CN101488305A - Self-lighting one way perspective paste and manufacturing process thereof - Google Patents

Self-lighting one way perspective paste and manufacturing process thereof Download PDF

Info

Publication number
CN101488305A
CN101488305A CNA2009100455222A CN200910045522A CN101488305A CN 101488305 A CN101488305 A CN 101488305A CN A2009100455222 A CNA2009100455222 A CN A2009100455222A CN 200910045522 A CN200910045522 A CN 200910045522A CN 101488305 A CN101488305 A CN 101488305A
Authority
CN
China
Prior art keywords
parts
autoluminescence
phthalate
way perspective
lighting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2009100455222A
Other languages
Chinese (zh)
Inventor
陈富龙
倪品官
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI FUSHUN UNIDIRECTIONAL VISION MATERIAL CO Ltd
Original Assignee
SHANGHAI FUSHUN UNIDIRECTIONAL VISION MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI FUSHUN UNIDIRECTIONAL VISION MATERIAL CO Ltd filed Critical SHANGHAI FUSHUN UNIDIRECTIONAL VISION MATERIAL CO Ltd
Priority to CNA2009100455222A priority Critical patent/CN101488305A/en
Publication of CN101488305A publication Critical patent/CN101488305A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses an autoluminescence unidirectional perspective paste and a manufacturing method thereof. The autoluminescence unidirectional perspective paste comprises a bottom paper base and a polymer-based unidirectional perspective film thereon which is an autoluminescence thin film, the autoluminescence thin film is compounded on the paper base, the autoluminescence thin film material comprises the ingredients, based on 100 parts by weight of polyvinyl chloride, of: 15-35 parts of alkaline-earth metal aluminosilicate powders, 20-40 parts of plasticizer, 0.1-8 parts of stabilizing agent and 0-10 parts of other auxiliary agents, wherein, the other auxiliary agents are acrylic resin copolymers and/or chlorinated polyethylene. The manufacturing process thereof comprises the steps: 1, coating the autoluminescence thin film by a calendaring process on the surface of the paper base with a silica gel coating; 2, perforating the thin film so that the thin film forms a dense netlike thin film structure, and separating the thin film from the original paper base for future use; 3, coating adhesive on the paper base to be then bonded with the netlike thin film, thus forming the autoluminescence unidirectional perspective paste. The autoluminescence unidirectional perspective paste has the advantages of great ink absorption performance, convenient use, superior durability, auto-luminescent capability, energy consumption saving, no toxicity and zero radioactivity.

Description

Self-lighting one way perspective paste and manufacturing process thereof
Technical field
The present invention relates to a kind of single plane fluoroscopy pad pasting, relate in particular to a kind of self-lighting one way perspective paste, also relate to the manufacturing process of this one way perspective paste simultaneously.
Background technology
Luminous sheet material of tradition and film material adopt the surface to use luminescenjt powder or pigment coated mode, reach luminous voluntarily emergency identification and indicating effect.But exist fluorescent lifetime too short, pattern is too simple, shortcomings such as complicated, that application surface is narrow are installed.And because coating thickness is limited, easily swipe impaired or be corroded in the surface, and the coating ink absorption is poor, is difficult to keep the long period.
A kind of single plane fluoroscopy pad pasting is also arranged, be made up of PVC material and netted glass fibre, it is good that this material has pliability, and printing opacity is even, is convenient to cut apart, splices, consigns, and also is fit to the air brushing manufacturing.Its manufacture method can adopt knife scraping method, rolling process, applying method, but such material all is an organic material to combine, its hardness, heat distortion temperature, dimensional stability and reduction shrinkage factor are not fine, and its electrical insulating property and flame resistance are also undesirable sometimes in addition.
Therefore, be necessary the self-lighting one way perspective paste film that a kind of difficult scraping newly developed is impaired, ink absorption is good, improve the performance of single plane fluoroscopy pad pasting comprehensively.
Summary of the invention
Technical matters to be solved by this invention is, at existing single plane fluoroscopy pad pasting exist the surface easily scraping impaired or be corroded, the problem of ink absorption difference, the self-lighting one way perspective paste that a kind of durability is good, ink absorption is good is provided.
The present invention adopts following technical proposal to solve the problems of the technologies described above:
A kind of self-lighting one way perspective paste, be used for air brushing thereon and form advertisement layout, one way perspective paste comprise the bottom paper substrate and on polymer-based single-way perspective membrane, described polymer-based single-way perspective membrane is the autoluminescence film, the autoluminescence film is compounded on the paper substrate, described autoluminescence membraneous material also contains following component in 100 parts of Polyvinylchloride weight portions:
15-35 parts in alkaline earth aluminosilicate powder
20-40 parts in plastifier
0.1-8 parts of stabilizing agents
0-10 parts of other auxiliary agents,
Wherein, other auxiliary agents are acryl resin multipolymer and/or haloflex.
In technique scheme, 100 parts of weight portion meters of Polyvinylchloride, the alkaline earth aluminosilicate powder can be the arbitrary weight portion in 15 parts, 18 parts, 20 parts, 22 parts, 25 parts, 28 parts, 30 parts, 32 parts and 35 parts; Plastifier can be the arbitrary weight portion among 20 parts, 24 parts, 25 parts, 28 parts, 30 parts, 31 parts, 32 parts, 35 parts, 38 parts and 40 parts; Stabilizing agent can be the arbitrary weight portion among 0.1 part, 1.0 parts, 2.0 parts, 3.0 parts, 3.5 parts, 4.0 parts, 5.0 parts, 6.0 parts, 7.0 parts and 8.0 parts; Other auxiliary agents can be the arbitrary weight portion among 0 part, 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts and 10 parts.
On the technique scheme basis, described alkaline earth aluminosilicate fineness of powder is 100 orders-200 orders.
On the technique scheme basis, described plastifier is terephthalic acid (TPA) two (the 2-ethyl is an own) ester, diallyl phthalate, dioctyl phthalate, Bis(2-ethylhexyl) terephthalate, diethyl phthalate, diisobutyl phthalate, diisooctyl phthalate, dinonyl phthalate, diisooctyl phthalate, misery 13 esters of O-phthalic, phthalic acid fourth 14 esters, capryl octyl phthalate, O-phthalic ester butyl benzyl, phthalic acid two (methoxyl second) ester, phthalic acid two (methoxyl second) ester, phthalic acid C6~C10 n-alkanol mixed ester, phthalic acid C7~C10 alcohol mixed ester, dibutyl phthalate, di-sec-octyl phthalate, diisononyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, liquid nitrile rubber, the combination of one or several in chlorinated paraffin and the epoxidized soybean oil.
On the technique scheme basis, described stabilizing agent is one or two or more kinds the composition in barium-chromium-zinc stabilizer, zinc stearate, barium stearate, dolomol, liquid calcium zinc stabilizer, tribasic lead sulfate, dibasic lead phosphite, organic tin stabilizer, the liquid cadmium barium zinc stabilizer.
On the technique scheme basis, described Polyvinylchloride adopts suspension type polyvinyl-chloride.
A kind of manufacturing process of self-lighting one way perspective paste, in regular turn by following step manufacturing:
Step 1 overlays on the autoluminescence film on the paper substrate surface of silica-gel coating by calendering technology;
Step 2 to the film processing of punching, forms film to separate with raw base paper after the fine and close reticulated film structure standby;
Step 3 shifting adhesive coating on the paper substrate, is bonded into self-lighting one way perspective paste with reticulated film then.
On the technique scheme basis, described advertisement layout passes through the spray-drawing process air brushing on the single-way perspective membrane surface.
On the technique scheme basis, described spray-drawing process is a kind of in temperature-sensitive air brushing, hot transfer printing air brushing, static air brushing, ink-jet air brushing and the laser air brushing.
The present invention has following technique effect:
1. have good ink absorption, easy to use;
2. it is impaired, durable in use to be difficult for scraping, long service life;
3. can be luminous voluntarily, picture is clear bright-coloured, energy savings not only, and only need be by 20 minutes hold light and just can luminously reach tens hours;
4. do not contain radioactivity and noxious material, have good environment protecting.
Embodiment
A kind of self-lighting one way perspective paste, be used for air brushing thereon and form advertising plane, one way perspective paste comprise the bottom paper substrate and on polymer-based single-way perspective membrane, described polymer-based single-way perspective membrane is the autoluminescence film, the autoluminescence film is compounded on the paper substrate, described autoluminescence membraneous material also contains following component with 100 parts of Polyvinylchloride weight portions:
15-35 parts in alkaline earth aluminosilicate powder
20-40 parts in plastifier
0.1-8 parts of stabilizing agents
0-10 parts of other auxiliary agents,
Wherein, other auxiliary agents are acryl resin multipolymer and/or haloflex.
In the present embodiment, described alkaline earth aluminosilicate fineness of powder is 100 orders-200 orders.
In the present embodiment, described plastifier is terephthalic acid (TPA) two (the 2-ethyl is an own) ester, diallyl phthalate, dioctyl phthalate, Bis(2-ethylhexyl) terephthalate, diethyl phthalate, diisobutyl phthalate, diisooctyl phthalate, dinonyl phthalate, diisooctyl phthalate, misery 13 esters of O-phthalic, phthalic acid fourth 14 esters, capryl octyl phthalate, O-phthalic ester butyl benzyl, phthalic acid two (methoxyl second) ester, phthalic acid two (methoxyl second) ester, phthalic acid C6~C10 n-alkanol mixed ester, phthalic acid C7~C10 alcohol mixed ester, dibutyl phthalate, di-sec-octyl phthalate, diisononyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, liquid nitrile rubber, the combination of one or several in chlorinated paraffin and the epoxidized soybean oil.
In the present embodiment, described stabilizing agent is one or two or more kinds the composition in barium-chromium-zinc stabilizer, zinc stearate, barium stearate, dolomol, liquid calcium zinc stabilizer, tribasic lead sulfate, dibasic lead phosphite, organic tin stabilizer, the liquid cadmium barium zinc stabilizer.
In the present embodiment, described Polyvinylchloride adopts suspension type polyvinyl-chloride.
In the present embodiment, described advertising plane passes through the spray-drawing process air brushing on the single-way perspective membrane surface.
In the present embodiment, described spray-drawing process is a kind of in temperature-sensitive air brushing, hot transfer printing air brushing, static air brushing, ink-jet air brushing and the laser air brushing.
In the present embodiment, 100 parts of weight portion meters of Polyvinylchloride, the alkaline earth aluminosilicate powder can be the arbitrary weight portion in 15 parts, 18 parts, 20 parts, 22 parts, 25 parts, 28 parts, 30 parts, 32 parts and 35 parts; Plastifier can be the arbitrary weight portion among 20 parts, 24 parts, 25 parts, 28 parts, 30 parts, 31 parts, 32 parts, 35 parts, 38 parts and 40 parts; Stabilizing agent can be the arbitrary weight portion among 0.1 part, 1.0 parts, 2.0 parts, 3.0 parts, 3.5 parts, 4.0 parts, 5.0 parts, 6.0 parts, 7.0 parts and 8.0 parts; Other auxiliary agents can be the arbitrary weight portion among 0 part, 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts and 10 parts.Its concrete prescription corresponding relation can be as follows:
Prescription 1: 100 parts of Polyvinylchloride, 15 parts in alkaline earth aluminosilicate powder, 40 parts in plastifier, 0.1 part of stabilizing agent, 1 part of other auxiliary agent;
Prescription 2: 100 parts of Polyvinylchloride, 18 parts in alkaline earth aluminosilicate powder, 35 parts in plastifier, 1 part of stabilizing agent, 2 parts of other auxiliary agents;
Prescription 3: 100 parts of Polyvinylchloride, 15 parts in alkaline earth aluminosilicate powder, 30 parts in plastifier, 2 parts of stabilizing agents, 3 parts of other auxiliary agents;
Prescription 4: 100 parts of Polyvinylchloride, 20 parts in alkaline earth aluminosilicate powder, 28 parts in plastifier, 3 parts of stabilizing agents, 4 parts of other auxiliary agents;
Prescription 5: 100 parts of Polyvinylchloride, 22 parts in alkaline earth aluminosilicate powder, 25 parts in plastifier, 4 parts of stabilizing agents, 5 parts of other auxiliary agents;
Prescription 6: 100 parts of Polyvinylchloride, 28 parts in alkaline earth aluminosilicate powder, 40 parts in plastifier, 5 parts of stabilizing agents, 6 parts of other auxiliary agents;
Prescription 7: 100 parts of Polyvinylchloride, 32 parts in alkaline earth aluminosilicate powder, 40 parts in plastifier, 6 parts of stabilizing agents, 7 parts of other auxiliary agents;
Prescription 8: 100 parts of Polyvinylchloride, 16 parts in alkaline earth aluminosilicate powder, 33 parts in plastifier, 7 parts of stabilizing agents, 8 parts of other auxiliary agents;
Prescription 9: 100 parts of Polyvinylchloride, 21 parts in alkaline earth aluminosilicate powder, 30 parts in plastifier, 8 parts of stabilizing agents, 9 parts of other auxiliary agents;
Prescription 10: 100 parts of Polyvinylchloride, 27 parts in alkaline earth aluminosilicate powder, 25 parts in plastifier, 7.5 parts of stabilizing agents, 10 parts of other auxiliary agents.
Make self-lighting one way perspective paste by above-mentioned prescription, in regular turn by following step manufacturing:
Step 1 overlays on the autoluminescence film on the paper substrate surface of silica-gel coating by calendering technology;
Step 2 to the film processing of punching, forms film to separate with raw base paper after the fine and close reticulated film structure standby;
Step 3 shifting adhesive coating on the paper substrate, is bonded into self-lighting one way perspective paste with reticulated film then.
The purpose of film punching forms the technique effect as screen window, has therefore had the characteristics of single plane fluoroscopy
Effect is relatively: along with the alkaline earth aluminosilicate powder increases, the autoluminescence effect is strengthened in the above-mentioned prescription, but when the alkaline earth aluminosilicate powder is too high, the film flexibility decrease that becomes, and not folding, easily crisp.
The surface smoothness of the thin more product of the fineness of alkaline earth aluminosilicate powder is good more.
Stabiliser content should not be low excessively.
The batch mixing order of film also has requirement, if the film of making in no particular order blackout, the autoluminescence effect is bad.
Prolonging compression technology does not have excessive demand, just can finish technology and ensures the quality of products with the method for general calendering PVC film.

Claims (8)

1. self-lighting one way perspective paste, be used for air brushing thereon and form advertisement layout, one way perspective paste comprise the bottom paper substrate and on polymer-based single-way perspective membrane, it is characterized in that: described polymer-based single-way perspective membrane is the autoluminescence film, the autoluminescence film is compounded on the paper substrate, described autoluminescence membraneous material also contains following component in 100 parts of Polyvinylchloride weight portions:
15-35 parts in alkaline earth aluminosilicate powder
20-40 parts in plastifier
0.1-8 parts of stabilizing agents
0-10 parts of other auxiliary agents,
Wherein, other auxiliary agents are acryl resin multipolymer and/or haloflex.
2. self-lighting one way perspective paste according to claim 1 is characterized in that: described alkaline earth aluminosilicate fineness of powder is 100 orders-200 orders.
3. self-lighting one way perspective paste according to claim 1 is characterized in that: described plastifier is terephthalic acid (TPA) two (the 2-ethyl is an own) ester, diallyl phthalate, dioctyl phthalate, Bis(2-ethylhexyl) terephthalate, diethyl phthalate, diisobutyl phthalate, diisooctyl phthalate, dinonyl phthalate, diisooctyl phthalate, misery 13 esters of O-phthalic, phthalic acid fourth 14 esters, capryl octyl phthalate, O-phthalic ester butyl benzyl, phthalic acid two (methoxyl second) ester, phthalic acid two (methoxyl second) ester, phthalic acid C6~C10 n-alkanol mixed ester, phthalic acid C7~C10 alcohol mixed ester, dibutyl phthalate, di-sec-octyl phthalate, diisononyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, liquid nitrile rubber, the combination of one or several in chlorinated paraffin and the epoxidized soybean oil.
4. self-lighting one way perspective paste according to claim 1 is characterized in that: described stabilizing agent is one or two or more kinds the composition in barium-chromium-zinc stabilizer, zinc stearate, barium stearate, dolomol, liquid calcium zinc stabilizer, tribasic lead sulfate, dibasic lead phosphite, organic tin stabilizer, the liquid cadmium barium zinc stabilizer.
5. self-lighting one way perspective paste according to claim 1 is characterized in that: described Polyvinylchloride adopts suspension type polyvinyl-chloride.
6. at the manufacturing process of the described self-lighting one way perspective paste of one of claim 1 to 5, press following step manufacturing in regular turn:
Step 1 overlays on the autoluminescence film on the paper substrate surface of silica-gel coating by calendering technology;
Step 2, to the film processing of punching, make film form fine and close reticulated film structure after, separate standby with raw base paper;
Step 3 is being bonded into self-lighting one way perspective paste with reticulated film behind the adhesive coating on the transfer paper substrate.
7. self-lighting one way perspective paste according to claim 1 is characterized in that: described advertisement layout passes through the spray-drawing process air brushing on the single-way perspective membrane surface.
8. self-lighting one way perspective paste according to claim 6 is characterized in that: described spray-drawing process is a kind of in temperature-sensitive air brushing, hot transfer printing air brushing, static air brushing, ink-jet air brushing and the laser air brushing.
CNA2009100455222A 2009-01-19 2009-01-19 Self-lighting one way perspective paste and manufacturing process thereof Pending CN101488305A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2009100455222A CN101488305A (en) 2009-01-19 2009-01-19 Self-lighting one way perspective paste and manufacturing process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2009100455222A CN101488305A (en) 2009-01-19 2009-01-19 Self-lighting one way perspective paste and manufacturing process thereof

Publications (1)

Publication Number Publication Date
CN101488305A true CN101488305A (en) 2009-07-22

Family

ID=40891178

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2009100455222A Pending CN101488305A (en) 2009-01-19 2009-01-19 Self-lighting one way perspective paste and manufacturing process thereof

Country Status (1)

Country Link
CN (1) CN101488305A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102941691A (en) * 2010-08-16 2013-02-27 文明华 See-through film and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102941691A (en) * 2010-08-16 2013-02-27 文明华 See-through film and manufacturing method thereof
CN102941691B (en) * 2010-08-16 2014-09-10 文明华 See-through film and manufacturing method thereof

Similar Documents

Publication Publication Date Title
CN106393833B (en) Electrostatic attracting sheet and the display object for having used it
CN111491953B (en) PVC compositions, films, laminates, and related methods
AU748330B2 (en) Image receptor medium
RU2571140C2 (en) Non-pvc film and non-pvc multi-layer film
CN101509606B (en) Self-luminescence advertisement pad pasting
CN102245382A (en) Biodegradable material for an advertisement, and method for preparing same
CN101475803A (en) Self-luminescent material and preparation thereof
CN101488305A (en) Self-lighting one way perspective paste and manufacturing process thereof
CN210429059U (en) Waterproof luminous label
CN205223082U (en) Polyethylene adhesive tape
WO2000013910A1 (en) Recording sheet having phosphorescence and sign
CN202480581U (en) Medium-free inkjet printing material
CN105001810A (en) Hot melt adhesive for digital inkjet printing material and preparation method for hot melt adhesive
KR20090111146A (en) A pressure-sensitive adhesive sheet and a preparation method thereof
CN210617641U (en) Illumination-resistant and aging-resistant UV transfer printing film
CN207954913U (en) A kind of advertising painting material structure
CN203945833U (en) A kind of can be by the band coating air brushing film of magnetic
CN102152684A (en) Full-transparent ink-jet printing film for improving absorbency on pigment ink
CN202669101U (en) Anti-graffiti reflective film
JP4543220B2 (en) Marking film substrate and method for producing the same
CN204605246U (en) A kind of PVC high definition printing film
EP3996913A1 (en) Illuminable lamination interlayer and glazing
JP5255866B2 (en) Vinyl chloride resin sheet for desk mats or table mats
CN204870135U (en) Digital air brushing printing consumables
JP2008000973A (en) Decorative material for building material and flooring material

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Open date: 20090722