CN101484504B - Cosmetic compositions utilizing acrylate cross linked silicone copolymer networks - Google Patents

Abstract

The cosmetic compositions of the present invention comprise silicone copolymers, terpolymers and higher order polymers that comprise 1) polyether substituted structural units and 2) epoxy or oxirane structural units that are reacted with acrylate species to produce cross linked silicones comprising polyether substituted structural units and acrylate cross links. The cross linked polymers of the present invention are self-emulsifying and may be either water swellable or oil swellable.

Description

Utilize the make-up composition of acrylate cross linked silicone copolymer networks

The cross reference of related application

The application requires the rights and interests of the U.S. Provisional Application sequence number 60/746,079 of submission on May 1st, 2006.

Invention field

The present invention relates to comprise the purposes of compsn, the said method for compositions of preparation and the said compsn of crosslinked silicone copolymer networks, wherein said crosslinked segment (cross link) is origoester acrylate or polymkeric substance.

Background of invention

Personal care industries needs the multiple performance product based on the mixture of various ingredients can be provided, and various components have for the important or required performance of final preparation.A kind of required characteristic be for can providing the silkiness initial perception of lower molecular weight organosilicon (for example octamethylcyclotetrasiloxane or decamethylcyclopentaandoxane) in the comfortable preparation, but keeps high simultaneously but (shear-thinnable) viscosity of shear-thinning.Though these lower molecular weight organosilicons provide required sensorial characteristics, they are LV, highly flowable liquid.Therefore, be not easy to remain in the preparation, when being used for specifically using, preferring separating and from given container, flow out or uncontrollably flow through skin.In addition, hope when obtaining the silkiness initial perception, slick low residue sensation is provided after dry (dry-down).The polymerization organosilicon gel that discovery prepares in the volatility organosilicon passes to preparation with the organosilyl required initial perception of volatile low viscosity, HV is provided simultaneously and at dried slick silk-like feeling, for example referring to USP 5; 760,116,5,493; 041 and 4,987,169.

Usually through the hydrosilylation reactions preparation, the two forms crosslinked siloxane polymer to this polymerization organosilicon gel need to utilize SiH functional group and terminal olefin group.Therefore, have only the siloxane structure of the siloxane groups of the vinyl functional that can combine silyl hydride groups and choose wantonly to can be used for preparing these materials.In addition, the method for the crosslinked siloxane polymer of this generation has limited and can be attached to polymer architecture in the preparation of complicacy, to produce the scope of the required organic radical functional group of other feature performance benefit.Therefore, attempt organic radical functional group is included in the crosslinked siloxane polymer that contains the unsaturated organic group compatible with hydrosilylation reactions.

USP 6,313,249; 6,399,081; With 5,039,761 disclose the method for the acrylic copolymer of the organosilicon inarch that a kind of preparation is made up of acrylic acid or the like skeleton and ZGK 5 side chain.USP 6,207,782 disclose the acrylate/methacrylate and the emulsion that comprises these polymkeric substance of the radical polymerization of polyethers-end capped ZGK 5.USP 4,293,678 disclose one type of material that is called the epoxy organosilicon of acroleic acid esterification, and it comprises polyethers-substituted organosilicon by epoxy organosilicon and acrylic acid or the like preparation.

The organosilicon network polymer is widely used as the component of various personal care compsns.But these organosilicon network polymers of great majority are incompatible with polarizable medium (for example water).Therefore, need with the polarity of wide region or nonpolar medium be compatible and the close moisture organosilicon network of performance benefit (for example emulsification, thickening, bonding, gloss, durable and close moisture active substance antiseized) can be provided in personal care.

Summary of the invention

The invention provides method that a kind of preparation comprises the make-up composition of silicon composition, this makeup silicon composition and uses thereof, said compsn comprise following a), b) and reaction product c):

A) M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gWith

B) propenoate of stoichiometry or hyperstoichiometry amount, wherein

M＝R ¹R ²R ³SiO _1/2；

M ^H＝R ⁴R ⁵HSiO _1/2；

M ^PE＝R ⁴R ⁵(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _1/2；

M ^E＝R ⁴R ⁵(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2；

D ^PE＝R ⁸(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2；

DE＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2；

T＝R ¹⁹SiO _3/2；

T ^H＝HSiO _3/2；

T ^PE＝(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _3/2；

T ^E=(R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _3/2With

Q＝SiO _4/2；

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from monovalence alkyl independently of one another with 1-60 carbon atom;

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom;

R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom; R ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, and Q _sAnd have R ¹³Carbon form key, wherein R ¹⁶And R ¹⁸Cis or trans each other;

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number;

Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number;

Subscript c is a positive number, and numerical value is about 5-about 1,000;

Subscript d is a positive number, and numerical value is about 3-about 400;

Subscript e is 0 or positive number, and numerical value is 0-about 50;

Subscript f is 0 or positive number, and numerical value is 0-about 30;

Subscript g is 0 or positive number, and numerical value is 0-about 20;

Subscript h is 0 or positive number, and numerical value is that 0-is about 2, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript i is 0 or positive number, and numerical value is that 0-is about 200, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript j is 0 or positive number, and numerical value is that 0-is about 30, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript k is 0 or positive number, and numerical value is that 0-is about 2, obey following restricted condition: subscript k, 1 and the summation of m be positive number;

Subscript 1 is 0 or positive number, and numerical value is that 0-is about 200, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript m is 0 or positive number, and numerical value is that 0-is about 30, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript n is 0 or 1;

Subscript o is 0 or 1;

Subscript p is 0 or positive number, and numerical value is that 0-is about 100, obeys following restricted condition: (p+q+r)>0;

Subscript q is 0 or positive number, and numerical value is that 0-is about 100, obeys following restricted condition: (p+q+r)>0;

Subscript r is 0 or positive number, and numerical value is that 0-is about 100, obeys following restricted condition: (p+q+r)>0;

Subscript s is 0 or 1;

Subscript t is 0 or 1; With

C) radical initiator.

Detailed Description Of The Invention

In this please under the used stoichiometry target round values be meant molecule thing class, the target non integer value is meant the mixture of the molecule thing class on the molar mass average basis, on the number averaged basis or the x basis under the stoichiometry.Phrase substoichiometric and hyperstoichiometry refer to the relation between the reactant.Substoichiometric refers to that the amount of the required reactant of complete stoichiometric reaction takes place less than matrix part and this reactant the amount of reactant.Hyperstoichiometry refers to that the amount of the required reactant of complete stoichiometric reaction takes place greater than matrix part and this reactant the amount of reactant.Used " hyperstoichiometry " of the application can be equal to excessive excessive of stoichiometry excessive (that is stoichiometric integral multiple) or nonstoichiometry in some cases.

The invention provides the method for preparing the present composition, the various compsns that comprise the present composition and useful compsn.

Method of the present invention provides silyl hydride multipolymer and substoichiometric alkene polyethers under the hydrosilylation condition, to react, and obtains the substituted hydrogenate terpolymer of polyethers.

Therefore, in a kind of embodiment, the inventive method that produces the present composition is as follows, under the hydrosilylation condition, silyl hydride with substoichiometric (be that molar weight is less than the molar weight for subscript b and d summation; This amount is the summation of stoichiometry subscript h and i) the alkene polyether reactant,

Silyl hydride has formula:

M _aM ^H _bD _cD ^H _d，

Wherein

M＝R ¹R ²R ³SiO _1/2；

M ^H＝R ⁴R ⁵HSiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from the monovalence alkyl with 1-60 carbon atom independently of one another, wherein subscript a, b, c and d are 0 or positive number;

The alkene polyethers has formula:

CH ₂＝CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²

Wherein

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom, wherein subscript n can be 0 or 1; R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-, wherein subscript o can be 0 or 1; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom, and subscript p, q and r are 0 or positive number.When polyethers by mixed oxidization thiazolinyl group (being oxygen ethene, oxypropylene and oxygen butylene) when forming, this unit can be block or random distribution.Resulting terpolymer has the structural formula consistent with following formula:

M _aM ^H _b-hM ^PE _eD _cD ^H _d-iD ^PE _f

Wherein subscript PE representes that polyethers replaces, wherein

M ^PE=R ⁴R ⁵(CH ₂CH (R ⁹) (R ¹⁰) _nO (R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²) SiO _1/2With

D ^PE＝R ⁸(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O)p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2。

This terpolymer (is a molar weight less than the subscript (b-h) and (d-i) molar weight of summation with substoichiometric under the hydrosilylation condition; This amount is stoichiometry subscript k and 1 summation) olefin epoxide with formula or oxyethane further react:

This formula is R ¹⁷R ¹⁸C=CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴, R wherein ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, wherein subscript s and t are 0 or 1 independently, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, and Q _sAnd have R ¹³Carbon form key, wherein R ¹⁶And R ¹⁸Cis or trans each other.Resulting polymkeric substance has the structural formula consistent with following formula:

M _aM ^H _b-h-kM ^PE _eM ^E _gD _cD ^H _d-i-lD ^PE _fD ^E _j，

Wherein subscript E representative ring oxide compound or oxyethane replace, wherein

ME=R ⁴R ⁵(R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _1/2With

DE＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2。

When the hydrogenate of remnants greater than 0 the time, shown in stoichiometric (b-h-k) and nonzero value (d-i-l), can further carry out hydrosilylation reactions, to produce more high-grade polymkeric substance with various olefines (comprising the alkenyl silicone resin).It should be noted that the order of described hydrosilylation reactions can be put upside down, perhaps capable of being combined, and in a reaction, accomplish.

Polymkeric substance and vinylformic acid, substituted vinylformic acid or its ester with formula further react:

M _aM ^H _b-h-kM ^PE _eM ^E _gD _cD ^H _d-i-lD ^PE _fD ^E _j

Obtain the propenoate of epoxide or oxyethane functional group, the acrylic ester polymer with formula be provided:

M _aM ^H _b-h-kM ^PE _eM ^A _gD _cD ^H _d-i-lD ^PE _fD ^A _j

Wherein subscript A shows and is expressed as epoxy substituting group (R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) and esters of acrylic acid between the substituting group of reaction product.Excessive esters of acrylic acid adds with radical initiator, produces the crosslinked segment of polyacrylic ester.The polysiloxane copolymer of the polyether grafting of acroleic acid esterification can be under the radical polymerization condition and one or more comonomer polymerization or copolymerization, can in all kinds of SOLVENTS, carry out polymerization, uses known catalyzer in polymeric acrylate field and temperature.Suitable solvent includes but not limited to siloxanes liquid, water, alcohol, ester, hydrocarbon liquid or organic oil.The instance of free redical induced catalysis agent (hereinafter being called radical initiator) comprising: inorganic peroxide, for example hydrogen peroxide, ammonium persulphate, Potassium Persulphate etc.; The organic peroxy catalyzer; For example peroxo-di-isopropyl, peroxo-dilauryl, di-t-butyl peroxide, dicumyl peroxide of dialkyl peroxide for example; Alkyl hydroperoxide is t-butyl hydroperoxide (t-butyl hydrogen peroxide), hydrogen peroxide tert-pentyl, hydrogen peroxide cumyl for example; Diacyl peroxide is for example benzoyl hydroperoxide ethyl ester, pavalate superoxide of acetyl peroxide, lauroyl superoxide, Lucidol, peroxy esters for example; Azo cpd is 2-azo two (isopropyl cyanide), 1-azo two (1-cyclohexanenitrile) (1-azobis (1-cyclohexanecarbonitrile) etc., and the catalyzer of other generation radicals for example.

Therefore, in one embodiment, the present composition is to have the polymkeric substance of formula and the reaction product between the esters of acrylic acid:

M _aM ^H _b-h-kM ^PE _eM ^A _gD _cD ^H _d-i-lD ^PE _fD ^A _j。

More generally; Any organosilicon polymer that has hydrogenate can carry out this reaction process; To produce substituted, the substituted organosilicon polymer of polyethers of epoxy; Can react with vinylformic acid, substituted vinylformic acid or derivatives thereof subsequently, to produce the substituted organosilicon polymer network of acrylate cross linked polyethers.Polysiloxane copolymer with substituted polyether grafting of epoxy of formula:

M _aM ^H _b·h-kM ^PE _eM ^E _gD _cD ^H _d-i-lD ^PE _fD ^E _j

With propenoate (being generally acrylic or methacrylic acid) reaction, form the polysiloxane copolymer of the polyether grafting of acroleic acid esterification.Can under on-catalytic, carry out with the oxirane ring ring-opening reaction of propenoate, but also can use catalyzer.The instance of useful catalysts comprises 1; 4-diazabicyclo (2.2.2) octane, aluminum chloride, four (Virahol) titanium, tosic acid, methylsulfonic acid, trifluoroacetic acid, morpholine Tributylamine, benzoyl-n n dimetylaniline, tetraalkyl ureas compound for example 1; 1 ', 3,3 '-tetramethyl-urea.

More generally, the inventive method that produces the present composition comprise have formula silane under the hydrosilylation condition with substoichiometric alkene polyether reactant:

M _aM ^H _bD _cD ^H _dT _eT ^H _fQ _g

Wherein use the summation of (h+i+j) to represent the substoichiometric molar weight, obtain having the substituted polymkeric substance of polyethers of the structural formula consistent with following formula:

M _aM ^H _b-hM ^PE _hD _cD ^H _d-iD ^PE _iT _eT ^H _f-jT ^PE _jQ _g。

Subsequently, the substituted polymkeric substance of polyethers that has a formula under the hydrosilylation condition with substoichiometric olefin epoxide or reacting ethylene oxide:

M _aM ^H _b-hM ^PE _hD _cD ^H _d-iD ^PE _iT _eT ^H _f-jT ^PE _jQ _g

Wherein use the summation of (k+l+m) to represent the substoichiometric molar weight, obtain having the epoxy and the substituted polymkeric substance of polyethers of the structural formula consistent with following formula:

M _aM ^H _b-h-kM ^PE _hM ^E _kD _cD ^H _d-i-lD ^PE _iD ^E _lT _eT ^H _f-j-mT ^PE _jT ^E _mQ _g。

With M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gProduce the corresponding propenoate of epoxy or ethylene oxide group, the organosilicon polymer that obtains having formula with the reaction of the compound of acrylate-functional:

M _aM ^H _b-h-kM ^PE _hM ^A _kD _cD ^H _d-i-lD ^PE _iD ^A _lT _eT ^H _f-j-mT ^PE _jT ^A _mQ _g，

Wherein subscript A shows and is expressed as epoxy substituting group (R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) and esters of acrylic acid between the substituting group of reaction product.Polysiloxane copolymer with substituted polyether grafting of epoxy of formula:

M _aM ^H _b-h-kM ^PE _hM ^E _kD _cD ^H _d-i-lD ^PE _iD ^E _lT _eT ^H _f-j-mT ^PE _jT ^E _mQ _g

With propenoate (being generally acrylic or methacrylic acid) reaction, with the polysiloxane copolymer of the polyether grafting that forms acroleic acid esterification.Can under on-catalytic, carry out with the oxirane ring ring-opening reaction of propenoate, but also can use catalyzer.The instance of useful catalysts comprises 1; 4-diazabicyclo (2.2.2) octane, aluminum chloride, four (Virahol) titanium, tosic acid, methylsulfonic acid, trifluoroacetic acid, morpholine Tributylamine, benzoyl-n n dimetylaniline, tetraalkyl ureas compound for example 1; 1 ', 3,3 '-tetramethyl-urea.

Polymkeric substance M _aM ^H _B-h-kM ^PE _hM ^A _kD _cD ^H _D-i-lD ^PE _iD ^A _lT _eT ^H _F-j-mT ^PE _jT ^A _mQ _gCan be subsequently react under the acrylate component polymeric condition being suitable for the esters of acrylic acid of additional quantity or its mixture, thereby at precursor M _aM ^H _B-h-kM ^PE _hM ^A _kD _cD ^H _D-i-lD ^PE _iD ^A _lT _eT ^H _F-j-mT ^PE _jT ^A _mQ _gProduce origoester acrylate or crosslinked polymer between the polymkeric substance.Utilize the propenoate of stoichiometry or hyperstoichiometry amount can merge this two step.

The present composition comprises:

M _aM ^H _b-h-kM ^PE _hM ^E _kD _cD ^H _d-i-lD ^PE _iD ^E _lT _eT ^H _f-j-mT ^PE _jT ^E _mQ _g；

M _aM ^H _b-h-kM ^PE _hM ^A _kD _cD ^H _d-i-lD ^PE _iD ^A _lT _eT ^H _f-j-mT ^PE _jT ^A _mQ _g；

And the reaction product of these compounds and acrylate component.

The used word " propenoate " of the application is the collective noun of following chemical substance: vinylformic acid and methylacrylic acid or its ester derivative; For example methyl esters, ethyl ester, butyl ester, pentyl ester, 2-ethylhexyl, cyclohexyl, vinyl acetate, allyl ester, hydroxyl ethyl ester, perfluor ethyl ester, isobornyl thiocyanoacetate, phenoxy ethyl, Tetraglycol 99 ester, diacrylate, trihydroxymethylpropanyl ester, polyoxyalkylene derivative, organically-modified polyorganosiloxane ramification are (for example; At USP 6; 207; Be used as the close moisture ZGK 5 of the acroleic acid esterification of emulsion precursor in 782), anionic acrylic ester/methacrylic ester, for example the propenoate of sulfuric ester, sulphonate or phosphate functionalization or its mixture and with the required any catalyzer of epoxy or ethylene oxide group reaction.Can use the various combinations of single propenoate or propenoate and methacrylic ester.

Among the application under the used stoichiometry target round values be meant molecule thing class, the target non integer value is meant the mixture of the molecule thing class on the molar mass average basis, on the number averaged basis or the x basis under the stoichiometry.Under the situation of the mixture of The compounds of this invention, should recognize easily that with the pure compound contrast, target subscript MV can be integer or non-integer under the stoichiometry of mixture.

The invention provides a kind of method for preparing silicon composition, this silicon composition and uses thereof, said compsn comprise following a), b) and reaction product c):

A) M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gWith

B) propenoate of stoichiometry or hyperstoichiometry amount, wherein

M＝R ¹R ²R ³SiO _1/2；

MH＝R ⁴R ⁵HSiO _1/2；

MPE＝R ⁴R ⁵(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _1/2；

ME＝R ⁴R ⁵(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2；

D ^PE＝R ⁸(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2；

DE＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2；

T＝R ¹⁹SiO _3/2；

T ^H＝HSiO _3/2；

T ^PE＝(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _3/2；

T ^E=(R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _3/2With

Q＝SiO _4/2；

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from monovalence alkyl independently of one another with 1-60 carbon atom;

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom;

R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom; R ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, and Q _sAnd have R ¹³Carbon form key, wherein R ¹⁶And R ¹⁸Cis or trans each other;

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number;

Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number;

Subscript c is a positive number, and numerical value is about 5-about 1,000;

Subscript d is a positive number, and numerical value is about 3-about 400;

Subscript e is 0 or positive number, and numerical value is 0-about 50;

Subscript f is 0 or positive number, and numerical value is 0-about 30;

Subscript g is 0 or positive number, and numerical value is 0-about 20;

Subscript h is 0 or positive number, and numerical value is that 0-is about 2, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript i is 0 or positive number, and numerical value is that 0-is about 200, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript j is 0 or positive number, and numerical value is that 0-is about 30, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript k is 0 or positive number, and numerical value is that 0-is about 2, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript l is 0 or positive number, and numerical value is that 0-is about 200, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript m is 0 or positive number, and numerical value is that 0-is about 30, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript n is 0 or 1;

Subscript o is 0 or 1;

Subscript p is 0 or positive number, and numerical value is that 0-is about 100, obeys following restricted condition: (p+q+r)>0;

Subscript q is 0 or positive number, and numerical value is that 0-is about 100, obeys following restricted condition: (p+q+r)>0;

Subscript r is 0 or positive number, and numerical value is that 0-is about 100, obeys following restricted condition: (p+q+r)>0;

Subscript s is 0 or 1;

Subscript t is 0 or 1; With

C) radical initiator.

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number.Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number.In all cases, summation a+b >=2, promptly according to the T that exists and the number of Q group, the summation of a and b is necessary for 2 or bigger.

M _aM ^H _bD _cD ^H _dT _eT ^H _fQ _gBe raw material, and

With acrylate reactions before, M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PB _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gBe polymer materials, crosslinked subsequently.

The subscript c that relates to the unitary amount of initial D is a positive number, and numerical value is about 1,000 for about 5-, and it is about 700 to be specially about 10-, more specifically is that about 30-is about 500, is specially about 50-about 300 most.

Relate to initial D ^HThe subscript d of unitary amount is a positive number, and numerical value is about 400 for about 3-, and it is about 300 to be specially about 3-, more specifically is that about 3-is about 175, is specially about 3-about 40 most.

The subscript e that relates to the unitary amount of initial T is 0 or positive number, and numerical value is that 0-is about 50, and it is about 35 to be specially about 0-, and is more specifically about 20 for about 0-, is specially about 0-about 10 most.

Relate to initial T ^HThe subscript f of unitary amount is 0 or positive number, and numerical value is that 0-is about 30, and it is about 25 to be specially about 0-, and is more specifically about 17 for about 0-, is specially about 0-about 10 most.

The subscript g that relates to the unitary amount of initial Q is 0 or positive number, and numerical value is that 0-is about 20, and it is about 17 to be specially about 0-, and is more specifically about 13 for about 0-, is specially about 0-about 10 most.

Relate to M ^PEThe subscript h of unitary amount is 0 or positive number, and numerical value is that 0-is about 2, and it is about 1 to be specially about 0-most, and the summation of obeying following restricted condition: subscript h, i and j is a positive number, i.e. (h+i+j)>=0, and (b+d+f)>=(h+i+j)+(k+l+m).

Relate to D ^PEThe subscript i of unitary amount is 0 or positive number, and numerical value is that 0-is about 200, is specially about 0-about 140; More specifically about 80 for about 0-, it is about 30 to be specially about 1-most, and the summation of obeying following restricted condition: subscript h, i and j is a positive number; I.e. (h+i+j)>=0, and (b+d+f)>=(h+i+j)+(k+l+m).

Relate to T ^PEThe subscript j of unitary amount is 0 or positive number, and numerical value is that 0-is about 30, is specially about 0-about 24; More specifically about 18 for about 0-, it is about 10 to be specially about 0-most, and the summation of obeying following restricted condition: subscript h, i and j is a positive number; I.e. (h+i+j)>=0, and (b+d+f)>=(h+i+j)+(k+l+m).

Relate to M ^EThe subscript k of unitary amount is 0 or positive number, and numerical value is that 0-is about 2, and it is about 1 to be specially about 0-most, and the summation of obeying following restricted condition: subscript k, l and m is a positive number, i.e. (k+l+m)>=0, and (b+d+f)>=(h+i+j)+(k+l+m).

Relate to D ^EThe subscript l of unitary amount is 0 or positive number, and numerical value is that 0-is about 200, is specially about 0-about 140; More specifically about 90 for about 0-, it is about 20 to be specially about 2-most, and the summation of obeying following restricted condition: subscript k, l and m is a positive number; I.e. (k+l+m)>=0, and (b+d+f)>=(h+i+j)+(k+l+m).

Relate to T ^EThe subscript m of unitary amount is 0 or positive number, and numerical value is that 0-is about 30, is specially about 0-about 23; More specifically about 16 for about 0-, it is about 10 to be specially about 0-most, and the summation of obeying following restricted condition: subscript k, l and m is a positive number; I.e. (k+l+m)>=0, and (b+d+f)>=(h+i+j)+(k+l+m).

For alkene polyethers with formula:

CH ₂＝CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²

Subscript n is 0 or 1.

Subscript o is 0 or 1.

Subscript p is 0 or positive number, and numerical value is that 0-is about 100, and it is about 85 to be specially about 0-, and is more specifically about 55 for about 0-, and it is about 40 to be specially about 0-most, obeys following restricted condition: (p+q+r)>0.

Subscript q is 0 or positive number, and numerical value is that 0-is about 100, and it is about 80 to be specially about 0-, and is more specifically about 60 for about 0-, and it is about 40 to be specially about 0-most, obeys following restricted condition: (p+q+r)>0.

Subscript r is 0 or positive number, and numerical value is that 0-is about 100, and it is about 75 to be specially about 0-, and is more specifically about 50 for about 0-, and it is about 40 to be specially about 0-most, obeys following restricted condition: (p+q+r)>0.

According to D, D in final crosslinked copolymers group of networks compound ^AAnd D ^PEThe relative quantity of group, crosslinked compsn can be by following material swellings: 1) hydroxylic solvent, the for example moisture or non-water hydroxylic solvent of water, alcohol or the carboxylic acid solvent mixture that is component; Or 2) the non-close water-containing solvent of non-water can be the organosilicon or the organic solvent that hereinafter define; Or contain the mixture of these solvents.With regard to the purpose of this discussion, only the network multipolymer of these two types of crosslinked swellables is called " water swellable " or " but oil swell ", (but term oil swell comprise all swelling solvents that term " water swellable " does not comprise).Usually, when having following the relation, crosslinked network multipolymer has water-swellable more easily:

1) for the number of the D group that exists: the number of about 5 < D groups≤about 90;

2) for the D that exists ^PEThe number of group: D ^PE>About 5; With

3) acrylate cross linked formation is at least about 5% weight or the crosslinked polymer network of more non-swollen.

On the contrary, when having following the relation, crosslinked network multipolymer has oil swell property more easily:

1) for the number of the D group that exists: the number of about 90≤D group;

2) for the D that exists ^PEThe number of group: about 1<d ^PEThe number of group≤about 7; With

3) no more than about 10% weight of acrylate cross linked formation or the crosslinked polymer network of non-swollen still less.

What should stress is; Can change and interrelated for target aforementioned range under water-swellable or illustrational structural parameter of oil swell property and the stoichiometry; And each parametric variable can exceed (being greater than or less than) said scope; And, still can observe the swelling of particular type owing to change in another structure relevant or the homeostasis (homeostatic) in the stoichiometry parameter with concrete polymkeric substance.

Because acrylate cross linked and polyethers substituting group all can form hydrogen bond with water and other hydroxylic solvents, improve the content of the two, other all composition variables keep constant, often increase the water-swellable of resulting crosslinked network polymer.Owing to can restricted hardly mode change the composition parameter of crosslinked network multipolymer of the present invention; Therefore; But some compsn not only had been water swellable but also for oil swell; But other are merely water swellable or oil swell, and some compsn can not be by any solvent-swollen that this paper discussed.The degree of swelling of the network in the available fluid of crosslinked amount that exists in the crosslinked network characterizes.In another embodiment, the crosslinked structure of network makes 1.01-5000 that network is swelling to its initial volume from its initial volume doubly effectively, more preferably 2-1000 doubly, even more preferably 5-500 swollen volume doubly.For example can confirm the initial volume of network through extraction or all fluid components that evaporate silicon composition of the present invention with the residue initial volume, that is, and at the volume that does not have the polyether siloxane copolymer network under the fluid.

The present composition is a self-emulsifying.

Can under high shearing, further process said silicon composition low, to regulate the viscosity and the sensory feel of compsn.For example can realize this point through compsn being stood medium paramount shearing force.For example can use sonolator, Gaulin homogenizer or microcosmic fluidizer to apply high-shear.Before shearing, can choose wantonly one or more fluids are added in the silicon composition.

A kind of preferred embodiment in, silicon composition of the present invention is a solid, has butyraceous denseness usually, wherein copolymer networks serves as the instrument with fluid gelization, to give fluid with solid property reversiblely.When static, silicon composition has the performance of solid gel material.Silicon composition of the present invention has high stability and dehydration tolerance shrinkability; Promptly; Said compositions table reveals seldom or does not make fluid effusive tendency from compsn, gives comprising personal care compsn high stability and the dehydration tolerance shrinkability of silicon composition as component.High stability and dehydration tolerance shrinkability prolong the aging of this silicon composition and personal care compsn.But, stand shearing force through making silicon composition, for example, through friction composition between finger, fluid can discharge from network, and the improved sensory feel characteristic of the fluid components of organosilicon material is provided.

Water (or water Equivalent, for example non-water hydroxylic solvent), siloxanes, straight chain or ring-type or lipophilic fluid (oil swell agent, but oil swell) can be used as swelling agent.Be suitable for as the lipophilic fluid of the fluid components of the present composition at room temperature or near room temperature (for example about 20 ℃-Yue 50 ℃) and about 1 normal atmosphere being the mixture of those compounds of liquid state or two kinds or more compounds down; Comprise; For example, siloxanes liquid, hydrocarbon fluid, ester, alcohol, Fatty Alcohol(C12-C14 and C12-C18), two pure and mild organic oils.In preferred embodiment, the viscosity of the fluid components of the present composition under 25 ℃ is less than about 1, and 000cSt preferably less than about 500cSt, is more preferably less than about 250cSt, most preferably less than 100cSt.

A kind of preferred embodiment in, polyacrylic ester silicone copolymers network is for being insoluble to various fluid components, but can be by the crosslinked network of fluid swollen.The degree of swelling that is present in network in the available fluid of crosslinked amount in the crosslinked network characterizes.Another preferred embodiment in, the crosslinked structure of network make effectively network by water from its initial volume swelling most its initial volume 1.01-5000 doubly, more preferably 2-1000 doubly, even more preferably 5-500 swollen volume doubly.For example can confirm the initial volume of network through extraction or all fluid components that evaporate silicon composition of the present invention with the residue initial volume, that is, and at the volume that does not have the polyacrylic ester silicone copolymers network under the fluid.Another preferred embodiment in, the crosslinked structure of network make effectively network by lipophilic fluid from its initial volume swelling most its initial volume 1.01-5000 doubly, more preferably 2-1000 doubly, even more preferably 5-500 swollen volume doubly.For example can confirm the initial volume of network through extraction or all fluid components that evaporate silicon composition of the present invention with the residue initial volume, that is, and at the volume that does not have the polyacrylic ester silicone copolymers network under the fluid.Another preferred embodiment in; The crosslinked structure of network make effectively network by low-molecular-weight siloxane liquid (for example decamethylcyclopentaandoxane) from its initial volume swelling most its initial volume 1.01-5000 doubly; More preferably 2-1000 doubly, even more preferably 5-500 swollen volume doubly.For example can confirm the initial volume of network through extraction or all fluid components that evaporate silicon composition of the present invention with the residue initial volume, that is, and at the volume that does not have the polyacrylic ester silicone copolymers network under the fluid.

In one embodiment, fluid components of the present invention comprises tenderizer (emollient) compound.Suitable tenderizer compound comprises any fluid that the tenderizer performance is provided, that is, when being applied to skin, be prone to be retained on the skin surface or in the stratum corneum of skin, with as lubricant, reduce and peel off and improve skin appearance.The tenderizer compound is usually known, comprises, for example, hydrocarbon, for example Permethyl 99A., NSC 109495 and Parleam; Organic wax, for example Jojoba haze tallow; Siloxanes liquid, for example D5, YSR 3286 and two phenyl propyl YSR 3286; Ester, for example PIVALIC ACID CRUDE (25) monooctyl ester dodecyl ester and oleic acid oil base ester; And lipid acid and alcohol, for example oleyl alcohol and different tetradecanol.

In one embodiment, fluid components of the present invention comprises siloxanes liquid, more preferably has the siloxanes liquid of tenderizer performance, preferred low-molecular-weight siloxane liquid or low-molecular-weight siloxane compound.Suitable siloxanes liquid comprises, for example, and formula D _rCyclic organic, wherein D, R ⁸And R ⁹Like preceding definition, preferred R wherein ⁸And R ⁹Be selected from the monovalence alkyl of a monovalence 1-6 carbon atom, more preferably methyl, and r is an integer, wherein 3≤r≤12, for example hexamethyl cyclotrisiloxane (" D ₃"), octamethylcyclotetrasiloxane (" D ₄"), decamethylcyclopentaandoxane (" D ₅") and ten diformazan basic rings, six siloxanes (" D ₆") and straight or branched organopolysiloxane with formula:

M′D′ _uT′ _vM′

Wherein:

M ' is R ¹⁹ ₃SiO _1/2

D ' is R ²⁰ ₂SiO _2/2

T ' is R ²¹SiO _3/2

R ¹⁹, R ²⁰And R ²¹Independent of separately containing alkyl, the aryl or aralkyl of 1-60 carbon atom;

U and v are integer 0-300 independently separately, are preferably 0-100, and more preferably 0-50 most preferably is 0-20.

In preferred embodiment; Silicon composition of the present invention comprises the silicon composition 0.1-99pbw of per 100 weight parts (" pbw "); More preferably 0.5pbw-30pbw; Also more preferably polyacrylic ester silicone copolymers network and the 1pbw-99.9pbw of 1-15pbw, more preferably 70pbw-99.5pbw, the also more preferably fluid of 85pbw-99pbw.

The organosilicon component in the emulsion is used or be used as to the form that polyacrylic ester siloxane copolymer network compositions of the present invention can prepare.As known usually, emulsion comprises at least 2 immiscible phases, and one of them is an external phase, and another is a discontinuous phase.Other emulsions can be the liquid or solid with different viscosity.In addition, the granularity of emulsion can be microemulsion, when enough hour of granularity, can be transparent.In addition, also can prepare the emulsion of emulsion, be commonly referred to multiple emulsion.These emulsions can be:

1) aqueous emulsion, wherein discontinuous phase comprises water, and external phase comprises polyacrylic ester silicone copolymers network of the present invention;

2) aqueous emulsion, wherein discontinuous phase comprises polyacrylic ester silicone copolymers network of the present invention, and external phase comprises water;

3) nonaqueous emulsion, wherein discontinuous phase comprises non-water hydroxylic solvent, and external phase comprises polyacrylic ester silicone copolymers network of the present invention; With

4) nonaqueous emulsion, wherein external phase comprises non-water hydroxyl organic solvent, and discontinuous phase comprises polyacrylic ester silicone copolymers network of the present invention.

Nonaqueous emulsion is included in USP 6,060, and the sequence number of the common pending trial of submitting on March 3rd, 546 and 1998 is the organosilicon phase described in 09/033,788 the U. S. application, and this patent is incorporated into as a reference at this especially.

The term " non-water hydroxyl organic compound " that the application is used or " non-water hydroxylic solvent " are meant that in room temperature (for example about 25 ℃) and about 1 normal atmosphere be down the organic cpds of the hydroxyl of liquid, for example alcohol, glycol, polyvalent alcohol and polymeric glycol and composition thereof.The organic hydroxylic solvent of non-water is selected from room temperature (for example about 25 ℃) and about 1 normal atmosphere is down the organic cpds of the hydroxyl of liquid, for example alcohol, glycol, polyvalent alcohol and polymeric glycol and composition thereof.Preferred non-water hydroxyl organic solvent is selected from terepthaloyl moietie, ethanol, propyl alcohol, Virahol, Ucar 35, DPG, tripropylene glycol, butyleneglycol, isobutyl glycol, methyl propanediol, glycerine, Sorbitol Powder, polyoxyethylene glycol, W 166 monoalky lether, polyoxyalkylene copolymers and composition thereof.

When obtaining desired form; No matter whether only contain the organosilicon phase, comprise the anhydrous mixture of organosilicon phase, the aqueous mixture that comprises the organosilicon phase, water-in-oil emulsion, emulsion oil-in-water; Perhaps be a kind of in two kinds of nonaqueous emulsions or its variant, resulting material is generally has the HV breast frost that good feel characteristic and highly volatile silicones absorb.Can be blended into the preparation that is used for hair nursing, skin care, anti-sweat, sun-proof, cosmetics, additive color makeup, wormer, Metabolism Vitamins and Hormones carrier, fragrance carrier etc.

Can use polyacrylic ester silicone copolymers network of the present invention and comprise derived from the personal care application of silicon composition of the present invention; But be not limited to; Reodorant, antiperspirant, antiperspirant/deodorant, the product that shaves, skin liquid, wetting Agent for Printing Inks, toning agent, bathhouse article, cleaning product, for example shampoo of hair products, amendment, mousse, hair styling gel having, hairdressing spray, hair dye, hair dyeing product, bleached hair agent, hair-waving product, straighter, for example nail varnish, enamel remover, nail frost and dew, stratum corneum tenderizer, protective cream for example lipstick, foundation cream, face powder, eyeliner, eye shadow, kermes, cosmetics, the mascara and added other personal care formulations of organosilicon component usually of opalizer, wormer and aging products, additive color makeup for example of product of having a manicure, and the drug delivery system of topical application that is used for to be applied to the medicinal compositions of skin.

In preferred embodiment, personal care compsn of the present invention also comprises one or more personal care compositions.Suitable personal care composition comprises; For example, tenderizer, wetting Agent for Printing Inks, wetting agent, pigment comprise for example mica, tinting material, spices, biocide, sanitas, inhibitor, biocide, anti-mycotic agent, antiperspirant, keratoderma stripper (exfoliant), hormone, enzyme, medicinal compound, VITAMINs, salt, ionogen, alcohol, polyvalent alcohol, UV light absorber, plant milk extract, tensio-active agent, silicone oil, organic oil, wax, membrane-forming agent, viscosifying agent pyrogenic silica or hydrated SiO 2, particulate filler talcum, kaolin, starch, treated starch, mica, nylon, the clay clay of wilkinite and organic radical modification for example for example for example of pearl white and titanium dioxide-coated of pearly pigment.

Suitable personal care articles compsn is through getting with mode combination system known in the art, for example, through with one or more said components and said polyacrylic ester silicone copolymers network, preferably mixes with the form of silicon composition of the present invention and makes.Suitable personal care articles compsn can be the form of monophasic form or emulsion; Said emulsion form comprises that organosilicon wherein can be oil-in-water, water-in-oil and the anhydrous emulsion of discontinuous phase or external phase mutually; And multiple emulsion, for example, water-in-oil bag fat liquor and water-in-oil-in-water compositions.

In a kind of useful embodiment, Antipers pirant compositions comprises polyacrylic ester silicone copolymers network of the present invention and one or more active antiperspirant.Suitable antiperspirant comprises; For example; Active antiperspirant composition in FDA Food and Drug Administration (U.S.Food and Drug Administration) on the October 10th, 1993 of listed type I in about the monograph of directly selling to human antiperspirant medicament prodn; For example aluminum halide, hydroxyhalides (aluminum hydroxyhalide) for example Wickenol CPS 325 and with the mixture or the mixture of zirconyl oxyhalides oxygen zirconium and alkali formula halogenation oxygen zirconium; For example Wickenol CPS 325-zirconium (aluminum-zirconium chlorohydrate), aluminium zirconium glycocoll mixture (aluminumzirconium glycine complexe), for example aluminum zirconium tetrachlorohydrate glycocoll mixture (aluminumzirconium tetrachlorohydrex gly).

In another useful embodiment, skin care compsns comprises polyacrylic ester silicone copolymers network (preferred silicon composition form of the present invention) and carrier (for example silicone oil or organic oil).Said skin care compsns can be chosen wantonly and also comprise tenderizer; For example the alkyl or alkenyl ester of triglyceride level, wax ester, lipid acid or polyol ester and one or more are generally used for the known component in the skin care compsns; For example pigment, VITAMINs (for example vitamin A, vitamins C and vitamin E), opalizer or sun screening compound, for example titanium oxide, zinc oxide, 2-hydroxyl-4-methoxyl group-UVNUL MS-40, octyl methoxycinnamate, PAROSOL 1789, para-amino benzoic acid and octyldimethyl-para-amino benzoic acid.

In another useful embodiment; The additive color make-up composition, for example lipstick, cosmetics or mascara composition comprise polyacrylic ester silicone copolymers network (preferred silicon composition form of the present invention) and tinting material (for example pigment, water-soluble dye or lipid-soluble dye).

In another useful embodiment, the present composition is used for being used in combination with fragrance material.These fragrance materials can be the flavor compounds of flavor compounds, encapsulate or discharge the compound of fragrance, and they can be pure compound or for encapsulate.Compatible especially with the present composition is the organosilyl compound that contains that discharges fragrance, like USP 6,046, and 156,6,054,547,6,075,111,6,077,923,6,083,901 and 6,153, disclosed in 578; These all these patents are incorporated into as a reference at this particularly.

The purposes of compsn of the present invention is not limited to the personal care articles compsn, also can expect with the other products of compositions-treated of the present invention for example wax, lustering agent and textiles.

The present composition is used in particular for personal care application.Use present composition preparation personal care application can comprise adding and dissolve in all kinds of SOLVENTS or insoluble material.From conventional considering chemically reactive, above listed component can be before synthetic or the preparation present composition, any time adding after the process neutralization, and condition is that resultant composition is not had injurious effects.Therefore; The reaction of preparation property can be carried out in the presence of the solvent systems of solute comprising; This solute is the composition in the make-up composition, and perhaps preparation feedback can carry out in the presence of pigment or other particulate matters, produces round pigment or particulate matter polymerization and the polymer matrices sealed.

Embodiment

Except as otherwise noted, otherwise in following examples, R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be chosen as methyl.At USP 6,531, in 540 and 6,538,061 (this patent is incorporated into as a reference at this especially in full), this paper is corresponding to R ⁶And R ⁷The R substituting group on the substituted D structural unit of alkyl to be chosen as the R group be that C1 (methyl) is to C16-18 to C30+ (C30-C45).

Embodiment 1The preparation of polyacrylic ester siloxane copolymer network compositions I in water

234.9g is roughly consisted of MD ₈₅D ^* _2.2D ＂ _5.5M (D ^*: derive from Si-H and 4 vinyl cyclohexene-1, the reaction of 2-epoxide; D ＂: the polyethers CH that derives from Si-H and allyl capped ₂=CH-CH ₂-O-(EO) ₂₄(PO) ₂₇-CH ₃Hydrosilylation) organopolysiloxane mix with 29.5g vinylformic acid.Add about 20mg4-methoxyphenol and 0.8g titanium isopropylate.With mixture heating up to 90 ℃, continue about 2 hours.Subsequently the resulting material of 72g is mixed with 13.36g vinylformic acid and 341g deionized water.Nitrogen bubble is through 30 minutes, from system, to remove oxygen.Add 0.86g xitix and 2.58g hydrogen peroxide subsequently.With mixture stir about 2 hours, obtain opaque soft solid.

Embodiment 2The preparation of polyacrylic ester siloxane copolymer network compositions II in siloxanes liquid

400g is roughly consisted of MD ₁₂₅D ^H _7.5The silane liquid of M (hydride fluid) and 12.15g 4 vinyl cyclohexene-1,2-epoxide and 746.55g have formula CH ₂=CH-CH ₂-O-(EO) ₂₄(PO) ₂₇-CH ₃The polyethers of allyl capped mix.Slow down reaction with Sodium Propionate.With mixture heating up to 85 ℃, and add 0.7ml platinum catalyst solution (ethanolic soln of the Platinic chloride of 10mg/ml).Mixture was stirred 3 hours down in 90 ℃, to form epoxy functionalized polyether-polysiloxane copolymers.Use in the sodium hydrogencarbonate and resulting multipolymer, coupling vacuum stripping (vacuum strip) is filtered.Subsequently resulting epoxy functionalized polyether-polysiloxane copolymers of 52.31g and 1.24g vinylformic acid are mixed.Add about 10mg4-methoxyphenol and 0.1g titanium isopropylate.With mixture heating up to 90 ℃, continue about 2 hours.Subsequently mixture is cooled to room temperature, and adds the 53.5g D5.Nitrogen bubble was through 30 minutes.Subsequently mixture is heated with stirring to 95 ℃.Add the 0.03g Lucidol subsequently.Mixture in 95 ℃ of following stir abouts 2 hours, is obtained transparent soft solid.

Embodiment 3The preparation of polyacrylic ester siloxane copolymer network compositions III in siloxanes liquid

200g is roughly consisted of MD ₂₀₀D ^H _7.5The silane liquid of M and 5.99g 4 vinyl cyclohexene-1,2-epoxide and 84.34g have formula CH ₂=CH-CH ₂-O-(EO) ₅(PO) ₅-CH ₃The polyethers of allyl capped mix.Slow down reaction with Sodium Propionate.With mixture heating up to 85 ℃, and add 0.1ml platinum catalyst solution (ethanolic soln of the Platinic chloride of 10mg/ml).Mixture was stirred 3 hours down in 80 ℃, to form epoxy functionalized polyether-polysiloxane copolymers.Use in the sodium hydrogencarbonate and resulting multipolymer, coupling vacuum stripping is filtered.Subsequently the resulting epoxy functionalized polyether-polysiloxane copolymers of 50.00g is mixed with 1.59g vinylformic acid.Add about 10mg4-methoxyphenol and 0.1g titanium isopropylate.With mixture heating up to 90 ℃, continue about 2 hours.Subsequently mixture is cooled to room temperature, adds 4.66g vinylformic acid and 127.54g D5 subsequently.Nitrogen bubble was through 30 minutes.Mixture is heated with stirring to 100 ℃.Add the 0.07g Lucidol subsequently.Mixture in 100 ℃ of following stir abouts 2 hours, is obtained translucent soft solid.

Embodiment 4The preparation of polyacrylic ester siloxane copolymer network compositions IV in siloxanes liquid

870g is roughly consisted of MD ₁₂₅D ^H _7.5The silane liquid of M and 26.06g 4 vinyl cyclohexene-1,2-epoxide and 366.88g have formula CH ₂=CH-CH ₂-O-(EO) ₅(PO) ₅-CH ₃The polyethers of allyl capped mix.Slow down reaction with Sodium Propionate.With mixture heating up to 85 ℃, and add 0.4ml platinum catalyst solution (ethanolic soln of the Platinic chloride of 10mg/ml).Mixture was stirred 3 hours down in 80 ℃, to form epoxy functionalized polyether-polysiloxane copolymers.Use in the sodium hydrogencarbonate and resulting multipolymer, coupling vacuum stripping is filtered.Subsequently the resulting epoxy functionalized polyether-polysiloxane copolymers of 300.00g is mixed with 13.07g vinylformic acid.Add about 16mg4-methoxyphenol and 0.47g titanium isopropylate.With mixture heating up to 90 ℃, continue about 2 hours.Subsequently the resulting material of 19.50g is mixed with the 110.50g D5.Nitrogen bubble was through 30 minutes.Mixture is heated with stirring to 100 ℃.Add the 0.06g Lucidol subsequently.Mixture in 100 ℃ of following stir abouts 2 hours, is obtained transparent soft solid.

Embodiment 5The preparation of silicon gel V

10g is mixed with 10g water according to the polyacrylic ester siloxane copolymer network compositions I of embodiment 1 preparation, and being neutralized to pH is 6.5, uses Power Gen 700D mixing machine, under 7500 RPM, and homogenizing 2 minutes.The viscosity of resulting silicon gel V is 550,000 centipoises (" cPs ") (measuring after 24 hours).

Embodiment 6The preparation of silicon gel VI

10g is mixed with the 6.7g D5 according to the polyacrylic ester siloxane copolymer network compositions II of embodiment 2 preparations, use PowerGen 700D mixing machine, under 7500 RPM, homogenizing 2 minutes.The viscosity of resulting silicon gel VI is 72,000cPs (measuring after 24 hours).

Embodiment 7The preparation of silicon gel VII

10g is mixed with the 10g D5 according to the polyacrylic ester siloxane copolymer network compositions III of embodiment 3 preparations, use PowerGen 700D mixing machine, under 7500 RPM, homogenizing 2 minutes.The viscosity of resulting silicon gel VII is 59,500cPs (measuring after 24 hours).

Embodiment 8Silicon gel V is as the purposes of water viscosifying agent

According to following steps, through preparing the aqueous compsn of the thickening of embodiment 8 in the listed composition merging of the relative quantity described in the Table I down.Use PowerGen 700D mixing machine, under 7500RPM, will be according to the silicon gel V of embodiment 5 preparations with deionized water homogenizing 2 minutes.The viscosity of resulting material (measuring after 24 hours) is listed in Table I.

Table I

The aqueous compsn of thickening

Composition	Sample 8-1	Sample 8-2	Sample 8-3
				Silicon gel V	16.7	33.3	66.7
Deionized water	83.3	66.7	33.3
Viscosity (cPs)	31,500	192,500	508,500

The effective viscous water solution of silicon gel V.

Embodiment 9Silicon gel V is as the purposes of oil-in-water emulsifiers

To merge with water, D5, bernyl ester and glycerine according to the silicon gel V of embodiment 5 preparation, mixing is until evenly.In heating with freeze-melt in the test and significantly be separated, estimate the stability of these emulsions through visual observation.In the heating test, samples of latex kept 5 days in 50 ℃ baking oven.Freeze-melt at each and carry out in the test freezing-melt circulation three times.The composition and the test result of these emulsions are summarized in Table II.

Table II

The emulsion oil-in-water compsn

Emulsion oil-in-water in the Table II is in heating and freeze-melt the stability that shows excellence under the condition.

Embodiment 10The purposes of silicon gel V in the liquid foundation compsn

According to following steps, through will in Table III, merging preparation liquid foundation compsn (sample 10) and comparative example 1 by listed composition: (1) until evenly, prepares part A through various compositions are mixed; (2) subsequently part B is added in the part A, and mix, until evenly; (3) subsequently with mixture and portion C and part D combination; (4) should batch be heated to 80 ℃, and mix, until evenly.

Table III

The liquid foundation compsn

Composition	The comparative example 1	Sample 10
			Part A
Natvosol	0.40	-
			Neusilin	0.40	-
Silicon gel V	-	5.98
			Water	In right amount	In right amount
Part B
			Talcum	3.00	3.00
Portion C
			Ceteareth (cetereth)-20	5.00	5.00
Ucar 35	5.00	5.00
			Vinlub	3.00	3.00
Wickenol 111	5.00	5.00
			Tego Alkanol 16	4.00	4.00
Unimac 5680	4.00	4.00
			Part D
Titanium oxide	6.00	6.00
			Red stone	0.94	0.94

Sense organ group test (sensory paneltest) result shows, compares with comparative example 1, and silicon gel V has improved the easy property used and the aftersensation (after feel) of foundation cream, cannot not comprise stickingly, drying and silk-like feeling.

Embodiment 11The preparation of emulsion oil-in-water VIII

Will be according to the silicon gel V of embodiment 5 preparation with water and D5 merging and mix, until evenly.Significantly be separated through visual observation and estimate the stability of this emulsion.The composition of emulsion is shown in Table IV.

Table IV

Emulsion oil-in-water compsn VIII

Composition	Relative quantity
		Silicon gel V	20
Water	40
		D5	40

Emulsion oil-in-water VIII is stable.

Embodiment 12The purposes of emulsion oil-in-water VIII in composition for processing skin

According to following steps, through will in Table V, merging by listed composition preparation sample 12 and comparative example's 2 composition for processing skin: (1) is through merging all compositions and mix; Until evenly; Preparation part B, (2) merge part A and mixing with part B subsequently, until evenly.According to embodiment 11 preparation emulsion oil-in-water VIII.Organoleptic properties through sense organ group evaluating skin treatment compositions.

Table V

Composition for processing skin

The test of sense organ group shows that emulsion oil-in-water VIII reduces the viscosity aftersensation of composition for processing skin, and gives composition for processing skin refrigerant sensation.

Embodiment 13The purposes of silicon gel V in rinsing type hair conditioner composition

According to following steps, through will in Table VI, merging by listed composition preparation sample 13 and comparative example's 3 rinsing type hair conditioner composition: (1) is passed through various compositions are merged, and mixes down in 60 ℃, until evenly, prepares part A; (2) mixing portion B in independent container adds in the part A subsequently; (3) subsequently mixture is mixed, until evenly.

Table VI

Rinsing type hair conditioner composition

The test of evaluation group shows that silicon gel V has improved the flexibility of hair and reduced static and flown upward.

Tergitol?TMN-6	The branched secondary alcohol ethoxylate derives from Dow Chemicals
		SF?1632	C16-18 alkyl YSR 3286 derives from Momentive Performance Materials Inc.
Polyquaternium-10	UCARE polymkeric substance JR30M derives from Dow Chemicals

Embodiment 14The purposes of silicon gel V in the sunlight lotion compsn

According to following steps, merge the sunlight lotion compsn of preparation sample 14 through will be in Table VII listed composition: (1) through merging various compositions and mix, until evenly, and the preparation part A; (2) mixing portion B in independent container adds in the part A subsequently; (3) subsequently mixture is mixed, until evenly.

Table VII

The sunlight lotion compsn

Composition	Relative quantity
		Part A	Sample 14
Silicon gel V	13.8
		Deionized water	In right amount
Glycerine	5
		Part B
Octyl methoxycinnamate	2
		Octyl salicylate	1
Phenylformic acid C 12-15Alkyl ester	20

Prepared stable oil-in-water-type sunlight lotion.In rubbing in (rub-in) process and after rubbing in, said composition has highly required organoleptic properties.When being applied to skin, outstanding cooling effect is provided also.

Embodiment 15The purposes of silicon gel VI in liquid lip gloss compsn

According to following steps, merge preparation sample 15 and comparative example's 4 liquid lip gloss compsn through will be in Table VIII listed composition: will merge with other compositions according to the silicon gel VI of embodiment 6 preparations, and in 80 ℃ of mixing down, until evenly.After being applied to the liquid colour preparation on the skin, the two estimates gloss with using glossmeter through vision.Use long-time abrasion (long-wear) performance that the gamut of skin surface is estimated these samples through measuring preparation.Use tintometer (colormeter) to come quantitatively this effect.

Table VIII

Liquid lip gloss compsn

Composition *	The comparative example 4	Sample 15
			Silicon gel VI	-	10
SE?30	10	10
			SF?1642	2	2
SF?1528	2.6	2.6
			Permethyl 99A.	In right amount	In right amount
Red pigment	29	29

TiO 2

2.9

2.9

The two measuring result of vision and glossmeter shows that all silicon gel VI has improved the gloss of liquid lip gloss preparation.The tintometer test shows, silicon gel VI has also improved colour intensity and has reduced gamut.

SE30 YSR 3286 natural gum derives from Momentive Performance Materials

Inc.

SF1642 C30-45 alkyl YSR 3286 derives from Momentive Performance

Materials?Inc.

The SF1528 D5 (with) the PEG/PPG-20/15 YSR 3286, derive from

Momentive?Performance?Materials?Inc.

The red 7 color lake dispersion-ss of red pigment, Kobo C020R7C (Viscotrol C, red 7 color lakes and three different hard

The different third oxygen titanium salt of resin acid), derive from Kobo

Embodiment 16Polyacrylic ester siloxane copolymer network compositions III is as the purposes of water-in-oil type emulsifier

Will be based on the organosilicon group of networks compound III of embodiment 3 preparation with water, D5 and glycerine merging and mix, until evenly.In heating with freeze-melt in the test and significantly be separated, estimate the stability of these emulsions through visual observation.The composition of these emulsions is shown in Table I X.

Table I X

The water-in-oil emulsion compsn

Composition	The comparative example 5	Sample 16
			Polyacrylic ester siloxane copolymer network compositions III	0	20
D5	60	40
			Glycerine	8	8
Water	32	32

The water-in-oil emulsion of sample 16 is in heating (to 50 ℃) and freeze-melt the stability that shows excellence under the condition.Can not mix through various compositions and prepare water-in-oil emulsion comparative example 5.

Embodiment 17The purposes of silicon gel VII in humectant composition

According to following steps, merge preparation sample 17 and comparative example's 6 humectant composition through will be in Table X listed composition: (1) under 60 ℃, through various compositions are merged and mix, until evenly, the preparation part A; (2) part B is added in the part A, and mix, until evenly; (3) mixing portion C in independent container adds in the mixture of part A and part B subsequently; (4) mixture is mixed down in 60 ℃, until evenly.In heating with freeze-melt in the test and significantly be separated, estimate the stability of these compsns through visual observation.Estimate organoleptic properties through expert panel.

Table X

Humectant composition

The humectant composition of sample 17 is in heating (to 50 ℃) and freeze-melt the stability that shows excellence under the condition.Control sample demonstration under heating condition significantly is separated.Compare with comparative example 6, sense organ group test-results shows that silicon gel VII has improved the aftersensation of anti-washability (substantivity), the cooling effect on skin and humectant composition.

^*The SF1540 D5 (with) the PEG/PPG-20/15 YSR 3286, derive from

Momentive?Performance?Materials?Inc.

SF 1550 phenyl gather trimethicone, derive from Momentive Performance Materials

Inc.

The SF96-1000 polydimethylsiloxane fluid derives from Momentive Performance Materials

Inc.

SF 1632 cetearyl polymethyl siloxanes (cetearyl Methicone) derive from

Momentive?Performance?Materials?Inc.

Tospearl gathers methyl silsesquioxane, derives from Momentive Performance Materials

2000B Inc.

Tween20 T 46155 (20) sorbitan monolaurate derives from GE Healthcare

Embodiment 18The purposes of silicon gel VII in retention type (leave-on) hair conditioner composition

Through will in Table X I, merging and mix by listed composition,, prepare sample 18 and comparative example's 7 retention type hair conditioner composition until evenly.

(annotate: before the preparation hair conditioner composition, the organosilicon SF1708 of amino-functional can with silicon gel VII blend.The blend viscosity of SF1708 and silicon gel VII is high.

Table X I

Retention type hair conditioner composition

The test of evaluation group shows, compares with comparative example 7, when the compsn with sample 18 is applied to hair, sensation of softness is provided, and opposite with comparative example 7, and not sticking sensation is provided.

^*The amino YSR 3286 of SF1708 derives from Momentive Performance MaterialsInc..

Embodiment 19Polyacrylic ester siloxane copolymer network compositions IV reveals the purposes in the compsn at the type of anti-rinsing water-in-oil type sunscreen

According to following steps, merge through will be in Table X II listed composition, prepare the type of anti-rinsing water-in-oil type sunscreen and reveal preparation: (1) through merging various compositions and mix, until evenly, preparation part B; (2) part A is added among the part B, and mix, until evenly; (3) mixing portion C in independent container adds in the mixture of part A and part B subsequently; (4) subsequently mixture is mixed, until evenly.Through visual observation in heating with freeze-melt significantly to be separated in the test and estimate the stability of said composition.Estimate organoleptic properties through the sense organ group.Be immersed in the water of stirring and measure through on skin surface, carrying out external SPF before and after 40 minutes, estimate the anti-rinsing property of said composition.

Table X II

The type of anti-rinsing water-in-oil type sunscreen reveals compsn

Composition	Relative quantity
		Part A	Sample 19
Organosilicon group of networks compound IV	15
		Part B
Octyl methoxycinnamate	7.5
		UVNUL MS-40-3	3
Octyl salicylate	5
		Phenylformic acid C 12-15Alkyl ester	4.5
Portion C
		Water	60
Glycerine	5

The type of anti-rinsing water-in-oil type sunscreen of embodiment 19 reveals compsn and is heating (to 50 ℃) and freezing-melt the stability that shows excellence under the condition.It has highly required sensory feel, the cooling effect on skin.The external SPF measuring result on skin surface that 40 minutes front and back of dipping record in the water that stirs is respectively 25 and 25 (MVs of 3 measurements).Polyacrylic ester siloxane copolymer network compositions IV provides about 100%SPF retention rate after the water rinsing processing.In addition, when compsn is applied to skin, not only on the skin surface that repels water, form film, and water-fast rinsing, in fact water can absorb by tunicle, or the emulsification film forming, therefore, on skin, keeps the integrity of film.The part or all of benefit in waterproof, anti-rinsing and the sweat proof is given in expection.

Embodiment 20The preparation of polyacrylic ester siloxane copolymer network compositions IX in water

434g is roughly consisted of MD ₈₅D ^* _2.2D ＂ _5.5M (D ^*: derive from Si-H and 4 vinyl cyclohexene-1, the reaction of 2-epoxide; D ＂: the polyethers CH that derives from Si-H and allyl capped ₂=CH-CH ₂-O-(EO) ₂₄(PO) ₂₇-CH ₃Hydrosilylation) organopolysiloxane mix with 54g vinylformic acid.Add about 30mg 4-methoxyphenol and 1.0g titanium isopropylate.With mixture heating up to 90 ℃, continue about 2 hours.Subsequently the resulting material of 6g and 29g Sipomer PAM-200 (SULPHOSUCCINIC ACID ESTER of polypropylene glycol monomethacrylate derives from Rhodia), 1g Tergitol TMN-6 and 63.56g deionized water are mixed.It is 6.5 that mixture is neutralized to pH.Nitrogen bubble is through 30 minutes, from system, to remove oxygen.Add 0.14g sodium sulfite anhy 96 and 0.3g Potassium Persulphate subsequently.Mixture was heated about 17 hours down in 50 ℃, obtain opaque soft solid.

Embodiment 21The preparation of polyacrylic ester siloxane copolymer network compositions X in water

With 6g polysiloxane copolymer A ^*Mix with 29g Sipomer PAM-200,1g Tergitol TMN-6 and 63.56g deionized water.It is 6.5 that mixture is neutralized to pH.Nitrogen bubble is through 30 minutes, from system, to remove oxygen.Add 0.14g sodium sulfite anhy 96 and 0.3g Potassium Persulphate subsequently.Mixture was heated about 17 hours down in 50 ℃, obtain opaque soft solid.

^*Polysiloxane copolymer A: the siloxanes polyoxyalkylene hydrocarbon copolymer of acroleic acid esterification.CH ₂=CH-CO (OC ₂H ₄) ₈OC ₃H ₆Si (CH ₃) ₂(OSi (CH ₃) ₂) ₁₅OSi (CH ₃) ₂C ₃H ₆O (C ₂H ₄) ₈COCH=CH ₂, derive from Momentive Performance Materials Inc..

Embodiment 22Functionalized organosilicon network IX is as the purposes of water viscosifying agent

According to following steps, through will merging the aqueous compsn of the thickening of preparation embodiment 22 at the listed composition of relative quantity described in the following table XIII.Use PowerGen 700D mixing machine, under 7500RPM, will be according to the functionalized organosilicon network IX of embodiment 20 preparations with deionized water homogenizing 2 minutes.Use the lemon acid for adjusting pH.

Table X III

The aqueous compsn of thickening

Composition	Sample 22
		Functionalized organosilicon network IX	16.7
Deionized water	83.3
		Viscosity during pH 3.5 (cPs)	16,500
Viscosity during pH 5.5 (cPs)	46,000

Viscosity during pH 7 (cPs)

69,000

In pH is the scope of 3.5-7, the effective viscous water solution of polyacrylic ester siloxane copolymer network compositions IX.

Embodiment 23 polyacrylic ester siloxane copolymer network compositions X are as the purposes of water viscosifying agent

According to following steps, through will merging the aqueous compsn of the thickening of preparation embodiment 23 at the listed composition of relative quantity described in the following table XIV.Use PowerGen 700D mixing machine, under 7500RPM, will be according to the functionalized organosilicon network X of embodiment 21 preparations with deionized water homogenizing 2 minutes.Use the lemon acid for adjusting pH.

Table X IV

The aqueous compsn of thickening

Composition	Sample 23
		Functionalized organosilicon network X	16.7
Deionized water	83.3
		Viscosity during pH 4 (cPs)	7,000
Viscosity during pH 5.5 (cPs)	14,000
		Viscosity during pH 7 (cPs)	33,000

In pH is the scope of 4-7, the functionalized effective viscous water solution of organosilicon network X.

Embodiment 24The purposes of polyacrylic ester siloxane copolymer network compositions IX in alpha-hydroxy acid skin treatment cream composition

According to following steps, through will in Table X V, merging preparation alpha-hydroxy acid skin treatment cream composition (sample 24) and comparative example 8 and 9 by listed composition: (1) until evenly, prepares part A through various compositions are mixed; (2) add part B subsequently, and mix, until evenly; (3), and add portion C with mixture heating up to 50 ℃; (4) subsequently with mixture heating up to 75 ℃; (5) under 75 ℃, in independent container, all compositions among the part D are mixed, add to subsequently in the mixture of part A, B and C; (6) should batch mix down, until evenly in 75 ℃; (7) subsequently mixture is cooled to 40 ℃; (8) subsequently with shown in order add each composition of part E; (9), until evenly, and be cooled to room temperature with this batch stirring.

Table X V

Alpha-hydroxy acid skin treatment cream composition

Composition	The comparative example 8	The comparative example 9	Sample 24
				Part A
Natvosol	-	0.29	-
				Neusilin	-	1.43	-
Functionalized organosilicon group of networks compound IX	-	-	6.00
				Water	In right amount	In right amount	In right amount
Part B
				Glycerine	4.76	4.76	4.76
Portion C
				Trolamine	0.71	0.71	0.71
Part D
				Tego Alkanol 16	2.85	2.85	2.85
Stearin (with) PEG-100 stearate (Arlacel165)	4.28	4.28	4.28
				Triple Pressed Stearic Acid	1.43	1.43	1.43
Isopropyl myristate	4.28	4.28	4.28
				MO	4.28	4.28	4.28
YSR 3286,500cst	1.43	1.43	1.43
				Part E
Oxyacetic acid (70%)	7.14	7.14	7.14
				Sodium hydroxide	2.66	2.66	2.66

Sense organ group test-results shows, compares with comparative example 9, and polyacrylic ester siloxane copolymer network compositions IX has improved the aftersensation of the easy property used and alpha-hydroxy acid skin treatment frost, cannot not comprise stickingly, drying and silk-like feeling.The result also shows, compares with comparative example 8, and polyacrylic ester siloxane copolymer network compositions IX has improved the easy property of using, and improves the viscosity and the anti-washability of skin treatment cream composition.

Embodiment 25The preparation of polyacrylic ester siloxane copolymer network compositions XI in siloxanes liquid

900g is roughly consisted of MD ₁₂₅D ^H _7.7The silane liquid of M and 29.93g4-VCH-1,2-epoxide and 386.28g have formula CH ₂=CH-CH ₂-O-(EO) ₅(PO) ₅-CH ₃The polyethers of allyl capped mix.Slow down reaction with Sodium Propionate.With mixture heating up to 85 ℃, and add 0.67ml platinum catalyst solution (ethanolic soln of the Platinic chloride of 10mg/ml).Mixture was stirred 1 hour down in 85 ℃, to form epoxy functionalized polyether-polysiloxane copolymers.Use in the sodium hydrogencarbonate and resulting multipolymer, coupling vacuum stripping is filtered.Subsequently the resulting epoxy functionalized polyether-polysiloxane copolymers of 300.00g is mixed with 13.5g vinylformic acid.Add about 6mg2,2,6,6-tetramethyl piperidine 1-oxygen base and 1.05g titanium isopropylate.With mixture heating up to 90 ℃, continue about 3 hours.Subsequently the resulting material of 150.00g is mixed with the 350.00g D5.Nitrogen bubble was through 30 minutes.Mixture is heated with stirring to 100 ℃.Add 0.31g two bay acyl peroxides subsequently.Mixture in 100 ℃ of following stir abouts 2 hours, is obtained translucent soft solid.

Embodiment 26The preparation of silicon gel XII

100g is mixed with the 100g D5 according to the polyacrylic ester siloxane copolymer network compositions XI of embodiment 25 preparations, and use top mixing machine (overhead mixer), mixed 30 minutes down in 600RPM.The viscosity of resulting silicon gel XII is 94,000 centipoises (" cPs ") (measuring after 24 hours).

Embodiment 27Silicon gel XII reveals the purposes in the compsn at the bright skin of oil-in-water-type

According to following steps, merge through will be in Table X VI listed composition, the bright skin of preparation sample 27 reveals compsn: (1) merges the oil-phase component beyond division ring five siloxanes, is heated to 75 ℃, and mixes down in 500RPM, until evenly; (2) will merge except that trolamine and the water-phase component the Germaben-IIE, be heated to 75 ℃, and mix down, until evenly in 500RPM; (3) subsequently under 75 ℃, slowly add to oil mixture in the aqueous mixture; (4) mixture is cooled to 40 ℃, and mixes down, until evenly in 400RPM; (5) subsequently D5, trolamine and Germaben-IIE are added in the mixture; (6) mixture is stirred down in 400RPM, until evenly, and be cooled to room temperature.

Table X VI

The bright skin of oil-in-water-type reveals compsn

Composition	Weight percent
		Oil phase	Sample 27
VLTN 6 polyethers-2	2
		VLTN 6 polyethers-21	1.5
D5	3
		Silicon gel XII	5
Caryl polymethyl siloxane (Carylyl Methicone)	3
		The trimethylsiloxy silicon ester (with) D5	0.5
VITAMIN E ACETATE	0.3
		PF-5TiO 2CR50	0.3
Phenylformic acid C 12-15Alkyl ester	0.6
		UVNUL MS-40-3	2
Octyl methoxycinnamate	4
		PAROSOL 1789	1.5
Water
		Deionized water	67.79
Glycerine	5
		Vitamin PP	2
Panthenol	1
		EDTA four sodium	0.08
Carbomer?941	0.16
		Germaben-IIE	0.07
Trolamine	0.16
		The phosphoric acid sodium ascorbate	0.04

This illustrative example explanation silicon gel XII can easily be mixed with emulsion oil-in-water.Sense organ group test-results shows, this bright skin has revealed composition exhibiting and luxurious especially had smooth and a buffered silk-like feeling.

Embodiment 28The purposes of silicon gel XII in jettable compositions

Under room temperature, according to listed order in the table, through will in Table X VII, mixing by listed all compositions the jettable compositions of preparation embodiment 28.

Table X VII

Jettable compositions

Composition	Weight percent
			Embodiment 28
Two iso stearyl TriMethylolPropane(TMP) siloxysilicate materials	8
		Phenylformic acid C 12-15Alkyl ester	10
Phenyl gathers trimethicone	15
		The trimethylsiloxy silicon ester (with) D5	5
Octyl methoxycinnamate	7
		Viosorb 930 (octocrylene)	8
Silicon gel XII	5
		The ethyl trisiloxanes	42

This embodiment explanation can easily combine silicon gel XII in jettable compositions, obtain luxurious silk-like feeling, does not have thickening or blockage problem.

Embodiment 29The purposes of silicon gel XII in the antiperspirant gelatinous compsn

According to following steps, through will in Table X VIII, merging by listed composition, prepare the antiperspirant gelatinous compsn of embodiment 29: (1) is passed through various compositions are merged, and mixes down in 600 RPM, until evenly, prepares part A; (2) pass through various compositions are merged, and mix down,, prepare part B until evenly in 600 RPM; (3) part B is dropwise added in the part A, and mix down, until evenly in 600 RPM.

Table X VIII

The antiperspirant gelatinous compsn

Composition	Weight percent
		Part A	Sample 29

D5 (with) the PEG/PPG-20/15 YSR 3286	1.87
		D5	8.13
The hydrogenation poly decene	3
		Silicon gel XII	5
Part B
		45% tetrachloro hydration aluminum zirconium glycine (Aluminumzirconium tetrachlorohydrex glycol)	47
Ucar 35	21
		Deionized water	14

The purposes of this illustrative example explanation silicon gel XII in antiperspirant applications.The antiperspirant gelatinous compsn of sample 29 has unique comfort.Through changing the ratio of Ucar 35 and water, the refractive index of coupling water and oil phase also can obtain transparent gel.

Embodiment 30The purposes of silicon gel XII in low pH alpha hydroxy acid (AHA) cream composition

According to following steps, through will in Table X IX, merging by listed all compositions, prepare the low pH alpha hydroxy acid cream composition of embodiment 30: (1) is passed through all compositions are merged, and mixes down in 60 ℃, until evenly, prepares part A; (2) pass through all compositions are merged, and mix down,, prepare part B until evenly in 60 ℃; (3) part B is dropwise added in the part A, and mixture is stirred, until evenly; (4) portion C is added in the mixture, it is 4 that compsn is adjusted to pH.

Table X IX

Low pH alpha hydroxy acid cream composition

Composition	Weight percent
		Part A
The PEG-8 YSR 3286	6
		Silicon gel XII	20
Octyl methoxycinnamate	7.5
		D5 (with) the PEG/PPG-20/15 YSR 3286	3
Part B

Glycerine	12
		NaCl	0.5
70% oxyacetic acid	4.4
		Deionized water	43.20
Portion C
		Trolamine	3.4

Under room temperature, this AHA cream composition shows satisfactory stability property.It has luxurious skin feel, and is very different with " AHA-shouting pain (sting) " sensation of other low pH AHA products of great majority.

Embodiment 31The purposes of silicon gel XII in lipstick

According to following steps, through will in Table X X, merging by listed composition, prepare the lipstick compsn of sample 31: (1) is passed through all compositions are merged, and mixes 15 minutes down in 98 ℃, until evenly, prepares part A; (2) composition among the part B is added in the part A, and mixture is stirred, until evenly; (3) subsequently mixture is poured in the lipstick mould warm in advance in 50 ℃ baking oven; (4) subsequently mould is placed on-10 ℃ freeze in the case, until mixture solidified; (5) subsequently mould is removed from freeze case; (6) curing mixture is shifted out from mould, and be placed in the lipstic case.

Table X X

The lipstick compsn

Composition	Weight percent
			Sample 31
Part A
		Snow-white vaseline	25.9
Two isostearoyl base TriMethylolPropane(TMP) siloxysilicate materials	15
		Silicon gel XII	5
Gama wax	4
		Cera alba	6
Ceresine	7
		Yellow POLISHING WAX-103	4

Orchil/Viscotrol C	28
		Part B
Permethyl 99A.	5
		Propylben	0.1

The lipstick compsn of sample 31 has unique softness and silk-like feeling.

Embodiment 32The purposes of silicon gel XII in liquid lip gloss compsn

According to following steps, through will in Table X XI, merging by listed composition, preparation sample 32 and comparative example's 10 liquid lip gloss compsn: (1) is placed on all compositions in the container, and heats 30 minutes down in 90 ℃; (2) subsequently in the Flack-Tec mixing machine, under 3500 RPM, with mixture mixing 5 minutes.The liquid lip compositions is applied to skin surface, carries out gloss measurement.Use BYK-Gardner Micro TRI glossmeter to estimate gloss.The gloss measurement result is shown in Table X XII.

Table X XI

Liquid lip gloss compsn

Composition	Weight percent	Weight percent
				The comparative example 10	Sample 32
YSR 3286 *	10	10
			D5 (with) C30-45 alkyl hexadecyl YSR 3286 cross-linked polymer	26.3	21.3
Silicon gel XII	-	5
			C30-45 alkyl YSR 3286	2	2
D5 (with) the PEG/PPG20/15 YSR 3286	2.6	2.6
			Permethyl 99A.	27.3	27.3
Red pigment	29	29
			TiO 2	2.9	2.9

Table X XII

Sample 32 and comparative example's 10 gloss measurement result

Compsn	With lower angle (°) reflection	MV	SD
				The comparative example 10	20	2.5	0.0
The comparative example 10	60	22.2	0.0
				The comparative example 10	85	47.4	0.1
				Sample 32	20	3.3	0.0
Sample 32	60	35.9	0.0
				Sample 32	85	54.3	0.6

Gloss measurement is the result show, compares with comparative example 10, and silicon gel XII has improved the gloss of this lip gloss compsn.

Embodiment 33The purposes of silicon gel XII in rinsing type bathing amendment

Through will in Table X III, merging and mix by listed composition,, prepare sample 33 and comparative example's 11 rinsing type bathing conditioner composition until evenly.

About 0.02g preparation is applied on tester's the arm skin of 3cm * 3cm area.This skin washed 20 seconds with about 0.5ml washing composition (aqueous solution of 30% Standapol ES-I) subsequently, and with warm water rinsing 20 seconds.Paper towel dry skin subsequently.The fragrance on the arm skin is stayed in three people's group assessments by having normal sense of smell.

Table X XIII

Rinsing type bathing conditioner composition

The test of evaluation group shows, compares with comparative example 11, and the fragrance that silicon gel XII has improved this rinsing type bathing conditioner composition of sample 33 keeps.

The SF96-350 YSR 3286 derives from Momentive Performance Materials Inc.

Starlet perfume oil derives from Givaudan

Embodiment 34Silicon gel XII is as the purposes of oil phase viscosifying agent

According to following steps; Through merging at the listed composition of relative quantity described in the following table XXIII; The compsn of the thickening of preparation embodiment 34: will mix with D5 or Finsolv TN according to the silicon gel XII of embodiment 26 preparations; Use the top mixing machine, under 600 RPM, mixed 20 minutes.The viscosity of resulting material (measuring after 24 hours) is listed in Table X XIV.

Table X XIV

The Unctuous compositions of thickening

Composition	Sample 34-1	Sample 34-2	Sample 34-3
				Silicon gel XII	20.00	20.00	20.00
D5	20.00	-	19.00
				Finsolv?TN	-	20.00	-
MagnaSoft?Plus	-	-	1.00
				Viscosity (cPs)	2,000	3,200	29,500

Silicon gel XII thickening in silicone oil and organic oil.When silicon gel XII and amido organosilicon combination, the thickening effectiveness in silicone oil is more remarkable.

The siloxanes liquid that MagnaSoft Plus is amino modified derives from Momentive PerformanceMaterials.

Embodiment 35The purposes of silicon gel XII in rinsing type hair conditioner

According to following steps, merge preparation rinsing type hair conditioner preparation through will be in Table X XV listed composition: (1) through merging various compositions, and mix, until evenly, and preparation part B; (2) subsequently under 70 ℃, part B is mixed with composition in the portion C, until evenly; (3) subsequently the mixture of part B and portion C is added to part A; (4) mixture is mixed down in 70 ℃,, be cooled to 35 ℃ subsequently, mix simultaneously until evenly.This rinsing type hair conditioner preparation of test on platinum blonde topknot.The platinum blonde topknot of two bundles under the standard laboratory step, is used typical shampoo formulation washing, use the rinsing type hair conditioner treated of sample 35 subsequently.With these topknots of after scouring, and use blower dry.Measure dry anti-the entanglement (detangling), and be defined as when topknot is placed on the calibration chart, and the inch number that comb is advanced when comb is to the bottom from the top.Fly upward through measurement and to estimate Electrostatic Control.With the quick combing of hair 10 times, fly upward the total width that is defined as whole topknot and the difference of hair width of topknot after combing.Fly upward lowly more, explain that Electrostatic Control is good more.

Table X XV

Rinsing type hair conditioner composition

Composition	Weight percent
			Sample 35
Part A
		Deionized water	88
Part B
		Gel XII	2
Decapryl ether	2
		Portion C
Tego Alkanol 16	2
		Ceteareth-20	2
Cetearyl alcohol	4

Table X XVI

The drying of sample 35 prevents tangling and flying upward measuring result

The measuring result of Table X XVI shows that the rinsing type hair conditioner composition of sample 35 has improved dry anti-entanglement, and Electrostatic Control is provided.The test of evaluation group shows that also the compsn of sample 35 has improved the flexibility of topknot.

Embodiment 36The purposes of silicon gel XII in retention type hair-cream (hair serum)

Under room temperature, will in Table X XVII, mix by listed composition preparation retention type hair-cream preparation in order.This retention type hair-cream preparation of test on platinum blonde topknot.The platinum blonde topknot of two bundles under the standard laboratory step, is used typical shampoo formulation washing, use the rinsing type hair conditioner treated of sample 36 subsequently.Use dry these topknots of blower subsequently.Carry out the anti-entanglement of drying and fly upward measurement like embodiment 35.

Table X XVII

Retention type hair-cream compsn

Composition	Weight percent
			Sample 36
Gel XII	2
		SF1215	50
Permethyl 99A.	29.5
		Isooctadecanol	12
Isopropyl myristate	6.5

^*SF1215 D5 and YSR 3286 derive from Momentive PerformanceMaterials.

Table X XVIII

The drying of sample 36 prevents tangling and flying upward measuring result

The measuring result of Table X XVIII shows that the retention type hair-cream compsn of sample 36 has improved dry anti-entanglement, and Electrostatic Control is provided.The test of evaluation group shows that also the compsn of sample 36 has improved the flexibility of topknot.

Embodiment 37The purposes of silicon gel XII in hair setting composition

Through will in Table X XIX, mixing by listed composition preparation hair fixing preparation.This hair fixing preparation of test on light brown topknot.It is wetting to restraint topknots with two, uses the hair fixing treated of embodiment 37 subsequently.The topknot that these are treated is rolled with sending out roller, and drying is 1 hour in 100 ℃ baking oven, under envrionment temperature, nurses one's health subsequently and spends the night.Subsequently these topknots are carefully removed from roller, be suspended on the scale frame.Measure the length of these topknots, and be recorded as initial length.Subsequently the topknot on the scale frame is placed in the chamber of 25 ℃ and 90% relative humidity.Carried out a linear measure in per 15 minutes, measured altogether 2 hours.Use the curling reservation (curl retention) of the treated topknot of the every bundle of computes.

Wherein: L is the length that hair extends fully

L ₀For being placed on the humidity chamber length of hair before

L ' is for being placed on the length of hair after humidity chamber t minute

Table X XIX

Hair setting composition

Table X XX

The curling reservation measuring result of embodiment 37

	Handle
				Be placed on time after the humidity chamber (minute)	The comparative example 12	Sample 37-1	Sample 37-2
	Curl and keep %	Curl and keep %	Curl and keep %
				0	100	100	100
15	33	62	79
				30	25	54	79
45	17	54	71
				60	17	46	71
75	17	46	71
				90	17	46	71
105	17	46	71
				120	17	46	71

The measuring result of Table X XX shows, compares with comparative example 12, and gel XII significantly improves curly headed to be kept.Compared with gel XII itself, gel XII and SF 1708, amino-functional organosilyl combination provide higher hair to keep.This is a unexpected result, because compare with independent D5, the SF1708 of 1% content does not provide extra curling reservation effect in D5.Therefore, gelatinous compsn XII and the combination of aminosiloxane liquid provide obviously to keep effect with beyond thought collaborative curling.

The test of evaluation group shows, when the compsn with sample 37-1 or 37-2 is applied to hair, compares with comparative example 12, and more slick sensation is provided, less curling, and the better combing of hair.

Embodiment 38Silicon gel XII is as the purposes of water-in-oil type emulsifier

Based on following steps, will merge with other listed in Table X XXI compositions based on the silicon gel XII of embodiment 26 preparations: (1) until evenly, prepares part A through various compositions are mixed; (2) in independent container, pass through various compositions are mixed,, prepare part B until evenly; (3) part B is slowly added in the part A, and mixture is mixed, until evenly.Measure the viscosity of emulsion preparation these emulsions after 24 hours.In heating with freeze-melt in the test and significantly be separated, estimate the stability of these emulsions through visual observation.In the heating test, samples of latex was kept 5 days in 50 ℃ baking oven.Freeze-melt at each and carry out in the test freezing-melt circulation three times.The composition of these emulsions and test result are summarized in Table X XXI.

Table X XXI

The water-in-oil emulsion compsn

What the water-in-oil emulsion composition exhibiting of sample 38-1 and 38-2 was excellent freezes-the warm thermostability that adds.Viscosity measurement shows that also compared with silicon gel XII itself, silicon gel XII and Magnasoft Plus, amino-functional organosilyl water-in-oil emulsion that is combined as provide better thickening.

Embodiment 39The preparation of silicon gel XIII

100g is merged with 98g D5 and 2g SF1708 amino-functional siloxane liquid according to the polyacrylic ester siloxane copolymer network compositions XI of embodiment 25 preparations; And use top mixing machine; Under 600 RPM, mixed 30 minutes, to produce silicon gel XIII.

The sample of silicon gel XII and silicon gel XIII is placed on the aluminium surface, lets D5 under envrionment temperature and humidity, evaporate.Produce film like this.The viscosity of the film that postevaluation in 48 hours forms is classified as 0-10 (wherein 0 is sticking for not, and 10 is " very sticking ").The viscosity evaluation result is seen Table X XXII.

Table X XXII

The viscosity evaluation of the film that produces by gelatinous compsn

	Gel XII	Gel XIII
			Stickiness feeling	8	2

The viscosity evaluation result clearly illustrates that, the film that is produced by gel XIII has very little viscosity, and much smaller than the viscosity of the film that produces by gel XII.

This is a unexpected result, because amino-functional siloxane liquid SF 1708 has high viscosity when sprawling to film.It is unexpected that the fluid that therefore, will have a high viscosity is attached to the effect that can produce the low-down film of viscosity among the gelatinous compsn XIII.

Embodiment 40The preparation of functionalized organosilicon group of networks compound XIII in siloxanes liquid

1000g is roughly consisted of MD ₁₂₅D ^H _7.7The silane liquid of M and 34.18g 4 vinyl cyclohexene-1,2-epoxide and 470.36g have formula CH ₂=CH-CH ₂-O-(EO) ₅(PO) ₅-CH ₃The polyethers of allyl capped mix.With mixture heating up to 85 ℃, and add 0.40g platinum catalyst solution (ethanolic soln of the Platinic chloride of 10mg/ml).Slow down reaction with Sodium Propionate.Mixture was stirred 2 hours down in 85 ℃, to form epoxy functionalized polyether-polysiloxane copolymers.Use the sodium hydrogencarbonate neutralized copolymer subsequently, coupling vacuum stripping is filtered.Subsequently the resulting epoxy functionalized polyether-polysiloxane copolymers of 150.00g is mixed with 1.40g vinylformic acid.Add about 3mg 2,2,6,6-tetramethyl piperidine-1-oxygen base and 0.45g titanium isopropylate.With mixture heating up to 90 ℃, continue about 3 hours.Subsequently the resulting material of 150.00g is mixed with the 350.00g D5.Nitrogen bubble was through 30 minutes.Mixture is heated with stirring to 100 ℃.Add 0.31g two bay acyl peroxides subsequently.Mixture in 100 ℃ of following stir abouts 2 hours, is obtained translucent soft solid.

Embodiment 41The preparation of silicon gel XIV

30g is mixed with the 50g D5 according to the functionalized organosilicon group of networks compound XIII of embodiment 40 preparations, and use the top mixing machine, under 600RPM, mixed 30 minutes.The viscosity of resulting silicon gel XIV is 76,000 centipoises (" cPs ") (measuring after 24 hours).

Embodiment 42

Table X XXIII

Influence the substituent exemplary configurations of polyethers and the stoichiometry parameter of water-swellable or oil swell property

The polyethers substituting group is based on following formula:

(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)

	Water-soluble expanding	Oil swell
			R 9	H，CH 3	H，CH 3
R 10	CH 2	CH 2
			R 11	Do not have	Do not have
R 12	H，CH 3	H，CH 3, ethanoyl, butyl
n	1	1
			o	0	0
p	11-40	5-24
			q	0-27	5-27
r	0	0

			p/q	>2/3

What stress once more is; Illustrate target variable rangeization under aforementioned structure parameter and the stoichiometry of water-swellable or oil swell property among the Table X XXIII; And it is interrelated; And each parametric variable can exceed (being greater than or less than) said scope, and owing to change in another structure relevant with concrete polymkeric substance or the homeostasis in the stoichiometry parameter, still can observe the swelling of particular type.

Previous embodiment only is to explanation of the present invention, is used to explain only some characteristics of the present invention.Wide as far as possible the present invention that the accompanying claims intention requires protection to expect, the embodiment that described the application's embodiment explanation is selected from various all possible embodiment.Therefore, applicant's intention is that accompanying claims is not used to explain that by selected the embodiment of characteristic of the present invention limits.Used wording in the claim " comprise " also mean and comprise the wording of various degree in logic with its phraseological variant, such as but not limited to, " basically by ... form " with " by ... composition ".In the time of necessary, scope is provided; Those scopes comprise all subranges therebetween.This scope can be regarded a Ma Kushi group or a plurality of Ma Kushi group of being made up of different paired digital boundaries as; Described Ma Kushi group or a plurality of Ma Kushi group are limited its lower limit and the upper limit fully, increase in number from lower limit to the upper limit with normal mode.Expectation those of ordinary skills should be able to expect the variation of these scopes, if do not offer to the public, these variations also should be interpreted as by accompanying claims as much as possible and cover.Also expectation is, scientific-technical progress will make that at present these variants also should be interpreted as by accompanying claims as much as possible and cover because the former thereby unexpected equivalence of the inaccuracy of language is replaced the possibility that becomes.The full content of all USPs (and patented claim) of the application institute reference herein through with reference to incorporating the application into, just looks like that they put down in writing the same in this application in full all.

Claims (59)

1. make-up composition, said make-up composition comprises silicon composition, said silicon composition comprise following a), b) and reaction product c):

A) M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gWith

B) propenoate of stoichiometry or hyperstoichiometry amount, wherein

M＝R ¹R ²R ³SiO _1/2；

M ^H＝R ⁴R ⁵HSiO _1/2；

M ^PE＝R ⁴R ⁵(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _1/2；

M ^E＝R ⁴R ⁵(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2；

D ^PE＝R ₈(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2；

D ^E＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2；

T＝R ¹⁹SiO _3/2；

T ^H＝HSiO _3/2；

T ^PE＝(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _3/2；

T ^E=(R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _3/2With

Q＝SiO _4/2；

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from monovalence alkyl independently of one another with 1-60 carbon atom;

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom;

R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom; R ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, wherein R ¹⁶And R ¹⁸Cis or trans each other;

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number;

Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number;

Subscript c is a positive number, and numerical value is 5-1,000;

Subscript d is a positive number, and numerical value is 3-400;

Subscript e is 0 or positive number, and numerical value is 0-50;

Subscript f is 0 or positive number, and numerical value is 0-30;

Subscript g is 0 or positive number, and numerical value is 0-20;

Subscript h is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript i is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript j is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript k is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript l is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript m is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript n is 0 or 1;

Subscript o is 0 or 1;

Subscript p is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript q is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript r is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript s is 0 or 1;

Subscript t is 0 or 1; With

C) radical initiator, wherein said make-up composition have the dehydration tolerance shrinkability of raising.

2. the compsn of claim 1, wherein said silicon composition is a self-emulsifying.

3. the compsn of claim 1, wherein said silicon composition can be by solvent-swollen.

4. the compsn of claim 3, wherein said solvent is a water.

5. the compsn of claim 3, wherein said solvent is non-hydrophilic solvent, the siloxanes of hydroxylic solvent, non-water.

6. the compsn of claim 3, wherein said solvent is straight chain or ring-type or lipophilic fluid.

7. the compsn of claim 3, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

8. the compsn of claim 4, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

9. the compsn of claim 5, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

10. the compsn of claim 8, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

11. the compsn of claim 9, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

12. make-up composition, said make-up composition comprises aqueous emulsion, and wherein discontinuous phase comprises water, and external phase comprises silicon composition, said silicon composition comprise following a), b) and reaction product c):

A) M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gWith

B) propenoate of stoichiometry or hyperstoichiometry amount, wherein

M＝R ¹R ²R ³SiO _1/2；

M ^H＝R ⁴R ⁵HSiO _1/2；

M ^PE＝R ⁴R ⁵(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _1/2；

M ^E＝R ⁴R ⁵(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2；

D ^PE＝R ⁸(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2；

D ^E＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2；

T＝R ¹⁹SiO _3/2；

T ^H＝HSiO _3/2；

T ^PE＝(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) ₀(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _3/2；

T ^E=(R ¹⁷R ¹⁸C-CR1 ^6Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _3/2With

Q＝SiO _4/2；

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from monovalence alkyl independently of one another with 1-60 carbon atom;

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom;

R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom; R ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, wherein R ¹⁶And R ¹⁸Cis or trans each other;

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number;

Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number;

Subscript c is a positive number, and numerical value is 5-1,000;

Subscript d is a positive number, and numerical value is 3-400;

Subscript e is 0 or positive number, and numerical value is 0-50;

Subscript f is 0 or positive number, and numerical value is 0-30;

Subscript g is 0 or positive number, and numerical value is 0-20;

Subscript h is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript i is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript j is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript k is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript l is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript m is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript n is 0 or 1;

Subscript o is 0 or 1;

Subscript p is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript q is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript r is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript s is 0 or 1;

Subscript t is 0 or 1; With

C) radical initiator, wherein said make-up composition have the dehydration tolerance shrinkability of raising.

13. the compsn of claim 12, wherein said silicon composition is a self-emulsifying.

14. the compsn of claim 12, wherein said silicon composition can be by solvent-swollen.

15. the compsn of claim 14, wherein said solvent are water.

16. the compsn of claim 14, wherein said solvent are non-hydrophilic solvent, the siloxanes of hydroxylic solvent, non-water.

17. the compsn of claim 14, wherein said solvent are straight chain or ring-type or lipophilic fluid.

18. the compsn of claim 14, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

19. the compsn of claim 15, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

20. the compsn of claim 16, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

21. the compsn of claim 19, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

22. the compsn of claim 20, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

23. compsn, said compsn comprises aqueous emulsion, and wherein external phase comprises water, discontinuous phase comprise following a), b) and reaction product c):

A) M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gWith

B) propenoate of stoichiometry or hyperstoichiometry amount, wherein

M＝R ¹R ²R ³SiO _1/2；

M ^H＝R ⁴R ⁵HSiO _1/2；

M ^PE＝R ⁴R ⁵(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _1/2；

M ^E＝R ⁴R ⁵(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2；

D ^PE＝R ⁸(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2；

D ^E＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2；

T＝R ¹⁹SiO _3/2；

T ^H＝HSiO _3/2；

T ^PE＝(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _3/2；

T ^E=(R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _3/2With

Q＝SiO _4/2；

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from monovalence alkyl independently of one another with 1-60 carbon atom;

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom;

R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom; R ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, wherein R ¹⁶And R ¹⁸Cis or trans each other;

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number;

Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number;

Subscript c is a positive number, and numerical value is 5-1,000;

Subscript d is a positive number, and numerical value is 3-400;

Subscript e is 0 or positive number, and numerical value is 0-50;

Subscript f is 0 or positive number, and numerical value is 0-30;

Subscript g is 0 or positive number, and numerical value is 0-20;

Subscript h is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript i is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript j is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript k is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript l is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript m is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript n is 0 or 1;

Subscript o is 0 or 1;

Subscript p is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript q is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript r is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript s is 0 or 1;

Subscript t is 0 or 1; With

C) radical initiator, wherein said compsn have the dehydration tolerance shrinkability of raising.

24. the compsn of claim 23, wherein said reaction product is a self-emulsifying.

25. the compsn of claim 23, wherein said reaction product can be by solvent-swollen.

26. the compsn of claim 25, wherein said solvent are water.

27. the compsn of claim 25, wherein said solvent are non-hydrophilic solvent, the siloxanes of hydroxylic solvent, non-water.

28. the compsn of claim 25, wherein said solvent are straight chain or ring-type or lipophilic fluid.

29. the compsn of claim 25, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

30. the compsn of claim 26, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

31. the compsn of claim 27, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

32. the compsn of claim 30, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

33. the compsn of claim 31, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

34. make-up composition, said make-up composition comprises nonaqueous emulsion, and wherein discontinuous phase comprises non-water hydroxylic solvent, external phase comprise following a), b) and reaction product c):

A) M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gWith

B) propenoate of stoichiometry or hyperstoichiometry amount, wherein

M＝R ¹R ²R ³SiO _1/2；

M ^H＝R ⁴R ⁵HSiO _1/2；

M ^PE＝R ⁴R ⁵(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _1/2；

M ^E＝R ⁴R ⁵(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2；

D ^PE＝R ⁸(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2；

D ^E＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2；

T＝R ¹⁹SiO _3/2；

T ^H＝HSiO _3/2；

T ^PE＝(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _3/2；

T ^E=(R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _3/2With

Q＝SiO _4/2；

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from monovalence alkyl independently of one another with 1-60 carbon atom;

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom;

R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom; R ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, wherein R ¹⁶And R ¹⁸Cis or trans each other;

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number;

Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number;

Subscript c is a positive number, and numerical value is 5-1,000;

Subscript d is a positive number, and numerical value is 3-400;

Subscript e is 0 or positive number, and numerical value is 0-50;

Subscript f is 0 or positive number, and numerical value is 0-30;

Subscript g is 0 or positive number, and numerical value is 0-20;

Subscript h is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript i is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript j is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript k is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript l is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript m is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript n is 0 or 1;

Subscript o is 0 or 1;

Subscript p is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript q is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript r is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript s is 0 or 1;

Subscript t is 0 or 1; With

C) radical initiator, wherein said make-up composition have the dehydration tolerance shrinkability of raising.

35. the compsn of claim 34, wherein said reaction product is a self-emulsifying.

36. the compsn of claim 34, wherein said reaction product can be by solvent-swollen.

37. the compsn of claim 36, wherein said solvent are water.

38. the compsn of claim 36, wherein said solvent are non-hydrophilic solvent, the siloxanes of hydroxylic solvent, non-water.

39. the compsn of claim 36, wherein said solvent are straight chain or ring-type or lipophilic fluid.

40. the compsn of claim 36, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

41. the compsn of claim 37, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

42. the compsn of claim 38, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

43. the compsn of claim 41, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

44. the compsn of claim 42, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

45. make-up composition, said make-up composition comprises nonaqueous emulsion, and wherein external phase comprises non-water hydroxyl organic solvent, discontinuous phase comprise following a), b) and reaction product c):

A) M _aM ^H _B-h-kM ^PE _hM ^E _kD _cD ^H _D-i-lD ^PE _iD ^E _lT _eT ^H _F-j-mT ^PE _jT ^E _mQ _gWith

B) propenoate of stoichiometry or hyperstoichiometry amount, wherein

M＝R ¹R ²R ³SiO _1/2；

M ^H＝R ⁴R ⁵HSiO _1/2；

M ^PE＝R ⁴R ⁵(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _1/2；

M ^E＝R ⁴R ⁵(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _1/2；

D=R ⁶R ⁷SiO _2/2With

D ^H＝R ⁸HSiO _2/2；

D ^PE＝R ⁸(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _2/2；

D ^E＝R ⁸(-R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC)R ¹³R ¹⁴)SiO _2/2；

T＝R ¹⁹SiO _3/2；

T ^H＝HSiO _3/2；

T ^PE＝(-CH ₂CH(R ⁹)(R ¹⁰) _nO(R ¹¹) _o(C ₂H ₄O) _p(C ₃H ₆O) _q(C ₄H ₈O) _rR ¹²)SiO _3/2；

T ^E=(R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴) SiO _3/2With

Q＝SiO _4/2；

R wherein ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹Be selected from monovalence alkyl independently of one another with 1-60 carbon atom;

R ⁹For H or have the alkyl of 1-6 carbon atom; R ¹⁰For having the divalent alkyl of 1-6 carbon atom;

R ¹¹For being selected from-C ₂H ₄O-,-C ₃H ₆O-and-C ₄H ₈The divalent group of O-; R ¹²For H, have the alkyl or the ethanoyl of the simple function of 1-6 carbon atom; R ¹³, R ¹⁴, R ¹⁵, R ¹⁶, R ¹⁷And R ¹⁸Be selected from hydrogen and the monovalence alkyl with 1-60 carbon atom, Q independently of one another _tBe divalence or the trivalent hydrocarbon radical with 1-60 carbon atom, Q _sFor having the bivalent hydrocarbon radical of 1-60 carbon atom, obey following restricted condition: work as Q _tDuring for trivalent, R ¹⁴Do not exist, wherein R ¹⁶And R ¹⁸Cis or trans each other;

Subscript a can be 0 or positive number, and obey following restricted condition: when subscript a was 0, b was necessary for positive number;

Subscript b can be 0 or positive number, and obey following restricted condition: when b was 0, subscript a was necessary for positive number;

Subscript c is a positive number, and numerical value is 5-1,000;

Subscript d is a positive number, and numerical value is 3-400;

Subscript e is 0 or positive number, and numerical value is 0-50;

Subscript f is 0 or positive number, and numerical value is 0-30;

Subscript g is 0 or positive number, and numerical value is 0-20;

Subscript h is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript i is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript j is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript h, i and j is a positive number;

Subscript k is 0 or positive number, and numerical value is 0-2, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript l is 0 or positive number, and numerical value is 0-200, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript m is 0 or positive number, and numerical value is 0-30, and the summation of obeying following restricted condition: subscript k, l and m is a positive number;

Subscript n is 0 or 1;

Subscript o is 0 or 1;

Subscript p is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript q is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript r is 0 or positive number, and numerical value is 0-100, obeys following restricted condition: (p+q+r)＞0;

Subscript s is 0 or 1;

Subscript t is 0 or 1; With

C) radical initiator, wherein said make-up composition have the dehydration tolerance shrinkability of raising.

46. the compsn of claim 45, wherein said reaction product is a self-emulsifying.

47. the compsn of claim 45, wherein said reaction product can be by solvent-swollen.

48. the compsn of claim 47, wherein said solvent are water.

49. the compsn of claim 47, wherein said solvent are non-hydrophilic solvent, the siloxanes of hydroxylic solvent, non-water.

50. claim 47 compsn, wherein said solvent is straight chain or ring-type or lipophilic fluid.

51. the compsn of claim 47, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

52. the compsn of claim 48, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

53. the compsn of claim 49, wherein R ¹, R ², R ³, R ⁴, R ⁵, R ⁶, R ⁷, R ⁸And R ¹⁹The methyl of respectively doing for oneself.

54. the compsn of claim 52, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

55. the compsn of claim 53, wherein R ¹⁷R ¹⁸C-CR ¹⁶Q _sQ _tR ¹⁵(COC) R ¹³R ¹⁴Be the VCH oxide compound.

56. make-up composition, said make-up composition comprises emulsion oil-in-water, and said emulsion comprises the silicon composition of claim 1, and wherein said compsn is present in aqueous phase.

57. make-up composition, said make-up composition comprises water-in-oil emulsion, and said emulsion comprises the silicon composition of claim 1, and wherein said compsn is present in aqueous phase.

58. make-up composition, said make-up composition comprises nonaqueous emulsion, and wherein discontinuous phase comprises the silicon composition of non-water hydroxyl organic solvent and claim 1.

59. make-up composition, said make-up composition comprises nonaqueous emulsion, and wherein external phase comprises the silicon composition of non-water hydroxyl organic solvent and claim 1.