CN101475399A - Dry powder additive for riverway sludge self-heat preserving sintering porous brick and use thereof - Google Patents

Dry powder additive for riverway sludge self-heat preserving sintering porous brick and use thereof Download PDF

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Publication number
CN101475399A
CN101475399A CNA2009100459331A CN200910045933A CN101475399A CN 101475399 A CN101475399 A CN 101475399A CN A2009100459331 A CNA2009100459331 A CN A2009100459331A CN 200910045933 A CN200910045933 A CN 200910045933A CN 101475399 A CN101475399 A CN 101475399A
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CN
China
Prior art keywords
riverway sludge
dry powder
heat preserving
powder additive
sludge self
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CNA2009100459331A
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Chinese (zh)
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CN101475399B (en
Inventor
陈文光
蒋正武
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Shanghai Xinjinshan Building Materials Development Co., Ltd.
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SHANGHAI XINJINSHAN SILT RESEARCH DEVELOPMENT Co Ltd
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Priority to CN2009100459331A priority Critical patent/CN101475399B/en
Publication of CN101475399A publication Critical patent/CN101475399A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/63Flame-proofing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Sludge (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention relates to a dry powder additive for heat-insulating wall body materials of buildings, and discloses a dry powder additive for riverway sludge self heat-insulating sintered porous bricks and application thereof. The dry powder additive for the riverway sludge self heat-insulating sintered porous bricks comprises the following compositions in percentage by mass: 30 to 70 percent of saw dust, 20 to 40 percent of cinder, 8 to 30 percent of basalt fibers and 2 to 25 percent of one or two between wood fibers or polystyrene foam particles. By addition of the dry powder additive into the riverway sludge self heat-insulating sintered porous bricks, the early cracking resistant and the later strength of green bricks can be improved, and the heat-insulating property of the riverway sludge self heat-insulating sintered porous bricks can be greatly improved as well.

Description

Dry powder additive for riverway sludge self-heat preserving sintering porous brick and application thereof
Technical field
The present invention relates to a kind of building heat preservation materials for wall dry powder additive, be specifically related to be used to improve the additive of the heat-insulating property and the splitting resistance of riverway sludge self-heat preserving sintering porous brick.
Background technology
Riverway sludge is one of important kind of a kind of municipal solid wastes.City river has accumulated a large amount of inorganicss and organism because for many years sewage is in line in river silt, by and overlying water between diffusion and exchange, become the secondary pollution source.The training of channel in the densely covered networks of rivers such as China water transport river course, rivers and lakes will produce a large amount of mud, and along with the planning and the upgrading in river course, Shanghai, will produce more riverway sludge.How effectively, suit measures to local conditions, the recycle riverway sludge has great importance to avoiding bringing secondary pollution, resource recycling, suggestion conservation-minded society.Both at home and abroad all in the effective method of comprehensive utilization and the technology of active research mud.
Concerning building materials industry, along with constant development of economy, the demand of conventional gelling material such as cement and materials for wall increases gradually, is faced with the day by day deficient condition of starting material equally.Therefore, many countries, particularly developed country have all dropped into great amount of manpower and material resources, developing high-tech, and research and utilization nature and industrial waste substitute natural starting material, produce to reach ecological eco-cement and the materials for wall that requires.The comprehensive utilization riverway sludge is one of effective way of environment protection and changing waste into resources.Along with the fast development of China's capital construction, the demand of building brick is also increasing.Originally the traditional brick-making technology of China is to utilize vitrified bond brickmaking, because it need plough in a large amount of diggings, basic farmland is caused a large amount of destruction, and country prohibites and produces and use clay solid brick, limit production and use porous clay brick.Therefore some Bricks and Tiles Plants are faced with the development predicament of shortage of raw materials.Utilize the riverway sludge instead of clay, produce sintered perforated brick, not only can avoid it to second environmental pollution, and can realize the Sustainable development of Bricks and Tiles Plant.At present, domestic a plurality of patents of invention of having applied for have proposed to utilize mud to produce vitrified brick, as application number 200610040094.0,02137142.3,200620077568.3 etc.From these patents, at present, the riverway sludge sintered perforated brick still exists some problems to need further to solve, and the one, the river course sludge content is lower in the adobe raw material, can not realize the instead of clay of mud 100%; The 2nd, riverway sludge vitrified brick splitting resistance is relatively poor, fraction defective is higher; The 3rd, the heat-insulating property of this brick is relatively poor, can not satisfy the light energy conservation heat-insulation and heat-preservation requirement of modern architecture to materials for wall.The heat-insulating property how research effectively improves sludge self-heat preserving sintering porous brick is one of important channel of realizing building energy conservation, has great practical significance.
Summary of the invention
Technical problem to be solved by this invention is to overcome defective of the prior art, a kind of dry powder additive that is used to make the riverway sludge self-heat preserving brick is provided, utilize this dry powder additive, can increase substantially splitting resistance, interior porosity, the self-heat conserving performance of riverway sludge self-heat preserving brick.
One aspect of the present invention provides a kind of dry powder additive for riverway sludge self-heat preserving sintering porous brick, and its component and mass percent are as follows:
Wood chip 30~70%
Cinder 20~40%
Basalt fibre 8~30%
One or both 2-25% in wood fibre or the polystyrene foam particles.
Preferable, based on the total mass of riverway sludge self-heat preserving sintering porous brick, its component and mass percent are as follows:
Wood chip: 35~65%
Cinder 20~30%
Basalt fibre: 10~20%
Wood fibre: 3~12%
Polystyrene foam particles: 2~8%.
Among the present invention, wood chip is that exsiccant, particle diameter are 0.5~1mm wood chip.
The basalt fibre of the preferred diameter 5-10 of basalt fibre μ m, length 5~15mm.
Wood fibre is the lignin fibre of diameter 5-10 μ m, length 5~10mm preferably.
The particle diameter 0.3-2mm of polystyrene foam particles.
The particle diameter 0.5-3mm of cinder.
The preparation method of dry powder additive of the present invention is: select various starting material in accordance with regulations, press formula rate and add required wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder in stirrer, stir and get final product.Also can directly add in proportion in the riverway sludge adobe.
Second aspect present invention discloses the application of above-mentioned dry powder additive in the preparation riverway sludge self-heat preserving sintering porous brick.
Third aspect present invention discloses a kind of preparation method of riverway sludge self-heat preserving sintering porous brick, is included in that to add weight percent in the raw material be 1~5% above-mentioned dry powder additive.
Add dry powder additive of the present invention in the riverway sludge self-heat preserving brick, it not only can improve the early stage splitting resistance and the later strength of adobe, and because of during the adobe high-temperature roasting or self the burning, or because decomposition discharges gas under the high temperature, or in goods, stayed little pore in a large amount of different apertures because of air hole structure itself, make brick have higher porosity, thereby reduce product density significantly, thermal conductivity, improve the heat-insulating property of riverway sludge sintered perforated brick greatly.In the common building structure is gone along with sb. to guard him, can realize that building energy conservation is more than 50%.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is elaborated.
Embodiment 1:
The riverway sludge self-heat preserving sintering porous brick dry-mix is made up of wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder, and each constituent mass percentage is as follows:
Wood chip: 32%
Basalt fibre: 20%
Wood fibre: 15%
Polystyrene foam particles: 3%
Cinder 30%
The dry powder additive of this proportioning preparation, the volume with 1.5% add in the adobe of riverway sludge sintered perforated brick can improve its splitting resistance, long-term volume stability greatly, improves the finished product rate, and the cracking destructive rate of adobe is 1.2%, and yield rate reaches 97%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.35W/ (mK).
Embodiment 2:
Riverway sludge self-heat preserving sintering porous brick dry-mix of the present invention is made up of wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder, and each constituent mass percentage is as follows:
Wood chip: 40%
Basalt fibre: 15%
Wood fibre: 15%
Polystyrene foam particles: 7%
Cinder 23%
The dry powder additive of this proportioning preparation, the volume with 1.5% add in the adobe of riverway sludge sintered perforated brick can improve its splitting resistance, long-term volume stability greatly, improves the finished product rate, and the cracking destructive rate of adobe is 1.0%, and yield rate reaches 97%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.28W/ (mK).
Case study on implementation 3:
Riverway sludge self-heat preserving sintering porous brick dry-mix of the present invention is made up of wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder, and each constituent mass percentage is as follows:
Wood chip: 45%
Basalt fibre: 10%
Wood fibre: 15%
Polystyrene foam particles: 10%
Cinder 20%
The dry powder additive of this proportioning preparation, the volume with 1.5% add in the adobe of riverway sludge sintered perforated brick can improve its splitting resistance, long-term volume stability greatly, improves the finished product rate, and the cracking destructive rate of adobe is 1.5%, and yield rate reaches 95%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.20W/ (mK).
Embodiment 4
The riverway sludge self-heat preserving sintering porous brick dry-mix is made up of wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder, and each constituent mass percentage is as follows:
Wood chip: 45%
Basalt fibre: 21%
Wood fibre: 9%
Polystyrene foam particles: 3%
Cinder 22%
The dry powder additive of this proportioning preparation, the volume with 1.5% add in the adobe of riverway sludge sintered perforated brick can improve its splitting resistance, long-term volume stability greatly, improves the finished product rate, and the cracking destructive rate of adobe is 1.0%, and yield rate reaches 98%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.45W/ (mK).
Embodiment 5
The riverway sludge self-heat preserving sintering porous brick dry-mix is made up of wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder, and each constituent mass percentage is as follows:
Wood chip: 70%
Basalt fibre: 8%
Polystyrene foam particles: 2%
Cinder 20%
The dry powder additive of this proportioning preparation, the volume with 1.5% add in the adobe of riverway sludge sintered perforated brick can improve its splitting resistance, long-term volume stability greatly, improves the finished product rate, and the cracking destructive rate of adobe is 0.7%, and yield rate reaches 96%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.30W/ (mK).
Embodiment 6
The riverway sludge self-heat preserving sintering porous brick dry-mix is made up of wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder, and each constituent mass percentage is as follows:
Wood chip: 45%
Basalt fibre: 30%
Wood fibre: 5%
Cinder 20%
The dry powder additive of this proportioning preparation, the volume with 1.5% add in the adobe of riverway sludge sintered perforated brick can improve its splitting resistance, long-term volume stability greatly, improves the finished product rate, and the cracking destructive rate of adobe is 1.5%, and yield rate reaches 95%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.29W/ (mK).
Embodiment 7
The riverway sludge self-heat preserving sintering porous brick dry-mix is made up of wood chip, basalt fibre, wood fibre polystyrene foam particles, cinder, and each constituent mass percentage is as follows:
Wood chip: 20%
Basalt fibre: 25%
Wood fibre: 10%
Polystyrene foam particles: 5%
Cinder 40%
The dry powder additive of this proportioning preparation, the volume with 1.5% add in the adobe of riverway sludge sintered perforated brick can improve its splitting resistance, long-term volume stability greatly, improves the finished product rate, and the cracking destructive rate of adobe is 0.2%, and yield rate reaches 98%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.40W/ (mK).
Comparative Examples
Do not add the common riverway sludge sintered perforated brick of dry powder additive, the cracking destructive rate of adobe is 12%, and yield rate only is 70%.The thermal conductivity of the riverway sludge self-heat preserving sintering porous brick that is prepared from is about 0.52W/ (mK).

Claims (9)

1. dry powder additive for riverway sludge self-heat preserving sintering porous brick, its component and mass percent are as follows:
Wood chip 30~70%
Cinder 20~40%
Basalt fibre 8~30%
One or both 2-25% in wood fibre or the polystyrene foam particles.
2. dry powder additive for riverway sludge self-heat preserving sintering porous brick according to claim 1 is characterized in that based on the total mass of riverway sludge self-heat preserving sintering porous brick, its component and mass percent are as follows:
Wood chip: 35~65%
Cinder 20~30%
Basalt fibre: 10~20%
Wood fibre: 3~12%
Polystyrene foam particles: 2~8%.
3. dry powder additive for riverway sludge self-heat preserving sintering porous brick as claimed in claim 1 or 2 is characterized in that described wood chip is that exsiccant, particle diameter are 0.5~1mm wood chip.
4. dry powder additive for riverway sludge self-heat preserving sintering porous brick as claimed in claim 1 or 2 is characterized in that, described basalt fibre diameter 5-10 μ m, and length is 5~15mm.
5. claim 1 or 2 described dry powder additive for riverway sludge self-heat preserving sintering porous brick is characterized in that, described wood fibre diameter 5-10 μ m, length 5~10mm.
6. claim 1 or 2 described dry powder additive for riverway sludge self-heat preserving sintering porous brick is characterized in that, the particle diameter 0.2-2mm of described polystyrene foam particles.
7. claim 1 or 2 described dry powder additive for riverway sludge self-heat preserving sintering porous brick is characterized in that, the particle diameter 1-3mm of described cinder.
8. the application of the described dry powder additive for riverway sludge self-heat preserving sintering porous brick of arbitrary claim in the preparation riverway sludge self-heat preserving sintering porous brick among the claim 1-7.
9. the preparation method of a riverway sludge self-heat preserving sintering porous brick is included in that to add weight percent in the raw material be the described dry powder additive of arbitrary claim among 1~5% the claim 1-7.
CN2009100459331A 2009-01-22 2009-01-22 Dry powder additive for riverway sludge self-heat preserving sintering porous brick and use thereof Active CN101475399B (en)

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Application Number Priority Date Filing Date Title
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CN101475399B CN101475399B (en) 2012-07-04

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101723634B (en) * 2009-11-27 2012-12-05 李莉 Concrete wall material and preparation method thereof
CN106187096A (en) * 2016-07-25 2016-12-07 安徽圆梦建筑有限公司 A kind of emery wheel ash hollow brick and preparation method thereof
CN106242607A (en) * 2016-07-25 2016-12-21 安徽圆梦建筑有限公司 A kind of grinding waste material porous brick
CN106673511A (en) * 2016-12-09 2017-05-17 苏州市世好建材新技术工程有限公司 Production method of small-bore honeycomb building block
CN109809781A (en) * 2019-03-08 2019-05-28 江南大学 Fabricated construction lightweight wall key technology is done in Dredged bed mud solidification

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1060987C (en) * 1996-01-04 2001-01-24 王建华 Technology for producing brick by using flyash
CN1200187C (en) * 2003-06-06 2005-05-04 单国民 Light energy-saving bricks
CN101081732A (en) * 2006-06-02 2007-12-05 林建国 Stone powder sludge sintering brick and method for making the same
CN101105060A (en) * 2006-07-13 2008-01-16 浙江大学 Method for manufacturing diatomite porous thermal insulation brick
CN101157541A (en) * 2007-09-20 2008-04-09 常州市武进区建筑业协会 Method for producing sintering energy-saving tile by employing gehu lake inland river sullage

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101723634B (en) * 2009-11-27 2012-12-05 李莉 Concrete wall material and preparation method thereof
CN106187096A (en) * 2016-07-25 2016-12-07 安徽圆梦建筑有限公司 A kind of emery wheel ash hollow brick and preparation method thereof
CN106242607A (en) * 2016-07-25 2016-12-21 安徽圆梦建筑有限公司 A kind of grinding waste material porous brick
CN106673511A (en) * 2016-12-09 2017-05-17 苏州市世好建材新技术工程有限公司 Production method of small-bore honeycomb building block
CN109809781A (en) * 2019-03-08 2019-05-28 江南大学 Fabricated construction lightweight wall key technology is done in Dredged bed mud solidification

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SE01 Entry into force of request for substantive examination
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Effective date of registration: 20100115

Address after: Shanghai City, Jinshan District Hing tower town North Hing tower brick factory, zip code: 201502

Applicant after: Shanghai Xin Jingshan silt R & D Co., Ltd.

Co-applicant after: Shanghai Xinjinshan Building Materials Development Co., Ltd.

Address before: Shanghai City, Jinshan District Hing tower town North Hing tower brick factory, zip code: 201502

Applicant before: Shanghai Xinjinshan Silt Research Development Co., Ltd.

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GR01 Patent grant