than about 1500, less than about 1500 to about 800, or even less than about 1400 to about 1000 described spices.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Device aspect 1

In yet another aspect, disclose the device of packing, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: free spice, one or more perfume delivery systems and their mixture; And described device can comprise free spice and/or one or more perfume delivery systems.In this regard, described packing can comprise about 0.001% to about 10% based on overall package weight, about 0.03% to about 3%, or even about 0.03% to about 0.3% free spice and/or about 0.001% to about 50%, about 0.01% to about 20%, or even one or more spices package delivery systems of about 0.01% to about 5%, and described device can comprise about 0.001% to about 30% based on overall apparatus weight, about 0.05% to about 10%, or even about 0.1% to about 3% free spice and/or about 0.001% to about 30%, about 0.05% to about 15%, or even one or more perfume delivery systems of about 0.1% to about 5%.Aspect above-mentioned, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 or even about 1:10 about 5:1 extremely extremely.Aspect above-mentioned, in the device ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Device aspect 2

In yet another aspect, the device of packing is disclosed, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: free spice, cyclodextrin, starch capsule are sealed temper, polymkeric substance assisted delivery, preceding spices, molecule assisted delivery, amine assisted delivery, zeolite/inorganic carrier delivery system and their mixture.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described device can comprise about 0.001% to about 60% based on overall apparatus weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the device ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Device aspect 3

On the other hand, disclose the device of packing, wherein said packing can comprise spices package delivery system, and described system is selected from the group of being made up of following: heat fusing delivery system, the plastics that are loaded with spices and their mixture; And described device can comprise sends out material fragrant, describedly sends out material fragrant and is selected from the group of being made up of following: free spice, cyclodextrin, starch capsule are sealed temper, microcapsule, are loaded with the zeolite of spices, the tubule that is loaded with spices, amine reaction product, light-preceding spices and their mixture.In this regard, described packing can comprise about 0.001% to about 50% based on overall package weight, about 0.01% to about 20%, or even about 0.01% to about 5% described spices package delivery system, and described device can comprise about 0.001% to about 60% based on overall apparatus weight, about 0.05% to about 25%, or even about 0.1% to about 8% describedly send out material fragrant.Aspect above-mentioned, when packing comprises free spice, in the packing ratio of free spices and perfume delivery systems for about 1:100 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.Aspect above-mentioned, in the product matrix ratio of free spices and perfume delivery systems for about 1:1000 to about 20:1, about 1:20 is about 10:1 extremely, or even about 1:10 about 5:1 extremely.

Aspect one or more, above the packaged products in the aspect 1 can comprise PAD storage system and PAD matrix system and/or amine assisted delivery (AAD) system of perfume microcapsule form.

Aspect one or more, described perfume delivery systems can comprise one or more substrates, wherein described perfume delivery technology is applied in described one or more substrates, perhaps wherein will be clipped between described one or more substrates between described perfume delivery technology.In one aspect, described one or more substrates comprise one or more perfume delivery technology, such as polymer-based carbon plastome.In one aspect, described folder perfume delivery technology can be microcapsule, such as perfume microcapsule.

Aspect one or more, above the packaged products in the aspect 1 can comprise preceding spices, and for example spices (PPP) and PAD store system, PAD matrix system and/or amine assisted delivery (AAD) system before the light.On the other hand, described PAD storing body is perfume microcapsule (PMC); And even be wherein capsule wall based on the perfume microcapsule of melocol and/or melamine formaldehyde resin.On the other hand, described AAD system comprises material, and described material is selected from the group of being made up of following: polymine (PEI) and polyvinylamine (PVAm).

Aspect one or more, above the packaged products in the aspect 1 can comprise the nanometer tubule.This type of packaged products also can comprise material, and described material is selected from the group of being made up of following: polymkeric substance assisted delivery system, amine assisted delivery system, amine reaction product, cyclodextrin, starch capsule are sealed temper, are loaded with the zeolite of spices, the zeolite that is loaded with spices, preceding spices and their mixture of bag quilt.

Aspect replenishing, this type of additional aspect is with above disclosed aspect is identical, and different is to choose wantonly with the spices package delivery system of any packing associating.In brief, this type of aspect can not contain spices package delivery system.

Other additional aspect, this type of additional aspect is with above disclosed aspect is identical, different described packings are to choose wantonly.In brief, this type of aspect can not have packing.

Aspect replenishing, this type of aspect can be with above disclosed aspect be identical, and interrelates with demonstration in this respect, and described demonstration comprises that spices shows delivery system, and it is identical with disclosed spices package delivery system in the disclosed described aspect above.

Aspect above-mentioned, because the experience that provides via single FMOT technology is not enough to satisfy all needs of human consumer sometimes, so can use multiple FMOT technology.For example, the spices that is provided by unitary package method or FMOT perfume delivery technology (PDT) discharges and possibly can't or notice by every consumer experience.For example, human consumer can mention the product capping and experience FMOT PDT beneficial effect, such as based on polymkeric substance assisted delivery (PAD) technology of matrix (for example spices heat fusing thing or send out fragrant plastics insert); Yet the another one human consumer may not can want to mention capping, and more may change the FMOTPDT that notes being positioned at product or packing outside into.This type of FMOT PDT can select from tabulation, and described tabulation comprises 1) PAD matrix type heat fusing thing, 2) spices injection plastic, 3) send out label fragrant, 4) scraping and induction type flavor delivery system, or even 5) be positioned near the spices sample of product, such as the part of store display.Can independently select any among these FMOT PDT, and it can be separately located on the product, such as on the top that is positioned at described product and/or packing, side or bottom.

At improving this needs that FMOT experiences, the example of another kind of solution is to use same or analogous PDT such as spices heat fusing thing, but this type of same or analogous PDT is present on the product in the more than one position.For example, the heat fusing thing can be present under the product capping, and identical or different FMOT PDT can be positioned at the product bottom.Based on desired experience, selection is used for incorporation into spices among a kind of FMOT PDT (for example heat fusing thing or send out fragrant plastics insert) can be identical, similar on spices is formed or be different from the spices of selecting to be used for incorporation in one or more other heat fusing things, and described other heat fusing thing is as the part of product and/or the packing of product and involved.

To discharge the difference that perfume base (PRM) can utilize the spices release characteristics to inject different speed such as plastic with alternative FMOT PDT such as spices based on the system of heat fusing thing or tackiness agent, so that the sense of smell beneficial effect bigger than single PDT to be provided, wherein spices teacher or product formulator need be reached some compromise, all multifactor with balance, such as characteristic, intensity, release characteristics, cost etc.For example, a kind of option that makes up is that different piece at product comprises identical FMOT PDT, but different samples are selected different spices fragrant-inner agents.For example, a kind of FMOT PDT can comprise the top perfume (or spice) of Kovats index (KI) value in 800 to 1200 scopes of high per-cent, and another kind of heat fusing thing can comprise middle perfume (or spice) or the PRM of more Kovats indexs (KI) value in 1200 to 1500 scopes, and another kind also can comprise Kovats index (KI) value greater than 1500 bottom note.This advantage that will have is to select the spices load based on the release characteristics with different volatile PRM.

For any FMOT PDT such as heat fusing thing or spices plastics, by selecting to improve described system for the key PRM that discharges based on parameters combination such as Kovats index (KI) and odor detection threshold (ODT).For PRM, preferred KI scope can be 800 to 1500, more preferably 1000 to 1400, even more preferably 1000 to 1200.In addition, can select independent PRM or spices fragrant-inner agent to strengthen the fragrance of spices in the product.These PRM are optional to be freed from chemical instability for example and those PRM of being not easy to prepare.Wherein select other spices design example of different PRM or fragrant-inner agent also to belong in the category of this invention to different FMOT PDT and/or spices in the variant production.

Another aspect of the present invention comprises use FMOT PDT combination, so that desired experience to be provided when comprising the purchase of low flavour content or perfume-free product.The human consumer can select this type of product farthest to reduce during the application experience or on the arid region with the contacting of spices.Because remaining preparation composition, this series products with flavour content in the low production can have unexpected smell.Equally, FMOT PDT or multiple FMOT PDT can be used to improve the scent experience at point of purchase place.

Aspect above-mentioned, the human consumer has desirable scent experience when using product also be important.For example, the human consumer tackles that pure and fresh characteristic and the preferred intensity of product fragrance pleases oneself between the usage period.Though FMOT PDT or multiple FMOT PDT are adapted at point of purchase place usually desired sensory experience requirement are provided, but because for example product can be consumed during use, or the zone of handling is consumed before use, or flavour intensity is not enough to satisfy human consumer's requirement in intensity between the usage period, so they can't be sent during whole application experience.In addition, a plurality of human consumer's point of contact during the application experience can need the PDT that adds to advance desired sensory experience.For example, when unpacking and/or when product is poured out box or bottle, may need a kind of SMOT PDT that desired product scent experience is provided, and need another kind of SMOT PDT to keep desired washing soln flavour intensity and characteristic.In addition, can select identical or different SMOT PDT, so that the fragrance that fills the air and retain to be provided in the room that uses product therein, and provide fragrance to the processing zone.For example, under the situation of laundry detergent or fabric conditioner, SMOT PDT can provide desired scent experience in moistened garment, especially when it takes out from washing machine.For the human consumer who washes by hand polyester fabric, the spices of this type of application release (also being called strong perfume (or spice)) is even more important for scent experience.Other example comprises hair and skin care products, includes but not limited to shampoo and hair conditioner, bath shampoo (comprise and have one or more independent mutually those), soap slab, antiperspirant, reodorant etc.For this series products, product is important with its pure form or strong perfume (or spice) between the water dilute form usage period to the SMOT consumer experience.

Use SMOT PDT or multiple SMOT PDT that perfume intensity or the strong property of spices of enhancing can be provided between the usage period at product, comprise wherein and trigger the situation that spices discharges by moisture, so that be not current in the packing of product, or FMOT PDT is not when providing the fragrance that enough and straight product accompany combinations of perfumes, can experience fragrance, even fragrance is full of the room.

Wherein said any PDT can be used in any combination of the consumer's goods, to obtain desired FMOT or SMOT scent experience.The example of SMOT PDT comprises that the starch capsule seals temper, cyclodextrin, preceding spices, is loaded with the polymkeric substance of spices, and it comprises matrix (for example nano rubber latex) and (microcapsule) system of storage.

Wherein increase the SMOT PDT that trigger spices release by moisture at product between the usage period and be particularly useful for the low moisture product form, for example detergent granules, fabric softener sheet, clothes washing tablet etc.

In many cases, SMOT PDT can reduce the spices headspace of straight product smell (NPO) or product top, is not bound by theory, and this is the interaction between carrier and perfume base (PRM) due to.Those skilled in the art attempt to compensate the minimizing of spices headspace by adding additional free spice, yet this method can increase the product expense, and by causing fragrance can influence the consumer experience at other human consumer's point of contact place unfriendly in distortion aspect feature or the intensity.The present invention of FMOT and SMOT PDT has been made up in employing, can solve by the problem of using described SMOT or TMOT PDT to cause, and described SMOT or TMOT PDT are intended to product provides beneficial effect between the usage period or after using.For example, cyclodextrin and/or SEA be load spices and be formulated into granular laundry detergent separately, and it can provide the perfume intensity of unexpected enhancing or increase when product uses.Yet a kind of mode that the flavour intensity of straight product and characteristic can be such reaches not enough or distortion, to reduce human consumer's acceptance that FMOT (point of purchase) locates.Similarly, add FMOT PDT, solved described problem by making formulator can improve whole scent experience.This comprises that when some or all of spices discharge a small amount of spices that is present on product or the packing approaches with washing soln fragrance on fragrance characteristic from SMOT PDT.Alternatively, the spices that can select to have different qualities and intensity is incorporated among the FMOT PDT.

On the other hand, the method that can overcome the challenge that the human consumer is fed up with to the identical fragrance of perceiving from the straight product smell is disclosed, the method for application experience, and even the method for using the back to experience.This invention can provide different fragrance characteristics at each human consumer's point of contact.Therefore, spices in the wrapping material can be different from the spices in the bottle, and optional be different from the spices that product discharged between the usage period, and the optional spices that discharges from wetting zones or delivery system that is different from, described delivery system uses the back to discharge spices from wetting or arid region at product.Therefore, this makes formulator can pass through combination any or all following PDT as herein described, the whole consumer scent experience of balance.

Another advantage of the present invention is can improve release characteristic or rate of release by the combination of using FMOT and SMOT PDT.Specific PRM can have characteristic, makes its headspace that is difficult to provide desired degree, for example when existing such as tensio-active agent with other preparation composition, if PRM has the situation of low-steam pressure.Use FMOT PDT, this type of PRM is present near in the headspace of product, so that the beneficial effect of described PRM can be implemented.

It is useful adopting multiple SMOT PDT.Though some fragrance carrier is the interior PRM of compound broad range effectively, many being subject to by complete compound PRM.This type of restriction relates to for example molecular size or shape.In the case, SMOT PDT that need be outside given SMOT PDT supplementary quota.For example, for some high-volatile PRM, it has loss in starch capsule encapsulation process.Yet this type of PRM is easier to be incorporated in the cyclodextrin, especially when they have high binding constant.Similarly, the combination of SEA and CD can provide aspect feature and the intensity than they independent bigger fragrance beneficial effects that provides in the product.

Though adopt the product of FMOT PDT can improve the consumer experience at point of purchase place, and SMOT PDT can provide the application experience of improvement, also need to improve the fragrance of arid region.For example, be outstanding demand at the dry fabric smell (DFO) that improvement is provided aspect fragrance characteristic and the intensity.Therefore, TMOT PDT is available.For many TMOT PDT, between carrier and spices, there is strong interaction.For the regional smell that is improved, need to increase the deposition of PRM on the zone.This can realize by adopting carrier technique, yet this carrier can suppress the straight product smell so that twist FMOT and experience.This problem is solved by the present invention, wherein strengthens overall experience by the combination of using FMOT PDT and TMOT PDT.

For example, polymer wall or matrix are sealed the capsule of spices and can be protected spices to avoid contacting harsh working condition, and can increase spices to the deposition in zone.Be not bound by theory, because trigger mechanism, before spices discharged from carrier, the capsule wrapper technology can suppress the spices headspace.This type of trigger mechanism includes but not limited to diffusion, friction, heat, dilution, ionic strength, water, pH, light etc.The inhibition of spices headspace can cause the distortion of straight product smell and FMOT consumer experience.Use FMOT PDT, the feature by improving initial stage human consumer point of contact or crucial moment place and intensity and use TMOT PDT come to treatment zone for example DFO provide beneficial effect to solve this problem.

(PMC) is similar with perfume microcapsule, when other TMOT PDT described in this patent application of use, uses FMOT PDT that confers similar advantages can be provided.This includes but not limited to preceding spices, be loaded with the zeolite of spices (PLZ), other polymkeric substance assisted delivery system such as nano rubber latex, amine assisted delivery technology and nanometer tubule.

It is useful adopting multiple TMOT.Many human consumer point of contact relevant with TMOT are arranged, and it needs to use more than one PDT to satisfy human consumer's needs usually.For example, for fabric applications, when its 1) when from dryer, shifting out, 2) when leaving drying line, 3) folding and when storing, when 4) pressing, when 5) just having put on, 6) put on after several hours by human consumer or other people smell when hearing 7) before dressed or use after when dressing again, when and 8) from dirty clothing heap, taking out before the clothes washing, need different TMOT PDT to improve feature and the intensity of drying or approximate drying clothes.Another example comprises hair or skin (or scalp) application, wherein 1) using washing, take a shower, during drying up with for example towel and/or hair or hand dryer behind the products such as shower or afterwards, 2) leaving the room that wherein uses product or zone (for example bathroom or shower cabinet) afterwards, 3) after returning the place of using product, 4) using product after several hours, or 5) using product after one day or several days, when the consumer alert arrives the spices fragrance of they self or other people on one's body, need different TMOT PDT to improve feature and the intensity of drying or approximate dry hair or skin.Other human consumer point of contact relevant with TMOT includes but not limited to use the fragrance on hair or skin products (comprising antiperspirant and reodorant) the back fabric, and the flavour intensity relevant with regional change of moisture content and/or the variation of feature.Use single to use or use the back repeatedly use or use after can provide the combination of the perfume delivery technology of beneficial effect can handle all above-mentioned human consumer's point of contact.

Some PRM during the product stock or product between the usage period " seepage " outside perfume microcapsule (PMC), be not unusual.This invention has been described and has been used PDT to come and the PRM lower than the desired delivery efficiency of PMC interacts or the method for " removings " PRM, to provide than independent use PMC or the more superior spices experience of PAD.For some PMC system, the PRM that is easier to seepage comprises having low CLogP value and/or hang down those of Kovats index (KI) value, comprises the PRM that is called as " top is fragrant "; PAD and AAD PDT can be used to improve sending of this type of PRM.Another selection that utilizes the TMOT combination is to divide to open with PMC to add extra free PRM, comprises that the top is fragrant, and uses PAD and/or AAD technology to improve the deposition of the PRM of described independent adding, with deposition and/or the release of PMC system combinations to improve other PRM.But can be used for improving PAD and/or the AAD system preload spices of PMC deposition equally, perhaps separate with spices and join in the product matrix, therefore the characteristic that the deposition of the free PRM of improvement and PMC, and optional change free spice and/or capsule encapsulated perfume discharge from the zone.

Except making up to send different spices, spices fragrant-inner agent or PRM with balance global feature and the intensity by use TMOT PDT, another advantage of using TMOT PDT combination is to improve integral body deposition and the release characteristics of PDT.For example, can use cationic polymers and/or other additive to increase the deposition of PMC on the zone.In addition, examples of such additives can change the characteristic that spices discharges from PMC.Be not bound by theory, can or change wall ability mutually inside or that the foreign minister is spread via additive raising or reduction wall pore rate and change spices release.Equally, be not bound by theory, described additive can be used as the spices receptor that triggers the PRM that discharges before or after the release from PMC.

In another aspect of this invention, the PRM of selection can diffuse through the PMC wall.Expect that this type of diffusion can realize that the spices that continues discharges, yet in other cases, the release of this type of PRM is considered to too fast, and causes lacking some PRM and change preferable feature or intensity.Use extra TMOT PDT such as preceding spices, can keep desired feature for a long time by lasting spices release (comprising the release of those PRM that can diffuse through the PMC wall) is provided.Therefore, can't effectively send or need can send via the TMOT PDT based on preceding spices technology with PRM different or that change headspace concentration is sent by PMC.

Another aspect of the present invention is to use TMOT PDT to strengthen the deposition of one or more other TMOT PDT.For example, polymkeric substance, preferred cationic polymkeric substance can be formulated into product strengthening the deposition of specific PRM, and can strengthen the deposition of another kind of TMOT PDT such as preceding spices.This type of preceding spices comprises light-triggered preceding spices.Described polymkeric substance not only can be used for strengthening deposition, also can be used as fragrance carrier to add PRM to regional delivery.Described polymkeric substance also can be used for changing the release characteristics that discharges in PRM or the multiple PRM the past spices.

Other example that improves deposition can wait to realize by combination PMC, preceding spices, zeolite or clay, polymkeric substance assisted delivery (for example nano rubber latex), amine assisted delivery, inorganic nano tubule, light-preceding spices, siloxanes.

Another aspect of the present invention can make formulator can make up TMOT PDT, farthest increasing pure and fresh degree, or farthest reduces the fragrance differentiation.For example, preceding spices can be sent single PRM, or even multiple PRM.This type of spices discharges can provide single and preferred characteristic and intensity, yet only the release of some PRM can cause the aromatic property multiplicity lower, or even differentiation or make the unhappy scent experience of people.But by using the PRM that sends from other TMOT PDT to come balance fragrance characteristic and intensity head it off.For example, use perfume microcapsule (PMC) and preceding spices that the more superior scent experience than any PDT of independent use can be provided.

This invention also comprises uses TMOT PDT to make up the flavour intensity that provides higher, and improves the fragrance characteristic at different human consumer's point of contact place.For example, TMOT PDT combination can provide desired fragrance soon and at slower time point place after regional drying.Attempting to solve the long-time difficult point that continues the demand of spices release need to be too much spices realize desired result.If PRM is volatile, and too fast dissipation, or have high odor detection threshold (ODT), and must be to use according to the unpractiaca content of the theoretical spices load limit of PDT, then especially true.By using TMOT PDT combination, wherein trigger spices at the different time points place and discharge this demand that solves.For example, polymkeric substance assisted delivery TMOT PDT can provide fragrance soon after regional drying, and the preceding spices that enzyme triggers can discharge spices from being stored in hamper clothing medium to be washed.Use the PDT combination also to make formulator can shelter or suppress part spices, provide desired intensity and/or feature until extremely needing to discharge described perfume composition.Utilizing effective trigger mechanism to come regularly spices to discharge is a kind of method that realizes this purpose, has wherein suppressed some the PRM headspace by a kind of TMOT PDT load, until causing release by suitable trigger mechanism.

Another example of two or more TMOT PDT combination comprises the zeolite that is loaded with spices (PLZ) of coating starch, and it can be deposited on the zone, and after with the product treatment zone immediately or soon, begin to discharge from the zone spices; With preceding spices, it can begin after contact discharges trigger mechanism from zone release PRM.Under the spices situation, described trigger mechanism is that electromagnetic radiation is such as light before the light that also is called as light-preceding spices triggers.Other preceding spices trigger mechanism comprise water, pH variation, enzyme or owing to condition for example concentration change the balance that causes and move, so that spices discharges with given pace, replenishes or strengthens by PDT and make up the beneficial effect that other used TMOT PDT provides in (such as the zeolite that is loaded with spices).

Another aspect of the present invention is to use one or more PDT on the zone, and one or more PDT on the different zones.For example, the perfume intensity that the perfume microcapsule from fabric discharges and/or feature can be enhanced by the spices that discharges from the identical or different PDT (such as another perfume microcapsule or preceding spices) that is positioned on hair or the skin.

In another aspect of this invention, can use any above-mentioned perfume delivery technology (PDT) to come capsule to seal or wrap by any other above-mentioned perfume delivery technology.This type of capsule is sealed or is wrapped and be can be used for strengthening capsule and seal or wrap by the stability of spices or PDT, or is used for changing deposition or spices release characteristic that encapsulated or capsule is sealed PDT.For example, can use core shell capsule wrapper technology to come capsule to seal and contain or do not contain the preceding spices that additional capsule is sealed free spice.In another example, available matrix or the polymkeric substance assisted delivery system of storing the system form are come capsule to seal cyclodextrin molecular or are loaded with the cyclodextrin of spices.The inorganic zeolite and/or the nanometer tubule that are loaded with spices can be encapsulated in polymeric matrix or polymer shell.In another example, use the mixture that comes capsule encapsulated perfume and siloxanes based on the polymeric system of carbamide, perhaps be coated with the polymeric system based on carbamide that is loaded with spices with siloxanes and/or the siloxanes that contains spices.In another example, be coated with PAD with PAD, USP5 for example is described in 188,753.

In another aspect of this invention, the heat fusing thing can be loaded or seal above-mentioned any perfume delivery technology (PDT) for coating or capsule.This type of PDT combination especially can be used for strengthening the consumer experience at FMOT place.

Embodiment

Prepare multiple detergent composition, described composition has the composition that shows in following examples.In these embodiments, the component of abbreviation sign has following meanings:

LAS: straight chain C ₁₂Sodium alkyl benzene sulfonate

CFAA:C ₁₂-C ₁₄Alkyl N-methyl glucose amide

HEDP: hydroxyl ethane dimethylene phosphonic acids

DETPMP: diethylenetriamine five (methylene phosphonic acid), can trade(brand)name Dequest 2060 commercially available from Monsanto

TEPAE: tetren ethoxylate

PVP: polyvinyl pyrrolidone polymers

PVNO: polyvinylpyridine-N-oxide, molecular-weight average are 50,000.

Whitening agent 4,4 '-two (2-sulfo group vinylbenzene) biphenyl disodium and/or 4,4 '-two (4-phenylamino-6-morpholinyl-1.3.5-triazine-2-yl) toluylene-2:2 '-disulfonic acid disodium

50 ℃ of suds suppressor-25% paraffin Mpt, 17% hydrophobic silica, 58% paraffin oil, particulate state suds suppressor 12% siloxanes/silicon-dioxide, 18% stearyl alcohol, 70% pearl starch

The PEI polymine

Enzyme: proteolytic enzyme, amylase, cellulase and/or lipase

SRP: the polyester of negatively charged ion end-blocking

The MEA monoethanolamine

SCS isopropyl benzene sodium sulfonate

The liquid detergent composition that comprises perfume delivery systems has following prescription:

Embodiment #1: the heavy duty type liquid laundry detergent composition

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Trisodium citrate	4.15	2.80	2.96	3.48	2.77	3.48	3.66
C _12-18The entity soap	6.77	3.02	2.75	3.24	3.24	2.19	5.12
								Ethanol	0.85	2.22	4.02	2.59	2.22	2.50	2.50
Monoethanolamine	1.22	1.95	2.55	1.50	5.04	1.50	1.50
								Calcium formiate	0.03	0.01	0.08	0.05	0.30	0.06	0.04
Propylene glycol	5.66	2.22	2.59	4.44	5.90	4.25	1.75
								Sodium formiate	0.05	0.25	0.088	0.103	0.125	0.15	0.35
Borax pre-composition (38%)	2.5	1.5	1.2	1.5	1	3.5	0.5
								Glycerine	2.9	2.35	2.3	2.7	2.05	0.5	4

NaOH	1.3	1.1	0.88	0.837	0.95	0.25	2.25
								Wetting ability dispersion agent (PEI 189E15-E18)	0.25	0.44	0.55	0.65	0.86	0.15	0.96
Proteolytic enzyme	0.031	0.034	0.0272	0.032	0.023	0.015	0.051
								Cellulase	0.0008	0.001	0.0009	0.001	0.001	0.0015	0.003
Mannase	0.005	0.004	0.0034	0.004	0.003	0.003	0.004
								Amylase	0.0035	0.0031	0.0025	0.003	0.0032	0.0026	0.0018
Suds suppressor	0.01	0.01	0.01	0.01	0.01	0.01	0.01
								DTPA	0.11	0.15	0.13	0.15	0.19	0.22	0.09
Hydrophobicity dispersion agent (PEI 600 E20)	1.21	1.19	1.09	1.29	1.75	2.4	0.75
								Whitening agent	0.106	0.125	0.106	0.125	0.125	0.106	0.125
C _12-14Alkyl-dimethyl amine oxide (amine oxide)	0.9	1.4	0.62	0.74	0.7	0.62	0.5
								C _12-13 AE9	2.2	2.22	1.88	2.22	2.55	2.88	4.05
C ₂₅AE1.1S Na paste	14.44	15.75	13.06	15.37	10.25	15.24	13.2
								NaLAS	6.948	5.532	4.03	4.743	6.948	5.53	4.76
Red HP liquid dye	0.002	0.002	0.002	0.002	0.002	0.002	0.002
								PAD stores system (melamine formaldehyde resin PMC)	1.0	--	--	0.7	2.1	0.4	0.2
PAD matrix system (SAD)	--	--	2	--	--	--	--
								PAD matrix system (nano rubber latex)	--	0.6	--	--	--	--	--
The amine assisted delivery	--	--	--	0.2	0.2		0.2
								Preceding spices	--	--	--	--	--	0.5	--
ZIC (inorganic nano tubule)	--	1.7	--	--	--	--	--
								Low KI spices fragrant-inner agent	--	--	--	--	--	0.1	--
Bonus flavor	0.7	0.3	0.5	0.7	0.4	0.9	0.2
								Miscellaneous and water ^*
PAD heat fusing thing ^**	Be	--	Be	--	Be	--	Be
								PAD sends out plastics fragrant ^**	--	Be	--	--	--	--	Be

^*Surplus

^*Above the packing of product is in the packing that comprises container, and described container comprises top cover.In one aspect, described packing comprises hotmelt or sends out fragrant the above-mentioned PAD matrix system of plastic form.In embodiment above, the PAD of hotmelt form is placed on described top cover below or places near described top cover.

Embodiment #2: the heavy duty type liquid laundry detergent composition

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								LAS	11.5	9.0	--	4.0	--	11.5	9.0
C ₂₅E2.5S	--	3.0	18.0	--	16.0	--	3.0
								C ₄₅E2.25S	11.5	3.0	--	16.0	--	11.5	3.0
C ₂₃E9	--	3.0	2.0	2.0	1.0	--	3.0
								C ₂₃E7	3.2	--	--	--	--	3.2	--
CFAA	--	--	5.0	--	3.0	--	--
								Top palm kernel fatty acid	2.0	--	2.0	0.5	2.0	2.0	--
Citric acid (50%)	6.5	1.0	2.5	4.0	2.5	6.5	1.0
								Ca and/or calcium formiate	0.6	0.7	0.2	0.05	0.05	0.6	0.7
SCS	4.0	1.0	3.0	1.2	--	4.0	1.0
								Borate	0.6	--	3.0	2.0	3.0	0.6	--
Sodium hydroxide	6.0	2.0	3.5	4.0	3.0	6.0	2.0
								Ethanol	2.0	1.0	4.0	4.0	3.0	2.0	1.0
1,2-propylene glycol	3.0	2.0	8.0	8.0	5.0	3.0	2.0
								Monoethanolamine	3.0	1.5	1.0	2.5	1.0	3.0	1.5
TEPAE	2.0	--	1.0	1.0	1.0	2.0	--
								Enzyme	0.03	0.01	0.03	0.02	0.02	0.03	0.01
SRP	0.2	--	0.1	--	--	0.2	--
								DTPA	--	--	0.3	--	--	--	--
PVNO	--	--	0.3	--	0.2	--	--
								Whitening agent	0.2	0.07	0.1	--	--	0.2	0.07
Suds suppressor	0.04	0.02	0.1	0.1	0.1	0.04	0.02
								PAD stores system	0.5	1.4	0.2	0.6	1.0	--	--
The PAD matrix system	--	--	0.5	0.2	0.8	--	1.0
								The amine assisted delivery	0.1	--	--	--	--	0.4	--

Preceding spices	--	--	--	0.2	0.2	0.6	0.3
								ZIC (being loaded with the tubule of spices)	1.2	0.4	--	--	--	--	--
Low KI spices fragrant-inner agent	--	--	--	--	0.2	0.1	0.1
								Bonus flavor	0.3	0.4	0.5	0.2	0.7	0.05	--
Miscellaneous and water ^*
								PAD heat fusing thing ^**	--	Be	--	--	Be	--	--
PAD sends out plastics fragrant ^**	--	--	Be	--	--	--	Be

^*Surplus

^*Above the packing of product is in the packing that comprises container, and described container comprises top cover.In one aspect, described packing comprises hotmelt or sends out fragrant the above-mentioned PAD matrix system of plastic form.

Embodiment #3: the heavy duty type liquid laundry detergent composition

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								C _12-15Alkyl oxide (25) vitriol	17.0	15.0	21.0	19.0	15.0	19.5	24.0
C _12-13Alkylethoxylate (9.0)	2.50	2.22	2.75	2.00	1.75	2.10	1.50
								C _12-14Glucose amide	3.20	3.10	3.90	3.50	2.88	4.55	3.55
Citric acid	2.55	3.10	3.60	3.00	3.20	3.20	3.80
								C _12-14Lipid acid	1.80	2.20	2.10	2.00	2.20	2.10	2.60
MEA, so that following pH to be provided:	8.0	8.3	8.5	7.8	8.0	8.0	8.1
								Ethanol	3.47	3.22	1.95	3.41	3.75	4.75	3.00
Propylene glycol	6.00	6.25	5.15	6.51	6.55	4.51	7.50
								Borax	2.0	3.0	2.5	2.5	2.0	3.0	2.5
PEI-Lupasol G(MW-100)	0.001	0.001	0.001	0.001	0.001	0.001	0.001
								Damascone	0.01	--	0.01	0.01	0.01	--	0.01
Dispersion agent	1.15	1.00	1.50	1.18	1.15	1.00	1.50
								Toluenesulfonic acid sodium salt	2.11	2.75	2.50	2.50	2.25	2.75	2.50
PAD stores system (PMC)	0.8	0.4	1.4	0.3	1.0	--	--
								The PAD matrix system	0.4	1.0	--	--	0.2 ^m	--	0.6
The amine assisted delivery	0.1	--	--	--	--	0.2	--
								Preceding spices	--	--	--	0.1	--	0.4	0.5

Be loaded with the tubule of spices	--	--	0.6	--	--	--	--
								Low KI spices fragrant-inner agent	--	--	--	--	0.2	0.1	0.1
Bonus flavor	0.7	0.7	0.5	0.7	0.7	0.5	--
								Dyestuff, whitening agent, enzyme, sanitas, suds suppressor, other minor component, water ^*
PAD heat fusing thing ^**	--	Be	--	--	Be	--	--
								PAD sends out plastics fragrant ^**	--	--	Be	--	--	--	Be

^*Surplus

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

Embodiment #4: the fabric intensifier composition

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								The fabric-softening active substance ^a	14.3	16.5	14.3	12.6	12.2	16.3	12.9
The fabric-softening active substance ^b	--	--	--	--	--	--	4.45
								The fabric-softening active substance ^c	--	--	--	--	4.15	--	--
Ethanol	2.18	2.57	2.18	1.95	1.95	2.57	2.57
								Virahol	--	--	--	--	--	--	--
Starch ^d	1.25	1.47	2.00	1.25	--	2.30	2.30
								Formaldehyde scavenger	0.40	0.13	0.065	0.25	0.03	0.030	0.030
The phase stabilization of polymers ^f	0.21	0.25	0.21	0.21	0.14	--	--
								Suds suppressor ^g	--	--	--	--	--	--	--
Calcium chloride	0.15	0.176	0.15	0.15	0.30	0.176	0.176
								DTPA ^h	0.017	0.017	0.017	0.017	0.007	0.007	0.007
Sanitas (ppm) ^i，j	5	5	5	5	5	5	5
								Defoamer ^k	0.015	0.018	0.015	0.015	0.015	0.015	0.015
Dyestuff (ppm)	40	40	40	40	40	40	40
								Ammonium chloride	0.100	0.118	0.100	0.100	0.115	0.115	0.115

HCl	0.012	0.014	0.012	0.012	0.028	0.028	0.028
								Structural agent ¹	0.01	0.01	0.01	0.01	0.01	0.01	0.01
PAD storage agent (perfume microcapsule)	0.4	0.7	0.4	0.5	0.3	0.6	--
								The PAD matrix system	0.5	0.6	1.0	--	--	0.2 ^m	--
The amine assisted delivery	0.2	--	--	--	--	--	--
								Preceding spices	--	--	--	0.2	--	--	0.6
ZIC (being loaded with the tubule of spices)	--	--	--	--	0.8	--	--
								Low KI spices fragrant-inner agent	0.1	0.1	--	--	0.2	--	0.1
Bonus flavor	0.3	0.7	0.5	0.4	0.3	0.3	0.9
								Deionized water ^*
PAD heat fusing thing ^**	--	Be	--	--	--	--	--
								PAD sends out plastics fragrant ^**	--	--	Be	--	--	--	Be

^*Surplus

^aN, N-two (tallow acyl-oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride.

^bMethyl two (butter amido ethyl)-2-hydroxyethyl methyl esters ammonium sulfate.

^cMol ratio is the reaction product of lipid acid and the methyldiethanolamine of 1.5:1, quaternized with methyl chloride, obtain the N that mol ratio is 1:1, N-two (stearoyl keto ethyl)-N, N-alkyl dimethyl ammonium chloride and N-(stearoyl keto ethyl)-N-hydroxyethyl-N, the mixture of N-alkyl dimethyl ammonium chloride.

^dWith trade(brand)name

Derive from the positively charged ion amylomaize starch of National Starch.

^eFormaldehyde scavenger is as described in this area.

^fThe multipolymer of oxyethane and terephthalate has as US 5,574,15 are listed as the capable described chemical formula of 1-5 in 179, wherein each X is methyl, and each n is that 40, u is 4, each R1 is 1 substantially, the 4-phenylen moiety, each R2 is vinyl, 1 substantially, 2-propenyl part or their mixture.

^gDerive from the SE39 of Wacker

^hDiethylenetriamine five acetic acid.

ⁱDerive from Rohm and Haas Co.'s

CG." PPM " is " each 1,000,000 parts of parts ".

^jGlutaraldehyde

^kDerive from the silicone antifoam agent of Dow Corning Corp. with trade(brand)name DC2310.Derive from DowCorning Corp..

^lDerive from the urethane of ethoxylation of the hydrophobically modified of Rohm and Haas with trade(brand)name Aculan 44.

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

^*Above the packing of product among the embodiment 1 to 4 is in the packing that comprises container, and described container comprises top cover.Described packing comprises any above-mentioned PAD that sends out plastics insert form fragrant, and described top cover comprises any above-mentioned PAD of heat fusing thing form.Usually the PAD with heat fusing thing form is placed on described top cover below or close described top cover placement.

^*Hereinafter the packing of product among the embodiment 5 to 6 is in the packing that comprises container, and described container comprises top cover or capping.Described packing comprises any above-mentioned PAD that sends out plastics insert form fragrant, and described capping comprises any above-mentioned PAD of heat fusing thing form.For example, the PAD with heat fusing thing form is placed on capping below, the box, on the handle, label is first-class.Sending out plastics fragrant also can become the part of packing.

Embodiment #5: granular detergent composition

Preparation comprises heavy duty type detergent granules (HDG) composition of described perfume delivery systems.This type of granular detergent composition has following prescription:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								C ₁₂Linear alkylbenzene sulfonate	8.25	7.75	9.55	9.31	8.53	10.22	9.22
C _14-15Alkylsulfonate	12.15	15.15	13.55	12.74	9.50	13.25	12.00
								Zeolite builders	26.34	23.66	29.62	27.79	30.15	28.25	29.39
Yellow soda ash	29.35	26.33	27.11	27.31	28.28	29.35	27.35
								PEG 4000	1.55	1.43	1.87	1.60	1.96	1.55	1.63
Dispersion agent	2.23	2.65	1.98	2.26	2.24	2.26	2.21
								C _12-13Alkylethoxylate (E9)	1.4	1.3	1.6	1.5	1.8	1.3	1.4
Sodium peroxoborate	1.01	1.23	1.73	1.03	1.01	0.96	0.89
								Soil release polymer	0.40	0.22	0.35	0.41	0.40	0.55	0.85
Enzyme	0.54	0.58	0.53	0.59	0.78	0.35	0.89
								PAD stores system	--	0.8	--	1.1	0.4	0.6	--
The PAD matrix system	--	0.6	--	--	--	--	0.2
								The starch capsule is sealed temper	0.5	--	0.2	0.1	--	--	0.2
ZIC (being loaded with the zeolite of spices)	0.5	--	--	--	--	0.3	--
								ZIC (nanometer tubule)	--	--	--	--	0.7	--	--

Beta-cyclodextrin derivative	--	--	--	--	--	--	0.2
								Preceding spices	--	--	0.1	0.02 ^p	0.2 ^q	--	0.1 ^r
Bonus flavor	0.5	0.2	0.1	0.1	0.1	0.3	--
								The amine assisted delivery	--	--	--	--	--	--	0.1
Whitening agent, suds suppressor, other minor component and moisture ^*
								PAD heat fusing thing ^**	--	Be	--	--	Be	--	--
PAD sends out plastics fragrant ^**	--	--	Be	--	--	--	Be

^*Surplus

^pPreceding spices comprises amine reaction product (ARP) system based on PEI

^qPreceding spices comprises light-preceding spices (PPP) system based on nitrogen

^rPreceding spices is for discharging 3 ', 5 '-dimethoxy st-yrax derivative of perfume alcohol

Embodiment #6: granular detergent composition

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								C ₁₂Linear alkylbenzene sulfonate	8.25	7.75	9.55	9.31	8.53	10.22	9.22
C _14-15Alkylsulfonate	12.15	15.15	13.55	12.74	9.50	13.25	12.00
								Zeolite builders	26.34	23.66	29.62	27.79	30.15	28.25	29.39
Yellow soda ash	29.35	26.33	27.11	27.31	28.28	29.35	27.35
								PEG 4000	1.55	1.43	1.87	1.60	1.96	1.55	1.63
Dispersion agent	2.23	2.65	1.98	2.26	2.24	2.26	2.21
								C _12-13Alkylethoxylate (E9)	1.4	1.3	1.6	1.5	1.8	1.3	1.4
Sodium peroxoborate	1.01	1.23	1.73	1.03	1.01	0.96	0.89
								Soil release polymer	0.40	0.22	0.35	0.41	0.40	0.55	0.85
Enzyme	0.54	0.58	0.53	0.59	0.78	0.35	0.89
								The PAD of matrix system form	--	--	0.8 ^m		0.3	--	--
The starch capsule is sealed temper	0.5	--	--	0.2	--	--	0.3
								Amine reaction product	--	--	--	0.05	--	--	0.1
ZIC (being loaded with the zeolite of spices)	--	--	--	--	--	--	0.2
								Cyclodextrin	0.3	--	--	--	--	--	--

Preceding spices	--	0.4	0.1	--	--	0.3	--
								ZIC (being loaded with the tubule of spices)	--	--	--	--	0.5	--	--
Additional spray-type spices	0.2	0.3	--	0.2	0.4		0.1
								Damascone	--	--	0.01	0.01	--	--	--
The amine assisted delivery	--	--	--	0.08	--	--	--
								Whitening agent, suds suppressor, other minor component and moisture ^*
PAD heat fusing thing ^**	--	Be	Be	Be	--	--	--
								PAD sends out plastics fragrant ^**	--	Be	--	--	Be	Be	Be

^*Surplus

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

Embodiment #7: unite the device of the non-woven mat form of use with hard surface cleaning composition

Below be can be used among the present invention hard surface cleaning composition, especially with USP6, the non-limiting example of the hard surface cleaning composition of cleaning pad described in 663, the 306B2 and/or burnisher combination.

Composition (per-cent by weight, %)	A	B	C	D	E
						Neodol 1-5 ¹	0.03	--	0.03	--	--
Witconate NAS-8 ²	0.01	0.02	0.01	--	--
						Planteran 2000 ³	--	0.05	--	0.004	0.004
Ammonium hydroxide	--	--	--	0.1	--
						Glacial acetic acid	--	--	--	--	--
DMAMP-80 ⁴	0.01	0.01％	0.06％	--	0.01％
						Dowanol PnP ⁵	2.0	2.0	2.0	4.0	4.0
Polyvinyl pyridine N-oxide	0.015	0.015	0.015	0.003	0.003
						1-methoxyl group-2-butanols	--	--	--	--	--
Silicone suds suppressor ⁶	0.00125	0.00125	0.00125
						Spices	0.033	0.06	0.035	--	--
To diformazan phenolphthalein	--	--	0.001	--	--
						PAD stores system	0.19	0.39	--	--	0.25
The PAD matrix system	0.05	0.1	0.45	--	--

The amine assisted delivery	0.08	--	--	--	--
						Preceding spices	--	--	0.07	0.10	--
ZIC (being loaded with the tubule of spices)	--	--	--	--	0.42
						Low KI spices fragrant-inner agent	0.004	0.01	--	--	0.02
Deionized water	Surplus	Surplus	Surplus	Surplus	Surplus
						PAD heat fusing thing ^**	Be	--	Be	Be	--
PAD sends out plastics fragrant ^**	--	--	--	--	Be

Composition (per-cent by weight, %)	F	G	H	I	J
						Neodol 1-5 ¹	--	0.03	0.03	0.03	0.03
Witconate NAS-8 ²	--	0.01	0.01	0.01	0.01
						Planteran 2000 ³	0.004	--	--	--	--
Ammonium hydroxide	0.01	--	--	--	--
						Glacial acetic acid	--	0.05	0.05	--	0.05
DMAMP-80 ⁴	--	--	--	0.01	--
						Dowanol PnP ⁵	4.0	--	2.0	--	--
Polyvinyl pyridine N-oxide	0.003	0.015	0.015	0.015	0.015
						1-methoxyl group-2-butanols	--	--	--	2.0	--
Silicone suds suppressor ⁶	--	0.00125	0.00125	0.00125	0.00125
						Spices	0.015	0.03	0.03	0.03	0.03
To diformazan phenolphthalein	--	--	--	--	--
						PAD stores system	0.18	0.36	0.13	--	--
The PAD matrix system	--	--	--	--	--
						The amine assisted delivery	--	--	--	0.08	0.10
Spices before light-triggered	--	--	0.22	0.11	0.10
						Additional low KI spices fragrant-inner agent	--	0.015	--	--	0.11
Deionized water	Surplus	Surplus	Surplus	Surplus	Surplus
						PAD heat fusing thing ^**	Be	--	Be	Be	--
PAD sends out plastics fragrant ^**	--	--	--	--	Be

¹The C11E5 alcohol ethoxylate can be commercially available from Shell Chemical.

²Straight chain C 8 sulfonate can be commercially available from Witco Chemical.

³The C8-C16 alkyl polyglucoside can be commercially available from Henkel.

⁴2-dimethylamino-2-methyl isophthalic acid-propyl alcohol can be commercially available from Angus Chemical.

⁵Propylene glycol n-propyl ether can be commercially available from Dow Chemical.

⁶Silicone suds suppressor can trade(brand)name Dow Corning

Emulsion is commercially available from Dow Corning.

For embodiment #7, unite the device of the non-woven mat form of use with hard surface cleaning composition above and also can choose the combination that comprises the perfume delivery technology wantonly, include but not limited to following those.Any PDT combination in the liquid composite optionally with the non-woven mat composition in any PDT make up.

Composition (per-cent by weight, %)	K	L	M	N	O
						The device of the non-woven mat form described in US 06663306	>90	>90	>90	>90	>90
Spices	0.05	--	--	--	0.1
						Low KI spices fragrant-inner agent	0.02	--	--	--	--
PAD stores system	0.2	0.03	--	0.1	--
						The PAD matrix system	--	0.01	0.02	0.15 ^m	--
The starch capsule is sealed temper	--	--	0.058	--	--
						Amine reaction product	--	--	--	0.018	--
ZIC	--	--	--	--	0.01
						Cyclodextrin	--	--	--	--	--
The amine assisted delivery	0.01	--	--	--	--
						Preceding spices (ARP)	--	--	--	0.09 ^p	--
Preceding spices (PPP)	--	0.09 ^q	--		--
						Other minor component and moisture	Surplus	Surplus	Surplus	Surplus	Surplus

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

^pPreceding spices comprises amine reaction product (ARP) system based on PEI

Composition (per-cent by weight, %)	P	Q	R	S	T
						The device of the non-woven mat form described in US 06663306	>90	>90	>90	>90	>90
Spices	0.04	0.01	--	--	0.07
						The PAD of PMC form stores system	1.9	4.0	0.3	--	--
The PAD matrix system of SAD form	0.5	--	--	1.4	--
						The starch capsule is sealed temper	--	--	0.55	--	--
The ZIC of fused silica form	--	--	--	0.6	--
						Cyclodextrin	--	--	--	--	0.75
The amine assisted delivery	--	0.2	--	--	--
						Preceding spices	--	--	--	--	--
Other minor component and moisture ^*
						PAD heat fusing thing ^**	Be	--	--	--	--
PAD sends out plastics fragrant ^**	--	--	--	Be	--

^*Surplus

^*In one aspect, described packing comprises hotmelt or sends out fragrant the above-mentioned PAD matrix system of plastic form.

Embodiment #8

In one aspect of the invention, described perfume delivery systems especially can be used for heavy duty liquid detergent and/or fabric intensifier.Described perfume delivery systems comprises:

1) the PAD matrix system of positively charged ion, negatively charged ion or non-ionic polymers form and/or AAD system

2) PAD of perfume microcapsule (PMC) form stores system

3) Ren Xuan free spice

Be not bound by theory, comprise the perfume delivery technology (PDT) of PAD matrix system and/or AAD system or a plurality of systems, can work in stability, deposition and the release at FMOT, SMOT and TMOT place by interacting to change spices with spices.Perfume microcapsule (PMC) also interacts to change spices in stability, deposition and the release at FMOT, SMOT and TMOT place with spices.Surprisingly, when storing system combinations, one or more PAD of one or more PAD matrix systems and/or one or more AAD systems and perfume microcapsule (PMC) form can significantly observe collaborative beneficial effect, beneficial effect or the combination of desired beneficial effect that described beneficial effect observes greater than independent PDT.In one aspect of the invention, but described PMC preload spices, but and the polymkeric substance preload spices in the PAD matrix system, or separate with spices and to join in the product.Be not bound by theory, the combination of PAD matrix system and/or AAD system and perfume microcapsule can be brought into play one or more functions.A kind of function is the deposition that PAD and/or AAD PDT can increase PMC.Another kind of function is that PAD and/or AAD can be used for " removing " owing to have PMC and obtainable spices.Be not bound by theory, some spices can leak out PMC during any stage of PMC life period, described life period comprise production, processing, purifying, separation, transportation, become assignment system with other or be stored in delivery system or product in during.Be not bound by theory, described PAD and/or AADPDT can improve some PRM, especially CLogP especially effectively less than those PRM of about 3 and/or Kovats index (KI) value sending less than those PRM of 1500.Some PRM can't remain among the PMC effectively, especially during the product stock and under the high temperature; And by combination PMC and PAD and/or AAD PDT, can more effectively send this type of PRM.Equally, by perfume intensity and feature that combination PMC and PAD and/or AAD PDT can't obtain to obtain the PDT combination is not provided at FMOT, SMOT and TMOT place, that tunable spices spreads is stable, spices and PDT area deposition and spices release characteristic.Be not bound by theory, when under no PMC situation, during with PAD and/or AAD PDT combination, because some among these PRM are high compaction, and can have low odor detection threshold (ODT), therefore can't effectively sending this type of PRM.Therefore, need usually to use PMC to suppress the content of free spices in the product, so that spices can not twist the consumer experience at FMOT place.Other PRM has limited stability during product stock, therefore be not bound by theory, PAD and/or AAD PDT by with add as free spice or seepage or be diffused into PMC or those PRM that other perfume delivery systems is outer interact in time, can be used for further minimizing the degraded of PRM.

Embodiment #9

In another aspect of the present invention, described perfume delivery systems especially can be used for heavy duty liquid detergent and/or fabric intensifier.Described perfume delivery systems comprises:

2) PAD of perfume microcapsule (PMC) form stores system

3) Ren Xuan free spice

4) " product or the packing on or among " FMOT PDT

FMOT PDT: be not bound by theory, FMOT PDT such as PAD heat fusing thing and/or PAD send out plastics fragrant and work by the interaction of spices and fragrance carrier such as polymkeric substance, to change flavor chemistry stability and spices rate of release, provide human consumer's desired intensity and feature surprisingly, when FMOT PDT and PAD and/or AAD PDT and/or PMC, also preferred unite to can be observed when using with free spice work in coordination with beneficial effect significantly.Be not bound by theory, PDT combination can be used for alleviating owing to PAD and/or AAD PDT and/or PMC and preload or adds the distortion of the fragrance characteristic that the interaction of spices produces separately.By using FMOT PDT, the combination of spices and PAD and/or AAD and/or PMC PDT can be optimised, so that maximum human consumer's beneficial effect to be provided during SMOT and TMOT.The formulator of spices and PDT is difficult in desirable flavour intensity and the feature of all human consumer's point of contact place acquisitions.Use FMOT PDT can reduce the influence of institute's spices of preparing and the FMOT experience of PDT such as straight product smell astoundingly.Equally, this minimizes some restriction to the spices preparation, and can make formulator can optimize PAD and/or AAD and/or PMCPDT, especially can be used for obtaining maximum TMOT effect.By this PDT combination, can reduce the distortion that needs is used for making the maximized straight product smell of TMOT beneficial effect.Specifically, because the accident of the straight product intensity relevant with above-mentioned unexpected spices interaction reduces and changing features can be alleviated by FMOT PDT, therefore when the combinatorial association with PAD and/or AAD and/or PMC PDT uses, maximum astoundingly to the needs of FMOT PDT.

Embodiment #10

In one aspect of the invention, described perfume delivery systems especially can be used for heavy duty liquid detergent and/or fabric intensifier.On the other hand, described perfume delivery systems comprises:

1) (optional) cationic polymers (PAD and/or AAD)

2) based on the PMC of urea or melamino-formaldehyde

3) free spice

4) on product top cover or the capping or under (choosing wantonly) heat fusing thing or send out the plastics insert fragrant

Embodiment #11

1) (optional) cationic polymers (PAD and/or AAD)

2) based on the PMC of urea or melamino-formaldehyde

3) free spice

5) light-preceding spices (PPP)

Be not bound by theory, PPP, PMC, PAD, AAD and APAD PDT and spices interact, to change stability, deposition and the release of FMOT, SMOT and TMOT place spices.Surprisingly, when PPP and PMC and/or PAD and/or AAD PDT combination, can be observed significant collaborative beneficial effect.Specifically, can select PPP PDT, so as from the PRM in zone discharge replenish PMC and/or PAD and/or the AAD PDT observed those.Specifically, though PMC and/or PAD and/or AAD PDT can be effectively to the multiple PRM of regional delivery, but in some cases, some PRM can cause desired intensity and feature to be distorted to cross lower concentration and be present in that the zone is gone up or to be discharged into above the zone in the headspace to cross slowly speed.After the long-time drying in zone, especially true.We find amazedly, when PPP and PMC and/or PAD PDT unite use, can keep feature and/or intensity for more time.In addition, PMC and PAD and/or AAD PDT can increase the deposition of PPPPDT.Be not bound by theory equally, PMC and/or PAD and/or AAD PDT can change the feature that discharges from the arid region from the spices of PPP.Be not bound by theory, this afterclap other PDT has due to changed PPP and the interaction of the PRM that discharges from the arid region, thereby has changed the spices release characteristic.

Embodiment #12

In one aspect of the invention, perfume delivery systems especially can be used in the clothes washing particle.On the other hand, described perfume delivery systems comprises:

1) SEA; With

2) PMC; With

3) (optional) spray perfume; With

4) " on product or the packing or among " (optional) FMOT PDT

Be not bound by theory, be surprisingly found out that, use SEA and PMC combination to have the symbiosis effect.Two kinds of PDT can use prerequisite for the volatile spice retention of improving the human consumer; Yet the different release characteristics of SEA and PMC can make delivery systme be superior to any PDT of independent use.It is very fast that product uses the back to discharge spices from SEA, and discharge slower from PMC.This strong property and the combination that discharges from the arid region triggering provide beneficial effect during whole experience.

Embodiment #13

1) PLZ and/or PLT; With

2) PMC; With

3) (optional) spray perfume; With

4) " on product or the packing or among " (optional) FMOT PDT

5) (optional) SEA

Be not bound by theory, be surprisingly found out that, use PLZ and/or PLT and PMC combination to have the symbiosis effect.Two kinds of PDT can use prerequisite for the volatile spice retention of improving the human consumer; Yet, the different release characteristics of SEA and PMC can, especially the feature that discharges from the arid region provides the unexpected delivery systme more superior than any independent PDT.Not bound by theory, PLZ and/or PLT are different with the spices release characteristic of PMC.For PLZ, cause spices and trigger release to the diffusion in the headspace of arid region by removing water-soluble coating.For PLT, by removing any capping group and spreading to trigger release by reverse capillary action.For PMC, also can be by removing optional water-soluble coating and/or triggering release by being diffused in the headspace of arid region.Optimized every kind of PDT, sending can be to the spices fragrant-inner agent of technique works.For PLZ, also based on molecular dimension PRM is selected.For PLT, the selection of PRM is based on numerous factors, comprises volatility, odor detection threshold, size and Kovats index (KI) value.For PMC, select to comprise the consideration to wall perviousness or seepage.Therefore, the combination of these PDT can be enriched the scope of PRM more, to obtain desired intensity and feature.Except spices diffusion releasing mechanism, also can select PMC to discharge or outburst to provide the spices friction to trigger, cause bigger perfume intensity and preferable feature.The spices diffusion of preferred PRM and this kind combination of spices outburst owing to changed releasing mechanism, provide than desired better accident and have improved beneficial effect.

Embodiment #14

1) is selected from the PDT of PLZ, SEA, CD, PMC

2) (optional) spray perfume; With

3) " product or the packing on or among " FMOT PDT

Because encloses container, the clothes washing particle is difficult to emit a smell.FMOT PDT on product or the packing outside surface provides FMOT flavour intensity and feature.On the other hand, be present in the FMOT PDT accident of packing on the internal surface synergy with other PDT is provided.

Embodiment #15

1) nanometer tubule (PLT); With

2) perfume microcapsule (PMC); With

3) (optional) spray perfume; With

4) " on product or the packing or among " (optional) FMOT PDT

5) (optional) SEA

Embodiment #16

In one aspect of the invention, perfume delivery systems especially can be used in the fabric softener sheet.On the other hand, described perfume delivery systems comprises:

1) cyclodextrin (CD); With

2) perfume microcapsule (PMC); With

3) (optional) pure spices; With

4) " on product or the packing or among " (optional) FMOT PDT

5) (optional) SEA

Embodiment #17

In one aspect of the invention, perfume delivery systems especially can be used in the fabric softener.On the other hand, described perfume delivery systems comprises:

1) hexadecanoic acid geraniol ester (palmitinic acid geraniol ester) 0.25%; With

2) perfume microcapsule (PMC) 1.3%; With

3) (optional) pure spices 0.6%; With

4) " on product or the packing or among " (optional) FMOT PDT

5) (optional) SEA

All listed among this embodiment 17 per-cents are all based on total product weight, and are irrelevant with any container and/or packing.

The weight percent of mentioned component can change on demand, for example the content of hexadecanoic acid geraniol ester (also being called as (E)-3,7-dimethyl-2,6-octadienyl n-Hexadecane acid esters) is about 0.05% to about 10%, about 0.1% to about 1%, or even about 0.25% to about 0.75%; The content of PMC is about 0.05% to about 10%, about 0.1% to about 3%, or even about 0.3% to about 1.5%; And pure flavour content is about 0.01% to about 10%, about 0.1% to about 3%, or even about 0.5% to about 1.5%.Above-mentioned perfume delivery systems can be used for comprising other cleaning and/or treating product in other consumer's goods, for example comprises this series products of least fat enzyme or fat-free enzyme.In addition, the alternative hexadecanoic acid geraniol ester of other terpenoid, or even can use beta-keto esters.Can be according to USP5, the instruction in 652,205, the terpenoid that preparation is suitable.For example, according to USP5, the instruction of example I in 625,205, and substitute succsinic acid with palmitinic acid, perhaps according to USP5, the instruction of example II in 652,205, and substitute lauroyl chloride with palmityl chloride, prepare the hexadecanoic acid geraniol ester.According to USP 6,100, the instruction in 233 and 5,965,767 prepares suitable beta-keto esters.

Embodiment #18

In one aspect of the invention, perfume delivery systems especially can be used in the shampoo.On the other hand, described perfume delivery systems comprises:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Lauryl polyethenoxy ether sodium sulfate/Texapon Special	16	14	20	16	14	20	16
Unister E 275	1.5	1.1	1.6	1.5	1.1	1.6	1.5
								Polydimethylsiloxane	1.4	1.1	1.8	1.4	1.1	1.8	1.4
Hexadecanol	0.90	1.2	1.4	0.90	1.2	1.4	0.90
								Coconut oleoyl amine MEA	0.75	0.95	0.55	0.75	0.95	0.55	0.75
Sodium-chlor	0.65	1.0	1.3	0.65	1.0	1.3	0.65
								Polyquaternium-10 (LR-400)	0.50	0.30	0.20	0.50	0.30	0.20	0.50
Trisodium Citrate	0.60	0.40	0.50	0.60	0.40	0.50	0.60
								The hydrogenation poly decene	0.30	0.20	0.70	0.30	0.20	0.70	0.30
Sodium Benzoate	0.20	0.35	0.40	0.20	0.35	0.40	0.20
								Disodium ethylene diamine tetraacetate	0.12	0.085	0.15	0.12	0.085	0.15	0.12
Trimethylolpropane tris octanoate/three decylates	0.10	0.15	0.10	0.10	0.15	0.10	0.10
								Citric acid	0.040	0.050	0.040	0.040	0.050	0.040	0.040
Provitamin	0.060	--	0.030	0.060	--	0.030	0.060
								Methylchloroisothiazandnone/	0.0004	0.0010	0.0003	0.0004	0.0010	0.0003	0.0004
Methylisothiazolinone	0.0001	0.0002	0.0003	0.0001	0.0002	0.0003	0.0001

The PAD of perfume microcapsule (PMC) form stores system	0.5	1.4	0.2	0.6	1.0	--	--
								The PAD matrix system	--	0.3 ^m	0.4	--	0.6	--	1.1
The amine assisted delivery	0.2	--	--	--	--	0.4	--
								Preceding spices	--	--	--	--	0.2	0.6	--
Be loaded with the tubule of spices	--	--	--	--	--	--	0.3
								Low KI spices fragrant-inner agent	--	--		0.2	0.2	0.1	0.3
Bonus flavor	0.5	0.3	0.7	0.4	0.6	1.1	--
								Water/carrier/refiner ^*
PAD heat fusing thing ^**	--	Be	--	Be	Be	--	--
								PAD sends out plastics fragrant ^**	--	--	Be	--	--	--	Be

^*Surplus

^*On the packing or the heat fusing thing in the packing and/or send out fragrant plastics and be not included in the prescription composition surplus.For this embodiment, the FMOT technology be positioned on the top cover or under.

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

Embodiment #19

In one aspect of the invention, perfume delivery systems especially can be used in the hair conditioner.On the other hand, described perfume delivery systems comprises:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Laureth-3-ammonium sulfate	10	10	12	10	10	10	10
Texapon Special	10	6	4	6	6	10	6
								Coconut oleoyl amine MEA	1.45	0.85	0.68	0.8	0.8	1.45	0.85
Polyquaternium 10 ⁵	0.2	0	0.4	0	0.15	0.2	0
								Rhaball Gum CG-M 8M ⁶	0	0.2	0	0.15	0	0	0.2
The hydrogenation polyalphaolefin ⁷	0.4	0.32	0.25	0.4	0.3	0.4	0.32
								Hexadecanol	0.42	0	0.42	0.6	0.42	0.42	0
Stearyl alcohol	0.18	0	0.18	0	0.18	0.18	0
								Unister E 275	1.5	2.0	1.5	1.5	2.0	1.5	2.0
Polydimethylsiloxane ⁸	2.0	1.0	0	0	1.5	2.0	1.0
								Monosodium phosphate	0.1	0.1	0.1	0	0	0.1	0.1

Di-Sodium Phosphate	0.1	0.2	0.2	0	0	0.1	0.2
								Ethylenediamine tetraacetic acid (EDTA)	0.1	0.1	0.1	0.1	0.1	0.1	0.1
The DMDM glycolylurea	0.37	0.37	0.37	0.37	0.37	0.37	0.37
								The PAD of microencapsulation form	0.5	1.4	0.2	0.6	1.0	--	--
The PAD of matrix system form	--	0.3	0.4	--	0.6	--	1.1
								The amine assisted delivery	0.2	--	--	--	--	0.4	--
Preceding spices	--	--	--	--	0.2	0.6	--
								Be loaded with the tubule of spices	--	--	--	--	--	--	0.3
Low KI spices fragrant-inner agent	--	--	--	0.2	0.2	0.1	0.3
								Bonus flavor	0.45	0.3	0.6	0.45	0.6	1.1	--
Water/carrier/refiner ⁹
								PAD heat fusing thing ¹⁰	--	Be	--	Be	Be	--	--
PAD sends out plastics fragrant ¹⁰	--	--	Be	--	--	--	Be

⁵JR 30M derives from Amerchol

⁶Jaguar C-17 derives from Rhone-Poulenc

⁷SHF 62, derive from Mobil Chemical

⁸Polydimethylsiloxane is that the SE-76 polydimethylsiloxane natural gum that derives from GeneralElectric Silicones Division of 40 (natural gum)/60 (fluid) weight ratios is the blend of the polydimethylsiloxane fluid of 350 centistokes with viscosity.

⁹Surplus

¹⁰On the packing or the heat fusing thing in the packing and/or send out fragrant plastics and be not included in the prescription composition surplus.For this embodiment, the FMOT technology be positioned on the top cover or under.

Embodiment #20

In one aspect of the invention, perfume delivery systems especially can be used in the bath shampoo.On the other hand, described perfume delivery systems comprises:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Sodium laureth sulfate	7.5	8.5	8.2	7.5	8.5	8.2	7.5
Cocoamidopropyl	6.5	5.5	4.5	6.5	5.5	4.5	6.5
								Sodium lauroyl sareosine	0.75	0.65	1.2	0.75	0.65	1.2	0.75
Citric acid	0.26	0.33	0.38	0.26	0.33	0.38	0.26
								Rhaball Gum CG-M 8M	0.50	0.30	0.30	0.50	0.30	0.30	0.50
Lauryl alcohol	0.65	0.80	0.77	0.65	0.80	0.77	0.65
								The DMDM glycolylurea	0.21	0.26	0.11	0.21	0.26	0.11	0.21
Sodium Benzoate	0.25	0.15	0.18	0.25	0.15	0.18	0.25
								Disodium ethylene diamine tetraacetate	0.10	0.05	0.20	0.10	0.05	0.20	0.10
The PAD microcapsule of PMC form	0.5	1.4	0.2	0.6	1.0	--	--
								The PAD matrix system	--	0.3 ^m	0.4	--	0.6	--	1.1
The amine assisted delivery	0.2	--	--	--	--	0.4	--
								Preceding spices	--	--	--	--	0.2 ^q	0.6 ^t	--
Be loaded with the tubule of spices	--	--	--	--	--	--	0.3
								Low KI spices fragrant-inner agent	--	--	--	0.2	0.2	0.1	0.3
Bonus flavor	0.5	0.3	0.7	0.4	0.6	1.1	--
								Water/carrier/refiner ^*
PAD heat fusing thing ^**	--	Be	--	Be	Be	--	--
								PAD sends out plastics fragrant ^**	--	--	Be	--	--	--	Be

^*Surplus

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

^qPreceding spices comprises light-preceding spices (PPP) system based on nitrogen, and described system discharges coumarin derivatives and spices aldehyde.

^tPreceding spices comprises light-preceding spices (PPP) system based on ester, and described system discharges coumarin derivatives and perfume alcohol.

Embodiment #21

In one aspect of the invention, perfume delivery systems especially can be used in the antiperspirant/deodorant.On the other hand, described perfume delivery systems comprises:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Ring-type polymethyl siloxane (Cyclomethicone)	7	7	6	8	7	7	7
Dimethicone copolyol	5	5	5	6	5	5	5
								Polydimethylsiloxane	7	--	3	6	7	6	8
Aluminium chlorhydrate salt	50	53	51	50	50	51	49
								Propylene glycol	15	15	15	15	15	15	15
PAD stores system	0.6	1.2	0.8	0.5	1.5	2.4	0.2
								The PAD matrix system	--	1.8	0.4	--	--	--	1.1
The amine assisted delivery	0.2	--	--	--	--	0.4	--
								Cyclodextrin	--	--	--	1.4	0.7	--	2.2
The starch capsule is sealed temper	--	--	0.6	--	--	--	--
								Low ODT spices fragrant-inner agent	--	--	--	0.2	0.2	0.1	0.3
Bonus flavor	0.5	0.3	0.7	0.4	0.6	1.1	--
								Water/carrier/refiner ^*
PAD heat fusing thing	Be	--	--	--	--	--	--
								PAD sends out plastics fragrant	--	--	Be	--	--	--	--

^*Surplus

Composition (per-cent by weight, %)	H	I	J	K	L	M	N
								The ring-type polymethyl siloxane	7	7	6	8	7	7	7
Dimethicone copolyol	5	5	5	6	5	5	5
								Polydimethylsiloxane	7	--	3	6	7	6	8
Aluminium chlorhydrate salt	50	53	51	50	50	51	49
								Propylene glycol	15	15	15	15	15	15	15
The PAD of PMC form stores system	--	--	--	--	1.0	--	--
								The molecule assisted delivery	--	--	3.5	--	--	--	--
Cyclodextrin	0.9	1.6	--	0.6	--	1.5	--
								The starch capsule is sealed temper	--	--	--	0.4	--	--	0.6
The ZIC of PLZ form	--	--	--	--	--	--	0.4

The ZIC of PLT form	--	1.5	--	--	--	--	--
								Preceding spices	--	--	--	--	0.2	0.4	--
Low KI spices fragrant-inner agent	--	--	0.5	0.4	0.2	0.1	0.3
								Bonus flavor	1.5	0.2	2.3	1.4	0.6	1.1	--
Water/carrier/refiner ^*
								PAD heat fusing thing	--	Be	--	Be	--	--	Be
PAD sends out plastics fragrant	Be	--	--	--	--	--	Be

^*Surplus

Embodiment #22

In one aspect of the invention, perfume delivery systems especially can be used in the invisible solid hidroschesis rod.On the other hand, described perfume delivery systems comprises:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Tetrachloro hydration aluminum zirconium glycine ¹	25.3	25.3	25.3	25.3	25.3	25.3	25.3
Encircle penta siloxanes	In right amount	In right amount	In right amount	In right amount	In right amount	In right amount	In right amount
								Vaseline	5.0	4.7	4.7	5.0	4.7	4.7	4.7
Ceresine	9.0	1.0	1.0	9.0	1.0	1.0	1.0
								Stearyl alcohol	--	12.0	12.0	--	12.0	12.0	12.0
The PPG-14 butyl ether	4.0	--	--	4.0	--	--	--
								Castor wax	9.0	9.0	9.0	9.0	9.0	9.0	9.0
Talcum	--	4.0	4.0	--	4.0	4.0	4.0
								Behenyl alcohol	--	0.2	0.2	--	0.2	0.2	0.2
D-panthenol triacetate	--	1.0	1.0	--	1.0	1.0	1.0
								The PAD of PMC form stores system	0.4	--	0.4	--	1.0	--	--
The molecule assisted delivery	--	--	3.5	--	1.0	--	--
								The starch capsule is sealed temper	--	--	--	0.4	--	--	0.6
Be loaded with the zeolite (PLZ) of spices	--	0.4	--	--	--	--	--
								Be loaded with the tubule (PLT) of spices	--	--	--	--	--	--	1.5
Preceding spices	--	--	--	--	0.2	0.4	--
								Low KI spices fragrant-inner agent	--	--	0.2	0.4	0.2	0.1	0.3
Main perfume compound	0.75	0.70	0.80	0.72	0.71	0.78	1.25

Height in Secondary Fragrance-beta-cyclodextrin mixture influences fragrant-inner agent ²	0.50	0.45	0.55	0.80	0.30	0.44	0.30
								Additional not cooperation cyclodextrin	0.9	1.6	--	0.6	--	1.5	--
Water/carrier/refiner ^*
								PAD heat fusing thing	--	Be	--	Be	--	--	Be
PAD sends out plastics fragrant	Be	--	--	--	--	--	Be

^*Surplus

Embodiment #23

In one aspect of the invention, perfume delivery systems especially can be used in the white cream type hidroschesis rod.On the other hand, described perfume delivery systems comprises:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Tetrachloro hydration aluminum zirconium glycine ¹	25.3	25.6	25.1	25.9	26.3	26.0	25.0
Encircle penta siloxanes	0.01	1.1	--	--	5	Trace	Trace
								Polydimethylsiloxane	5.2	5.1	4.9	4.5	5.5	4.9	5.0
Syncrowax HGLC	1.2	1.3	1.1	1.0	1.4	1.2	1.2
								Perhydro-high erucic acid rape seed oil	4.0	5.0	6.0	5.5	5.2	6.2	5.0
Mineral oil	1.0	--	1.2	--	0.8	--	--
								The PAD of PMC form stores system	0.6	1.2	0.8	0.5	1.5	2.4	0.2
The PAD matrix system	1.8 ^m	--	0.4	--	--	0.2	1.1
								The amine assisted delivery	0.2	0.3	--	--	--	0.4	--
The starch capsule is sealed temper	--	--	--	--	--	--	0.6
								Preceding spices	--	--	--	--	0.2	0.4	--
Main perfume compound	0.75	0.70	0.80	--	0.33	0.78	1.25
								Secondary Fragrance---the height in the beta-cyclodextrin mixture influences fragrant-inner agent ²	0.50	0.45	0.55	0.80	0.30	0.44	0.30
Additional not cooperation cyclodextrin	--	--	0.2	--	1.7	--	0.3
								Water/carrier/refiner ^*
PAD heat fusing thing ^**	--	Be	--	Be	--	--	Be
								PAD sends out plastics fragrant ^**	Be	--	--	--	--	--	Be

^*Surplus

¹The ratio of metal and metal chloride=1.25; 75% anhydrous no buffer reagent activity substance content (Westwood Chemical Co.)

²Perfume compound described in US2006/0263313

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

Embodiment #24

In one aspect of the invention, described perfume delivery systems especially can be used in fragrance oil/meticulous perfume composition.On the other hand, described perfume delivery systems comprises:

Composition (per-cent by weight, %)	A	B	C	D	E	F	G
								Perfume compound ³	1.5	5	4	7	12	5	4
Cyclodextrin (CD) ⁴	2.5	5	--	--	6	--	--
								Alternative additional ring dextrin	--	0.3	--	--	--	--	--
PAD stores system	--	--	1.1		1.2	--	0.8
								The PAD matrix system	--	--	2.1	1.8 ^m	--	--	--
The molecule assisted delivery	--	--	--	2	--	--	--
								The amine assisted delivery	0.3	--	--	--	0.3	0.5	0.2
Preceding spices	--	0.4	--	--	--	0.7	--
								Deionized water	15.8	12.9	13.7	12.9	--	13.3	12.9
Ethanol	To 100	To 100	To 100	To 100	To 100	To 100	To 100

^mThe PAD matrix system that comprises siloxanes assisted delivery (SAD) system

Composition (per-cent by weight, %)	H	I	J	K	L	M	N
								Perfume compound ³	1.5	5	4	7	12	5	4
Cyclodextrin (CD) ⁴	2.5	--	--	5	--	--	--
								PAD stores system	--	--	1.1	--	--	1.2	1.8
The PAD matrix system of SAD form	--	--	--	1.8	To 100	To 100	--
								The molecule assisted delivery	--	--	--	--	--	--	To 100
The amine assisted delivery	--	--	--	--	--	--	--
								The preceding spices of PPP form	--	0.4	--	--	--	--	--
ZIC	0.2	--	--	--	--	--	--
								Deionized water	15.8	12.9	13.7	12.9	--	--	--

Ethanol

To 100

--

PAD heat fusing thing

--

Be

--

PAD sends out plastics fragrant

--

Be

--

Be

³Be selected from the perfume compound of US 2007/0037731 A1 example I to the V.

⁴β W7 M derives from Wacker-Chemie GmbH, and Hanns-Seidel-Platz 4, Munchen, DE.

The All Files of quoting in detailed Description Of The Invention is all incorporated herein by reference in relevant portion.Should not be interpreted as admitting that for quoting of any file it is relevant prior art of the present invention.When any implication of term in any implication of term among the present invention or definition and the file of incorporating into way of reference or when defining contradiction, should obey implication or the definition of giving this term in the present invention.

Though illustrated and described specific embodiments of the present invention, it will be apparent to one skilled in the art that and under the situation that does not deviate from spirit and scope of the invention, can make various other changes and modification.Therefore, claims all such changes and modification of being intended to be included in the scope of the present invention.

Claims

1. packaged products, described product comprises:

A.) packing, described packing comprises 0.001% to 10% free spice and 0.001% to 50% spices package delivery system based on overall package weight; With

B.) product matrix, described product matrix comprises 0.001% to 30% free spice and 0.001% to 60% perfume delivery systems based on total product matrix weight,

Wherein said spices package delivery system comprises the material that is selected from by the following group of forming: heat fusing delivery system, the plastics that are loaded with spices and their mixture,

Wherein said spices package delivery system is positioned on the top of described packing, side or bottom, and

Preceding spices, the nano rubber latex that is loaded with spices, siloxanes assisted delivery system, the polymeric amine assisted delivery system that seal mixture, the starch capsule that wherein said perfume delivery systems is selected from perfume microcapsule, spices and cyclodextrin temper, water trigger, capsule is sealed or wrap the zeolite that is loaded with spices of quilt, the tubule that is loaded with spices, amine reaction product, light-triggered before spices and their mixture.

2. packaged products as claimed in claim 1, free spices is 1: 100 to 20: 1 with the ratio of spices package delivery system in the wherein said packing, and the ratio of dissociate in the described product matrix spices and perfume delivery systems is 1: 1000 to 20: 1.

3. packaged products as claimed in claim 1, wherein said product matrix is fluid, and described product matrix comprises one or more perfume delivery systems of 0.001% to 30% based on total product matrix weight.

4. packaged products as claimed in claim 1, wherein said product matrix comprise and have Kovats index less than the free spice of 1500 perfume base.

5. packaged products as claimed in claim 4, wherein said product matrix comprises 0.0001% to 60% described perfume base based on total product matrix weight, and described perfume base has the Kovats index less than 1500.

6. packaged products as claimed in claim 1, wherein said product matrix comprises 2% to 99.9% non-aqueous fluid based on total product matrix weight and has the Kovats index value less than free spice and the perfume delivery systems of 1500 perfume base, mixture, the starch capsule that described perfume delivery systems is selected from spices and cyclodextrin seal preceding spices, the perfume microcapsule that temper, water trigger, the zeolite that is loaded with spices, the tubule that is loaded with spices, amine reaction product, light-triggered before spices and their mixture.

7. packaged products as claimed in claim 1, wherein said product matrix comprises solid, and described product matrix comprises 0.001% to 30% free spice and one or more perfume delivery systems of 0.001% to 30% based on total product matrix weight.

8. packaged products as claimed in claim 7, wherein said product matrix comprises solid, described product matrix comprises and has the Kovats index value less than free spice and the perfume delivery systems of 1500 perfume base, mixture, the starch capsule that described perfume delivery systems is selected from spices and cyclodextrin seal preceding spices, the perfume microcapsule that temper, water trigger, the zeolite that is loaded with spices, the tubule that is loaded with spices, amine reaction product, light-triggered before spices and their mixture.

9. packaged products as claimed in claim 1, described product comprise perfume microcapsule and are loaded with matrix system and/or the amine assisted delivery system of spices.

10. packaged products as claimed in claim 1, described product comprises preceding spices and perfume microcapsule, the matrix system that is loaded with spices and/or amine assisted delivery system.

11. packaged products as claimed in claim 10, wherein said preceding spices comprises light-triggered preceding spices.

12. packaged products as claimed in claim 1, described product comprise the nanometer tubule that is loaded with spices.