CN101489780A - Alcohol and water repellent non-woven fabrics - Google Patents
Alcohol and water repellent non-woven fabrics Download PDFInfo
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- CN101489780A CN101489780A CNA2007800088542A CN200780008854A CN101489780A CN 101489780 A CN101489780 A CN 101489780A CN A2007800088542 A CNA2007800088542 A CN A2007800088542A CN 200780008854 A CN200780008854 A CN 200780008854A CN 101489780 A CN101489780 A CN 101489780A
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Abstract
The invention relates to alcohol and water repellent non-woven fabrics made from synthetic polymer fibers. The fibers comprise a surface modifier admixed with the synthetic polymer to impart alcohol and water repellency properties.
Description
Background of invention
The present invention relates to the alcohol and water repellent supatex fabric made by the synthetic polymeric fibers that mixes with surface modifier.
The purposes of supatex fabric is various, comprises as hospital apparel, and for example surgery is used with coverlet, surgery with cap, surgery and hidden clothes, surgery work clothes, and curtain.Supatex fabric also can be used in the filter,, is used for filter particulates and aerosol (aerosol) pollutant, for example face shield, water filter and air cleaner that is.
Multiple fluorine-containing chemical (fluorochemicals) has been used to make various substrates to possess water proofing property, grease proofness and soil pollution resistance.The most normal employing topical application of these fluorine-containing chemicals (for example, by spraying, filler, or (finish bath immersion) soaked in the finished product bath).Formed supporting prevents that the property substrate has obtained extensive use in the field of paying attention to waterproof and/or grease proofing (and soil anti-soil) characteristic, for example be used for the protective garment that medical technician and laboratory workman wear, expect that here it can prevent blood, blood-borne pathogens, and other body fluid passes fabric (that is, blocking-up and chemical toxicity or infectious substance contacts).For the great majority of these application, expect that also it has antistatic property.
Static charge buildup is in the processing of many industrial products and material and the reason that various problems produces in using.Electrostatic charge may cause material to stick together or repel mutually.This is the problem in the processing of fiber and textile especially.In addition, static charge buildup may cause object attract dirt and dust, thereby reduces the effectiveness that fluorine-containing chemical supports anti-agent (fiuorochemicalrepellent).Static release from insulating bodies also may bring serious danger.For example, in the presence of flammable materials, for example, under surgical environments, static discharges may become burning things which may cause a fire disaster, causes and catches fire and/or explode.Static is the problem in the electronics industry especially, because modern electronics very easily discharges by permanent damages because of static.
Traditional antistatic additive (wherein major part is a wetting agent, and electric-charge-dissipating is carried out in its absorption and conduction that relies on water) be not very effective with fluorine-containing chemical when anti-agent is used in combination usually.The result of this combination greatly disappear when causing antistatic property usually or supporting anti-characteristic (perhaps both) (and even elimination) with respect to the arbitrary additive of independent use.
In addition, traditional antistatic additive and fluorine-containing chemical are combined in the polymer melt processed and applied to anti-agent, this point is difficulty very, because for example, the water relevant with the wetting agent antistatic additive can evaporate rapidly under the melt processing temperature.This just causes forming undesirable bubble in polymer, and causes extrusion equipment screw slippage to occur.Many antistatic additive also lack essential heat endurance, cause producing bad smell (for example, in melting and spraying application, use high extrusion temperature).
Therefore, still need the fabric of alcohol and water repellent, expect that it can also make substrate possess good antistatic property and characteristic is prevented in good supporting, particularly can be used as melt additive, and can not cause processing problems or metal defects.
Summary of the invention
The present invention relates to the supatex fabric of the alcohol and water repellent made by synthetic polymeric fibers.Described fiber comprises the surface modifier that mixes with synthetic polymer, to produce the character of anti-pure and mild waterproof.Described surface modifier also can reduce buildup of static electricity.Therefore, fabric of the present invention provides antipollution barrier, and described pollution is aqueous solution (comprising body fluid) and alcohol solution (comprising isopropyl alcohol) for example, and can be used for for example hospital environment.
Therefore, first aspect of the present invention relates to the supatex fabric that comprises the synthetic polymeric fibers that mixes with surface modifier, the molecular weight of wherein said surface modifier is less than 25KDa, expectation is less than 20kDa, 18kDa, 16kDa, 15kDa, 14kDa, 13kDa, 12kDa, 11kDa, 10kDa, 8kDa, 6kDa, and even 4kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups.
In related fields, the present invention relates to comprise the article of fiber of the present invention.Can use the article of fiber making of the present invention to include but not limited to: surgery is used with coverlet, surgery with cap, surgery and is hidden clothes, surgery work clothes, mouth mask, gloves, curtain, and filter, that is, respirator, water filter, air cleaner or face shield.
On the other hand, the present invention relates to increase the method for the supatex fabric water proofing property of making by synthetic polymeric fibers, by described polymer fiber is mixed with surface modifier, the molecular weight of wherein said surface modifier is less than 25KDa, expectation is less than 20kDa, 18kDa, 16kDa, 15kDa, 14kDa, 13kDa, 12kDa, 11kDa, 10kDa, 8kDa, 6kDa, and even 4kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to increase water proofing property.
And on the other hand, the present invention relates to increase the method for the anti-alcohol of making by synthetic polymeric fibers of supatex fabric, by described polymer fiber is mixed with surface modifier, the molecular weight of wherein said surface modifier is less than 25KDa, expectation is less than 20kDa, 18kDa, 16kDa, 15kDa, 14kDa, 13kDa, 12kDa, 11kDa, 10kDa, 8kDa, 6kDa, and even 4kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to increase anti-alcohol.
On the other hand, the present invention relates to reduce the method for buildup of static electricity in the supatex fabric of making by synthetic polymeric fibers, by described polymer fiber is mixed with surface modifier, the molecular weight of wherein said surface modifier is less than 25KDa, expectation is less than 20kDa, 18kDa, 16kDa, 15kDa, 14kDa, 13kDa, 12kDa, 11kDa, 10kDa, 8kDa, 6kDa, and even 4kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to reduce buildup of static electricity.
On the other hand, the present invention relates to reduce the method that pathogen adheres to the supatex fabric of being made by synthetic polymeric fibers, by described polymer fiber is mixed with surface modifier, the molecular weight of wherein said surface modifier is less than 25KDa, expectation is less than 20kDa, 18kDa, 16kDa, 15kDa, 14kDa, 13kDa, 12kDa, 11kDa, 10kDa, 8kDa, 6kDa, and even 4kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to reduce the adhesion of pathogen to described fabric.
In above-mentioned either side, described synthetic polymeric fibers can include but not limited to be selected from following polymer: polyurethanes, polysulfones, Merlon, polyester, polyolefin, organosilicon polymer, polyamine, polyacrylonitrile, terephthalate and polysaccharide.Desirably, described synthetic polymeric fibers is to be selected from following polyolefin: polyethylene, polypropylene, polytetrafluoroethylene (PTFE), polystyrene, poly-(acronitrile-butadiene-styrene), polybutadiene, polyisoprene, polyvinyl acetate, polyvinyl chloride, and copolymer.
In above-mentioned either side, described polymerization site part can comprise block copolymer.Desirably, described polymerization site partly comprises following segment: polyurethanes, polyureas, polyamide, polyalkylene oxide, Merlon, polyester, polylactone, organosilicon polymer, polyether sulfone, polyolefin, polyvinyl derivative, polypeptide, polysaccharide, polysiloxanes, dimethyl silicone polymer, polyethylene-butylene, polyisobutene, polybutadiene, PPOX, PEO, PolyTHF or polyvinylidene (polyethylenebutylene).
In above-mentioned either side, fabric of the present invention comprises 0.05% to 15%, 0.05% to 13%, 0.05% to 10%, 0.05% to 5%, 0.05% to 3%, 0.5% to 15%, 0.5% to 10%, 0.5% to 6%, 0.5% to 4%, 1% to 15%, 1% to 10%, 1% to 8%, 1% to 6%, 1% to 5%, 2% to 5% or the surface modifier of 4% to 8% (w/w).
In above-mentioned either side, described surface active groups is selected from: dimethyl silicone polymer, hydrocarbon, fluorocarbon, fluorinated polyether, polyalkylene oxide and combination thereof.For example, described surface modifier can be the following formula description:
F
T-(oligo)-F
T
Perhaps
In following formula, FT is poly-fluorine organic (polyfluoroorgano) group, and oligo is an oligomeric segment, and LinkB is for connecting segment (coupling segment), and C is the chain termination group, and a is the integer greater than 0.Desirably, F
TBe poly-fluoroalkyl, and molecular weight is 100 to 1,500Da.The fluoro-alkyl example that can be used for surface modifier of the present invention comprises general formula CF
3(CF
2)
rCH
2CH
2-group, wherein r is 2 to 20 and general formula CF
3(CF
2)
s(CH
2CH
2O)
χGroup, wherein χ is 1 to 10, and s is 1 to 20.Desirably, oligo is that repetitive is less than 20 the side chain or the oligomeric segment of non-side chain.
In above-mentioned either side, described surface active groups is described with following formula:
F
T-[B-(oligo)]
n-B-F
T
In following formula, F
TFor poly-fluorine organic group (that is, comprises general formula CF
3(CF
2)
rCH
2CH
2-group, wherein r is 2 to 20 and general formula CF
3(CF
2)
s(CH
2CH
2O)
χGroup, wherein χ is 1 to 10, and s is 1 to 20); B wraps urea-alkyl containing; Oligo comprises PPOX, PEO, or PolyTHF; And n is 1 to 10 integer.
" oligo " is meant the repetitive or the unit of relatively short length, is less than about 50 monomeric units usually, and molecular weight is less than 10,000, but preferred＜5000.Preferably, oligo is selected from: polyurethanes, polyureas, polyamide, polyalkylene oxide, Merlon, polyester, polylactone, organosilicon polymer, polyether sulfone, polyolefin, polyethylene, polypeptide, polysaccharide; And be connected with the segment of ether and amine.
As used herein, " surface modifier " is meant low-molecular-weight relatively polymer, and it comprises less than 20kDa, and the core that is connected with covalent bond with at least one surface active groups.The low-molecular-weight of surface modifier makes in the middle of its macromolecule polyalcohol chain that can be scattered in synthetic polymeric fibers.
" surface active groups " is meant the lipophilic group that is connected with surface modifier with covalent bond.The position of surface active groups can cover one or two end of surface modifier site polymerization part, perhaps can link to each other with the one or more side chains that are present in surface modifier site polymerization part.The example of surface active groups includes but not limited to: dimethyl silicone polymer, hydrocarbon, fluorocarbon, fluorinated polyether, polyalkylene oxide, and combination.
" minimizing buildup of static electricity " is meant with the identical fabric of the no surface modifier for preparing and compares, and the buildup of static electricity that contains the fabric of surface modifier reduces.The method of assessment static of the fabric electric-charge-dissipating feature is seen embodiment.
" increase water proofing property " is meant with the identical fabric of the no surface modifier for preparing and compares, and the water proofing property that contains the fabric of surface modifier increases.The assessment fabric supports the method for anti-property feature and sees embodiment.
" increase anti-alcohol " and be meant with the identical fabric of the no surface modifier for preparing and compare, the fabric that contains surface modifier is to the anti-property increase of supporting of methyl alcohol, ethanol and propyl alcohol.The assessment fabric supports the method for anti-property feature and sees embodiment.
The adhesion of pathogen " reduce " when being meant in being exposed to pathogen, compares with the identical fabric of the no surface modifier of preparation, and the fabric that contains surface modifier is by pathogen (that is, fungi, bacterium and/or the virus) adhesion or the minimizing of growing surely.Pathogen to the available known method of the adhesion of fabric come quantitatively (referring to, for example, people such as Klueh, J Biomed.Mater.Res., 53:621 (2000)).
As used herein, " LinkB " is meant the connection segment that two oligo parts and surface active groups can be connected with covalent bond.Usually, the molecular weight of linkB molecule is 40 to 700.Preferably; the linkB molecule is selected from: the triamine of functional groupization, vulcabond, disulfonic acid, dicarboxylic acids, diacyl chlorine and dialdehyde; the component of wherein said functional groupization has secondary official energy chemistry (secondary functional chemistry), and the chemistry that is used for surface active groups connects.This secondary group (secondary group) comprises, for example, and ester, carboxylate, sulfonate, phosphonate, mercaptan, vinyl (vinyls) and secondary amine.Terminal hydroxyl on the oligo intermediate, amine or carboxylic acid can form the oligo-acid amides with diamine reactant; Form oligo-carbamate (oligo-urethanes), oligo-urea, oligo-acid amides with di-isocyanate reaction; Form oligo-sulphonic acid ester, oligo-sulfonamide with the disulfonic acid reaction; Form oligo-ester, oligo-acid amides with the dicarboxylic acids reaction; Form oligo-ester, oligo-acid amides with the reaction of diacyl chlorine; Form oligo-acetal (acetal), oligo-imines with two aldehyde reactions.
As used herein, " C " is meant chain termination group.The example of chain termination group comprises the monofunctional group that contains amine, alcohol or carboxylic-acid functional base.
Further feature of the present invention and advantage will obviously easily be seen in following detailed description and claims.
Detailed Description Of The Invention
Method and composition of the present invention relates to the supatex fabric of being made by the synthetic polymeric fibers that mixes with surface modifier of the present invention.Fabric of the present invention has alcohol and water repellent.Described fabric can also antistatic accumulation.
The preparation method of surface modifier of the present invention sees and is set forth in U.S. Patent No. 6,127,507, incorporates this paper by reference into.The selected surface modifier of the present invention, comprise the core compatible with polymer fiber and with the inconsistent surface-active part of polymer fiber.Select the compatibility segment of surface modifier, so that the anchor site of surface modifier in the polymer fiber substrate when mixing to be provided.Surface active groups partly helps surface modifier is transported to the mixture surface, and this moment, the surface-active end group was exposed to outside the surface.Therefore, any loss of surface modifier on fiber of the present invention or fabric face all continues to migrate to the surface from mixture by surface modifier and replenished.The driving force of back one process is considered to the thermodynamics incompatibility of surface active groups and polymeric substrates, and the tendency of setting up low-surface-energy on the surface of mixture.When obtaining balance between grappling and the surface migration, it is stable that surface modifier keeps on the surface of polymer, meanwhile changes surface nature.
Suitable synthetic polymer (it can be a thermoplasticity or heat cured) includes but not limited to: daily plastic, for example poly-(vinyl chloride), polyethylene (high density, low-density, extra-low density), polypropylene and polystyrene; Engineering plastics, for example, polyester (as, poly-(PETP) and poly-(butylene terephthalate)), polyamide (aliphatic, amorphous, aromatic series), Merlon (for example, aromatic polycarbonate, as derivative) by bisphenol-A, polyformaldehyde, polyacrylate and polymethacrylates (as, poly-(methyl methacrylate)), some MPS (for example, styrene-acrylonitrile (SAN) and acrylonitrile-butadiene-styrene (ABS) (ABS) copolymer), high impact polystyrene (SB), fluoroplastics, and mixture, for example poly-(phenylate)-polystyrene and polycarbonate-ABS; High performance plastics, for example, liquid crystal polymer (LCP), polyether-ketone (PEEK), polysulfones, polyimides and PEI; Thermosetting plastic, for example, alkyd resins, phenolic resins, amino resins are (for example, melamine and urea resin), epoxy resin, unsaturated polyester (UP) (comprising so-called vinyl esters), polyurethanes, allylic (for example, the derived polymer of allyl diglycol carbonates (allyldiglycolcarbonate)), fluorubber and polyacrylate; And composition thereof.
Synthetic polymeric fibers combines with surface modifier of the present invention and forms mixture.In view of the machinability of its melt, more preferably thermoplastic polymer.Thermoplastic polymer at high temperature has melt processability, and described high temperature for example is higher than 120 ℃ (more preferably, are higher than 200 ℃, and even are higher than 300 ℃).Desirable thermosetting polymer comprises: polyurethanes, epoxy resin and unsaturated polyester (UP).Desirable thermoplastic polymer comprises, for example: the copolymer of polypropylene, polyethylene, ethene and one or more alpha-olefins (for example, poly-(ethene-butylene) and gather (ethylene-octene)), polyester, polyurethanes, Merlon, PEI, polyimides, polyether-ketone, polysulfones, polystyrene, Acrylonitrile Butadiene, polyamide, fluorubber, and composition thereof.
Carry out the melt first being processed at polymer and add surface modifier generation fiber.In order to be processed to form mixture by melt, surface modifier can, for example,, carry out melt processing with known method then with the mixed with polymers of making granular or powdery, for example, casting mold (molding), melt and spray, melt spinning, or melt extruding.Surface modifier can be directly and mixed with polymers, perhaps can at first carry out premix with polymer, forms surface modifier concentrate/mixture of polymers.If desired, the organic solution of surface modifier can with make powdery or granular mixed with polymers, evaporating solvent then carries out melt processing again.Perhaps, surface modifier can be injected the polymerization logistics of fusing, before being about to be squeezed into fiber, form mixture.
After melt processing, can carry out annealing steps to promote that polymer fiber is antistatic and to support the formation of anti-characteristic.Except that annealing steps, or replace annealing steps, can also between the roller of two heating to the composition embossing (emboss) after the melt processing, one or two roller can have pattern.Annealing steps carry out being lower than under the melt temperature of polymer usually (for example, if polyamide, about 150 to 220 ℃ down annealing reach 5 minutes).
Be added to the amount of the surface modifier in thermoplasticity or the thermosetting polymer, should be enough to obtain required antistatic of application-specific and support anti-characteristic.Usually, the consumption of surface modifier is 0.05 to 15% (w/w) of mixture.Can determine consumption by rule of thumb, perhaps can adjust as required, obtaining antistatic and to support anti-characteristic, and other physical characteristic of impact polymer not.
Form thus melt and spray or melt spun fibre is used to make supatex fabric, it is in office what is the need for and want certain level antistatic and support in the application of preventing characteristic purposes is all arranged.For example, fabric of the present invention can be used for medical fabrics, medical treatment and industrial apparel, is used to make the fabric of clothes, family expenses stuff and filtration system, for example chemical technology filter or respirator.This fabric has anti-pure and mild fire resistance characteristic.This fabric also can have antistatic and grease proofing characteristic (with the soil pollution resistance) under various environmental conditions, and can be used for multiple application.
Can by melt and spray or spun-bonded fibre net production in used method prepare non-woven webs or fabric.For example, can use Wente at " superfine thermoplastic fibre (SuperfineThermoplastic Fibers) " Indus.Eng ' g Chem.48, in 1342 (1956), the perhaps similar approach of people described in " production of superfine organic fiber (Manufacture of Superfine OrganicFibers) " Naval Research Laboratories Report No.4364 (1954) such as Wente.The sandwich construction of being made by supatex fabric has wide industrial and commercial use, for example as medical fabrics.The composition of the formation layer of this sandwich construction, can be according to required final operating characteristic and different, in many useful combinations, this structure can comprise two-layer or two-layer above melting and spraying and spun-bonded fibre net, for example in U.S. Patent No. 5,145,727 (people such as Potts) and U.S. Patent No.s 5, combination described in 149,576 people such as () Potts, these are described and incorporate this paper by reference into.Surface modifier can be applied to one or more layers of sandwich construction, make entire infrastructure possess antistatic and support anti-characteristic.
Fabric feature of the present invention is that its surface can be resisted the adhesion of pathogen (as fungi, bacterium and virus) or be grown surely.Therefore, fabric of the present invention can be used for reducing dirt and keeps aseptic.
If desired, fabric of the present invention can also comprise one or more this areas conventional additive commonly used, for example, and dyestuff, pigment, antioxidant, UV stabilizer, fire retardant, surfactant, plasticizer, tackifier, filler and composition thereof.Especially, can serviceability reinforcing agent (for example) as the polymer of polybutene, to improve antistatic in for example the melt additive polyolefin is used and/or to support anti-characteristic.
The proposition of following examples, for those of ordinary skill in the art complete open and described methods described herein and compound is how to implement, prepare and assess, and these embodiment are illustration of the present invention, can't limit the scope that the inventor confirms its invention.
Embodiment 1: support anti-property testing
Can with the mixture of deionized water and isopropyl alcohol (for example, 100/0,90/10,80/20,70/30,60/40,50/50 ... .10/90,0/100 (v/v) mixture) penetrativity of test fabric sample, assess the anti-alcohol of supatex fabric.At first, fabric of the present invention is placed on the surface of smooth, level.Get five small drops of water or water/isopropanol mixture, put gently on sample, at a distance of at least two inches.If after 45 is observed 10 seconds, see four spherical in shape or hemisphericals in five, think that then this fabric has to anti-property mixture.It is desirable to fabric has to anti-property 40/60 (water/isopropyl alcohol) mixture at least.
Perhaps, can use liquid to penetrate (strikethrough) Resistance Test and assess fabric the anti-ability of supporting of liquid.Penetrate (strikethrough) test instrument and comprise vertically arranged lucite pipe, flange is arranged at the bottom of pipe, settles fabric sample with rubber washer.Each specimen is fixed on the bottom of pipe.With in test solution to be measured (that is, water, alcohol, oil or its mixture) inlet tube, produce the hydraulic pressure of fixed rate increase with the filling speed set.Liquid and supatex fabric are all transferred to 23 ± 1 ℃.When first drop of liquid penetrates sample, read post height (the milliliter number of liquid) for this sample.This value is high more, supports and prevents that property is big more.
Embodiment 2: the electrostatic charge dissipation test
The static charge dissipation characteristics of supatex fabric, can be according to federal test method standard (Federal Test Method Standard) 101B, method 4046, " antistatic behaviour of material (Antistatic Properties of Materials) ", use ETS406C type Static Decay TestUnit (the Electro-Tech Systems of manufacturer, Inc., Glenside Pa.) measures.This instrument observes surface voltage reduce to the die-away time of initial induced charge 10% from 5000 volts (any electrostatic charge of perhaps being inducted) by use high voltage (5000 volts) the initial electrostatic electric charge (electrostatic charge of on average inducting) of inducting on the surface of flat test material with the electric field tester.This is the electrostatic charge dissipation time.The electrostatic charge dissipation time is short more, and the antistatic behaviour of test material is good more.
Embodiment 3: surface resistivity (Resistivity) test
The surface resistivity of supatex fabric can be according to ASTM standard D-257 rules, and " D.C. resistance or the electricity of insulating materials led (D.C.Resistance or Conductance ofInsulating Materials) " measures.For example, (Glenside Pa.) measures surface resistivity for Electro-Tech Systems, Inc. can to use the ETS872 molded breadth range ohmer of being furnished with 803B type probe.This instrument is used 100 volts external voltage by two concentric ring electrodes that contact with flat test material, obtains the reading of surface resistivity, and unit is an ohm-sq.
Other embodiment
This paper is all incorporated in all publications, patent and patent application that this specification is mentioned by reference into, as each independent publication or patent application all clearly and individually explanation be to incorporate into by reference.
Although with its specific embodiment the present invention is done to describe, but be understood that, the present invention can do further modification, and this application can comprise various variation of the present invention, purposes or modification, principle of the present invention is followed in these variations, purposes or modification usually, comprise and depart from the present invention's content in the known or convention scope openly but in correlative technology field of the present invention, go for essential characteristic mentioned above, and drop within the scope of claims.
Other embodiment is in the scope of claims.
Claims (25)
1. supatex fabric that comprises the synthetic polymeric fibers that mixes with surface modifier, the molecular weight of wherein said surface modifier be less than 16kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups.
2. the fabric of claim 1, wherein said synthetic polymeric fibers comprise and are selected from following polymer: polyurethanes, polysulfones, Merlon, polyester, polyolefin, organosilicon polymer, polyamine, polyacrylonitrile, terephthalate and polysaccharide.
3. the fabric of claim 2, wherein said synthetic polymeric fibers is to be selected from following polyolefin: polyethylene, polypropylene, polytetrafluoroethylene (PTFE), polystyrene, poly-(acronitrile-butadiene-styrene), polybutadiene, polyisoprene, polyvinyl acetate, polyvinyl chloride and copolymer thereof.
4. the fabric of claim 1, wherein said polymerization site partly comprises block copolymer.
5. the fabric of claim 4, wherein said polymerization site partly comprises following segment: polyurethanes, polyureas, polyamide, polyalkylene oxide, Merlon, polyester, polylactone, organosilicon polymer, polyether sulfone, polyolefin, polyvinyl derivative, polypeptide, polysaccharide, polysiloxanes, dimethyl silicone polymer, polyethylene-butylene, polyisobutene, polybutadiene, PPOX, PEO, PolyTHF or polyvinylidene.
6. the fabric of claim 1, wherein said fabric comprises the described surface modifier of 0.05% to 5% (w/w).
7. the fabric of claim 1, wherein said surface active groups is selected from: dimethyl silicone polymer, hydrocarbon, fluorocarbon, fluorinated polyether, polyalkylene oxide and combination thereof.
8. the fabric of claim 1, wherein said surface modifier are that following formula is described:
F
T-(oligo)-F
T
F wherein
TBe poly-fluorine organic group, oligo is an oligomeric segment.
9. the fabric of claim 1, wherein said surface modifier are that following formula is described:
Wherein
(i) F
TFor poly-fluorine organic group, be connected with covalent bond with LinkB;
(ii) C is the chain termination group;
(iii) Oligo is an oligomeric segment;
(iv) LinkB is for connecting segment; And
(v) a is the integer greater than 0.
10. claim 8 or 9 fabric, wherein F
TBe poly-fluoroalkyl.
11. the fabric of claim 8 or 9, wherein F
TMolecular weight be 100 to 1,500Da.
12. the fabric of claim 8 or 9, wherein F
TBe selected from general formula CF
3(CF
2)
rCH
2CH
2-group, wherein r is 2 to 20; With general formula CF
3(CF
2)
s(CH
2CH
2O)
xGroup, wherein x is 1 to 10, and s is 1 to 20.
13. the fabric of claim 8 or 9, wherein said oligo are the oligomeric segment that is less than the side chain or the non-side chain of 20 repetitives.
14. the fabric of claim 13, wherein said polymerization site partly comprises following segment: polyurethanes, polyureas, polyamide, polyalkylene oxide, Merlon, polyester, polylactone, organosilicon polymer, polyether sulfone, polyolefin, polyvinyl derivative, polypeptide, polysaccharide, polysiloxanes, dimethyl silicone polymer, polyethylene-butylene, polyisobutene, polybutadiene, PPOX, PEO, PolyTHF or polyvinylidene.
15. article that comprise the fabric of claim 1.
16. the article of claim 15, wherein said article are selected from: surgery with cap, surgery with coverlet, surgery with hiding clothes, surgery with work clothes, mouth mask, gloves and surgery curtain.
17. the article of claim 15, wherein said article are the surgery curtain.
18. the article of claim 15, wherein said article are filter.
19. the article of claim 18, wherein said filter are the parts of respirator, water filter, air cleaner or face shield.
20. the method for the supatex fabric water proofing property that an increase is made by synthetic polymeric fibers, described method comprises makes described polymer fiber mix with surface modifier, the molecular weight of wherein said surface modifier is less than 16kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to increase water proofing property.
21. the method for the anti-alcohol of supatex fabric that an increase is made by synthetic polymeric fibers, described method comprises makes described polymer fiber mix with surface modifier, the molecular weight of wherein said surface modifier is less than 16kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to increase anti-alcohol.
22. the method for the supatex fabric buildup of static electricity that a minimizing is made by synthetic polymeric fibers, described method comprises makes described polymer fiber mix with surface modifier, the molecular weight of wherein said surface modifier is less than 16kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to reduce buildup of static electricity.
23. one kind is reduced the method that pathogen adheres to the supatex fabric of being made by synthetic polymeric fibers, described method comprises makes described polymer fiber mix with surface modifier, the molecular weight of wherein said surface modifier is less than 16kDa, and comprise the polymerization site part that is connected with covalent bond with surface active groups, the amount of wherein said surface modifier is enough to reduce the adhesion of pathogen to described fabric.
24. the fabric of claim 8, wherein said surface modifier is further described by following formula:
F
T-[B-(oligo)]
n-B-F
T
Wherein
B comprises carbamate;
Oligo comprises PPOX, PEO or PolyTHF;
F
TBe poly-fluorine organic group; And
N is 1 to 10 integer.
25. article that comprise the fabric of claim 24.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75949506P | 2006-01-17 | 2006-01-17 | |
| US60/759,495 | 2006-01-17 | ||
| US60/760,339 | 2006-01-18 |
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| Publication Number | Publication Date |
|---|---|
| CN101489780A true CN101489780A (en) | 2009-07-22 |
Family
ID=40892023
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007800088542A Pending CN101489780A (en) | 2006-01-17 | 2007-01-17 | Alcohol and water repellent non-woven fabrics |
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| Country | Link |
|---|---|
| CN (1) | CN101489780A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105169834A (en) * | 2015-10-13 | 2015-12-23 | 南通澳润建材科技有限公司 | Dust collection cloth bag used for moisture-contained gas |
| CN108796820A (en) * | 2018-06-22 | 2018-11-13 | 合肥洁诺医疗用品有限公司 | A kind of non-woven fabrics that humidity resistance is excellent |
| CN110177601A (en) * | 2016-11-29 | 2019-08-27 | 演出服装公司 | Modularization facial masks |
| CN110302594A (en) * | 2009-12-22 | 2019-10-08 | 霍林斯沃思和沃斯有限公司 | Filter medium and product comprising dendrimers and/or other components |
-
2007
- 2007-01-17 CN CNA2007800088542A patent/CN101489780A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110302594A (en) * | 2009-12-22 | 2019-10-08 | 霍林斯沃思和沃斯有限公司 | Filter medium and product comprising dendrimers and/or other components |
| CN110302594B (en) * | 2009-12-22 | 2021-06-29 | 贺氏（苏州）特殊材料有限公司 | Filter media and articles comprising dendrimers and/or other components |
| CN105169834A (en) * | 2015-10-13 | 2015-12-23 | 南通澳润建材科技有限公司 | Dust collection cloth bag used for moisture-contained gas |
| CN110177601A (en) * | 2016-11-29 | 2019-08-27 | 演出服装公司 | Modularization facial masks |
| CN110177601B (en) * | 2016-11-29 | 2021-01-26 | 演出服装公司 | Modular facial mask |
| CN108796820A (en) * | 2018-06-22 | 2018-11-13 | 合肥洁诺医疗用品有限公司 | A kind of non-woven fabrics that humidity resistance is excellent |
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