CN101474901B - Heat-insulating pad pasting - Google Patents

Heat-insulating pad pasting Download PDF

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Publication number
CN101474901B
CN101474901B CN 200910105088 CN200910105088A CN101474901B CN 101474901 B CN101474901 B CN 101474901B CN 200910105088 CN200910105088 CN 200910105088 CN 200910105088 A CN200910105088 A CN 200910105088A CN 101474901 B CN101474901 B CN 101474901B
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China
Prior art keywords
layer
heat insulation
agau
film
insulation type
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Expired - Fee Related
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CN 200910105088
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Chinese (zh)
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CN101474901A (en
Inventor
李金明
佘自力
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Zhongshan Wanfeng Adhesive Tape & Electron Co Ltd
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Zhongshan Wanfeng Adhesive Tape & Electron Co Ltd
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Priority to CN 200910105088 priority Critical patent/CN101474901B/en
Publication of CN101474901A publication Critical patent/CN101474901A/en
Application granted granted Critical
Publication of CN101474901B publication Critical patent/CN101474901B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention relates to an energy-saving material, in particular to a heat insulation film. The heat insulation film has a laminar structure, and comprises a self-cleaning layer, a scratch resisting layer, a first substrate layer, a film coating layer, a first adhesive layer, a second substrate layer, a second adhesive layer and a mold release layer arranged from inside to outside, wherein the film coating layer is multicoating, and a film system structure of the multicoating is ZAO-AgAu-TiO2-AgAu-ZAO, wherein a ZAO film layer is made of aluminum zinc oxide, a AgAu film layer is made of gold-silver alloy, the content of Au in the AgAu is 2 to 6 percent, and a TiO2 film layer is made of titanium dioxide. The heat insulation film is self-cleaning, scratch resistant and convenient to use, and has the advantages of good heat insulation effect and high visible light transmittance.

Description

A kind of Heat insulation type adhering film
Technical field
The present invention relates to energy-saving material, relate in particular to a kind of Heat insulation type adhering film.
Background technology
For reaching energy-conservation purpose,, often require when satisfying the printing opacity requirement, to require ornament materials to have effect of heat insulation concurrently in occasions such as house decoratons.Means commonly used are on materials such as glass, to paste Heat insulation type adhering film.
Existing Heat insulation type adhering film generally adopts and is coated with multilayer film on the matrix, and the film structure of multilayer film is generally " medium-metal-dielectric " or " medium-metal-dielectric-metal-dielectric ", and mostly metal level is silver layer, and effect of heat insulation is bad.During pad pasting, need gluing or on-the-spot applying adhesive layer, generally need the patent personnel to adopt the patent instrument to accomplish, use inconvenient.This pad pasting will be handled the light transmittance that then reduces pad pasting of a specified duration with cleaning agent after polluting.
Summary of the invention
The objective of the invention is to overcome the weak point of above-mentioned prior art and provide a kind of and self-cleaningly, anti-scrape, Heat insulation type adhering film easy to use, the present invention also aims to provide a kind of good heat-insulation effect and the high Heat insulation type adhering film of visible light transmittance rate.
The object of the invention can be realized through following technical scheme:
A kind of Heat insulation type adhering film has layer structure, it is characterized in that: from outside to inside; The order that is provided with of each layer is self-cleaning layer-resist and scrape layer-first substrate layer-coatings-first adhesive layer-second substrate layer-second adhesive layer-separated type material layer, wherein; Coatings is a multicoating, and its film structure is ZAO-AgAu-TiO2-AgAu-ZAO, and the ZAO rete is a zinc oxide aluminum; The AgAu rete is an electrum, and the content of Au in AgAu is 2%-6%, and the TiO2 rete is a titanium dioxide.
A kind of Heat insulation type adhering film is characterized in that: the content of said Au in AgAu is 4%-5%; The thickness of AgAu rete is 3nm-30nm.
A kind of Heat insulation type adhering film is characterized in that: said self-cleaning layer is a Nano titanium dioxide.
A kind of Heat insulation type adhering film is characterized in that: said first substrate layer and said second substrate layer are flexible parent metal.
A kind of Heat insulation type adhering film is characterized in that: said first substrate layer and said second substrate layer are the PET film.
A kind of Heat insulation type adhering film is characterized in that: said first adhesive layer is hot melt adhesive or self-adhesive.
A kind of Heat insulation type adhering film is characterized in that: said second adhesive layer is a self-adhesive.
A kind of Heat insulation type adhering film is characterized in that: said release layer is release liners or mould release membrance.
The Heat insulation type adhering film that the present invention relates to; From outside to inside, the order that is provided with of each layer is the self-cleaning layer-anti-layer-first substrate layer-coatings-first adhesive layer-second substrate layer-second adhesive layer-separated type material layer of scraping; Coatings is arranged between first substrate layer and second substrate layer; No matter be when fitting, still in the use, all can the scratch or the coatings of wearing and tearing; The outer patent of first substrate layer is provided with that one deck is anti-scrapes layer, avoids because of the scratch of accident to first substrate layer, thereby causes the oxidation of coatings; The outermost layer of Heat insulation type adhering film of the present invention is set to self-cleaning layer, compares with existing pad pasting, has reduced the corrosion and the wearing and tearing that pad pasting are brought because of cleaning; Heat insulation type adhering film of the present invention, second adhesive layer be and the usefulness of material applying such as glass, opens the separated type material layer can directly use, and the existing pad pasting of contrast has characteristics easy to use.The Heat insulation type adhering film that the present invention relates to, the content of the Au of AgAu is merely 2%-6% in its assembly of thin films, has reduced about 2/3rds than prior art, greatly reduces cost.Because of Au content lower (the visible light partial reflectance is low), the light transmittance of thermal isolation film increases simultaneously, and compared with prior art, it is brighter that thermal insulation film seems.The ZAO-AgAu-TiO2-AgAu-ZAO film structure, the ectonexine medium adopts material different, forms real double thermal insulation, and with comparing of the single medium of ectonexine, effect of heat insulation is better.ZAO and the AgAu combination that contains Au2%-6%, its two-way effect of heat insulation all significantly improves more than or equal to the 760nm wavelength time, because the adding of Au is arranged, it is to visible optical transmission and all much higher than Ag layer to the obstruct of infrared waves.Therefore, Heat insulation type adhering film visible light transmittance rate of the present invention is high, effect of heat insulation is better.
Description of drawings
Fig. 1 is the schematic cross-section of first embodiment of the invention.
Fig. 2 is the sketch map of first embodiment of the invention coatings.
The specific embodiment
To combine accompanying drawing that the present invention is made further detailed description below.
With reference to figure 1, first embodiment of the present invention is a kind of Heat insulation type adhering film, has layer structure; It is characterized in that: from outside to inside, the order that is provided with of each layer is the anti-layer 102-first substrate layer 103-coatings 104-first adhesive layer 105-second substrate layer 106-second adhesive layer 107-separated type material layer 108 of scraping of self-cleaning layer 101-; Wherein, coatings 104 is a multicoating, with reference to figure 2; Its film structure is ZAO-AgAu-TiO2-AgAu-ZAO, and ZAO rete 1041 (and 1045) is a zinc oxide aluminum, and AgAu rete 1042 (and 1044) is an electrum; The content of Au in AgAu is 4%, and the thickness of AgAu rete 1042 (and 1044) is 8nm.TiO2 rete 1043 is a titanium dioxide.In the present embodiment; Said self-cleaning layer 101 is Nano titanium dioxides; The said anti-layer 102 of scraping adopts the anti-blooming of scraping of the prior art, and so imperial unicorn is disclosed in Chinese invention patent document CN100426008C anti-ly scrapes blooming, can certainly adopt other anti-material of scraping of selling on the market; Said first substrate layer 103 is flexible PET film with said second substrate layer 106; Said first adhesive layer 105 is a hot melt adhesive, and said second adhesive layer 107 is a self-adhesive, and said release layer 108 is mould release membrances.Refer again to Fig. 2, in the present embodiment, the thickness of ZAO rete 1041 (and 1045) is 20nm, and the thickness of TiO2 rete 1043 is 12nm.Properties of product, visible light transmittance rate about 85%, the infrared waves rejection rate is greater than 96%.A distortion as present embodiment replaces zinc oxide aluminum with tin-antiomony oxide, and all the other structures are constant, and product light transmittance and infrared waves rejection rate are constant basically.

Claims (8)

1. a Heat insulation type adhering film has layer structure, it is characterized in that: from outside to inside; The order that is provided with of each layer is self-cleaning layer-resist and scrape layer-first substrate layer-coatings-first adhesive layer-second substrate layer-second adhesive layer-separated type material layer, wherein; Coatings is a multicoating, and its film structure does
ZAO-AgAu-TiO2-AgAu-ZAO,
The ZA0 rete is a zinc oxide aluminum, and the AgAu rete is an electrum, and the content of Au in AgAu is 2%-6%, and the TiO2 rete is a titanium dioxide;
The thickness of ZA0 rete is 20nm, and the thickness of TiO2 rete is 12nm.
2. a kind of Heat insulation type adhering film according to claim 1 is characterized in that: the content of said Au in AgAu is 4%-5%; The thickness of AgAu rete is 3nm-30nm.
3. a kind of Heat insulation type adhering film according to claim 1 is characterized in that: said self-cleaning layer is a Nano titanium dioxide.
4. a kind of Heat insulation type adhering film according to claim 1 is characterized in that: said first substrate layer and said second substrate layer are flexible parent metal.
5. a kind of Heat insulation type adhering film according to claim 4 is characterized in that: said first substrate layer and said second substrate layer are the PET film.
6. a kind of Heat insulation type adhering film according to claim 1 is characterized in that: said first adhesive layer is hot melt adhesive or self-adhesive.
7. a kind of Heat insulation type adhering film according to claim 1 is characterized in that: said second adhesive layer is a self-adhesive.
8. a kind of Heat insulation type adhering film according to claim 1 is characterized in that: said separated type material layer is release liners or mould release membrance.
CN 200910105088 2009-01-16 2009-01-16 Heat-insulating pad pasting Expired - Fee Related CN101474901B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200910105088 CN101474901B (en) 2009-01-16 2009-01-16 Heat-insulating pad pasting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200910105088 CN101474901B (en) 2009-01-16 2009-01-16 Heat-insulating pad pasting

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CN101474901A CN101474901A (en) 2009-07-08
CN101474901B true CN101474901B (en) 2012-12-05

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103507370A (en) * 2012-06-20 2014-01-15 苏州金海薄膜科技发展有限公司 Scratch-resistant stain-repellent solar heat insulation membrane
CN103302934B (en) * 2013-05-25 2015-09-23 甘春丽 A kind of antifouling light modulation thermal isolation film
CN104354412A (en) * 2014-11-03 2015-02-18 大连爱瑞德纳米科技有限公司 Solar heat insulation film and method for continuously preparing solar heat insulation films
CN106827722B (en) * 2017-03-20 2019-06-07 大连爱瑞德纳米科技有限公司 Multifunctional glass film
CN112552833A (en) * 2020-07-24 2021-03-26 九江力达科技有限公司 Safe heat-insulation roof car cover film and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003213230A (en) * 2002-01-25 2003-07-30 Asahi Glass Co Ltd Protective film

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003213230A (en) * 2002-01-25 2003-07-30 Asahi Glass Co Ltd Protective film

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JP平2-202441A 1990.08.10
JP特开平4-091936A 1992.03.25

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Granted publication date: 20121205

Termination date: 20130116