CN101497768A - Silencing film for automobile - Google Patents

Silencing film for automobile Download PDF

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Publication number
CN101497768A
CN101497768A CNA2009100680201A CN200910068020A CN101497768A CN 101497768 A CN101497768 A CN 101497768A CN A2009100680201 A CNA2009100680201 A CN A2009100680201A CN 200910068020 A CN200910068020 A CN 200910068020A CN 101497768 A CN101497768 A CN 101497768A
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CN
China
Prior art keywords
automobile
film
resin
percent
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2009100680201A
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Chinese (zh)
Other versions
CN101497768B (en
Inventor
李建武
高之香
王永明
李士学
吴子刚
王艳芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongming Guangzhou Yang Auto Parts Co., Ltd.
Original Assignee
Sanyou Tianjin Macromolecular Techonoloy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyou Tianjin Macromolecular Techonoloy Co Ltd filed Critical Sanyou Tianjin Macromolecular Techonoloy Co Ltd
Priority to CN2009100680201A priority Critical patent/CN101497768B/en
Publication of CN101497768A publication Critical patent/CN101497768A/en
Application granted granted Critical
Publication of CN101497768B publication Critical patent/CN101497768B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention relates to a binding material, in particular to an automobile sound deadening film which is used on metal plates for locally reinforcing the metal plates and particularly on automobile doors to reduce noises generated by the vibration of a running automobile. The automobile sound deadening film is prepared by mixing and extruding 10-25 percent of synthetic rubber, 5-15 percent of thermoplastic resin, 5-20 percent of thickening resin, 10-25 percent of plasticizing agent, 25-50 percent of vibration damping and sound deadening agent, 10-20 percent of oil absorbing and filling agent and 5-10 percent of reinforcing filling material. The automobile sound deadening film can be used for the large-area sound deadening and vibration damping of the metal plates during the automobile manufacturing process. When being used, the automobile sound deadening film can be operated by hands, is innoxious and odorless, is easy to separate from release paper, has good manufacturability, can not shift after being pasted, is less susceptible to oil washing, phosphating process, electrophoresis, paint spraying and drying, and other subsequent automobile body manufacturing processes and is convenient to use.

Description

Silencing film for automobile
Technical field
The present invention relates to jointing material, particularly a kind of sheet metal, especially arrangements for automotive doors of being used for can be reduced in the noise that vibration produces takes place in the automobilism, and has the silencing film for automobile of sheet metal local reinforcement effect.
Background technology
In the body of a motor car manufacturing processed, adopt the pasty state sealing agent to seal noise reduction usually.Automobile one of the main source that produces noise that is in operation is a car door, and the pasty state sealing agent only is applicable to the noise reduction of the less and horizontal plane thin plate in slit, the performance muffler of having relatively high expectations for the arrangements for automotive doors part, the pasty state sealing agent is difficult to reach requirement, therefore, need a kind of vibration silencer performance height of development, the convenient product that uses, to improve car comfort.
Summary of the invention
The purpose of this invention is to provide a kind of nontoxic, tasteless, silencing film for automobile that good vibration damping erasure effect, good pasta bounding force are arranged.Synthetic rubber and the efficient vibration damping noise reduction weighting agent of this silencing film to have vibration damping erasure effect, be equipped with the thermoplastic resin that improves plasticity, add tackifying resin and can improve film to bonding force with oily steel plate with efficient oil suction weighting agent, prevent film displacement in use, add softening agent and can make rubber softening, be beneficial to construction; Make the film of preparing when guaranteeing enough bonding strengths and good vibration silencer, also have good manual operations.And can with hand the moulding silencing film be placed on required place compacting, floating according to particular location size and Special Circumstances.Tack-free in the construction process, nontoxic, tasteless, therefore, its application can not produce detrimentally affect to interior and environment.
The technical scheme that the present invention is taked for achieving the above object is: a kind of silencing film for automobile is the composition of forming by weight percentage, and its component is formed and the weight percentage ranges of each component is:
(1) synthetic rubber 10-25%
(2). thermoplastic resin 5-15%
(3). tackifying resin 5-20%
(4). softening agent 10-25%
(5). vibration damping sound-absorbing weighting agent 25-50%
(6). oil suction weighting agent 10-20%
(7). reinforced filling 5-10%
The method for preparing silencing film for automobile may further comprise the steps:
A. 10-25% synthetic rubber, 5-15% thermoplastic resin, 10-25% softening agent, 25-50% vibration damping sound-absorbing weighting agent, 10-20% oil suction weighting agent, 5-10% reinforced filling are mixed, stir, in two roller mills, be rolled into soft decorating film;
B. 5-20% tackifying resin is fully mediated in kneader with making soft decorating film;
C. extrude on separate paper by the product size requirement with screw extrusion press;
D. press the dimensional requirement cutting after applying combined glass glass cloth.
The beneficial effect that the present invention produces is: silencing film for automobile can be used for metal sheet big area vibration silencer in the automobile making process.Can use the hand direct control during use, nontoxic, tasteless, easy and separate paper breaks away from, and good manufacturability, and is unshift after pasting, and can stand vehicle body and make operations such as follow-up washing oil, phosphatization, electrophoresis, the baking of spraying paint, easy to use.
Embodiment
Silencing film for automobile is the composition of forming by weight percentage, and synthetic rubber is wherein selected polyisobutene, isoprene-isobutylene rubber, chlorinated butyl rubber, chloroprene rubber for use.
Thermoplastic resin is selected polyvinyl chloride (PVC) RESINS, vinyl chloride-vinyl acetate copolymer resin, acrylate resin, thermoplastic polyester for use.
Tackifying resin is selected petroleum resin, terpine resin, ancient marlon resin, liquid polybutene, esterase, staybelite for use.
Softening agent is selected naphthenic oil, 32# machine oil, low molecular weight polycaprolactone ester, adjacent stupid dioctyl phthalate butyl benzyl, Dinonylphthalate for use.
Vibration damping sound-absorbing weighting agent is selected mica powder, talcum powder, pure aluminium silicate, Magnesium Silicate q-agent, barium sulfate, magnesium oxide, perlite powder for use.
The oil suction weighting agent is selected active nano-calcium carbonate, active nano zinc oxide for use.
Reinforced filling is selected precipitated silica, hard(carbon)black for use.
Embodiment 1: silencing film for automobile is the composition of forming by weight percentage, and its component is formed and the weight percent of each component is:
Polyisobutene 10%
Polyvinyl chloride (PVC) RESINS 9.6%
Terpine resin 10.5%
Naphthenic oil 10%
Mica powder 38%
Active nano-calcium carbonate 15.6%
Hard(carbon)black 6.3%
The method for preparing silencing film for automobile may further comprise the steps:
A, the polyisobutene with 10%, 9.6% polyvinyl chloride (PVC) RESINS, 10% naphthenic oil, 38% mica powder, 15.6% active nano-calcium carbonate and 6.3% hard(carbon)black mix, and stir, and are rolled into soft decorating film in two roller mills;
B. 10.5% terpine resin is fully mediated in kneader with making soft decorating film;
C. extrude on separate paper by the product size requirement with screw extrusion press;
D. press the dimensional requirement cutting after applying combined glass glass cloth.
Example 2: silencing film for automobile is the composition of forming by weight percentage, and its component is formed and the weight percent of each component is:
Isoprene-isobutylene rubber 14%
Chloroprene rubber 2.0%
Vinyl chloride-vinyl acetate copolymer resin 8.3%
Petroleum resin 8.7%
Low molecular weight polycaprolactone ester 5.6%
32# machine oil 7.8%
Pure aluminium silicate 26.6%
Active nano-calcium carbonate 18.2%
Precipitated silica 6.4%
Hard(carbon)black 2.4%
The method for preparing silencing film for automobile may further comprise the steps:
A, the isoprene-isobutylene rubber with 14%, 2.0% chloroprene rubber, 8.3% vinyl chloride-vinyl acetate copolymer resin, 5.6% low molecular weight polycaprolactone ester, 7.8% 32# machine oil, 26.6% pure aluminium silicate, 18.2% active nano-calcium carbonate, 6.4% precipitated silica and 2.4% hard(carbon)black mix, stir, in two roller mills, be rolled into soft decorating film;
B. 8.7% petroleum resin are fully mediated in kneader with making soft decorating film;
C. extrude on separate paper by the product size requirement with screw extrusion press;
D. press the dimensional requirement cutting after applying combined glass glass cloth.
Example 3: silencing film for automobile is the composition of forming by weight percentage, and its component is formed and the weight percent of each component is:
Chlorinated butyl rubber 19.2%
Acrylate resin 12%
Ancient marlon resin 3.8%
Esterase 3.7%
Adjacent stupid dioctyl phthalate butyl benzyl 6.6%
Talcum powder 27.2%
Active nano zinc oxide 10.4%
Precipitated silica 5.5%
Hard(carbon)black 1.6%
The method for preparing silencing film for automobile may further comprise the steps:
A, the chlorinated butyl rubber with 19.2%, 12% acrylate resin, 16.6% adjacent stupid dioctyl phthalate butyl benzyl, 27.2% talcum powder, 10.4% active nano zinc oxide, 5.5% precipitated silica and 1.6% hard(carbon)black mix, stir, in two roller mills, be rolled into soft decorating film;
B. 3.8% ancient marlon resin and 3.7% esterase are fully mediated in kneader with making soft decorating film;
C. extrude on separate paper by the product size requirement with screw extrusion press;
D. press the dimensional requirement cutting after applying combined glass glass cloth.
Example 4: silencing film for automobile is the composition of forming by weight percentage, and its component is formed and the weight percent of each component is:
Isoprene-isobutylene rubber 9.2%
Polyisobutene 12.8%
Thermoplastic polyester 6.0%
Ancient marlon resin 4.0%
Staybelite 6.0%
Dinonylphthalate 16.6%
Magnesium Silicate q-agent 27.5%
Active nano zinc oxide 10.8%
Precipitated silica 5.5%
Hard(carbon)black 1.6%
The method for preparing silencing film for automobile may further comprise the steps:
A, the isoprene-isobutylene rubber with 9.2%, 12.8% polyisobutene, 6.0% thermoplastic polyester, 16.6% Dinonylphthalate, 27.5% Magnesium Silicate q-agent, 10.8% active nano zinc oxide, 5.5% precipitated silica and 1.6% hard(carbon)black mix, stir, in two roller mills, be rolled into soft decorating film;
B. 4.0% ancient marlon resin and 6.0% staybelite are fully mediated in kneader with making soft decorating film;
C. extrude on separate paper by the product size requirement with screw extrusion press;
D. press the dimensional requirement cutting after applying combined glass glass cloth.
Example 5: silencing film for automobile is the composition of forming by weight percentage, and its component is formed and the weight percent of each component is:
Isoprene-isobutylene rubber 16%
Chlorinated butyl rubber 9.0%
Acrylate resin 5%
Petroleum resin 8.0%
Liquid polybutene 7.0%
Dinonylphthalate 5.6%
32# machine oil 7.8%
Pure aluminium silicate 25.6%
Active nano-calcium carbonate 10.2%
Precipitated silica 3.8%
Hard(carbon)black 2.0%
The method for preparing silencing film for automobile may further comprise the steps:
A, the isoprene-isobutylene rubber with 16%, 9.0% chlorinated butyl rubber, 5% acrylate resin, 5.6% Dinonylphthalate, 7.8% 32# machine oil, 25.6% pure aluminium silicate, 10.2% active nano-calcium carbonate, 3.8% precipitated silica and 2.0% hard(carbon)black mix, stir, in two roller mills, be rolled into soft decorating film;
B. 8.0% petroleum resin and 7.0% liquid polybutene are fully mediated in kneader with making soft decorating film;
C. extrude on separate paper by the product size requirement with screw extrusion press;
D. press the dimensional requirement cutting after applying combined glass glass cloth.
Among the above embodiment, load weighted tackifying resin is fully mediated in kneader with making soft decorating film, promptly obtained the finished product material, in screw extrusion press, extrude.
Simultaneously apply glasscloth at the film of extruding, another side applies separate paper, and the film of determining qualified size with sanction glue machine promptly obtains finished product.Take separate paper during use off and stick on inboard the getting final product of the outer steel plate of car door.Recording technical indicator is:
Outward appearance (range estimation) black sheet
The insoluble mistake of tolerate P-levels liquid
Subtract vibratility (400HZ) 〉=0.3
Penetration degree (1/10mm) 60-90
Density (g/cm 3) 1.20 ± 0.05
Initial bonding strength (N/cm 2) 〉=5
Non-volatile part (%)〉98
Pasta cementability non-displacement
The heating droop (mm, 120 ℃, 20min)<5
Low-temperature bending does not rupture, does not separate
High thermal resistance is not separated
Quality guaranteed period (moon)〉3.

Claims (9)

1. a silencing film for automobile is the composition of forming by weight percentage, and its component is formed and the weight percentage ranges of each component is:
(1). synthetic rubber 10-25%
(2). thermoplastic resin 5-15%
(3). tackifying resin 5-20%
(4). softening agent 10-25%
(5). vibration damping sound-absorbing weighting agent 25-50%
(6). oil suction weighting agent 10-20%
(7). reinforced filling 5-10%.
2. silencing film for automobile according to claim 1, described synthetic rubber is selected polyisobutene, isoprene-isobutylene rubber, chlorinated butyl rubber, chloroprene rubber for use.
3. silencing film for automobile according to claim 1, described thermoplastic resin is selected polyvinyl chloride (PVC) RESINS, vinyl chloride-vinyl acetate copolymer resin, acrylate resin, thermoplastic polyester for use.
4. silencing film for automobile according to claim 1, described tackifying resin are selected petroleum resin, terpine resin, ancient marlon resin, liquid polybutene, esterase, staybelite for use.
5. silencing film for automobile according to claim 1, described softening agent are selected naphthenic oil, 32# machine oil, the adjacent stupid dioctyl phthalate butyl benzyl of low molecular weight polycaprolactone ester, Dinonylphthalate for use.
6. silencing film for automobile according to claim 1, described vibration damping sound-absorbing weighting agent is selected mica powder, talcum powder, pure aluminium silicate, Magnesium Silicate q-agent, barium sulfate, magnesium oxide, perlite powder for use.
7. silencing film for automobile according to claim 1, described oil suction weighting agent is selected active nano-calcium carbonate, active nano zinc oxide for use.
8. silencing film for automobile according to claim 1, described reinforced filling is selected precipitated silica, hard(carbon)black for use.
9. the preparation method of a silencing film for automobile is characterized in that may further comprise the steps:
A. 10-25% synthetic rubber, 5-15% thermoplastic resin, 10-25% softening agent, 25-50% vibration damping sound-absorbing weighting agent, 10-20% oil suction weighting agent, 5-10% reinforced filling are mixed, stir, in two roller mills, be rolled into soft decorating film;
B. 5-20% tackifying resin is fully mediated in kneader with the soft decorating film of making;
C. extrude on separate paper by the product size requirement with screw extrusion press;
D. press the dimensional requirement cutting after applying combined glass glass cloth.
CN2009100680201A 2009-03-04 2009-03-04 Silencing film for automobile Expired - Fee Related CN101497768B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2009100680201A CN101497768B (en) 2009-03-04 2009-03-04 Silencing film for automobile

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CN101497768B CN101497768B (en) 2011-08-31

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181238A (en) * 2011-04-19 2011-09-14 三友(天津)高分子技术有限公司 Heat-cured high-intensity flaky adhesive for automobile and preparation method thereof
CN102514286A (en) * 2011-12-07 2012-06-27 常熟市东涛金属复合材料有限公司 Composite metal vibration damper plate
CN102952468A (en) * 2012-10-27 2013-03-06 蚌埠凤凰滤清器有限责任公司 Filter adhesive film prepared by mixing neoprene and brominated butyl rubber
CN103320088A (en) * 2013-06-27 2013-09-25 苏州工业园区依利电子贸易有限公司 Silencing adhesive
CN103604746A (en) * 2013-11-27 2014-02-26 三友(天津)高分子技术有限公司 Initial viscosity testing machine and method for adhesive property of automobile silencing film
CN103980607A (en) * 2014-06-10 2014-08-13 广州市恩威曲新材料有限公司 Damping shock-absorption noise-reduction material, and preparation method and application thereof
CN104403601A (en) * 2014-11-04 2015-03-11 张桂华 Artificial board adhesive
CN104804313A (en) * 2015-05-08 2015-07-29 王本祥 Environment-friendly hot-melting damping plate and preparation method thereof
CN106085294A (en) * 2016-07-19 2016-11-09 柳州市兴拓工贸有限责任公司 Automobile multifunctional damping film and preparation method thereof
CN106221603A (en) * 2016-09-20 2016-12-14 东莞市纳利光学材料有限公司 A kind of noise reduction protecting film and preparation method thereof
CN106476987A (en) * 2016-11-30 2017-03-08 南京睿宇物联网科技有限公司 A kind of fire-retardant sound insulation watertight door
CN106628046A (en) * 2016-11-30 2017-05-10 南京睿宇物联网科技有限公司 Flame-retardant corrosion-resistant watertight door
CN109320861A (en) * 2018-10-25 2019-02-12 株洲时代新材料科技股份有限公司 A kind of wide temperature zone high damping halogenated butyl rubber material and preparation method thereof
CN110014708A (en) * 2019-03-12 2019-07-16 天津市浩迪橡塑科技有限公司 Dedicated cladded type foaming damping piece of a kind of car door and preparation method thereof
CN110819016A (en) * 2019-12-12 2020-02-21 张家港爱科思汽车配件有限公司 Butyl damping fin
CN111205784A (en) * 2020-01-17 2020-05-29 天津瑞宏汽车配件制造有限公司 Vibration-damping noise-reducing glue for high-efficiency vibration-damping noise-reducing film
CN114072478A (en) * 2019-08-15 2022-02-18 电化株式会社 Adhesive tape

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1176157C (en) * 2002-12-26 2004-11-17 上海交通大学 Soft superhigh gravity composite materials for acoustic insulation and noise elimination

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181238A (en) * 2011-04-19 2011-09-14 三友(天津)高分子技术有限公司 Heat-cured high-intensity flaky adhesive for automobile and preparation method thereof
CN102514286A (en) * 2011-12-07 2012-06-27 常熟市东涛金属复合材料有限公司 Composite metal vibration damper plate
CN102952468A (en) * 2012-10-27 2013-03-06 蚌埠凤凰滤清器有限责任公司 Filter adhesive film prepared by mixing neoprene and brominated butyl rubber
CN102952468B (en) * 2012-10-27 2013-11-13 蚌埠凤凰滤清器有限责任公司 Filter adhesive film prepared by mixing neoprene and brominated butyl rubber
CN103320088A (en) * 2013-06-27 2013-09-25 苏州工业园区依利电子贸易有限公司 Silencing adhesive
CN103604746A (en) * 2013-11-27 2014-02-26 三友(天津)高分子技术有限公司 Initial viscosity testing machine and method for adhesive property of automobile silencing film
CN103980607A (en) * 2014-06-10 2014-08-13 广州市恩威曲新材料有限公司 Damping shock-absorption noise-reduction material, and preparation method and application thereof
CN104403601A (en) * 2014-11-04 2015-03-11 张桂华 Artificial board adhesive
CN104804313A (en) * 2015-05-08 2015-07-29 王本祥 Environment-friendly hot-melting damping plate and preparation method thereof
CN106085294B (en) * 2016-07-19 2018-06-12 柳州市兴拓工贸有限责任公司 Automobile multifunctional damping film and preparation method thereof
CN106085294A (en) * 2016-07-19 2016-11-09 柳州市兴拓工贸有限责任公司 Automobile multifunctional damping film and preparation method thereof
CN106221603A (en) * 2016-09-20 2016-12-14 东莞市纳利光学材料有限公司 A kind of noise reduction protecting film and preparation method thereof
CN106628046A (en) * 2016-11-30 2017-05-10 南京睿宇物联网科技有限公司 Flame-retardant corrosion-resistant watertight door
CN106476987A (en) * 2016-11-30 2017-03-08 南京睿宇物联网科技有限公司 A kind of fire-retardant sound insulation watertight door
CN109320861A (en) * 2018-10-25 2019-02-12 株洲时代新材料科技股份有限公司 A kind of wide temperature zone high damping halogenated butyl rubber material and preparation method thereof
CN110014708A (en) * 2019-03-12 2019-07-16 天津市浩迪橡塑科技有限公司 Dedicated cladded type foaming damping piece of a kind of car door and preparation method thereof
CN110014708B (en) * 2019-03-12 2021-05-04 天津市浩迪橡塑科技有限公司 Coated brewing vibration sheet special for automobile door and preparation method thereof
CN114072478A (en) * 2019-08-15 2022-02-18 电化株式会社 Adhesive tape
CN114072478B (en) * 2019-08-15 2023-07-25 电化株式会社 Adhesive tape
CN110819016A (en) * 2019-12-12 2020-02-21 张家港爱科思汽车配件有限公司 Butyl damping fin
CN110819016B (en) * 2019-12-12 2022-06-10 张家港爱科思汽车配件有限公司 Butyl damping fin
CN111205784A (en) * 2020-01-17 2020-05-29 天津瑞宏汽车配件制造有限公司 Vibration-damping noise-reducing glue for high-efficiency vibration-damping noise-reducing film

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Owner name: GUANGZHOU DONGMINGYANG AUTO PARTS CO., LTD.

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Address after: 510800 Guangdong city in Guangzhou Province, Xinhua Street, Huadu District, Xinhua Industrial Zone No. 32 Longhai Road, No. 9 by tanway science and Technology Park

Patentee after: Dongming Guangzhou Yang Auto Parts Co., Ltd.

Address before: 300211 Taishan Road, Tianjin, No. 6, No.

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