CN101481557A - Colored powdered glass printing ink, oil paint and coating - Google Patents
Colored powdered glass printing ink, oil paint and coating Download PDFInfo
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- CN101481557A CN101481557A CNA2008100009496A CN200810000949A CN101481557A CN 101481557 A CN101481557 A CN 101481557A CN A2008100009496 A CNA2008100009496 A CN A2008100009496A CN 200810000949 A CN200810000949 A CN 200810000949A CN 101481557 A CN101481557 A CN 101481557A
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Abstract
A color glass powder printing ink/lacquer/paint comprises staining compound, thinner, forming agent, polymerization inhibitor and addition agent. The staining compound adopts color glass powder or screen printing glaze powder.
Description
Technical field:
The present invention relates to printing-ink, paint, coating.
Background technology:
UV light-curable ink, paint, coating mainly are made up of photosensitive resin, photosensitizers, pigment and auxiliary agent, do not contain deleterious volatile matter such as solvent.Therefore, UV light-curable ink, paint, coating are a kind of printing ink, paint, coating that meets environmental protection concept.In the UV solidification process, when the irradiation of UV light-curable ink, paint, coating contact ultraviolet, the photosensitive resin in UV light-curable ink, paint, the coating is intermolecular, and just generation is crosslinked rapidly, thereby realizes solidifying.This process is very fast, only needs the time of 0.5～3s usually.Therefore, UV light-curable ink, paint, coating have the energy of saving and place, the characteristics of increasing work efficiency in application process.In screen printing process, because the printing ink on the half tone fails to contact ultraviolet irradiation, so its network blocking never, this has brought very big convenience for accurate picture and text of printing and continuity operation.In the paint application process,, reduce pollution to environment owing to do not contain deleterious volatile matter such as solvent.In coating, use,, can greatly reduce the engineering time because the time of ultraviolet light polymerization is very short.
Common ink is by colouring matter, resin, and thinner, forming agent, stopper, auxiliary agent is formed, and the pigment in the common ink easily decomposes and fades under long-term illumination condition.
Patent 02111442.0 " UV solidified intaglio printing decorative ink ", 20061003019.5 " UV cured concealed fluorescent frequency conversion inks ", " 200510048225.5 a kind of ultraviolet cured offset printing ink ", 200510048225.5 " a kind of ultraviolet cured offset printing ink " above-mentioned patent all adopts oil colour as tinting material, oil colour easily fades under long-term outdoor illumination condition, be not suitable for making long-term outdoor use goods, mould the decorative pattern of Wood products etc. as outdoor use." 200580008304.1 metal pigment composition and use its UV metal ink or coating composition ", UV wire netting printing ink is in solidification process, need to absorb the energy of UV light, the metallic ink layer is from the surface to the deep layer, the intensity of the UV light of being accepted is descending gradually, because it is opacifying property that metal ink itself has, UV light is difficult to penetrating metal China ink layer and reaches China ink layer bottom deeply.Will cause the metal ink deep layer to solidify saturating like this and the phenomenon that sticking power reduces occurs.Another shortcoming of metal ink is the easy oxidation of metal.
200610044779.2 a thermoplastic acrylic paint adds pigment dyestuff in the paint, pigment dyestuff easily decomposes under long-term illumination condition, fades, and reduces the working life of paint.
Summary of the invention:
The objective of the invention is: 1,,, improve the printing ink weather resistance as the tinting material of printing ink by with making the colored glass powder in pigment or the dyestuff adding high-temperature fusion glass.2, by printing the tinting material of powdered frit, improve the printing ink weather resistance as printing ink.3,, improve the decorate properties of glass ink by the refraction of light characteristic of colored glass powder in different angles.4, utilize the light transmission of colored glass powder, rate of crosslinking between photosensitive molecular resin when improving uviolizing.5, metallic particles is wrapped in the transparent glass, improves the laser curing velocity of metal ink, prevent the metallic particles oxidation.6, colored glass powder or printing powdered frit improve the wear resisting property of printing ink, paint, coating.
Colored glass powder printing ink, paint, coating that the present invention proposes comprise, colouring matter, thinner, forming agent, stopper, auxiliary agent, colouring matter adopts colored glass powder or printing powdered frit, the colored glass powder be with glass heats after molten state, add pigment or dyestuff and make band look melten glass liquid, through cooling, pulverizing is made.Add the suitable stronger printing ink of opacifying power of making of colored glass powder of pigment, the colored glass powder that adds dyestuff suits to make transparent or semitransparent printing ink.The suitable extraordinary ambetti printing ink of making translucent pattern of mixed zone look glass powder that adds pigment and dyestuff.Because colored glass powder or printing powdered frit tinting material have stable chemical property, can not dissolve mutually, therefore, the color of pigment or dyestuff is according to the special-purpose look of product requirements with color dye or dyestuff preparation, the colour that single color or multiple color are formed in colored glass powder or the printing powdered frit.
The shape of colored glass powder or printing powdered frit is the irregular particle that grinds out by shredder, or after the colored glass liquid of molten state pulled into glass yarn, through cutting off, pulverizing was made.The different shapes glass particle has different refraction of light characteristics in different visual position, and different refraction of light characteristics produces different visual effects, improves the decorate properties of glass ink.
Add prepolymer and light trigger in colored glass powder printing ink or the printing powdered frit, make curing glass powder printing ink or photocuring printing powdered frit, it is the printing material that meets environmental protection concept that curing glass powder printing ink or photocuring printing powdered frit does not contain harmful volatile matter such as solvent, curing glass powder printing ink or another advantage of photocuring printing powdered frit are that curing speed is fast, high efficiency.
The granularity of colored glass powder or printing powdered frit is controlled between the 1nm-40 μ m usually according to the product difference.
When making luminous zone look glass powder or printing powdered frit printing ink, paint, coating, add luminescent material in colored glass powder or the printing powdered frit.
When making metal strip look powdered glass printing ink, paint, coating, in fusion zone look transparent or semitransparent glass metal, add metallic particles, as gold, silver, copper, aluminum particulate or sheet through atomizing, manufacture wrap look glass powder semi-transparent metals pigment after the pulverizing.
When making thermo-color liquid crystal ink, paint, coating, fusion zone look transparent or semitransparent glass metal internal heating variable color liquid crystal particle, through atomizing, manufacture the translucent thermo-color liquid crystal pigment of wrap look glass powder after the pulverizing, the thermo-color liquid crystal particle of parcel glass powder, can prevent the oxidation of thermo-color liquid crystal particle, improve the work-ing life of thermo-color liquid crystal material.
When making phototropic printing ink, paint, coating, add the phototropic particle in the colored glass powder.As: UV-light variable color particle comprises organic fluorescence, inorganic fluorescence, rare-earth fluorescent particle.Infrared light variable color particle comprises rare earth fluorine, rare earth oxyhalide oxide compound, rare earth oxide.
For improving the consistency of glass powder or printing powdered frit and prepolymer, colored glass powder or printing powdered frit add coupling agent.Coupling agent comprises any in silane coupling agent, titanate coupling agent, aluminic acid lipoprotein coupling agent, zirconium aluminic acid lipoprotein coupling agent, the hyper-dispersant.
The prepolymer that curing glass powder printing ink or photocuring printing powdered frit use, thinner, light trigger, forming agent, stopper, auxiliary agent are the materials used in the existing UV light-curable ink.
Prepolymer comprises: epoxy acrylic resin, polyalcohol modified epoxy acrylic resin, fatty acid modified epoxy acrylic resin, the epoxy soybean oil acrylic resin, the vinylformic acid polyurethane resin, polyether-modified vinylformic acid polyurethane resin, fatty acid modified vinylformic acid polyurethane resin, polyester vinylformic acid polyurethane resin, the epoxy methacrylic resin, polyalcohol modified epoxy methacrylic resin, fatty acid modified epoxy methacrylic resin, epoxy soybean oil methacrylic resin, the methacrylic acid polyurethane resin, polyether-modified methacrylic resin, fatty acid modified methacrylic acid polyurethane resin, one or more in the polyester methacrylic acid polyurethane resin are used.Prepolymer is the acrylic resin that carries out ultraviolet light polymerization in the printing ink.
Thinner comprises: the simple function group acrylate monomer, the bifunctional acrylate monomer, the trifunctional acrylate monomer, the four-functional group acrylate monomer, five functional group's acrylate monomer, the water dispersible acrylate monomer, simple function group methacrylic acid alicyclic monomer, bifunctional methacrylic acid alicyclic monomer, trifunctional methacrylic acid alicyclic monomer, four-functional group methacrylic acid alicyclic monomer, five functional group's methacrylic acid alicyclic monomers, monomeric one or more of water dispersible methacrylate are used.Its effect is to regulate the printing ink viscosity, curing speed, and the curing inks performance is participated in photocuring reaction.
Light trigger is a free radical photo-initiation; comprise: 2; 4,6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO); 4-methylbenzene sulfenyl benzophenone (BMS); 2-methyl isophthalic acid-[4--methylthio group phenyl]-2-morpholinyl-1-acetone; 1-hydroxyl-cyclohexyl-phenyl ketone; 2-hydroxy-2-methyl-1-phenyl-1-acetone; sec.-propyl thia anthraquinone (2; 4 heterogeneous mixtures); 4-dimethylamino-phenylformic acid second fat; 4-dimethylamino-phenylformic acid (2-ethyl) fat; the benzoylbenzoic acid formicester; trisbromomethyl phenyl sulfone; the 4-chlorobenzophenone; 4-methyldiphenyl ketone; the o-benzoylbenzoic acid formicester; benzophenone; in the benzoin dimethylether one or more are used.Light trigger is that radical photoinitiator causes the curing reaction material.
Forming agent comprises: SO2, BSO3, CCO3, AL2O3, MaCO3, talcum powder, kaolin, pearlescence, PE, PP, PVC powder etc.
Inhibitor action is to improve the stability of printing ink, as: the poly-liquid of the compound resistance that Shanghai produces, Japan and light Q-1301, the ST series of refined precious chemistry, Ying Li 510 etc.
Auxiliary agent comprises: flow agent, dispersion agent, smooth agent, defoamer, thixotropic agent etc.
Advantage of the present invention is: 1, by with making the colored glass powder in pigment or the dyestuff adding high-temperature fusion glass, as the tinting material of printing ink, improve the printing ink weather resistance, prevent to fade.2, by printing the tinting material of powdered frit, improve the printing ink weather resistance as printing ink.3, utilize the light transmission of colored glass powder, rate of crosslinking between photosensitive molecular resin when improving uviolizing.4, metallic particles is wrapped in the transparent glass, improves the laser curing velocity of metal ink, prevent the metallic particles oxidation.5, because the colored glass powder is irregular shape, when different angles were observed, different variations took place with brightness in form and aspect, improve the decorate properties of printing ink, coating, paint.6, colored glass powder or printing powdered frit improve the wear resisting property of printing ink, paint, coating, particularly in imitative wooden decorative pattern floor, improve the wear resistance on floor, increase frictional force and work-ing life.
Below in conjunction with embodiment the present invention is further described.
Embodiment:
Embodiment 1:
The preparation of colored glass powder pigment: 1, the transparent glass material is heated to 1250 degree high temperature, makes glass be the molten glass paste.2, the color that requires according to goods fits in special-purpose colorant with pigment not of the same race, pours in the molten glass pulp, stirs, and makes special-purpose colorant and molten glass pulp be mixed into one, manufactures the colored glass slurries.3, the colored glass slurries are cooled to the colored glass fragment rapidly.4, the colored glass fragment is put into grinding machine for grinding with the silane coupling agent of weight ratio 0.5% and is become 0.The colored glass powder of 1-30 micron.
Embodiment 2:
The preparation of colored glass bean vermicelli pigment: 1, the transparent glass material is heated to 1250 degree high temperature, makes glass be the molten glass paste.2, the color that requires according to goods fits in special-purpose colorant with pigment not of the same race, pours in the molten glass pulp, stirs, and makes special-purpose colorant and molten glass pulp be mixed into one, manufactures the colored glass slurries.3, the colored glass slurries are pulled into the colored glass silk by drawing wire machine.4, the colored glass silk cuts into the staple fibre glass yarn with stapling machine.5, the silane coupling agent of staple fibre glass yarn and weight ratio 0.5% will be put into grinding machine for grinding and become 0.The colored glass bean vermicelli of 1-20 micron.
Embodiment 3:
The preparation of metal strip look glass powder pigment: 1, the transparent glass material is heated to 1250 degree high temperature, makes glass be the molten glass paste.2, the color that requires according to goods is poured dyestuff in the molten glass pulp into, stirs, and makes dyestuff and molten glass pulp be mixed into one, manufactures band look transparent glass slurries.3, stir in the fusion zone of levigated metallic particles or the tinsel adding in advance look transparent glass slurries, metallic particles or tinsel are atomized into the metallic particles of parcel transparent glass liquid by spray method.4, the metallic particles of parcel transparent glass liquid is put into the grinding machine for grinding that has rare gas element with the silane coupling agent of weight ratio 0.5% and is become 0.The metal strip look glass particle of 1-20 micron.The metal strip look glass particle of parcel glass, by the refractive nature of glass, accelerating ultraviolet curing speed.
Embodiment 4:
UV photocuring colored glass powder or screen printing glaze arogel printing ink
Colored glass powder or printing powdered frit pigment 10%
Prepolymer
Polyalcohol modified epoxy acrylic resin 15%
Fatty acid modified epoxy acrylic resin 15%
Polyether-modified vinylformic acid polyurethane resin 10%
Polyester vinylformic acid polyurethane resin 10%
Thinner:
Trimethylol propane trimethyl CALCIUM ACRYLATE 5%
Tetramethylolmethane three CALCIUM ACRYLATE 10%
Dipentaerythritol five CALCIUM ACRYLATE 5%
Light trigger:
2,4,6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 1%
Benzophenone and methyldiphenyl ketone 17%
Benzoin dimethylether 1%
Tert-butyl phenol 1%
UV photocuring colored glass powder or screen printing glaze arogel printing ink manufacturing processed are as follows:
At first with colored glass powder or printing powdered frit pigment and polyalcohol modified epoxy acrylic resin 5%; fatty acid modified epoxy acrylic resin 5%; polyether-modified vinylformic acid polyurethane resin 3%; polyester vinylformic acid polyurethane resin 3%; trimethylol propane trimethyl CALCIUM ACRYLATE 2%; tetramethylolmethane three CALCIUM ACRYLATE 3%; Dipentaerythritol five CALCIUM ACRYLATE 2% are mixed pre-slurry; porphyrize on triple-roller mill; after grinding finishes; add remaining polyalcohol modified epoxy acrylic resin 10% respectively; fatty acid modified epoxy acrylic resin 10%; polyether-modified vinylformic acid polyurethane resin 7%; polyester vinylformic acid polyurethane resin 7%; trimethylol propane trimethyl CALCIUM ACRYLATE 3%; tetramethylolmethane three CALCIUM ACRYLATE 7%; Dipentaerythritol five CALCIUM ACRYLATE 3%; 2; 4,6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 1%, benzophenone and methyldiphenyl ketone 17%; benzoin dimethylether 1%; tert-butyl phenol 1% changes-2000 rev/mins 1500 and carries out the high-speed stirring grinding, manufactures UV photocuring colored glass powder or screen printing glaze arogel printing ink.
Embodiment 5:
UV photocuring colored glass powder or printing powdered frit letterpress printing ink
Colored glass powder or printing powdered frit pigment 25%
Prepolymer
Epoxy acrylic resin 15%
Polyether-modified vinylformic acid polyurethane resin 5%
Polyester acrylic polyurethane resin 5%
Thinner:
Trimethylol propane trimethyl CALCIUM ACRYLATE 10%
Tetramethylolmethane three CALCIUM ACRYLATE 10%
Dipentaerythritol five CALCIUM ACRYLATE 1%
Light trigger:
2,4,6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 5%
Benzophenone and methyldiphenyl ketone 1%
Benzoin dimethylether 1%
Amine aided initiating 1%
Tert-butyl phenol 2%
UV photocuring colored glass powder or printing powdered frit letterpress printing ink manufacturing processed are as follows:
At first with colored glass powder or printing powdered frit pigment and epoxy acrylic resin 5%; polyether-modified vinylformic acid polyurethane resin 2%; polyester vinylformic acid polyurethane resin 2%; trimethylol propane trimethyl CALCIUM ACRYLATE 3%; tetramethylolmethane three CALCIUM ACRYLATE 3%, Dipentaerythritol five CALCIUM ACRYLATE 1% are mixed pre-slurry, porphyrize on triple-roller mill; after grinding finishes; add remaining epoxy acrylic resin 10% respectively, polyether-modified vinylformic acid polyurethane resin 3%, polyester vinylformic acid polyurethane resin 3%; trimethylol propane trimethyl CALCIUM ACRYLATE 7%; tetramethylolmethane three CALCIUM ACRYLATE 7%, Dipentaerythritol five CALCIUM ACRYLATE 3%, 2; 4; 6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 5%, benzophenone and methyldiphenyl ketone 1%, benzoin dimethylether 1%; amine aided initiating 1%; tert-butyl phenol 2% changes-2000 rev/mins 1500 and carries out the high-speed stirring grinding, manufactures UV photocuring colored glass powder or printing powdered frit letterpress printing ink.
Embodiment 6:
UV photocuring colored glass powder or screen printing glaze bean vermicelli net printing ink
Metal strip look glass powder or printing powdered frit pigment 30%
Prepolymer
Epoxy acrylic resin 15%
Polyester acrylic polyurethane resin 5%
Vinylformic acid polyurethane resin 20%
Thinner:
Trimethylol propane trimethyl CALCIUM ACRYLATE 5%
Tetramethylolmethane three CALCIUM ACRYLATE 10%
Dipentaerythritol five CALCIUM ACRYLATE 5%
Light trigger:
2,4,6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 1%
Benzophenone and methyldiphenyl ketone 5%
Benzoin dimethylether 1%
Amine aided initiating 1%
Tert-butyl phenol 2%
UV photocuring colored glass powder or printing powdered frit screen printing ink manufacturing processed are as follows:
At first with colored glass powder pigment or printing powdered frit and epoxy acrylic resin 5%; vinylformic acid polyurethane resin 6%; polyester vinylformic acid polyurethane resin 2%; trimethylol propane trimethyl CALCIUM ACRYLATE 2%; tetramethylolmethane three CALCIUM ACRYLATE 3%, Dipentaerythritol five CALCIUM ACRYLATE 2% are mixed pre-slurry, porphyrize on triple-roller mill; after grinding finishes; add remaining epoxy acrylic resin 10% respectively, vinylformic acid polyurethane resin 14%, polyester vinylformic acid polyurethane resin 3%; trimethylol propane trimethyl CALCIUM ACRYLATE 3%; tetramethylolmethane three CALCIUM ACRYLATE 7%, Dipentaerythritol five CALCIUM ACRYLATE 3%, 2; 4; 6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 1%, benzophenone and methyldiphenyl ketone 5%, benzoin dimethylether 1%; amine aided initiating 1%; tert-butyl phenol 2% changes-2000 rev/mins 1500 and carries out the high-speed stirring grinding, manufactures UV photocuring colored glass powder or printing powdered frit screen printing ink.Colored glass powder or printing powdered frit granules of pigments size depend on the size of printing screen mesh, and colored glass powder or printing powdered frit granules of pigments are got 1/3 of silk screen mesh aperture usually.
Embodiment 7:
UV photocuring colored glass powder or printing powdered frit gravure ink
Metal strip look glass powder or printing powdered frit pigment 30%
Prepolymer
Epoxy acrylic resin 5%
Polyester acrylic polyurethane resin 5%
Vinylformic acid polyurethane resin 5%
Alkaline soluble acrylic resin 25%
Thinner:
The three triethylene glycol diacrylate fat 5% that contract
Ethoxyquin trimethylolpropane triacrylate 5%
Ethoxyquin tetramethylolmethane tetrapropylene acid fat 5%
Polyoxyethylene glycol diacrylate fat 5%
Light trigger:
2,4,6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 5%
Benzophenone and methyldiphenyl ketone 1%
Benzoin dimethylether 1%
Amine aided initiating 1%
Tert-butyl phenol 2%
UV photocuring colored glass powder or printing powdered frit gravure ink manufacturing processed are as follows:
At first with colored glass powder pigment or printing powdered frit pigment and epoxy acrylic resin 2%; vinylformic acid polyurethane resin 2%; polyester vinylformic acid polyurethane resin 2%; the alkaline soluble acrylic resin 5% 3 triethylene glycol diacrylate fat 2% that contracts; ethoxyquin trimethylolpropane triacrylate 2%; ethoxyquin tetramethylolmethane tetrapropylene acid fat 2%; polyoxyethylene glycol diacrylate fat 2% mixes pre-slurry; porphyrize on triple-roller mill; after grinding finishes; add remaining epoxy acrylic resin 3% respectively; vinylformic acid polyurethane resin 3%; polyester vinylformic acid polyurethane resin 3%; alkaline soluble acrylic resin 20%; the three triethylene glycol diacrylate fat 3% that contract; ethoxyquin trimethylolpropane triacrylate 3%; ethoxyquin tetramethylolmethane tetrapropylene acid fat 3%, polyoxyethylene glycol diacrylate fat 3%, 2; 4; 6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO) 5%, benzophenone and methyldiphenyl ketone 1%, benzoin dimethylether 1%; amine aided initiating 1%; tert-butyl phenol 2% changes-2000 rev/mins 1500 and carries out the high-speed stirring grinding, manufactures UV photocuring colored glass powder or printing powdered frit gravure ink.
Embodiment 8:
UV photocuring colored glass powder or printing powdered frit paint
Colored glass powder pigment or printing powdered frit pigment 25%
Prepolymer
Epoxy acrylic resin 35%
Vinylformic acid polyurethane resin 5%
Thinner:
The three triethylene glycol diacrylate fat 25% that contract
Light trigger:
Benzophenone and methyldiphenyl ketone 5%
Flow agent 2%
Defoamer 0.5%
Stopper 0.5%
Fire retardant 2%
UV photocuring colored glass powder or printing powdered frit paint manufacturing processed are as follows:
At first the silane coupling agent of colored glass powder pigment or printing powdered frit pigment and weight ratio 1% is ground in shredder and obtain coupling stained glass powder pigment or powdered frit pigment is printed in coupling, with coupling stained glass powder pigment or coupling printing powdered frit pigment and epoxy acrylic resin 10%, vinylformic acid polyurethane resin 5%, the three triethylene glycol diacrylate fat 10% that contract, mix pre-slurry, porphyrize on triple-roller mill, after grinding finishes, add remaining epoxy acrylic resin 25% respectively, the three triethylene glycol diacrylate fat 15% that contract, benzophenone is carried out secondary with methyldiphenyl ketone 5% and is mixed, and grind to form granules of pigments≤20 μ m mill bases, add flow agent 2% again, defoamer 0.5%, stopper 0.5%, fire retardant 2%, the use high speed dispersor stirs, mixing obtains UV photocuring stained glass powder paint or UV photocuring printing powdered frit paint.
Claims (11)
1, a kind of colored glass powder printing ink, paint, coating comprise, colouring matter, and resin, thinner, forming agent, stopper, auxiliary agent is characterized in that: colouring matter adopts colored glass powder or printing powdered frit.
2, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: the colored glass powder be with glass heats after molten state, add pigment or dyestuff and make band look melten glass liquid, cooling, pulverizing is made.
3, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: add prepolymer and light trigger in colored glass powder printing ink or the printing powdered frit, make curing glass powder printing ink or photocuring printing powdered frit.
4, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: the color of pigment or dyestuff is the special-purpose look with color dye or dyestuff preparation in colored glass powder or the printing powdered frit.
5, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: the color in colored glass powder or the printing powdered frit is the colour that monochromatic or multiple color is formed.
6, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: the colored glass powder is after the colored glass liquid with molten state pulls into glass yarn, and through cutting off, pulverizing is made.
7, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: add luminescent material in colored glass powder or the printing powdered frit.
8, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: add metallic particles in the colored glass powder.
9, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: colored glass powder internal heating variable color liquid crystal particle.
10, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: add the phototropic particle in the colored glass powder.
11, colored glass powder printing ink as claimed in claim 1, paint, coating is characterized in that: colored glass powder or printing powdered frit add coupling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100009496A CN101481557A (en) | 2008-01-09 | 2008-01-09 | Colored powdered glass printing ink, oil paint and coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100009496A CN101481557A (en) | 2008-01-09 | 2008-01-09 | Colored powdered glass printing ink, oil paint and coating |
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| Publication Number | Publication Date |
|---|---|
| CN101481557A true CN101481557A (en) | 2009-07-15 |
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| CN102391785A (en) * | 2011-10-18 | 2012-03-28 | 青岛华世基电子有限公司 | Air-spraying blending paint |
| WO2012037802A1 (en) * | 2010-09-25 | 2012-03-29 | 深圳市华熙生物科技有限公司 | Luminous glass printing ink,preparation and printing method on glass product thereof |
| CN104326644A (en) * | 2014-10-17 | 2015-02-04 | 安徽盛世新能源材料科技有限公司 | Melted color decoration glass production technology |
| CN104419246A (en) * | 2013-08-22 | 2015-03-18 | 中国科学院宁波材料技术与工程研究所 | High-temperature-resistant printing ink and preparation method thereof |
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| CN105482513A (en) * | 2014-10-11 | 2016-04-13 | 中国科学院宁波材料技术与工程研究所 | Method for modification and dispersion of glass powder and pigment for ink and high-temperature-resistant ink |
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- 2008-01-09 CN CNA2008100009496A patent/CN101481557A/en active Pending
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| WO2012037802A1 (en) * | 2010-09-25 | 2012-03-29 | 深圳市华熙生物科技有限公司 | Luminous glass printing ink,preparation and printing method on glass product thereof |
| CN102391785A (en) * | 2011-10-18 | 2012-03-28 | 青岛华世基电子有限公司 | Air-spraying blending paint |
| CN104419246A (en) * | 2013-08-22 | 2015-03-18 | 中国科学院宁波材料技术与工程研究所 | High-temperature-resistant printing ink and preparation method thereof |
| CN105482513A (en) * | 2014-10-11 | 2016-04-13 | 中国科学院宁波材料技术与工程研究所 | Method for modification and dispersion of glass powder and pigment for ink and high-temperature-resistant ink |
| CN105482513B (en) * | 2014-10-11 | 2017-12-26 | 中国科学院宁波材料技术与工程研究所 | The modification process for dispersing and high temperature resistant ink of ink glass dust and pigment |
| CN104326644A (en) * | 2014-10-17 | 2015-02-04 | 安徽盛世新能源材料科技有限公司 | Melted color decoration glass production technology |
| CN105368140A (en) * | 2015-12-07 | 2016-03-02 | 佛山市高明绿色德化工有限公司 | Photo-cured high-temperature colored glass printing ink and preparation method therefor and painting method thereof |
| CN106221579B (en) * | 2016-08-14 | 2019-03-22 | 安徽雅圆建材科技有限公司 | With bright pearl effect high intensity exterior coating and preparation method |
| CN106221579A (en) * | 2016-08-14 | 2016-12-14 | 李文刚 | There is bright pearl effect high intensity exterior coating and preparation method |
| CN108659658A (en) * | 2018-05-18 | 2018-10-16 | 张家港宝视特影视器材有限公司 | High brightness moulds the coating material and preparation method thereof of projection screen in vain |
| CN110437676A (en) * | 2019-09-16 | 2019-11-12 | 杭州科望特种油墨有限公司 | One kind is with scape color shifting ink |
| WO2021051824A1 (en) * | 2019-09-16 | 2021-03-25 | 杭州科望特种油墨有限公司 | Ink capable of changing color with environment and solar glass product |
| CN111560184A (en) * | 2020-05-26 | 2020-08-21 | 广东健诚高科玻璃制品股份有限公司 | High-temperature offset printing ink for preparing glass decal paper and preparation method thereof |
| CN116478571A (en) * | 2023-04-26 | 2023-07-25 | 佛山市高明绿色德化工有限公司 | High-temperature UV-LED imprinting ink for glass surface and preparation method thereof |
| CN116206800A (en) * | 2023-04-28 | 2023-06-02 | 乾宇微纳技术(深圳)有限公司 | Medium slurry and preparation method thereof |
| CN116206800B (en) * | 2023-04-28 | 2023-07-21 | 乾宇微纳技术(深圳)有限公司 | Medium slurry and preparation method thereof |
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Application publication date: 20090715 |